JP2004510834A5 - - Google Patents
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- JP2004510834A5 JP2004510834A5 JP2001509408A JP2001509408A JP2004510834A5 JP 2004510834 A5 JP2004510834 A5 JP 2004510834A5 JP 2001509408 A JP2001509408 A JP 2001509408A JP 2001509408 A JP2001509408 A JP 2001509408A JP 2004510834 A5 JP2004510834 A5 JP 2004510834A5
- Authority
- JP
- Japan
- Prior art keywords
- polyamide
- ammonium
- clay
- acid
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000004927 clay Substances 0.000 description 224
- 229910052570 clay Inorganic materials 0.000 description 224
- 239000000203 mixture Substances 0.000 description 200
- 239000000463 material Substances 0.000 description 194
- -1 ammonium cations Chemical class 0.000 description 150
- 239000004952 Polyamide Substances 0.000 description 142
- 229920002647 polyamide Polymers 0.000 description 142
- 229920000642 polymer Polymers 0.000 description 115
- 239000011528 polyamide (building material) Substances 0.000 description 110
- 239000002131 composite material Substances 0.000 description 93
- 239000002114 nanocomposite Substances 0.000 description 91
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 81
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 68
- 239000002245 particle Substances 0.000 description 67
- 239000010410 layer Substances 0.000 description 66
- 125000004432 carbon atoms Chemical group C* 0.000 description 63
- 229910052739 hydrogen Inorganic materials 0.000 description 56
- 239000001257 hydrogen Substances 0.000 description 56
- 210000001772 Blood Platelets Anatomy 0.000 description 55
- WNLRTRBMVRJNCN-UHFFFAOYSA-N Adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 48
- 239000011159 matrix material Substances 0.000 description 46
- 229910052901 montmorillonite Inorganic materials 0.000 description 46
- KARVSHNNUWMXFO-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane;hydrate Chemical compound O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O KARVSHNNUWMXFO-UHFFFAOYSA-N 0.000 description 44
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 42
- 235000012216 bentonite Nutrition 0.000 description 41
- 150000001768 cations Chemical class 0.000 description 39
- 229920001577 copolymer Polymers 0.000 description 36
- 238000002425 crystallisation Methods 0.000 description 36
- 230000005712 crystallization Effects 0.000 description 36
- 150000004985 diamines Chemical class 0.000 description 35
- 229910052760 oxygen Inorganic materials 0.000 description 35
- 239000003760 tallow Substances 0.000 description 35
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 34
- 239000001301 oxygen Substances 0.000 description 34
- 239000007789 gas Substances 0.000 description 32
- 230000027455 binding Effects 0.000 description 30
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 30
- 239000003446 ligand Substances 0.000 description 30
- 150000001875 compounds Chemical class 0.000 description 29
- 230000035699 permeability Effects 0.000 description 29
- PNCQLRYMHQOAOR-UHFFFAOYSA-N bis(2-hydroxyethyl)-methyl-octadecylazanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(CCO)CCO PNCQLRYMHQOAOR-UHFFFAOYSA-N 0.000 description 28
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 28
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 description 27
- 238000009833 condensation Methods 0.000 description 27
- 230000005494 condensation Effects 0.000 description 27
- 229920000139 polyethylene terephthalate Polymers 0.000 description 27
- 239000005020 polyethylene terephthalate Substances 0.000 description 27
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 26
- 229940092782 Bentonite Drugs 0.000 description 26
- 239000000440 bentonite Substances 0.000 description 26
- 229910000278 bentonite Inorganic materials 0.000 description 26
- 238000002156 mixing Methods 0.000 description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 25
- 239000000126 substance Substances 0.000 description 25
- 239000006185 dispersion Substances 0.000 description 23
- 229910052757 nitrogen Inorganic materials 0.000 description 23
- 235000015424 sodium Nutrition 0.000 description 23
- 239000011734 sodium Substances 0.000 description 22
- 229910052708 sodium Inorganic materials 0.000 description 22
- 230000002829 reduced Effects 0.000 description 21
- 239000001361 adipic acid Substances 0.000 description 20
- 235000011037 adipic acid Nutrition 0.000 description 20
- 150000002430 hydrocarbons Chemical class 0.000 description 20
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 description 20
- 239000011780 sodium chloride Substances 0.000 description 20
- 125000003545 alkoxy group Chemical group 0.000 description 19
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 19
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 18
- 239000007787 solid Substances 0.000 description 18
- 229940080314 Sodium Bentonite Drugs 0.000 description 17
- 150000003868 ammonium compounds Chemical class 0.000 description 17
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 description 17
- 230000001965 increased Effects 0.000 description 17
- 150000004010 onium ions Chemical class 0.000 description 17
- 229910000280 sodium bentonite Inorganic materials 0.000 description 17
- 239000000155 melt Substances 0.000 description 16
- 238000002844 melting Methods 0.000 description 16
- 150000002892 organic cations Chemical class 0.000 description 16
- QQVIHTHCMHWDBS-UHFFFAOYSA-N Isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 15
- 125000000217 alkyl group Chemical group 0.000 description 15
- 150000003863 ammonium salts Chemical class 0.000 description 15
- 239000011541 reaction mixture Substances 0.000 description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 15
- 150000001412 amines Chemical class 0.000 description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 238000001125 extrusion Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000008188 pellet Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 12
- 238000004458 analytical method Methods 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- RXOHFPCZGPKIRD-UHFFFAOYSA-N 2,6-Naphthalenedicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 10
- ZVMAGJJPTALGQB-UHFFFAOYSA-N 2-[3-(carboxymethoxy)phenoxy]acetic acid Chemical compound OC(=O)COC1=CC=CC(OCC(O)=O)=C1 ZVMAGJJPTALGQB-UHFFFAOYSA-N 0.000 description 10
- JFCQEDHGNNZCLN-UHFFFAOYSA-N Glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 10
- CXMXRPHRNRROMY-UHFFFAOYSA-N Sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 10
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 150000004820 halides Chemical group 0.000 description 10
- 238000000399 optical microscopy Methods 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 239000004760 aramid Substances 0.000 description 9
- 229920003235 aromatic polyamide Polymers 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 9
- 150000002431 hydrogen Chemical class 0.000 description 9
- 229920001690 polydopamine Polymers 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 239000004677 Nylon Substances 0.000 description 8
- 125000002947 alkylene group Chemical group 0.000 description 8
- CPELXLSAUQHCOX-UHFFFAOYSA-M bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 8
- 238000005341 cation exchange Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- 230000000875 corresponding Effects 0.000 description 8
- PXGZQGDTEZPERC-UHFFFAOYSA-N cyclohexane-1,4-dicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 8
- 229920001778 nylon Polymers 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 8
- XFEGRFIENDJTCK-UHFFFAOYSA-N 2-phenyl-2,3-dihydroindene-1,1-dicarboxylic acid Chemical compound C1C2=CC=CC=C2C(C(=O)O)(C(O)=O)C1C1=CC=CC=C1 XFEGRFIENDJTCK-UHFFFAOYSA-N 0.000 description 7
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 7
- 239000000654 additive Substances 0.000 description 7
- 150000001450 anions Chemical class 0.000 description 7
- 238000000113 differential scanning calorimetry Methods 0.000 description 7
- 238000004821 distillation Methods 0.000 description 7
- 238000005755 formation reaction Methods 0.000 description 7
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 7
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 239000004215 Carbon black (E152) Chemical group 0.000 description 6
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 150000001991 dicarboxylic acids Chemical class 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 239000010445 mica Substances 0.000 description 6
- 229910052618 mica group Inorganic materials 0.000 description 6
- GLUUGHFHXGJENI-UHFFFAOYSA-N piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 6
- 229920001142 polymer nanocomposite Polymers 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 241000894007 species Species 0.000 description 6
- 238000004627 transmission electron microscopy Methods 0.000 description 6
- PIICEJLVQHRZGT-UHFFFAOYSA-N 1,2-ethanediamine Chemical group NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
- XFNJVJPLKCPIBV-UHFFFAOYSA-N 1,3-Diaminopropane Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 5
- YQPCHPBGAALCRT-UHFFFAOYSA-N 2-[1-(carboxymethyl)cyclohexyl]acetic acid Chemical compound OC(=O)CC1(CC(O)=O)CCCCC1 YQPCHPBGAALCRT-UHFFFAOYSA-N 0.000 description 5
- BDJRBEYXGGNYIS-UHFFFAOYSA-N Azelaic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 5
- QEVGZEDELICMKH-UHFFFAOYSA-N Diglycolic acid Chemical compound OC(=O)COCC(O)=O QEVGZEDELICMKH-UHFFFAOYSA-N 0.000 description 5
- NAQMVNRVTILPCV-UHFFFAOYSA-N Hexamethylenediamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 206010040844 Skin exfoliation Diseases 0.000 description 5
- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 description 5
- CRVGTESFCCXCTH-UHFFFAOYSA-O bis(2-hydroxyethyl)-methylazanium Chemical compound OCC[NH+](C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-O 0.000 description 5
- 238000000071 blow moulding Methods 0.000 description 5
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 229910000271 hectorite Inorganic materials 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 5
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 5
- 239000000138 intercalating agent Substances 0.000 description 5
- 238000010128 melt processing Methods 0.000 description 5
- 238000000386 microscopy Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid group Chemical group C(C=1C(C(=O)O)=CC=CC1)(=O)O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 5
- 239000002954 polymerization reaction product Substances 0.000 description 5
- 229910000275 saponite Inorganic materials 0.000 description 5
- 239000001384 succinic acid Substances 0.000 description 5
- UVZICZIVKIMRNE-UHFFFAOYSA-N thiodiacetic acid Chemical compound OC(=O)CSCC(O)=O UVZICZIVKIMRNE-UHFFFAOYSA-N 0.000 description 5
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-Tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 4
- LCJRHAPPMIUHLH-UHFFFAOYSA-N 1-$l^{1}-azanylhexan-1-one Chemical compound [CH]CCCCC([N])=O LCJRHAPPMIUHLH-UHFFFAOYSA-N 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N Caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 4
- IKHGUXGNUITLKF-UHFFFAOYSA-N acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 4
- SUZSZZWHCFLFSP-UHFFFAOYSA-M bis(2-hydroxyethyl)-methyl-octadecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(CCO)CCO SUZSZZWHCFLFSP-UHFFFAOYSA-M 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000004299 exfoliation Methods 0.000 description 4
- REYJJPSVUYRZGE-UHFFFAOYSA-O hydron;octadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCC[NH3+] REYJJPSVUYRZGE-UHFFFAOYSA-O 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 150000003951 lactams Chemical class 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000012299 nitrogen atmosphere Substances 0.000 description 4
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 4
- 229910000273 nontronite Inorganic materials 0.000 description 4
- 238000010899 nucleation Methods 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 229910052698 phosphorus Chemical group 0.000 description 4
- 239000011574 phosphorus Chemical group 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229910052904 quartz Inorganic materials 0.000 description 4
- 239000010453 quartz Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- PDSVZUAJOIQXRK-UHFFFAOYSA-N trimethyl(octadecyl)azanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)C PDSVZUAJOIQXRK-UHFFFAOYSA-N 0.000 description 4
- 229910052902 vermiculite Inorganic materials 0.000 description 4
- 239000010455 vermiculite Substances 0.000 description 4
- 235000019354 vermiculite Nutrition 0.000 description 4
- DNXOCFKTVLHUMU-UHFFFAOYSA-N 2-[4-(carboxymethoxy)phenoxy]acetic acid Chemical compound OC(=O)COC1=CC=C(OCC(O)=O)C=C1 DNXOCFKTVLHUMU-UHFFFAOYSA-N 0.000 description 3
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 3
- 239000004953 Aliphatic polyamide Substances 0.000 description 3
- 229920000299 Nylon 12 Polymers 0.000 description 3
- 229920003231 aliphatic polyamide Polymers 0.000 description 3
- VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 3
- 150000007942 carboxylates Chemical group 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 239000002734 clay mineral Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- 230000001264 neutralization Effects 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 229920000406 phosphotungstic acid polymer Polymers 0.000 description 3
- 229910052615 phyllosilicate Inorganic materials 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- 125000004066 1-hydroxyethyl group Chemical group [H]OC([H])([*])C([H])([H])[H] 0.000 description 2
- FQLAJSQGBDYBAL-UHFFFAOYSA-N 3-(azepane-1-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2CCCCCC2)=C1 FQLAJSQGBDYBAL-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 2
- 229920000305 Nylon 6,10 Polymers 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000005210 alkyl ammonium group Chemical group 0.000 description 2
- 239000002168 alkylating agent Substances 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 230000000111 anti-oxidant Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- 235000013405 beer Nutrition 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-O bis(2-hydroxyethyl)azanium Chemical compound OCC[NH2+]CCO ZBCBWPMODOFKDW-UHFFFAOYSA-O 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-O butylazanium Chemical compound CCCC[NH3+] HQABUPZFAYXKJW-UHFFFAOYSA-O 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229910052798 chalcogen Inorganic materials 0.000 description 2
- 150000001787 chalcogens Chemical class 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- YNCKYQRLEFFNQC-UHFFFAOYSA-N diethoxy-methyl-octadecylazanium Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(OCC)OCC YNCKYQRLEFFNQC-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 2
- 238000010101 extrusion blow moulding Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 125000003827 glycol group Chemical group 0.000 description 2
- 238000003621 hammer milling Methods 0.000 description 2
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- 238000010902 jet-milling Methods 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
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- BJQWBACJIAKDTJ-UHFFFAOYSA-N tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC BJQWBACJIAKDTJ-UHFFFAOYSA-N 0.000 description 1
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- WFIYFFUAOQKJJS-UHFFFAOYSA-N tetraoctylphosphanium Chemical compound CCCCCCCC[P+](CCCCCCCC)(CCCCCCCC)CCCCCCCC WFIYFFUAOQKJJS-UHFFFAOYSA-N 0.000 description 1
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| US14335299P | 1999-07-12 | 1999-07-12 | |
| US35420599A | 1999-07-15 | 1999-07-15 | |
| US09/452,826 US6417262B1 (en) | 1998-12-07 | 1999-12-01 | High barrier amorphous polyamide-clay nanocomposite and a process for preparing same |
| US21006400P | 2000-06-07 | 2000-06-07 | |
| PCT/US2000/016483 WO2001004197A1 (en) | 1999-07-12 | 2000-06-14 | A polyamide composition comprising a layered clay material modified with an alkoxylated onium compound |
Publications (2)
| Publication Number | Publication Date |
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| JP2004510834A JP2004510834A (ja) | 2004-04-08 |
| JP2004510834A5 true JP2004510834A5 (es) | 2004-12-24 |
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| JP2001509408A Pending JP2004510834A (ja) | 1999-07-12 | 2000-06-14 | アルコキシル化オニウム化合物変性層状クレー材料含有ポリアミド組成物 |
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| JP (1) | JP2004510834A (es) |
| WO (1) | WO2001004197A1 (es) |
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| US6841211B1 (en) * | 2000-05-12 | 2005-01-11 | Pechiney Emballage Flexible Europe | Containers having improved barrier and mechanical properties |
| EP1308478B1 (en) * | 2001-10-31 | 2008-08-20 | Mitsubishi Gas Chemical Company, Inc. | Polyamide resin composition |
| EP1405874B1 (en) | 2002-10-03 | 2014-03-26 | Mitsubishi Gas Chemical Company, Inc. | Process for production of polyamide composite material |
| CA2510156A1 (en) * | 2002-12-20 | 2004-07-15 | Dow Global Technologies Inc. | Polymerized macrocyclic oligomer nanocomposite compositions |
| WO2004113448A1 (ja) * | 2003-06-18 | 2004-12-29 | Bridgestone Corporation | 高分子組成物、並びにこれを用いた高圧ホース、球技用ボール及び自転車用タイヤチューブ |
| US20050009976A1 (en) * | 2003-07-10 | 2005-01-13 | Honeywell International, Inc. | Delamination-resistant, barrier polyamide compositions for 3-layer pet beverage bottles |
| WO2006045641A1 (en) * | 2004-10-27 | 2006-05-04 | Arkema France | Process for the production of (co) polyamide nanocomposite materials |
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| US4739007A (en) * | 1985-09-30 | 1988-04-19 | Kabushiki Kaisha Toyota Chou Kenkyusho | Composite material and process for manufacturing same |
| US6084019A (en) * | 1996-12-31 | 2000-07-04 | Eastman Chemical Corporation | High I.V. polyester compositions containing platelet particles |
| CA2295293A1 (en) * | 1997-07-09 | 1999-01-21 | Robert Boyd Barbee | Polyester composite material and method for its manufacturing |
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2000
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- 2000-06-14 WO PCT/US2000/016483 patent/WO2001004197A1/en active Application Filing
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