JP2004331573A - Solid polyhydric alcohol base - Google Patents
Solid polyhydric alcohol base Download PDFInfo
- Publication number
- JP2004331573A JP2004331573A JP2003129839A JP2003129839A JP2004331573A JP 2004331573 A JP2004331573 A JP 2004331573A JP 2003129839 A JP2003129839 A JP 2003129839A JP 2003129839 A JP2003129839 A JP 2003129839A JP 2004331573 A JP2004331573 A JP 2004331573A
- Authority
- JP
- Japan
- Prior art keywords
- polyhydric alcohol
- solid
- mol
- poe
- alcohol base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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Abstract
Description
【０００１】
【発明の属する技術分野】
この発明は、優れた使用性を有し、温感効果，マッサージ効果，メーク落とし効果に優れ、クレンジング，パック，マッサージ用化粧料として有用な、固形状多価アルコール基剤に関する。さらに詳細には、洗い流したあとさっぱり感があり、しかも高温安定性の良好な固形状多価アルコール基剤に関する。
【０００２】
【従来の技術】
従来から化粧品に広く使われている多価アルコールの中でもグリセリンは、水に接すると水和熱により温感を生じる事が知られており、マッサージ料やパック料等のゲル状化粧料として広く用いられている（特許文献１参照）。このグリセリンのゲル化には、グアーガム，ローカストビーンガム，キサンタンガムなどの多糖類、ヒドロキシエチルセルロース，カルボキシメチルセルロース，アルギン酸塩などの半合成高分子、ポリビニルピロリドン，カルボキシビニルポリマー，ポリアクリル酸ナトリウム等の合成高分子といった、増粘剤高分子が広く利用されている（特許文献２，３参照）。
【０００３】
しかしながら、増粘剤高分子で生成させたゲルは、長期保存による高分子の重合度の変化などにより粘度が上昇若しくは下降して、ゲルの手指でのとれが悪くなったり皮膚に塗布する際の伸びが悪くなったりする、液状油を配合した際に離油を生じる、という問題があった。また洗浄効果にも劣るものであり、水で洗い流した後、べたつくものもあった。
【０００４】
また、近年アルコール類の固化を目的として、さまざまなゲル化，固化剤が提案されている。例えば、グリセリン又はその縮合物と、炭素数２〜２８の直鎖状飽和脂肪酸と、炭素数１２〜２８の脂肪族飽和二塩基酸とのオリゴエステルは、アルコールに添加することにより、均一かつ滑らかで粘稠性のある安定なゲル若しくは固化物を形成することができることが開示されている（特許文献４参照）。かかるオリゴエステルについては、有機液体のゲル化又は固化剤としての用途（特許文献５）、日焼け止め化粧料への配合（特許文献６参照）、乳化安定化作用（特許文献７，８参照）、化粧料への配合（特許文献９参照）、油分並びにエチルセルロース類と併用した皮膚外用剤（特許文献１０参照）、流動油を併用した固形状クレンジング基剤（特許文献１１）、分岐構造を有する炭化水素と併用した油性メイクアップ化粧料（特許文献１２参照）等が既に開示されている。しかしながら、上記のオリゴエステルでゲル化した多価アルコールゲル組成物は、洗い流したあとがべたつく、高温で保存した場合に離液が認められる、といった欠点があった。
【０００５】
【特許文献１】
特開平１１−１２１２６号公報
【特許文献２】
特開平６−９２８２０号公報
【特許文献３】
特開平１１−１２１２６号公報
【特許文献４】
特開平７−１２６６０３号公報
【特許文献５】
特開平７−１２６６０４号公報
【特許文献６】
特開平１０−２７３４３３号公報
【特許文献７】
特開平１０−３０５２２２号公報
【特許文献８】
特開平１１−１２８７１３号公報
【特許文献９】
特開２０００−２０４０６０号公報
【特許文献１０】
特開２０００−２１９６１７号公報
【特許文献１１】
特開２００２−３７０９３０号公報
【特許文献１２】
特開２００３−１０４８４３
【０００６】
【発明が解決しようとする課題】
本発明においては、上記のような問題点を解決し、優れた使用性を有し、温感効果，マッサージ効果，メーク落とし効果に優れ、クレンジング，パック，マッサージ用化粧料として有用な、固形状多価アルコール基剤において、洗い流したあとさっぱり感があり、しかも高温安定性の良好な固形状多価アルコール基剤を提供することを目的とした。
【０００７】
【課題を解決するための手段】
上記の課題を解決するにあたり、種々検討を行ったところ、多価アルコールの固化剤としてオリゴエステル系ゲル化剤を用いたゲル組成物において、非イオン性界面活性剤を併用することにより、洗い流したあとさっぱり感があり、しかも高温安定性の良好な固形状多価アルコール基剤が得られることを見いだし、本発明を完成するに至った。
【０００８】
【発明の実施の形態】
本発明の実施の形態を説明する。
【０００９】
本発明において用いる多価アルコールとしては、１，３−ブチレングリコール，１，４−ブチレングリコール，グリセリン，プロピレングリコール，ジプロピレングリコール，ポリプロピレングリコール，１，２−ペンタンジオール，エチレングリコール，ジエチレングリコール，ポリエチレングリコール，ジグリセリン，ヘキサグリセリン，デカグリセリン，ソルビトール，エリスリトール，キシリトールなどが例示される。これらの多価アルコールの中でも、温感作用及びマッサージ効果の点からグリセリンを用いることが好ましい。本発明においては、多価アルコールを３０重量％以上９５重量％未満配合する。多価アルコールが３０重量％未満では、多価アルコール基剤の性状を保つことができない。また９５重量％以上配合すると、固形状の性状を保てなくなったり、高温安定性の悪化が認められる。
【００１０】
本発明において用いるオリゴエステル系ゲル化剤としては、グリセリン又はその縮合物と、炭素数１８〜２８の直鎖状飽和脂肪酸と、炭素数２０〜２８の脂肪族飽和二塩基酸とのエステル化生成物が好ましく用いられる。かかるオリゴエステル系ゲル化剤を構成するグリセリン又はその縮合物としては、グリセリン若しくは平均重合度２〜１５のものをいい、具体的にはグリセリン，ジグリセリン，トリグリセリン，ペンタグリセリン，ヘキサグリセリン，デカグリセリン等が例示され、これらを単独で、若しくは２種以上を併用して用いる。これらのグリセリン又はその縮合物としては、平均重合度が５以上のものが好ましく、さらに好ましくは平均重合度が１０のデカグリセリンを用いることが、多価アルコールのゲル化作用の点から好ましい。
【００１１】
前記オリゴエステル系ゲル化剤を構成する脂肪酸、すなわち一塩基酸は、炭素数１８〜２８の直鎖状飽和脂肪酸であり、具体的にはステアリン酸，１０−ヒドロキシステアリン酸，１０−ケトステアリン酸，１２−ヒドロキシステアリン酸，アラキン酸，ベヘン酸，モンタン酸等が例示される。これらは、単独で、若しくは２種以上を併用して用いる。かかる脂肪酸の炭素数が１８未満であると、多価アルコールを固形化しにくくなる。また二塩基酸としては、炭素数が２０〜２８の脂肪族飽和状のものを用いる。具体的にはエイコサジカルボン酸，ドコサジカルボン酸，テトラコサジカルボン酸，ヘキサコサジカルボン酸，オクタコサジカルボン酸等が例示され、これから選択される１種を単独で、若しくは２種以上を併用して用いる。
【００１２】
かかるオリゴエステル系ゲル化剤は、定法により製造することができる。具体的には特開平７−１２６６０３号公報に記載された方法により、グリセリン又はその重合物と脂肪酸と二塩基酸を、触媒の存在下エステル重合させることにより得られる。
【００１３】
オリゴエステル系ゲル化剤は市販品を用いることが可能であり、例えばノムコートＲＨＫ−Ｐ，ノムコートＲＨＫ−Ｇ（共に日清オイリオ株式会社製）を挙げることができる。ノムコートＲＨＫ−Ｐは、ベヘン酸／エイコサジカルボン酸デカグリセリル、ノムコートＲＨＫ−Ｇは、ベヘン酸／エイコサジカルボン酸グリセリルである。
【００１４】
オリゴエステル系ゲル化剤の配合量は、多価アルコールに対して１〜１５重量％、好ましくは３〜１０重量％添加することにより、ゲル化能を発揮する。１重量％未満の配合では、良好なゲル化能を得ることができない。１５重量％を超えて配合すると、使用時の伸びが重くなる傾向がある。
【００１５】
本発明において用いる非イオン性界面活性剤としては、洗い流したあとのべたつきの点からＨＬＢ値が７〜１７の非イオン性界面活性剤が好ましく用いられる。
【００１６】
本発明において使用し得るＨＬＢ値が７〜１７の非イオン性界面活性剤としては特に制限されない。具体的には、ポリオキシエチレン（以下、ＰＯＥともいう）（５〜１０モル）ヘキサデシルエーテル、ＰＯＥ（６〜９モル）オレイルエーテル、ＰＯＥ（５〜７モル）ラウリルエーテル、ＰＯＥ（５〜１０モル）イソステアリルエーテル、ＰＯＥ（８〜１２モル）ジラウレート、ＰＯＥ（６〜１２モル）モノイソステアレート、ＰＯＥ（１０〜２０モル）ジイソステアレート、ＰＯＥ（５〜１２モル）モノオレエート、ＰＯＥ（５〜４０モル）グリセリルモノイソステアレート、ＰＯＥ（２０〜４０モル）グリセリルトリイソステアレート、ＰＯＥ（１０〜４０モル）グリセリルジイソステアレート、ＰＯＥ（１５〜２５モル）ソルビタンモノラウレート、ＰＯＥ（１５〜２５モル）ソルビタンモノオレエート、ＰＯＥ（２０〜５０モル）グリセリルトリオレエート、ＰＯＥ（２０〜４０モル）トリメチロールプロパントリミリステート、ＰＯＥ（２０〜５０モル）トリメチロールプロパントリイソステアレート、ＰＯＥ（１０〜４０モル）硬化ヒマシ油、ＰＯＥ（１５〜５０モル）ヒマシ油、ＰＯＥ（２０〜６０モル）硬化ヒマシ油モノラウレート、ＰＯＥ（２０〜６０モル）硬化ヒマシ油モノイソステアレート、ＰＯＥ（３０〜６０モル）硬化ヒマシ油トリイソステアレート、モノイソステアリン酸ソルビタン、モノオレイン酸ソルビタン、モノイソステアリン酸テトラグリセリル、モノイソステアリン酸ヘキサグリセリル、モノイソステアリン酸デカグリセリル、ジイソステアリン酸ヘキサグリセリル、ジイソステアリン酸デカグリセリル、などが例示される。これらの非イオン性界面活性剤は、１種を単独で、若しくは２種以上を併用して用いることができる。
【００１７】
ノニオン性界面活性剤は使用後の水洗性を考えると、固形状多価アルコー基剤全量中１重量％以上の配合が好ましく、１重量％未満では使用後の水洗性が乏しくなる傾向にある。また、３０質量％を超えると、皮膚への安全性が低下してくる。また、界面活性剤の増量により相対的に多価アルコールの配合量が減少して使用時の伸びが重くなってくる傾向があり、３０重量％以下に抑えることが好ましい。したがって、界面活性剤の含有量は、固形状多価アルコール基剤全量中１〜３０重量％であることが好ましい。
【００１８】
本発明の固形状多価アルコール基剤は、定法により調製することができる。具体的には、多価アルコールをオリゴエステル系ゲル化剤の融点以上の温度に加熱し、オリゴエステル系ゲル化剤及び非イオン性界面活性剤を添加して溶解した後、常温まで冷却、固化させることにより、調製することができる。
【００１９】
本発明の固形状多価アルコール基剤は、その性状，効果を損なわない範囲で適宜他の成分を配合することができる。配合し得るほかの成分としては、例えば液状油分，ペースト状油分，固形油分，保湿剤，本発明以外のゲル化剤，高分子，低級アルコール，糖類，カチオン性界面活性剤，アニオン性界面活性剤，両性界面活性剤，ｐＨ調整剤，紫外線吸収剤，アミノ酸類，ビタミン類，薬剤，酸化防止剤，美白剤，殺菌剤，抗菌剤，金属イオン封鎖剤，清涼剤，香料，色素等があげられる。
【００２０】
本発明の固形状多価アルコール基剤は、前記成分を配合して保湿用外用剤，老化防止用外用剤，美白用外用剤等種々の用途の外用剤として応用することが可能であり、通常のゲル状クリーム用途のみならず、マッサージ料，パック料，クレンジング料として利用することも可能である。
【００２１】
本発明の固形状多価アルコール基剤に液状油を添加することにより、油性メイク等の油性汚れに対し高いクレンジング力を付加することができる。かかる液状油としては、例えば、流動パラフィン、α−オレフィンオリゴマー、スクワラン等の炭化水素、ヨウ素化７０〜１００の植物油、ミリスチン酸イソプロピル、パルミチン酸イソオクチル、イソオクタン酸セチル、トリ２−エチルヘキサン酸グリセリル、テトラ２−エチルヘキサン酸ペンタエリスリトール、ジカプリン酸ネオペンチルグリコール、コハク酸ジオクチル、ノナン酸イソノニル等のエステル油、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルフェニルポリシロキサン等のシリコーン油等を挙げることができる。これらの液状油は１種類を単独で、若しくは２種類以上を組み合わせて配合する。
液状油は、固形状多価アルコール基剤全量中に１〜６０重量％配合することができる。１重量％未満ではクレンジング力の向上が認められず、逆に６０重量％以上配合すると、多価アルコールによる温感効果を得ることができない。
【００２２】
また固形状多価アルコール基剤に液状油を配合してクレンジング用化粧料として用いる場合には、ＨＬＢ値が７〜１７の非イオン性界面活性剤と、ＨＬＢ値が７未満の非イオン性界面活性剤と併用して用いることが好ましい。かかるＨＬＢ値が７未満の非イオン性界面活性剤としては例えば、モノステアリン酸グリセリル，モノイソステアリン酸グリセリル，モノオレイン酸ジグリセリル，ジオレイン酸ジグリセリル，モノイソステアリン酸ジグリセリン，モノオレイン酸テトラグリセリル，トリオレイン酸デカグリセリル，トリイソステアリン酸デカグリセリル，ペンタオレイン酸デカグリセリル，ペンタイソステアリン酸デカグリセリル，モノオレイン酸ソルビタン，セスキオレイン酸ソルビタン，トリオレイン酸ソルビタン，モノイソステアリン酸ソルビタン，セスキイソステアリン酸ソルビタン，ＰＯＥ（２〜６モル）モノオレエート，ＰＯＥ（３〜１０モル）ヒマシ油，ＰＯＥ（５モル）硬化ヒマシ油，ＰＯＥ（３モル）モノイソステアレート，ＰＯＥ（２〜１２モル）ジイソステアレート，ＰＯＥ（３〜５モル）グリセリルモノイソステアレート，ＰＯＥ（３〜２０モル）グリセリルトリイソステアレート，ＰＯＥ（３〜２０モル）トリメチロールプロパントリイソステアレート，ＰＯＥ（５〜２０モル）硬化ヒマシ油モノイソステアレート，ＰＯＥ（５〜３０モル）硬化ヒマシ油トリイソステアレート，イソステアリン酸グリセリルエーテル，ショ糖ステアリン酸エステル，ショ糖オレイン酸エステル，ショ糖パルミチン酸エステル，ショ糖ミリスチン酸エステル，ショ糖ラウリン酸エステル，ポリオキシエチレン・ポリオキシプロピレンブロック共重合体などが例示され、これらのノニオン性界面活性剤の中でもモノステアリン酸グリセリルが好ましい例として挙げられる。
【００２３】
【実施例】
本発明の詳細について、実施例を用いて説明する。
【００２４】
【表１】
表１に示した処方にて固形状多価アルコール基剤を調製した。固形状多価アルコール基剤は、全成分を７０℃に加温して溶融し、そのまま常温で放冷することにより調製した。得られた実施例及び比較例の固化状態，高温安定性並びにべたつきは、以下の基準に従い評価した。
【００２６】
［固化状態］
調製後２４時間室温にて保存したあと、固形物の状態を観察した。評価は、◎：硬く均一で滑らかな固化物、○：均一で滑らかな固化物、△：均一ではあるがわずかに流動性を有する物、×：一部が固液分離する物、とした。
【００２７】
［高温安定性］
調製後２４時間室温にて保存したあと、５０℃にて３０日間保存し、さらに２４時間室温で保存したあとの固形物の状態を観察した。評価は、◎：硬く均一で滑らかな固化物、○：均一で滑らかな固化物、△：均一ではあるがわずかに流動性を有する物、×：一部が固液分離する物、とした。
【００２８】
［べたつき］
実施例若しくは比較例を適量手にとり、マッサージした後ぬるま湯で洗い流したあとのべたつき感を、◎：全くべたつかない、○：わずかにべたつがあまり気にならない、△：べたつきが少し気になる、×：べたつきがかなりきになる、の４段階で評価した。
【００２９】
【表２】
表２に示した処方にて、本発明の固形状多価アルコールゲル基剤を用いた皮膚外用剤を調製し、状態及び使用感の評価を行った。その結果、固化状態、高温安定性が良好で、しかもべたつきのない良好な使用感を有する皮膚外用剤を得ることができた。
【００３１】
【表３】
表３に示した処方にて、固形状クレンジング料を調製し、状態及び使用感の評価を行った。クレンジング力は、油性ファンデーション，口紅，油性アイライナー，マスカラを用いたメークを、実施例を使用してクレンジングして評価した。
評価は、◎：非常によく落ちほとんどメークが肌に残らない、○：よく落ちるがわずかにメークが肌に残る、△：メークが少し肌に残っている、×：メークが肌に残っている、の４段階とした。また、温感効果，マッサージ効果は、クレンジング時に、それぞれの効果を、◎：強く感じる、○：感じる、△：わずかに感じる、×：ほとんど感じない、の４段階で評価した。
【００３３】
評価の結果、実施例７〜実施例１２に示した固形状クレンジング料は、固化状態，高温安定性が良好で、温感効果、マッサージ効果、クレンジング力に優れしかもべたつきのない良好な使用感を有するものであった。
【００３４】
【発明の効果】
以上詳述したように、本発明により、優れた使用性を有し、温感効果，マッサージ効果，メーク落とし効果に優れ、クレンジング，パック，マッサージ用化粧料として有用な、固形状多価アルコール基剤において、洗い流したあとさっぱり感があり、しかも高温安定性の良好な固形状多価アルコール基剤を提供することができた。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a solid polyhydric alcohol base which has excellent usability, is excellent in warming effect, massage effect, and makeup removing effect, and is useful as a cleansing, pack, and massage cosmetic. More specifically, the present invention relates to a solid polyhydric alcohol base having a refreshing feeling after washing and having good high-temperature stability.
[0002]
[Prior art]
Among polyhydric alcohols that have been widely used in cosmetics, glycerin is known to produce a warm feeling due to heat of hydration when in contact with water, and is widely used as a gel cosmetic such as massages and packs. (See Patent Document 1). This glycerin gelation can be achieved by using polysaccharides such as guar gum, locust bean gum, and xanthan gum, semi-synthetic polymers such as hydroxyethyl cellulose, carboxymethyl cellulose, and alginate, synthetic polymers such as polyvinylpyrrolidone, carboxyvinyl polymer, and sodium polyacrylate. Thickener polymers such as molecules are widely used (see Patent Documents 2 and 3).
[0003]
However, the gel produced with the thickener polymer increases or decreases in viscosity due to changes in the degree of polymerization of the polymer due to long-term storage, etc. There was a problem that the elongation deteriorated or oil separation occurred when liquid oil was blended. Also, the cleaning effect was inferior, and some were sticky after washing with water.
[0004]
In recent years, various gelling and solidifying agents have been proposed for the purpose of solidifying alcohols. For example, an oligoester of glycerin or a condensate thereof, a linear saturated fatty acid having 2 to 28 carbon atoms, and an aliphatic saturated dibasic acid having 12 to 28 carbon atoms can be uniformly and smoothly added to alcohol. It is disclosed that a viscous and stable gel or solidified product can be formed (see Patent Document 4). For such oligoesters, use as a gelling or solidifying agent for organic liquid (Patent Document 5), blending into sunscreen cosmetics (see Patent Document 6), emulsion stabilizing action (see Patent Documents 7 and 8), Formulation in cosmetics (see Patent Document 9), oil and skin external preparation in combination with ethyl cellulose (see Patent Document 10), solid cleansing base in combination with fluid oil (Patent Document 11), carbonization having a branched structure Oil-based makeup cosmetics used in combination with hydrogen (see Patent Document 12) and the like have already been disclosed. However, the polyhydric alcohol gel composition gelled with the above-described oligoester has a drawback that it is sticky after washing, and liquid separation is observed when stored at a high temperature.
[0005]
[Patent Document 1]
Japanese Patent Laid-Open No. 11-12126 [Patent Document 2]
JP-A-6-92820 [Patent Document 3]
Japanese Patent Laid-Open No. 11-12126 [Patent Document 4]
JP-A-7-126603 [Patent Document 5]
JP-A-7-126604 [Patent Document 6]
Japanese Patent Laid-Open No. 10-273433 [Patent Document 7]
Japanese Patent Laid-Open No. 10-305222 [Patent Document 8]
JP-A-11-128713 [Patent Document 9]
JP 2000-204060 A [Patent Document 10]
JP 2000-219617 A [Patent Document 11]
JP 2002-370930 A [Patent Document 12]
JP 2003-104843 A
[0006]
[Problems to be solved by the invention]
In the present invention, it solves the above problems, has excellent usability, is excellent in warm feeling effect, massage effect, make-up removal effect, and is useful as a cleansing, pack, and massage cosmetic. The purpose of the polyhydric alcohol base is to provide a solid polyhydric alcohol base that has a refreshing feeling after being washed away and has good high-temperature stability.
[0007]
[Means for Solving the Problems]
In order to solve the above-mentioned problems, various studies were conducted, and the gel composition using an oligoester gelling agent as a polyhydric alcohol solidifying agent was washed away by using a nonionic surfactant in combination. It has been found that a solid polyhydric alcohol base having a refreshing feeling and good high-temperature stability can be obtained, and the present invention has been completed.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
An embodiment of the present invention will be described.
[0009]
Examples of the polyhydric alcohol used in the present invention include 1,3-butylene glycol, 1,4-butylene glycol, glycerin, propylene glycol, dipropylene glycol, polypropylene glycol, 1,2-pentanediol, ethylene glycol, diethylene glycol, and polyethylene glycol. , Diglycerin, hexaglycerin, decaglycerin, sorbitol, erythritol, xylitol and the like. Among these polyhydric alcohols, it is preferable to use glycerin from the viewpoints of warmth and massage effect. In the present invention, the polyhydric alcohol is blended in an amount of 30% by weight to less than 95% by weight. If the polyhydric alcohol is less than 30% by weight, the properties of the polyhydric alcohol base cannot be maintained. Moreover, when it mix | blends 95weight% or more, a solid property cannot be maintained, or the deterioration of high temperature stability is recognized.
[0010]
As an oligoester gelling agent used in the present invention, esterification of glycerin or a condensate thereof, a linear saturated fatty acid having 18 to 28 carbon atoms, and an aliphatic saturated dibasic acid having 20 to 28 carbon atoms The product is preferably used. The glycerin constituting the oligoester gelling agent or the condensate thereof refers to glycerin or those having an average degree of polymerization of 2 to 15, specifically glycerin, diglycerin, triglycerin, pentaglycerin, hexaglycerin, deca Examples thereof include glycerin, and these are used alone or in combination of two or more. As these glycerin or the condensate thereof, those having an average degree of polymerization of 5 or more are preferable, and it is more preferable to use decaglycerin having an average degree of polymerization of 10 from the viewpoint of the gelling action of polyhydric alcohol.
[0011]
The fatty acid that constitutes the oligoester gelling agent, that is, a monobasic acid, is a linear saturated fatty acid having 18 to 28 carbon atoms, specifically stearic acid, 10-hydroxystearic acid, 10-ketostearic acid. , 12-hydroxystearic acid, arachidic acid, behenic acid, montanic acid and the like. These are used alone or in combination of two or more. If the fatty acid has less than 18 carbon atoms, the polyhydric alcohol is difficult to solidify. As the dibasic acid, an aliphatic saturated one having 20 to 28 carbon atoms is used. Specifically, eicosadicarboxylic acid, docosadicarboxylic acid, tetracosadicarboxylic acid, hexacosadicarboxylic acid, octacosadicarboxylic acid and the like are exemplified, and one kind selected from these alone or in combination of two or more kinds Use.
[0012]
Such an oligoester gelling agent can be produced by a conventional method. Specifically, it can be obtained by ester polymerization of glycerin or a polymer thereof, a fatty acid and a dibasic acid in the presence of a catalyst by the method described in JP-A-7-126603.
[0013]
A commercially available product can be used as the oligoester-based gelling agent, and examples thereof include Nomcoat R HK-P and Nomcoat R HK-G (both manufactured by Nisshin Oilio Co., Ltd.). Nomcoat R HK-P is behenic acid / eicosadicarboxylic acid decaglyceryl, and Nomcote R HK-G is behenic acid / eicosadicarboxylic acid glyceryl.
[0014]
The compounding amount of the oligoester-based gelling agent exhibits gelling ability by adding 1 to 15% by weight, preferably 3 to 10% by weight, based on the polyhydric alcohol. When the amount is less than 1% by weight, good gelling ability cannot be obtained. When it exceeds 15% by weight, the elongation during use tends to be heavy.
[0015]
As the nonionic surfactant used in the present invention, a nonionic surfactant having an HLB value of 7 to 17 is preferably used from the viewpoint of stickiness after washing.
[0016]
The nonionic surfactant having an HLB value of 7 to 17 that can be used in the present invention is not particularly limited. Specifically, polyoxyethylene (hereinafter also referred to as POE) (5 to 10 mol) hexadecyl ether, POE (6 to 9 mol) oleyl ether, POE (5 to 7 mol) lauryl ether, POE (5 to 10 mol) Mol) isostearyl ether, POE (8-12 mol) dilaurate, POE (6-12 mol) monoisostearate, POE (10-20 mol) diisostearate, POE (5-12 mol) monooleate, POE ( 5-40 mol) glyceryl monoisostearate, POE (20-40 mol) glyceryl triisostearate, POE (10-40 mol) glyceryl diisostearate, POE (15-25 mol) sorbitan monolaurate, POE (15-25 mol) sorbitan monooleate, POE (20-50 mol) g Seryl trioleate, POE (20-40 mol) trimethylolpropane trimyristate, POE (20-50 mol) trimethylolpropane triisostearate, POE (10-40 mol) hydrogenated castor oil, POE (15-50 mol) ) Castor oil, POE (20-60 mol) hydrogenated castor oil monolaurate, POE (20-60 mol) hydrogenated castor oil monoisostearate, POE (30-60 mol) hydrogenated castor oil triisostearate, monoisostearate Examples include sorbitan acid, sorbitan monooleate, tetraglyceryl monoisostearate, hexaglyceryl monoisostearate, decaglyceryl monoisostearate, hexaglyceryl diisostearate, decaglyceryl diisostearate, and the like. These nonionic surfactants can be used alone or in combination of two or more.
[0017]
The nonionic surfactant is preferably blended in an amount of 1% by weight or more based on the total amount of the solid polyvalent alcohol base considering the washability after use, and if it is less than 1% by weight, the washability after use tends to be poor. Moreover, when it exceeds 30 mass%, the safety to skin will fall. Further, the blending amount of the polyhydric alcohol is relatively decreased due to the increase in the amount of the surfactant, and the elongation during use tends to be heavy, and it is preferably suppressed to 30% by weight or less. Accordingly, the content of the surfactant is preferably 1 to 30% by weight in the total amount of the solid polyhydric alcohol base.
[0018]
The solid polyhydric alcohol base of the present invention can be prepared by a conventional method. Specifically, the polyhydric alcohol is heated to a temperature equal to or higher than the melting point of the oligoester gelling agent, dissolved by adding the oligoester gelling agent and the nonionic surfactant, and then cooled to room temperature and solidified. Can be prepared.
[0019]
The solid polyhydric alcohol base of the present invention can be appropriately mixed with other components as long as its properties and effects are not impaired. Other components that can be blended include, for example, liquid oils, pasty oils, solid oils, moisturizers, gelling agents other than the present invention, polymers, lower alcohols, sugars, cationic surfactants, anionic surfactants , Amphoteric surfactants, pH adjusters, UV absorbers, amino acids, vitamins, drugs, antioxidants, whitening agents, bactericides, antibacterial agents, sequestering agents, cooling agents, fragrances, pigments, etc. .
[0020]
The solid polyhydric alcohol base of the present invention can be applied as an external preparation for various uses such as a moisturizing external preparation, an anti-aging external preparation, a whitening external preparation by blending the above-mentioned components. It can be used not only as a gel cream but also as a massage fee, pack fee, and cleansing fee.
[0021]
By adding liquid oil to the solid polyhydric alcohol base of the present invention, high cleansing power can be added to oily dirt such as oily makeup. Examples of the liquid oil include liquid paraffin, α-olefin oligomer, squalane and other hydrocarbons, iodinated 70-100 vegetable oil, isopropyl myristate, isooctyl palmitate, cetyl isooctanoate, glyceryl tri-2-ethylhexanoate, Examples include ester oils such as penta-2-erythritol tetra-2-ethylhexanoate, neopentyl glycol dicaprate, dioctyl succinate, isononyl nonanoate, silicone oils such as decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and methylphenylpolysiloxane. be able to. These liquid oils are blended singly or in combination of two or more.
Liquid oil can be mix | blended 1 to 60 weight% in solid polyhydric-alcohol base whole quantity. If it is less than 1% by weight, no improvement in cleansing power is observed. Conversely, if 60% by weight or more is blended, the warming effect of polyhydric alcohol cannot be obtained.
[0022]
When a liquid oil is blended into a solid polyhydric alcohol base and used as a cleansing cosmetic, a nonionic surfactant having an HLB value of 7 to 17 and a nonionic interface having an HLB value of less than 7 It is preferably used in combination with an activator. Examples of the nonionic surfactant having an HLB value of less than 7 include glyceryl monostearate, glyceryl monoisostearate, diglyceryl monooleate, diglyceryl dioleate, diglyceryl monoisostearate, tetraglyceryl monooleate, Decaglyceryl trioleate, decaglyceryl triisostearate, decaglyceryl pentaoleate, decaglyceryl pentaisostearate, sorbitan monooleate, sorbitan sesquioleate, sorbitan trioleate, sorbitan monoisostearate, sorbitan sesquiisostearate, POE (2-6 mol) monooleate, POE (3-10 mol) castor oil, POE (5 mol) hydrogenated castor oil, POE (3 mol) monoisostearate, POE ( ~ 12 mol) diisostearate, POE (3-5 mol) glyceryl monoisostearate, POE (3-20 mol) glyceryl triisostearate, POE (3-20 mol) trimethylolpropane triisostearate, POE (5-20 mol) hydrogenated castor oil monoisostearate, POE (5-30 mol) hydrogenated castor oil triisostearate, glyceryl ether isostearate, sucrose stearate, sucrose oleate, sucrose palmitic Examples include acid esters, sucrose myristic acid esters, sucrose lauric acid esters, polyoxyethylene / polyoxypropylene block copolymers, etc. Among these nonionic surfactants, glyceryl monostearate is a preferred example. .
[0023]
【Example】
Details of the present invention will be described using examples.
[0024]
[Table 1]
A solid polyhydric alcohol base was prepared according to the formulation shown in Table 1. The solid polyhydric alcohol base was prepared by heating and melting all components at 70 ° C. and allowing to cool at room temperature. The solidified state, high temperature stability and stickiness of the obtained Examples and Comparative Examples were evaluated according to the following criteria.
[0026]
[Solidified state]
After storage for 24 hours after preparation, the state of the solid was observed. The evaluation was as follows: ◎: hard, uniform and smooth solidified product, ○: uniform and smooth solidified product, Δ: uniform but slightly fluidized product, ×: product partially separated into solid and liquid.
[0027]
[High temperature stability]
After the preparation, it was stored at room temperature for 24 hours, then stored at 50 ° C. for 30 days, and the solid state after further storage at room temperature for 24 hours was observed. The evaluation was as follows: ◎: hard, uniform and smooth solidified product, ○: uniform and smooth solidified product, Δ: uniform but slightly fluidized product, ×: product partially separated into solid and liquid.
[0028]
[Stickiness]
Take an appropriate amount of the examples or comparative examples, massage and then rinse off with lukewarm water, ◎: not sticky, ○: slightly sticky, △: slightly sticky, × : Evaluated in 4 stages, with a lot of stickiness.
[0029]
[Table 2]
With the formulation shown in Table 2, a skin external preparation using the solid polyhydric alcohol gel base of the present invention was prepared, and the state and feeling of use were evaluated. As a result, it was possible to obtain an external preparation for skin having a good solidified state and high-temperature stability and having a good feeling of use without stickiness.
[0031]
[Table 3]
A solid cleansing material was prepared according to the formulation shown in Table 3, and the state and feeling of use were evaluated. The cleansing power was evaluated by cleansing a makeup using an oily foundation, lipstick, oily eyeliner, and mascara using Examples.
Evaluation: ◎: very well falls and almost no makeup remains on skin, ○: well falls but slightly makeup remains on skin, △: makeup slightly remains on skin, ×: makeup remains on skin The four stages were. In addition, the warming effect and the massage effect were evaluated in four stages of cleansing: ◎: feel strongly, ○: feel, △: feel slightly, ×: hardly feel.
[0033]
As a result of the evaluation, the solid cleansing materials shown in Examples 7 to 12 have a solid state, good high-temperature stability, excellent warm feeling effect, massage effect, cleansing power and good feeling without stickiness. I had it.
[0034]
【The invention's effect】
As described in detail above, according to the present invention, a solid polyhydric alcohol group having excellent usability, excellent warm feeling effect, massage effect, makeup removing effect, and useful as a cleansing, pack, and massage cosmetic. In the preparation, it was possible to provide a solid polyhydric alcohol base having a refreshing feeling after washing and having good high-temperature stability.
Claims (2)
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| KR102002908B1 (en) * | 2016-03-15 | 2019-07-23 | 가부시키가이샤 만다무 | Warm feeling cosmetics |
| JP2018070470A (en) * | 2016-10-26 | 2018-05-10 | 株式会社 サティス製薬 | Pasty cleansing cosmetics |
| JP6086462B1 (en) * | 2016-10-26 | 2017-03-01 | 株式会社 サティス製薬 | Paste cleansing cosmetic |
| WO2019124065A1 (en) * | 2017-12-18 | 2019-06-27 | 三菱鉛筆株式会社 | Solid cosmetic |
| EP3730124A4 (en) * | 2017-12-18 | 2022-03-09 | Mitsubishi Pencil Company, Limited | Solid cosmetic |
| JP2021070666A (en) * | 2019-11-01 | 2021-05-06 | エスコ 株式会社 | Gel-like cleansing cosmetic |
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