JP2003511535A5 - - Google Patents
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- JP2003511535A5 JP2003511535A5 JP2001530405A JP2001530405A JP2003511535A5 JP 2003511535 A5 JP2003511535 A5 JP 2003511535A5 JP 2001530405 A JP2001530405 A JP 2001530405A JP 2001530405 A JP2001530405 A JP 2001530405A JP 2003511535 A5 JP2003511535 A5 JP 2003511535A5
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- Prior art keywords
- filler
- surface area
- wet slip
- composition
- bet surface
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- 239000000203 mixture Substances 0.000 description 39
- 229920001971 elastomer Polymers 0.000 description 31
- 239000000806 elastomer Substances 0.000 description 31
- 239000000945 filler Substances 0.000 description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- 238000000034 method Methods 0.000 description 12
- 239000000377 silicon dioxide Substances 0.000 description 11
- 239000006229 carbon black Substances 0.000 description 8
- 230000001737 promoting effect Effects 0.000 description 6
- 239000012763 reinforcing filler Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
Description
【特許請求の範囲】
【請求項１】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）モース硬さが４．５超且つＢＥＴ表面積が１００ｍ２／ｇ未満の、少なくとも１種の充填材、
（ｃ）ＢＥＴ表面積が８０ｍ２／ｇ又はそれよりも大きい、少なくとも１種の充填材、及び
（ｄ）表面積が１００ｍ２／ｇ未満の、少なくとも１種の充填材、
を含有し、前記充填材（ｂ）、（ｃ）及び（ｄ）が互いに異なっている、組成物。
【請求項２】 前記充填材（ｂ）、（ｃ）及び（ｄ）が充填材のタイプに関して異なっている、請求項１に記載の組成物。
【請求項３】 前記充填材（ｂ）、（ｃ）及び（ｄ）が表面積に関して異なっている、請求項１に記載の組成物。
【請求項４】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）モース硬さが４．５超且つＢＥＴ表面積が１００ｍ２／ｇ未満の、非アルミニウム含有充填材である少なくとも１種の充填材、及び
（ｃ）ＢＥＴ表面積が少なくとも８０ｍ２／ｇの、少なくともシリカを含む少なくとも１種の充填材、
を含有する、組成物。
【請求項５】 前記（ｂ）の充填材がＳｉＣである、請求項４に記載の組成物。
【請求項６】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）モース硬さが４．５超且つＢＥＴ表面積が１００ｍ２／ｇ未満の、少なくとも１種の充填材、並びに
（ｃ）（１）ケイ素含有種相及び炭素相を有する結合体、（２）金属含有種相及び炭素相を有する結合体、（３）少なくとも１つの有機基が結合した炭素生成物、若しくは（４）シリカをコーティングされたカーボンブラック、又はそれらの組み合わせから選択される、少なくとも１種の充填材、
を含有する、組成物。
【請求項７】 前記（ｂ）の充填材がシリカである、請求項１，４，６のいずれかに記載の組成物。
【請求項８】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）ＢＥＴ表面積が４０ｍ２／ｇ未満の、少なくとも１つのタイプのシリカ、及び
（ｃ）ＢＥＴ表面積が少なくとも８０ｍ２／ｇの、少なくとも１種の充填材、
を含有する、組成物。
【請求項９】 前記（ｃ）の充填材がカーボンブラックである、請求項１，４，８のいずれかに記載の組成物。
【請求項１０】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）モース硬さが４．５超且つＢＥＴ表面積が１００ｍ２／ｇ未満の、アルミニウム及びシリカを含有しない少なくとも１種の充填材、並びに
（ｃ）ＢＥＴ表面積が少なくとも８０ｍ２／ｇの、少なくとも１種の充填材、
を含有する、組成物。
【請求項１１】 前記（ｂ）の充填材がＳｉＣであり、前記（ｃ）の充填材がカーボンブラック若しくはシリカ又はそれら両方である、請求項１０に記載の組成物。
【請求項１２】 前記強化充填材が、カーボンブラック、又は５：９５〜９５：５の重量比のカーボンブラックとシリカの配合を含む、請求項１に記載の組成物。
【請求項１３】 前記（ｂ）の充填材の大きさが１０〜６０ｍ２／ｇである、請求項４に記載の組成物。
【請求項１４】 前記（ｃ）の充填材が、カーボンブラック、又は５：９５〜９５：５の重量比のカーボンブラックとシリカの配合を含む、請求項４に記載の組成物。
【請求項１５】 請求項１又は４に記載の組成物を含有するタイヤ部品。
【請求項１６】 前記エラストマー成分が、ブタジエンモノマー、イソプレンモノマー、クロロプレンモノマー、それらの組み合わせ、又はそれらの反応生成物から選択される少なくとも１種のモノマーを含有する、請求項１又は４に記載の組成物。
【請求項１７】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）モース硬さが４．５超且つＢＥＴ表面積が１００ｍ２／ｇ未満の、少なくとも１種の濡れすべり促進充填材、
（ｃ）ＢＥＴ表面積が８０ｍ２／ｇ又はそれよりも大きい、少なくとも１種の強化充填材、及び
（ｄ）表面積が１００ｍ２／ｇ未満の、少なくとも１種の充填材、
を組み合わせて、濡れすべり抵抗性エラストマー組成物を作ることを含み、前記充填材（ｂ）、（ｃ）及び（ｄ）が互いに異なっている、エラストマー組成物の濡れすべり抵抗性を改良する方法であって、ここで前記濡れすべり促進充填材を伴わない前記エラストマー組成物と比較して、前記濡れすべり抵抗性エラストマー組成物の濡れすべり抵抗性が増加している、エラストマー組成物の濡れすべり抵抗性を改良する方法。
【請求項１８】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）モース硬さが４．５超且つＢＥＴ表面積が１００ｍ２／ｇ未満の、非アルミニウム含有充填材である少なくとも１種の濡れすべり促進充填材、及び
（ｃ）ＢＥＴ表面積が少なくとも８０ｍ２／ｇの、少なくともシリカを含む少なくとも１種の強化充填材、
を共に組み合わせることを含む、エラストマー組成物の濡れすべり抵抗性を改良する方法であって、ここで前記濡れすべり促進充填材を伴わない前記エラストマー組成物と比較して、前記濡れすべり抵抗性エラストマー組成物の濡れすべり抵抗性が増加している、エラストマー組成物の濡れすべり抵抗性を改良する方法。
【請求項１９】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）モース硬さが４．５超且つＢＥＴ表面積が１００ｍ２／ｇ未満の、少なくとも１種の濡れすべり促進充填材、並びに
（ｃ）（１）ケイ素含有種相及び炭素相を有する結合体、（２）金属含有種相及び炭素相を有する結合体、（３）少なくとも１つの有機基が結合した炭素生成物、若しくは（４）シリカをコーティングされたカーボンブラック、又はそれらの組み合わせから選択される、少なくとも１種の充填材、
を共に組み合わせることを含む、エラストマー組成物の濡れすべり抵抗性を改良する方法であって、ここで前記濡れすべり促進充填材を伴わない前記エラストマー組成物と比較して、前記濡れすべり抵抗性エラストマー組成物の濡れすべり抵抗性が増加している、エラストマー組成物の濡れすべり抵抗性を改良する方法。
【請求項２０】 （ａ）少なくとも１種のエラストマー成分、
（ｂ）ＢＥＴ表面積が４０ｍ２／ｇ未満の、少なくとも１つのタイプのシリカ、及び
（ｃ）ＢＥＴ表面積が少なくとも８０ｍ２／ｇの、少なくとも１種の強化充填材、
を共に組み合わせることを含む、エラストマー組成物の濡れすべり抵抗性を改良する方法であって、ここで前記強化充填材を伴わない前記エラストマー組成物と比較して、前記濡れすべり抵抗性エラストマー組成物の濡れすべり抵抗性が増加している、エラストマー組成物の濡れすべり抵抗性を改良する方法。
【請求項２１】 前記濡れすべり抵抗性が、前記成分を伴わないエラストマー組成物と比較して、少なくとも２％大きい、請求項１７，１９，２０のいずれかに記載の方法。
【請求項２２】 前記濡れすべり抵抗性が、前記成分を伴わないエラストマー組成物と比較して、少なくとも１０％大きい、請求項１７，１９，２０のいずれかに記載の方法。
【請求項２３】 前記濡れすべり抵抗性エラストマー組成物を製造品に成形すること、及びその後で前記濡れすべり抵抗性エラストマー組成物を加硫することを更に含む、請求項１７〜２０のいずれかに記載の方法。
【請求項２４】 前記成形工程が、前記濡れすべり抵抗性エラストマー組成物をタイヤ部品に成形することを含む、請求項１７〜２０のいずれかに記載の方法。
[Claims]
(A) at least one elastomer component,
(B) Mohs hardness is 4 . At least one filler having a BET surface area of more than 5 and less than 100 m 2 / g;
(C) at least one filler having a BET surface area of 80 m 2 / g or greater; and (d) at least one filler having a surface area of less than 100 m 2 / g;
And wherein the fillers (b), (c) and (d) are different from each other.
2. The composition according to claim 1, wherein the fillers (b), (c) and (d) are different with respect to the type of filler.
3. The composition according to claim 1, wherein said fillers (b), (c) and (d) differ in surface area.
(4) at least one elastomer component,
(B) Mohs hardness is 4 . 5 Ultra and BET surface area of less than 1 00m 2 / g, at least one filler material which is a non-aluminum-containing filler, and (c) a BET surface area of at least 8 0 m 2 / g, at least one comprising at least silica Filler,
A composition comprising:
5. The composition according to claim 4 , wherein the filler of (b) is SiC.
6. (a) at least one elastomer component,
(B) Mohs hardness is 4 . At least one filler having a BET surface area of more than 5 and a BET surface area of less than 100 m 2 / g; At least one filler selected from (3) a carbon product to which at least one organic group is bonded, or (4) a silica-coated carbon black, or a combination thereof.
A composition comprising:
7. A filler of the (b) is silica, the composition according to any of claims 1,4,6.
8. (a) at least one elastomer component,
(B) at least one type of silica having a BET surface area of less than 40 m 2 / g; and (c) at least one filler having a BET surface area of at least 80 m 2 / g.
A composition comprising:
9. Fillers said (c) is carbon black composition according to any one of claims 1, 4, 8.
10. (a) at least one elastomer component,
(B) Mohs hardness is 4 . 5 Ultra and BET surface area of less than 1 00m 2 / g, at least one filler containing no aluminum and silica, and (c) a BET surface area of at least 8 0 m 2 / g, at least one filler,
A composition comprising:
11. A filler of the (b) is SiC, the filling material is both carbon black or silica, or their said (c), A composition according to claim 10.
12. The reinforcing filler is carbon black, or 5:95 10 5: including the formulation of carbon black and silica in a weight ratio of 5 A composition according to claim 1.
13. The composition according to claim 4 , wherein the size of the filler of (b) is 10 to 60 m 2 / g.
14. Fillers of said (c) is carbon black, or 5:95 10 5: including the formulation of carbon black and silica in a weight ratio of 5 A composition according to claim 4.
15. A tire component containing the composition according to claim 1 .
16. The elastomer component, butadiene monomer, isoprene monomer, chloroprene monomer, combinations thereof, or at least one monomer selected from the reaction products thereof, as claimed in claim 1 or 4 Composition.
17. (a) at least one elastomer component,
(B) Mohs hardness is 4 . At least one wet slip promoting filler having a BET surface area of more than 5 and a BET surface area of less than 100 m 2 / g;
(C) at least one reinforcing filler having a BET surface area of 80 m 2 / g or greater; and (d) at least one filler having a surface area of less than 100 m 2 / g;
Combining the fillers to form a wet slip resistant elastomer composition, wherein the fillers (b), (c) and (d) are different from each other, in a method for improving the wet slip resistance of an elastomer composition. And wherein the wet slip resistance of the wet slip resistant elastomer composition is increased compared to the elastomer composition without the wet slip promoting filler, the wet slip resistance of the elastomer composition How to improve.
18. (a) at least one elastomer component,
(B) Mohs hardness is 4 . 5 Ultra and BET surface area of less than 1 00m 2 / g, at least one wet slip promoting filler is a non-aluminum-containing filler, and (c) a BET surface area of at least 8 0 m 2 / g, containing at least silica At least one reinforcing filler,
A method for improving the wet slip resistance of an elastomer composition, wherein the wet slip resistant elastomer composition is compared with the elastomer composition without the wet slip promoting filler. A method for improving the wet slip resistance of an elastomer composition, wherein the wet slip resistance of the product is increased.
(A) at least one elastomer component,
(B) Mohs hardness is 4 . At least one wet slip promoting filler having a BET surface area of more than 5 and a BET surface area of less than 100 m 2 / g, and (c) (1) a binder having a silicon-containing species phase and a carbon phase, and (2) a metal-containing species phase And at least one filler selected from (3) a carbon product to which at least one organic group is bonded, or (4) silica-coated carbon black, or a combination thereof. ,
A method for improving the wet slip resistance of an elastomer composition, wherein the wet slip resistant elastomer composition is compared with the elastomer composition without the wet slip promoting filler. A method for improving the wet slip resistance of an elastomer composition, wherein the wet slip resistance of the product is increased.
20. (a) at least one elastomer component,
(B) at least one type of silica having a BET surface area of less than 40 m 2 / g; and (c) at least one reinforcing filler having a BET surface area of at least 80 m 2 / g.
A method for improving the wet slip resistance of an elastomer composition, comprising combining together, wherein the wet slip resistant elastomer composition is compared to the elastomer composition without the reinforcing filler. A method for improving the wet slip resistance of an elastomer composition, wherein the wet slip resistance is increased.
21. The method according to claim 17, wherein the wet slip resistance is at least 2 % greater than an elastomer composition without the component.
22. The wet slip resistance, as compared to the elastomeric composition without the component, at least 1 0% greater, The method according to any one of claims 17, 19, 20.
23. The method of any of claims 17 to 20 , further comprising forming the wet slip resistant elastomer composition into an article of manufacture, and thereafter vulcanizing the wet slip resistant elastomer composition. The described method.
24. The method of any of claims 17 to 20, wherein the forming step comprises forming the wet slip resistant elastomer composition into a tire component.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/415,357 US6469089B2 (en) | 1999-10-08 | 1999-10-08 | Elastomeric compounds with improved wet skid resistance and methods to improve wet skid resistance |
| US09/415,357 | 1999-10-08 | ||
| PCT/US2000/027530 WO2001027192A1 (en) | 1999-10-08 | 2000-10-06 | Elastomeric compounds with improved wet skid resistance and methods to improve wet skid resistance |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012108769A Division JP5443539B2 (en) | 1999-10-08 | 2012-05-10 | Elastomer compounds with improved wet slip resistance and methods for improving wet slip resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2003511535A JP2003511535A (en) | 2003-03-25 |
| JP2003511535A5 true JP2003511535A5 (en) | 2007-10-04 |
Family
ID=23645368
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001530405A Withdrawn JP2003511535A (en) | 1999-10-08 | 2000-10-06 | Elastomeric compounds with improved wet slip resistance and method for improving wet slip resistance |
| JP2012108769A Expired - Lifetime JP5443539B2 (en) | 1999-10-08 | 2012-05-10 | Elastomer compounds with improved wet slip resistance and methods for improving wet slip resistance |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012108769A Expired - Lifetime JP5443539B2 (en) | 1999-10-08 | 2012-05-10 | Elastomer compounds with improved wet slip resistance and methods for improving wet slip resistance |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6469089B2 (en) |
| EP (1) | EP1237999A1 (en) |
| JP (2) | JP2003511535A (en) |
| AU (1) | AU7754800A (en) |
| WO (1) | WO2001027192A1 (en) |
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| EP1360227B1 (en) * | 2001-01-02 | 2007-05-23 | Société de Technologie Michelin | Rubber composition made with diene elastomer and a reinforcing silicon carbide |
| US6908961B2 (en) * | 2001-12-07 | 2005-06-21 | Cabot Corporation | Elastomer composites, elastomer blends and methods |
| FR2841560B1 (en) * | 2002-07-01 | 2006-02-03 | Michelin Soc Tech | RUBBER COMPOSITION BASED ON DIENE ELASTOMER AND REINFORCING SILICON NITRIDE |
| JP4628670B2 (en) * | 2003-12-24 | 2011-02-09 | 住友ゴム工業株式会社 | Rubber composition |
| WO2006060896A1 (en) * | 2004-12-08 | 2006-06-15 | Lanxess Inc. | Peroxide vulcanizable butyl compositions useful for rubber articles |
| JP4566888B2 (en) * | 2005-01-28 | 2010-10-20 | 住友ゴム工業株式会社 | Rubber composition and tire having tread using the same |
| US7368490B2 (en) * | 2005-11-28 | 2008-05-06 | Momentive Performance Materials Inc. | Rubber compositions comprising unsaturated imidoalkoxysilanes |
| DE102007019942A1 (en) | 2007-04-27 | 2008-11-06 | Continental Aktiengesellschaft | Rubber compound with improved rebound resilience |
| US9074073B2 (en) * | 2009-12-07 | 2015-07-07 | The Goodyear Tire & Rubber Company | Rubber composition containing silica reinforcement and functionalized crosslinks and products with component thereof |
| EP3705538B1 (en) | 2010-12-14 | 2021-04-28 | Cabot Corporation | Filler-polymer compositions comprising silicone polymer and a two-phase filler having a silica phase and a carbon phase |
| JP6173556B2 (en) | 2013-03-13 | 2017-08-02 | キャボット コーポレイションＣａｂｏｔ Ｃｏｒｐｏｒａｔｉｏｎ | COATING COMPRISING FILLER-POLYMER COMPOSITION HAVING COMBINED LOW DIELECTRICITY, HIGH RESISTOR AND OPTICAL DENSITY CHARACTERISTICS, AND CONTROLLED ELECTRICAL RESISTOR, DEVICE PRODUCED THEREFROM, AND METHOD FOR PRODUCING THE SAME |
| US20180346621A1 (en) * | 2015-05-26 | 2018-12-06 | Basell Poliolefine Italia S.R.L. | Polyolefin gaskets for closures |
| US20240042800A1 (en) * | 2020-12-07 | 2024-02-08 | Eneos Materials Corporation | Polymer composition, cross-linked body, and tire |
| WO2023230251A1 (en) | 2022-05-27 | 2023-11-30 | Cabot Corporation | Aerogel composition for thermal insulation |
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-
1999
- 1999-10-08 US US09/415,357 patent/US6469089B2/en not_active Expired - Lifetime
-
2000
- 2000-10-06 AU AU77548/00A patent/AU7754800A/en not_active Abandoned
- 2000-10-06 EP EP00967330A patent/EP1237999A1/en not_active Withdrawn
- 2000-10-06 JP JP2001530405A patent/JP2003511535A/en not_active Withdrawn
- 2000-10-06 WO PCT/US2000/027530 patent/WO2001027192A1/en not_active Application Discontinuation
-
2012
- 2012-05-10 JP JP2012108769A patent/JP5443539B2/en not_active Expired - Lifetime
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