JP2004243330A - Salt core for light alloy casting, its manufacturing method, and method for manufacturing light alloy cast product - Google Patents

Salt core for light alloy casting, its manufacturing method, and method for manufacturing light alloy cast product Download PDF

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Publication number
JP2004243330A
JP2004243330A JP2003033037A JP2003033037A JP2004243330A JP 2004243330 A JP2004243330 A JP 2004243330A JP 2003033037 A JP2003033037 A JP 2003033037A JP 2003033037 A JP2003033037 A JP 2003033037A JP 2004243330 A JP2004243330 A JP 2004243330A
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Japan
Prior art keywords
casting
light alloy
salt
alloy casting
nitrate
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JP2003033037A
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Japanese (ja)
Inventor
Tatsuhiko Kato
龍彦 加藤
Tadashi Makiguchi
直史 牧口
Takuya Nitta
拓也 新田
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Sintokogio Ltd
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Sintokogio Ltd
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Priority to JP2003033037A priority Critical patent/JP2004243330A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a salt core for light alloy casting, a salt core that can be easily removed from a cast product after light alloy casting and that can eliminate post processing including shot blast, sand blast, and spray of high pressure water, and also to provide its manufacturing method and method for manufacturing light alloy cast product using this salt core. <P>SOLUTION: This melting salt core is used for casting of a light alloy cast product such as the cast product of an aluminum alloy or magnesium alloy, and is manufactured by using nitrate in which the fusion point of the melting salt is in the range higher than 290°C and not higher than 500°C. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は、軽合金鋳物(アルミ合金鋳物やマグネシウム合金鋳物)の鋳造に適した塩中子及びその塩中子の製造方法並びに塩中子を使用して鋳造する軽合金鋳物の製造方法に関する。
【0002】
【従来の技術】
従来からアルミ合金鋳物やマグネシウム合金鋳物等の軽合金鋳物の鋳造方法として、砂型、金型を用いた重力鋳造、低圧鋳造および高圧のダイカスト、スクイ−ズダイカストなどがある。しかし、どの鋳造プロセスにおいても中子を用いる場合は、砂中子が用いられている(例えば、特許文献1参照。)。
【0003】
【特許文献1】
特開平03−23035号公報(第1〜3頁、第1図)
【0004】
【発明が解決しようとする課題】
上記したように、アルミ合金鋳物やマグネシウム合金鋳物等の軽合金鋳物の鋳造において砂中子が用いられるが、細い溝や袋部等では、砂が焼き付いたりしてショットブラスト、サンドブラスト、高圧水などを吹き付け落しているが、完全に砂落しができなくCCDスコープ等を用い、砂残りの有無の検査や手での砂落しがなされている。
【0005】
本発明は、上記の問題を解決するためになされたもので、軽合金鋳物を鋳造した後、中子を鋳物から容易に除去でき、ショットブラスト、サンドブラスト、高圧水等の吹き付け等の後処理を省略できる軽合金鋳物鋳造用塩中子及びその製造方法並びに軽合金鋳物の製造方法を提供することを目的とする。
【0006】
【課題を解決するための手段】
上記の目的を達成するために、本発明における軽合金鋳物鋳造用塩中子は、アルミ合金鋳物又はマグネシウム合金鋳物等の軽合金鋳物の鋳造に用いる溶融塩中子であって、該溶融塩は融点が290℃より高く500℃以下の範囲内の硝酸塩を使用したものであり、また前記硝酸塩は、成分として硝酸ナトリウム、硝酸カリウム、亜硝酸ナトリウム、硝酸バリウム、硝酸ストロンチウムのうち、少なくとも硝酸バリウムと硝酸ストロンチウムのどちらかを含むことを特徴とする。ここで本発明において融点とは固相線温度をいう。
【0007】
さらに本発明における軽合金鋳物鋳造用塩中子の製造方法は、融点が290℃より高く500℃以下の範囲内の硝酸塩の溶融塩状態のものを、金型に流し込み、凝固固化後に、金型から離型することを特徴とする。加えて軽合金鋳物の製造において温水浴もしくは水蒸気を用いて塩を洗浄した温水もしくは水蒸気を、硝酸塩濃縮法により塩濃度をあげ、その高濃度塩水を塩浴にもどし、さらに、金型に流し込み、凝固固化後に、金型から離型することを特徴とする。
【0008】
また本発明における軽合金鋳物の製造方法は、融点が290℃より高く500℃以下の範囲内の溶融塩中子を用いて軽合金鋳物を鋳造し、その塩中子を温水浴もしくは水蒸気を用いて除去して軽合金鋳物を生産することを特徴とする。加えて融点が290℃より高く500℃以下の範囲内の溶融塩中子を用いて軽合金鋳物を鋳造し、該軽合金鋳物を、その塩中子を溶融する塩浴内に浸漬して溶解し、取り出した後、温水浴もしくは水蒸気を用いて鋳物に付着する塩を除去して軽合金鋳物を生産することを特徴とするものである。
【0009】
ここで溶融塩は融点が290℃より高く500℃以下の範囲内としたのは、次の理由による。融点290℃以下では、軽合金鋳物の肉厚が薄い場合は問題ないが、軽合金鋳物の肉厚が厚かったり、金型を用いた鋳造の場合において金型の温度が高い場合、塩中子の溶解が生じるからである。また、融点500℃より高いと、温水浴もしくは水蒸気を用いて塩中子を除去しにくいためである。
【0010】
【発明の実施の形態】
(実施例)
まず、基礎試験として、鋳造アルミ材料はAC4Bとし、金型温度400℃、注湯温度740℃というかなり厳しい条件で、塩中子の材料として硝酸塩(硝酸ナトリウム、硝酸バリウム、硝酸カリウム、亜硝酸ナトリウムの混合塩)で融点が300℃、380℃、455℃、495℃、510℃のものを用い、各々温度を上げ、液体状態にしたのち、金型に流しこみ凝固させたものを塩中子とし、鋳造テストを実施した。その結果を表1に示す。
【0011】
【表1】

Figure 2004243330
【0012】
以上の結果から、軽合金鋳物の鋳造用中子に用いる塩の融点はある程度高いものが必要であることが判る。
【0013】
次に上記の硝酸塩中子を用いて鋳造したアルミ合金鋳物を同一成分の塩浴中に(各塩の融点より50〜70℃程度高い温度)漬け、塩中子を溶解後、60〜80℃の温水に漬けて洗浄した。その洗浄水は硝酸塩濃縮装置(新東ブレ−タ製「排水濃縮装置 型式0040」)にて硝酸塩濃度を高め、その高めた塩水を塩浴(溶融状態)に戻し、硝酸塩がシステム外に出ないクローズドシステムとした。また鋳造後、直ちに温水もしくは水蒸気にて洗浄してもよいが、上記装置の能力がかなり大きいものが必要になるため、鋳造後は塩浴中にて塩中子を溶解するほうが望ましい。
【0014】
【発明の効果】
本発明は、上記の説明から明らかなように、アルミ合金鋳物又はマグネシウム合金鋳物等の軽合金鋳物の鋳造に用いる溶融塩中子であって、該溶融塩の融点が290℃より高く500℃以下の範囲内の硝酸塩を使用したことを特徴とする軽合金鋳物鋳造用塩中子及びこの軽合金鋳物鋳造用塩中子の製造方法並びにその塩中子を使用する軽合金鋳物の製造方法であるから、砂落し等の必要がなく、装置、処理が容易になり、また塩をシステム外に出さないようにすることにより、環境に対しても配慮したシステムとなる等優れた効果がある。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a salt core suitable for casting a light alloy casting (aluminum alloy casting or magnesium alloy casting), a method of manufacturing the salt core, and a method of manufacturing a light alloy casting cast using the salt core.
[0002]
[Prior art]
2. Description of the Related Art Conventionally, as a casting method of a light alloy casting such as an aluminum alloy casting or a magnesium alloy casting, there are a gravity casting, a low pressure casting, a high pressure die casting, a squeeze die casting and the like using a sand mold and a mold. However, when a core is used in any casting process, a sand core is used (for example, see Patent Document 1).
[0003]
[Patent Document 1]
JP-A-03-23035 (pages 1-3, FIG. 1)
[0004]
[Problems to be solved by the invention]
As described above, sand cores are used in casting of light alloy castings such as aluminum alloy castings and magnesium alloy castings. However, it was not possible to completely remove the sand, and a CCD scope or the like was used to inspect for remaining sand and to remove the sand by hand.
[0005]
The present invention has been made in order to solve the above problems, and after casting a light alloy casting, the core can be easily removed from the casting, and shot blasting, sand blasting, and post-processing such as spraying with high-pressure water. It is an object of the present invention to provide a salt core for casting a light alloy casting which can be omitted, a method for manufacturing the same, and a method for manufacturing a light alloy casting.
[0006]
[Means for Solving the Problems]
In order to achieve the above object, a salt core for casting a light alloy casting in the present invention is a molten salt core used for casting a light alloy casting such as an aluminum alloy casting or a magnesium alloy casting, wherein the molten salt is A nitrate having a melting point of higher than 290 ° C. and not higher than 500 ° C. is used. It is characterized by containing either strontium. Here, in the present invention, the melting point refers to a solidus temperature.
[0007]
Further, in the method for producing a salt core for casting a light alloy casting according to the present invention, a molten salt state of nitrate having a melting point in a range of higher than 290 ° C. and not higher than 500 ° C. is poured into a mold and solidified and solidified. It is characterized in that it is released from the mold. In addition, in the production of light alloy castings, warm water or steam whose salt has been washed using a hot water bath or steam, the salt concentration is increased by a nitrate concentration method, the high-concentration salt water is returned to the salt bath, and further poured into a mold. After solidification and solidification, the mold is released from the mold.
[0008]
Further, the method for producing a light alloy casting according to the present invention comprises casting a light alloy casting using a molten salt core having a melting point in the range of higher than 290 ° C and not higher than 500 ° C, and using a hot water bath or steam for the salt core. To produce a light alloy casting. In addition, a light alloy casting is cast using a molten salt core having a melting point higher than 290 ° C. and not higher than 500 ° C., and the light alloy casting is immersed in a salt bath for melting the salt core and melted. Then, after taking out, the salt adhering to the casting is removed using a hot water bath or steam to produce a light alloy casting.
[0009]
Here, the reason why the melting point of the molten salt is set to be higher than 290 ° C. and lower than 500 ° C. is as follows. When the melting point is 290 ° C. or lower, there is no problem in the case where the thickness of the light alloy casting is thin, but when the thickness of the light alloy casting is thick or the temperature of the mold is high in the case of casting using a mold, the salt core is used. Is dissolved. If the melting point is higher than 500 ° C., it is difficult to remove the salt core using a hot water bath or steam.
[0010]
BEST MODE FOR CARRYING OUT THE INVENTION
(Example)
First, as a basic test, the cast aluminum material was AC4B, and under quite severe conditions of a mold temperature of 400 ° C. and a pouring temperature of 740 ° C., nitrate (sodium nitrate, barium nitrate, potassium nitrate, sodium nitrite) was used as a salt core material. A mixed salt having a melting point of 300 ° C., 380 ° C., 455 ° C., 495 ° C., and 510 ° C. is heated to a liquid state, then poured into a mold and solidified to form a salt core. , A casting test was performed. Table 1 shows the results.
[0011]
[Table 1]
Figure 2004243330
[0012]
From the above results, it is understood that the salt used for the casting core of the light alloy casting needs to have a certain high melting point.
[0013]
Next, the aluminum alloy casting cast using the above-mentioned nitrate core is immersed in a salt bath of the same component (at a temperature about 50 to 70 ° C. higher than the melting point of each salt), and after dissolving the salt core, the temperature is 60 to 80 ° C. Washed in hot water. The washing water is increased in nitrate concentration by a nitrate concentrator (“Drainage Concentrator Model 0040” manufactured by Shinto Breta), and the increased salt water is returned to a salt bath (in a molten state) so that nitrate does not go out of the system. Closed system. After casting, it may be washed with hot water or steam immediately. However, since the above-mentioned apparatus requires a considerably large capacity, it is preferable to dissolve the salt core in a salt bath after casting.
[0014]
【The invention's effect】
The present invention is, as apparent from the above description, a molten salt core used for casting a light alloy casting such as an aluminum alloy casting or a magnesium alloy casting, wherein the melting point of the molten salt is higher than 290 ° C and 500 ° C or less. A salt core for casting a light alloy casting, a method of manufacturing the salt core for casting a light alloy casting, and a method of manufacturing a light alloy casting using the salt core, characterized by using a nitrate in the range of Therefore, there is no need to remove sand and the like, and the apparatus and treatment are easy, and by preventing salt from leaving the system, there are excellent effects such as a system that is environmentally friendly.

Claims (6)

アルミ合金鋳物又はマグネシウム合金鋳物その他の軽合金鋳物の鋳造に用いる溶融塩中子であって、該溶融塩は融点が290℃より高く500℃以下の範囲内の硝酸塩を使用したことを特徴とする軽合金鋳物鋳造用塩中子。A molten salt core used for casting an aluminum alloy casting or a magnesium alloy casting or other light alloy casting, wherein the molten salt is a nitrate having a melting point higher than 290 ° C and lower than 500 ° C. Salt core for casting light alloy castings. 前記硝酸塩は、成分として硝酸ナトリウム、硝酸カリウム、亜硝酸ナトリウム、硝酸バリウム、硝酸ストロンチウムのうち、少なくとも硝酸バリウムと硝酸ストロンチウムのどちらかを含むことを特徴とする請求項1に記載の軽合金鋳物鋳造用塩中子。The light nitrate casting according to claim 1, wherein the nitrate contains at least one of barium nitrate and strontium nitrate as a component among sodium nitrate, potassium nitrate, sodium nitrite, barium nitrate, and strontium nitrate. Salt core. 融点が290℃より高く500℃以下の範囲内の硝酸塩の溶融塩状態のものを、金型に流し込み、凝固固化後に、金型から離型することを特徴とする軽合金鋳物鋳造用塩中子の製造方法。A salt core for light alloy casting casting, wherein a molten salt state of nitrate having a melting point higher than 290 ° C. and not higher than 500 ° C. is poured into a mold, and after solidification and solidification, is released from the mold. Manufacturing method. 融点が290℃より高く500℃以下の範囲内の溶融塩中子を用いて軽合金鋳物を鋳造し、その塩中子を温水浴もしくは水蒸気を用いて除去して軽合金鋳物を生産することを特徴とする軽合金鋳物の製造方法。Casting a light alloy casting using a molten salt core having a melting point higher than 290 ° C and not higher than 500 ° C, and removing the salt core using a hot water bath or steam to produce a light alloy casting. Characteristic light alloy casting manufacturing method. 融点が290℃より高く500℃以下の範囲内の溶融塩中子を用いて軽合金鋳物を鋳造し、該軽合金鋳物を、その塩中子を溶融する塩浴内に浸漬して溶解し、取り出した後、温水浴もしくは水蒸気を用いて鋳物に付着している塩を除去して軽合金鋳物を生産することを特徴とする軽合金鋳物の製造方法。A light alloy casting is cast using a molten salt core having a melting point higher than 290 ° C and not higher than 500 ° C, and the light alloy casting is immersed and dissolved in a salt bath for melting the salt core, A method for producing a light alloy casting, comprising removing a salt adhering to the casting using a hot water bath or steam after taking out the light alloy casting to produce a light alloy casting. 請求項4又は5に記載の軽合金鋳物の製造方法において、温水浴もしくは水蒸気を用いて塩を洗浄した温水もしくは水蒸気を、硝酸塩濃縮法により塩濃度をあげ、その高濃度塩水を塩浴に戻し、さらに金型に流し込み、凝固固化後に、金型から離型することを特徴とする軽合金鋳物鋳造用塩中子の製造方法。The method for producing a light alloy casting according to claim 4 or 5, wherein the salt concentration of hot water or steam whose salt has been washed using a hot water bath or steam is increased by a nitrate concentration method, and the high-concentration salt water is returned to the salt bath. A method for producing a salt core for light alloy casting casting, further comprising: pouring the mixture into a mold; solidifying and solidifying the mixture; and releasing the mold from the mold.
JP2003033037A 2003-02-12 2003-02-12 Salt core for light alloy casting, its manufacturing method, and method for manufacturing light alloy cast product Pending JP2004243330A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110202095A (en) * 2019-06-20 2019-09-06 广东肇庆动力金属股份有限公司 Core mold and the casting mould for preparing core mold

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110202095A (en) * 2019-06-20 2019-09-06 广东肇庆动力金属股份有限公司 Core mold and the casting mould for preparing core mold

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