JP2003305468A - Alkaline ion water preparing unit - Google Patents

Alkaline ion water preparing unit

Info

Publication number
JP2003305468A
JP2003305468A JP2002112992A JP2002112992A JP2003305468A JP 2003305468 A JP2003305468 A JP 2003305468A JP 2002112992 A JP2002112992 A JP 2002112992A JP 2002112992 A JP2002112992 A JP 2002112992A JP 2003305468 A JP2003305468 A JP 2003305468A
Authority
JP
Japan
Prior art keywords
electrolysis
output
voltage
water
control unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2002112992A
Other languages
Japanese (ja)
Other versions
JP3960107B2 (en
Inventor
Koji Noguchi
幸治 野口
Masahiro Ono
昌浩 大野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP2002112992A priority Critical patent/JP3960107B2/en
Publication of JP2003305468A publication Critical patent/JP2003305468A/en
Application granted granted Critical
Publication of JP3960107B2 publication Critical patent/JP3960107B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

<P>PROBLEM TO BE SOLVED: To provide an alkaline ion water preparing unit capable of rapidly coping with the change of a water flow rate or water quality and supplying ionized water having stable pH value. <P>SOLUTION: The alkaline ion water preparing unit prepares alkaline ion water and acidic ion water by electrolyzing feed water and is constituted so as to output a numerical code from a control part 19 to an electrolysis control part 21 as an energizing output to an electrolytic cell 7 and to convert the numerical code to a voltage level corresponding to the numerical code by using a D/A converter circuit in the electrolysis control part 21 to control the energizing output to the electrolytic cell 7. <P>COPYRIGHT: (C)2004,JPO

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、水道水等の原水を
電気分解して、飲料用や医療用として利用するアルカリ
イオン水および化粧水、殺菌洗浄水等として利用する酸
性イオン水を生成するアルカリイオン整水器に関するも
のである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention electrolyzes raw water such as tap water to produce alkaline ionized water used for beverages and medical purposes and acidic ionized water used as lotion, sterilizing and washing water, and the like. The present invention relates to an alkaline ionized water device.

【0002】[0002]

【従来の技術】近年、連続電解方式のイオン水生成器と
して、アルカリイオン整水器が普及している。このアル
カリイオン整水器は、電解槽内で水道水等を電気分解し
て、陽極側に酸性イオン水を生成し、陰極側にアルカリ
イオン水を生成するものである。
2. Description of the Related Art In recent years, an alkaline ionized water conditioner has become popular as a continuous electrolysis type ionized water generator. This alkaline ionized water device electrolyzes tap water or the like in an electrolytic cell to produce acidic ionized water on the anode side and alkaline ionized water on the cathode side.

【0003】以下、従来の連続電解方式のアルカリイオ
ン整水器について説明する。
A conventional continuous electrolysis type alkaline ionized water conditioner will be described below.

【0004】図3は、従来のアルカリイオン整水器の概
略構成図である。
FIG. 3 is a schematic configuration diagram of a conventional alkaline ionized water device.

【0005】図3に示すように従来の連続電解方式のア
ルカリイオン整水器は、水道水等の原水管1と、水栓2
と、水栓2を介して原水管1と接続されたアルカリイオ
ン整水器3と、原水を浄化する浄水部4と、通水流量を
後述の制御部に知らせる流量センサ5と、カルシウム等
のカルシウムイオンを原水中に付与し導電率を高めるカ
ルシウム供給部6と、流量センサ5およびカルシウム供
給部6を経由してきた水を電気分解する電解槽7と、電
解槽7を2分し電極室を形成する隔膜8と、隔膜8で2
分されて形成された各電極室に配置された電極板9、1
0と、電極板10側の水を通水する通水管11と、電極
板9側の水を吐水する吐水管12を備え、さらに商用電
源から電気を供給する電源投入用プラグ13と、商用電
源を整流して電解および制御に必要な直流電源にする電
源部14と、電解槽7に電力出力を行う電解出力部15
と、電解出力時の電流値および電圧値を検知する電解電
流検出回路16および電解電圧検出回路17と、使用者
が電解の強さおよび酸性水またはアルカリイオン水の選
択を行う操作表示部18と、操作表示部18の設定にも
とづき、電解電流検出回路16および電解電圧検出回路
17の値を監視しながら、電解出力の制御を行う制御部
19を備えて構成されている。
As shown in FIG. 3, a conventional continuous ionization type alkaline ionized water conditioner comprises a raw water pipe 1 for tap water and a faucet 2.
, An alkaline ionized water conditioner 3 connected to the raw water pipe 1 via the faucet 2, a water purification unit 4 for purifying raw water, a flow rate sensor 5 for notifying a control unit of a water flow rate to be described later, calcium, etc. A calcium supply unit 6 that adds calcium ions to the raw water to increase conductivity, an electrolysis tank 7 that electrolyzes the water that has passed through the flow rate sensor 5 and the calcium supply unit 6, and the electrolysis tank 7 is divided into two parts to form an electrode chamber. The diaphragm 8 to be formed and the diaphragm 8
Electrode plates 9 and 1 arranged in each of the divided electrode chambers
0, a water passage pipe 11 for passing water on the electrode plate 10 side, a water discharge pipe 12 for discharging water on the electrode plate 9 side, and a power supply plug 13 for supplying electricity from a commercial power source, and a commercial power source Power source section 14 for rectifying the electric current to generate a direct current power source required for electrolysis and control, and an electrolytic output section 15 for outputting electric power to the electrolytic cell 7.
An electrolysis current detection circuit 16 and an electrolysis voltage detection circuit 17 for detecting a current value and a voltage value at the time of electrolysis output, and an operation display section 18 for the user to select the electrolysis strength and acidic water or alkaline ionized water. A control unit 19 for controlling the electrolysis output while monitoring the values of the electrolysis current detection circuit 16 and the electrolysis voltage detection circuit 17 based on the setting of the operation display unit 18 is configured.

【0006】次に以上のように構成された従来の連続電
解方式のアルカリイオン整水器について、アルカリイオ
ン水を生成する際の動作を説明する。
Next, the operation of the conventional continuous electrolysis type alkaline ionized water conditioner having the above-described structure for producing alkaline ionized water will be described.

【0007】利用者は、操作表示部18のモード選択ボ
タンを押圧してアルカリイオン水生成モード、または酸
性イオン水生成モードおよび必要とするpH値レンジを
選択し、水栓2を開く。水栓2から通水された原水は、
浄水部4で浄化され、流量センサ5を経てカルシウム供
給部6にてカルシウム等が溶解されて電解容易な水に処
理された後、電解槽7に通水される。
The user presses the mode selection button of the operation display unit 18 to select the alkaline ionized water producing mode or the acidic ionized water producing mode and the required pH value range, and opens the faucet 2. The raw water passed from the tap 2
After being purified by the water purification unit 4, calcium and the like are dissolved by the calcium supply unit 6 through the flow rate sensor 5 to be treated as water that is easy to electrolyze, and then water is passed to the electrolytic bath 7.

【0008】一方、電源投入用プラグ13からは商用電
源であるAC100Vが供給され、電源部14内のトラ
ンスおよび整流回路で電気分解に必要な直流電圧電流を
発生させ、制御部19の指示に従い、電解出力部15を
介して電解槽7の電極板9および10に電気分解に必要
な電力が供給される。このとき相対的にプラス電圧を印
加する電極板を陽極、マイナス電圧を印加する電極板を
陰極とすると、電解槽7内に隔膜8で仕切られた陽極室
と陰極室とが形成される。なお、アルカリイオン水生成
モード時においては電極10が陽極となり、電極板9が
陰極となる。また酸性イオン水生成モード時においては
電極板9が陽極となり、電極板10が陰極となる。
On the other hand, AC100V, which is a commercial power source, is supplied from the power-on plug 13 to generate a DC voltage / current necessary for electrolysis in the transformer and the rectifier circuit in the power supply unit 14, and according to the instruction of the control unit 19, Electric power required for electrolysis is supplied to the electrode plates 9 and 10 of the electrolytic cell 7 through the electrolytic output unit 15. At this time, when the electrode plate to which the positive voltage is applied is the anode and the electrode plate to which the negative voltage is applied is the cathode, the anode chamber and the cathode chamber partitioned by the diaphragm 8 are formed in the electrolytic cell 7. In the alkaline ionized water generation mode, the electrode 10 serves as an anode and the electrode plate 9 serves as a cathode. In the acidic ionized water production mode, the electrode plate 9 serves as an anode and the electrode plate 10 serves as a cathode.

【0009】さて、通水後、制御部19は流量センサ5
の信号を読み取り、信号のレベルが一定量を超えると、
この状態を通水中と判断する。このとき、操作表示部1
8の生成モードおよびpH値レンジ選択ボタンの押圧に
よりすでに電気分解条件が設定されているので、制御部
19は電解槽7にて電気分解を行うため電極板9および
10に所定の電圧が印加されるように電解出力部15に
動作命令の出力をおこなう。これにより、アルカリイオ
ン水生成モード時においては電極板9が陰極、電極板1
0が陽極となり、吐水管12よりアルカリイオン水が吐
水され、酸性イオン水生成モード時においては電極板9
が陽極、電極板10が陰極となり、吐水管12より酸性
イオン水が吐水される。水栓2により原水が止水される
と、流量センサ5の信号レベルが一定量を下回り、制御
部19は止水と判断し、その電解出力部15より電解槽
7の電極板9および10への電圧印加を停止する。
After passing water, the control unit 19 controls the flow rate sensor 5
When you read the signal of, and the signal level exceeds a certain amount,
It is judged that this state is under water. At this time, the operation display unit 1
Since the electrolysis conditions have already been set by pressing the generation mode of 8 and the pressing of the pH value range selection button, the control unit 19 applies a predetermined voltage to the electrode plates 9 and 10 to perform electrolysis in the electrolytic cell 7. As described above, the operation command is output to the electrolytic output unit 15. As a result, in the alkaline ionized water production mode, the electrode plate 9 is the cathode and the electrode plate 1 is
0 becomes the anode, the alkaline ionized water is discharged from the water discharge pipe 12, and the electrode plate 9 is used in the acidic ionized water generation mode.
Serves as an anode and the electrode plate 10 serves as a cathode, and acidic ionized water is discharged from the water discharge pipe 12. When the raw water is stopped by the faucet 2, the signal level of the flow rate sensor 5 falls below a certain amount, and the control unit 19 determines that the water is stopped, and the electrolytic output unit 15 transfers it to the electrode plates 9 and 10 of the electrolytic cell 7. The voltage application of is stopped.

【0010】ここで、アルカリイオン水生成モード時お
よび酸性イオン水生成モード時に、制御部19は電解出
力部15で発生する直流電圧を電解槽7の電極板9およ
び10に供給する。一定の直流電圧を電極板9および1
0に供給した場合、原水の水質および通水流量によっ
て、電極板9および10との間に流れる電流は変化し、
生成されるpH値も変化する。そこで、pH値を一定に
保つために、その電流および水量の変化を電解電流検出
回路17および流量センサ5により検出し、流量センサ
5で検出した信号レベルに応じた電解電流を印加する必
要がある。そのためには、電解槽7の電極板9と10に
供給する直流電圧を一定周期で供給時間を制御する、い
わゆるデューティを可変することで電解制御する方法が
あり、電解電流検出回路17で検出された電解電流値が
利用者の必要とするpH値レンジの電解電流値に到達し
ていなければ、前記デューティを上げることで電解電流
を増加させ、あるいは、電解電流検出回路16で検出さ
れた電解電流値が利用者の必要とするpH値レンジの電
解電流値を超えていれば、前記デューティを下げること
で電解電流を減少させ、利用者の必要とするpH値レン
ジに合わせるように制御部19の指示で制御する。な
お、電圧検知回路17で検知した電圧は、原水の電気導
電率が低く電流が流れにくい場合の各レンジでのpHの
目標値に近づけるための電圧上限値として予め決めてお
き、それ以上電圧を印加しないように制御するためのも
のである。
Here, in the alkaline ionized water producing mode and the acidic ionized water producing mode, the control unit 19 supplies the DC voltage generated in the electrolytic output unit 15 to the electrode plates 9 and 10 of the electrolytic cell 7. A constant DC voltage is applied to the electrode plates 9 and 1
When supplied to 0, the current flowing between the electrode plates 9 and 10 changes depending on the water quality of the raw water and the flow rate of the water.
The pH value produced also changes. Therefore, in order to keep the pH value constant, it is necessary to detect changes in the current and the amount of water by the electrolytic current detection circuit 17 and the flow rate sensor 5, and apply the electrolytic current according to the signal level detected by the flow rate sensor 5. . For that purpose, there is a method of controlling the supply time of the DC voltage supplied to the electrode plates 9 and 10 of the electrolytic cell 7 at a constant cycle, that is, a so-called duty is varied to perform electrolytic control, which is detected by the electrolytic current detection circuit 17. If the electrolysis current value has not reached the electrolysis current value in the pH value range required by the user, the electrolysis current is increased by increasing the duty, or the electrolysis current detected by the electrolysis current detection circuit 16 is increased. If the value exceeds the electrolysis current value in the pH value range required by the user, the electrolysis current is reduced by lowering the duty, and the control unit 19 of the control unit 19 adjusts so as to match the pH value range required by the user. Control with instructions. The voltage detected by the voltage detection circuit 17 is determined in advance as a voltage upper limit value for approaching the target value of pH in each range when the electric conductivity of the raw water is low and a current is difficult to flow, and the voltage is set higher than that. It is for controlling not to apply.

【0011】[0011]

【発明が解決しようとする課題】前記した従来の連続電
解方式のアルカリイオン整水器では、電解出力制御は直
流電源電圧を一定周期でオン、オフ制御している。この
ような状態で電解電流を正確に検知するには、電解電流
を電圧信号に変換し、その変換した電圧波形を電解電流
検出回路部でコンデンサ等を用いてオンとオフ信号を鈍
らせ平均化し検出している。しかし、滑らかな波形とな
るように平均化するためには、電解電流検出回路17内
にあるサンプリング回路のコンデンサの容量をある程度
大きくしたり、制限抵抗の抵抗値を大きくする必要があ
り、コンデンサの容量や制限抵抗の抵抗値を大きくする
ことにより検出する信号波形の変化が遅くなり、電解出
力制御の応答が遅くなる傾向にあった。
In the conventional continuous electrolysis type alkaline ionized water conditioner described above, the electrolytic output control is performed by turning on and off the DC power supply voltage at a constant cycle. To detect the electrolytic current accurately in such a state, convert the electrolytic current into a voltage signal and average the converted voltage waveform by dulling the ON and OFF signals using a capacitor in the electrolytic current detection circuit. It is detecting. However, in order to perform averaging so as to obtain a smooth waveform, it is necessary to increase the capacitance of the capacitor of the sampling circuit in the electrolytic current detection circuit 17 to some extent or to increase the resistance value of the limiting resistor. Increasing the resistance value of the capacitance or the limiting resistance slows down the change in the signal waveform to be detected, which tends to slow down the response of electrolytic output control.

【0012】本発明は上記従来の問題点を解決するもの
で、通水開始時と通水時の通水流量または水質の変化に
迅速に対応し、必要とするpH値のイオン水を安定して
供給できる連続電解方式のアルカリイオン整水器を提供
することを目的とする。
The present invention solves the above-mentioned problems of the prior art by rapidly responding to changes in the water flow rate or water quality at the start of water supply and during water supply, and stabilizing ionized water having a required pH value. It is an object of the present invention to provide a continuous electrolysis-type alkaline ionized water conditioner that can be supplied by the method.

【0013】[0013]

【課題を解決するための手段】本発明は上記の課題を解
決するため、原水を電気分解してアルカリイオン水およ
び酸性イオン水を生成するアルカリイオン整水器であっ
て、操作表示部からの操作指令にしたがい、前記流量セ
ンサの検出した通水流量と原水の水質により変化する電
解電流および電圧値を前記電解電流検出回路および電解
電圧検出回路で検出し、制御部からの不連続な数値コー
ドを電解制御回路に出力する構成としたものである。
In order to solve the above-mentioned problems, the present invention is an alkaline ionized water conditioner for electrolyzing raw water to produce alkaline ionized water and acidic ionized water, which comprises: According to the operation command, the electrolytic current and voltage values that change depending on the water flow rate detected by the flow rate sensor and the quality of the raw water are detected by the electrolytic current detection circuit and the electrolytic voltage detection circuit, and the discontinuous numerical codes from the control unit. Is output to the electrolytic control circuit.

【0014】本発明によれば、目的のpHのイオン水を
生成するのに必要な電解電流および電解電圧のフィード
バック制御を正確かつ迅速にして、原水の水質や通水流
量が変化してもより安定したpH値のイオン水を生成す
ることができる。
According to the present invention, the feedback control of the electrolysis current and electrolysis voltage necessary for producing the ionic water having the desired pH is accurately and quickly performed, and the quality of the raw water and the flow rate of the raw water can be improved. It is possible to generate ionized water having a stable pH value.

【0015】[0015]

【発明の実施の形態】本発明の請求項1に記載の発明
は、通水路に通水流量を検出できる流量センサと、原水
を電気分解してアルカリイオン水または酸性イオン水を
生成する電解槽と、商用電源に接続されて電解槽へ通電
出力する内部に出力調整回路を備えた電源部と、通電出
力状態の電流および電圧値を検出する電解電流検出回路
および電解電圧検出回路と、通電出力状態の電流および
電圧値をもとに電源部を制御するための数値コードを出
力する制御部と、制御部からの数値コードを電圧出力に
変換し、内部にD/A変換回路と信号増幅回路とを備え
電源部の電源電圧出力を決定する電解制御部と、制御部
へ操作指令を行う操作部および動作状態を表示する表示
部を有する操作表示部とを備えたアルカリイオン整水器
において、操作表示部からの操作指令にしたがい、流量
センサの検出した通水流量と原水の水質により変化する
電解電流値および電解電圧値を電解電流検出回路および
電解電圧検出回路で検出し、検出した電解電流値および
電解電圧値に応じた電解槽への通電出力として制御部か
らの数値コードを電解制御部に出力し、電解制御部内の
D/A変換回路により数値コードに応じた電圧レベルに
変換し信号増幅回路を通して電源部内の出力調整回路へ
出力し、電解槽への通電出力状態を制御するようにした
アルカリイオン整水器であり、電源回路の出力電圧の閾
値を迅速に変化させ、電解槽への通電出力状態を変化さ
せることで、イオン水生成における電解時の電解電流の
迅速なフィードバック制御を行うという作用を有する。
BEST MODE FOR CARRYING OUT THE INVENTION The invention according to claim 1 of the present invention is a flow rate sensor capable of detecting a flow rate of water flowing through a water passage, and an electrolytic cell for electrolyzing raw water to generate alkaline ionized water or acidic ionized water. And a power supply section that is internally connected to a commercial power source and outputs current to the electrolytic cell, an output adjustment circuit, an electrolytic current detection circuit and an electrolytic voltage detection circuit that detect current and voltage values in the current output state, and a current output A control unit that outputs a numerical code for controlling the power supply unit based on the current and voltage values of the state, and a numerical code from the control unit is converted into a voltage output, and a D / A conversion circuit and a signal amplification circuit are internally provided. In an alkaline ionized water device provided with an electrolysis control unit for determining the power supply voltage output of the power supply unit, and an operation display unit having an operation unit for performing an operation command to the control unit and a display unit for displaying the operating state, Operation display The electrolysis current value and electrolysis voltage detection circuit detect the electrolysis current value and electrolysis voltage value that change depending on the water flow rate detected by the flow rate sensor and the quality of the raw water according to the operation command from the A numerical code from the control unit is output to the electrolysis control unit as an energization output to the electrolytic cell according to the voltage value, and the D / A conversion circuit in the electrolysis control unit converts it to a voltage level according to the numerical code and passes it through the signal amplification circuit. It is an alkaline ionized water device that outputs to the output adjustment circuit in the power supply section and controls the energization output state to the electrolytic cell.It quickly changes the threshold of the output voltage of the power supply circuit and outputs the energization output to the electrolytic cell. By changing the state, it has the effect of performing quick feedback control of the electrolysis current during electrolysis in the production of ionized water.

【0016】本発明の請求項2に記載の発明は、請求項
1に記載のアルカリイオン整水器において、制御部から
の数値コード出力を一定周期毎に変化させるようにした
ものであり、不連続なある数値コードと、次の数値コー
ド間の電圧出力を擬似的につくり出すという作用を有す
る。
According to a second aspect of the present invention, in the alkaline ionized water device according to the first aspect, the numerical code output from the control unit is changed at regular intervals. It has the function of artificially creating a voltage output between a continuous numerical code and the next numerical code.

【0017】以下、本発明の実施の形態について図面を
参照しながら説明する。
Embodiments of the present invention will be described below with reference to the drawings.

【0018】(実施の形態1)図1は、本発明の実施の
形態1におけるアルカリイオン整水器の概略構成図、図
2は、同アルカリイオン整水器における制御ブロック図
である。
(Embodiment 1) FIG. 1 is a schematic configuration diagram of an alkaline ionized water device according to Embodiment 1 of the present invention, and FIG. 2 is a control block diagram of the alkaline ionized water device.

【0019】なお、図1において従来の技術の説明で用
いた符号と同一符号のものは、本実施の形態1において
も基本的に同一であるため、これらの詳細な説明は従来
の技術に譲って省略する。
Note that the same reference numerals as those used in the description of the conventional technique in FIG. 1 are basically the same in the first embodiment as well, and therefore the detailed description thereof will be given to the conventional technique. And omit.

【0020】図1において、1は水道水等の原水管、2
は水栓、3は本実施の形態のアルカリイオン整水器本
体、4は浄水部、5は流量センサ、6はカルシウム供給
部、7は電解槽、8は隔膜、9および10は電極板、1
1は通水管、12は吐水管、13は電源投入用プラグで
ある。
In FIG. 1, reference numeral 1 is a raw water pipe for tap water or the like, 2
Is a faucet, 3 is the main body of the alkaline ionized water device of the present embodiment, 4 is a water purification unit, 5 is a flow rate sensor, 6 is a calcium supply unit, 7 is an electrolytic cell, 8 is a diaphragm, 9 and 10 are electrode plates, 1
Reference numeral 1 is a water passage pipe, 12 is a water discharge pipe, and 13 is a power-on plug.

【0021】図1および図2において、20は本実施の
形態1の電源部で内部に出力調整回路を備えたスイッチ
ング電源回路になっている。15は電解出力部、16は
電解電流検出回路、17は電解電圧検出回路、18は操
作表示部、19は操作表示部18の設定にもとづき電解
電流検出回路16および電解電圧検出回路17で検出し
た電解電流および電圧値を監視しながら、電解出力の制
御を行う制御部であり、後述電解制御部に数値コードで
電解電圧の制御を行う。21は制御部からの数値コード
を電圧信号に変換する電解制御部であり、内部にD/A
変換回路と信号増幅回路を備えている。
In FIGS. 1 and 2, reference numeral 20 denotes a power supply unit according to the first embodiment, which is a switching power supply circuit having an output adjusting circuit therein. Reference numeral 15 is an electrolysis output unit, 16 is an electrolysis current detection circuit, 17 is an electrolysis voltage detection circuit, 18 is an operation display unit, and 19 is detection by the electrolysis current detection circuit 16 and the electrolysis voltage detection circuit 17 based on the setting of the operation display unit 18. The control unit controls the electrolysis output while monitoring the electrolysis current and voltage value, and controls the electrolysis voltage by a numerical code in the electrolysis control unit described later. Reference numeral 21 is an electrolysis control unit that converts a numerical code from the control unit into a voltage signal, and has an internal D / A
It has a conversion circuit and a signal amplification circuit.

【0022】以上のように構成された本実施の形態1の
アルカリイオン整水器3について、アルカリイオン水を
生成する際の動作を説明する。
The operation of the alkaline ionized water device 3 of the first embodiment having the above-described structure when producing alkaline ionized water will be described.

【0023】利用者は、操作表示部18のモード選択ボ
タンを押圧してアルカリイオン水生成モード、または酸
性イオン水生成モードおよび必要とするpH値レンジを
選択し、水栓2を開く。水栓2から通水された原水は、
浄水部4で浄化され、流量センサ5を経てカルシウム供
給部6にてカルシウム等が溶解されて電解容易な水に処
理された後、電解槽7に通水される。
The user presses the mode selection button on the operation display unit 18 to select the alkaline ionized water production mode or the acidic ionized water production mode and the required pH value range, and opens the faucet 2. The raw water passed from the tap 2
After being purified by the water purification unit 4, calcium and the like are dissolved by the calcium supply unit 6 through the flow rate sensor 5 to be treated as water that is easy to electrolyze, and then water is passed to the electrolytic bath 7.

【0024】一方、電源投入用プラグ13からは商用電
源であるAC100Vが供給され、電源部20内のトラ
ンスおよび整流回路で直流電圧変換し、出力調整回路で
電解に必要な直流電圧電流を発生させる。そのとき、制
御部19は所定の数値コードを電解制御部21に出力
し、電解制御部21内のD/A変換回路により数値コー
ドに応じた電圧レベルに変換し信号増幅回路を通して電
源部20内の出力調整回路へ電解電圧信号を出力する。
電源部20内の出力調整回路で電解に必要な直流電圧電
流は、電解出力部15を介して電解槽7の電極版9およ
び10に電気分解に必要な電力が供給される。このとき
相対的にプラス電圧を印加する電極板を陽極、マイナス
電圧を印加する電極板を陰極とすると、電解槽7内に隔
膜8で仕切られた陽極室と陰極室とが形成される。な
お、アルカリイオン水生成モード時においては電極板1
0が陽極となり、電極板9が陰極となる。また酸性イオ
ン水生成モード時においては電極板9が陽極となり、電
極板10が陰極となる。
On the other hand, AC100V, which is a commercial power source, is supplied from the power-on plug 13, the transformer and the rectifier circuit in the power source section 20 convert the DC voltage, and the output adjusting circuit generates the DC voltage current necessary for electrolysis. . At that time, the control unit 19 outputs a predetermined numerical code to the electrolysis control unit 21, the D / A conversion circuit in the electrolysis control unit 21 converts it into a voltage level according to the numerical code, and the power amplifier 20 in the power supply unit 20 through the signal amplification circuit. The electrolytic voltage signal is output to the output adjustment circuit of.
The DC voltage / current required for electrolysis in the output adjusting circuit in the power supply unit 20 is supplied to the electrode plates 9 and 10 of the electrolytic cell 7 via the electrolysis output unit 15 as electric power required for electrolysis. At this time, when the electrode plate to which the positive voltage is applied is the anode and the electrode plate to which the negative voltage is applied is the cathode, the anode chamber and the cathode chamber partitioned by the diaphragm 8 are formed in the electrolytic cell 7. The electrode plate 1 is used in the alkaline ionized water generation mode.
0 serves as an anode, and the electrode plate 9 serves as a cathode. Further, in the acidic ionized water production mode, the electrode plate 9 serves as an anode and the electrode plate 10 serves as a cathode.

【0025】さて、通水後、制御部19は流量センサ5
の信号を読み取り、流量レベルが一定量を超えると、こ
の状態を通水中と判断する。このとき、操作表示部18
の生成モード選択ボタンの押圧によりすでに電気分解条
件が設定されているので、制御部19は電解槽7にて電
気分解を行うため電極板9および10に所定の電圧が印
加されるように、所定の数値コードを電解制御部21に
出力し、電解出力部15に電解出力指令を行い、電解槽
7の電極板9および10への電圧印加を開始する。これ
により、アルカリイオン水生成モード時においては電極
板9が陰極、電極板10が陽極となり、吐水管12より
アルカリイオン水が吐水され、酸性イオン水生成モード
時においては電極板9が陽極、電極板10が陰極とな
り、吐水管12より酸性イオン水が吐水される。水栓2
により原水が止水されると、流量センサ5の信号により
制御部19は止水と判断し、電解出力部15より電解槽
7の電極板9および10への電圧印加を停止する。
Now, after passing water, the control unit 19 controls the flow rate sensor 5
Signal is read, and if the flow rate level exceeds a certain amount, it is judged that this state is water passing. At this time, the operation display unit 18
Since the electrolysis conditions have already been set by pressing the generation mode selection button of No. 1, the control unit 19 sets a predetermined voltage so that a predetermined voltage is applied to the electrode plates 9 and 10 for performing electrolysis in the electrolytic cell 7. Is output to the electrolysis control unit 21, the electrolysis output command is issued to the electrolysis output unit 15, and voltage application to the electrode plates 9 and 10 of the electrolysis tank 7 is started. Thus, in the alkaline ionized water producing mode, the electrode plate 9 serves as a cathode and the electrode plate 10 serves as an anode, and the alkaline ionized water is ejected from the water discharge pipe 12, and in the acidic ionized water producing mode, the electrode plate 9 serves as an anode and an electrode. The plate 10 serves as a cathode, and acidic ionized water is discharged from the water discharge pipe 12. Faucet 2
When the raw water is stopped by, the control unit 19 determines that the water is stopped by the signal of the flow sensor 5, and stops the voltage application from the electrolytic output unit 15 to the electrode plates 9 and 10 of the electrolytic cell 7.

【0026】ここで、アルカリイオン水生成モード時お
よび酸性イオン水生成モード時に、制御部19は電解出
力部15で発生する直流電圧を電解槽7の電極板9およ
び10に供給する。一定の直流電圧を電極板9および1
0に供給した場合、原水の水質および通水流量によっ
て、電極板9および10との間に流れる電解電流は変化
し、生成されるpH値も変化する。そのような状態で、
pH値を一定に保つために、その電解電流および通水流
量の変化を電解電流検出回路16および流量センサ5に
より検出し、流量センサ5で検出した信号レベルに応じ
た電解電流を印加する必要がある。
Here, in the alkaline ionized water producing mode and the acidic ionized water producing mode, the control section 19 supplies the DC voltage generated in the electrolytic output section 15 to the electrode plates 9 and 10 of the electrolytic cell 7. A constant DC voltage is applied to the electrode plates 9 and 1
When supplied to 0, the electrolytic current flowing between the electrode plates 9 and 10 changes depending on the water quality of the raw water and the water flow rate, and the generated pH value also changes. In such a state,
In order to keep the pH value constant, it is necessary to detect the changes in the electrolytic current and the flow rate of the flowing water by the electrolytic current detection circuit 16 and the flow sensor 5, and apply the electrolytic current according to the signal level detected by the flow sensor 5. is there.

【0027】そこで、制御部19は電解槽7にて設定さ
れたpH値レンジに合わせで電気分解をおこなうため電
極板9および10に所定の電圧が印加されるように電解
出力部15に電解出力指令をおこなうとき、電解電圧設
定の数値コード信号を更新して電解制御部21に出力す
る。
Therefore, the control unit 19 carries out electrolysis in accordance with the pH value range set in the electrolytic cell 7 so that a predetermined voltage is applied to the electrode plates 9 and 10 so that an electrolytic output is given to the electrolytic output unit 15. When the command is issued, the numerical code signal for setting the electrolysis voltage is updated and output to the electrolysis control unit 21.

【0028】電解制御部21では制御部19からの更新
された数値コード信号をD/A変換回路で電圧信号に変
換し、信号増幅回路を介して電源部20に伝達する。電
源部20では電解制御部21からの信号に応じた電力を
出力するように電源出力調節回路で制御を行い、電解電
流検出回路16で検出された電解電流値が利用者の必要
とするpH値を生成する電解電流値に到達していなけれ
ば、電解制御部への数値コードを1ランクアップさせ電
解電圧を上げることで電解電流を増加させ、あるいは、
電解電流検出回路16で検出された電解電流値が利用者
の必要とするpH値を生成する電解電流値を超えていれ
ば、電解制御回路への数値コードを1ランクダウンさせ
電解電圧を下げることで電解電流を減少させて利用者の
必要とするpH値レンジに合わせるように制御部19の
指示で制御する。その後、電解制御部21からの信号に
合わせて、それに応じた電力を出力するように電源部2
0で制御するので、電解出力部15に供給される電力は
安定したものになる。
In the electrolysis control section 21, the updated numerical code signal from the control section 19 is converted into a voltage signal by the D / A conversion circuit and transmitted to the power supply section 20 through the signal amplification circuit. In the power supply unit 20, the power supply output adjusting circuit controls so as to output the electric power according to the signal from the electrolysis control unit 21, and the electrolysis current value detected by the electrolysis current detection circuit 16 is the pH value required by the user. If the electrolysis current value for generating is not reached, the electrolysis current is increased by increasing the electrolysis voltage by one rank by increasing the numerical code to the electrolysis control unit, or
If the electrolysis current value detected by the electrolysis current detection circuit 16 exceeds the electrolysis current value that produces the pH value required by the user, lower the electrolysis control circuit by one rank to lower the electrolysis voltage. Then, the electrolytic current is reduced to control with the instruction of the control unit 19 so as to match the pH value range required by the user. Then, in accordance with the signal from the electrolysis control unit 21, the power supply unit 2 outputs electric power according to the signal.
Since it is controlled by 0, the electric power supplied to the electrolytic output unit 15 becomes stable.

【0029】なお、電解電圧検出回路17で検知した電
圧は、従来の技術と同じく原水の電気導電率が低く電流
が流れにくい場合、各アルカリイオン水生成モード、ま
たは酸性イオン水生成モード設定電圧の上限値を予め決
めておき、それ以上の電圧を印加しないように制御する
ためのものである。
The voltage detected by the electrolysis voltage detection circuit 17 is the same as that in the prior art when the electric conductivity of the raw water is low and the current hardly flows, the voltage of each alkaline ion water generation mode or the acidic ion water generation mode set voltage is set. The upper limit is determined in advance, and the upper limit is controlled so that a voltage higher than that is not applied.

【0030】また、電解制御部21内のD/A変換回路
の分解能より細やかな電圧制御が必要な場合は、制御部
19からの数値コード出力を一定周期毎に変化させるこ
とにより、目的の電圧値を超えた電圧に成る数値コード
と目的の電圧値以下の電圧に成る数値コード間の電圧出
力を擬似的につくり出し制御することができる。
When finer voltage control than the resolution of the D / A conversion circuit in the electrolysis control section 21 is required, the numerical code output from the control section 19 is changed at regular intervals to obtain the desired voltage. The voltage output between the numerical code having a voltage exceeding the value and the numerical code having a voltage equal to or lower than the target voltage value can be artificially created and controlled.

【0031】たとえば、数値コードが3ビットで0から
7の8段階で数値コードが0の時電解電圧は5V、数値
コードが1のとき電解電圧は10V、数値コードが2の
とき電解電圧は15V、数値コードが3のとき電解電圧
は20V、数値コードが4のとき電解電圧は25V、数
値コードが5のとき電解電圧は30V、数値コードが6
のとき電解電圧は35V、数値コードが7のとき電解電
圧は40Vとした場合、目的のpHのレンジを確保する
電解電流値を出力するのに12Vの電解電圧が必要な
時、数値コードを1msの10個をひとつの単位とし1
0ms周期で、前半の8つを数値コードが1で電解電圧
は10V、後半の2つを数値コードが2で電解電圧は1
5Vの出力を繰り返すことで12V電解電圧を擬似的に
つくり出すことができる。
For example, when the numerical code is 3 bits and 8 steps from 0 to 7, the electrolysis voltage is 5V when the numeric code is 0, the electrolysis voltage is 10V when the numeric code is 1, and the electrolysis voltage is 15V when the numeric code is 2. When the numerical code is 3, the electrolysis voltage is 20V, when the numerical code is 4, the electrolysis voltage is 25V, when the numerical code is 5, the electrolysis voltage is 30V, and the numerical code is 6.
When the electrolysis voltage is 35 V and the electrolysis voltage is 40 V when the numerical code is 7, when the electrolysis voltage of 12 V is required to output the electrolysis current value that secures the target pH range, the numerical code is 1 ms. 1 of 10 units
In the 0 ms cycle, the first 8 are numerical code 1 and electrolysis voltage is 10V, the latter 2 are numerical code 2 and electrolysis voltage is 1
By repeating the output of 5V, a 12V electrolytic voltage can be artificially created.

【0032】つぎに、図2の電解出力部15内の電解電
流検出回路16および電解電圧検出回路17の電解電流
値および電解電圧値について説明する。
Next, the electrolytic current value and electrolytic voltage value of the electrolytic current detection circuit 16 and the electrolytic voltage detection circuit 17 in the electrolytic output section 15 of FIG. 2 will be described.

【0033】前記数値コード出力制御にすることで、直
流電源電圧(40V)を一定周期でオン、オフ制御する
場合は0Vから40Vのオン/オフ波形となり、電解電
流の変化量も大きいが、数値コードで分割制御とした場
合は直前に出力した数値コードで決定される電圧レベル
と次の数値コードで決定される電圧レベルとの差とな
り、電解電流の変化量が少ない。それにより、コンデン
サ等を用いて電解電流値および電解電圧値信号を鈍らせ
て検出する回路においてはサンプリング回路のコンデン
サの容量を小さくでき、かつ、制限抵抗の抵抗値も小さ
くすることができ、検出する信号波形の変化が速くな
り、電解出力制御の応答も速くなる。
With the above numerical code output control, when the DC power supply voltage (40V) is controlled to be turned on and off at a constant cycle, an ON / OFF waveform of 0V to 40V is obtained, and the amount of change in electrolytic current is large, but When the code is divided and controlled, there is a difference between the voltage level determined by the numerical code output immediately before and the voltage level determined by the next numerical code, and the amount of change in electrolytic current is small. As a result, in a circuit that detects the electrolytic current value and the electrolytic voltage value signal by using a capacitor or the like, the capacity of the sampling circuit capacitor can be reduced, and the resistance value of the limiting resistor can also be reduced. The signal waveform changes rapidly, and the electrolytic output control response also becomes faster.

【0034】[0034]

【発明の効果】以上の説明より明らかなように本発明の
アルカリイオン整水器によれば、通水開始時と通水時の
通水流量または水質の変化に迅速に対応し、必要とする
pH値のアルカリイオン水または酸性イオン水を安定し
て供給することができるものであり、その効果は大き
い。
As is apparent from the above description, according to the alkaline ionized water device of the present invention, it is necessary to promptly respond to changes in the flow rate or the quality of water at the start of water flow and at the time of water flow. It is possible to stably supply alkaline ionized water or acidic ionized water having a pH value, and the effect is great.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の実施の形態1におけるアルカリイオン
整水器の概略構造図
FIG. 1 is a schematic structural diagram of an alkaline ionized water device according to a first embodiment of the present invention.

【図2】同アルカリイオン整水器における電解制御回路
ブロック図
FIG. 2 is a block diagram of an electrolytic control circuit in the alkaline ionized water device.

【図3】従来のアルカリイオン整水器の概略構造図FIG. 3 is a schematic structural diagram of a conventional alkaline ionized water device.

【符号の説明】[Explanation of symbols]

1 原水管 2 水栓 3 整水器本体 4 浄水部 5 流量センサ 6 カルシウム供給部 7 電解槽 8 隔膜 9,10 電極板 11 通水管 12 吐水管 13 電源投入用プラグ 14 電源部 15 電解出力部 16 電解電流検出回路 17 電解電圧検出回路 18 操作表示部 19 制御部 20 電源部 21 電解制御部 1 raw water pipe 2 faucet 3 water conditioner body 4 Water Purification Department 5 Flow rate sensor 6 Calcium supplier 7 Electrolyzer 8 diaphragm 9,10 Electrode plate 11 water pipe 12 Discharge pipe 13 Power-on plug 14 power supply 15 Electrolysis output section 16 Electrolytic current detection circuit 17 Electrolytic voltage detection circuit 18 Operation display 19 Control unit 20 power supply 21 Electrolysis control unit

フロントページの続き Fターム(参考) 4D061 DA03 DB08 EA02 EB01 EB04 EB12 EB37 EB38 EB39 ED12 GA02 GA12 GA14 GB30 GC12 GC14 Continued front page    F-term (reference) 4D061 DA03 DB08 EA02 EB01 EB04                       EB12 EB37 EB38 EB39 ED12                       GA02 GA12 GA14 GB30 GC12                       GC14

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】通水路に通水流量を検出できる流量センサ
と、原水を電気分解してアルカリイオン水または酸性イ
オン水を生成する電解槽と、商用電源に接続されて電解
槽へ通電出力する内部に出力調整回路を備えた電源部
と、通電出力状態の電流および電圧値を検出する電解電
流検出回路および電解電圧検出回路と、通電出力状態の
電流および電圧値をもとに前記電源部を制御するための
数値コードを出力する制御部と、制御部からの数値コー
ドを電圧出力に変換し、内部にD/A変換回路と信号増
幅回路とを備え電源部の電源電圧出力を決定する電解制
御部と、前記制御部へ操作指令を行う操作部および動作
状態を表示する表示部を有する操作表示部とを備えたア
ルカリイオン整水器において、操作表示部からの操作指
令にしたがい、前記流量センサの検出した通水流量と原
水の水質により変化する電解電流値および電解電圧値を
前記電解電流検出回路および電解電圧検出回路で検出
し、検出した電解電流値および電解電圧値に応じた電解
槽への通電出力として制御部からの数値コードを電解制
御部に出力し、電解制御部内のD/A変換回路により数
値コードに応じた電圧レベルに変換し信号増幅回路を通
して電源部内の出力調整回路へ出力し、電解槽への通電
出力状態を制御することを特徴とするアルカリイオン整
水器。
1. A flow rate sensor capable of detecting a flow rate of water flowing through a water passage, an electrolytic cell for electrolyzing raw water to generate alkaline ionized water or acidic ionized water, and a power source connected to a commercial power source for energization output. A power supply unit internally provided with an output adjustment circuit, an electrolytic current detection circuit and an electrolytic voltage detection circuit for detecting current and voltage values in the energized output state, and the power supply unit based on the current and voltage values in the energized output state. Electrolysis that includes a control unit that outputs a numeric code for controlling, a numeric code from the control unit that is converted into a voltage output, and that has a D / A conversion circuit and a signal amplification circuit inside to determine the power supply voltage output of the power supply unit In an alkaline ionized water device provided with a control unit and an operation display unit having an operation unit for performing an operation command to the control unit and a display unit for displaying an operating state, according to an operation command from the operation display unit, the The electrolysis current value and the electrolysis voltage value that change depending on the water flow rate and the raw water quality detected by the quantity sensor are detected by the electrolysis current detection circuit and the electrolysis voltage detection circuit, and the electrolysis according to the detected electrolysis current value and electrolysis voltage value is performed. A numerical code from the control unit is output to the electrolysis control unit as the energization output to the tank, and the D / A conversion circuit in the electrolysis control unit converts it into a voltage level according to the numerical code and the output adjustment circuit in the power supply unit through the signal amplification circuit. The alkaline ionized water conditioner is characterized in that the electric current is output to the electrolyzer to control the output state of electricity to the electrolytic cell.
【請求項2】前記制御部からの数値コード出力を一定周
期毎に変化させることを特徴とする請求項1記載のアル
カリイオン整水器。
2. The alkaline ionized water device according to claim 1, wherein the numerical code output from the control unit is changed at regular intervals.
JP2002112992A 2002-04-16 2002-04-16 Alkaline ion water conditioner Expired - Fee Related JP3960107B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2002112992A JP3960107B2 (en) 2002-04-16 2002-04-16 Alkaline ion water conditioner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2002112992A JP3960107B2 (en) 2002-04-16 2002-04-16 Alkaline ion water conditioner

Publications (2)

Publication Number Publication Date
JP2003305468A true JP2003305468A (en) 2003-10-28
JP3960107B2 JP3960107B2 (en) 2007-08-15

Family

ID=29395301

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2002112992A Expired - Fee Related JP3960107B2 (en) 2002-04-16 2002-04-16 Alkaline ion water conditioner

Country Status (1)

Country Link
JP (1) JP3960107B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006008877A1 (en) * 2004-07-15 2006-01-26 Miura-Denshi Kabushiki-Kaisha Electrolytic water generating, diluting, and supplying apparatus and electrolytic water generating, diluting, and supplying method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006008877A1 (en) * 2004-07-15 2006-01-26 Miura-Denshi Kabushiki-Kaisha Electrolytic water generating, diluting, and supplying apparatus and electrolytic water generating, diluting, and supplying method
JPWO2006008877A1 (en) * 2004-07-15 2008-07-31 三浦電子株式会社 Electrolytic water generation/dilution supply device and electrolyzed water generation/dilution supply method
JP4874104B2 (en) * 2004-07-15 2012-02-15 三浦電子株式会社 Electrolyzed water generation / dilution supply equipment

Also Published As

Publication number Publication date
JP3960107B2 (en) 2007-08-15

Similar Documents

Publication Publication Date Title
JPH06343959A (en) Alkaline ion water adjusting device
JP2810262B2 (en) Control device for continuous electrolytic ionized water generator
JP2000317451A (en) Alkaline ionized water producer
JPH07136653A (en) Electrolytic water maker
JP2001259634A (en) Ionic water producer
JP3960107B2 (en) Alkaline ion water conditioner
JP4106788B2 (en) Alkaline ion water conditioner
JP3192182B2 (en) Control device for continuous electrolytic ionized water generator
JP3666102B2 (en) Alkaline ion water conditioner
JP3991484B2 (en) Control method of alkaline ionized water apparatus
JP4378803B2 (en) Alkaline ion water conditioner
JP2646937B2 (en) Electrolysis controller of ion water generator
JPH08155456A (en) Electrolytic water generator
JPH10309580A (en) Alkali ion water generator
JPH06335681A (en) Alkaline ion water regulator
JP3887882B2 (en) Alkaline ion water conditioner
JPH07124562A (en) Electrolytic water making machine
JPH07323281A (en) Alkali ion water regulator
JPH1080685A (en) Alkali ionized water adjuster
JPH07124561A (en) Electrolytic water making machine
JP2006187702A (en) Alkali ion water generator
KR100478658B1 (en) Method for controlling water quality of ionic water
JPH11244857A (en) Electrolyzed ionic water producing implement
JPH07290059A (en) Ionized water producer
JP2970212B2 (en) Ion water supply device

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20050329

RD01 Notification of change of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7421

Effective date: 20050706

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20070316

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A821

Effective date: 20070322

RD02 Notification of acceptance of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7422

Effective date: 20070322

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20070326

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20070424

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20070507

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100525

Year of fee payment: 3

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100525

Year of fee payment: 3

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20100525

Year of fee payment: 3

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20110525

Year of fee payment: 4

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120525

Year of fee payment: 5

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120525

Year of fee payment: 5

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130525

Year of fee payment: 6

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130525

Year of fee payment: 6

FPAY Renewal fee payment (prs date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140525

Year of fee payment: 7

LAPS Cancellation because of no payment of annual fees