JP2004504454A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2004504454A5 JP2004504454A5 JP2002514209A JP2002514209A JP2004504454A5 JP 2004504454 A5 JP2004504454 A5 JP 2004504454A5 JP 2002514209 A JP2002514209 A JP 2002514209A JP 2002514209 A JP2002514209 A JP 2002514209A JP 2004504454 A5 JP2004504454 A5 JP 2004504454A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- alkyl
- same
- different
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000003118 aryl group Chemical group 0.000 description 34
- 125000000217 alkyl group Chemical group 0.000 description 25
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 16
- 229910052736 halogen Inorganic materials 0.000 description 16
- 150000002367 halogens Chemical class 0.000 description 16
- 229920001296 polysiloxane Polymers 0.000 description 16
- -1 3,3,3-trifluoropropyl Chemical group 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 14
- 238000000034 method Methods 0.000 description 14
- 125000003545 alkoxy group Chemical group 0.000 description 13
- 150000001447 alkali salts Chemical class 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 12
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 12
- 125000002877 alkyl aryl group Chemical group 0.000 description 10
- 239000004593 Epoxy Substances 0.000 description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 9
- 125000003710 aryl alkyl group Chemical group 0.000 description 8
- 125000000623 heterocyclic group Chemical group 0.000 description 8
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 8
- 229920006395 saturated elastomer Polymers 0.000 description 8
- 229910052720 vanadium Inorganic materials 0.000 description 8
- 150000001336 alkenes Chemical class 0.000 description 7
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 7
- 125000004093 cyano group Chemical group *C#N 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 6
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 6
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 6
- 125000004423 acyloxy group Chemical group 0.000 description 6
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 6
- 125000005099 aryl alkyl carbonyl group Chemical group 0.000 description 6
- 125000005129 aryl carbonyl group Chemical group 0.000 description 6
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 description 6
- 125000003739 carbamimidoyl group Chemical group C(N)(=N)* 0.000 description 6
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 150000001735 carboxylic acids Chemical class 0.000 description 6
- 125000003010 ionic group Chemical group 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 6
- 239000002243 precursor Substances 0.000 description 6
- 229960002317 succinimide Drugs 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 5
- 125000002355 alkine group Chemical group 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 229920000233 poly(alkylene oxides) Chemical class 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical class OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001408 amides Chemical class 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 101100294115 Caenorhabditis elegans nhr-4 gene Proteins 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000004663 dialkyl amino group Chemical group 0.000 description 2
- 125000004188 dichlorophenyl group Chemical group 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000001072 heteroaryl group Chemical group 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920001281 polyalkylene Chemical class 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 125000001174 sulfone group Chemical group 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 125000005309 thioalkoxy group Chemical group 0.000 description 2
- 229920000428 triblock copolymer Polymers 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- PFCDGQOZMFOVHJ-UHFFFAOYSA-N CC(C(Cl)I)=O Chemical compound CC(C(Cl)I)=O PFCDGQOZMFOVHJ-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0009722A FR2812296B1 (fr) | 2000-07-25 | 2000-07-25 | Procede de synthese de copolymeres hybrides et organiques par polymerisation radicalaire controlee |
| PCT/FR2001/002433 WO2002008307A1 (fr) | 2000-07-25 | 2001-07-25 | Procede de synthese de copolymeres hybrides silicones et organiques par polymerisation radicalaire controlee |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004504454A JP2004504454A (ja) | 2004-02-12 |
| JP2004504454A5 true JP2004504454A5 (https=) | 2006-01-05 |
| JP4025192B2 JP4025192B2 (ja) | 2007-12-19 |
Family
ID=8852878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002514209A Expired - Lifetime JP4025192B2 (ja) | 2000-07-25 | 2001-07-25 | 制御した遊離基重合によってシリコーン及び有機ハイブリッド共重合体を合成する方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6858696B2 (https=) |
| EP (1) | EP1309638B1 (https=) |
| JP (1) | JP4025192B2 (https=) |
| CN (1) | CN1280324C (https=) |
| AT (1) | ATE276292T1 (https=) |
| AU (1) | AU2001278565A1 (https=) |
| DE (1) | DE60105620T2 (https=) |
| FR (1) | FR2812296B1 (https=) |
| WO (1) | WO2002008307A1 (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2826568B1 (fr) * | 2001-06-29 | 2005-09-02 | Rhodia Chimie Sa | Procede de stabilisation de formulation a base de tensioactifs et comprenant une huile organique, minerale et/ ou derive |
| US7026414B1 (en) * | 2001-12-06 | 2006-04-11 | Northwestern University | Methods for the preparation of monodisperse high polymers by mechanical degradation |
| DE10227338B4 (de) | 2002-06-19 | 2006-05-24 | Byk-Chemie Gmbh | Verwendung von Polyacrylat-modifizierten Polysiloxanen als Verlaufmittel in Beschichtungsmitteln |
| FR2842814B1 (fr) | 2002-07-26 | 2004-10-22 | Coatex Sas | Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications. |
| WO2005075542A1 (en) * | 2004-02-02 | 2005-08-18 | Dow Corning Corporation | Mq-t propyl siloxane resins |
| FR2889194A1 (fr) * | 2005-07-27 | 2007-02-02 | Rhodia Chimie Sa | Copolymere a blocs comprenant un bloc lcst presentant une temperature inferieur critique de solubilite, formulations comprenant le copolymere et utilisation pour vectoriser un ingredient actif |
| FR2889704B1 (fr) * | 2005-08-12 | 2007-10-26 | Rhodia Chimie Sa | Particules minerales de surface modifiee par des composes porteurs de fonctions xanthate et silane. |
| FR2889702B1 (fr) * | 2005-08-12 | 2011-06-17 | Rhodia Chimie Sa | Composes porteurs de fonctions terminales xanthate et silane |
| KR100945632B1 (ko) * | 2005-11-04 | 2010-03-04 | 엘에스전선 주식회사 | 수산화마그네슘 폴리머 하이브리드 입자의 제조방법 |
| CN100362043C (zh) * | 2006-01-12 | 2008-01-16 | 上海交通大学 | 一种含氟的二氧化硅杂化材料及其制备方法 |
| US7858690B2 (en) * | 2006-10-06 | 2010-12-28 | Bridgestone Corporation | Functional coupling agents and polymers prepared therewith |
| US20080153982A1 (en) * | 2006-12-20 | 2008-06-26 | John Ta-Yuan Lai | Vinyl-Thiocarbonate and Polyol Containing Block Copolymers |
| EP2193159A1 (de) * | 2007-09-27 | 2010-06-09 | Evonik Goldschmidt GmbH | Polysiloxan blockcopolymere |
| EP2282716A2 (en) | 2008-04-23 | 2011-02-16 | Basf Se | Delivery of hydrophobic benefit agents from bodywashes and the like onto a keratinous substrate |
| EP2537878A1 (de) | 2011-06-24 | 2012-12-26 | hanse chemie AG | Polysiloxane mit Thiolgruppen und Verfahren zur Herstellung |
| EP2945976B1 (de) | 2013-01-18 | 2016-12-21 | Basf Se | Block-copolymere mit einem polydimethylsiloxan-block |
| US10987469B2 (en) | 2014-09-25 | 2021-04-27 | Pmt Partners, Llc | Rotatable finger loop for syringe, syringe configured to receive the rotatable finger loop and associated methods |
| EP3970849B1 (en) | 2014-10-31 | 2025-12-17 | Illumina Cambridge Limited | Polymers and dna copolymer coatings |
| JP6949099B2 (ja) * | 2016-07-11 | 2021-10-13 | スリーエム イノベイティブ プロパティズ カンパニー | ポリマー材料及び制御ラジカル開始剤を使用した製造方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2716509B2 (ja) * | 1989-03-01 | 1998-02-18 | 三菱化学株式会社 | ジチオカーバメート基含有ポリシロキサン |
| FR2645868B1 (fr) * | 1989-04-13 | 1991-06-14 | Rhone Poulenc Chimie | Copolymere sequence polydiorganosiloxane/ disulfure de thiurame, sa preparation et son utilisation dans la polymerisation de monomeres vinyliques |
| US5057619A (en) * | 1989-08-14 | 1991-10-15 | Minnesota Mining And Manufacturing Co. | Siloxane iniferter compounds, block copolymers made therewith and a method of making the block copolymers |
| US5032460A (en) * | 1989-08-14 | 1991-07-16 | Minnesota Mining And Manufacturing Company | Method of making vinyl-silicone copolymers using mercapto functional silicone chain-transfer agents and release coatings made therewith |
| FR2764892B1 (fr) * | 1997-06-23 | 2000-03-03 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs |
| EP1165628A1 (en) * | 1999-03-05 | 2002-01-02 | Dow Corning Corporation | Use of an initiator for controlled polymerisation reactions |
-
2000
- 2000-07-25 FR FR0009722A patent/FR2812296B1/fr not_active Expired - Fee Related
-
2001
- 2001-07-25 EP EP01956640A patent/EP1309638B1/fr not_active Expired - Lifetime
- 2001-07-25 DE DE60105620T patent/DE60105620T2/de not_active Expired - Lifetime
- 2001-07-25 CN CN01814760.7A patent/CN1280324C/zh not_active Expired - Lifetime
- 2001-07-25 WO PCT/FR2001/002433 patent/WO2002008307A1/fr not_active Ceased
- 2001-07-25 AT AT01956640T patent/ATE276292T1/de not_active IP Right Cessation
- 2001-07-25 AU AU2001278565A patent/AU2001278565A1/en not_active Abandoned
- 2001-07-25 US US10/333,882 patent/US6858696B2/en not_active Expired - Lifetime
- 2001-07-25 JP JP2002514209A patent/JP4025192B2/ja not_active Expired - Lifetime
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2004504454A5 (https=) | ||
| US6812291B1 (en) | Method for block polymer synthesis by controlled radical polymerization from dithiocarbamate compounds | |
| JP4744783B2 (ja) | 制御されたラジカル重合によって造られる界面活性ブロックコポリマー | |
| JP3542580B2 (ja) | ハロゲン化されたキサントゲン酸エステルにより制御された遊離ラジカル重合によって重合体を合成するための方法 | |
| FR2773161A1 (fr) | Procede de synthese de polymeres a blocs | |
| AU740771B2 (en) | Method for block polymer synthesis by controlled radical polymerization | |
| EP1419181B1 (en) | Process for the preparation of latices using block copolymers as surfactants | |
| US7109276B2 (en) | Method for free radical reduction of dithiocarbonylated or dithiophosphorylated functions borne by a polymer | |
| JP4025192B2 (ja) | 制御した遊離基重合によってシリコーン及び有機ハイブリッド共重合体を合成する方法 | |
| JP2004509181A (ja) | ジスルフィド化合物の存在下における制御されたラジカル重合によるブロックポリマーの合成方法 | |
| WO2002010223A2 (fr) | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee | |
| JP5087552B2 (ja) | メタクリル単位および／またはメタクリレート単位を含むリビングポリマーの製造方法 | |
| US7396901B2 (en) | Method for synthesis of polymers with thiol functions | |
| KR100980434B1 (ko) | 열린사슬 알콕시아민 및 제어되는 저온 라디칼 중합반응에대한 이들의 상응하는 니트록사이드 | |
| US6890980B2 (en) | Synthesis of block polymers obtained by controlled free radical polymerization | |
| WO2015121225A1 (fr) | Polymère porteur de fonctions phosphorées et d'au moins une fonction azoture, son procédé de synthèse et son utilisation | |
| FR2840613A1 (fr) | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee par de nouveaux agents de controle dithiophosphotesters |