JP2004203710A - Woody cement plate, and production method therefor - Google Patents

Woody cement plate, and production method therefor Download PDF

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Publication number
JP2004203710A
JP2004203710A JP2002377644A JP2002377644A JP2004203710A JP 2004203710 A JP2004203710 A JP 2004203710A JP 2002377644 A JP2002377644 A JP 2002377644A JP 2002377644 A JP2002377644 A JP 2002377644A JP 2004203710 A JP2004203710 A JP 2004203710A
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Japan
Prior art keywords
wood
cement
mat
curing
mixed
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JP2002377644A
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Japanese (ja)
Inventor
Naoki Murase
直樹 村瀬
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Nichiha Corp
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Nichiha Corp
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Priority to JP2002377644A priority Critical patent/JP2004203710A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Panels For Use In Building Construction (AREA)
  • Producing Shaped Articles From Materials (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a woody cement plate in which the quick hardening of cement is possible, and which has no problems caused by chlorides, and to provide a production method therefor. <P>SOLUTION: In the woody cement plate and the method of producing the woody cement plate, raw materials essentially consisting of a cement-based inorganic material and a woody reinforcing material are added to and mixed with magnesium formate, the mixture is scattered over a substrate to form a mat, the mat is pressed and is subjected to primary hardening/curing, and the primarily hardened/cured mat is subjected to cold curing or autoclave curing. <P>COPYRIGHT: (C)2004,JPO&NCIPI

Description

【0001】
【発明の属する技術分野】
本発明は主として建築物に使用される木質セメント板およびその製造方法に関するものである。
【0002】
【発明の背景】
木質セメント板は、木質補強材とセメント系無機材料とを主な原料として湿式法、乾式法、あるいは半乾式法によって製造されている。
該木質補強材としては、木片、木毛、木質パルプ等が用いられるが、近年木質資源が不足の傾向にあり、また地球環境保護の観点からも木質資源の節約が求められている。
したがって、最近では、木質資源の節約のために木造建築物を解体する際に発生する古材、製材工程から発生する鋸屑や端材、針葉樹の間伐材、木質セメント板のスクラップ等、従来では埋め立てや焼却して処分されている木質スクラップから再生した木質補強材の使用が検討されている。
【0003】
しかしながら、上記木質スクラップは多種多様の樹種からなり、したがって該木質スクラップにはセメントの硬化阻害物質となる糖類等を多量に含む樹種も混入され、このような樹種を木質スクラップから除去することは非常に手間がかかり困難な作業となる。
したがって木質スクラップから再生した木質補強材を木質セメント板の原料として実用的に使用するには、セメントの硬化を円滑に進めることができるようにしなければならない。
【0004】
【従来の技術】
従来より、木質補強材に含有される糖類等によるセメント硬化阻害を解消するために、木質補強材中に塩化カルシウムや塩化マグネシウム等の金属塩化物を硬化促進剤として含浸させたり混合することによってセメントの硬化を促進する方法が提供されている。
木質補強材から溶出したセメント硬化阻害物質たる糖類等は不溶物として未反応セメントクリンカ−の周囲を覆うが、上記金属塩化物は該不溶物を溶解するため、該不溶物が溶解した部分から水が侵入して、未反応セメントクリンカ−とが反応し、セメントの硬化が開始する。
【0005】
【特許文献1】
特開昭59−18153号
【特許文献2】
特開昭60−118658号
【0006】
【発明が解決しようとする課題】
しかしながら、上記塩化カルシウムは該糖類等の不溶物を部分的に溶解し、該不溶物が溶解した部分から侵入した水が未反応セメントクリンカ−と反応することによってセメントの硬化が進行するため、該硬化反応速度は大きくなく、したがって上記金属塩化物による硬化促進作用は十分であるとはいい難かった。
さらに、上記金属塩化物は、鉄等の金属を錆びさせたり、塩素・塩化物によっては人体に悪影響を及ぼしたり、焼却時にダイオキシンの発生原因となる等、種々の問題を有している。
したがって、本発明の課題は、セメントの速やかな硬化が可能で、塩化物に起因する上記問題のない木質セメント板およびその製造方法を提供することである。
【0007】
【課題を解決するための手段】
上記の課題を解決するために本請求項1に記載の発明は、セメント系無機材料と木質補強材とを主原料とした原料に、蟻酸マグネシウムを添加混合し、該混合物にてマットをフォ−ミングし、該マットを硬化養生せしめたことによって得られた木質セメント板であることを特徴としている。
上記の構成によれば、セメントの速やかな硬化が可能で、塩化物に起因する問題のない木質セメント板を提供することが出来る。
【0008】
また、本請求項2に記載の発明は、セメント系無機材料と木質補強材とを主原料とした原料に、蟻酸マグネシウムを添加混合し、該混合物を基板上に散布してマットをフォ−ミングし、該マットを圧締して一次硬化養生せしめ、該一次硬化養生マットを常温養生又はオ−トクレ−ブ養生することを特徴とする木質セメント板の製造方法である。
上記の構成によれば、セメントの速やかな硬化が可能で、塩化物に起因する問題のない木質セメント板を製造することが出来る。
【0009】
【発明の実施の形態】
以下、本発明の実施の形態を具体的に説明する。
[セメント系無機材料]
本発明に使用されるセメント系無機材料とは、ケイ酸カルシウムを主成分とした水硬性の無機材料であり、このような無機材料としては例えばポルトランドセメント、高炉スラグセメント、フライアッシュセメント、シリカセメント、アルミナセメント、白色セメント等のセメント類がある。
上記セメント類は二種以上混合使用されてもよい。
【0010】
[木質補強材]
本発明に使用される木質補強材としては、木粉、木片、木毛、木質繊維、木質パルプ、木質繊維束、ドライパルプ等の形状のものが使用される。
好ましい木質補強材の形状としては、巾0.5〜2.0mm、長さ1〜20mm、長さと厚みの比率(アスペクト比)が20〜30の木片や、直径0.1〜2.0mm、長さ2〜35mmの分枝および/または彎曲および/または折曲した木質繊維束がある。
また、本発明に使用される木質補強材の樹種としては、ひのき、杉辺材、ひば、松、あかまつ、いたや楓、白樺辺材、もみ、みずなら、米ひば、米ひのき、レッドラワン等のセメント硬化阻害物質の少ない樹種はもちろん、杉芯材、からまつ、なら、けやき、米杉、米松、米つが、イエロ−ラワン、ケナフ、竹、麻、バガス、もみ殻等の比較的セメント硬化阻害物質を多く含む樹種についても使用出来る。
上記木質補強材は二種以上混合されてもよい。
【0011】
[骨材]
上記セメント系無機材料および木質補強材以外に、本発明においては骨材、特に軽量骨材を混合してもよい。
上記骨材としては、例えば、ケイ砂、ケイ石粉等が使用され、上記軽量骨材としては、例えばパ−ライト、シラスバル−ン、膨張頁石、膨張粘土、焼成珪藻土、フライアッシュ、石炭ガラ等が使用される。
【0012】
[第三成分]
上記混合物には、所望なれば更に硫酸アルミニウム、硫酸マグネシウム、アルミン酸塩類、水ガラス等の硬化促進剤やロウ、ワックス、パラフィン、界面活性剤、シリコン等の防水剤や撥水剤等が混合されてもよい。
【0013】
[蟻酸マグネシウム]
本発明で使用する蟻酸マグネシウムは、水溶液として添加することが好ましい。
マグネシウムはアルカリ土類金属に属し、セメント硬化阻害物質である糖類等の木質溶出有機成分を不溶、固定化する効果が大きい。
マグネシウムはカルシウムよりも元素周期律表の上段に位置するため、一般に同じ対イオンによる塩を生成した場合、マグネシウム塩はカルシウム塩よりも溶解度が小さくイオン化傾向が小さいので、セメント硬化阻害物質である木質溶出有機成分が共存する場合、未反応セメントクリンカ−を被覆して不溶物となった木質溶出有機成分を分解させ、セメントの水和反応を進行させると同時に、この物質とマグネシウムが塩となった場合には速やかに固定化してイオン化せず、木質溶出有機成分がセメントに接触することを防止する。
またカルシウムよりも原子量が小さいため、同質量でもモル数が大きくなり、木質溶出有機成分に対する反応性がよい。
上記蟻酸マグネシウムの添加量は、セメントに対して又はセメントとケイカル反応する骨材との合計100質量部に対して通常0.5〜7.0質量比とされる。
【0014】
[木質セメント板の製造方法]
本発明においては、半乾式製法または乾式製法によって木質セメント板を製造する。
半乾式製法の場合、まず、上記セメントおよび木質補強材、そして所望により骨材、第三成分を含有する混合物に、上記蟻酸マグネシウム及び水を添加混合するか又は蟻酸マグネシウム水溶液を添加混合し、得られた成形材料を基板上に散布してマットをフォ−ミングする。
水は該マットの水分含有率が15〜65質量%となるように添加するのが好ましい。
【0015】
乾式製法の場合、まず、上記セメントおよび木質補強材、そして所望により骨材、第三成分を含有する混合物に、上記蟻酸マグネシウム及び水を添加混合するか又は蟻酸マグネシウム水溶液を添加混合し、得られた成形材料を基板上に散布してマットをフォ−ミングし、該マットに更に水を添加する。
更に添加する水は該マットの水分含有率が15〜65質量%となるように添加するのが好ましい。
【0016】
以上のようにマットがフォ−ミングされたら、該マットを基板とともに圧締して加熱状態下で一次硬化養生せしめる。
該一次硬化養生において適用される温度は通常50〜100℃であり、圧締圧は通常2〜5MPaである。
上記一次硬化養生後、得られた一次硬化養生体は脱型した上で常温養生またはオ−トクレ−ブ養生する。
常温養生は、通常常温で4〜10日間行われ、オ−トクレ−ブ養生は、130〜180℃の温度で10〜18時間行われる。
常温養生またはオ−トクレ−ブ養生後は、乾燥工程を経て表面塗装等を行い、最終製品とする。
【0017】
木質セメント板表面に凹凸模様を付する場合には、該基板の型面に該凹凸模様に対応した凹凸模様を形成しておけばよい。
また、表面に凹凸模様の無い平滑な木質セメント板を製造するには基板として直接搬送板を使用しても良い。
【0018】
以上説明した本発明の方法によって、二層構造または三層構造の木質セメント板を製造することも出来る。
二層構造の場合には、まず粒子径の細かい木質補強材を混合した成形材料を基板上に散布し、次いでその上に粒子径の大きい木質補強材を混合した成形材料を散布して二層構造のマットをフォ−ミングし、該マットを圧締・加熱して上記粒子径の細かい木質補強材を混合した成形材料によって緻密構造の表層部を形成し、上記粒子径の大きい木質補強材を混合した成形材料によって粗構造の裏面部を形成する。
【0019】
三層構造の場合には、上記二層構造の場合の粒子径の大きい木質補強材を混合した成形材料の上に更に粒子径の細かい木質補強材を混合した成形材料を散布して三層構造のマットをフォ−ミングし、該マットを圧締・加熱して上記粒子径の大きい木質補強材を混合した成形材料からなる層を芯層部とし、その上下の粒子径の細かい木質補強材を混合した成形材料からなる層を表裏層部とする。
また、上記二層構造のマットを、粒子径の大きい木質補強材を混合した成形材料からなる層相互が接触するように二枚積層して圧締・加熱してもよい。
【0020】
【実施例】
以下、本発明の実施例を挙げる。
【0021】
表1に示す配合にて実施例1〜6、比較例1、2を製造した。
原料配合は、配合原料に対して水分量44質量%になるように水を添加し、均一混合した。
蟻酸マグネシウム及び塩化マグネシウムは、木片と廃材粉砕物を除く粉体の質量に対しての添加量である。
得られた原料混合物を基板上に散布してマットをフォ−ミングし、該マットを3.4MPaで圧締し、そのまま50℃、8時間で一次硬化養生した。
その後、圧締条件を解き、実施例1、2及び比較例1は常温4日で自然養生し、実施例3から6及び比較例2は、160℃、8時間キ−プでオ−トクレ−ブ養生し、その後、乾燥、塗装工程を経て製品とした。
これらの諸物性を表1に示す。
【0022】
【表1】

Figure 2004203710
【0023】
また、表2に示す配合にて三層構造の実施例7、8、比較例3を製造した。
原料配合は、配合原料に対して水分量30質量%になるように水を添加し、均一混合した。
蟻酸マグネシウム及び塩化マグネシウムは、木質原料と廃材粉砕物と発泡ポリスチレンビ−ズを除いた粉体の質量に対しての添加量である。
得られた原料混合物の表裏層用の原料をまず基板上に散布して表層とし、その上に芯層用の原料を散布して芯層とし、更にその上に表裏層用の原料を散布して裏層として三層構造としてマットをフォ−ミングし、該マットを3.9MPaで圧締し、そのまま50℃、8時間で一次硬化養生した。
その後、圧締条件を解き、160℃、8時間キ−プでオ−トクレ−ブ養生し、その後、乾燥、塗装工程を経て製品とした。
これらの諸物性を表3に示す。
【0024】
【表2】
Figure 2004203710
【0025】
【表3】
Figure 2004203710
【0026】
表1に示すように、実施例2と比較例1、実施例5と比較例2とを比べると、製品強度に相当する二次養生後の曲げ強度はさほど変わらなかったが、一次硬化養生後の曲げ強度は実施例のほうが高い値となった。
このことは、一次硬化養生後の曲げ強度が高くないと脱型等にて板材の破損等が生じやすく問題となるもので、一次硬化養生後の曲げ強度が製造工程中の時間を左右する重要因子であることによるものである。
【0027】
また、厚み膨潤率においても、比較例1、2よりも実施例のほうが若干優れた値となった。
【0028】
また、三層構造で製造した実施例8と比較例3においても、一次硬化養生後の曲げ強度、厚み膨潤率のいずれも塩化マグネシウムを使用した比較例3よりも蟻酸マグネシウムを使用した実施例8の方が優れた値を示した。
【0029】
【発明の効果】
以上説明したように、請求項1に記載の発明によれば、セメント系無機材料と木質補強材とを主原料とした原料に、蟻酸マグネシウムを添加混合し、該混合物にてマットをフォ−ミングし、該マットを硬化養生せしめたことによって得られた木質セメント板であるので、セメントの速やかな硬化が可能で、塩化物に起因する問題のない木質セメント板を提供することが出来る。
【0030】
また、請求項2に記載の発明は、セメント系無機材料と木質補強材とを主原料とした原料に、蟻酸マグネシウムを添加混合し、該混合物を基板上に散布してマットをフォ−ミングし、該マットを圧締して一次硬化養生せしめ、該一次硬化養生マットを常温養生又はオ−トクレ−ブ養生することを特徴とする木質セメント板の製造方法であるので、セメントの速やかな硬化が可能で、塩化物に起因する問題のない木質セメント板を製造することが出来る。[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a wood cement board mainly used for buildings and a method for producing the same.
[0002]
BACKGROUND OF THE INVENTION
The wood cement board is manufactured by a wet method, a dry method, or a semi-dry method using a wood reinforcing material and a cement-based inorganic material as main raw materials.
As the wood reinforcing material, wood chips, wood wool, wood pulp, and the like are used. However, in recent years, there has been a tendency for wood resources to be insufficient, and from the viewpoint of global environmental protection, it is required to save wood resources.
Therefore, recently, in the past, landfills such as old wood generated when dismantling wooden buildings to save wood resources, sawdust and offcuts generated from the sawmilling process, thinned coniferous wood, scrap wood-based cement boards, etc. The use of wood reinforcements regenerated from wood scraps that have been incinerated and disposed of is being considered.
[0003]
However, the woody scrap is composed of a wide variety of wood species, and therefore, the woody scrap is also mixed with a woody species containing a large amount of saccharides and the like, which are cement hardening inhibitors, and it is very difficult to remove such woody species from the woody scrap. This is a laborious and difficult task.
Therefore, in order to use the wood reinforcing material regenerated from the wood scrap practically as a raw material of the wood cement board, it is necessary to smoothly advance the hardening of the cement.
[0004]
[Prior art]
Conventionally, in order to eliminate the inhibition of cement hardening due to saccharides and the like contained in the wood reinforcing material, cement has been impregnated or mixed with a metal chloride such as calcium chloride or magnesium chloride as a hardening accelerator in the wood reinforcing material. There is provided a method for accelerating the curing of
The saccharides and the like, which are the cement hardening inhibitory substances eluted from the wood reinforcing material, cover the periphery of the unreacted cement clinker as an insoluble substance, but since the metal chloride dissolves the insoluble substance, water is discharged from the portion where the insoluble substance is dissolved. Penetrates and reacts with the unreacted cement clinker to start hardening of the cement.
[0005]
[Patent Document 1]
JP-A-59-18153 [Patent Document 2]
JP-A-60-118658
[Problems to be solved by the invention]
However, the calcium chloride partially dissolves insolubles such as the saccharides, and water invading from a portion where the insolubles are dissolved reacts with unreacted cement clinker to promote hardening of the cement. The curing reaction rate was not high, and it was difficult to say that the above metal chlorides had a sufficient curing promoting action.
Furthermore, the above-mentioned metal chloride has various problems, such as rusting metals such as iron, harming the human body depending on chlorine and chloride, and causing dioxin during incineration.
Therefore, an object of the present invention is to provide a wood cement board which enables rapid hardening of cement and does not have the above-mentioned problems caused by chlorides, and a method for producing the same.
[0007]
[Means for Solving the Problems]
In order to solve the above-mentioned problems, the invention according to claim 1 is to add and mix magnesium formate to a raw material mainly composed of a cement-based inorganic material and a wood reinforcing material, and form a mat with the mixture. And a wood cement board obtained by hardening and curing the mat.
According to the above configuration, it is possible to quickly harden the cement, and to provide a wood cement board having no problem caused by chloride.
[0008]
Further, according to the invention of claim 2, magnesium formate is added to and mixed with a raw material mainly composed of a cement-based inorganic material and a wood reinforcing material, and the mixture is sprayed on a substrate to form a mat. A method for producing a wood cement board, comprising pressing the mat to primary hardening and curing the primary hardening mat at room temperature or autoclave.
According to the above configuration, it is possible to quickly cure the cement, and it is possible to manufacture a wood cement board having no problem caused by chloride.
[0009]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be specifically described.
[Cement-based inorganic materials]
The cement-based inorganic material used in the present invention is a hydraulic inorganic material containing calcium silicate as a main component, such as Portland cement, blast furnace slag cement, fly ash cement, silica cement , Alumina cement, white cement and the like.
The cements may be used as a mixture of two or more.
[0010]
[Wood reinforcement]
Examples of the wood reinforcing material used in the present invention include wood flour, wood chips, wood wool, wood fiber, wood pulp, wood fiber bundle, and dry pulp.
Preferred shapes of the wood reinforcing material include a wood piece having a width of 0.5 to 2.0 mm, a length of 1 to 20 mm, a length to thickness ratio (aspect ratio) of 20 to 30 or a diameter of 0.1 to 2.0 mm, There are branches and / or bent and / or bent wood fiber bundles of length 2-35 mm.
In addition, as the tree species of the wood reinforcing material used in the present invention, hinoki, cedar sapwood, leek, pine, red pine, itaya maple, birch sapwood, fir, mizuhara, rice hiba, rice hinoki, red lauan Cedar core, karamatsu, nara, zelkova, rice cedar, rice pine, rice tsutsumi, as well as tree species with low cement hardening inhibitors, such as yellow-lauan, kenaf, bamboo, hemp, bagasse, rice husk, etc. It can also be used for tree species that contain a large amount of hardening inhibitors.
Two or more kinds of the wood reinforcing materials may be mixed.
[0011]
[aggregate]
In the present invention, in addition to the cement-based inorganic material and the wood reinforcing material, an aggregate, particularly a lightweight aggregate, may be mixed.
As the above-mentioned aggregate, for example, silica sand, silica stone powder and the like are used. As the above-mentioned lightweight aggregate, for example, perlite, shirasu balloon, expanded shale, expanded clay, calcined diatomaceous earth, fly ash, coal ash, etc. Is used.
[0012]
[Third component]
If desired, a hardening accelerator such as aluminum sulfate, magnesium sulfate, aluminates, water glass, a wax, a wax, a paraffin, a surfactant, a waterproofing agent such as silicone, a water repellent, etc. may be added to the mixture. You may.
[0013]
[Magnesium formate]
The magnesium formate used in the present invention is preferably added as an aqueous solution.
Magnesium belongs to alkaline earth metals, and has a great effect of insoluble and immobilizing wood-eluting organic components such as sugars, which are cement hardening inhibitors.
Since magnesium is located at the top of the Periodic Table of the Elements compared with calcium, when salts are formed with the same counter ion, magnesium salts are generally less soluble and less ionizable than calcium salts. When the eluted organic components coexist, the unreacted cement clinker was coated to decompose the insoluble wood-eluted organic components, and the hydration reaction of the cement proceeded, and at the same time, this substance and magnesium became salts. In this case, it is immobilized quickly and does not ionize, thereby preventing the wood-eluting organic components from coming into contact with the cement.
In addition, since the atomic weight is smaller than that of calcium, the number of moles is large even with the same mass, and the reactivity to the wood-eluting organic components is good.
The amount of the magnesium formate to be added is usually 0.5 to 7.0 mass ratio with respect to the cement or a total of 100 mass parts of the cement and the aggregate which undergoes a calcite reaction.
[0014]
[Method of manufacturing wood cement board]
In the present invention, a wood cement board is manufactured by a semi-dry method or a dry method.
In the case of the semi-dry production method, first, the above-mentioned cement and the wood reinforcing material, and optionally the aggregate, the mixture containing the third component are added and mixed with the above-mentioned magnesium formate and water, or an aqueous solution of magnesium formate is added and mixed. The obtained molding material is sprayed on a substrate to form a mat.
Water is preferably added so that the moisture content of the mat is 15 to 65% by mass.
[0015]
In the case of the dry manufacturing method, first, the above-mentioned cement and wood reinforcing material, and if necessary, an aggregate, a mixture containing the third component, the above-mentioned magnesium formate and water are added or mixed, or an aqueous solution of magnesium formate is added and mixed. The molding material is sprayed on the substrate to form a mat, and water is further added to the mat.
Further, it is preferable to add water so that the moisture content of the mat is 15 to 65% by mass.
[0016]
After the mat has been formed as described above, the mat is pressed together with the substrate and primary cured under heating.
The temperature applied in the primary curing curing is usually 50 to 100 ° C., and the pressing pressure is usually 2 to 5 MPa.
After the above-mentioned primary hardening curing, the obtained primary hardening living body is demolded and then cured at room temperature or autoclave.
The room temperature curing is usually performed at room temperature for 4 to 10 days, and the autoclave curing is performed at a temperature of 130 to 180 ° C. for 10 to 18 hours.
After room temperature curing or autoclave curing, the surface is coated through a drying process to obtain a final product.
[0017]
When an uneven pattern is provided on the surface of the wood cement board, an uneven pattern corresponding to the uneven pattern may be formed on the mold surface of the substrate.
In order to manufacture a smooth wood cement board having no uneven pattern on the surface, a direct transport board may be used as a substrate.
[0018]
By the method of the present invention described above, a two-layer or three-layer wood cement board can also be manufactured.
In the case of a two-layer structure, first, a molding material mixed with a fine-grained wood reinforcing material is sprayed on a substrate, and then a molding material mixed with a large-grained wood reinforcing material is sprayed thereon to form a two-layer structure. Forming a mat having a structure, pressing and heating the mat, forming a surface layer portion of a dense structure with a molding material mixed with the wood reinforcing material having a fine particle diameter, and forming the wood reinforcing material having a large particle diameter. The back surface of the rough structure is formed by the mixed molding material.
[0019]
In the case of a three-layer structure, a three-layer structure is obtained by spraying a molding material in which a finer particle-size wood reinforcing material is further mixed on a molding material in which a larger-particle diameter wood reinforcing material in the case of the two-layer structure is mixed. Is formed, and the mat is pressed and heated to form a core layer containing a molding material obtained by mixing the above-described wood reinforcing material having a large particle diameter as a core layer portion. The layers made of the mixed molding materials are referred to as front and back layer portions.
Alternatively, two mats having the above-described two-layer structure may be laminated and pressed and heated so that layers made of a molding material mixed with a wood reinforcing material having a large particle diameter are in contact with each other.
[0020]
【Example】
Hereinafter, examples of the present invention will be described.
[0021]
Examples 1 to 6 and Comparative Examples 1 and 2 were produced with the formulations shown in Table 1.
In the raw material blending, water was added so as to have a water content of 44% by mass with respect to the blended raw materials, and mixed uniformly.
Magnesium formate and magnesium chloride are added to the mass of the powder excluding the wood chips and the crushed waste material.
The obtained raw material mixture was sprayed on a substrate to form a mat, and the mat was pressed at 3.4 MPa, and primary hardened and cured at 50 ° C. for 8 hours.
Thereafter, the pressing conditions were released, and Examples 1 and 2 and Comparative Example 1 were naturally cured at room temperature for 4 days. Examples 3 to 6 and Comparative Example 2 were autoclaved at 160 ° C. for 8 hours. Cured, then dried and painted to produce a product.
Table 1 shows these physical properties.
[0022]
[Table 1]
Figure 2004203710
[0023]
Further, Examples 7 and 8 and Comparative Example 3 having a three-layer structure were manufactured with the formulations shown in Table 2.
The raw materials were mixed by uniformly adding water so that the water content was 30% by mass based on the raw materials.
Magnesium formate and magnesium chloride are added to the mass of the powder excluding the wood raw material, the crushed waste material, and the expanded polystyrene beads.
First, a raw material for the front and back layers of the obtained raw material mixture is sprayed on a substrate to form a surface layer, and a raw material for a core layer is sprayed thereon to form a core layer, and a raw material for the front and back layers is further sprayed thereon. The mat was formed into a three-layer structure as a backing layer, and the mat was pressed at 3.9 MPa and primary cured at 50 ° C. for 8 hours.
Thereafter, the pressing conditions were released, and autoclave curing was performed at 160 ° C. for 8 hours, followed by drying and coating to obtain a product.
Table 3 shows these physical properties.
[0024]
[Table 2]
Figure 2004203710
[0025]
[Table 3]
Figure 2004203710
[0026]
As shown in Table 1, when Example 2 was compared with Comparative Example 1 and Example 5 was compared with Comparative Example 2, the bending strength after the secondary curing corresponding to the product strength did not change much, but after the primary curing curing. The bending strength of Example was higher than that of Example.
This means that if the bending strength after the primary curing curing is not high, breakage of the plate material or the like is likely to occur due to demolding, etc., and the bending strength after the primary curing curing determines the time during the manufacturing process. It is because it is a factor.
[0027]
Also, the thickness swelling ratio of the example was slightly superior to that of the comparative examples 1 and 2.
[0028]
Also, in Example 8 and Comparative Example 3 which were manufactured in a three-layer structure, the bending strength and the thickness swelling ratio after the primary hardening were both higher than those in Comparative Example 3 using magnesium chloride. Showed an excellent value.
[0029]
【The invention's effect】
As described above, according to the first aspect of the present invention, magnesium formate is added to and mixed with a raw material mainly composed of a cement-based inorganic material and a wood reinforcing material, and a mat is formed with the mixture. And since it is a wood cement board obtained by hardening and curing the mat, it is possible to provide a wood cement board which can quickly cure cement and has no problems caused by chlorides.
[0030]
According to a second aspect of the present invention, magnesium formate is added to and mixed with a raw material mainly composed of a cement-based inorganic material and a wood reinforcing material, and the mixture is sprayed on a substrate to form a mat. The method is a method of manufacturing a wood cement board characterized in that the mat is pressed and primary cured and the primary cured mat is cured at room temperature or autoclaved. It is possible to manufacture a wood cement board which is possible and has no problem caused by chloride.

Claims (2)

セメント系無機材料と木質補強材とを主原料とした原料に、蟻酸マグネシウムを添加混合し、該混合物にてマットをフォ−ミングし、該マットを硬化養生せしめたことを特徴とする木質セメント板A wood cement board characterized in that magnesium formate is added to and mixed with a raw material containing a cement-based inorganic material and a wood reinforcing material as main raw materials, a mat is formed from the mixture, and the mat is cured and cured. セメント系無機材料と木質補強材とを主原料とした原料に、蟻酸マグネシウムを添加混合し、該混合物を基板上に散布してマットをフォ−ミングし、該マットを圧締して一次硬化養生せしめ、該一次硬化養生マットを常温養生又はオ−トクレ−ブ養生することを特徴とする木質セメント板の製造方法Magnesium formate is added to and mixed with a raw material containing a cement-based inorganic material and a wood reinforcing material as main raw materials, and the mixture is sprayed on a substrate to form a mat. A method for producing a wood cement board, comprising subjecting the primary hardened mat to normal temperature curing or autoclave curing.
JP2002377644A 2002-12-26 2002-12-26 Woody cement plate, and production method therefor Pending JP2004203710A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009196868A (en) * 2008-02-25 2009-09-03 Koichi Suchi Completely integrated composite multi-purpose aggregate by recycling waste

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009196868A (en) * 2008-02-25 2009-09-03 Koichi Suchi Completely integrated composite multi-purpose aggregate by recycling waste

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