JP2004115954A - Stretchable fancy yarn having antimicrobial property - Google Patents

Stretchable fancy yarn having antimicrobial property Download PDF

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Publication number
JP2004115954A
JP2004115954A JP2002280443A JP2002280443A JP2004115954A JP 2004115954 A JP2004115954 A JP 2004115954A JP 2002280443 A JP2002280443 A JP 2002280443A JP 2002280443 A JP2002280443 A JP 2002280443A JP 2004115954 A JP2004115954 A JP 2004115954A
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JP
Japan
Prior art keywords
yarn
stretchable
thin film
flat foil
film layer
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Pending
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JP2002280443A
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Japanese (ja)
Inventor
Nobutada Yamada
山田 延正
Toshiyuki Matsuda
松田 俊行
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Reiko Co Ltd
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Reiko Co Ltd
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Publication date
Application filed by Reiko Co Ltd filed Critical Reiko Co Ltd
Priority to JP2002280443A priority Critical patent/JP2004115954A/en
Publication of JP2004115954A publication Critical patent/JP2004115954A/en
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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a stretchable fancy yarn which has metallic luster, antimicrobial properties and antistatic characteristic, keeps the antimicrobial properties and antistatic characteristic for a long period of time and provides corrosion resistance and low antigenicity. <P>SOLUTION: The stretchable yarn is obtained by cutting a laminate film, in which a metal thin film layer composed of silver or copper exists on at least one side of a plastic film, into a filamentous state to form a flat foil yarn having metallic luster, winding the flat foil yarn on an elastic yarn being a core yarn in a drawn state in fixed length in one direction and winding a press yarn on the wound yarn in the reverse direction. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、抗菌性を有する伸縮性意匠糸に関し、静電気防止性をも有し、さらには耐腐食性や低抗原性にも優れた伸縮性意匠糸に関する。
【0002】
【従来の技術】
金銀糸やラメ糸等の箔糸は長年の間、伸びると箔に亀裂が生じ、金属光沢がなくなるため、伸縮性あるものを製造できないとされていた。
その後、弾性糸に箔糸を巻きつけた伸縮性ある意匠糸が開発され、該意匠糸に係る発明を本出願人は既に特許出願し特許を取得済みである(特許文献1参照)が、金属光沢を有する該意匠糸に係る製品に、商品価値ある抗菌性や、さらには静電気防止性、耐腐食性、低抗原性をも付与することはできなかった。
ここでいう低抗原性とは、皮膚障害の原因となる抗原性(アレルギーの原因物質であるアレルゲンになり得る性質)が低いことをいう。
【0003】
【特許文献1】
特許第2796708号公報
【0004】
【発明が解決しようとする課題】
本発明は、金属光沢を有するとともに、抗菌性及び静電気防止性を有し、また該抗菌性及び静電気防止性を長期間維持し、さらには耐腐食性や低抗原性をも付与することができる伸縮性意匠糸を提供するものである。
【0005】
【課題を解決するための手段】
本発明の伸縮性意匠糸は、少なくとも、プラスチックフイルムの片面に、銀又は銅からなる金属薄膜層が存在する積層体フイルムを糸状に裁断してなる金属光沢ある平箔糸を、一定長に伸ばした状態の芯糸である弾性糸に、一方向に巻きつけ、その上から押さえ糸を逆方向に巻きつけてなることを特徴とするものである。
【0006】
かかる意匠糸は、平箔糸の構成中に銀又は銅からなる金属薄膜層が存在しているので抗菌性とともに、静電気防止性をも有するものとなる。
また、押さえ糸が平箔糸のずれを防止するので弾性糸と平箔糸が離れることがなく、さらに押さえ糸は伸縮性意匠糸全体の補強ともなるので、本発明の伸縮性意匠糸は安定した伸縮が可能となるのである。
【0007】
本発明で使用する平箔糸は、プラスチックフイルムの片面に金属薄膜層を形成した、いわゆる1プライ構成のものであってもよく、またプラスチックフイルムに金属薄膜層を形成した積層体を2枚、金属薄膜層を内側にして接着剤層で貼り合せたり、プラスチックフイルムに金属薄膜層を形成した積層体の金属薄膜層側にプラスチックフイルムを接着剤層で貼り合せた、いわゆる2プライ構成のものであってもよい。
特に、2プライ構成の平箔糸は、金属薄膜層の表裏両面にプラスチックフイルムが存在するので、該金属薄膜層の腐食が防止され、抗菌性及び静電気防止性が長期間維持されるものである。
【0008】
上記プラスチックフイルムとしては、ポリエチレンテレフタレートフイルム、ポリアミドフイルム、ポリエチレンフイルム、ポリプロピレンフイルム等、従来平箔糸に使用されている各種プラスチックフイルムが使用できる。
【0009】
接着剤層の形成は、ポリエステル樹脂、ポリウレタン樹脂等の従来平箔糸の接着剤層に使用されている各種の樹脂を使用して、グラビアコーティング法、リバースコーティング法等従来公知のコーティング法で形成できる。
【0010】
平箔糸の金属薄膜層は、プラスチックフイルム上に真空蒸着、スパッタリング、イオンプレーティング等の従来公知の薄膜形成法で形成した銀又は銅からなる。
金属薄膜層に銀又は銅を使用することにより、抗菌性とともに静電気防止性をも有するものとなるのである。
【0011】
平箔糸は、プラスチックフイルムと金属薄膜層間に、両者間の密着性向上を目的にアミノ樹脂、ポリエステル樹脂、エポキシ樹脂、アクリル樹脂、ウレタン樹脂等の適宜の樹脂からなるいわゆるアンカーコート層が形成されていてもよい。また、耐腐食性の向上を目的として、金属薄膜層の、プラスチックフイルムあるいはアンカーコート層が形成されている側と反対側の面に、アミノ樹脂、ポリエステル樹脂、エポキシ樹脂、アクリル樹脂、ウレタン樹脂等の適宜の樹脂からなるいわゆるトップコート層が形成されていてもよい。
【0012】
また、2プライ構成の平箔糸のプラスチックフイルムと金属薄膜層間にアミノ樹脂含有量が40〜3重量%であるアンカーコート層を形成すれば、両者間の密着性がより向上するとともに、伸縮性意匠糸が汗やアルカリ等に触れても容易に腐食しない優れた耐腐食性を有するものとなり、その結果、抗菌性及び静電気防止性をさらに長期間安定して維持することができるものとなる。
【0013】
そして、さらに金属薄膜層のアンカーコート層が形成されている側と反対側の面にアミノ樹脂含有量が40〜3重量%であるトップコート層を形成すれば、上記アンカーコート層のみを形成した場合より、さらに伸縮性意匠糸の耐腐食性が向上するのでより好ましい。
【0014】
特に、2プライ構成の平箔糸において、アミノ樹脂含有量が40〜3重量%であるアンカーコート層及びトップコート層を形成し、かつ金属薄膜層を銀薄膜層とした場合には、染色よりも条件の厳しい精錬にも耐え得る非常に優れた耐腐食性、すなわち耐精錬性をも兼ね備えた伸縮性意匠糸となる。
【0015】
ところで、アミノ樹脂塗料中には一般的に抗原性が高いとされるホルムアルデヒドがかなりの量含まれているため、アミノ樹脂塗料をアンカーコート層やトップコート層形成の際に使用した場合には、アンカーコート層中やトップコート層中のアミノ樹脂含有量の増加とともに平箔糸からのホルムアルデヒドの溶出量が増えることとなる。
そこで、2プライ構成の平箔糸における前記のアンカーコート層やトップコート層のアミノ樹脂含有量を20〜3重量%とすることにより、アミノ樹脂含有量が20%を超える場合の耐腐食性を維持するとともに、アンカーコート層やトップコート層からのホルムアルデヒドの溶出量が抑制されるため、有害物質から消費者を保護する目的で定められた「有害物質を含有する家庭用品の規制に関する法律施行規則(昭和49年9月26日厚生省令第34号)」(以下、厚生省令第34号と略す)で示されるホルムアルデヒドの溶出量を完全にクリアし、厚生省令第34号で示される基準の中でも特に厳格に定められている乳幼児用繊維製品の基準(吸光度差0.05以下)をも完全にクリアすることができるので、かかる平箔糸を使用した本発明の伸縮性意匠糸も、当然上記基準をクリアするものとなり、優れた低抗原性を有するとともに耐腐食性をも兼備したものとなる。
従って、本発明の伸縮性意匠糸は、乳幼児用繊維製品や直接肌に触れる下着類にも使用可能となった。
【0016】
尚、平箔糸は、プラスチックフイルムと金属薄膜層間にアンカーコート層とは別に、適宜の染料や顔料等で着色した着色層を形成してもよく、またアンカーコート層を着色してアンカーコート層が着色層を兼ねたものとしてもよい。
また、抗菌性の向上を目的に、アンカーコート層やトップコート層中に抗菌剤を混入して、抗菌性あるアンカーコート層やトップコート層としたり、平箔糸の表裏表面に抗菌剤を混入した樹脂層を形成してもよい。
【0017】
本発明の伸縮性意匠糸は、弾性糸を一定長に伸ばした状態で、水溶性の糸を引き揃えたものを芯糸とし、この芯糸に前記平箔糸を一方向に巻きつけ、その上から押さえ糸を逆方向に巻きつけたものとしてもよい。
【0018】
本発明は、前記したとおり、押さえ糸が、平箔糸のずれを防止するとともに伸縮性意匠糸全体の補強ともなるので、安定した伸縮が可能となるのであるが、弾性糸を一定長に伸ばした状態で、水溶性の糸を引き揃えたものを芯糸とし、この芯糸に前記平箔糸を一方向に巻きつけ、その上から押さえ糸を逆方向に巻きつけることにより、より一層伸縮が安定する。
水溶性の糸を引き揃えると、引き揃えた水溶性の糸の長さ以上には弾性糸が伸びないので、製織時又は製編時には伸びが制限されて作業性よく製織又は製編できる。
しかも、製織後又は製編後の染色や精錬時には、水溶性の糸は溶解して脱落するため、その後は伸縮性及び金属光沢を有する意匠糸として織布や編布に妙味ある外観と、抗菌性を付与できるものとなるのである。
【0019】
本発明の伸縮性意匠糸は、そのまま単糸状で使用してもよいが、二本以上撚糸して使用してもよく、織布、編布、レース、リリヤーン等のいずれの形態にも、品質よく、伸縮性を保持した状態で利用できる。
さらに、上記織布、編布等は、タオル、テーブルクロス、枕カバー、下着、ベビー服、靴下、パンティストッキング、パジャマ、エプロン、シャツ、セーター、衣服の裏地、カーテン、ラグ、マット、カーペット、椅子カバー、カーシート、布団、布巾、シーツ等のさまざまな繊維製品に使用できる。
【0020】
伸縮性意匠糸の芯糸となる弾性糸としては、ゴム弾性のある伸縮性ある糸がいずれも使用でき、特にその材質が限られるものではなく、例えばナイロンウーリー糸、ポリウレタン弾性糸、ポリエステル強撚糸、天然繊維強撚糸等の弾性糸が使用できる。
【0021】
弾性糸の太さは、一般に7〜1000デニール程度であるのがよい。
7デニールより細いと、強度が弱く糸切れが発生し易くなり、また撚糸ができ難くなる。
一方1000デニールより太いと、強度が強くなりすぎて風合いが悪くなる。10〜300デニール程度であるのが特に好ましい。
【0022】
次に、本発明で使用する平箔糸の厚さと幅は特に限定されないが、一般に厚さ3〜60μm程度、幅0.13〜10mm程度であるのが扱い易く、特に厚さ9〜35μm程度、幅0.15〜3.3mm程度であるのが好ましい。
厚さが3μmより薄いと、薄すぎて撚糸時に平箔糸が伸び易く、60μmより厚いと、厚すぎて風合いが悪くなる。
また、幅が0.13mmより狭いと、細すぎて撚糸時に平箔糸が伸び易く、10mmより広いと広すぎて扱い難く、風合いも悪くなる。
【0023】
さらに、弾性糸を伸長した状態で、それに巻きつけた平箔糸の上から、逆方向に巻きつける押さえ糸は、平箔糸のずれを防止し、同時に本発明の伸縮性意匠糸全体を補強して、伸縮を安定させるためのものであるので、実質的に非伸縮性の糸であるのが好ましい。
押さえ糸に使用する繊維の種類としては、天然繊維、半合成繊維、合成繊維のいずれでもよく、短繊維からなるものであっても、長繊維からなるものであってもよい。
【0024】
平箔糸の巻きつけ、及び押さえ糸の巻きつけは、撚糸すなわち撚ることにより行うことができる。
撚糸方法は、弾性糸を1.1〜5.0倍に伸ばした状態で、平箔糸を巻きつけるのがよく、撚糸時の弾性糸の伸び率が1.1倍より小さいと撚糸し難く、また平箔糸のループ形成が十分でなく、逆に5.0倍より大であると、伸び率が大きすぎて、やはり撚糸し難く、平箔糸のループが大きくなりすぎて、引っ掛かり易く、扱い難くなる。
水溶性の糸を弾性糸に引き揃えて使用する場合には、弾性糸は1.5〜5.0倍程度に伸ばした状態で、水溶性の糸を引き揃え、その上から平箔糸を巻きつけるのがよい。
尚、いずれの場合も撚糸時の弾性糸の伸長状態は、伸び率1.5〜3.5倍程度であるのがより好ましい。
【0025】
平箔糸の弾性糸への巻きつけ回数(撚数)は、弾性糸の伸長状態、弾性糸や平箔糸の太さによって異なるが、弾性糸を伸ばした状態で、通常50〜1500T/Mであるのが好ましい。
この回転が、50T/Mより少ない場合や1500T/Mより多い場合は、平箔糸によって形成されるループの数が少なすぎたり、多すぎたりして、ループが平均的に出難く、良好な風合いの製品が得難い。
特に好ましい撚数は100〜600T/Mである。
【0026】
次に、やはり弾性糸を伸長した状態で、平箔糸の上から、平箔糸とは逆方向に巻きつける押さえ糸の巻きつけ回数(撚数)は、100〜2000T/Mであるのが好ましい。
100T/Mより少ないと、伸縮性意匠糸全体の補強が不充分になり、また平箔糸のずれ防止も不充分で、平箔糸が固定せず、長手方向に移動し易く、良好な風合いを得ることもできない。
逆に、2000T/Mより多いと、押さえ糸のループが多すぎて固定せずに長手方向に移動し易く、その結果補強として役立たず、また良好な風合いを得ることも困難となる。特に好ましい撚数は200〜600T/Mである。
尚、平箔糸の上から巻きつける押さえ糸の撚数は、通常平箔糸の撚数と同等以上、例えば平箔糸の撚数の1〜13倍程度とするのが好ましく、特に1〜5倍程度とするのが好ましい。
【0027】
また、弾性糸に巻きつける押さえ糸の太さは、弾性糸の伸長状態における太さの0.5〜15倍程度であるのが好ましい。
【0028】
弾性糸に引き揃えて使用する水溶性の糸は、水溶性のフィラメント糸であるのが好ましく、水溶性ビニロン糸などが使用できる。
その太さは、弾性糸の伸縮性を制限するため、弾性糸の伸長状態における太さと同等以上、1〜8倍程度、特に1〜6倍程度であるのがよい。
【0029】
【発明の実施の形態】
次に、本発明を実施例に従ってさらに詳しく説明する。
・ 平箔糸の製造
A.厚さ12μmの透明なポリエチレンテレフタレートフイルムの片面に、ポリエステル樹脂95重量%とメラミン樹脂5重量%である樹脂に黄色の染料を混入した厚さ0.8μmの着色層を形成し、次にポリエステル樹脂95重量%とメラミン樹脂5重量%からなる厚さ0.8μmのアンカーコート層を形成し、さらにアンカーコート層上に真空蒸着により厚さ60nmの銀薄膜層を形成した後、銀薄膜層上に前記アンカーコート層と同じ樹脂からなる厚さ0.8μmのトップコート層を形成して積層体を得た。
次に上記積層体のトップコート層上に、厚さ12μmの透明なポリエチレンテレフタレートフイルムに前記着色層と同じ樹脂を厚さ0.8μmに形成したものを着色層を内側にして、厚さ1.5μmのポリエステル樹脂接着剤層で貼り合せたものをスリットして、幅0.3mmで厚さ約28μmの表裏両面が金色の平箔糸を得た。
B.厚さ9μmの透明なポリエチレンテレフタレートフイルムの片面に、ポリエステル樹脂90重量%とメラミン樹脂10重量%からなる厚さ0.8μmのアンカーコート層を形成し、さらにアンカーコート層上に真空蒸着により厚さ60nmの銀薄膜層を形成した後、銀薄膜層上にポリエステル樹脂90重量%とメラミン樹脂10重量%である樹脂に酸化チタン粉末を混入した厚さ1.0μmの白色トップコート層を形成して積層体を得た。
次に上記積層体を2枚準備し、該2枚をいずれもトップコート層を内側として厚さ1.5μmのポリエステル樹脂接着剤層で貼り合せたものをスリットして、幅0.1mmで厚さ約23μmの表裏両面が銀色の平箔糸を得た。
C.厚さ9μmの透明なポリエチレンテレフタレートフイルムの片面に、ポリエステル樹脂80重量%とアクリル樹脂20重量%からなる厚さ1.0μmのアンカーコート層を形成し、次にアンカーコート層上に真空蒸着により厚さ60nmの銅薄膜層を形成した積層体を得た。
次に上記積層体を2枚準備し、該2枚をいずれも銅薄膜層を内側として厚さ1.5μmのポリエステル樹脂接着剤層で貼り合せたものをスリットして、幅0.2mmで厚さ約22μmの表裏両面が銅色の平箔糸を得た。
D.アンカーコート層上に、銀薄膜層に代えて、真空蒸着により厚さ60nmのアルミニウム薄膜層を形成した以外は、Bの平箔糸と同様の方法で、表裏両面が銀色の平箔糸を得た。
【0030】
【実施例1】
70デニールの弾性糸(東レ・デュポン社のポリウレタン糸:ライクラ)を2.5倍に伸長した状態(伸長状態における糸の太さは約28デニール)で、前記Aで得た平箔糸を200T/Mの撚数で右撚りし、その上から、50デニールのナイロン糸を400T/M撚数で左撚りした。
弾性糸の伸長状態を解除して、金色の平箔糸のループが全体に均一に形成された伸縮性に富む本発明の伸縮性意匠糸を得た。
【0031】
【実施例2】
平箔糸として、前記Bで得た平箔糸を使用した以外は、実施例1と同様の方法で、銀色の平箔糸のループが全体に均一に形成された本発明の伸縮性意匠糸を得た。
【0032】
【実施例3】
平箔糸として、前記Cで得た平箔糸を使用した以外は、実施例1と同様の方法で、銅色の平箔糸のループが全体に均一に形成された本発明の伸縮性意匠糸を得た。
【0033】
【比較例1】
平箔糸として、前記Dで得た平箔糸を使用した以外は、実施例1と同様の方法で、銀色の平箔糸のループが全体に均一に形成された伸縮性意匠糸を得た。
【0034】
【実施例4】
実施例1〜3で得た伸縮性意匠糸を、それぞれ2本針のリリヤーンAと4本針のリリヤーンBに製造した。
実施例1で得た伸縮性意匠糸を使用したリリヤーンA及びリリヤーンBは金色の、実施例2で得た伸縮性意匠糸を使用したリリヤーンA及びリリヤーンBは銀色の、実施例3で得た伸縮性意匠糸を使用したリリヤーンA及びリリヤーンBは銅色の金属光沢をそれぞれ呈するとともに、上記全てのリリヤーンA及びリリヤーンBは、伸縮性を有するものであった。
【0035】
【実施例5】
20デニールの弾性糸(旭化成社製のポリウレタン糸:ロイカ)を3.0倍に伸長した状態(伸長状態における糸の太さは約7デニール)で、これに30デニールの水溶性ビニロン糸(ニチビ社製:ソルブロン)を引き揃え、これを芯糸とし、その上に前記Bで得た平箔糸を約600T/Mの撚数で巻きつけ、その後、15デニールのナイロン糸を逆向きに600T/Mの撚数で巻きつけて、本発明の伸縮性意匠糸を得た。
【0036】
【実施例6】
実施例5で得た伸縮性意匠糸を、製織したところ、引き揃えた水溶性ビニロン糸により弾性糸の伸びが制限されているため、普通の糸と同様に作業性よく製織できた。
製織後、精錬及び高圧染色したところ、水溶性ビニロン糸は染浴に溶解除去されて弾性糸の伸縮性が復元され、美しく染色された伸縮性ある織布を得ることができた。
尚、該織布は、精錬によっても銀薄膜層の腐食が全く生じず、耐腐食性に非常に優れ、耐精錬性を有するものであった。
【0037】
【実施例7】
実施例5で得た伸縮性意匠糸を、よこ編み機で製編したところ、引き揃えた水溶性ビニロン糸により弾性糸の伸びが制限されているため、問題なく、品質のよいニット地を得ることができた。
このニット地を高圧染色したところ、水溶性ビニロン糸は染浴に溶解除去されて弾性糸の伸縮性が復元され、美しく染色された落ち着いた金属光沢ある伸縮性ニット地を得ることができた。この得られた伸縮性ニット地は、強力ないわゆるキックバック性を有していた。
【0038】
【実施例8】
実施例7で得たニット地を使用してカーシートを製造したところ、自動車の乗り降り時に静電気の発生がほとんどなく、静電気防止性に優れたものであった。
【0039】
1.抗菌性試験
(評価試料)実施例1〜3、5で得た本発明の伸縮性意匠糸、及び比較例1で得た伸縮性意匠糸をそれぞれ0.4グラム準備して試料とした。
(評価方法)SEK菌数測定法:試料をオートクレープで滅菌後、約10CFU/mlになる様に1/20ニュートリエント培地で調整した白せん菌液0.2mlをそれぞれの試料に接種し、37℃、18時間保存後、生残菌数を測定した。
(評価結果)平箔糸の金属薄膜層が銀又は銅薄膜層で形成されている実施例1〜3、5で得た本発明の伸縮性意匠糸は、生残菌数が培養前の菌数の1/10以下に減少しており、優れた抗菌性を有していた。
一方、平箔糸の金属薄膜層がアルミニウム薄膜層で形成されている比較例1で得た伸縮性意匠糸については、生残菌数が培養前の菌数と全く変化なく、抗菌性を全く有していなかった。
【0040】
2.ホルムアルデヒド試験
(評価試料)実施例1、2、5で得た本発明の伸縮性意匠糸をそれぞれ2.5グラム準備して試料とした。
(評価方法)厚生省令第34号に定められる乳幼児用繊維製品についての試験方法。
(評価結果)いずれの伸縮性意匠糸も吸光度差0.01であり、乳幼児用繊維製品の基準(吸光度差0.05以下)を満たすものであった。
【0041】
【発明の効果】
本発明では、少なくとも、プラスチックフイルムの片面に、銀又は銅からなる金属薄膜層が存在する積層体フイルムを糸状に裁断してなる金属光沢ある平箔糸を、一定長に伸ばした状態の芯糸である弾性糸に、一方向に巻きつけ、その上から押さえ糸を逆方向に巻きつけることにより、抗菌性が良好で、しかも金属光沢、伸縮性、及び静電気防止性を兼ね備えた意匠性ある糸を得ることができる。
また、弾性糸に水溶性の糸を引き揃えたものを芯糸としたものでは、通常の織機や編機でより安定して織物や編物を得ることができ、その後染色時等に水溶性の糸を溶解除去し、抗菌性に優れた意匠性ある弾性布帛を得ることが可能となる。
【0042】
伸縮性意匠糸に使用する平箔糸を2プライ構成とした場合には、該平箔糸の金属薄膜層の表裏両面にはプラスチックフイルムが存在するので、該金属薄膜層の腐食が防止され、抗菌性及び静電気防止性が長期間維持される意匠糸となるものである。
【0043】
さらに、2プライ構成の平箔糸のプラスチックフイルムと金属薄膜層間にアミノ樹脂含有量が40〜3重量%であるアンカーコート層を形成すれば、両者間の密着性がより向上するとともに、伸縮性意匠糸が汗やアルカリ等に触れても容易に腐食しない優れた耐腐食性を有するものとなり、その結果、抗菌性及び静電気防止性をさらに長期間安定して維持することができるものとなる。
【0044】
そして、さらに金属薄膜層のアンカーコート層が形成されている側と反対側の面にアミノ樹脂含有量が40〜3重量%であるトップコート層を形成すれば、上記アンカーコート層のみを形成した場合より、さらに伸縮性意匠糸の耐腐食性が向上するのでより好ましい。
特に、このとき金属薄膜層を銀薄膜層とした場合には、耐精錬性をも兼ね備えたものとなる。
【0045】
また、前記2プライ構成の平箔糸のアンカーコート層やトップコート層のアミノ樹脂含有量を20〜3重量%とした場合には、アミノ樹脂含有量が20%を超える場合の耐腐食性を維持するとともに、アンカーコート層やトップコート層からのホルムアルデヒドの溶出量が抑制されるため、厚生省令第34号で示される基準の中でも特に厳格に定められている乳幼児用繊維製品の基準(吸光度差0.05以下)をも完全にクリアすることができるので、かかる平箔糸を使用した本発明の伸縮性意匠糸も、当然上記基準をクリアするものとなり、優れた低抗原性を有するとともに耐腐食性をも兼備したものとなる。
従って、本発明の伸縮性意匠糸は、乳幼児用繊維製品や直接肌に触れる下着類にも使用可能となった。
【0046】
本発明の伸縮性意匠糸は、弾性糸を一定長に伸ばした状態で、水溶性の糸を引き揃えたものを芯糸とし、この芯糸に前記平箔糸を一方向に巻きつけ、その上から押さえ糸を逆方向に巻きつけたものとしてもよい。
水溶性の糸を引き揃えると、引き揃えた水溶性の糸の長さ以上には弾性糸が伸びないので、製織時又は製編時には伸びが制限されて作業性よく製織又は製編できる。
しかも、製織後又は製編後の染色や精錬時には、水溶性の糸は溶解して脱落するため、その後は伸縮性及び金属光沢を有する意匠糸として織布や編布に妙味ある外観と、抗菌性を付与できるものとなるのである。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a stretchable design yarn having antibacterial properties, and also relates to a stretchable design yarn having antistatic properties, and further having excellent corrosion resistance and low antigenicity.
[0002]
[Prior art]
For many years, foil yarns such as gold and silver yarns and lame yarns have been considered to be unable to produce stretchable yarns because cracks occur in the foil when stretched, resulting in loss of metallic luster.
After that, a stretchable design yarn in which a foil yarn is wound around an elastic yarn was developed, and the present applicant has already applied for a patent and obtained a patent for the invention relating to the design yarn (see Patent Document 1). It was impossible to impart commercial value antibacterial properties, antistatic properties, corrosion resistance, and low antigenicity to the glossy product of the design yarn.
The term “low antigenicity” as used herein means that the antigenicity that causes skin damage (the property that can be an allergen that is a substance causing allergy) is low.
[0003]
[Patent Document 1]
Japanese Patent No. 2796708
[Problems to be solved by the invention]
The present invention has a metallic luster, has antibacterial properties and antistatic properties, maintains the antibacterial properties and antistatic properties for a long time, and can also impart corrosion resistance and low antigenicity. An object of the present invention is to provide a stretchable design yarn.
[0005]
[Means for Solving the Problems]
Stretchable decorative yarn of the present invention, at least one side of the plastic film, a metal glossy flat foil yarn obtained by cutting a laminate film having a metal thin film layer made of silver or copper into a thread, stretched to a certain length. It is characterized in that it is wound in one direction around an elastic yarn which is a core yarn in a folded state, and a pressing yarn is wound therefrom in an opposite direction.
[0006]
Such a design yarn has not only antibacterial properties but also antistatic properties since a metal thin film layer made of silver or copper is present in the structure of the flat foil thread.
In addition, the holding yarn prevents the flat foil yarn from shifting, so that the elastic yarn and the flat foil yarn do not separate, and since the holding yarn also reinforces the entire stretchable design yarn, the stretchable design yarn of the present invention is stable. It becomes possible to expand and contract.
[0007]
The flat foil yarn used in the present invention may have a so-called one-ply configuration in which a metal thin film layer is formed on one side of a plastic film, or two laminates each having a metal thin film layer formed on a plastic film. This is a so-called two-ply configuration in which the metal thin film layer is bonded inside with an adhesive layer, or a plastic film is bonded to the metal thin film layer side of the laminate in which the metal thin film layer is formed on a plastic film with an adhesive layer. There may be.
In particular, in the two-ply flat foil yarn, since the plastic film exists on both the front and back surfaces of the metal thin film layer, corrosion of the metal thin film layer is prevented, and antibacterial properties and antistatic properties are maintained for a long time. .
[0008]
As the plastic film, various plastic films conventionally used for flat foil yarns, such as a polyethylene terephthalate film, a polyamide film, a polyethylene film and a polypropylene film, can be used.
[0009]
The adhesive layer is formed by a conventionally known coating method, such as a gravure coating method or a reverse coating method, using various resins conventionally used for an adhesive layer of a flat foil yarn such as a polyester resin and a polyurethane resin. it can.
[0010]
The metal thin film layer of the flat foil yarn is made of silver or copper formed on a plastic film by a conventionally known thin film forming method such as vacuum deposition, sputtering, or ion plating.
By using silver or copper for the metal thin film layer, it has antistatic properties as well as antibacterial properties.
[0011]
The flat foil yarn has a so-called anchor coat layer formed of an appropriate resin such as an amino resin, a polyester resin, an epoxy resin, an acrylic resin, or a urethane resin for the purpose of improving the adhesion between the plastic film and the metal thin film. May be. Also, for the purpose of improving corrosion resistance, an amino resin, a polyester resin, an epoxy resin, an acrylic resin, a urethane resin, or the like is provided on the surface of the metal thin film layer opposite to the side on which the plastic film or the anchor coat layer is formed. A so-called top coat layer made of an appropriate resin may be formed.
[0012]
In addition, if an anchor coat layer having an amino resin content of 40 to 3% by weight is formed between the plastic film of the two-ply flat foil yarn and the metal thin film layer, the adhesion between the two is further improved and the elasticity is improved. The design yarn has excellent corrosion resistance that does not corrode easily even if it comes into contact with sweat, alkali, or the like. As a result, antibacterial properties and antistatic properties can be maintained more stably for a long period of time.
[0013]
Further, if a top coat layer having an amino resin content of 40 to 3% by weight is formed on the surface of the metal thin film layer opposite to the side on which the anchor coat layer is formed, only the anchor coat layer is formed. It is more preferable than the case because the corrosion resistance of the stretchable design yarn is further improved.
[0014]
In particular, in a two-ply flat foil yarn, when an anchor coat layer and a top coat layer each having an amino resin content of 40 to 3% by weight are formed and the metal thin film layer is a silver thin film layer, In addition, it becomes a stretchable design yarn having very excellent corrosion resistance, that is, it can withstand severe refining, that is, also has refining resistance.
[0015]
By the way, since the amino resin paint contains a considerable amount of formaldehyde which is generally considered to have high antigenicity, when the amino resin paint is used for forming an anchor coat layer or a top coat layer, As the amino resin content in the anchor coat layer and the top coat layer increases, the amount of formaldehyde eluted from the flat foil yarn increases.
Therefore, by setting the amino resin content of the anchor coat layer and the top coat layer in the two-ply flat foil yarn to 20 to 3% by weight, the corrosion resistance when the amino resin content exceeds 20% is improved. Since the amount of formaldehyde eluted from the anchor coat layer and the top coat layer is suppressed while maintaining the level, the `` Regulations for Enforcement of the Regulations on the Regulation of Household Products Containing Hazardous Substances '' were established to protect consumers from harmful substances. (September 26, 1974, Ministry of Health and Welfare Ordinance No. 34) "(hereinafter abbreviated as Ministry of Health and Welfare Ordinance No. 34). In particular, it is possible to completely clear the strictly defined standards for textile products for infants (absorbance difference of 0.05 or less). Stretchable design yarn Ming also naturally be to clear the above criteria, it becomes having both also corrosion resistance while having excellent low antigenicity.
Therefore, the stretchable decorative yarn of the present invention can be used for textile products for infants and underwear that directly touches the skin.
[0016]
In addition, the flat foil yarn may form a colored layer colored with an appropriate dye or pigment, etc. separately from the anchor coat layer between the plastic film and the metal thin film layer, or the anchor coat layer by coloring the anchor coat layer. May also serve as a colored layer.
In addition, for the purpose of improving antibacterial properties, an antibacterial agent is mixed into the anchor coat layer and the topcoat layer to form an anchorcoat layer and a topcoat layer with antibacterial properties, and the antibacterial agent is mixed into the front and back surfaces of the flat foil yarn. A formed resin layer may be formed.
[0017]
The stretchable design yarn of the present invention, in a state where the elastic yarn is stretched to a certain length, a core yarn obtained by aligning water-soluble yarns, and the flat foil yarn is wound around the core yarn in one direction. The holding thread may be wound in the opposite direction from above.
[0018]
According to the present invention, as described above, since the presser yarn prevents the displacement of the flat foil yarn and also reinforces the entire stretchable design yarn, stable expansion and contraction becomes possible, but the elastic yarn is stretched to a certain length. In a state where the water-soluble yarn is aligned, the core yarn is used as the core yarn, and the flat foil yarn is wound around this core yarn in one direction, and the holding yarn is wound in the opposite direction from above, thereby further expanding and contracting. Becomes stable.
When the water-soluble yarns are aligned, the elastic yarns do not extend beyond the length of the aligned water-soluble yarns. Therefore, the elongation is limited during weaving or knitting, and weaving or knitting can be performed with good workability.
In addition, during dyeing or refining after weaving or knitting, the water-soluble yarn dissolves and drops off. The property can be imparted.
[0019]
The stretchable design yarn of the present invention may be used in the form of a single yarn as it is, or may be used by twisting two or more yarns, and in any form such as a woven fabric, a knitted fabric, a lace, a lily yarn, and the like. Can be used with good elasticity.
Furthermore, the above-mentioned woven cloth, knitted cloth, etc. are towels, tablecloths, pillow covers, underwear, baby clothes, socks, pantyhose, pajamas, aprons, shirts, sweaters, lining of clothes, curtains, rugs, mats, carpets, chair covers. It can be used for various textile products such as car seats, futons, cloths and sheets.
[0020]
As the elastic yarn serving as the core yarn of the stretchable design yarn, any elastic yarn having rubber elasticity can be used, and the material is not particularly limited. For example, nylon wooly yarn, polyurethane elastic yarn, polyester strong twist yarn An elastic yarn such as a natural fiber strong twist yarn can be used.
[0021]
Generally, the thickness of the elastic yarn is preferably about 7 to 1000 denier.
If the thickness is less than 7 denier, the strength is weak, and the yarn breaks easily, and the twisting becomes difficult.
On the other hand, if the thickness is greater than 1000 denier, the strength becomes too strong and the texture becomes poor. It is particularly preferred that it is about 10 to 300 denier.
[0022]
Next, the thickness and width of the flat foil yarn used in the present invention are not particularly limited, but are generally about 3 to 60 μm in thickness and about 0.13 to 10 mm in width for easy handling, and particularly about 9 to 35 μm in thickness. And a width of about 0.15 to 3.3 mm.
If the thickness is less than 3 μm, the flat foil yarn is too thin to easily stretch at the time of twisting. If the thickness is more than 60 μm, the texture becomes too thick and the texture becomes poor.
On the other hand, if the width is less than 0.13 mm, the flat foil yarn is too thin to easily stretch at the time of twisting. If the width is more than 10 mm, it is too wide and difficult to handle, and the texture is poor.
[0023]
Furthermore, the holding yarn wound in the opposite direction from the top of the flat yarn wound around the elastic yarn while it is stretched prevents the flat yarn from shifting and at the same time reinforces the entire stretchable design yarn of the present invention. In order to stabilize expansion and contraction, the yarn is preferably substantially non-stretchable.
The type of fiber used for the holding yarn may be any of natural fiber, semi-synthetic fiber and synthetic fiber, and may be made of short fiber or long fiber.
[0024]
The winding of the flat foil yarn and the winding of the presser yarn can be performed by twisting, that is, twisting.
In the twisting method, it is preferable to wind a flat foil yarn in a state where the elastic yarn is stretched 1.1 to 5.0 times, and it is difficult to twist when the elongation rate of the elastic yarn during twisting is smaller than 1.1 times. On the other hand, if the loop formation of the flat foil yarn is not sufficient, and if it is more than 5.0 times, the elongation is too large, it is also difficult to twist, and the loop of the flat foil yarn becomes too large and it is easy to catch. , Becomes difficult to handle.
In the case where the water-soluble yarn is used by being aligned with the elastic yarn, the elastic yarn is stretched about 1.5 to 5.0 times, the water-soluble yarn is aligned, and the flat foil yarn is laid on top of the water-soluble yarn. Good to wrap.
In any case, the stretched state of the elastic yarn at the time of twisting is more preferably about 1.5 to 3.5 times the elongation.
[0025]
The number of windings (twisting number) of the flat foil yarn around the elastic yarn varies depending on the stretched state of the elastic yarn and the thickness of the elastic yarn or the flat foil yarn, but is usually 50 to 1500 T / M in a state where the elastic yarn is stretched. It is preferred that
When this rotation is less than 50 T / M or more than 1500 T / M, the number of loops formed by the flat foil yarn is too small or too large, and it is difficult for the loops to appear on average. It is difficult to obtain a textured product.
A particularly preferred number of twists is 100 to 600 T / M.
[0026]
Next, the number of windings (twisting number) of the presser yarn wound in the opposite direction to the flat foil yarn from above the flat foil yarn in a state where the elastic yarn is stretched should be 100 to 2000 T / M. preferable.
If it is less than 100 T / M, the whole of the stretchable design yarn is insufficiently reinforced, and the flat foil yarn is not sufficiently prevented from being displaced. The flat foil yarn is not fixed, easily moves in the longitudinal direction, and has a good texture. I can't get it.
Conversely, if it is more than 2000 T / M, the number of loops of the presser thread is too large, so that it is easy to move in the longitudinal direction without fixing, and as a result, it does not serve as reinforcement and it is difficult to obtain a good texture. A particularly preferred number of twists is 200 to 600 T / M.
In addition, the number of twists of the presser yarn wound from above the flat foil yarn is usually equal to or more than the number of twists of the flat foil yarn, for example, it is preferably about 1 to 13 times the number of twists of the flat foil yarn, and particularly preferably 1 to 1. It is preferably about five times.
[0027]
The thickness of the presser yarn wound around the elastic yarn is preferably about 0.5 to 15 times the thickness of the elastic yarn in the stretched state.
[0028]
The water-soluble yarn used in line with the elastic yarn is preferably a water-soluble filament yarn, and a water-soluble vinylon yarn or the like can be used.
In order to limit the elasticity of the elastic yarn, the thickness is preferably equal to or more than the thickness of the elastic yarn in the stretched state, about 1 to 8 times, particularly about 1 to 6 times.
[0029]
BEST MODE FOR CARRYING OUT THE INVENTION
Next, the present invention will be described in more detail with reference to examples.
Production of flat foil yarn On one side of a transparent polyethylene terephthalate film having a thickness of 12 μm, a colored layer having a thickness of 0.8 μm is formed by mixing a yellow dye in a resin of 95% by weight of a polyester resin and 5% by weight of a melamine resin, and then forming a polyester resin. An anchor coat layer having a thickness of 0.8 μm comprising 95% by weight and 5% by weight of a melamine resin is formed, and a 60 nm-thick silver thin film layer is further formed on the anchor coat layer by vacuum evaporation. A 0.8 μm thick top coat layer made of the same resin as the anchor coat layer was formed to obtain a laminate.
Next, a transparent polyethylene terephthalate film having a thickness of 0.8 μm formed on a transparent polyethylene terephthalate film having a thickness of 12 μm was formed on the top coat layer of the above-mentioned laminate, with the coloring layer being on the inside. The laminate bonded with a 5 μm polyester resin adhesive layer was slit to obtain a flat foil yarn having a width of 0.3 mm and a thickness of about 28 μm, both front and back surfaces of which were golden.
B. On one surface of a transparent polyethylene terephthalate film having a thickness of 9 μm, an anchor coat layer having a thickness of 0.8 μm comprising 90% by weight of a polyester resin and 10% by weight of a melamine resin is formed. After forming a 60 nm silver thin film layer, a 1.0 μm thick white top coat layer in which titanium oxide powder is mixed into a resin of 90% by weight of a polyester resin and 10% by weight of a melamine resin is formed on the silver thin film layer. A laminate was obtained.
Next, two sheets of the above-mentioned laminated body were prepared, and the two sheets were bonded together with a 1.5 μm-thick polyester resin adhesive layer with the top coat layer on the inside. A flat foil having a silver color of about 23 μm on both sides was obtained.
C. A 1.0 μm thick anchor coat layer composed of 80% by weight of a polyester resin and 20% by weight of an acrylic resin is formed on one side of a transparent polyethylene terephthalate film having a thickness of 9 μm. A laminate having a 60 nm thick copper thin film layer was obtained.
Next, two sheets of the above laminated body were prepared, and the two sheets were bonded together with a 1.5 μm-thick polyester resin adhesive layer with the copper thin film layer on the inner side, and slit. A flat foil yarn having a copper color on both the front and back sides having a thickness of about 22 μm was obtained.
D. On the anchor coat layer, a silver flat foil yarn having both front and back surfaces was obtained in the same manner as the flat foil yarn of B except that a 60 nm thick aluminum thin film layer was formed by vacuum evaporation instead of the silver thin film layer. Was.
[0030]
Embodiment 1
In a state where a 70-denier elastic yarn (polyurethane yarn from Toray DuPont: Lycra) is stretched 2.5 times (the thickness of the yarn in the stretched state is about 28 denier), the flat foil yarn obtained in the above A is subjected to 200T. / M twisted to the right, and a 50-denier nylon yarn was twisted leftward at a twist of 400 T / M.
The stretched state of the elastic yarn was released to obtain a stretchable design yarn of the present invention in which a loop of a gold flat foil yarn was formed uniformly over the entire surface and was highly stretchable.
[0031]
Embodiment 2
Except for using the flat foil obtained in B above as the flat foil, in the same manner as in Example 1, the stretchable design yarn of the present invention in which the loops of the silver flat foil were uniformly formed throughout. Got.
[0032]
Embodiment 3
The stretchable design of the present invention in which the loops of the copper-colored flat foil yarn were uniformly formed in the same manner as in Example 1 except that the flat foil yarn obtained in the above C was used as the flat foil yarn. Yarn was obtained.
[0033]
[Comparative Example 1]
Except for using the flat foil obtained in the above D as the flat foil, a stretchable design yarn in which the loop of the silver flat foil was uniformly formed on the whole was obtained in the same manner as in Example 1. .
[0034]
Embodiment 4
The stretchable design yarns obtained in Examples 1 to 3 were produced into a two-needle liliyaan A and a four-needle liliyaan B, respectively.
The lily yarn A and the lily yarn B using the stretchable design yarn obtained in Example 1 are golden, the lily yarn A and the lily yarn B using the stretchable design yarn obtained in Example 2 are silver, and they are obtained in Example 3. The lily yarn A and the lily yarn B using the stretchable design yarn each exhibited a copper-colored metallic luster, and all the above-mentioned lily yarns A and B had elasticity.
[0035]
Embodiment 5
A 20 denier elastic yarn (polyurethane yarn made by Asahi Kasei Corporation: Leica) is stretched 3.0 times (the thickness of the yarn in the stretched state is about 7 deniers), and a 30 denier water-soluble vinylon yarn (Nichibi) is added. Co., Ltd .: Solblon), which is used as a core yarn, and the flat foil yarn obtained in the above B is wound thereon with a twist number of about 600 T / M, and then a 15-denier nylon yarn is turned upside down to 600 T / M. / M twists to obtain a stretchable design yarn of the present invention.
[0036]
Embodiment 6
When the stretchable decorative yarn obtained in Example 5 was woven, the stretch of the elastic yarn was restricted by the aligned water-soluble vinylon yarn, so that the fabric could be woven with good workability in the same manner as ordinary yarn.
After weaving, refining and high-pressure dyeing revealed that the water-soluble vinylon yarn was dissolved and removed in the dye bath, and the elasticity of the elastic yarn was restored. Thus, a beautifully dyed elastic woven fabric was obtained.
The woven fabric did not cause any corrosion of the silver thin film layer even by refining, was extremely excellent in corrosion resistance, and had refining resistance.
[0037]
Embodiment 7
When the stretchable decorative yarn obtained in Example 5 was knitted by a weft knitting machine, the elongation of the elastic yarn was restricted by the aligned water-soluble vinylon yarns, so that a good-quality knit fabric was obtained without any problem. Was completed.
When the knitted fabric was subjected to high-pressure dyeing, the water-soluble vinylon yarn was dissolved and removed in a dye bath, and the elasticity of the elastic yarn was restored. The obtained elastic knitted fabric had a strong so-called kickback property.
[0038]
Embodiment 8
When a car seat was manufactured using the knitted fabric obtained in Example 7, almost no static electricity was generated at the time of getting on and off the car, and the car seat was excellent in antistatic property.
[0039]
1. Antimicrobial test (evaluation sample) 0.4 g of the stretchable design yarn of the present invention obtained in Examples 1 to 3 and the stretchable design yarn obtained in Comparative Example 1 were prepared as samples.
(Evaluation method) SEK microbial counting method: After sterilizing the sample with autoclave, inoculate each sample with 0.2 ml of a leukomycobacterial solution adjusted to about 10 5 CFU / ml with a 1/20 nutrient medium. After storage at 37 ° C. for 18 hours, the number of surviving bacteria was measured.
(Evaluation Results) The stretchable design yarn of the present invention obtained in Examples 1 to 3 and 5 in which the metal thin film layer of the flat foil yarn is formed of the silver or copper thin film layer, has a viable cell count before culturing. It was reduced to 1/10 or less of the number and had excellent antibacterial properties.
On the other hand, with respect to the stretchable design yarn obtained in Comparative Example 1 in which the metal thin film layer of the flat foil yarn was formed of the aluminum thin film layer, the number of surviving bacteria did not change at all from the number of bacteria before culturing, and the antibacterial property was not changed. Did not have.
[0040]
2. Formaldehyde test (evaluation sample) 2.5 g of the stretchable design yarn of the present invention obtained in Examples 1, 2, and 5 was prepared and used as a sample.
(Evaluation method) Test method for textile products for infants specified in Ministry of Health and Welfare Ordinance No. 34.
(Evaluation Results) All of the stretchable design yarns had a difference in absorbance of 0.01, satisfying the standard for textile products for infants (absorbance difference of 0.05 or less).
[0041]
【The invention's effect】
In the present invention, at least one side of a plastic film, a metallic glossy flat foil yarn obtained by cutting a laminate film having a metal thin film layer made of silver or copper into a thread shape is stretched to a certain length. The elastic yarn is wound in one direction, and the presser yarn is wound in the opposite direction from above, so that it has good antibacterial properties, and also has a metallic luster, elasticity, and antistatic properties. Can be obtained.
In addition, in the case where the core yarn is made of a combination of elastic yarns and water-soluble yarns, a woven or knitted fabric can be obtained more stably with a normal loom or knitting machine. By dissolving and removing the yarn, it is possible to obtain a designable elastic fabric having excellent antibacterial properties.
[0042]
When the flat foil yarn used for the stretchable design yarn has a two-ply configuration, since the plastic film exists on both front and back surfaces of the metal thin film layer of the flat foil yarn, corrosion of the metal thin film layer is prevented, The anti-bacterial property and the anti-static property can be maintained for a long time.
[0043]
Furthermore, if an anchor coat layer having an amino resin content of 40 to 3% by weight is formed between the plastic film of the two-ply flat foil yarn and the metal thin film layer, the adhesion between the two is further improved and the elasticity is improved. The design yarn has excellent corrosion resistance that does not corrode easily even if it comes into contact with sweat, alkali, or the like. As a result, antibacterial properties and antistatic properties can be maintained more stably for a long period of time.
[0044]
Further, if a top coat layer having an amino resin content of 40 to 3% by weight is formed on the surface of the metal thin film layer opposite to the side on which the anchor coat layer is formed, only the anchor coat layer is formed. It is more preferable than the case because the corrosion resistance of the stretchable design yarn is further improved.
In particular, when the metal thin film layer is a silver thin film layer at this time, it also has refining resistance.
[0045]
When the amino resin content of the anchor coat layer or the top coat layer of the two-ply flat foil yarn is 20 to 3% by weight, the corrosion resistance when the amino resin content exceeds 20% is reduced. In addition, the amount of formaldehyde eluted from the anchor coat layer and the top coat layer is suppressed, so that the standards for the textile products for infants (absorbance difference (0.05 or less), the stretchable design yarn of the present invention using such a flat foil yarn naturally satisfies the above criterion, and has excellent low antigenicity and resistance to resistance. It also has corrosiveness.
Therefore, the stretchable decorative yarn of the present invention can be used for textile products for infants and underwear that directly touches the skin.
[0046]
The stretchable design yarn of the present invention, in a state where the elastic yarn is stretched to a certain length, a core yarn obtained by aligning water-soluble yarns, and the flat foil yarn is wound around the core yarn in one direction. The holding thread may be wound in the opposite direction from above.
When the water-soluble yarns are aligned, the elastic yarns do not extend beyond the length of the aligned water-soluble yarns. Therefore, the elongation is limited during weaving or knitting, and weaving or knitting can be performed with good workability.
In addition, during dyeing or refining after weaving or knitting, the water-soluble yarn dissolves and drops off. The property can be imparted.

Claims (7)

一定長に伸ばした状態の芯糸である弾性糸に、少なくとも、プラスチックフイルムの片面に、銀又は銅からなる金属薄膜層が存在する積層体フイルムを糸状に裁断してなる金属光沢ある平箔糸を、一方向に巻きつけ、その上から押さえ糸を逆方向に巻きつけてなることを特徴とする抗菌性を有する伸縮性意匠糸。A metallic glossy flat foil yarn obtained by cutting a laminate film having a metal thin film layer made of silver or copper on at least one surface of a plastic film into an elastic yarn which is a core yarn stretched to a certain length. Is stretched in one direction, and a presser yarn is wound in the opposite direction from above, the stretchable design yarn having antibacterial properties. 平箔糸が、表裏両面にプラスチックフイルムが存在し、これらのフイルム間に銀又は銅からなる金属薄膜層が存在するものである請求項1記載の伸縮性意匠糸。The stretchable decorative yarn according to claim 1, wherein the flat foil yarn has a plastic film on both front and back surfaces, and a metal thin film layer made of silver or copper exists between these films. プラスチックフイルムと金属薄膜層間にアミノ樹脂含有量が40〜3重量%であるアンカーコート層が形成されている請求項2記載の伸縮性意匠糸。The stretchable decorative yarn according to claim 2, wherein an anchor coat layer having an amino resin content of 40 to 3% by weight is formed between the plastic film and the metal thin film layer. 金属薄膜層のアンカーコート層が形成されている側と反対側の面にアミノ樹脂含有量が40〜3重量%であるトップコート層が形成されている請求項3記載の伸縮性意匠糸。The stretchable decorative yarn according to claim 3, wherein a top coat layer having an amino resin content of 40 to 3% by weight is formed on the surface of the metal thin film layer opposite to the side on which the anchor coat layer is formed. 金属薄膜層が、銀薄膜層である請求項4記載の伸縮性意匠糸。The stretchable decorative yarn according to claim 4, wherein the metal thin film layer is a silver thin film layer. アミノ樹脂含有量が20〜3重量%である請求項3〜5のいずれか1項記載の伸縮性意匠糸。The stretchable decorative yarn according to any one of claims 3 to 5, wherein the amino resin content is 20 to 3% by weight. 弾性糸を一定長に伸ばした状態で、水溶性の糸を引き揃えたものを芯糸とした請求項1〜6のいずれか1項記載の伸縮性意匠糸。The stretchable design yarn according to any one of claims 1 to 6, wherein a core yarn is obtained by stretching water-soluble yarns in a state where the elastic yarns are stretched to a predetermined length.
JP2002280443A 2002-09-26 2002-09-26 Stretchable fancy yarn having antimicrobial property Pending JP2004115954A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006124900A (en) * 2004-05-28 2006-05-18 Matsuyama Keori Kk Electrically conductive fabric and metallic fabric

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006124900A (en) * 2004-05-28 2006-05-18 Matsuyama Keori Kk Electrically conductive fabric and metallic fabric

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