JP2004014968A - Plasma processing apparatus - Google Patents

Plasma processing apparatus Download PDF

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Publication number
JP2004014968A
JP2004014968A JP2002169567A JP2002169567A JP2004014968A JP 2004014968 A JP2004014968 A JP 2004014968A JP 2002169567 A JP2002169567 A JP 2002169567A JP 2002169567 A JP2002169567 A JP 2002169567A JP 2004014968 A JP2004014968 A JP 2004014968A
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Japan
Prior art keywords
plasma
processing apparatus
processing chamber
measurement
light
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JP2002169567A
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Japanese (ja)
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JP4109020B2 (en
Inventor
Mitsuru Suehiro
末広 満
Hiroshi Kanekiyo
兼清 寛
Tetsuo Fujimoto
藤本 哲男
Muneo Furuse
古瀬 宗雄
Katsuya Watanabe
渡辺 克哉
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Hitachi High Tech Corp
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Hitachi High Technologies Corp
Hitachi High Tech Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a plasma processing apparatus capable of measuring plasma luminescence in a processing chamber stably and accurately for a long period without degrading the transmissivity of a measurement port for measuring the plasma luminescence. <P>SOLUTION: For measuring the emission state of a plasma generated in the apparatus, stable plasma measurement can be realized by installing at least one or more branching pipes on a structure contacting to the plasma and a measurement window 140 at the end of the branching pipe and then preventing pollution on the measurement window 140 when measuring the plasma. The plasma processing apparatus has a mechanism heating a component part in the processing chamber in a vacuum state to an arbitrary temperature with an optical heating source 160 arranged in an atmospheric side. Therein the measurement window 140 capable of improving the accuracy of the results of temperature measurement is provided by preventing stray light from the optical heating source 160 or the entry of light caused by the plasma luminescence in the processing chamber and then eliminating the affect of radiation heat from other than these component parts in the processing chamber. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、プラズマ処理装置、特に半導体製造工程における微細なパターンを形成するのに好適なプラズマ処理装置に係り、処理室内のプラズマ発光や構成部材の温度測定を行うための計測ポートに関する。
【0002】
【従来の技術】
半導体製造工程では、エッチング、成膜、アッシングなどの微細加工プロセスで、プラズマ処理装置が広く用いられている。プラズマ処理装置は、真空処理室(リアクタ)の内部に導入されたプロセスガスをプラズマ発生手段によりプラズマ化し、半導体ウエハ表面で反応させて微細な孔や溝などの加工あるいは成膜などの処理を行うとともに、揮発性の反応生成物を排気することにより所定の処理を行うものである。
【0003】
このプラズマ処理装置においては、処理中のプラズマからの発光を検出してエッチング処理の終点を検出しプラズマ発光のウエハ表面の薄膜における反射光や干渉信号などから膜厚やエッチング・成膜の速度(レート)をリアルタイムで測定してプラズマ処理の精度を向上させたり、処理室構成部材の実体温度を計測し、設定された温度にコントロールすることにより、処理する試料間の誤差が最小になるような制御が行われている。たとえば、特開平5−136098号公報には、平行平板型プラズマエッチング装置において、ウエハと対向する電極面に2つ以上のプラズマ受光センサーをもうけることで、ウエハ上の複数点のプラズマ発光強度からレートや膜厚の均一性や分布に関する情報を得てプラズマ密度を均一化させる方法が記載されている。
【0004】
また、特開平3−148118号公報には、平行平板型プラズマエッチング装置において、レーザ光を上部平板電極を貫いて上方からウエハに照射して反射レーザ光からエッチング量を測定して終点を検出する装置について、上部電極の汚れを防止するための石英製の電極カバーのレーザ光が通過する部分にφ10mm程度の穴を形成することで、電極カバーが汚れてもレーザ光が減衰することなく正確にエッチング量を測定して、安定に終点検出を行う方法が記載されている。
【0005】
これらの装置では、プラズマに接する処理室壁面に計測窓を直接、取り付けており、スパッタによる計測窓の厚さ減少、スパッタ及び反応生成物の付着防止対策についてはは記載されていない。
【0006】
【発明が解決しようとする課題】
しかしながら上記の方法では、次のような課題があった。
【0007】
まず、ウエハ表面の薄膜などの状態のモニタリングは、ウエハに対向する上方、あるいは45度程度までの斜め上方から計測するのが望ましいが、こうした方法で計測が可能なプラズマ処理装置は方式や構造が限定されてしまう。たとえば、マイクロ波ECR方式や誘導結合方式のプラズマ処理装置などでは、処理室内にマイクロ波を放射したり誘導電界を導入するために石英製の透明な窓や板をウエハの上方に設けることがあり、この場合にはウエハ表面の状態を上方から計測することができる。しかしながら、容量結合式のいわゆる平行平板型のプラズマ処理装置では、ウエハに対向する上部電極はアルミなどの導電性の金属であるため、ウエハ表面を直接透視できるような構造にはなっていない。このため、処理室側面に計測ポートを設け、プラズマからの発光スペクトルの増減をモニタリングすることにより、プラズマによる試料の処理が終わったことを検出する。しかしながら、実際には放電を重ねるにつれてプラズマ受光センサーを取り付けている計測窓には反応生成物が堆積し、光が透過しにくくなるので、長時間にわたって安定した計測を行うことは困難である。
【0008】
この課題を解決しようとしたのが、特開平3−148118号公報に記された方法であり、プラズマに直接さらされる石英製の電極カバーのレーザ光が通過する計測部分にφ10mm程度の穴を形成することで、石英カバー表面に堆積膜が付着しても計測には影響を及ぼさないとしたものである。しかしながら、実際にはこの方法もまた、安定した計測は困難である。プラズマ処理に必要な所定のプラズマ密度を得るためには上部電極には数kWもの大電力の高周波電力が印加されるので、上記公報に記されているようなφ10mm程度の穴を電極や電極カバーに形成すると、穴の部分で局部的な異常放電を引き起こしたり、穴の内部にプラズマが侵入したりして、上部電極や電極カバーが損傷を受けることになる。また、上部電極にはバイアスが印加されるので、電極カバーの穴をとおして上部電極がプラズマ中のイオンでスパッタされることになるが、上部電極はアルミなどの金属で形成されているために損傷したり異物発生の要因になったりするといった問題もある。
【0009】
もちろん、ウエハに対向する上方からでなく、処理室の側壁から浅い角度をもたせてウエハ表面を計測することも原理的には可能ではある。しかしながら、特に酸化膜エッチング装置では、プロセスガスの過剰な解離を抑制したりプロセス再現性を向上させるために、試料と対向しておよそ数10mm程度の距離を隔てた位置にシリコンなどの平板を対向させて設置する対向平板型の構造をとることが多い。しかしこの場合にも、計測窓が直接プラズマに曝されるため、計測窓の表面がスパッタされて、透明性を失われたり、逆に、スパッタされない場合には反応生成物が付着、堆積してやはり計測窓の透明性が失われことにより、長時間にわたって安定した計測を行うことは困難である。
【0010】
また、先に、マイクロ波ECR方式や誘導結合方式のプラズマ処理装置などで、ウエハ上方の石英製の計測窓からウエハ表面の計測が可能であると述べたが、実際には放電を重ねるごとに石英製の窓の表面に反応生成物が付着して透過率が低下したり、逆に表面がエッチングされてあれたりするために、やはり長期にわたる安定した計測は難しいという問題があり、実用的ではなかった。
【0011】
本発明は、上記の課題を解決するためになされたものであり、プラズマに接する処理室に短管を設置し、この短観の先端に計測窓を設置することにより、取り付け方向に関係なく試料面やプラズマの状態を精度よく、かつ異常放電や異物を発生させることなく、長期的に安定して計測できるようなプラズマ処理装置を提供することを目的とする。
【0012】
【課題を解決するための手段】
本発明者らは、上記の課題について、実用性と信頼性の観点から検討を重ねた結果、次のような解決方法を見出すにいたった。
【0013】
本発明は、真空処理室内に処理ガスを供給して、プラズマ発生装置によりプラズマを発生させ、当該プラズマにより試料台上に載置された試料をプラズマ処理するプラズマ処理装置において、装置内で発生するプラズマの発光状態を計測するために、プラズマと接する構造体に少なくとも1個以上の分岐管を設け、分岐管の端部に真空を形成するための計測窓を設け、この計測窓の大気側に光伝送体の光学センサー端面がほぼ接するように設置、プラズマ計測中の計測窓の汚染を防止することにより、長期間、安定してプラズマ計測を可能とした分岐管の端部に観測窓を設けることを特徴とする。
【0014】
また、大気側に設けた光学式加熱源により真空中の処理室内構成部品を任意の温度に加温する機構と、加熱された処理室内構成部品からの放射熱を測定し温度に換算することにより処理室内構成部品の温度を計測する手段を備え、光学式加熱源からの迷光及び処理室内のプラズマ発光による光の進入を防止し、これら処理室内構成部品以外からの放射熱の影響を排除することにより、温度測定結果の精度を向上させることが可能な計測窓を設けたことを特徴とする。
【0015】
尚、光伝送体141は、「透明」であること、すなわち可視光領域全域に対して透過性を持つことは必ずしも必要ではなく、計測する波長領域で十分な透過率を有していればよい。
【0016】
本発明の他の特徴は、光の光量を確保できる径、最低でも光学伝送手段に用いるセンサー径以上内径を有する短管を処理室と接する壁に取付け、その先端に計測用の計測窓をとりつけ、短管の長さをプラズマ中で発生するラジカルがこの計測窓に到達出来ない長さにすることで、計測窓表面にラジカルが堆積することを防止し、計測測窓が汚れることにより光の透過量が減少し、測定装置の感度が低下することによりノイズ等の重畳により測定精度が低下することを防止すること。さらに、光学センサーで被加熱構造物からの放射熱を測定するため、放射熱導入路から光を導入する計測窓を設け、放射熱導入路側面からの侵入光により、光量が変化し測定誤差を生じることを防止するため、導入路側面に光りを反射する材料をコーティングしたり、光を吸収するスリーブを設けたことにある。
【0017】
本発明の他の特徴は、光量を確保するため途中までの短管径を大きくし、その先端に径の小さい短管を取り付け、小さい短管の先端に計測窓を設けることにより、光の量を確保しながら、ラジカルが計測窓に到達しない長さにした、短管を用いたことにある。
【0018】
本発明のさらに他の特徴は、短管の長さを短くすることを目的に、短管内部にラジカルが計測窓に到着しないよう、管内に1ケないし複数のバッフル板を設けた短管を設けたことにある。
【0019】
(作用)
本発明によれば、プラズマ中で発生したイオンやラジカルが計測窓に到着しない長さの短管を設けているので計測窓がスパッタされたり、反応生成物が堆積して計測窓の透明性が失われることにより、計測値の精度が向上し、しかも長期間、安定して計測が可能となる。また、光伝送路の周辺を、放射熱を透過しない物質でコーティングまたは放射熱を透過しないスリーブ状の物質で覆っている為、被測定物以外の放射熱の侵入を防止できるため、計測精度を向上させることができる。
【0020】
【発明の実施の形態】
以下、本発明の実施例について、図面に基づいて説明する。
【0021】
図1は、本発明を、有磁場UHF帯電磁波放射放電方式のプラズマエッチング装置へ適用した実施例を示すもので、当該プラズマエッチング装置の断面模式図である。
【0022】
図1において、処理室100は、10−6Torr程度の真空度を達成可能な真空容器であり、その上部にプラズマ発生手段としての電磁波を放射するアンテナ110を、下部にはウエハなどの試料Wを載置する下部電極130を、それぞれ備えている。アンテナ110と下部電極130は、平行して対向する形で設置される。処理室100の周囲には、たとえば電磁コイルとヨークからなる磁場形成手段101が設置されており、所定の分布と強度をもつ磁場が形成される。そして、アンテナ110から放射される電磁波と磁場形成手段101で形成される磁場との相互作用により、処理室内部に導入された処理ガスをプラズマ化して、プラズマPを発生させ、試料Wを処理する。処理室100は、真空室103に接続された真空排気系104と圧力制御手段105により真空排気と圧力調整がなされて、内部の圧力がたとえば0.5Pa以上4Pa以下程度の所定の値に制御できる。処理室100および真空室103はアース電位となっている。処理室100の側壁102は、図示しない温度制御手段により、たとえば50℃程度に温調されている。
【0023】
電磁波を放射するアンテナ110は、円板状導電体111、誘電体112、誘電体リング113からなり、真空容器の一部としてのハウジング114に保持される。また、円板状導電体111のプラズマに接する側の面にはプレート115が設置される。試料のエッチング、成膜等の処理を行なう処理ガスは、ガス供給手段116から所定の流量と混合比をもって供給され、円板状導電体111の内部で均一化されて、プレート115に設けられた多数の孔を通して処理室100に供給される。
【0024】
処理室100の下部には、アンテナ110に対向して下部電極130が設けられている。下部電極130は、静電吸着装置131により、その上面すなわち試料載置面にウエハなどの試料Wを載置保持する。下部電極130には、望ましくは400kHzから13.56MHzの範囲のバイアス電力を供給するバイアス電源134がマッチング回路・フィルタ系135を介して接続されて、試料Wに印加するバイアスを制御する。本実施例では、バイアス電源134は周波数を800kHzとしている
【0025】
次に、本実施例の要部である、プラズマの発光状態を計測するために設置された計測ポート140A、及び、処理室内部の被加熱構造対からの放射熱を測定する計測ポート140Bについて説明する。本実施例では、計測ポート140Aは処理室側面、140Bはハウジング114に取り付けられている。
【0026】
もちろん、計測ポートの取り付けはここで説明したように処理室側面とハウジングの2カ所に限られるものではなく、1カ所のみあるいは2カ所以上としてもよく、あるいはたとえば円周上に配列するなど別の配置にしてもよいことはいうまでもない。
【0027】
計測ポート140Aの端部には、たとえば光ファイバやレンズなどの光学伝送手段151A、151Bが設けられており、プラズマPの発光状態を反映する光学情報が、計測器152に伝送されて計測される。本実施例では、光学伝送手段151A、151Bは共通の計測器152に接続されているが、別々の計測器を設けて、接続しても問題はない。計測器152は、計測器制御・演算手段153により制御されるとともに、さらに上位のシステム制御手段154と接続される。システム制御手段154は、制御インタフェース155を介して、ウェハ処理終了したか否かの判定を行う。計測ポート140Bには、処理室内部構成材の温度を一定に保つため、光学式加熱装置160により加熱される被加熱構成材161の温度を放射熱を温度に換算、計測することにより、光学式加熱装置の出力を調整する。これにより、プラズマにより被加熱構造物が加熱され、一定の温度以上に達したならば、加熱制御装置162により光学式加熱装置160の出力を調整し、被加熱構造対161の温度および出力を制御することにより、光学式加熱装置160の寿命を延ばしている。
【0028】
次に、計測ポート140A、140Bについて、その詳細な構造を図2から図5を用いて説明する。
【0029】
図2は、図1の実施例において、処理室側壁102に取り付けられた計測ポート140Aの部分を拡大した断面図である。
【0030】
処理室側壁102に取り付けられた短管142Aの端部には計測窓143がとりつけられており、そして、計測窓143の大気側の端面に、たとえば光ファイバやレンズなどの光学伝送手段151が設けられている。そして、プラズマPからの直接光145が、破線で示す光路のように、短管142A内を通過し、計測窓143を透過して光学伝送手段151に達し、さらに計測器152に伝送されて計測される。
【0031】
この時、プラズマ中で発生するイオンやラジカルは真空中で移動する距離は、圧力と分子量できまる平均自由行程の距離を移動し、衝突した壁面のエネルギーレベルが高ければ、衝突したイオンにたたき出されたイオンが平均自由行程の長さまで移動する。これを繰り返すうちに計測窓143に達し、大気側に接して温度の低い計測窓143の表面に堆積し、計測窓143の光の透過率を低下させることにより、ウェハ処理が終了したことを検知するプラズマPの発光量を計測する精度が低下し、確実なエッチング終了を判定するのが困難になる。本発明では、短管の長さをプラズマ中で発生するガス成分の平均自由行程長以上にとり、且つ、短管142Aの壁面がプラズマから離れた大気と接しているため、短管142Aのプラズマに面した開口部から侵入したイオンやラジカルは直接計測窓143に到達することが困難となる。
【0032】
また短管142Aの温度の低い壁に衝突したイオンやラジカルはそのエネルギーを吸収されるため、再度、壁面から飛び出すことはない。
【0033】
このようにプラズマ中で発生したイオンやラジカルが計測窓143に到達することが困難になり、計測窓143はいつまでも清浄な状態を保つことができ、光の透過率が現象することがないため、初期の計測精度を長期間にわたり維持することが可能である。
【0034】
図3の例は原理は図2と同じだが、短管へのイオンやラジカルの侵入を防ぐため、短管の径を小さくすると、判定に必要な光量が計測窓143に到達せず、光伝送手段の感度を低下せせてしまう可能性がある場合に、プラズマPに接する側の管の径を大きくした径違い短管142Bを側壁102に設け、計測窓143の近くまで充分な光量を確保した例である。この場合においても短管の長さは、処理ガスの平均自由行程長以上とすることが望ましい。
【0035】
図4の例は、処理室周辺に充分な空間がなく、短管の長さが処理ガスの平均自由行程長を確保できない場合、短管142Cに飛び込んでくるイオンやラジカル146が計測窓143に到達しないよう、短管142Cの内面にバッフル147を設けた例である。短管142Cの開口面から飛び込んだイオンやラジカルは計測窓143に到達する前にバッフル147に衝突するため、計測窓143に到達することが困難になる。この場合、短管142Cの径は小さいほど、イオンやラジカル146の侵入量が小さくなるので計測窓143に堆積する量も小さくなるので、光学伝送手段151が許容する光量の確保が可能な径まで小さくすることが重要である。径を小さくして支障がある場合は図2と図3をくみあわせた短管構造とすることも可能である。
【0036】
これらの効果の総合的な結果として、計測窓143は、端面に反応生成物が付着したり表面があれたりすることがなく、光透過特性が放電を重ねても一定に保たれるので、長期にわたって安定した計測が可能となる。
【0037】
図5〜7に真空処理室100内の被加熱構造材161の温度を測定する場合の計測窓の詳細構造について述べる。
【0038】
図6は本発明を適用しない場合の状態である。光学系加熱装置160で加熱された真空処理室内の被加熱構造材161は温度が上昇すると放射熱が高くなる。放射熱は光伝送体141を通って光伝送手段151にて計測され、計測器152を経由して制御インターフェース155に電気信号として伝送される。
【0039】
この時、光学系加熱装置160の光やプラズマの発光が迷光163として光伝導体141の側面より入射、光伝送手段151にて熱信号として計測される。従って、光伝送手段151は被加熱構造材161の実体温度よりも高い温度を誤って検出し、被加熱構造材161を一定の温度を保つために光学系加熱装置160の出力を低下させる制御を行う。このため、被加熱構造材161の温度は設定温度よりも低い温度で維持されるため装置の性能を阻害する要因となる。
【0040】
図6はこの問題を解決するための実施例である。光学系加熱装置160の光やプラズマの発光の迷光163が光伝送体141の側面より入射するのを防止するため、光伝送体141の側面に迷光163の侵入を防止するため反射材164をコーティングした例である。光伝送体141の側面に迷光163の侵入を防止することにより光伝送手段151には被加熱構造材161だけからの放射熱だけを計測することができ、計測精度を上げることができる。
【0041】
図7は反射材164の代わりに、光学系加熱装置160の光やプラズマ光からの迷光163のスペクトルが透過しない波長を持った、スリーブ165を光伝送体141の側面に設けた例をす。効果については図6で説明した内容と同じである。
【0042】
ところで、これまでの実施例では、光伝送体141に透明石英製を用いていたが、これは一例であって、放射熱のスペクトルは透過するが光学系加熱装置160の光やプラズマ光の迷光163のスペクトルは透過できない材質を光伝送体141に使用することができれば、図6、図7で述べた反射材164やスリーブ165を設けることなく光学系加熱装置160の光やプラズマ光の迷光163の侵入を防止することも可能である。
【0043】
なお、前記の各実施例は、いずれも有磁場UHF帯電磁波放射放電方式のプラズマ処理装置の場合であったが、放射される電磁波はUHF帯以外にも、たとえば2.45GHzのマイクロ波や、あるいは数10MHzから300MHz程度までのVHF帯でもよい。また、磁場強度は、450MHzに対する電子サイクロトロン共鳴磁場強度である160ガウスの場合について説明したが、必ずしも共鳴磁場を用いる必要はなく、これよりも強い磁場やあるいは数10ガウス程度以上の弱い磁場を用いてもよい。さらに電磁波放射放電方式だけでなく、容量結合型の平行平板プラズマ処理装置やマグネトロン型のプラズマ処理装置、あるいは誘導結合型のプラズマ処理装置にも、本発明が同様に適用できることはいうまでもない。
【0044】
【発明の効果】
以上説明したように、本発明によれば、プラズマの発光状態や処理室内の被加熱構造材の温度を大気側に設けた計測窓を通じ、光学伝送手段により量産レベルでも長期的に安定して精度よく測定できる。この結果、エッチング処理の終点検出や大気側加熱源の出力制御が可能となるので、より進んだプロセス制御の方法が提供できるとともに、処理の再現性や安定性も向上できるので装置の稼働率や生産性の向上に寄与しうるプラズマ処理装置を提供することが可能となる。
【図面の簡単な説明】
【図1】本発明の一実施例である、プラズマエッチング装置の断面模式図。
【図2】本発明の要部である、貫通孔分岐管部分の構造を示す図。
【図3】本発明の要部である、径を大きくした貫通孔分岐管部分の構造を示す図。
【図4】本発明の要部である、バッフルを設け、長さを短くした貫通孔分岐管部分の構造を示す図。
【図5】従来の計測窓の構造例を示す図。
【図6】本発明における計測窓の実施例を示す図。
【図7】本発明における計測窓のその他の実施例を示す図。
【符号の説明】
100…処理室、101…磁場形成手段、102…処理室側壁、103…真空室、104…真空排気系、105…圧力制御手段、110…アンテナ、
111…円板状導電体、112…誘電体、113…誘電体リング、
114…ハウジング、115…プレート、116…ガス供給手段、
130…下部電極、131…静電吸着装置、134…バイアス電源、
135…マッチング回路・フィルタ系、140A/B…計測ポート、
141…光伝送体、142A/B/C…短管、143…計測窓、
145…プラズマ直射光、146…イオン・ラジカル、147…バッフル、
151A/B…光学伝送手段、152…計測器、153…計測器制御・演算手段、154…システム制御手段、154…制御インターフェイス、
160…光学式加熱装置、161…被加熱構造材、162…加熱制御装置、
163…迷光、164…反射材、165…スリーブ、P…プラズマ、W…試料
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to a plasma processing apparatus, and more particularly to a plasma processing apparatus suitable for forming a fine pattern in a semiconductor manufacturing process, and relates to a measurement port for performing plasma emission in a processing chamber and temperature measurement of components.
[0002]
[Prior art]
In a semiconductor manufacturing process, a plasma processing apparatus is widely used in a fine processing process such as etching, film formation, and ashing. The plasma processing apparatus converts a process gas introduced into a vacuum processing chamber (reactor) into plasma by a plasma generating means, and reacts on the surface of the semiconductor wafer to perform processing such as processing of fine holes and grooves or film formation. At the same time, predetermined processing is performed by exhausting volatile reaction products.
[0003]
In this plasma processing apparatus, the light emission from the plasma being processed is detected, the end point of the etching process is detected, and the film thickness, the etching / film forming speed ( Rate) is measured in real time to improve the accuracy of plasma processing, or by measuring the actual temperature of the processing chamber components and controlling it to the set temperature to minimize errors between samples to be processed. Control is being performed. For example, Japanese Unexamined Patent Publication No. 5-136098 discloses that in a parallel plate type plasma etching apparatus, two or more plasma light receiving sensors are provided on an electrode surface facing a wafer so that the rate of plasma emission at a plurality of points on the wafer can be increased. A method is described in which information on the uniformity and distribution of film thickness and film thickness is obtained to make the plasma density uniform.
[0004]
In Japanese Patent Application Laid-Open No. 3-148118, in a parallel plate type plasma etching apparatus, a laser beam is irradiated on a wafer from above through a top plate electrode, and an etching amount is measured from a reflected laser beam to detect an end point. For the device, by forming a hole of about 10 mm in the portion of the quartz electrode cover through which the laser light passes to prevent contamination of the upper electrode, even if the electrode cover becomes dirty, the laser light does not attenuate accurately. A method of measuring an etching amount and stably detecting an end point is described.
[0005]
In these apparatuses, the measurement window is directly attached to the wall surface of the processing chamber in contact with the plasma, and no description is given of measures to reduce the thickness of the measurement window due to spatter and to prevent spatter and adhesion of reaction products.
[0006]
[Problems to be solved by the invention]
However, the above method has the following problems.
[0007]
First, it is desirable to monitor the state of the thin film on the wafer surface, etc., from above, facing the wafer, or obliquely up to about 45 degrees. However, the plasma processing apparatus that can measure by such a method has a method and a structure. It will be limited. For example, in a microwave ECR or inductively coupled plasma processing apparatus, a transparent window or plate made of quartz may be provided above a wafer in order to radiate a microwave or introduce an induced electric field into a processing chamber. In this case, the state of the wafer surface can be measured from above. However, in a capacitively-coupled so-called parallel plate type plasma processing apparatus, the upper electrode facing the wafer is made of a conductive metal such as aluminum, so that the structure is not such that the wafer surface can be directly seen through. For this reason, a measurement port is provided on the side of the processing chamber to monitor the increase / decrease of the emission spectrum from the plasma, thereby detecting that the processing of the sample by the plasma is completed. However, in practice, reaction products accumulate in the measurement window on which the plasma light receiving sensor is attached as the discharge is repeated, making it difficult for light to pass therethrough. Therefore, it is difficult to perform stable measurement over a long period of time.
[0008]
In order to solve this problem, a method described in Japanese Patent Application Laid-Open No. 3-148118 discloses a method in which a hole of about 10 mm is formed in a measurement portion of a quartz electrode cover directly exposed to plasma through which laser light passes. Thus, even if the deposited film adheres to the surface of the quartz cover, the measurement is not affected. However, in practice, this method also has difficulty in stable measurement. In order to obtain a predetermined plasma density required for plasma processing, high-frequency power of a large power of several kW is applied to the upper electrode. Therefore, a hole having a diameter of about 10 mm as described in the above publication is formed in the electrode or the electrode cover. If formed, the upper electrode and the electrode cover will be damaged due to the occurrence of local abnormal discharge at the hole and the penetration of plasma into the hole. Also, since a bias is applied to the upper electrode, the upper electrode is sputtered with ions in the plasma through the hole in the electrode cover, but since the upper electrode is formed of a metal such as aluminum, There are also problems such as damage or foreign matter generation.
[0009]
Of course, it is possible in principle to measure the wafer surface not from above but facing the wafer but at a shallow angle from the side wall of the processing chamber. However, especially in an oxide film etching apparatus, in order to suppress excessive dissociation of the process gas and to improve the process reproducibility, a flat plate made of silicon or the like is opposed to the sample at a distance of about several tens of mm. In many cases, an opposing flat plate type structure is installed. However, also in this case, the measurement window is directly exposed to the plasma, so that the surface of the measurement window is sputtered and loses transparency, or conversely, if not sputtered, reaction products adhere and deposit. Again, it is difficult to perform stable measurement for a long time due to the loss of transparency of the measurement window.
[0010]
In addition, as mentioned earlier, it is possible to measure the wafer surface from the quartz measurement window above the wafer with a microwave ECR system or an inductively-coupled plasma processing device, etc. The reaction product adheres to the surface of the quartz window to lower the transmittance, and the surface is etched away. Did not.
[0011]
The present invention has been made in order to solve the above-mentioned problems, and a short pipe is installed in a processing chamber in contact with plasma, and a measurement window is installed at the tip of this tankan, so that the sample surface can be mounted regardless of the mounting direction. It is an object of the present invention to provide a plasma processing apparatus capable of accurately and stably measuring the state of plasma and plasma over a long period of time without generating abnormal discharge or foreign matter.
[0012]
[Means for Solving the Problems]
The present inventors have repeatedly studied the above problems from the viewpoints of practicality and reliability, and have found the following solution.
[0013]
The present invention provides a plasma processing apparatus that supplies a processing gas into a vacuum processing chamber, generates plasma by a plasma generator, and performs plasma processing on a sample mounted on a sample stage by the plasma. In order to measure the emission state of the plasma, at least one or more branch pipes are provided in the structure in contact with the plasma, and a measurement window for forming a vacuum is provided at an end of the branch pipe. An observation window is provided at the end of a branch pipe that enables stable and long-term plasma measurement by preventing the contamination of the measurement window during plasma measurement by installing the optical sensor so that the optical sensor end face of the optical transmission body is almost in contact. It is characterized by the following.
[0014]
Also, a mechanism for heating the processing chamber components in a vacuum to an arbitrary temperature by an optical heating source provided on the atmosphere side, and by measuring the radiant heat from the heated processing chamber components and converting them to temperature Provision of means for measuring the temperature of components in the processing chamber to prevent stray light from the optical heating source and light from plasma emission in the processing chamber from entering, and to eliminate the influence of radiant heat from components other than the processing chamber. Thus, a measurement window capable of improving the accuracy of the temperature measurement result is provided.
[0015]
Note that the optical transmitter 141 is not necessarily “transparent”, that is, it is not necessary to have transparency in the entire visible light region, and it is sufficient that the optical transmitter 141 has a sufficient transmittance in the wavelength region to be measured. .
[0016]
Another feature of the present invention is that a short pipe having a diameter capable of securing the amount of light, at least an inner diameter of the sensor used for the optical transmission means, is attached to a wall in contact with the processing chamber, and a measurement window for measurement is attached to a tip of the short pipe. By making the length of the short tube such that the radicals generated in the plasma cannot reach this measurement window, the radicals are prevented from accumulating on the measurement window surface, and the measurement measurement window is contaminated. To prevent a decrease in measurement accuracy due to superposition of noise or the like due to a decrease in transmission amount and a decrease in sensitivity of a measuring device. Furthermore, in order to measure the radiant heat from the structure to be heated by the optical sensor, a measurement window for introducing light from the radiant heat introduction path is provided. In order to prevent such a phenomenon, a light reflecting material is coated on the side of the introduction path, or a light absorbing sleeve is provided.
[0017]
Another feature of the present invention is to increase the diameter of the short pipe halfway to secure the light quantity, attach a short pipe with a small diameter at the tip, and provide a measurement window at the tip of the small short pipe, thereby reducing the amount of light. While using a short tube that has a length that does not allow the radicals to reach the measurement window while ensuring the above.
[0018]
Still another feature of the present invention is to provide a short tube provided with one or more baffle plates in the tube in order to reduce the length of the short tube so that radicals do not reach the measurement window inside the short tube. It has been provided.
[0019]
(Action)
According to the present invention, the measurement window is sputtered or a reaction product is deposited because the short tube having a length such that ions and radicals generated in the plasma do not reach the measurement window is provided, so that the transparency of the measurement window is reduced. By being lost, the accuracy of the measured value is improved, and moreover, stable measurement can be performed for a long period of time. In addition, since the periphery of the optical transmission line is coated with a material that does not transmit radiant heat or covered with a sleeve-like material that does not transmit radiant heat, it is possible to prevent the intrusion of radiant heat other than the object to be measured. Can be improved.
[0020]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
[0021]
FIG. 1 shows an embodiment in which the present invention is applied to a magnetic field UHF band electromagnetic wave radiation discharge type plasma etching apparatus, and is a schematic sectional view of the plasma etching apparatus.
[0022]
In FIG. 1, a processing chamber 100 is a vacuum container capable of achieving a degree of vacuum of about 10 −6 Torr, and an antenna 110 for emitting electromagnetic waves as plasma generating means is provided at an upper part thereof, and a sample W such as a wafer is provided at a lower part thereof. Are provided, respectively. The antenna 110 and the lower electrode 130 are installed so as to face each other in parallel. A magnetic field forming means 101 composed of, for example, an electromagnetic coil and a yoke is provided around the processing chamber 100, and a magnetic field having a predetermined distribution and strength is formed. Then, by the interaction between the electromagnetic wave radiated from the antenna 110 and the magnetic field formed by the magnetic field forming means 101, the processing gas introduced into the processing chamber is turned into plasma to generate plasma P and process the sample W. . The processing chamber 100 is evacuated and pressure-adjusted by a vacuum exhaust system 104 and a pressure control means 105 connected to a vacuum chamber 103, so that the internal pressure can be controlled to a predetermined value of, for example, about 0.5 Pa or more and 4 Pa or less. . The processing chamber 100 and the vacuum chamber 103 are at the ground potential. The temperature of the side wall 102 of the processing chamber 100 is controlled to, for example, about 50 ° C. by a temperature control unit (not shown).
[0023]
An antenna 110 that emits an electromagnetic wave includes a disc-shaped conductor 111, a dielectric 112, and a dielectric ring 113, and is held by a housing 114 as a part of a vacuum container. Further, a plate 115 is provided on the surface of the disc-shaped conductor 111 on the side in contact with the plasma. A processing gas for performing processing such as etching and film formation of the sample is supplied from the gas supply means 116 at a predetermined flow rate and a mixing ratio, is made uniform inside the disc-shaped conductor 111, and is provided on the plate 115. It is supplied to the processing chamber 100 through many holes.
[0024]
A lower electrode 130 is provided below the processing chamber 100 so as to face the antenna 110. The lower electrode 130 holds a sample W such as a wafer on its upper surface, that is, a sample mounting surface, by the electrostatic chuck 131. To the lower electrode 130, a bias power supply 134 for supplying a bias power in a range of 400 kHz to 13.56 MHz is connected via a matching circuit / filter system 135 to control a bias applied to the sample W. In this embodiment, the frequency of the bias power supply 134 is 800 kHz.
Next, a description will be given of a measurement port 140A installed to measure the light emission state of the plasma and a measurement port 140B measuring the radiant heat from the heated structure pair inside the processing chamber, which are the main parts of the present embodiment. I do. In this embodiment, the measurement port 140A is attached to the side of the processing chamber, and 140B is attached to the housing 114.
[0026]
Of course, the attachment of the measurement port is not limited to the two places of the processing chamber side and the housing as described herein, but may be only one place or two or more places, or another place such as arranging on a circumference. It goes without saying that they may be arranged.
[0027]
At the end of the measurement port 140A, optical transmission means 151A and 151B such as an optical fiber and a lens are provided, and optical information reflecting the light emission state of the plasma P is transmitted to the measurement device 152 and measured. . In this embodiment, the optical transmission means 151A and 151B are connected to the common measuring instrument 152. However, there is no problem if separate measuring instruments are provided and connected. The measuring device 152 is controlled by the measuring device control / arithmetic unit 153 and is connected to a higher-order system control unit 154. The system control unit 154 determines via the control interface 155 whether or not the wafer processing has been completed. The measurement port 140B converts the temperature of the component to be heated 161 heated by the optical heating device 160 into radiant heat to measure the temperature of the component to be heated in order to keep the temperature of the component inside the processing chamber constant. Adjust the output of the heating device. Thus, when the heated structure is heated by the plasma and reaches a certain temperature or higher, the output of the optical heating device 160 is adjusted by the heating control device 162 to control the temperature and the output of the heated structure pair 161. By doing so, the life of the optical heating device 160 is extended.
[0028]
Next, the detailed structure of the measurement ports 140A and 140B will be described with reference to FIGS.
[0029]
FIG. 2 is an enlarged cross-sectional view of the measurement port 140A attached to the processing chamber side wall 102 in the embodiment of FIG.
[0030]
A measurement window 143 is attached to an end of the short pipe 142A attached to the processing chamber side wall 102, and an optical transmission means 151 such as an optical fiber or a lens is provided on an end surface of the measurement window 143 on the atmosphere side. Has been. Then, the direct light 145 from the plasma P passes through the short pipe 142A, passes through the measurement window 143, reaches the optical transmission means 151, and is further transmitted to the measuring device 152 for measurement as shown by the optical path indicated by the broken line. Is done.
[0031]
At this time, the ions and radicals generated in the plasma move in vacuum over the distance of the mean free path determined by the pressure and molecular weight, and if the energy level of the colliding wall is high, they strike the colliding ions. The moved ions travel the length of the mean free path. While repeating this process, it reaches the measurement window 143, contacts the atmosphere side, accumulates on the surface of the low-temperature measurement window 143, and reduces the light transmittance of the measurement window 143, thereby detecting the end of the wafer processing. The accuracy of measuring the light emission amount of the generated plasma P decreases, and it is difficult to reliably determine the end of etching. In the present invention, the length of the short tube is set to be equal to or longer than the mean free path length of the gas component generated in the plasma, and the wall surface of the short tube 142A is in contact with the atmosphere separated from the plasma. It is difficult for ions and radicals that have entered from the facing opening to reach the measurement window 143 directly.
[0032]
In addition, ions and radicals that have collided with the low-temperature wall of the short tube 142A absorb their energy, and do not jump out of the wall again.
[0033]
As described above, it becomes difficult for ions and radicals generated in the plasma to reach the measurement window 143, and the measurement window 143 can be kept in a clean state forever, and the light transmittance does not occur. It is possible to maintain the initial measurement accuracy for a long time.
[0034]
Although the principle of FIG. 3 is the same as that of FIG. 2, if the diameter of the short tube is reduced in order to prevent the penetration of ions and radicals into the short tube, the amount of light required for determination does not reach the measurement window 143 and the light transmission If there is a possibility that the sensitivity of the means may be reduced, a short-diameter tube 142B having a larger diameter on the side in contact with the plasma P is provided on the side wall 102, and a sufficient amount of light is secured near the measurement window 143. It is an example. Also in this case, it is desirable that the length of the short pipe be equal to or longer than the mean free path length of the processing gas.
[0035]
In the example of FIG. 4, when there is not enough space around the processing chamber and the length of the short pipe cannot secure the average free path length of the processing gas, ions and radicals 146 that jump into the short pipe 142 </ b> C enter the measurement window 143. This is an example in which a baffle 147 is provided on the inner surface of the short pipe 142C so as not to reach. The ions and radicals that have jumped from the opening surface of the short pipe 142 </ b> C collide with the baffle 147 before reaching the measurement window 143, so that it is difficult to reach the measurement window 143. In this case, the smaller the diameter of the short pipe 142C, the smaller the amount of ions and radicals 146 penetrated, and the smaller the diameter of the short pipe 142C. Therefore, the smaller the diameter of the short pipe 142C, the smaller the diameter of the short pipe 142C. It is important to keep it small. If there is a problem with reducing the diameter, a short tube structure combining FIG. 2 and FIG. 3 can be used.
[0036]
As a comprehensive result of these effects, the measurement window 143 has a long term because the reaction product does not adhere to the end face or the surface does not come off, and the light transmission characteristic is kept constant even after repeated discharge. Stable measurement over a wide range.
[0037]
5 to 7 illustrate the detailed structure of the measurement window when measuring the temperature of the heated structural member 161 in the vacuum processing chamber 100.
[0038]
FIG. 6 shows a state where the present invention is not applied. As the temperature of the heated structural member 161 in the vacuum processing chamber heated by the optical system heating device 160 increases, the radiant heat increases. The radiant heat is measured by the light transmission means 151 through the light transmission body 141 and transmitted as an electric signal to the control interface 155 via the measuring instrument 152.
[0039]
At this time, the light from the optical system heating device 160 and the light emission of the plasma enter the side surface of the photoconductor 141 as stray light 163, and are measured as a heat signal by the light transmission means 151. Therefore, the optical transmission means 151 erroneously detects a temperature higher than the actual temperature of the heated structural member 161 and performs control to lower the output of the optical system heating device 160 in order to maintain the heated structural member 161 at a constant temperature. Do. For this reason, the temperature of the structural material 161 to be heated is maintained at a temperature lower than the set temperature, which is a factor that hinders the performance of the apparatus.
[0040]
FIG. 6 shows an embodiment for solving this problem. In order to prevent the light of the optical system heating device 160 and the stray light 163 of the light emission of the plasma from entering from the side surface of the optical transmission body 141, a reflective material 164 is coated on the side surface of the optical transmission body 141 to prevent the penetration of the stray light 163. This is an example. By preventing the stray light 163 from entering the side surface of the light transmitting body 141, only the radiant heat from the heated structural member 161 alone can be measured in the light transmitting means 151, and the measuring accuracy can be improved.
[0041]
FIG. 7 shows an example in which a sleeve 165 having a wavelength at which the spectrum of the stray light 163 from the light of the optical system heating device 160 or the plasma light is not transmitted is provided on the side surface of the optical transmitter 141 instead of the reflecting member 164. The effects are the same as those described with reference to FIG.
[0042]
By the way, in the above-described embodiments, the optical transmission member 141 is made of transparent quartz. However, this is merely an example. Although the spectrum of the radiant heat is transmitted, the light of the optical system heating device 160 and the stray light of the plasma light are transmitted. If a material that cannot transmit the spectrum of the light 163 can be used for the optical transmitter 141, the stray light 163 of the light of the optical system heating device 160 or the plasma light can be provided without providing the reflector 164 and the sleeve 165 described in FIGS. It is also possible to prevent intrusion.
[0043]
In each of the above-described embodiments, the magnetic field is applied to the UHF band electromagnetic wave radiation discharge type plasma processing apparatus. However, other than the UHF band, the radiated electromagnetic wave is, for example, a microwave of 2.45 GHz, Alternatively, a VHF band from several tens of MHz to about 300 MHz may be used. The magnetic field strength is described as being 160 gauss, which is the electron cyclotron resonance magnetic field strength for 450 MHz. However, it is not always necessary to use a resonance magnetic field, and a stronger magnetic field or a weak magnetic field of about several tens gauss or more is used. May be. Further, it goes without saying that the present invention can be similarly applied not only to the electromagnetic radiation discharge method but also to a capacitively coupled parallel plate plasma processing apparatus, a magnetron type plasma processing apparatus, or an inductively coupled plasma processing apparatus.
[0044]
【The invention's effect】
As described above, according to the present invention, the light emission state of the plasma and the temperature of the structural material to be heated in the processing chamber can be accurately and stably maintained over a long term even at a mass production level by the optical transmission means through the measurement window provided on the atmosphere side. Can measure well. As a result, it becomes possible to detect the end point of the etching process and to control the output of the atmosphere side heating source, so that a more advanced process control method can be provided, and the reproducibility and stability of the process can be improved. It is possible to provide a plasma processing apparatus that can contribute to an improvement in productivity.
[Brief description of the drawings]
FIG. 1 is a schematic sectional view of a plasma etching apparatus according to an embodiment of the present invention.
FIG. 2 is a view showing a structure of a through-hole branch pipe portion which is a main part of the present invention.
FIG. 3 is a view showing a structure of a through-hole branch pipe part having a large diameter, which is a main part of the present invention.
FIG. 4 is a view showing a structure of a through-hole branch pipe portion provided with a baffle and having a reduced length, which is a main part of the present invention.
FIG. 5 is a diagram showing a configuration example of a conventional measurement window.
FIG. 6 is a diagram showing an embodiment of a measurement window according to the present invention.
FIG. 7 is a view showing another embodiment of the measurement window in the present invention.
[Explanation of symbols]
100 processing chamber, 101 magnetic field forming means, 102 side wall of processing chamber, 103 vacuum chamber, 104 evacuation system, 105 pressure control means, 110 antenna
111: disk-shaped conductor, 112: dielectric, 113: dielectric ring,
114 ... housing, 115 ... plate, 116 ... gas supply means,
130: lower electrode, 131: electrostatic chucking device, 134: bias power supply,
135: Matching circuit / filter system, 140A / B: Measurement port,
141: optical transmission body, 142A / B / C: short tube, 143: measurement window,
145: plasma direct light, 146: ion / radical, 147 ... baffle,
151A / B: optical transmission means, 152: measuring instrument, 153: measuring instrument control / calculation means, 154: system control means, 154: control interface,
160: optical heating device, 161: heated structural material, 162: heating control device
163: stray light, 164: reflective material, 165: sleeve, P: plasma, W: sample

Claims (7)

真空処理室内に処理ガスを供給して、プラズマ発生装置によりプラズマを発生させ、当該プラズマにより試料台上に載置された試料をプラズマ処理するプラズマ処理装置において、
装置内で発生するプラズマの発光状態を計測するために、プラズマと接する構造体に少なくとも1個以上の分岐管を設け、分岐管の端部に真空を形成するための計測窓を設け、この計測窓の大気側に光伝送体の光学センサーを端面がほぼ接するように設置し、プラズマ計測中の計測窓の汚染を防止することにより、長期間、安定してプラズマ計測を可能とした分岐管の端部に観測窓を設けることを特徴とするプラズマ処理装置。
In a plasma processing apparatus that supplies a processing gas into a vacuum processing chamber, generates plasma by a plasma generator, and performs plasma processing on a sample placed on a sample stage by the plasma,
In order to measure the light emission state of the plasma generated in the apparatus, at least one or more branch pipes are provided in a structure in contact with the plasma, and a measurement window for forming a vacuum is provided at an end of the branch pipe. An optical sensor of an optical transmitter is installed on the atmosphere side of the window so that the end face is almost in contact with the window, and contamination of the measurement window during plasma measurement is prevented. A plasma processing apparatus characterized in that an observation window is provided at an end.
請求項1記載のプラズマ処理装置において、大気側に設けた光学式加熱源により真空中の処理室内構成部品を任意の温度に加温する機構と、加熱された処理室内構成部品からの放射熱を測定し温度に換算することにより処理室内構成部品の温度を計測する手段を備え、光学式加熱源からの迷光及び処理室内のプラズマ発光による光の進入を防止し、これら処理室内構成部品以外からの放射熱の影響を排除することにより、温度測定結果の精度を向上させることが可能な計測窓を設けたことを特徴とするプラズマ処理装置。2. The plasma processing apparatus according to claim 1, wherein a mechanism for heating a component in the processing chamber in a vacuum to an arbitrary temperature by an optical heating source provided on the atmosphere side, and radiant heat from the component in the processing chamber heated. A means for measuring the temperature of the processing chamber components by measuring and converting the temperature to prevent stray light from the optical heating source and light from plasma emission in the processing chamber from entering; A plasma processing apparatus having a measurement window capable of improving the accuracy of a temperature measurement result by eliminating the influence of radiant heat. 請求項1記載のプラズマ処理装置において、前記分岐管の長さを処理ガスの平均自由行程長以上としたことを特徴とするプラズマ処理装置。2. The plasma processing apparatus according to claim 1, wherein the length of the branch pipe is equal to or longer than the mean free path length of the processing gas. 請求項1記載のプラズマ処理装置において、真空処理室内に取り付く側の短管の径より、計測窓が取り付く側の短管の径を小さくすることにより、光学センサーへの光の入射量を減衰させることなく、計測窓が汚れない分岐管を取り付けたことを特徴とするプラズマ処理装置。2. The plasma processing apparatus according to claim 1, wherein the diameter of the short pipe on the side where the measurement window is mounted is made smaller than the diameter of the short pipe on the side mounted in the vacuum processing chamber, thereby attenuating the amount of light incident on the optical sensor. A plasma processing apparatus characterized in that a branch pipe with a clean measurement window is attached without any trouble. 請求項1記載ののプラズマ処理装置において、真空処理室内に取り付く短管内面に邪魔板を設置し、短管の長さを処理ガスの平均自由行程長より短くできる、分岐管を取り付けたことを特徴とするプラズマ処理装置。2. The plasma processing apparatus according to claim 1, wherein a baffle plate is installed on an inner surface of the short tube attached to the vacuum processing chamber, and a branch tube is attached, the length of the short tube being shorter than the average free path length of the processing gas. Characteristic plasma processing equipment. 請求項2記載のプラズマ処理装置において、前記計測窓への光の導入経路の周囲を光学式加熱源やプラズマからの波長を透過させない材料でコーティングし、被測定物からの放射熱のみを取り込み、被測定物以外からの光の進入を防止することを特徴とするプラズマ処理装置。In the plasma processing apparatus according to claim 2, the periphery of the light introduction path to the measurement window is coated with a material that does not transmit the wavelength from the optical heating source or the plasma, and captures only the radiant heat from the measured object, A plasma processing apparatus for preventing light from entering from an object other than an object to be measured. 請求項2記載のプラズマ処理装置において、前記計測窓への光の導入経路の周囲に光学式加熱源やプラズマからの波長を透過させない材料で製作されたスリーブを設置することにより、被測定物からの放射熱のみを取り込み、被測定物以外からの光の進入を防止することを特徴とするプラズマ処理装置。The plasma processing apparatus according to claim 2, wherein a sleeve made of a material that does not transmit a wavelength from an optical heating source or plasma is provided around a light introduction path to the measurement window, so that the object to be measured can be removed. A plasma processing apparatus, which takes in only radiant heat of an object and prevents light from entering from an object other than an object to be measured.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008124460A (en) * 2006-10-31 2008-05-29 Applied Materials Inc Plasma for resist removal and facet control of feature under resist
US20120111269A1 (en) * 2010-11-05 2012-05-10 Chen-Chung Du View port device for plasma process and process observation device of plasma apparatus
KR101969422B1 (en) * 2017-10-31 2019-04-16 한국기초과학지원연구원 Plasma Process Monitoring Apparatus

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008124460A (en) * 2006-10-31 2008-05-29 Applied Materials Inc Plasma for resist removal and facet control of feature under resist
US20120111269A1 (en) * 2010-11-05 2012-05-10 Chen-Chung Du View port device for plasma process and process observation device of plasma apparatus
KR101969422B1 (en) * 2017-10-31 2019-04-16 한국기초과학지원연구원 Plasma Process Monitoring Apparatus

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