JP2004111199A - Lead-acid storage battery - Google Patents

Lead-acid storage battery Download PDF

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Publication number
JP2004111199A
JP2004111199A JP2002271624A JP2002271624A JP2004111199A JP 2004111199 A JP2004111199 A JP 2004111199A JP 2002271624 A JP2002271624 A JP 2002271624A JP 2002271624 A JP2002271624 A JP 2002271624A JP 2004111199 A JP2004111199 A JP 2004111199A
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JP
Japan
Prior art keywords
explosion
storage battery
exhaust
proof filter
lead
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2002271624A
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Japanese (ja)
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JP4552375B2 (en
Inventor
Yasutaka Doyama
堂山  泰隆
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Japan Storage Battery Co Ltd
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Japan Storage Battery Co Ltd
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Publication date
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Priority to JP2002271624A priority Critical patent/JP4552375B2/en
Publication of JP2004111199A publication Critical patent/JP2004111199A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Gas Exhaust Devices For Batteries (AREA)
  • Secondary Cells (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a safe lead-acid storage battery of a structure eliminating an unnecessary space in respect of energy density, with a more excellent anti-explosion function, preventing a secondary explosion from an explosion occurring outside the battery. <P>SOLUTION: An exhaust part set in recess on a top lid face of the lead-acid storage battery consists of an explosion-proof filter arranged at the bottom of the exhaust part, a canopy arranged at the top part of the explosion-proof filter, and an exhaust outlet formed between the explosion-proof filter and the canopy, and a topmost end of the exhaust outlet is so structured not to protrude from the top lid face of the lead-acid storage battery. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は鉛蓄電池に関するものである。
【0002】
【従来の技術】
鉛蓄電池は充電中に副反応として水の電気分解が起こり、次式に示すように酸素ガスと水素ガスが発生する。
O=1/2O+H
上記ガスは火気があると爆発する危険性を有している。したがって、蓄電池外に排気された上記ガスが爆発しても、その火気が蓄電池内に流入し、蓄電池自身が爆発しないように蓄電池が防爆機能を備えている場合が多い。防爆機能とは、排気部に防爆フィルターを配設して蓄電池外で引火、爆発した時に該防爆フィルターの狭隙構造により蓄電池内への火花の導入を阻止し、蓄電池自身の爆発を防止するものである。防爆フィルターにはセラミックの焼結体に撥水材を焼き付けたものや高分子多孔成型体からなるものが一般的に使用されている。
【0003】
従来は、前記防爆機能を有する防爆フィルターは、蓄電池の上蓋から突出して装着されることが一般的であった。これは、正・負極端子も上蓋に突出して設けられていることが多かったため防爆フィルターが上蓋から突出していても問題にならなかった。しかし、近年、蓄電池のエネルギー密度の向上に対する要望が強くなってきた中で不要な空間を少しでもなくする必要が生じ、端子を蓄電池の上蓋面より下部に設けた構造が多くなってきた。それに伴って、防爆フィルターも上蓋面からできるだけ低くする試みがなされるようになった。
【0004】
図1はその一例を示す要部断面図で、1は蓄電池上蓋、2は天蓋、3は通気孔、4は防爆フィルターをそれぞれ示す。
【0005】
図1に示すように本例では、防爆フィルターは上蓋1より下部に位置しているが、天蓋2が上蓋1より僅かに突出している構造である。この場合、蓄電池外部で発生した爆発の際の爆風により排気部周囲の水素ガスおよび火気を完全に除去し難い構造であるため、続いて二次爆発が発生する危険を有している。
【0006】
図2は他の例を示す要部断面図で、構成部材は図1と同じ番号を付記する。
【0007】
図2に示すように、天蓋2が蓄電池の上蓋1と同一面に形成され、余分な空間がなく、エネルギー密度の点で図1より優れている。しかし、図2に示す構造も、図1と同様、蓄電池外部で発生した爆発の際の爆風で排気部周囲の水素ガスおよび火気が完全に除去され難いこと、および蓄電池内部からの水素ガスがストレートに排気孔3からは排気されるので図1の場合よりも二次爆発の発生の可能性がより高い問題点を抱えている。
【0008】
【発明が解決しようとする課題】
本発明が解決しようとする課題は、エネルギー密度の点から不要な空間を排除した構造であって、蓄電池外部で発生した爆発の二次爆発を防止し、より防爆機能の優れた安全な鉛蓄電池を提供することにある。
【0009】
【課題を解決するための手段】
課題を解決するための手段として請求項1によれば蓄電池上蓋面に凹設された排気部であって、前記排気部の底部に配された防爆フィルターと、前記防爆フィルターの上部に配された天蓋と、前記防爆フィルターと前記天蓋との間に形成された排気口とからなり、前記排気口の最上端が前記蓄電池上蓋面より突出しない構造を備えたことを特徴とするものである。
【0010】
発明者は、充電中の鉛蓄電池において、排気部周囲で意識的に引火・爆発を起こさせた場合、本発明の構造の蓄電池では、連続的な二次爆発が発生せず、火気も蓄電池内に導入せず、防爆機能の優れていることを発見した。その理由は、凹設された排気部によって形成された凹部と防爆フィルターと天蓋との間に形成された排気口の最上端が前記蓄電池上蓋面より突出しない構造にある。このように排気口が蓄電池上蓋面より突出していないことによって、蓄電池内部からの水素ガスは必ず前記排気口を通って前記凹部に排気される。排気部周囲で着火・爆発が発生したときに、その爆風により凹部に滞留する水素ガスおよび火気が排除されその部分に一時的な真空状態が形成される。さらに、蓄電池内から発生した水素ガスは、垂直方向で上昇してそのまま蓄電池外部に排気されるのではなく、一旦、水平方向の流れに転換されて前記排気口を通って蓄電池外部に排気される構造なので、発生する水素ガスの流れが垂直方向から水平方向に転換される時に蓄電池外部への排気が瞬時遅れ、水素ガス排気の一時的な遮断状態となる。この二つの要素の相乗効果により、二次爆発の防止が効果的に行われ、優れた防爆機能が得られたと考えられる。
【0011】
【発明の実施の形態】
本発明の実施の形態は、蓄電池上蓋面に凹設された排気部と、前記排気部の底部に配された防爆フィルターと、前記防爆フィルターの上部に配された天蓋と、前記防爆フィルターと前記天蓋の間に形成された排気口とからなり、前記排気口の最上端が前記蓄電池上蓋面より突出しない構造により防爆機能が改善されるもので、以下、実施例により詳細に説明する。
【0012】
【実施例】
図3は本発明の実施例を示す要部断面図、図4は要部斜視図で、5は本発明の凹設された排気部、3aは本発明の排気口、6は凹部それぞれを示す。他の構成部材は図1と同じ番号を付記する。
【0013】
図3および図4に示すように、本発明では、蓄電池上蓋1の面に凹設された排気部5を設けて蓄電池外部と連通する構造であると共に排気部5の下部に防爆フィルター4を配し、その上部に天蓋2を設け、前記防爆フィルター4と前記天蓋2との間に排気口3aを形成し、該排気口3aの最上端が蓄電池上蓋1面より突出しない構造を特徴とするものである。排気口3aが上蓋面1より突出しない構造により、蓄電池からの水素ガスは排気口3aを通って必ず凹部6に排気される。凹部6に滞留する水素ガスおよび火気は、蓄電池外部で着火、爆発が発生した際の爆風により排除され、その部分が一時的に真空状態が形成される。さらに、蓄電池内部から発生する水素ガスが図3に示す矢印にようにその構造上、ガスの進行方向が垂直方向から水平方向に転換されることが外部への排気を瞬時遅らせ、一時的な遮断状態をつくりだす。これら二つの要素の相乗効果により、蓄電池外部で爆発が発生したときに連続的な二次爆発が発生せず、防爆機能がより有効に作用すると考えられる。
【0014】
図5は本発明の凹設された排気部による防爆機能を備えた制御弁式鉛蓄電池の一実施例を示す斜視図で、1は上蓋、5は凹設された排気部、6は凹部、7は電槽、8は中蓋、9は端子をそれぞれ示す。
【0015】
本実施例では、6個の単電池(セル)から構成される公称電圧12Vの制御弁式鉛蓄電池の例を示すもので、天蓋2および凹設された排気部5および防爆フィルター4(図5では図示されていない)は、蓄電池の上蓋1と一体に成型され、中央部に配設された形状を示すものである。図5には図示されていないが、中蓋8面には、6個の弁座を有する注液口が設けられ、前記弁座には安全弁が装着されている。これら安全弁から排気される水素ガスおよび酸素ガスが凹設された排気部5から一括に蓄電池外部に排気される構造である。しかし、本発明はこれに限定するものではなく、安全弁数個毎あるいは各安全弁毎に前記凹設された排気部5を設ける構造でもよい。
【0016】
また、上記図5の例では、上蓋1と天蓋2、防爆フィルター4および排気口3aからなる凹設された排気部5とが一体に成型された構造が示されているが、本発明はこれに限定するものではなく、上蓋1とは別に凹設された排気部5を成型して上蓋1に嵌め込む構造でもよい。
【0017】
【発明の効果】
以上の説明から明らかなように、蓄電池上蓋面に凹設された排気部であって、前記排気部の底部に配された防爆フィルターと、前記防爆フィルターの上部に配されたと天蓋と、前記防爆フィルターと前記天蓋との間に形成された排気口からなり、前記排気口の最上端が蓄電池の上蓋面から突出しない構造にすることにより、蓄電池外部の排気部周囲で着火、爆発が発生しても爆風により凹部に滞留する水素ガスおよび火気が除去され一時的にその部分に真空状態が形成されることおよび蓄電池内部から発生する水素ガスを垂直方向から水平方向に転換させる排気構造による蓄電池外部への排気の瞬時的な遅れが、水素ガスの一時的な遮断状態を作り出すこととの二つの要素の相乗効果により二次的な爆発を効果的に防止でき、優れた防爆機能が得られその工業的効果が大である。
【図面の簡単な説明】
【図1】従来の防爆構造の一例を示す要部断面図。
【図2】従来の防爆構造の他の例を示す要部断面図。
【図3】本発明の防爆構造の実施例を示す要部断面図。
【図4】本発明の防爆構造の実施例を示す要部斜視図。
【図5】本発明の防爆構造を備えた制御弁式鉛蓄電池の一例を示す斜視図
【符号の説明】
1 上蓋
2 天蓋
3 従来品の排気口
3a 本発明の排気口
4 防爆フィルター
5 凹設された排気部
6 凹部
7 蓄電池の電槽
8 蓄電池の中蓋
9 端子
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a lead storage battery.
[0002]
[Prior art]
In a lead storage battery, electrolysis of water occurs as a side reaction during charging, and oxygen gas and hydrogen gas are generated as shown in the following equation.
H 2 O = 1 / O 2 + H 2
The gas has the danger of explosion in the presence of fire. Therefore, even if the gas exhausted outside the storage battery explodes, the fire often flows into the storage battery and has an explosion-proof function so that the storage battery itself does not explode. The explosion-proof function means that when an explosion-proof filter is installed in the exhaust part, ignition and explosion occur outside the storage battery. It is. As the explosion-proof filter, a filter obtained by baking a water-repellent material on a ceramic sintered body or a filter formed of a porous polymer molded body is generally used.
[0003]
Conventionally, the explosion-proof filter having the explosion-proof function was generally mounted so as to protrude from the upper lid of the storage battery. This was not a problem even if the explosion-proof filter protruded from the upper lid, because the positive and negative terminals were often provided so as to protrude from the upper lid. However, in recent years, there has been a growing demand for an improvement in the energy density of the storage battery, and it has become necessary to eliminate unnecessary space. This has increased the number of structures in which terminals are provided below the upper lid surface of the storage battery. Accordingly, attempts have been made to make the explosion-proof filter as low as possible from the top lid surface.
[0004]
FIG. 1 is a cross-sectional view of an essential part showing an example thereof, wherein 1 is a battery cover, 2 is a canopy, 3 is a vent, and 4 is an explosion-proof filter.
[0005]
As shown in FIG. 1, in this example, the explosion-proof filter is located below the upper lid 1, but has a structure in which the canopy 2 slightly protrudes from the upper lid 1. In this case, there is a danger that a secondary explosion will occur subsequently because the structure is such that it is difficult to completely remove the hydrogen gas and the fire around the exhaust part by the blast at the time of the explosion generated outside the storage battery.
[0006]
FIG. 2 is a cross-sectional view of a main part showing another example.
[0007]
As shown in FIG. 2, the canopy 2 is formed on the same surface as the upper lid 1 of the storage battery, has no extra space, and is superior to FIG. 1 in terms of energy density. However, the structure shown in FIG. 2 is also similar to FIG. 1 in that it is difficult to completely remove the hydrogen gas and the fire around the exhaust part by the blast generated at the time of the explosion generated outside the storage battery. Since the exhaust gas is exhausted from the exhaust hole 3, there is a problem that the possibility of occurrence of the secondary explosion is higher than in the case of FIG.
[0008]
[Problems to be solved by the invention]
The problem to be solved by the present invention is a structure that eliminates unnecessary space in terms of energy density, prevents secondary explosion of an explosion generated outside the storage battery, and has a more excellent explosion-proof function. Is to provide.
[0009]
[Means for Solving the Problems]
As means for solving the problem, according to claim 1, there is provided an exhaust portion recessed in the upper surface of the storage battery, wherein the explosion-proof filter is disposed at the bottom of the exhaust portion, and disposed above the explosion-proof filter. It has a structure comprising a canopy and an exhaust port formed between the explosion-proof filter and the canopy, wherein the uppermost end of the exhaust port does not protrude from the upper surface of the storage battery.
[0010]
When the inventor intentionally ignites or explodes around the exhaust part in the charging lead storage battery, the storage battery of the present invention does not generate a continuous secondary explosion, and the fire is also stored in the storage battery. Without introducing it to the explosion-proof function. The reason is that the uppermost end of the exhaust port formed between the explosion-proof filter and the canopy does not protrude from the upper surface of the storage battery. Since the exhaust port does not protrude from the upper surface of the storage battery, hydrogen gas from the inside of the storage battery is always exhausted to the recess through the exhaust port. When an ignition or explosion occurs around the exhaust part, the blast blows off the hydrogen gas and the fire remaining in the concave portion, and a temporary vacuum state is formed in that part. Further, the hydrogen gas generated from the inside of the storage battery does not rise in the vertical direction and is discharged to the outside of the storage battery as it is, but is temporarily converted into a flow in the horizontal direction and is discharged to the outside of the storage battery through the exhaust port. Due to the structure, when the flow of the generated hydrogen gas is changed from the vertical direction to the horizontal direction, the exhaust to the outside of the storage battery is momentarily delayed, and the hydrogen gas exhaust is temporarily shut off. It is considered that the secondary explosion was effectively prevented by the synergistic effect of these two elements, and an excellent explosion-proof function was obtained.
[0011]
BEST MODE FOR CARRYING OUT THE INVENTION
An embodiment of the present invention includes an exhaust unit recessed in a storage battery upper lid surface, an explosion-proof filter disposed at the bottom of the exhaust unit, a canopy disposed above the explosion-proof filter, the explosion-proof filter, and the explosion-proof filter. An explosion-proof function is improved by a structure including an exhaust port formed between the canopies, and the uppermost end of the exhaust port does not protrude from the upper surface of the storage battery. This will be described in detail below with reference to examples.
[0012]
【Example】
FIG. 3 is a sectional view of an essential part showing an embodiment of the present invention, FIG. 4 is a perspective view of an essential part, 5 is a concave exhaust part of the present invention, 3a is an exhaust port of the present invention, and 6 is a concave part. . Other components are denoted by the same reference numerals as in FIG.
[0013]
As shown in FIGS. 3 and 4, the present invention has a structure in which a recessed exhaust portion 5 is provided on the surface of the storage battery upper lid 1 to communicate with the outside of the storage battery, and an explosion-proof filter 4 is disposed below the exhaust portion 5. A top lid 2 is provided on the upper part thereof, an exhaust port 3a is formed between the explosion-proof filter 4 and the canopy 2, and the top end of the exhaust port 3a does not protrude from the surface of the storage battery upper lid 1. It is. Due to the structure in which the exhaust port 3a does not protrude from the upper lid surface 1, hydrogen gas from the storage battery is always exhausted to the recess 6 through the exhaust port 3a. The hydrogen gas and the fire stagnating in the concave portion 6 are eliminated by the blast when an ignition or explosion occurs outside the storage battery, and a vacuum state is temporarily formed in that portion. Further, as shown by the arrow in FIG. 3, hydrogen gas generated from the inside of the storage battery is structurally changed from a vertical direction to a horizontal direction as shown by an arrow in FIG. Create a state. Due to the synergistic effect of these two elements, it is considered that a continuous secondary explosion does not occur when an explosion occurs outside the storage battery, and the explosion-proof function works more effectively.
[0014]
FIG. 5 is a perspective view showing an embodiment of a control valve type lead-acid battery having an explosion-proof function by a recessed exhaust unit according to the present invention, wherein 1 is an upper cover, 5 is a recessed exhaust unit, 6 is a recess, Reference numeral 7 denotes a battery case, 8 denotes an inner lid, and 9 denotes a terminal.
[0015]
In this embodiment, an example of a control valve type lead-acid battery having a nominal voltage of 12 V composed of six single cells (cells) is shown. The canopy 2, the recessed exhaust part 5, and the explosion-proof filter 4 (FIG. (Not shown in the figure) shows a shape molded integrally with the upper lid 1 of the storage battery and disposed at the center. Although not shown in FIG. 5, a liquid inlet having six valve seats is provided on the surface of the inner lid 8, and a safety valve is mounted on the valve seat. The structure is such that hydrogen gas and oxygen gas exhausted from these safety valves are exhausted collectively to the outside of the storage battery from the recessed exhaust portion 5. However, the present invention is not limited to this, and a structure in which the recessed exhaust portion 5 is provided for every several safety valves or for each safety valve may be used.
[0016]
Further, in the example of FIG. 5 described above, a structure is shown in which the upper lid 1 and the canopy 2, the explosion-proof filter 4, and the recessed exhaust portion 5 including the exhaust port 3a are integrally molded. However, the present invention is not limited thereto, and a structure may be employed in which the exhaust portion 5 which is provided separately from the upper lid 1 is molded and fitted into the upper lid 1.
[0017]
【The invention's effect】
As is apparent from the above description, an exhaust portion recessed in the storage battery upper lid surface, an explosion-proof filter disposed at the bottom of the exhaust portion, a canopy disposed at the top of the explosion-proof filter, and the explosion-proof An exhaust port formed between the filter and the canopy is formed, and the uppermost end of the exhaust port does not protrude from the upper cover surface of the storage battery, so that ignition or explosion occurs around the exhaust portion outside the storage battery. The blast also removes the hydrogen gas and the fire remaining in the recesses and temporarily creates a vacuum in that part, and the outside of the storage battery with an exhaust structure that converts the hydrogen gas generated inside the storage battery from vertical to horizontal direction The instantaneous delay of the exhaust gas creates a temporary shut-off state of hydrogen gas and the synergistic effect of the two factors can effectively prevent secondary explosion, and excellent explosion-proof function Obtained its industrial effect is large.
[Brief description of the drawings]
FIG. 1 is a sectional view of an essential part showing an example of a conventional explosion-proof structure.
FIG. 2 is a sectional view of a main part showing another example of a conventional explosion-proof structure.
FIG. 3 is a sectional view of a main part showing an embodiment of the explosion-proof structure of the present invention.
FIG. 4 is a perspective view of an essential part showing an embodiment of the explosion-proof structure of the present invention.
FIG. 5 is a perspective view showing an example of a control valve type lead-acid battery provided with the explosion-proof structure of the present invention.
DESCRIPTION OF SYMBOLS 1 Top cover 2 Top lid 3 Conventional exhaust port 3a Exhaust port 4 of the present invention 4 Explosion-proof filter 5 Recessed exhaust section 6 Recess 7 Battery case 8 Storage battery inner lid 9 Terminal

Claims (1)

蓄電池上蓋面に凹設された排気部であって、前記排気部の底部に配された防爆フィルターと、前記防爆フィルターの上部に配された天蓋と、前記防爆フィルターと前記天蓋との間に形成された排気口とからなり、前記排気口の最上端が前記蓄電池上蓋面より突出しない構造を備えたことを特徴とする鉛蓄電池。An exhaust portion recessed in the upper surface of the storage battery, the explosion-proof filter disposed at the bottom of the exhaust portion, a canopy disposed above the explosion-proof filter, and formed between the explosion-proof filter and the canopy. A lead-acid battery, wherein the exhaust port has a structure in which the upper end of the exhaust port does not protrude from the upper surface of the storage battery.
JP2002271624A 2002-09-18 2002-09-18 Lead acid battery Expired - Fee Related JP4552375B2 (en)

Priority Applications (1)

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JP2002271624A JP4552375B2 (en) 2002-09-18 2002-09-18 Lead acid battery

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008041587A (en) * 2006-08-10 2008-02-21 Furukawa Battery Co Ltd:The Sealed type lead-acid battery
CN105181940A (en) * 2015-10-29 2015-12-23 大庆市日上仪器制造有限公司 Anti-explosion automatic ventilation insulating oil corrosive sulfur determination instrument

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS595877U (en) * 1982-07-02 1984-01-14 株式会社ユアサコーポレーション storage battery
JPS5955857U (en) * 1982-10-04 1984-04-12 株式会社ユアサコーポレーション Ready-to-use storage battery
JPH027357A (en) * 1988-02-18 1990-01-11 Yuasa Battery Co Ltd Valve device of enclosed type storage battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS595877U (en) * 1982-07-02 1984-01-14 株式会社ユアサコーポレーション storage battery
JPS5955857U (en) * 1982-10-04 1984-04-12 株式会社ユアサコーポレーション Ready-to-use storage battery
JPH027357A (en) * 1988-02-18 1990-01-11 Yuasa Battery Co Ltd Valve device of enclosed type storage battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008041587A (en) * 2006-08-10 2008-02-21 Furukawa Battery Co Ltd:The Sealed type lead-acid battery
CN105181940A (en) * 2015-10-29 2015-12-23 大庆市日上仪器制造有限公司 Anti-explosion automatic ventilation insulating oil corrosive sulfur determination instrument

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