JP2004244733A - Stainproof garment - Google Patents

Stainproof garment Download PDF

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Publication number
JP2004244733A
JP2004244733A JP2003032851A JP2003032851A JP2004244733A JP 2004244733 A JP2004244733 A JP 2004244733A JP 2003032851 A JP2003032851 A JP 2003032851A JP 2003032851 A JP2003032851 A JP 2003032851A JP 2004244733 A JP2004244733 A JP 2004244733A
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JP
Japan
Prior art keywords
garment
titanium oxide
photocatalytic titanium
cuffs
fibers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2003032851A
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Japanese (ja)
Inventor
Kikuji Koyama
喜久次 小山
Noriyuki Okui
敬之 奥井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NICS CORP
OKUI KK
Original Assignee
NICS CORP
OKUI KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NICS CORP, OKUI KK filed Critical NICS CORP
Priority to JP2003032851A priority Critical patent/JP2004244733A/en
Publication of JP2004244733A publication Critical patent/JP2004244733A/en
Pending legal-status Critical Current

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  • Catalysts (AREA)
  • Artificial Filaments (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Outerwear In General, And Traditional Japanese Garments (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a stainproof garment having bactericidal action, offensive odor-eliminating and stainproofing functions by applying photocatalytic titanium oxide on necessary portions of a garment for animals or human beings. <P>SOLUTION: The stainproof garment has the following structure: the reverse surface and/or the front surface of at least one part of cuffs, neckline of a collar, a crotch part, pocket openings and a hem line are/is provided with fibers mixedly containing the photocatalytic titanium oxide; alternatively, synthetic fibers used for at least one part of cuffs, neckline of a collar, a crotch part, pocket openings and a hem line are mixed with the photocatalytic titanium oxide while maintaining the raw material formulation in the entire structure of the garment. Optionally, when the stainproof garment is used for animal, photocatalytic titanium oxide-formulated fibers are provided for the whole of the garment or the portion coming in contact with the body. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【0001】
【産業上の利用分野】
本発明は、光触媒酸化チタン配合の生地を使用した汚れ付着防止衣服に関するものである。
【0002】
【従来の技術】
従来より、消臭等効果を呈する様々な繊維が開発され、悪臭を繊維構造物で取り除く取り組みが行われている。例えば、消臭剤とポリエステル系樹脂を主成分とする繊維原料を溶融紡糸する技術が見られる(特許文献1)。
【0003】
【特許文献1】
特開平7−216751号公報
【0004】
【発明が解決しようとする課題】
しかしながら、消臭剤を利用したものは、消臭剤が飽和に達するともはや消臭効果を示さないことから、本発明は、当該効果を永続させるため、光分解触媒機能を有する光触媒酸化チタンを配合した生地を衣服等に利用することにより、消臭効果のみならず、防汚等の効果も半永久的に得られる衣服を提供しようとするものである。詳しくは、当該生地を生地を上手く汚れ発生部分に使用して、汚れ付着防止衣服を提供するものであり、従来の衣服に自然に上記発明繊維を取り込む方法を提供するものである。
一般に人間または動物が体に纏う衣服はおもに体から分泌される汚れと、空気中などの外界により塵垢が付着する。しかもその汚れは、人間の場合はおもに上半身であれば、袖口、襟口に集中し、下半身であれば、股部分及び裾に集中する。さらに、ポケット部分等は上下共通で汚れる部分である。
また、動物であれば、人間に比べ体から発散される体液等の分泌物や体臭が強いため、体が触れる部分には光触媒酸化チタン配合の繊維を使用した方が良いであろう。あるいは、服の全体を配合繊維で構成することも考えられる。
【0005】
【課題を解決するための手段】
上記課題を解決するために請求項1記載の汚れ付着防止衣服は、衣服の袖口、襟周り、股部分、ポケット口、裾周りの少なくとも1つ以上の裏面及び/又は表面に光触媒酸化チタンを練りこんだ繊維を配したことを要旨とする。
【0006】
また、請求項2記載の汚れ付着防止衣服は衣服の全体構成繊維の素材配分を維持したまま、衣服の袖口、襟周り、股部分、ポケット口、裾周りの少なくとも1つ以上の部分において合成繊維に光触媒酸化チタンを混合したことを要旨とする。
【0007】
また、請求項3記載の動物用の衣服は、衣服全体あるいは体と接する部分に光触媒酸化チタン配合の繊維を使用したことを要旨とする。
【0008】
【発明の実施の形態】
本発明における酸化チタンは光触媒酸化チタンを用いる。光触媒酸化チタンは電気的性質において半導体としての性質を持っている。二酸化チタンに光(特に380nm前後の近紫外線)が当たると、そのエネルギー(光子)を受けて空気中の酸素と水分に作用し、活性酸素と呼ばれる物質を生成する。この活性酸素は強い酸化力があり、光触媒酸化チタンの表面に付着したいろいろな有機化合物、すなわち悪臭や汚れの原因物質を酸化分解し、細菌も殺す効果がある。ちなみに他の酸化剤であるオゾンや過酸化水素、過酸化水素ラジカル、次亜塩素酸、塩素等と比べて2倍の酸化力がある。
【0009】
光触媒酸化チタンは、通常の条件では酸にもアルカリにも溶けず、化学的・物理的にも安定で無害である。さらに、光―化学反応においても、光触媒酸化チタンそのものは変化せず、永久にその機能を発揮することが可能となる。
活性酸素は光触媒酸化チタンの表面のみに存在し、空気中には放出されない。また、光触媒酸化チタンを含む材料の表面に触れるなどしても全く害はない。
【0010】
本発明で使用する光触媒酸化チタンは、粉末の光触媒酸化チタンの表面に薄いアパタイト(多孔質リン酸カルシウム)を被覆する方法を用いてなる。かかる方法により、従来、光触媒酸化チタンが、光―化学反応により有機物質を酸化分解し、プラスチックへの練りこみができなかったという欠点を克服し、優れた光触媒機能を保ちながら、バインダー・樹脂等に分散させても、媒体を破壊しないという機能を有することとなった。
【0011】
衣服への応用パターンとしては、汚れの強い袖口、襟口、裾、股部等に光触媒酸化チタンを含有した繊維を用いる方法や、天然繊維との混紡であれば、合成繊維含有分について、特に汚れの強い部分にさらに光触媒酸化チタンを混紡させるなどの方法が考えられる。別生地で汚れの強い部分に縫い合わせる場合は、裏側にのみ光触媒酸化チタン混紡の生地を使用しても良いし、その部分の表裏を一体的に光触媒酸化チタン混紡生地を使用しても良い。
【0012】
【実施例】
以下本発明の実施例を図1から図3を参照して説明する。
[実施例1]
本発明は、図1に示すように汚れの強い袖口(2)、襟周り(1)、裾周り(4)、股部(3)、ポケット口(5)等に光触媒酸化チタンを混紡した生地を使用したものである。
このような部分に光触媒酸化チタンの混紡された生地を使用すると、光触媒酸化チタンの下記のような性質により各種の作用を発揮する。
1)水や空気の浄化効果により、汚れた空気等も浄化されるので、襟首や袖口の汚れはぐっと少なくなる。
2)防汚効果(酸化分解によって、油汚れ等にも効果がある。)により、袖口、襟回り、裾周り等において、汚れの付着そのものを防止する。
3)抗菌防カビ効果(酸化分解による)があるため、汚れに付着後の細菌の繁殖を防止でき、汚れの悪化や広がりを防止できることとなる。
4)有害物質(悪臭等)を分解するため、付着した汚れが分解される。そして、紫外線が当たっている限り酸化分解を続けるので強力な悪臭でも、いつかは0にすることが可能となる。
5)帯電防止効果(埃よけ)があるため、衣服の汚れ具合が極端に小さくなる。
【0013】
図2には光触媒酸化チタン製品と活性炭・キトサン等製品についての汚れの減衰率を示した図である。この図から明らかなように、活性炭やキトサンはある程度までしか汚れが除去できないのに対して、光触媒酸化チタンであれば、時間をかければ0にまですることが可能となる。
なお、袖口等の生地の配し方は、表裏とも用いても良いし、裏面、すなわち肌に接する部分にのみ配しても良いことはもちろんである。
カッターシャツで実験したところ光触媒酸化チタン混紡の生地を使用しないカッターシャツにおいては、毎日汚れて取りかえる必要があったが、本発明のカッターシャツであれば、3日着用しても、ほとんど汚れが目立たない状態で、汗臭さも発生せず、2−3日の出張であれば、着替えを持参する必要がなくなった。
【0014】
[実施例2]
本発明は実施例1の事例において、本体の生地と違和感無く光触媒酸化チタン混紡の生地を使用した場合の一例を示す。
今カッターシャツの生地がポリエステル50%と綿50%の混紡であったとする。このような場合、袖口や襟首も綿が50%入った混紡の方が着心地が同一で好ましい。したがってこの場合は、例えばポリエステル50%を変更して、ポリエステル35%と光触媒酸化チタン繊維15%とし、全体としては、ポリエステル35%と光触媒酸化チタン繊維15%、綿50%の繊維で汚れの強い部分に使用する。
このような衣服であれば、光触媒酸化チタン繊維を使用している部分と使用していない部分との使用感の違いがおきにくく、着用者にとり着用感の異ならない好ましい衣服となる。
【0015】
[実施例3]
本発明は動物の衣服に、光触媒酸化チタン繊維を用いた場合の実施例
である。特に動物の場合は人間に比べ体臭や体液が多く、悪臭も強いため、動物の体に触れる部分には光触媒酸化チタンを含んだ繊維を配するようにした。図3の胴巻きでは内側部分(6)が本発明の光触媒酸化チタン繊維で構成している。このような胴巻きを使用すると、ペット特有のにおいが無くなり買主が快適に暮らせると共に、ペット自身にもダニ等の発生を防止する結果、皮膚のかゆみ等も起こらず、快適に過ごせるものである。
【0016】
【発明の効果】
以上説明したように、本発明に用いる光触媒酸化チタンは種々の酸化分解作用や、浄化作用、防汚作用等を有するため、汚れの付着防止や悪臭の分解、殺菌効果、帯電防止ひいては、埃の付着防止等、衣服の汚れに対してマイナス、分解方向の効果を多数有しており、衣服の特に汚れの強い部分に使用することでこれらの効果が倍増するため、単に繊維に織り込んで衣服を仕上げる場合に比較して顕著な効果が見られる。
また、動物の衣服に、光触媒酸化チタン繊維を用いた場合には、さらに顕著な効果が認められ、よりペットを買いやすい環境を提供することになる。
【図面の簡単な説明】
【図1】本発明の一実施例を示す概略説明図
【図2】光触媒酸化チタン製品と活性炭・キトサン等製品についての汚れの減衰率を示した図
【図3】動物の衣服に、光触媒酸化チタン繊維を用いた場合の概略説明図
【符号の説明】
1 襟周り
2 袖口
3 股部分
4 裾周り
5 ポケット口
6 胴巻き
[0001]
[Industrial applications]
The present invention relates to a dirt-adhesion preventing garment using a fabric containing a photocatalytic titanium oxide.
[0002]
[Prior art]
Conventionally, various fibers exhibiting deodorizing effects and the like have been developed, and efforts have been made to remove malodor with a fiber structure. For example, there is a technique of melt-spinning a fiber raw material containing a deodorant and a polyester resin as main components (Patent Document 1).
[0003]
[Patent Document 1]
Japanese Patent Application Laid-Open No. Hei 7-216751
[Problems to be solved by the invention]
However, since those using a deodorant no longer show a deodorizing effect when the deodorant reaches saturation, the present invention provides a photocatalytic titanium oxide having a photodecomposition catalytic function to maintain the effect. It is an object of the present invention to provide a garment in which not only a deodorizing effect but also an antifouling effect is semi-permanently obtained by using the blended fabric for clothes and the like. More specifically, the present invention provides a dirt-adhesion preventive garment by using the dough as a dirt-producing portion satisfactorily, and provides a method for naturally incorporating the above-mentioned fiber into conventional garments.
In general, clothes worn by humans or animals on the body mainly adhere to dirt secreted from the body and dust from the outside such as in the air. In addition, in the case of a human, the dirt concentrates mainly on the cuffs and the collar when the upper body is used, and concentrates on the crotch part and the hem when the lower body is used. Furthermore, the pocket portion and the like are portions that are commonly soiled in the upper and lower portions.
Further, in the case of animals, since secretions such as bodily fluids emitted from the body and body odor are stronger than humans, it is better to use a fiber containing titanium oxide photocatalyst in a portion where the body touches. Alternatively, it is conceivable that the whole of the clothes is composed of the compound fiber.
[0005]
[Means for Solving the Problems]
In order to solve the above-mentioned problem, the anti-fouling garment according to claim 1 is made by kneading photocatalytic titanium oxide on at least one of the back and / or front surfaces around the cuffs, collar, crotch, pocket, and hem of the garment. The gist is that inlaid fibers are arranged.
[0006]
In addition, the garment according to claim 2 has synthetic fibers in at least one or more of the cuffs, the collar, the crotch, the pocket, and the hem of the garment while maintaining the material distribution of the constituent fibers of the garment. The main point is that the photocatalyst titanium oxide is mixed with this.
[0007]
In addition, the animal clothing according to the third aspect is characterized in that fibers containing photocatalytic titanium oxide are used for the entire clothing or a portion in contact with the body.
[0008]
BEST MODE FOR CARRYING OUT THE INVENTION
The titanium oxide in the present invention uses a photocatalytic titanium oxide. Photocatalytic titanium oxide has semiconductor properties as electrical properties. When light (particularly near-ultraviolet light of about 380 nm) is applied to titanium dioxide, it receives the energy (photons) and acts on oxygen and moisture in the air to generate a substance called active oxygen. This active oxygen has a strong oxidizing power, and has an effect of oxidizing and decomposing various organic compounds attached to the surface of the photocatalytic titanium oxide, that is, substances causing odor and stain, and killing bacteria. Incidentally, it has twice the oxidizing power as compared with other oxidizing agents such as ozone, hydrogen peroxide, hydrogen peroxide radical, hypochlorous acid and chlorine.
[0009]
Under ordinary conditions, photocatalytic titanium oxide is insoluble in acids and alkalis and is chemically and physically stable and harmless. Further, even in the photo-chemical reaction, the photocatalytic titanium oxide itself does not change, and can exhibit its function forever.
Active oxygen exists only on the surface of the photocatalytic titanium oxide and is not released into the air. Moreover, there is no harm at all even if the surface of the material containing the photocatalytic titanium oxide is touched.
[0010]
The photocatalytic titanium oxide used in the present invention is obtained by a method of coating a thin apatite (porous calcium phosphate) on the surface of the powdered photocatalytic titanium oxide. By such a method, conventionally, the photocatalytic titanium oxide oxidized and decomposed organic substances by a photo-chemical reaction to overcome the drawback that it could not be kneaded into plastics. Has a function of not destroying the medium even when dispersed.
[0011]
As a pattern applied to clothing, the method of using fibers containing photocatalytic titanium oxide in strong cuffs, collars, hem, crotch and the like of dirt, or if mixed with natural fibers, synthetic fiber content, especially For example, a method in which a photocatalytic titanium oxide is further spun into a highly contaminated portion is considered. In the case where sewing is performed on a highly stained portion with a different fabric, a photocatalyst titanium oxide blended fabric may be used only on the back side, or a photocatalyst titanium oxide blended fabric may be integrally used for the front and back of the portion.
[0012]
【Example】
An embodiment of the present invention will be described below with reference to FIGS.
[Example 1]
As shown in FIG. 1, the present invention provides a fabric in which photocatalytic titanium oxide is blended in cuffs (2), around collars (1), around hem (4), crotch (3), pocket mouths (5), etc. Is used.
When a fabric mixed with photocatalytic titanium oxide is used in such a portion, various effects are exhibited by the following properties of the photocatalytic titanium oxide.
1) The dirty air and the like are also purified by the purifying effect of water and air, so that the dirt on the neck and cuffs is significantly reduced.
2) The antifouling effect (the effect of oxidative decomposition on oil stains, etc.) prevents the adhesion of stains on cuffs, around collars, around hem, and the like.
3) Since it has an antibacterial and antifungal effect (due to oxidative decomposition), it is possible to prevent the growth of bacteria after adhering to dirt, and to prevent deterioration and spread of dirt.
4) Decomposes harmful substances (such as bad smells), so that attached dirt is decomposed. Since the oxidative decomposition is continued as long as the ultraviolet rays are applied, even a strong odor can be reduced to zero someday.
5) Because of the antistatic effect (dust protection), the degree of dirt on clothes is extremely reduced.
[0013]
FIG. 2 is a graph showing the decay rate of dirt for the photocatalytic titanium oxide product and products such as activated carbon and chitosan. As is clear from this figure, activated carbon and chitosan can remove only a certain amount of dirt, whereas photocatalytic titanium oxide can be reduced to zero over time.
It should be noted that the cloth such as the cuffs may be disposed on both sides, or may be disposed only on the back side, that is, only on the portion in contact with the skin.
Experiments with a cutter shirt revealed that the cutter shirt that does not use the photocatalytic titanium oxide blended fabric needed to be replaced every day. There is no need to bring a change of clothes on a business trip of 2-3 days without any noticeable sweat odor.
[0014]
[Example 2]
The present invention shows an example in the case of Example 1 in which a photocatalytic titanium oxide blended fabric is used without any discomfort from the fabric of the main body.
Suppose that the fabric of the cutter shirt is a blend of 50% polyester and 50% cotton. In such a case, it is preferable that the cuffs and the neck have the same comfort when mixed with 50% cotton. Therefore, in this case, for example, the polyester is changed from 50% to 35% polyester and 15% photocatalytic titanium oxide fiber. As a whole, the fiber is 35% polyester, 15% photocatalytic titanium oxide fiber, and 50% cotton and is strongly stained. Used for parts.
With such a garment, there is little difference in the feeling of use between the portion using the photocatalytic titanium oxide fiber and the portion not using the photocatalyst titanium oxide fiber, and the garment is a preferable garment with no difference in wearing feeling for the wearer.
[0015]
[Example 3]
The present invention is an embodiment in which a photocatalytic titanium oxide fiber is used for animal clothes. In particular, animals have more body odors and body fluids than humans and have a strong odor, so fibers containing photocatalytic titanium oxide are arranged on the parts that come into contact with animals. 3, the inner portion (6) is made of the photocatalytic titanium oxide fiber of the present invention. When such a torso is used, the smell peculiar to the pet is eliminated, so that the buyer can live comfortably, and the pet itself prevents the occurrence of ticks and the like, so that itching of the skin does not occur and the pet can be spent comfortably.
[0016]
【The invention's effect】
As described above, the photocatalytic titanium oxide used in the present invention has various oxidative decomposition functions, a purification function, an antifouling function, and the like. It has many effects in the direction of disassembly, such as anti-adhesion, on the dirt of clothes, and these effects are doubled by using it on particularly dirty parts of the clothes. A remarkable effect is seen as compared with the case of finishing.
Further, when the photocatalytic titanium oxide fiber is used for the clothes of animals, a more remarkable effect is recognized, and an environment in which a pet can be more easily purchased is provided.
[Brief description of the drawings]
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic explanatory view showing one embodiment of the present invention. FIG. 2 is a view showing the attenuation rate of dirt on a photocatalytic titanium oxide product and products such as activated carbon and chitosan. Schematic explanation when titanium fiber is used [Explanation of symbols]
1 collar around 2 cuffs 3 crotch 4 hem around 5 pockets 6 torso

Claims (3)

衣服の袖口、襟周り、股部分、ポケット口、裾周りの少なくとも1つ以上の裏面及び/又は表面に光触媒酸化チタンを練りこんだ繊維を配したことを特徴とする汚れ付着防止衣服。A stain-preventing garment, characterized in that at least one or more of the back and / or the surface around the cuffs, collar, crotch, pocket, and hem of the garment is provided with fibers kneaded with photocatalytic titanium oxide. 衣服の全体構成繊維の素材配分を維持したまま、衣服の袖口、襟周り、股部分、ポケット口、裾周りの少なくとも1つ以上の部分において合成繊維に光触媒酸化チタンを混合したことを特徴とする汚れ付着防止衣服。The photocatalytic titanium oxide is mixed with synthetic fiber in at least one or more of the cuffs, collar, crotch, crotch, pocket, and hem of the garment while maintaining the material distribution of the overall constituent fibers of the garment. Anti-dirt clothing. 動物用の衣服であって、衣服全体あるいは体と接する部分に光触媒酸化チタン配合の繊維を使用したことを特徴とする動物用衣服Animal clothing characterized by using photocatalyst-titanium-oxide-blended fibers in the entire clothing or in contact with the body.
JP2003032851A 2003-02-10 2003-02-10 Stainproof garment Pending JP2004244733A (en)

Priority Applications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020170692A1 (en) * 2019-02-21 2020-08-27 東レ株式会社 Garment with fan
JP2021179016A (en) * 2020-05-11 2021-11-18 株式会社アイセル Manufacturing method of structure using fibers or leather, structure using fibers or leather, coating liquid and coating method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020170692A1 (en) * 2019-02-21 2020-08-27 東レ株式会社 Garment with fan
JPWO2020170692A1 (en) * 2019-02-21 2021-12-16 東レ株式会社 Clothing with a fan
JP2021179016A (en) * 2020-05-11 2021-11-18 株式会社アイセル Manufacturing method of structure using fibers or leather, structure using fibers or leather, coating liquid and coating method

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