JP2003183136A - Hair treatment agent composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a hair treatment agent composition capable of imparting the hair with feelings of sufficient softness, plasticity and moisturing hair. <P>SOLUTION: An amide amine compound expressed by the formula (1): R<SP>1</SP>CONH-(CH<SB>2</SB>)m-N(R<SP>2</SP>)<SB>2</SB>(wherein R<SP>1</SP>represents a residue of a 13-23C higher fatty acid; R<SP>2</SP>represents a 1-4C alkyl group; and (m) represents an integer of 2-4.), a glycerol mono fatty acid ester such as an oleic acid monoglyceride and an organic acid are blended. <P>COPYRIGHT: (C)2003,JPO

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair treatment composition, and more particularly to a hair treatment composition capable of imparting a sufficiently supple, soft and firm feeling to the hair.

[0002]

2. Description of the Related Art Conventionally, hair cleansing agents such as shampoos mainly contain anionic surfactants. Therefore, not only the dirt on the hair but also the oil that protects the hair surface is removed at the same time when washing the hair. , The softness and gloss of hair may be lost, and combing may be poor.

For the purpose of preventing such an adverse effect, a hair treatment composition such as a hair rinse, a hair treatment and a hair conditioner containing a quaternary ammonium salt which is a cationic surfactant as a main component is widely used. However, the quaternary ammonium salt alone cannot give the hair a sufficiently smooth feeling and a tight feeling, and the irritation is not sufficiently reduced.

In order to cope with these conventional problems, (a)
A hair treatment composition using an amidoamine compound, or a composition containing stearyl amidoamine lactate, alkylbenzene sulfonate, etc. (Japanese Patent Publication No. 48-1880).
No.), (b) a composition containing an amidami compound and a carboxylic acid compound (JP-A-62-51612), and (c) a composition containing an amidoamine compound and a phosphate compound (JP-A-62-51612). 62-51611), (d) a composition containing an amidoamine compound and a bis (2-alkyl-N-hydroxyethylimidazoline) chloroacetic acid complex type amphoteric surfactant (JP-A-64-62).
No. 10), (e) amidoamine compound and bis (2-
A composition containing an alkyl-N-hydroxyethyl imidazoline) chloroacetic acid complex type amphoteric surfactant and a polymeric silicone (JP-A-2-160714) has been proposed.

[0005]

However, although such a composition is less irritating to the human body,
In terms of imparting smoothness, flexibility and luster to hair, and protecting hair, satisfactory effects have not been obtained.

The present applicant has already blended a specific amidoamine compound, a higher fatty acid, an organic acid, and a specific high-molecular-weight dimethylpolysiloxane to give the hair sufficient smoothness, flexibility and luster. A hair cosmetic composition that can be applied and has an excellent hair-protecting effect has been developed (Japanese Patent Laid-Open No. 9-71516), but since the number of users of hair color has increased in recent years, it has a supple feeling and a firm feeling. There is a demand for a hair treatment composition having a further improved feeling.

The present invention has been made in view of the above circumstances, and an object thereof is to provide a hair treatment composition capable of imparting to the hair a sufficiently supple, supple and soft feeling. .

[0008]

Means for Solving the Problems The present inventor prepared a composition in which a glycerin monofatty acid ester was added to a gel using a specific amidoamine compound and an organic acid, and treated hair with the composition. It was found that the suppleness and the firmness are remarkably improved as compared with the conventional hair treatment agents, and the present invention has been completed based on this finding.

That is, the present invention provides (A) the following general formula (1)

[0010]

Embedded image R ¹ CONH— (CH ₂ ) m—N (R ² ) ₂ (1) (In the formula, R ¹ represents a residue of a higher fatty acid having 13 to 23 carbon atoms, and R ² represents a carbon atom. Represents an alkyl group of the number 1 to 4, m represents an integer of 2 to 4), and (B) glycerin monofatty acid ester,
A hair treatment composition comprising (C) an organic acid.

In the hair treatment composition of the present invention, the amount of amidoamine compound is 0.1 to 7.0% by mass, and the amount of glycerin monofatty acid ester is 0.1 to 5.0.
It is particularly preferable that the content of the organic acid is 0.01 to 6.0% by mass.

[0012]

BEST MODE FOR CARRYING OUT THE INVENTION The hair treatment composition of the present invention is described in detail below. The amidoamine compound as the component (A) used in the present invention is represented by the above general formula (1) (wherein R ¹ , R ² and m are as defined above). Specifically, stearic acid diethylaminoethylamide, stearic acid dimethylaminoethylamide, palmitic acid diethylaminoethylamide, palmitic acid dimethylaminoethylamide, myristic acid diethylaminoethylamide, myristic acid dimethylaminoethylamide, behenic acid diethylaminoethylamide, Behenic acid dimethylaminoethylamide, stearic acid diethylaminopropylamide, stearic acid dimethylaminopropylamide, palmitic acid diethylaminopropylamide, palmitic acid dimethylaminopropylamide,
Illustrative examples include myristic acid diethylaminopropylamide, myristic acid dimethylaminopropylamide, behenic acid diethylaminopropylamide, and behenic acid dimethylaminopropylamide. Among these, stearic acid dimethylaminopropylamide and stearic acid diethylaminoethylamide are preferably used. In the present invention, one kind or two or more kinds can be arbitrarily selected and used from these amidoamine compounds.

The blending amount of the component (A) is preferably 0.1 to 7.0% by mass, more preferably 0.5 to 5.0% by mass in the hair treatment composition of the present invention. is there.
If the amount is less than 0.1% by mass, the hair cannot be imparted with sufficient suppleness, softness and firmness, while 7.0%
If the content exceeds 100% by weight, the hair may be stiff.

The blending amount of the glycerin monofatty acid ester as the component (B) is preferably 0.1 to 5.0% by mass, more preferably 0.3 to 5.0% by mass in the hair treatment composition of the present invention. It is 1.0 mass%. If it is less than 0.1% by mass, it is not possible to impart sufficient suppleness, softness and tightness to the hair, while if it exceeds 5.0% by mass,
May give oily greasiness and stickiness to hair. The preferred glycerin monofatty acid ester in the present invention is oleic acid monoglyceride.

Examples of the organic acid which is the component (C) include citric acid, lactic acid, succinic acid, malic acid, L-glutamic acid, L-aspartic acid and pyrrolidonecarboxylic acid. Among them, citric acid, L -Glutamic acid is particularly preferably used. In the present invention, one kind or two or more kinds can be arbitrarily selected and used from these organic acids.

The blending amount of the component (C) is preferably 0.01 to 6.0% by mass, more preferably 0.01 to 5.0% by mass in the hair treatment composition of the present invention. is there. If it is less than 0.01% by mass or more than 6.0% by mass, a stable hair treatment composition may not be obtained.

In the hair treatment composition of the present invention, if necessary, in addition to the above essential components (A) to (C), other components generally used in the hair treatment composition of the present invention may be added. It can be used within a qualitative and quantitative range that does not impair the effect.

For example, hydrocarbons such as liquid paraffin, petrolatum and squalane; ester oils such as isopropyl myristate and isopropyl palmitate; vegetable oils such as camellia oil, olive oil and avocado oil; polyglycerin fatty acid esters, polyoxyethylene fatty acid esters, Nonionic surfactants such as polyoxyethylene sorbitan monolaurate; cellulose derivatives such as methyl cellulose and hydroxyethyl cellulose; cationized polymers such as cationized cellulose, moisturizers such as propylene glycol and glycerin; polypeptides, preservatives, dandruff Examples include agents, chelating agents, ultraviolet absorbers, dyes, and fragrances, and one or more of these can be arbitrarily selected and blended.

The hair treatment composition according to the present invention means any cosmetics used for the hair, and includes so-called hair cleansing agents such as shampoos, hair rinses, hair treatments, hair packs, hair conditioners and the like. It is widely included. In addition, the type of use, such as a type that is applied to the hair at the time of use and thoroughly rinsed with hair and then rinsed with hot water or the like, or a type that is not rinsed off such as hair cream and hair spray Also includes.

[0020]

EXAMPLES Next, examples and comparative examples of the present invention will be described. The present invention is not limited to these examples. The blending amount is% by mass.

Examples 1 to 4, Comparative Examples 1 and 2 Hair treatment compositions were prepared with the formulations and amounts shown in Table 1 below. The manufacturing method will be described below by taking Example 1 as an example, but other examples were manufactured in the same manner.

(Production Method) Cationized potato starch and cationized cellulose are added to purified water, and the mixture is stirred and dispersed, and then heated to 80 ° C. Glycerin, isopropanol, citric acid and L-glutamic acid are added and dissolved by stirring. Add dimethylamino propylamide stearate and dissolve with stirring. Oleic acid monoglyceride, lecithin, isononyl isononanoate, isostearyl alcohol, hydrogenated rapeseed oil alcohol and aminopropyl dimethicone are sequentially added and emulsified. After adding preservatives, pigments and fragrances, adjust the total amount with purified water and cool.

The hair treatment composition of each Example and each Comparative Example was actually used as a hair rinse as follows, and comparative evaluation was performed. The evaluation results are also shown in Table 1.

(1) Supple sensation samples were used by 10 professional panelists and sensory evaluation was performed on the suppleness of hair during and after use (after towel drying and after drying). The evaluation criteria are as follows. A: A very supple feeling was answered B: A slight supple feeling was answered C: A supple feeling was low

(2) The softness sample was used by 10 professional panelists, and the softness of the hair was sensory evaluated during use and after use (after towel drying and after drying). The evaluation criteria are as follows. A: Very flexible B: Somewhat flexible C: Less flexible

(3) Sit sensation Samples were used by 10 professional panelists and sensory evaluation was performed on the sensation of hair sensation during and after use (after towel drying and after drying). The evaluation criteria are as follows. A: Very sensitive, B: Somewhat sensitive C: Less sensitive

[0027]

[Table 1]

From the evaluation results of Table 1, it can be seen that the hair treatment composition of the present invention has very good suppleness, flexibility and tightness as compared with the conventional products.

[0029] Example 5 Hair rinse       Ingredient amount (% by mass) Stearic acid dimethylaminoethylamide 1.0 Cationized potato starch 0.24 Cationized cellulose 0.1 Hydrogenated rapeseed oil alcohol 6.18 Isononyl isononanoate 0.5 Isostearyl alcohol 1.0 Lecithin 0.1 Oleic acid monoglyceride 0.5 Aminopropyl dimethicone 2.3 Citric acid 0.06 L-glutamic acid 0.66 Glycerin 8.07 Isopropanol 5.0 Preservative Suitable amount Dye suitable amount Fragrance suitable amount Purified water residue

[0030] Example 6 Hair rinse       Ingredient amount (% by mass) Stearic acid dimethylaminoethylamide 1.0 Hydroxyethyl cellulose 0.2 Hydrogenated rapeseed oil alcohol 7.0 Cetyl isooctaate 0.5 Isostearyl alcohol 1.0 Oleic acid monoglyceride 0.5 Dimethicone 5.0 Stearoxymethyl polysiloxane 0.5 Citric acid 0.06 L-glutamic acid 0.66 Glycerin 4.25 Isopropanol 5.0 Preservative Suitable amount Dye suitable amount Fragrance suitable amount Purified water residue

[0031] Example 7 Treatment Hair Pack       Ingredient amount (% by mass) Purified water balance Cetostearyl alcohol 7.00 Behenyl alcohol 5.00 Dimethyl polysiloxane 1000cs 2.00 Cetyl isooctanoate 1.00 Stearic acid dimethylaminoethylamide 3.00 Amount to adjust the pH of DL-glutamic acid system to 4.2 Soy lecithin 0.10 Isoprene glycol 5.00 Oleic acid monoglyceride 0.50 Methylparaben 0.20 Edetic acid 2Na 0.01 Phenoxyethanol 0.20 Mixed fragrance 0.50

(Manufacturing Method) Purified water was heated, an oil agent of higher alcohol or less was added, and the mixture was vigorously stirred. Glutamic acid is added to lower the pH of the system to make it an emulsion, and other ingredients are added and mixed with stirring. After adjusting the particle size of the oil agent to 5 μm or less using a high-efficiency disperser, it is rapidly heated by a heat exchanger. Allow to cool and prepare treatment hair packs.

[0033] Example 8 Hair conditioner       Ingredient amount (% by mass) Purified water balance Cationic polymer 1.00 Cetostearyl alcohol 2.50 Behenyl alcohol 2.00 Partially amino-modified dimethylpolysiloxane (50000cs) 0.20 Dimethyl polysiloxane 20cs 1.80 Isononyl isononanoate 0.50 12-hydroxystearic acid 0.50 Stearic acid dimethylaminoethylamide 0.80 Amount to adjust the pH of DL-glutamic acid system to 4.2 Dipotassium glycyrrhizinate 0.10 Isoprene glycol 3.00 Stearic acid monoglyceride 0.50 Methylparaben 0.20 Seaweed extract 0.10 Phenoxyethanol 0.20 Mixed fragrance 0.50

(Manufacturing Method) Purified water was heated, an oil agent of higher alcohol or less was added, and the mixture was vigorously stirred. Silicones were added after mixing in a separate kettle. PH of system by adding glutamic acid
Is reduced to make an emulsion, other raw materials are added, and the mixture is stirred and mixed, and then the oil agent particles are adjusted to 3 μm or less by using a high efficiency disperser, and then rapidly cooled by a heat exchanger to prepare a hair conditioner.

[0035] Example 9 Hair conditioner       Ingredient amount (% by mass) Purified water balance Cationic polymer 1.00 Stearic acid dimethylaminoethylamide 1.50 Cetostearyl alcohol 1.00 Behenyl alcohol 2.00 Polyoxyethylene (3) stearyl ether 0.20 Dimethyl polysiloxane 6cs 1.80 Isocetyl isostearate 0.50 Stearic acid monoglyceride 0.30 Amount to adjust pH of succinic acid system to 4.2 Non-thermocoagulated egg white 0.01 Hydrogenated egg yolk oil 0.01 Vitamin E acetate 0.01 Soybean extract 0.10 Propylene glycol 10.00 Hydrophobic modified polyether urethane 0.50 Methylparaben 0.20 Phenoxyethanol 0.20 Mixed fragrance 0.50

(Manufacturing method) Purified water was heated, an oil agent of higher alcohol or less was added, and the mixture was vigorously stirred. Add succinic acid to lower the pH of the system to make it an emulsion, add other raw materials, stir and mix, and then use a high efficiency disperser to disperse the oil agent particles to 3 μm.
After being adjusted to m or less, it is rapidly cooled by a heat exchanger to prepare a hair conditioner.

Examples 10-13 Hair Cream

[0038]

[Table 2]

(Production method) 3 is dissolved in 2 and 8 is added here.
What is dissolved is added. Next 1, 4, 5, 6,
A homomixer treatment was carried out while gradually adding a mixture of No. 7 and 15 heated and dissolved at 70 ° C. to emulsify. 13 in which 9 or 10 or 11 or 12 was dissolved was added to the obtained oil-in-water emulsion to obtain a hair cream.

Examples 14 to 17 Hair Cream

[0041]

[Table 3]

(Production method) 3 is dissolved in 2 and 8 is added here.
What is dissolved is added. Next 1, 4, 5, 6,
A homomixer treatment was carried out while gradually adding a mixture of No. 7 and 15 heated and dissolved at 70 ° C. to emulsify. 13 in which 9 or 10 or 11 or 12 was dissolved was added to the obtained oil-in-water emulsion to obtain a hair cream.

Examples 18-21 Hair Spray

[0044]

[Table 4]

(Manufacturing method) 3 is dissolved in 2 and 7 is added here.
What is dissolved is added. Next 1, 4, 5, 6, 1
5 was heated and dissolved at 70 ° C., and a homomixer treatment was carried out while gradually adding what was heated and dissolved to emulsify. By adding 12 to the obtained water-soluble oil type emulsion,
An oil-in-water emulsion was obtained. To this, 12 in which 8 or 9 or 10 or 11 was dissolved was added to prepare a stock solution.
After filling this stock solution, 14 was filled to obtain a hair spray.

Examples 22 to 25 Hair Spray

[0047]

[Table 5]

(Manufacturing method) 3 is dissolved in 2 and 7 is added here.
What is dissolved is added. Next 1, 4, 5, 6, 1
5 was heated and dissolved at 70 ° C., and a homomixer treatment was carried out while gradually adding what was heated and dissolved to emulsify. By adding 12 to the obtained water-soluble oil type emulsion,
An oil-in-water emulsion was obtained. To this, 12 in which 8 or 9 or 10 or 11 was dissolved was added to prepare a stock solution.
After filling this stock solution, 14 was filled to obtain a hair spray.

Examples 26-29 Hair Mousse

[0050]

[Table 6]

(Manufacturing method) 3 is dissolved in 2 and 8 is added here.
What is dissolved is added. Next 1, 4, 5, 6,
Homomixer treatment was carried out while gradually heating and melting Nos. 7 and 16 at 70 ° C to emulsify. An oil-in-water emulsion was obtained by adding 13 to the obtained water-soluble oil emulsion. 9 or 1 for this
13 in which 0, 11 or 12 was dissolved was added to prepare a stock solution. After filling this stock solution, 15 was filled to obtain a hair mousse.

Examples 30 to 33 Hair Mousse

[0053]

[Table 7]

(Manufacturing method) 3 was dissolved in 2 and 8 was added here.
What is dissolved is added. Next 1, 4, 5, 6,
Homomixer treatment was carried out while gradually heating and melting Nos. 7 and 16 at 70 ° C to emulsify. An oil-in-water emulsion was obtained by adding 13 to the obtained water-soluble oil emulsion. 9 or 1 for this
13 in which 0, 11 or 12 was dissolved was added to prepare a stock solution. After filling this stock solution, 15 was filled to obtain a hair mousse.

Examples 34 to 37 Hair Mousse

[0056]

[Table 8]

(Manufacturing method) 3 is dissolved in 2 and 9 to 15 is dissolved therein.
What is dissolved is added. Next 1, 4, 5, 6,
Homomixer treatment was carried out by gradually adding 7, 8 and 17 heated and dissolved at 70 ° C., and emulsified. An oil-in-water emulsion was obtained by adding 14 to the obtained water-soluble oil emulsion. 10 to this
Alternatively, 14 in which 11 or 12 or 13 was dissolved was added to prepare a stock solution. After this stock solution was filled, 16 was filled to obtain a hair mousse.

Examples 38-41 Hair Mousse

[0059]

[Table 9]

(Manufacturing method) 3 is dissolved in 2 and 9 to 15 is dissolved therein.
What is dissolved is added. Next 1, 4, 5, 6,
Homomixer treatment was carried out by gradually adding 7, 8 and 17 heated and dissolved at 70 ° C., and emulsified. An oil-in-water emulsion was obtained by adding 14 to the obtained water-soluble oil emulsion. 10 to this
Alternatively, 14 in which 11 or 12 or 13 was dissolved was added to prepare a stock solution. After this stock solution was filled, 16 was filled to obtain a hair mousse.

[0061]

As is clear from the above description, according to the present invention, there is provided a hair treatment composition capable of imparting to the hair a sufficient suppleness, softness and firmness.

Continued front page    (72) Inventor Katsuo Hashimoto             2-2-1 Hayabuchi, Tsuzuki Ward, Yokohama City, Kanagawa Prefecture             Shiseido Research Center (Shin-Yokohama)             Within F-term (reference) 4C083 AA112 AC022 AC072 AC102                       AC122 AC172 AC182 AC232                       AC292 AC302 AC342 AC402                       AC421 AC422 AC432 AC482                       AC532 AC582 AC641 AC642                       AD042 AD072 AD092 AD132                       AD152 AD162 AD282 AD412                       AD532 AD572 AD662 CC32                       CC33 CC39 DD08 DD27 DD32                       EE06 EE07 EE28

Claims (3)

[Claims] 1. (A) The following general formula (1): R ¹ CONH- (CH ₂ ) m-N (R ² ) ₂ (1) (wherein R ¹ has 13 to 23 carbon atoms). Represents a residue of a higher fatty acid, R ² represents an alkyl group having 1 to 4 carbon atoms, and m represents an integer of 2 to 4), and (B) glycerin monofatty acid ester. And (C) an organic acid. 2. The blending amount of the amidoamine compound is 0.1 to 10.
The amount of glycerin monofatty acid ester is 0.1 to 5.0% by mass, and the amount of organic acid is 0.01 to 6.0% by mass. The hair treatment composition according to claim 1. 3. The hair treatment composition according to claim 1, wherein the glycerin monofatty acid ester is oleic acid monoglyceride.