JP2004268093A - Mold powder for continuous castings of alloy steel or carbon steel - Google Patents

Mold powder for continuous castings of alloy steel or carbon steel Download PDF

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Publication number
JP2004268093A
JP2004268093A JP2003062427A JP2003062427A JP2004268093A JP 2004268093 A JP2004268093 A JP 2004268093A JP 2003062427 A JP2003062427 A JP 2003062427A JP 2003062427 A JP2003062427 A JP 2003062427A JP 2004268093 A JP2004268093 A JP 2004268093A
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JP
Japan
Prior art keywords
mold powder
mold
continuous casting
slab
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2003062427A
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Japanese (ja)
Inventor
Tatsuya Kawamoto
達也 河本
Sohei Yamada
宗平 山田
Yasuhide Oba
康英 大塲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Special Steel Co Ltd
Original Assignee
Sanyo Special Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sanyo Special Steel Co Ltd filed Critical Sanyo Special Steel Co Ltd
Priority to JP2003062427A priority Critical patent/JP2004268093A/en
Publication of JP2004268093A publication Critical patent/JP2004268093A/en
Pending legal-status Critical Current

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a mold powder which can prevent interruption of mold powder in a casting mold during continuous casting and achieve uniform cooling and uniform solidification of a solidified shell of slab to improve surface quality of the slab by continuous casting. <P>SOLUTION: In the mold powder for continuous casting of an alloy steel or a carbon steel, the mold powder molten in the mold has a viscosity of not less than 1.5 Pa s at 1,300°C and the molten mold powder does not crystalize during solidification staying in an amorphous state. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
連続鋳造において合金鋼や炭素鋼の鋳造時に発生する鋳片の表面欠陥を低減し、かつ、ブレークアウトの発生を防止することができるモールドパウダーに関する。
【0002】
【従来の技術】
合金鋼を連続鋳造で製造する場合、鋳型と鋳片の凝固シェル間の潤滑を確保するために、粘度が0.5Pa・s以下のモールドパウダーを使用して鋳造している。しかし、粘度の低いモールドパウダーの場合、鋳型と鋳片の凝固シェル間へのモールドパウダーの流入が不均一になり、鋳片にパウダーストリークやデプレッションなどの表面欠陥が発生する。特に凝固温度の高い肌焼鋼についてはその傾向が顕著に見られる。
【0003】
これらの対策として、1300℃で0.3Pa・s以上のモールドパウダーを使用し、かつ、鋳型内の溶湯を電磁撹拌する方法がある(例えば、特許文献1参照)。さらに、鋳造初期には低粘度のモールドパウダーを使用し、定常時になると高粘度のモールドパウダーを使用する方法がある(例えば、特許文献2参照)。さらに、0.5Pa・s以上のモールドパウダーを使用し、かつ、トータルカーボン量を一定値以上とする方法がある(例えば、特許文献3参照)。
【0004】
【特許文献1】
特開2000−280051号公報
【特許文献2】
特開2002−178115号公報
【特許文献3】
特開2001−334351号公報
【0005】
【発明が解決しようとする課題】
鋳型内でモールドパウダーフィルムが破断すると、溶鋼とモールドが直接接触し、焼き付きを起こして鋳片の表面欠陥に繋がる。さらに、粘性が低いモールドパウダーの場合には、鋳型コーナー部に過剰流入を起こしやすく、このため均一冷却が出来なくなる。
【0006】
そこで、本発明が解決しようとする課題は、連続鋳造による鋳片の表面性状を改善するために、連続鋳造時の鋳型内におけるモールドパウダーの途切れを無くし、鋳片の凝固シェルの均一冷却および均一凝固を図ることのできるモールドパウダーを提供することである。
【0007】
【課題を解決するための手段】
モールドパウダーの粘度を1300℃で1.5Pa・s以上の高粘度とし、モールドパウダーフィルムの破断を防止し、鋳型内のコーナー部、面央部の流入差を少なくし凝固シェルの均一冷却を図る。さらに、モールドパウダーフィルムを結晶を生成しない非晶質化タイプにすることで抜熱の均一化を図るものである。
【0008】
すなわち、上記の課題を解決するための本発明の手段は、請求項1の発明では、合金鋼または炭素鋼の連続鋳造用のモールドパウダーにおいて、鋳型内の溶融モールドパウダーの1300℃における粘度は1.5Pa・s以上であることを特徴とする連続鋳造用モールドパウダーである。
【0009】
請求項2の発明では、鋳型内の溶融モールドパウダーは凝固時に結晶を生成することなく非晶質化することを特徴とする請求項1の手段の連続鋳造用モールドパウダーである。
【0010】
【発明の実施の形態】
本発明の実施の形態を以下の実施例に基づきに説明する。
【0011】
【実施例】
粘性を変えた2種類のモールドパウダーを用いて鉛含有の肌焼鋼を連続鋳造で鋳造し、鋳片の表面性状あるいは鋳片の疵状況などを調査した。表1に示す組成および物性を有する連続鋳造用モールドパウダーの本発明品並びに従来品を用いて、380mm×490mmのサイズのモールドで鋳造した。
【0012】
鉛含有の肌焼鋼の対象材はSCM420として鋳造速度Vc:0.45m/minで連続鋳造した。
【0013】
【表1】

Figure 2004268093
【0014】
得られた連鋳片の表面性状について表2に示す。
【0015】
【表2】
Figure 2004268093
【0016】
表2に見られるとおり、従来品のモールドパウダーの鋳片疵の発生率を1とするとき、本発明品は0.6で、約4割も疵の発生が少ない。モールドパウダーの使用量は本発明品では原単位で従来品の約66%である。振動鋳型による鋳片表面のオシレーションマークの乱れは従来品ではコーナー付近で多いが、本発明品ではオシレーションマークの乱れ自体が少なく、かつ、オシレーションマーク深さ指数も従来品を1としたときに0.64と浅くなっている。さらにオシレーションマークの谷部の偏析発生率も従来品が38%であったが、本発明品は33%であった。
【0017】
【発明の効果】
以上に説明したように、合金鋼または炭素鋼の連続鋳造において、本発明におけるモールドパウダーを用いることにより、連続鋳造時の鋳型内におけるモールドパウダーの途切れを無くし、モールドパウダー原単位を大幅に低減でき、鋳片表面性状の改善が図られ、さらに鋳片の表面疵の改善効果が大幅に得られ、またさらに、ブレークアウトなどの操業異常やモールドパウダーの噛み込みなどの品質異常も見られないなど、鋳片の凝固シェルの均一冷却および均一凝固を図ることができ、本発明は従来にない優れた作用効果を奏するものである。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a mold powder capable of reducing surface defects of a slab generated during casting of alloy steel or carbon steel in continuous casting and preventing occurrence of breakout.
[0002]
[Prior art]
When alloy steel is manufactured by continuous casting, in order to ensure lubrication between a solidified shell of a mold and a slab, casting is performed using a mold powder having a viscosity of 0.5 Pa · s or less. However, in the case of low-viscosity mold powder, the flow of the mold powder between the mold and the solidified shell of the slab becomes uneven, and surface defects such as powder streak and depletion occur in the slab. In particular, the tendency is remarkably observed in case hardening steel having a high solidification temperature.
[0003]
As a countermeasure, there is a method of using a mold powder having a pressure of 0.3 Pa · s or more at 1300 ° C. and electromagnetically stirring a molten metal in a mold (for example, see Patent Document 1). Further, there is a method in which a low-viscosity mold powder is used in the early stage of casting, and a high-viscosity mold powder is used in a steady state (for example, see Patent Document 2). Furthermore, there is a method of using a mold powder of 0.5 Pa · s or more and making the total carbon amount a certain value or more (for example, see Patent Document 3).
[0004]
[Patent Document 1]
Japanese Patent Application Laid-Open No. 2000-280051 [Patent Document 2]
JP 2002-178115 A [Patent Document 3]
JP 2001-334351 A
[Problems to be solved by the invention]
When the mold powder film breaks in the mold, the molten steel and the mold come into direct contact, causing seizure and leading to a surface defect of the slab. Further, in the case of a mold powder having a low viscosity, excessive inflow is likely to occur at the corner of the mold, so that uniform cooling cannot be performed.
[0006]
Therefore, the problem to be solved by the present invention is to improve the surface properties of the slab by continuous casting, eliminate the interruption of the mold powder in the mold during continuous casting, and uniformly cool and uniformly cool the solidified shell of the slab. An object of the present invention is to provide a mold powder capable of achieving solidification.
[0007]
[Means for Solving the Problems]
The viscosity of the mold powder is set to a high viscosity of 1.5 Pa · s or more at 1300 ° C. to prevent breakage of the mold powder film, to reduce the difference in inflow between the corners and the center of the mold, and to uniformly cool the solidified shell. . Further, the heat removal is made uniform by making the mold powder film an amorphous type which does not generate crystals.
[0008]
That is, the means of the present invention for solving the above-mentioned problem is that, in the invention of claim 1, in a mold powder for continuous casting of alloy steel or carbon steel, the viscosity of a molten mold powder in a mold at 1300 ° C. is 1 It is a mold powder for continuous casting characterized by being at least 0.5 Pa · s.
[0009]
According to a second aspect of the present invention, there is provided the mold powder for continuous casting according to the first aspect, wherein the molten mold powder in the mold is made amorphous without generating crystals during solidification.
[0010]
BEST MODE FOR CARRYING OUT THE INVENTION
Embodiments of the present invention will be described based on the following examples.
[0011]
【Example】
Using two types of mold powders of different viscosities, lead-containing case hardened steel was cast by continuous casting, and the surface properties of the slab or the state of flaws in the slab were investigated. Using the present invention product and the conventional product of the mold powder for continuous casting having the composition and physical properties shown in Table 1, casting was performed in a mold having a size of 380 mm × 490 mm.
[0012]
The target material of lead-containing case hardening steel was continuously cast as SCM420 at a casting speed Vc of 0.45 m / min.
[0013]
[Table 1]
Figure 2004268093
[0014]
Table 2 shows the surface properties of the obtained continuous cast pieces.
[0015]
[Table 2]
Figure 2004268093
[0016]
As shown in Table 2, when the occurrence rate of slab flaws of the conventional mold powder is 1, the product of the present invention is 0.6, and the generation of flaws is as small as about 40%. The amount of mold powder used in the product of the present invention is about 66% of the conventional product in the basic unit. Oscillation mark disturbance on the slab surface due to the vibrating mold is more disordered in the vicinity of the corner in the conventional product, but in the present invention product, the oscillation mark disturbance itself is small, and the oscillation mark depth index is 1 in the conventional product. Sometimes it is as shallow as 0.64. Further, the segregation occurrence rate of the valley portion of the oscillation mark was 38% in the conventional product, but was 33% in the product of the present invention.
[0017]
【The invention's effect】
As described above, in the continuous casting of alloy steel or carbon steel, by using the mold powder of the present invention, it is possible to eliminate breaks in the mold powder in the mold during continuous casting and significantly reduce the unit of mold powder. The surface properties of the slab are improved, the effect of improving the surface flaws of the slab is greatly improved, and furthermore, there is no operation abnormality such as breakout or quality abnormality such as mold powder biting. In addition, uniform cooling and uniform solidification of the solidified shell of the slab can be achieved, and the present invention has an unprecedented excellent operation and effect.

Claims (2)

合金鋼または炭素鋼の連続鋳造用のモールドパウダーにおいて、鋳型内の溶融モールドパウダーの1300℃における粘度は1.5Pa・s以上であることを特徴とする連続鋳造用モールドパウダー。A mold powder for continuous casting of alloy steel or carbon steel, wherein the viscosity of the molten mold powder in the mold at 1300 ° C. is 1.5 Pa · s or more. 鋳型内の溶融モールドパウダーは凝固時に結晶を生成することなく非晶質化することを特徴とする請求項1に記載の連続鋳造用モールドパウダー。The mold powder for continuous casting according to claim 1, wherein the molten mold powder in the mold becomes amorphous without generating crystals during solidification.
JP2003062427A 2003-03-07 2003-03-07 Mold powder for continuous castings of alloy steel or carbon steel Pending JP2004268093A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2003062427A JP2004268093A (en) 2003-03-07 2003-03-07 Mold powder for continuous castings of alloy steel or carbon steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003062427A JP2004268093A (en) 2003-03-07 2003-03-07 Mold powder for continuous castings of alloy steel or carbon steel

Publications (1)

Publication Number Publication Date
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Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008290087A (en) * 2007-05-22 2008-12-04 Sanyo Special Steel Co Ltd Mold powder for continuous casting of high carbon steel
CN108580822A (en) * 2018-07-09 2018-09-28 西峡龙成冶金材料有限公司 A kind of continuous crystallizer protecting slag of high viscosity Hot Metal in Beam Blank medium carbon steel or low-alloy steel

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008290087A (en) * 2007-05-22 2008-12-04 Sanyo Special Steel Co Ltd Mold powder for continuous casting of high carbon steel
CN108580822A (en) * 2018-07-09 2018-09-28 西峡龙成冶金材料有限公司 A kind of continuous crystallizer protecting slag of high viscosity Hot Metal in Beam Blank medium carbon steel or low-alloy steel
CN108580822B (en) * 2018-07-09 2020-01-24 西峡龙成冶金材料有限公司 Continuous casting crystallizer casting powder of high-viscosity special-shaped blank medium carbon steel or low alloy steel

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