JP2003277057A5 - - Google Patents

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JP2003277057A5
JP2003277057A5 JP2002078850A JP2002078850A JP2003277057A5 JP 2003277057 A5 JP2003277057 A5 JP 2003277057A5 JP 2002078850 A JP2002078850 A JP 2002078850A JP 2002078850 A JP2002078850 A JP 2002078850A JP 2003277057 A5 JP2003277057 A5 JP 2003277057A5
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titanium dioxide
less
raw material
flow rate
organic polymer
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JP2002078850A
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JP2003277057A (en
JP4155750B2 (en
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Priority claimed from JP2002078850A external-priority patent/JP4155750B2/en
Priority to JP2002078850A priority Critical patent/JP4155750B2/en
Priority to US10/507,776 priority patent/US20060074173A1/en
Priority to PCT/JP2003/003470 priority patent/WO2003078327A1/en
Priority to KR10-2004-7014795A priority patent/KR20050013533A/en
Priority to AU2003217482A priority patent/AU2003217482A1/en
Publication of JP2003277057A publication Critical patent/JP2003277057A/en
Publication of JP2003277057A5 publication Critical patent/JP2003277057A5/ja
Publication of JP4155750B2 publication Critical patent/JP4155750B2/en
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Claims (27)

二酸化チタンにおいて、レーザー式粒度分析法によって測定される平均粒径が5〜200μmの範囲内であり、TiO2としての純度が99.5質量%以上であり、Fe、Ni、Cr、Al及びZrがそれぞれ20質量ppm以下、Siが40質量ppm以下、Clが0.05質量%以下、及びSが50質量ppm以下であることを特徴とする二酸化チタン。In titanium dioxide, the average particle diameter measured by laser particle size analysis is in the range of 5 to 200 μm, the purity as TiO 2 is 99.5% by mass or more, and Fe, Ni, Cr, Al and Zr Are each 20 mass ppm or less, Si is 40 mass ppm or less, Cl is 0.05 mass% or less, and S is 50 mass ppm or less. 二酸化チタンの密度が、3.7g/cm3以上である請求項1記載の二酸化チタン。The titanium dioxide according to claim 1 , wherein the density of the titanium dioxide is 3.7 g / cm 3 or more. 二酸化チタンが、光触媒能を有する請求項1乃至2のいずれか一項に記載の二酸化チタン。The titanium dioxide according to any one of claims 1 to 2, wherein the titanium dioxide has a photocatalytic ability. 二酸化チタンが、下式(1)
球形度=(粒子の投影面積と同じ面積を有する円の周長)/(粒子投影像の輪郭の長さ)・・・・・・(1)
で定義される球形度が0.9以上の粒子である請求項1乃至3のいずれか一項に記載の二酸化チタン。
Titanium dioxide has the following formula (1)
Sphericality = (circumference of a circle having the same area as the projected area of the particle) / (length of the contour of the projected particle image) (1)
The titanium dioxide according to any one of claims 1 to 3, which is a particle having a sphericity defined by (1) of 0.9 or more.
原料二酸化チタンを火炎中に導入して製造する請求項1乃至4のいずれか一項に記載の二酸化チタンの製造方法。The manufacturing method of the titanium dioxide as described in any one of Claim 1 thru | or 4 which introduces and manufactures raw material titanium dioxide in a flame . 原料二酸化チタンが、四塩化チタンを含有するガス及び酸化性ガスをそれぞれ500℃以上に予熱し、それぞれ流速10m/秒以上で反応管に供給することにより反応させて得られる二酸化チタンであることを特徴とする請求項5に記載の二酸化チタンの製造方法。 The raw material titanium dioxide is titanium dioxide obtained by preheating the gas containing titanium tetrachloride and the oxidizing gas to 500 ° C. or more and supplying them to the reaction tube at a flow rate of 10 m / second or more. The method for producing titanium dioxide according to claim 5, wherein: 反応が、反応管内の600℃を越える温度領域に3秒以下の時間、四塩化チタンを含有するガス及び酸化性ガスを滞留させて行なわれる請求項6に記載の二酸化チタンの製造方法。The method for producing titanium dioxide according to claim 6, wherein the reaction is carried out by retaining a gas containing titanium tetrachloride and an oxidizing gas in a temperature region exceeding 600 ° C in the reaction tube for a period of 3 seconds or less. 原料二酸化チタンが、BET換算粒子径7〜500nm、レーザー式粒度分析法によって測定される平均粒子径0.4〜10μmであって、Fe、Ni、Cr、Al及びZrをそれぞれ20質量ppm以下、Siを40質量ppm以下、Clを1質量%以下、及びSを200質量ppm以下含む二酸化チタンである請求項5乃至7のいずれか一項に記載の二酸化チタンの製造方法。The raw material titanium dioxide has a BET equivalent particle diameter of 7 to 500 nm, an average particle diameter of 0.4 to 10 μm measured by a laser particle size analysis method, and Fe, Ni, Cr, Al and Zr are each 20 mass ppm or less, The method for producing titanium dioxide according to any one of claims 5 to 7, which is titanium dioxide containing Si at 40 mass ppm or less, Cl at 1 mass% or less, and S at 200 mass ppm or less. 原料二酸化チタンが、Fe、Ni、Cr、Al及びZrをそれぞれ20質量ppm以下、Siを40質量ppm以下、Clを1質量%以下、及びSを200質量ppm以下含む気相法二酸化チタンであって、BET換算粒子径7〜500nm及びレーザー式粒度分析法によって測定される平均粒子径0.4〜10μmである二酸化チタンと、BET換算粒子径150〜1000nm及びレーザー式粒度分析法によって測定される平均粒子径0.5〜20μmである二酸化チタンとの混合粉体であることを特徴とする請求項5乃至7のいずれか一項に記載の二酸化チタンの製造方法。The raw material titanium dioxide is vapor phase titanium dioxide containing Fe, Ni, Cr, Al, and Zr, each of 20 mass ppm or less, Si 40 mass ppm or less, Cl 1 mass% or less, and S 200 mass ppm or less. In addition, titanium dioxide having a BET equivalent particle diameter of 7 to 500 nm and an average particle diameter of 0.4 to 10 μm measured by a laser particle size analysis method, and a BET equivalent particle diameter of 150 to 1000 nm and a laser particle size analysis method. The method for producing titanium dioxide according to any one of claims 5 to 7, which is a mixed powder with titanium dioxide having an average particle diameter of 0.5 to 20 µm. 原料二酸化チタンが、配管内レイノルズ数10,000以上の乱流状態にあるキャリアーガスによって気流分散・運搬され、高温火炎中に導入される請求項5乃至9に記載の二酸化チタンの製造方法。The method for producing titanium dioxide according to any one of claims 5 to 9, wherein the raw material titanium dioxide is dispersed and transported by a carrier gas in a turbulent state having a Reynolds number of 10,000 or more in the pipe and introduced into the high-temperature flame. 原料キャリアーガスのノズルの噴き出し流速が8Nm/秒(Nは標準状態を意味する。Nm/秒は、ノズルから噴出するガスの流量を標準状態に換算した流量(Nm3/秒)を、ノズルの噴出口の面積(m2)で除して得た流速を示す。)以上であり、可燃性ガスのバーナーノズルの噴き出し流速が原料キャリアーガスのノズル噴き出し流速の0.8倍〜4倍、酸化性ガスのバーナーノズル噴き出し流速が原料キャリアーガスのノズル噴き出し流速の1.3倍〜11倍の範囲にあり、かつ酸化性ガスの噴き出し流速が可燃性ガスの噴き出し流速より大きいことを特徴とする請求項10記載の二酸化チタンの製造方法。The jet velocity of the nozzle of the raw material carrier gas is 8 Nm / sec (N means the standard state. Nm / sec is the flow rate (Nm 3 / sec) converted from the flow rate of the gas ejected from the nozzle to the standard state. The flow rate obtained by dividing by the area of the jet outlet (m 2 ) is shown above.) The combustion flow rate of the burner nozzle of the combustible gas is 0.8 to 4 times the nozzle flow rate of the raw material carrier gas. The burner nozzle ejection flow rate of the oxidizing gas is in the range of 1.3 to 11 times the nozzle ejection flow rate of the raw material carrier gas, and the oxidizing gas ejection flow rate is greater than the combustible gas ejection flow rate. Item 11. A method for producing titanium dioxide according to Item 10. 可燃性ガスが、メタン、エタン、プロパン、エチレン、プロピレン、アセチレン、ブタン、LPG、水素、一酸化炭素のいずれか、あるいはその混合気体であることを特徴とする請求項10または11に記載の二酸化チタンの製造方法。Combustible gas, methane, ethane, propane, ethylene, propylene, acetylene, butane, LPG, hydrogen, according to claim 10 or 11, characterized in that one of carbon monoxide, or vice gaseous mixture dioxide A method for producing titanium. 酸化性ガスが、酸素を15体積%以上100体積%以下含む請求項10乃至12のいずれか一項に記載の二酸化チタンの製造方法。The method for producing titanium dioxide according to any one of claims 10 to 12, wherein the oxidizing gas contains 15% by volume to 100% by volume of oxygen. 原料二酸化チタンが、キャリアーガスと共に火炎の上流部から燃焼ガスの下流方向に噴出される請求項10乃至13のいずれか一項に記載の二酸化チタンの製造方法。The method for producing titanium dioxide according to any one of claims 10 to 13, wherein the raw material titanium dioxide is jetted together with the carrier gas from the upstream portion of the flame in the downstream direction of the combustion gas. 請求項1乃至4のいずれか一項に記載の二酸化チタンを、組成物全質量中0.01%〜80質量%含むことを特徴とする有機重合体組成物。An organic polymer composition comprising 0.01% to 80% by mass of the titanium dioxide according to any one of claims 1 to 4 in the total mass of the composition. 有機重合体組成物の有機重合体が、合成熱可塑性樹脂、合成熱硬化性樹脂、及び天然樹脂からなる群より選ばれた少なくとも1種の樹脂である請求項15に記載の有機重合体組成物。The organic polymer composition according to claim 15, wherein the organic polymer of the organic polymer composition is at least one resin selected from the group consisting of a synthetic thermoplastic resin, a synthetic thermosetting resin, and a natural resin. . 有機重合体組成物が、コンパウンドである請求項15または16に記載の有機重合体組成物。The organic polymer composition according to claim 15 or 16, wherein the organic polymer composition is a compound. 有機重合体組成物が、マスターバッチである請求項15または16に記載の有機重合体組成物。The organic polymer composition according to claim 15 or 16, wherein the organic polymer composition is a master batch. 請求項15または16に記載の有機重合体組成物を成型してなることを特徴とする成型体。A molded article obtained by molding the organic polymer composition according to claim 15 or 16. 請求項1乃至4のいずれか一項に記載の二酸化チタンを含むことを特徴とするスラリー。A slurry comprising the titanium dioxide according to any one of claims 1 to 4. 請求項1乃至4のいずれか一項に記載の二酸化チタンを含むことを特徴とする塗工剤。The coating agent characterized by including the titanium dioxide as described in any one of Claims 1 thru | or 4. 請求項1乃至4のいずれか一項に記載の二酸化チタンを含むことを特徴とする塗料。The coating material characterized by including the titanium dioxide as described in any one of Claims 1 thru | or 4. 請求項1乃至4のいずれか一項に記載の二酸化チタンを表面に具備することを特徴とする構造体。A structure comprising the titanium dioxide according to any one of claims 1 to 4 on a surface. 請求項1乃至4のいずれか一項に記載の二酸化チタンを原料とすることを特徴とする二酸化チタン単結晶。Titanium dioxide single crystal characterized by using the titanium dioxide according to any one of claims 1 to 4 as a raw material. 請求項1乃至4のいずれか一項に記載の二酸化チタンを原料とすることを特徴とするセラミックス成形体。A ceramic molded body comprising the titanium dioxide according to any one of claims 1 to 4 as a raw material. 請求項1乃至4のいずれか一項に記載の二酸化チタンを含むことを特徴とする誘電体原料。A dielectric material comprising the titanium dioxide according to any one of claims 1 to 4. 請求項1乃至4のいずれか一項に記載の二酸化チタンを含む化粧料。
Cosmetics containing the titanium dioxide as described in any one of Claims 1 thru | or 4.
JP2002078850A 2002-03-20 2002-03-20 High purity titanium oxide and method for producing the same Expired - Fee Related JP4155750B2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2002078850A JP4155750B2 (en) 2002-03-20 2002-03-20 High purity titanium oxide and method for producing the same
AU2003217482A AU2003217482A1 (en) 2002-03-20 2003-03-20 High purity titanium oxide and production process thereof
PCT/JP2003/003470 WO2003078327A1 (en) 2002-03-20 2003-03-20 High purity titanium oxide and production process thereof
KR10-2004-7014795A KR20050013533A (en) 2002-03-20 2003-03-20 High purity titanium oxide and production process thereof
US10/507,776 US20060074173A1 (en) 2002-03-20 2003-03-20 High purity titanium oxide and production process thereof

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JP2002078850A JP4155750B2 (en) 2002-03-20 2002-03-20 High purity titanium oxide and method for producing the same

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JP2008131191A Division JP2008273832A (en) 2008-05-19 2008-05-19 High purity titanium oxide and method for producing the same

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JP2003277057A JP2003277057A (en) 2003-10-02
JP2003277057A5 true JP2003277057A5 (en) 2005-06-02
JP4155750B2 JP4155750B2 (en) 2008-09-24

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JP4743481B2 (en) * 2004-03-25 2011-08-10 昭和電工株式会社 Titanium-containing perovskite type compound and method for producing the same
TWI307679B (en) * 2004-08-11 2009-03-21 Showa Denko Kk Fine pariculate titanium dioxide, and production process and use thereof
JP5311707B2 (en) * 2004-08-11 2013-10-09 昭和電工株式会社 Method for producing fine particle titanium dioxide
TWI314919B (en) * 2005-02-28 2009-09-21 Showa Denko Kk Fine particulate titanium dioxide, and production process and uses thereof
JP6286395B2 (en) * 2015-08-05 2018-02-28 太陽インキ製造株式会社 Curable resin composition, dry film, cured product and printed wiring board
EP4349785A1 (en) 2021-05-24 2024-04-10 Denka Company Limited Inorganic oxide powder, method for producing same, and resin composition
EP4353685A1 (en) 2021-05-24 2024-04-17 Denka Company Limited Inorganic oxide powder, method for producing same, and resin composition
CN115557532B (en) * 2022-07-12 2024-01-26 沈阳工程学院 Preparation method and device of titanium tetraoxide micro powder

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