JP2003146727A - Light weight mortal and solidifying method for radioactive waste using the same - Google Patents

Light weight mortal and solidifying method for radioactive waste using the same

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Publication number
JP2003146727A
JP2003146727A JP2001354071A JP2001354071A JP2003146727A JP 2003146727 A JP2003146727 A JP 2003146727A JP 2001354071 A JP2001354071 A JP 2001354071A JP 2001354071 A JP2001354071 A JP 2001354071A JP 2003146727 A JP2003146727 A JP 2003146727A
Authority
JP
Japan
Prior art keywords
lightweight
weight
mortar
cement
waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001354071A
Other languages
Japanese (ja)
Other versions
JP4059376B2 (en
Inventor
Kazuaki Matsuo
和昭 松尾
Hisanori Umemura
久憲 梅村
Tatsuaki Sato
龍明 佐藤
Naomi Toyohara
尚実 豊原
Masaaki Kaneko
昌章 金子
Kazuji Natsui
和司 夏井
Kuniaki Niihori
邦明 新堀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coorstek KK
Toshiba Engineering Corp
Toshiba Corp
Original Assignee
Toshiba Engineering Corp
Toshiba Corp
Toshiba Ceramics Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Engineering Corp, Toshiba Corp, Toshiba Ceramics Co Ltd filed Critical Toshiba Engineering Corp
Priority to JP2001354071A priority Critical patent/JP4059376B2/en
Publication of JP2003146727A publication Critical patent/JP2003146727A/en
Application granted granted Critical
Publication of JP4059376B2 publication Critical patent/JP4059376B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/14Minerals of vulcanic origin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00086Mixtures with prolonged pot-life
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00767Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes
    • C04B2111/00775Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes the composition being used as waste barriers or the like, e.g. compositions used for waste disposal purposes only, but not containing the waste itself
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00862Uses not provided for elsewhere in C04B2111/00 for nuclear applications, e.g. ray-absorbing concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide light weight mortal wherein satisfactory fluidity can be maintained for a long time and which is excellent in packing properties, low in specific gravity and excellent in strength and the like of the solidified material thereby and to provide a solidifying method for a radioactive waste by which a waste body can be made light in weight. SOLUTION: The light weight mortal is used, consisting of water-hardenable cement, light weight aggregate, a dispersing agent, a separation suppressing agent, a weight lightening promoter and water and characterized in that the light weight aggregate is formed by mixing an igneous rock calcined material and an obsidian calcined material.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、軽量モルタルおよ
びそれを用いた放射性廃棄物の固化方法に関し、より詳
細には、原子力発電所のような放射性物質を取り扱う施
設から発生する金属やコンクリート等の大型雑廃棄物を
充填固化処理するために好適に用いられる軽量モルタル
およびそれを用いた放射性廃棄物の固化方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a lightweight mortar and a method for solidifying radioactive waste using the same, and more specifically, it relates to a method for solidifying metal such as metal or concrete generated from a facility handling radioactive materials such as a nuclear power plant. The present invention relates to a lightweight mortar that is preferably used for filling and solidifying large-scale miscellaneous waste and a method for solidifying radioactive waste using the same.

【0002】[0002]

【従来の技術】原子力発電所等の原子力施設からは、濃
縮廃液等を乾燥させ、粉体化した後、ペレット状に成形
したもの、金属切断片、フィルター、パッキン、コンク
リート塊のような固体の放射性雑廃棄物が多く発生す
る。このような廃棄物は、例えば、200リットルのド
ラム缶に充填可能なように適当なサイズに切断して収容
保管され、固化処理される。この固化処理の方法とし
て、廃棄物を収容したドラム缶内に、固化材としてセメ
ントモルタルを流し込み、ドラム缶と廃棄物の間の空隙
や廃棄物同士の間の空隙に充填させて固化する方法が考
えられており、このようにして固化された廃棄体の処分
が、一部では開始されている。
2. Description of the Related Art From nuclear facilities such as nuclear power plants, concentrated waste liquid is dried, pulverized, and then molded into pellets, solid pieces such as metal cutting pieces, filters, packings and concrete blocks. A lot of radioactive miscellaneous waste is generated. Such waste is cut and stored in an appropriate size so that it can be filled in, for example, a 200-liter drum, and then stored and solidified. As a method of this solidification treatment, a method is considered in which cement mortar is poured as a solidifying material into a drum containing waste, and the mixture is solidified by filling voids between the drum and waste or voids between wastes. The disposal of waste solidified in this way has started in some areas.

【0003】また、今後、原子力発電所の老朽化等に伴
い、その設備等の解体時に大型の廃棄物が大量に発生す
ると予想されるが、これらの廃棄物については、廃棄物
に固化材を直接充填するか、または、1m3 以上の大型
容器に収容した後、固化材を充填して、処分場に輸送し
て処分する方法が考えられている。
Further, it is expected that a large amount of large-scale waste will be generated at the time of dismantling the facilities of the nuclear power plant due to deterioration of the nuclear power plant, etc. A method of directly filling or storing in a large container of 1 m 3 or more, filling a solidifying material, and transporting to a disposal site for disposal is considered.

【0004】ところで、セメント系の固化材について
は、セメントに水を混ぜてセメントペーストとして使用
する方法、セメントに砂(細骨材)と水を混ぜてセメン
トモルタルにして使用する方法、あるいは、セメントに
砂(細骨材)と砂利(粗骨材)と水を混ぜてコンクリー
トにして使用する方法等が、土木建築業界では一般的で
ある。この中でも、原子力施設から発生する放射性雑廃
棄物については、一般に、セメントモルタルを充填する
ことにより、固化処理が行われている。
By the way, as for the cement-based solidifying material, a method of mixing water with cement to use it as a cement paste, a method of mixing sand (fine aggregate) and water with cement to form cement mortar, or cement In general, the method of mixing sand (fine aggregate), gravel (coarse aggregate), and water to form concrete is used in the civil engineering and construction industry. Among these, radioactive miscellaneous waste generated from nuclear facilities is generally solidified by filling cement mortar.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、上記の
ような、原子力発電所等の解体により発生する大型の放
射性廃棄物の固化処理の場合には、従来のセメントモル
タルを固化材として使用すると、その比重が大きすぎる
ため、重量規制の範囲を超えてしまい、廃棄体を吊り上
げたり、輸送することが困難になるおそれがある。ま
た、多大な設備または施設の使用が必要となるために、
コスト高となることが懸念される。
However, in the case of the solidification treatment of large radioactive waste generated by the dismantling of a nuclear power plant or the like as described above, when conventional cement mortar is used as the solidifying material, Since the specific gravity is too large, the weight regulation may be exceeded, and it may be difficult to lift or transport the waste. Also, since it requires the use of a large amount of equipment or facilities,
There is concern that costs will increase.

【0006】さらにまた、金属片やコンクリート塊等の
重量廃棄物を充填固化する際には、処分容器の耐久強度
等の関係から、1つの処分容器に収容する廃棄物の処理
量を著しく制限して、固化廃棄体の重量を抑える必要が
あると考えられる。このような廃棄物の処理量の制限
は、廃棄体の数の増加につながり、処分コストが高くな
るだけでなく、保管するための敷地面積の拡大や管理棟
の増設等が必要となる。このことは、諸外国と異なり、
国土面積に恵まれない日本においては深刻な問題であ
り、廃棄体の数を削減することに関しては、原子力事業
そのものを根底から翻すことにもなりかねず、今後の重
要な課題である。
Furthermore, when filling and solidifying heavy waste such as metal pieces and concrete lumps, the amount of waste to be stored in one disposal container is significantly limited due to the durability of the disposal container. Therefore, it is considered necessary to reduce the weight of the solidified waste. Such limitation of the amount of waste to be processed leads to an increase in the number of wastes, which not only increases the disposal cost, but also requires the expansion of the site area for storage and the addition of a management building. This is different from other countries
It is a serious problem in Japan, which is not endowed with a small land area, and reducing the number of waste will be an important issue in the future, as it could lead to the restructuring of the nuclear power business itself.

【0007】そこで、本発明者らは、廃棄体の軽量化を
図るために、固化材の軽量化を図ることに着目した。一
般に、セメントモルタルやコンクリートを軽量化するた
めには、軽量骨材を用いるか、または、気泡を注入して
固化体を軽量化する技術が用いられている。したがっ
て、このような技術を廃棄物の固化材に適用することも
考えられるが、この場合、モルタルについては、土木学
会で規定されているPロートによる流下時間が16〜5
0秒程度という高い流動性が求められ、しかも、1.5
MPa程度以上の強度が固化体に要求される。このた
め、廃棄物の固化材において、軽量骨材を用いたモルタ
ルの流動性を高くすると、廃棄物との比重差により、軽
量骨材が浮上分離してしまい、均一な固化体とすること
は困難である。また、気泡を注入する方法においては、
固化体の強度が低下することが課題となる。
Therefore, the present inventors have paid attention to reducing the weight of the solidifying material in order to reduce the weight of the waste. Generally, in order to reduce the weight of cement mortar and concrete, a technique of using a lightweight aggregate or injecting bubbles to reduce the weight of a solidified body is used. Therefore, it is conceivable to apply such a technique to a solidifying material for waste, but in this case, regarding the mortar, the run-down time by the P funnel specified by the Japan Society of Civil Engineers is 16 to 5
High fluidity of about 0 seconds is required and 1.5
The solidified body is required to have a strength of about MPa or higher. Therefore, in the solidified material of waste, if the fluidity of the mortar using the lightweight aggregate is increased, the lightweight aggregate is floated and separated due to the difference in specific gravity from the waste, and a uniform solidified body is not obtained. Have difficulty. In addition, in the method of injecting bubbles,
The problem is that the strength of the solidified body is reduced.

【0008】本発明は、上記技術的課題を解決するため
になされたものであり、良好な流動性を長時間維持する
ことができ、充填性に優れているとともに、比重が小さ
く、かつ、固化体の強度特性等に優れた軽量モルタルを
提供することを目的とするものである。
The present invention has been made in order to solve the above technical problems, and can maintain good fluidity for a long time, has excellent filling properties, has a small specific gravity, and solidifies. It is an object of the present invention to provide a lightweight mortar having excellent body strength characteristics and the like.

【0009】また、本発明の他の目的は、前記軽量モル
タルを用いて、充填性および固化体の強度特性に優れて
おり、しかも、廃棄体の軽量化を図ることができる放射
性廃棄物の固化方法を提供することである。
Another object of the present invention is to solidify radioactive waste by using the above-mentioned lightweight mortar, which has excellent filling properties and strength properties of the solidified product, and which can reduce the weight of the waste product. Is to provide a method.

【0010】[0010]

【課題を解決するための手段】本発明に係る軽量モルタ
ルは、水硬性セメント、軽量骨材、分散剤、分離抑制
剤、軽量化助剤および水からなる軽量モルタルであっ
て、前記軽量骨材は、火成岩焼成加工品と黒曜岩焼成加
工品とが混合されたものであることを特徴とする。この
ような原料を配合することにより、流動性、充填性に優
れているとともに比重が小さく、かつ、固化体の強度特
性等においても優れた軽量モルタルが得られる。
The lightweight mortar according to the present invention is a lightweight mortar comprising a hydraulic cement, a lightweight aggregate, a dispersant, a separation inhibitor, a weight reduction aid and water. Is characterized by being a mixture of an igneous fired product and an obsidian fired product. By blending such raw materials, it is possible to obtain a lightweight mortar which is excellent in fluidity and filling properties, has a small specific gravity, and is excellent in the strength characteristics of the solidified body and the like.

【0011】前記軽量モルタルにおいては、前記軽量骨
材の粒径が、1.2mm以下であることが好ましい。狭
小な空隙においても十分な充填性を担保するために、上
記範囲の小さい粒径の軽量骨材を用いることが好まし
い。
In the lightweight mortar, it is preferable that the particle diameter of the lightweight aggregate is 1.2 mm or less. In order to ensure a sufficient filling property even in a narrow void, it is preferable to use a lightweight aggregate having a particle size in the above range.

【0012】また、前記水硬性セメントは、ポルトラン
ドセメント、または、高炉スラグもしくはフライアッシ
ュを含むセメントであることが好ましい。高炉スラグ
は、軽量モルタルの化学的安定性の向上および固化時の
発熱抑制に寄与するものであり、また、フライアッシュ
は、軽量モルタルの流動性および充填性の向上に寄与す
るものであることによる。
The hydraulic cement is preferably Portland cement or cement containing blast furnace slag or fly ash. Blast furnace slag contributes to improving the chemical stability of lightweight mortar and suppressing heat generation during solidification, and fly ash contributes to improving the fluidity and filling of lightweight mortar. .

【0013】さらに、前記分離抑制剤は、モンモリロナ
イトを主成分とするベントナイトであることが好まし
い。該分離抑制剤は、セメントスラリーと軽量骨材との
分離防止や固化体の容積安定性を付与するために添加さ
れるものである。
Further, the separation inhibitor is preferably bentonite containing montmorillonite as a main component. The separation inhibitor is added to prevent the cement slurry from separating from the lightweight aggregate and to impart volume stability to the solidified body.

【0014】さらにまた、前記軽量化助剤は、ラウリル
硫酸ナトリウムであることが好ましい。該軽量化助剤
は、エマルジョン化作用により、軽量モルタルの一層の
低比重化を図り、また、軽量骨材の配合量を低減させる
ことに寄与するものである。
Furthermore, the weight saving aid is preferably sodium lauryl sulfate. The weight-reducing aid contributes to further lowering the specific gravity of the light mortar and reducing the blending amount of the lightweight aggregate due to the emulsifying action.

【0015】また、前記分散剤は、ナフタリンスルホン
酸系の分散剤であることが好ましい。該分散剤は、良好
な流動性を付与するためのものであり、作業性の観点か
らも、添加することが好ましい。
Further, the dispersant is preferably a naphthalene sulfonic acid type dispersant. The dispersant is for imparting good fluidity, and is preferably added also from the viewpoint of workability.

【0016】また、前記軽量モルタルは、水硬性セメン
トに対して、火成岩焼成加工軽量骨材が5〜15重量
%、黒曜岩焼成加工軽量骨材が10〜30重量%、分散
剤が0.5〜2.0重量%、分離抑制剤が5〜15重量
%、軽量化助剤が0.01〜0.05重量%含まれてい
ることが好ましい。本発明に係る軽量モルタルを調整す
るための処方として、好適な原料配合組成である。
The light weight mortar contains 5 to 15% by weight of igneous calcinated lightweight aggregate, 10 to 30% by weight of obsidian calcinated lightweight aggregate, and 0. It is preferable that 5 to 2.0% by weight, a separation inhibitor of 5 to 15% by weight, and a weight saving aid of 0.01 to 0.05% by weight are contained. The composition of raw materials is suitable as a formulation for adjusting the lightweight mortar according to the present invention.

【0017】前記軽量モルタルの比重が1.00g/c
3 以下であり、かつ、該軽量モルタルの固化体の圧縮
強度が1.5MPa以上であることが好ましい。上記比
重および固化体の圧縮強度を満たす軽量モルタルであれ
ば、軽量性および強度特性に優れたモルタルとして、廃
棄物の固化処理にも好適に用いることができる。
The specific gravity of the lightweight mortar is 1.00 g / c
It is preferable that m 3 or less and the compressive strength of the solidified mortar is 1.5 MPa or more. A lightweight mortar satisfying the specific gravity and the compressive strength of the solidified body can be suitably used for solidification treatment of waste as a mortar excellent in lightweightness and strength characteristics.

【0018】本発明に係る放射性廃棄物の固化方法は、
上記軽量モルタルを充填して固化することを特徴とす
る。本発明に係る軽量モルタルは、上記のように、流動
性、充填性、軽量性および固化体の強度特性にも優れて
いるため、これを用いて、放射性廃棄物を処理すること
により、廃棄体の軽量化、さらには、廃棄体数の削減に
寄与することができる。
The method for solidifying radioactive waste according to the present invention is
It is characterized in that the above-mentioned lightweight mortar is filled and solidified. As described above, the lightweight mortar according to the present invention is excellent in fluidity, filling property, lightweight property and strength property of the solidified body. Therefore, by treating the radioactive waste with the waste mortar, It is possible to contribute to the reduction of weight and the reduction of the number of waste.

【0019】[0019]

【発明の実施の形態】以下、本発明を詳細に説明する。
本発明に係る軽量モルタルは、水硬性セメントと、火成
岩焼成加工品と黒曜岩焼成加工品とを混合した軽量骨材
と、分散剤と、分離抑制剤と、軽量化助剤と水とが配合
されたものである。このような原料配合組成とすること
により、高い流動性、充填性を有するとともに、比重が
小さく、かつ、固化体の強度特性等においても優れた軽
量モルタルとすることができる。
BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below.
The lightweight mortar according to the present invention comprises a hydraulic cement, a lightweight aggregate obtained by mixing an igneous calcination processed product and an obsidian calcination processed product, a dispersant, a separation inhibitor, a lightweighting aid and water. It has been compounded. With such a raw material composition, it is possible to obtain a lightweight mortar having high fluidity and filling properties, a small specific gravity, and excellent strength properties of the solidified body.

【0020】本発明においては、軽量骨材は、火成岩焼
成加工品と黒曜岩焼成加工品とを混合して用いる。特
に、水硬性セメントに対して、火成岩焼成加工品が5〜
15重量%、黒曜岩焼成加工品が10〜30重量%の範
囲で混合して配合されることが好ましい。これらの2種
の軽量骨材を上記割合で混合して配合することにより、
それぞれを単独で添加する場合よりも、軽量骨材の添加
量を低減させることができるとともに、モルタルの密度
を大幅に低下させることができ、軽量モルタルとしての
密度の目標値である1.0g/cm3 以下を達成するこ
とができる。
In the present invention, the lightweight aggregate is used by mixing a igneous rock baked product and an obsidian baked product. Especially for hydraulic cement, igneous rock firing processed products are 5
It is preferable to mix 15% by weight and the obsidian calcined product in the range of 10 to 30% by weight. By mixing and blending these two types of lightweight aggregates in the above proportions,
Compared with the case where each is added alone, the addition amount of the lightweight aggregate can be reduced, and the density of the mortar can be significantly reduced, and the target value of the density of the lightweight mortar is 1.0 g / cm 3 or less can be achieved.

【0021】火成岩焼成加工軽量骨材を単独で15重量
%を超えて配合した場合、該骨材の吸水性の関係から、
多量の混練水を必要とし、このため、固化体の強度が低
下する。また、比重差から軽量骨材が浮上して分離しや
すくなるという不都合が生じる。一方、黒曜岩焼成加工
軽量骨材は中空状を呈しており、吸水性は、火成岩焼成
加工軽量骨材に比べてはるかに低く、このため、30重
量%を超えて配合すると、モルタルの粘性の関係から、
該骨材が固化体上部に浮上して、固化体の均質性を損ね
ることとなる。
When the igneous rock-fired lightweight aggregate alone is blended in an amount of more than 15% by weight, due to the water absorption of the aggregate,
A large amount of kneading water is required, which reduces the strength of the solidified body. In addition, due to the difference in specific gravity, a disadvantage occurs that the lightweight aggregate is easily floated and separated. On the other hand, the obsidian calcined lightweight aggregate has a hollow shape, and its water absorption is much lower than that of the igneous calcined lightweight aggregate. Therefore, if it exceeds 30% by weight, the viscosity of the mortar will increase. From the relationship
The aggregate floats above the solidified body and impairs the homogeneity of the solidified body.

【0022】また、前記軽量骨材は、火成岩焼成加工
品:黒曜岩焼成加工品=1:2(重量比)の割合で配合
されることが好ましい。このような配合比率とすること
により、軽量かつ均質であり、かつ、強度特性に優れた
固化体を得ることができる。
It is preferable that the lightweight aggregate is blended in a ratio of igneous fired product: obsidian fired product = 1: 2 (weight ratio). With such a blending ratio, it is possible to obtain a solidified body that is lightweight and homogeneous and has excellent strength characteristics.

【0023】また、前記軽量骨材の粒径は、いずれも
1.2mm以下であることが好ましい。モルタルは、廃
棄物の固化処理に用いられる場合、廃棄物同士の間の小
さい空隙に十分に充填される必要があり、粒径が1.2
mmを超える場合には、この充填性が不十分となる。
Further, the particle diameter of each of the lightweight aggregates is preferably 1.2 mm or less. Mortar, when used for solidification of waste, needs to be well filled in the small voids between wastes and has a particle size of 1.2.
If it exceeds mm, this filling property becomes insufficient.

【0024】本発明において用いられる水硬性セメント
としては、ポルトランドセメント、または、高炉スラグ
もしくはフライアッシュを含むセメントであることが好
ましい。具体的には、ポルトランドセメント、ポルトラ
ンドセメントに高炉スラグが配合された高炉セメント、
ポルトランドセメントにフライアッシュが配合されたフ
ライアッシュセメント等を用いることができる。
The hydraulic cement used in the present invention is preferably Portland cement or cement containing blast furnace slag or fly ash. Specifically, Portland cement, blast furnace cement that is a mixture of Portland cement and blast furnace slag,
Fly ash cement obtained by mixing fly ash with Portland cement can be used.

【0025】上記のように、水硬性セメントは、高炉ス
ラグを含むものが好ましいが、これは、化学的安定性の
向上および固化時の発熱を抑制することができるという
点で、優れた効果が得られることによるものである。モ
ルタルを用いて、大型廃棄物の充填固化処理等を行う場
合、充填する水硬性セメントも多量に必要となり、固化
時の熱容量が増大して、発熱により高温となる。特に、
金属廃棄物の場合には、その熱膨張により、亀裂が発生
しやすい。したがって、高炉スラグを配合した水硬性セ
メントを用いることによって、固化時の発熱量を抑制す
ることができ、これにより、上記亀裂の発生を防止する
効果も奏する。この場合の高炉スラグの配合量は、上記
効果の観点から、ポルトランドセメント:高炉スラグ=
7:3〜2:8(重量比)の範囲で混合することが好ま
しい。したがって、JIS規格により定められた高炉セ
メントのB種(高炉スラグ30〜60%配合)およびC
種(同60〜70%配合)を用いることもできる。
As described above, the hydraulic cement preferably contains blast-furnace slag, but this has an excellent effect in that the chemical stability can be improved and the heat generation during solidification can be suppressed. This is because it is obtained. When mortar is used for filling and solidifying large-scale waste, a large amount of hydraulic cement to be filled is also required, the heat capacity at the time of solidification increases, and the temperature rises due to heat generation. In particular,
In the case of waste metal, cracks are likely to occur due to its thermal expansion. Therefore, by using the hydraulic cement mixed with the blast furnace slag, it is possible to suppress the amount of heat generated during solidification, which also has the effect of preventing the occurrence of cracks. The blending amount of blast furnace slag in this case is, from the viewpoint of the above effects, Portland cement: blast furnace slag =
It is preferable to mix in the range of 7: 3 to 2: 8 (weight ratio). Therefore, Class B blast furnace cement (Blast furnace slag content of 30 to 60%) and C defined by JIS standard
It is also possible to use a seed (60 to 70% by weight).

【0026】また、水硬性セメントとして、フライアッ
シュを含むものも好適に用いることができるが、これ
は、フライアッシュ自体が球形状であることから、モル
タルの流動性の向上および充填性の向上に寄与するた
め、細管等の狭小な空隙にモルタルを充填する上で効果
的であることによるものである。この場合のフライアッ
シュの配合量は、上記効果の観点から、ポルトランドセ
メント:フライアッシュ=9.5:0.5〜7:3(重
量比)の範囲で混合することが好ましい。したがって、
JIS規格により定められたフライアッシュセメントの
A種(フライアッシュ5〜10%配合)、B種(同10
〜20%配合)、C種(同20〜30%配合)を用いる
こともできる。
As the hydraulic cement, one containing fly ash can also be preferably used. However, since the fly ash itself has a spherical shape, it improves the fluidity of the mortar and the filling property thereof. This is because it contributes and is effective in filling a narrow space such as a narrow tube with mortar. In this case, the blending amount of fly ash is preferably in the range of Portland cement: fly ash = 9.5: 0.5 to 7: 3 (weight ratio) from the viewpoint of the above effects. Therefore,
Fly ash cement type A (fly ash 5-10% blended), type B (same 10) specified by JIS standard.
.About.20% blending) and C type (the same 20-30% blending) can also be used.

【0027】上記のような水硬性セメントおよび軽量骨
材を混合し、混練する際に、分散剤を添加する。良好な
流動性を付与するためのものであり、特に、ナフタリン
スルホン酸系の分散剤が好ましい。この分散剤の添加量
は、水硬性セメントに対して、0.5〜2.0重量%の
範囲であることが好ましい。前記添加量が0.5重量%
未満である場合は、モルタルスラリーの良好な流動性
(Pロート流下時間基準値:50秒以下)を得ることが
困難である。一方、前記添加量が2重量%を超える場合
は、その添加量に見合う効果を得ることはできず、モル
タルのコストアップにつながる。
When the hydraulic cement and the lightweight aggregate as described above are mixed and kneaded, a dispersant is added. It is for imparting good fluidity, and a naphthalenesulfonic acid-based dispersant is particularly preferable. The amount of the dispersant added is preferably in the range of 0.5 to 2.0% by weight based on the hydraulic cement. 0.5% by weight
If it is less than the above, it is difficult to obtain good fluidity of the mortar slurry (P funnel flow time reference value: 50 seconds or less). On the other hand, if the addition amount exceeds 2% by weight, the effect corresponding to the addition amount cannot be obtained, leading to an increase in the cost of the mortar.

【0028】また、分離抑制剤は、セメントスラリーと
軽量骨材との分離防止や固化体の容積安定性を付与する
ために添加されるものであり、モンモリロナイトを主成
分とするベントナイトが好適に用いられる。この分離抑
制剤の添加量は、水硬性セメントに対して、5〜15重
量%の範囲であることが好ましい。前記添加量が5重量
%未満である場合は、軽量骨材と結合材であるセメント
スラリーとの間に分離現象が生じ、固化体上部に軽量骨
材が浮上する不都合が生じる。一方、前記添加量が15
重量%を超える場合は、モルタルの粘性が極端に上昇
し、混練水の増加とともに固化体の強度が低下すること
となる。
The separation inhibitor is added to prevent separation of the cement slurry from the lightweight aggregate and to impart volume stability of the solidified body, and bentonite containing montmorillonite as a main component is preferably used. To be The amount of the separation inhibitor added is preferably in the range of 5 to 15% by weight based on the hydraulic cement. When the addition amount is less than 5% by weight, a phenomenon of separation occurs between the lightweight aggregate and the cement slurry as the binder, and the lightweight aggregate floats above the solidified body. On the other hand, if the addition amount is 15
If it exceeds 5% by weight, the viscosity of the mortar increases extremely, and the strength of the solidified product decreases with an increase in kneading water.

【0029】また、軽量化助剤としては、ラウリル硫酸
ナトリウム(C1225・OSO3 Na)を用いることが
好ましい。ラウリル硫酸ナトリウムは、白色粉末状であ
り、混練水を添加すると、エマルジョン化して、軽量モ
ルタルの一層の低比重化を図ることができるとともに、
この添加によって、軽量骨材の配合量を低減させること
ができる。このラウリル硫酸ナトリウムの添加量は、水
硬性セメントに対して、0.01〜0.05重量%の範
囲であることが好ましい。前記添加量が0.01重量%
未満である場合、モルタルの軽量化を十分に図ることが
できない。一方、前記添加量が0.05重量%を超える
場合、混練水の増加に伴う固化体の強度の低下およびモ
ルタルの流動性の低下を招くこととなる。
Further, it is preferable to use sodium lauryl sulfate (C 12 H 25 .OSO 3 Na) as the weight saving aid. Sodium lauryl sulfate is in the form of a white powder, and when kneading water is added, it becomes an emulsion and can further reduce the specific gravity of the lightweight mortar,
This addition can reduce the amount of the lightweight aggregate compounded. The amount of sodium lauryl sulfate added is preferably in the range of 0.01 to 0.05% by weight based on the hydraulic cement. The addition amount is 0.01% by weight
If it is less than the above range, the weight of the mortar cannot be sufficiently reduced. On the other hand, when the addition amount exceeds 0.05% by weight, the strength of the solidified body and the fluidity of the mortar are lowered with the increase of the kneading water.

【0030】上記のように、前記軽量モルタルの好適な
原料配合組成は、水硬性セメントに対して、火成岩焼成
加工軽量骨材が5〜15重量%、黒曜岩焼成加工軽量骨
材が10〜30重量%、分散剤が0.5〜2.0重量
%、分離抑制剤が5〜15重量%、軽量化助剤が0.0
1〜0.05重量%含まれるものである。
As described above, the preferred raw material composition of the lightweight mortar is 5 to 15% by weight of igneous rock-calcined lightweight aggregate and 10 to 10% of obsidian calcined lightweight aggregate with respect to hydraulic cement. 30% by weight, 0.5 to 2.0% by weight of dispersant, 5 to 15% by weight of separation inhibitor, 0.0 of a weight reduction aid.
1 to 0.05% by weight is contained.

【0031】上記ような原料配合組成からなる軽量モル
タルの比重は1.00g/cm3 以下と低比重であり、
また、該軽量モルタルを養生させて得られた固化体の圧
縮強度は1.5MPa以上と高強度であるという特徴を
有する。すなわち、廃棄物の充填固化材として用いられ
るために要求されるモルタルの固化体の物性を満たすも
のである。
The specific gravity of the lightweight mortar having the above raw material composition is as low as 1.00 g / cm 3 or less,
In addition, the solidified body obtained by curing the lightweight mortar has a characteristic that the compression strength is as high as 1.5 MPa or more. That is, it satisfies the physical properties of the solidified mortar required to be used as a filling and solidifying material for waste.

【0032】したがって、上述した本発明に係る軽量モ
ルタルは、放射性廃棄物を固化処理する際に、好適に用
いることができる。その固化処理工程としては、まず、
水硬性セメントをベースとして、これに軽量骨材を配合
し、混合した後、分離抑制剤、軽量化助剤、分散剤、混
練水を添加し、ミキサー等で混練することにより、軽量
モルタルを得る。そして、得られた軽量モルタルを、放
射性廃棄物内に直接、または、予め放射性廃棄物が収容
された処分容器内に充填して固化させる。この廃棄物の
固化体(廃棄体)は、処分場に輸送されて処分される。
このように、本発明に係る軽量モルタルを用いて、放射
性廃棄物を固化処理することによって、従来の一般的な
モルタルで固定化されていた廃棄体に比べて、廃棄体を
大幅に軽量化させることができる。さらに、上記軽量モ
ルタルを用いることにより、大型の金属廃棄物の充填固
化の際にも、発熱が少ないことから、固化体に亀裂が発
生することがなく、また、細管等の狭小な空隙を多く含
む廃棄物の場合にも、十分に空隙に充填されるため、軽
量かつ均質であり、かつ、高強度の固化体を得ることが
できる。
Therefore, the above-described lightweight mortar according to the present invention can be preferably used when solidifying radioactive waste. As the solidification process, first,
Based on hydraulic cement, a lightweight aggregate is blended with this, and after mixing, a separation inhibitor, a weight-reducing aid, a dispersant, and kneading water are added, and a lightweight mortar is obtained by kneading with a mixer or the like. . Then, the obtained lightweight mortar is directly filled in the radioactive waste or is filled in a disposal container in which the radioactive waste is stored in advance to be solidified. The solidified body (waste body) of this waste is transported to the disposal site for disposal.
Thus, by solidifying the radioactive waste by using the lightweight mortar according to the present invention, the weight of the waste can be significantly reduced as compared with the waste that has been fixed by the conventional general mortar. be able to. Furthermore, by using the above-mentioned lightweight mortar, even when filling and solidifying a large-scale metal waste, since there is little heat generation, cracks do not occur in the solidified body, and there are many narrow voids such as thin tubes. Even in the case of the waste containing, since the voids are sufficiently filled, it is possible to obtain a solidified body which is lightweight and homogeneous and has high strength.

【0033】[0033]

【実施例】以下、本発明を実施例に基づきさらに具体的
に説明するが、本発明は下記の実施例により制限される
ものではない。 [実施例1]水硬性セメントとしてポルトランドセメン
トを用いて、この水硬性セメントに対して、粒径0.6
mm以下の火成岩焼成加工軽量骨材6.7重量%と粒径
1.2mm以下の黒曜岩焼成加工軽量骨材13.3重量
%を混合したもの(混合比1:2)を軽量骨材として配
合し、混合した後、さらに、ナフタリンスルホン酸系分
散剤1重量%、分離抑制剤としてベントナイト10重量
%、軽量化助剤としてラウリル硫酸ナトリウム0.03
重量%を添加し、水を加えて混練してモルタルを調製し
た。得られたモルタルのPロート流下時間および比重を
20℃にて測定した。さらに、各モルタルを28日間養
生させて得られた固化体の諸特性(ブリージング率、体
積変化率、圧縮強度)および外観を20℃にて評価し
た。その評価結果を表1に示す。なお、表1に示す目標
値は、廃棄物の固化材として用いられるモルタルに要求
される各物性値である。
EXAMPLES The present invention will be described in more detail based on the following examples, but the invention is not intended to be limited by the following examples. [Example 1] Portland cement was used as the hydraulic cement, and the particle size was 0.6 with respect to the hydraulic cement.
mm igneous rock calcination processed lightweight aggregate 6.7 wt% and obsidian calcination light weight aggregate 13.3 wt% 13.3 wt% mixed (mixing ratio 1: 2) is a lightweight aggregate As a naphthalenesulfonic acid-based dispersant 1% by weight, bentonite as a separation inhibitor 10% by weight, and sodium lauryl sulfate 0.03 as a weight-reducing aid.
A mortar was prepared by adding wt% and kneading with water. The P funnel flow time and the specific gravity of the obtained mortar were measured at 20 ° C. Further, various characteristics (breathing rate, volume change rate, compressive strength) and appearance of the solidified body obtained by curing each mortar for 28 days were evaluated at 20 ° C. The evaluation results are shown in Table 1. The target values shown in Table 1 are physical property values required for mortar used as a solidifying material for waste.

【0034】[実施例2]水硬性セメントとして高炉セ
メントB種を用いて、それ以外については、実施例1と
同様にして、モルタルを調製し、各物性評価を行った。
その評価結果を表1に示す。また、実施例2を代表とし
て、モルタルのPロート流下時間の経時変化を測定し
た。その結果を図1に線図として示す。図1において、
縦軸はPロート流下時間、横軸は混練後の経過時間を表
す。
Example 2 A mortar was prepared and physical properties were evaluated in the same manner as in Example 1 except that blast furnace cement type B was used as the hydraulic cement.
The evaluation results are shown in Table 1. In addition, the change over time of the P funnel flow time of the mortar was measured by using Example 2 as a representative. The result is shown as a diagram in FIG. In FIG.
The vertical axis represents the P funnel flow time, and the horizontal axis represents the elapsed time after kneading.

【0035】[実施例3]水硬性セメントとしてフライ
アッシュセメントを用いて、それ以外については、実施
例1と同様にして、モルタルスラリーを調製し、各物性
評価を行った。その評価結果を表1に示す。
Example 3 Fly ash cement was used as the hydraulic cement, and otherwise the mortar slurry was prepared in the same manner as in Example 1 and each physical property was evaluated. The evaluation results are shown in Table 1.

【0036】[実施例4〜9]表1の実施例4〜9に示
したような軽量骨材、分散剤、分離抑制剤、軽量化助
剤、混練水の配合量として、それ以外については、実施
例2と同様にして、モルタルスラリーを調製し、各物性
評価を行った。その評価結果を表1、2に示す。
[Examples 4 to 9] As for the lightweight aggregate, the dispersant, the separation inhibitor, the weight reduction aid, and the mixing amount of the kneading water as shown in Examples 4 to 9 of Table 1, other than that, A mortar slurry was prepared and each physical property was evaluated in the same manner as in Example 2. The evaluation results are shown in Tables 1 and 2.

【0037】[0037]

【表1】 [Table 1]

【0038】[0038]

【表2】 [Table 2]

【0039】表1、2に示したように、水硬性セメント
としてポルトランドセメントを用いた場合(実施例
1)、モルタルの比重が0.92g/cm3 、流動性を
表すPロート流下時間が29秒、固化体の圧縮強度が8
MPaであり、いずれも目標値を満たす結果が得られ
た。また、固化体にブリージングも見られず、良好な固
化体が得られることが認められた。また、水硬性セメン
トとして高炉セメントまたはフライアッシュセメントを
用いた場合(実施例2、3)も、流動性や固化体特性
は、ポルトランドセメントを用いた場合(実施例1)と
ほぼ同等であり、いずれも目標を満たすものであること
が認められた。さらに、図1に示したように、本発明に
係る軽量モルタルは、初期の流動性を2時間以上にわた
る長時間維持することができることが確認された。
As shown in Tables 1 and 2, when Portland cement was used as the hydraulic cement (Example 1), the specific gravity of the mortar was 0.92 g / cm 3 , and the P funnel flow time showing the fluidity was 29. Second, the compression strength of the solidified body is 8
It was MPa, and all obtained results satisfying the target value. Further, it was confirmed that no bleeding was observed in the solidified product and that a good solidified product was obtained. Also, when blast furnace cement or fly ash cement is used as the hydraulic cement (Examples 2 and 3), the fluidity and solidified body properties are almost the same as when Portland cement is used (Example 1), It was recognized that all of them met the goals. Further, as shown in FIG. 1, it was confirmed that the lightweight mortar according to the present invention can maintain the initial fluidity for a long time of 2 hours or more.

【0040】また、軽量骨材として、火成岩焼成加工
品:黒曜岩焼成加工品=1:2(重量比)で、水硬性セ
メントに対して、合計20重量%添加したモルタル(実
施例1〜3、6〜9)は、いずれも目標とする性能を得
られることが認められた。また、同様の組成からなる軽
量骨材を、合計15重量%添加した場合(実施例4)、
または、合計45重量%添加した場合(実施例5)も、
目標とする性能が得られたが、モルタル比重および固化
体の圧縮強度の観点から、軽量骨材(火成岩焼成加工
品:黒曜岩焼成加工品=1:2)の配合量は、水硬性セ
メントに対して、15〜45重量%であることが好まし
いと言える。また、軽量化助剤の添加量を増加させるこ
とにより、モルタル比重を低減させることはできるが、
固化体の圧縮強度の観点から、軽量化助剤の添加量は、
水硬性セメントに対して、0.01〜0.05重量%の
範囲であることが好ましい。
As a lightweight aggregate, calcinated igneous product: obsidian calcinated product = 1: 2 (weight ratio), and added 20% by weight in total to the hydraulic cement (Examples 1 to 1). It has been confirmed that the target performances can be obtained in all of Nos. 3, 6 to 9). When a total of 15% by weight of lightweight aggregate having the same composition is added (Example 4),
Alternatively, when a total of 45% by weight is added (Example 5),
Although the target performance was obtained, from the viewpoint of the specific gravity of the mortar and the compressive strength of the solidified body, the blending amount of the lightweight aggregate (calcined igneous rock product: calcined obsidian product = 1: 2) was a hydraulic cement. On the other hand, it can be said that it is preferably 15 to 45% by weight. Further, although the mortar specific gravity can be reduced by increasing the addition amount of the weight reduction aid,
From the viewpoint of the compressive strength of the solidified body, the addition amount of the weight saving aid is
It is preferably in the range of 0.01 to 0.05% by weight with respect to the hydraulic cement.

【0041】また、分離抑制剤であるベントナイトを、
水硬性セメントに対して、5重量%添加した場合(実施
例6)、または、15重量%添加した場合(実施例7)
も、いずれも目標とする性能が得られたが、モルタルの
流動性(Pロート流下時間)の観点から、分離抑制剤の
添加量は、水硬性セメントに対して、5〜15重量%の
範囲であることが好ましいと言える。
Bentonite, which is a separation inhibitor, is
When 5% by weight is added to hydraulic cement (Example 6), or when 15% by weight is added (Example 7)
In addition, although the target performance was obtained in all cases, the addition amount of the separation inhibitor was in the range of 5 to 15% by weight with respect to the hydraulic cement from the viewpoint of the fluidity of the mortar (flow time of the P funnel). It can be said that is preferable.

【0042】また、実施例8および9より、分散剤であ
るナフタリンスルホン酸の分散剤の配合量は、モルタル
の流動性の観点から、水硬性セメントに対して、0.5
〜2.0重量%の範囲であることが好ましいと言える。
Further, from Examples 8 and 9, the compounding amount of the dispersant of naphthalenesulfonic acid, which is a dispersant, was 0.5 with respect to the hydraulic cement from the viewpoint of the fluidity of the mortar.
It can be said that it is preferably in the range of up to 2.0% by weight.

【0043】[比較例1]水硬性セメントとして、実施
例2と同様の高炉セメントを用いて、軽量骨材を配合せ
ず、水硬性セメントに対して、ナフタリンスルホン酸系
の分散剤1.0重量%と水35重量%を添加して混練
し、モルタルを調製した。このモルタルおよびその固化
体について、実施例2と同様にして、各物性評価を行っ
た。その評価結果を表3に示す。なお、表3に示す目標
値は、表1と同様に、廃棄物の固化材として用いられる
モルタルに要求される各物性値である。
[Comparative Example 1] As the hydraulic cement, the same blast furnace cement as in Example 2 was used, and the lightweight aggregate was not blended. The naphthalenesulfonic acid-based dispersant 1.0 was added to the hydraulic cement. % And 35% by weight of water were added and kneaded to prepare a mortar. The physical properties of this mortar and its solidified product were evaluated in the same manner as in Example 2. The evaluation results are shown in Table 3. The target values shown in Table 3 are physical property values required for mortar used as a solidifying material for waste, as in Table 1.

【0044】[比較例2〜5]表3の比較例2〜5に示
したような軽量骨材、分散剤、分離抑制剤、軽量化助
剤、混練水の配合量として、それ以外については、実施
例2と同様にして、モルタルスラリーを調製し、各物性
評価を行った。その評価結果を表3に示す。
[Comparative Examples 2 to 5] Light weight aggregates, dispersants, separation inhibitors, lightening aids and kneading water as shown in Comparative Examples 2 to 5 of Table 3 are used in all other amounts. A mortar slurry was prepared and each physical property was evaluated in the same manner as in Example 2. The evaluation results are shown in Table 3.

【0045】[0045]

【表3】 [Table 3]

【0046】表3に示したように、軽量骨材を配合しな
い場合(比較例1)は、モルタルの流動性や固化体の圧
縮強度等の固化体特性は良好であるが、モルタル比重が
1.98g/cm3 と目標値の約2倍であった。また、
軽量骨材として火成岩焼成加工品のみを、水硬性セメン
トに対して、20重量%配合した場合(比較例2)、モ
ルタル比重が目標値1.0g/cm3 を超えてしまい、
また、流動性の向上のため、100重量%、すなわち、
軽量骨材と同量の混練水が必要となり、ブリージング水
が残留する結果となった。一方、軽量骨材として黒曜岩
焼成加工品のみを、水硬性セメントに対して、20重量
%配合した場合(比較例3)、モルタル比重を目標値
1.0g/cm3 以下にすることができたが、軽量骨材
が浮上して分離してしまい、固化体として一体化させる
ことは困難であった。
As shown in Table 3, when the lightweight aggregate is not blended (Comparative Example 1), the characteristics of the solidified body such as the fluidity of the mortar and the compressive strength of the solidified body are good, but the specific gravity of the mortar is 1 The value was 0.98 g / cm 3 , which was about twice the target value. Also,
When only 20% by weight of igneous rock fired product as a lightweight aggregate was mixed with hydraulic cement (Comparative Example 2), the mortar specific gravity exceeded the target value of 1.0 g / cm 3 ,
In order to improve fluidity, 100% by weight, that is,
The same amount of kneading water as the lightweight aggregate was required, resulting in residual breathing water. On the other hand, when 20% by weight of the obsidian calcined product is added as the lightweight aggregate to the hydraulic cement (Comparative Example 3), the mortar specific gravity can be set to the target value of 1.0 g / cm 3 or less. Although it was possible, the lightweight aggregate floated and separated, and it was difficult to integrate it as a solidified body.

【0047】また、分離抑制剤と軽量化助剤を添加しな
かった場合(比較例4)は、実施例2と比較して、流動
性を維持するための混練水の量を低減することができる
ものの、モルタル比重は目標値を満たすことができず、
ブリージング水の残留も見られ、また、固化体上面に荒
れが生じた。また、分離抑制剤としてベントナイトを添
加し、軽量化助剤を添加しなかった場合(比較例5)
は、軽量骨材の分離が抑制され、固化体特性は良好であ
ったが、モルタル比重が目標値に至らなかった。したが
って、実施例2から明らかなように、軽量化助剤(ラウ
リル硫酸ナトリウム)の添加は、固化体特性を損なうこ
となく、モルタル比重を目標値1g/cm3 以下にする
上で有効であると言える。
When the separation inhibitor and the weight saving aid were not added (Comparative Example 4), the amount of kneading water for maintaining the fluidity could be reduced as compared with Example 2. Although it is possible, the mortar specific gravity cannot meet the target value,
Remaining breathing water was also seen, and roughening occurred on the upper surface of the solidified body. Moreover, when bentonite was added as a separation inhibitor and no weight saving aid was added (Comparative Example 5).
, The separation of the lightweight aggregate was suppressed and the solidified body characteristics were good, but the mortar specific gravity did not reach the target value. Therefore, as is apparent from Example 2, the addition of the weight-reducing aid (sodium lauryl sulfate) is effective in reducing the specific gravity of the mortar to the target value of 1 g / cm 3 or less without impairing the properties of the solidified body. I can say.

【0048】[参考例]前記実施例2において、ナフタ
リンスルホン酸系の分散剤に代えて、ポリカルボン酸系
の減水剤を添加し、それ以外については、実施例2と同
様にして、モルタルスラリーを調製して、各物性評価を
行った。その評価結果を表3に示す。この場合は、固化
体の圧縮強度等の固化体特性については、良好な結果が
得られたが、モルタルのPロート流下時間が62秒と長
く、流動性が目標よりも低いものであった。
[Reference Example] A mortar slurry was prepared in the same manner as in Example 2 except that a polycarboxylic acid type water reducing agent was added in place of the naphthalenesulfonic acid type dispersant in Example 2 above. Was prepared and each physical property was evaluated. The evaluation results are shown in Table 3. In this case, good results were obtained regarding the solidified body properties such as the compressive strength of the solidified body, but the P funnel flow-down time of the mortar was as long as 62 seconds, and the fluidity was lower than the target.

【0049】[0049]

【発明の効果】本発明によれば、従来の廃棄物の固化処
理用モルタルと比較して、比重が約半分と軽量であり、
かつ、良好な流動性を長時間維持し、充填性、固化体の
強度特性等においても優れた軽量モルタルが得られる。
したがって、本発明に係る放射性廃棄物の固化方法によ
れば、上記軽量モルタルを用いることにより、廃棄体の
軽量化を図ることができるため、廃棄体数の削減等、廃
棄物処理の効率化に寄与することができる。
According to the present invention, as compared with the conventional mortar for solidifying waste, the specific gravity is about half and light,
In addition, it is possible to obtain a lightweight mortar that maintains good fluidity for a long time and is excellent in filling properties, strength properties of the solidified body, and the like.
Therefore, according to the method for solidifying radioactive waste according to the present invention, the weight of the waste can be reduced by using the above-mentioned lightweight mortar, so that the number of wastes can be reduced and the efficiency of the waste treatment can be improved. Can contribute.

【図面の簡単な説明】[Brief description of drawings]

【図1】実施例2の軽量モルタルについての流動性の経
時変化を示した線図である。
FIG. 1 is a diagram showing a change with time in fluidity of a lightweight mortar of Example 2.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C04B 24/22 C04B 24/22 A G21F 9/30 515 G21F 9/30 515F // C04B 103:40 C04B 103:40 103:44 103:44 (72)発明者 松尾 和昭 愛知県刈谷市小垣江町南藤1番地 東芝セ ラミックス株式会社刈谷製造所内 (72)発明者 梅村 久憲 愛知県刈谷市小垣江町南藤1番地 東芝セ ラミックス株式会社刈谷製造所内 (72)発明者 佐藤 龍明 神奈川県川崎市川崎区浮島町2番1号 株 式会社東芝浜川崎工場内 (72)発明者 豊原 尚実 神奈川県川崎市川崎区浮島町2番1号 株 式会社東芝浜川崎工場内 (72)発明者 金子 昌章 神奈川県川崎市川崎区浮島町2番1号 株 式会社東芝浜川崎工場内 (72)発明者 夏井 和司 神奈川県横浜市磯子区新杉田町8番地 株 式会社東芝横浜事業所内 (72)発明者 新堀 邦明 神奈川県川崎市幸区堀川町66番2 東芝エ ンジニアリング株式会社内 Fターム(参考) 4G012 PA06 PA07 PA27 PB22 PC03 PC08 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) C04B 24/22 C04B 24/22 A G21F 9/30 515 G21F 9/30 515F // C04B 103: 40 C04B 103 : 40 103: 44 103: 44 (72) Inventor Kazuaki Matsuo 1 Minamito, Ogakie-cho, Kariya city, Aichi Toshiba Ceramics Co., Ltd. Kariya Plant (72) Inventor Hisenori Umemura 1-nanfu, Ogakie-cho, Kariya city, Aichi prefecture Toshiba Ceramics Co., Ltd. Kariya Plant (72) Inventor Tatsuaki Sato 2-1, Ukishimacho, Kawasaki-ku, Kawasaki-shi, Kanagawa Stock Company Toshiba Hamakawasaki Plant (72) Inventor Naomi Toyohara Ukishima, Kawasaki-shi, Kanagawa Town No.2-1 Stock Company Toshiba Hamakawasaki Factory (72) Inventor Masaaki Kaneko No.2-1 Ukishimacho, Kawasaki-ku, Kawasaki-shi, Kanagawa Stock Company Shibahama Kawasaki Factory (72) Inventor Kaji Natsui 8 Shinsita-cho, Isogo-ku, Yokohama-shi, Kanagawa Kanagawa Prefecture, Yokohama Office (72) Inventor Kuniaki Shinbori 66-2, Horikawa-cho, Kawasaki-shi, Kanagawa Prefecture Toshiba Engineering Ring F Co., Ltd. F-term (reference) 4G012 PA06 PA07 PA27 PB22 PC03 PC08

Claims (9)

【特許請求の範囲】[Claims] 【請求項1】 水硬性セメント、軽量骨材、分散剤、分
離抑制剤、軽量化助剤および水からなる軽量モルタルで
あって、 前記軽量骨材は、火成岩焼成加工品と黒曜岩焼成加工品
とが混合されたものであることを特徴とする軽量モルタ
ル。
1. A lightweight mortar comprising hydraulic cement, lightweight aggregate, dispersant, separation inhibitor, lightweighting aid, and water, wherein the lightweight aggregate is an igneous calcinated product and an obsidian calcined product. A lightweight mortar characterized by being mixed with a product.
【請求項2】 前記軽量骨材の粒径が1.2mm以下で
あることを特徴とする請求項1記載の軽量モルタル。
2. The lightweight mortar according to claim 1, wherein the particle diameter of the lightweight aggregate is 1.2 mm or less.
【請求項3】 前記水硬性セメントが、ポルトランドセ
メント、または、高炉スラグもしくはフライアッシュを
含むセメントであることを特徴とする請求項1または請
求項2記載の軽量モルタル。
3. The lightweight mortar according to claim 1 or 2, wherein the hydraulic cement is Portland cement or cement containing blast furnace slag or fly ash.
【請求項4】 前記分離抑制剤が、モンモリロナイトを
主成分とするベントナイトであることを特徴とする請求
項1から請求項3までのいずれかに記載の軽量モルタ
ル。
4. The lightweight mortar according to any one of claims 1 to 3, wherein the separation inhibitor is bentonite containing montmorillonite as a main component.
【請求項5】 前記軽量化助剤が、ラウリル硫酸ナトリ
ウムであることを特徴とする請求項1から請求項4まで
のいずれかに記載の軽量モルタル。
5. The lightweight mortar according to claim 1, wherein the weight saving aid is sodium lauryl sulfate.
【請求項6】 前記分散剤が、ナフタリンスルホン酸系
の分散剤であることを特徴とする請求項1から請求項5
までのいずれかに記載の軽量モルタル。
6. The method according to claim 1, wherein the dispersant is a naphthalene sulfonic acid-based dispersant.
Lightweight mortar described in any of the above.
【請求項7】 前記軽量モルタルは、水硬性セメントに
対して、火成岩焼成加工軽量骨材が5〜15重量%、黒
曜岩焼成加工軽量骨材が10〜30重量%、分散剤が
0.5〜2.0重量%、分離抑制剤が5〜15重量%、
軽量化助剤が0.01〜0.05重量%含まれているこ
とを特徴とする請求項1から請求項6までのいずれかに
記載の軽量モルタル。
7. The lightweight mortar contains 5 to 15% by weight of igneous calcinated lightweight aggregate, 10 to 30% by weight of obsidian calcinated lightweight aggregate, and 0. 5 to 2.0% by weight, the separation inhibitor 5 to 15% by weight,
The lightweight mortar according to any one of claims 1 to 6, wherein the lightweighting aid is contained in an amount of 0.01 to 0.05% by weight.
【請求項8】 前記軽量モルタルの比重が1.00g/
cm3 以下であり、かつ、該軽量モルタルの固化体の圧
縮強度が1.5MPa以上であることを特徴とする請求
項1から請求項7までのいずれかに記載の軽量モルタ
ル。
8. The specific gravity of the lightweight mortar is 1.00 g /
cm 3 or less and, lightweight mortar according to claim 1, the compressive strength of the solidified bodies of said light amount mortar, characterized in that at least 1.5MPa to claim 7.
【請求項9】 請求項1から請求項8までのいずれかに
記載された軽量モルタルを充填して固化することを特徴
とする放射性廃棄物の固化方法。
9. A method of solidifying radioactive waste, which comprises filling and solidifying the lightweight mortar according to any one of claims 1 to 8.
JP2001354071A 2001-11-20 2001-11-20 Lightweight mortar and method for solidifying radioactive waste using the same Expired - Fee Related JP4059376B2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007210871A (en) * 2006-02-07 2007-08-23 Taiheiyo Consultant:Kk Cement-based packing/solidifying material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007210871A (en) * 2006-02-07 2007-08-23 Taiheiyo Consultant:Kk Cement-based packing/solidifying material

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