JP2003142974A - Crystal device - Google Patents

Crystal device

Info

Publication number
JP2003142974A
JP2003142974A JP2001338988A JP2001338988A JP2003142974A JP 2003142974 A JP2003142974 A JP 2003142974A JP 2001338988 A JP2001338988 A JP 2001338988A JP 2001338988 A JP2001338988 A JP 2001338988A JP 2003142974 A JP2003142974 A JP 2003142974A
Authority
JP
Japan
Prior art keywords
wiring layer
component
crystal
terms
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001338988A
Other languages
Japanese (ja)
Other versions
JP3906062B2 (en
Inventor
Takuya Ouchi
卓也 大内
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyocera Corp
Original Assignee
Kyocera Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyocera Corp filed Critical Kyocera Corp
Priority to JP2001338988A priority Critical patent/JP3906062B2/en
Publication of JP2003142974A publication Critical patent/JP2003142974A/en
Application granted granted Critical
Publication of JP3906062B2 publication Critical patent/JP3906062B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48225Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • H01L2224/48227Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation connecting the wire to a bond pad of the item

Landscapes

  • Compositions Of Oxide Ceramics (AREA)
  • Piezo-Electric Or Mechanical Vibrators, Or Delay Or Filter Circuits (AREA)

Abstract

PROBLEM TO BE SOLVED: To solve the problem that the reference signal generated by a crystal vibrator attenuates substantially in a wiring layer. SOLUTION: The crystal device 7 comprising a base body 1 which has mount parts 1a and 1b on both its top and reverse surfaces, the crystal vibrator 5 which is fixed to the mount part 1a on the top surface of the base body 1 through a fixing material 8, and a semiconductor element 6 which is mounted on the mount part 1b on the reverse surface of the base body 1 and performs temperature compensation of the crystal vibrator 5 is provided, and the base body 1 is a sinter containing a 25 to 80 wt.% Si component in terms of SiO2 , a 15 to 70 wt.% Ba component in terms of BaO, a 1.5 to 5 wt.% B component in terms of B2 O3 , a 1 to 30 wt.% Al component in terms of Al2 O3 , and a 0 to 30 wt.% Ca component in terms of CaO, the wiring layer 2 is formed of a metal material having <=2.5 μΩ.cm specific electric resistance, and the elasticity of the fixing material 8 is <=2.8 GPa.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、コンピュータ等の
情報処理装置や携帯電話等の電子装置において、時間お
よび周波数の高精度の基準源として使用される温度補償
型の水晶デバイスに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a temperature-compensated crystal device used as a highly accurate reference source of time and frequency in information processing devices such as computers and electronic devices such as mobile phones.

【0002】[0002]

【従来の技術】コンピュータ等の情報処理装置や携帯電
話等の電子装置において時間および周波数の高精度の基
準源として使用される温度補償型の水晶デバイスは、一
般に、四角板状の水晶基板に電圧印加用の電極を形成し
て成る水晶振動子と、この水晶振動子の温度補償を行な
う半導体素子とを、水晶振動子収納用パッケージ内に気
密に収容することによって形成されている。
2. Description of the Related Art A temperature-compensated crystal device used as a high-precision reference source of time and frequency in an information processing device such as a computer or an electronic device such as a mobile phone generally has a rectangular plate-shaped crystal substrate with a voltage applied thereto. It is formed by hermetically accommodating a crystal unit formed by applying electrodes and a semiconductor element for temperature compensating the crystal unit in a crystal unit housing package.

【0003】前記水晶振動子収納用パッケージは、一般
に、酸化アルミニウム質焼結体等の電気絶縁材料から成
り、上面中央部に水晶振動子を収容する空所を形成する
ための凹部を、下面中央部に半導体素子を収容する空所
となる凹部を、それぞれ有するとともに、各凹部表面か
ら外表面にかけて導出された、タングステン、モリブデ
ン等の高融点金属等の金属材料から成る配線層を有する
基体と、鉄−ニッケル−コバルト合金、鉄−ニッケル合
金等の金属材料、または酸化アルミニウム質焼結体等の
セラミックス材料から成る蓋体とから構成されている。
The crystal unit housing package is generally made of an electrically insulating material such as an aluminum oxide sintered body and has a recess for forming a space for accommodating the crystal unit in the center of the upper surface and a center of the lower surface. And a base having a wiring layer made of a metal material such as a refractory metal such as tungsten or molybdenum, which has a recessed portion serving as a space for accommodating a semiconductor element in each part, and which is led out from the surface of each recessed portion to the outer surface, The lid member is made of a metal material such as an iron-nickel-cobalt alloy or an iron-nickel alloy, or a ceramic material such as an aluminum oxide sintered body.

【0004】そして、水晶振動子の電極を基体上面の凹
部内表面に露出する配線層及びその周辺の基体表面に固
定材を介して取着することにより、水晶振動子を凹部内
に接着固定するとともに配線層に電気的に接続し、ま
た、基体下面の凹部内に半導体素子を収容するとともに
半導体素子の電極を配線層に電気的に接続し、しかる
後、基体の上面に蓋体を接着材による接着やシーム溶接
等の接合手段により取着して基体と蓋体とから成る容器
内部に水晶振動子を気密に収容するとともに基体下面の
凹部内に収容した半導体素子を蓋体や封止用樹脂で封止
することによって製品としての水晶デバイスが完成す
る。
Then, the electrodes of the crystal unit are attached to the wiring layer exposed on the inner surface of the concave portion on the upper surface of the base body and the peripheral surface of the base body via a fixing material, whereby the crystal unit is adhered and fixed in the concave section. Together with the wiring layer, the semiconductor element is housed in the recess on the lower surface of the base and the electrode of the semiconductor element is electrically connected to the wiring layer, and then the lid is attached to the upper surface of the base with an adhesive. The quartz crystal unit is hermetically housed in the container consisting of the base body and the lid body by being attached by a bonding means such as adhesive bonding or seam welding, and the semiconductor element housed in the recessed portion on the lower surface of the base body is used for the lid body and sealing. A crystal device as a product is completed by sealing with a resin.

【0005】なお、水晶振動子を取着するための固定材
としては、一般に、エポキシ樹脂等の有機樹脂と、銀粉
末等の導電性粉末とを主材として混合して成る導電性接
着材が使用されている。
As a fixing material for mounting the crystal unit, a conductive adhesive material is generally used which is a mixture of an organic resin such as epoxy resin and a conductive powder such as silver powder as a main material. It is used.

【0006】また、蓋体を基体にシーム溶接で取着する
場合、通常、予め基体の凹部周囲に枠状のロウ付け用メ
タライズ層を形成しておくとともにこのメタライズ層に
金属枠体をロウ付けし、金属枠体に蓋体をシーム溶接す
る方法が用いられる。
When the lid is attached to the substrate by seam welding, a frame-shaped brazing metallization layer is usually formed in advance around the recess of the substrate, and the metal frame is brazed to the metallized layer. Then, a method of seam welding the lid to the metal frame is used.

【0007】更に前記水晶デバイスの外部電気回路基板
への実装は、基体の外表面に導出された配線層を外部電
気回路基板の配線導体に半田等の導電性接続材を介して
接続することによって行われ、水晶振動子は配線層を介
し外部電気回路に電気的に接続されるとともに外部電気
回路から印加される電圧に応じて所定の周波数で振動
し、基準信号を外部電気回路に供給する。
Further, the crystal device is mounted on an external electric circuit board by connecting the wiring layer led out to the outer surface of the substrate to the wiring conductor of the external electric circuit board through a conductive connecting material such as solder. The crystal oscillator is electrically connected to the external electric circuit via the wiring layer and vibrates at a predetermined frequency according to the voltage applied from the external electric circuit to supply the reference signal to the external electric circuit.

【0008】[0008]

【発明が解決しようとする課題】しかしながら、従来の
水晶デバイスは、基体に形成されている配線層がタング
ステンやモリブデン、マンガン等の高融点金属材料によ
り形成されており、該タングステン等はその比電気抵抗
が5.4μΩ・cm(20℃)以上と高いことから配線
層に水晶振動子の基準信号や半導体素子の駆動信号を伝
搬させた場合、基準信号や駆動信号に大きな減衰が生
じ、基準信号や駆動信号を外部電気回路や水晶振動子と
半導体素子との間に正確、かつ確実に伝搬させることが
できないという欠点を有していた。
However, in the conventional crystal device, the wiring layer formed on the substrate is formed of a refractory metal material such as tungsten, molybdenum, or manganese, and the tungsten or the like has a specific electric charge. Since the resistance is as high as 5.4 μΩ · cm (20 ° C) or more, when the reference signal of the crystal unit or the drive signal of the semiconductor element is propagated to the wiring layer, the reference signal or the drive signal is greatly attenuated and the reference signal is increased. It has a drawback that the drive signal cannot be accurately and reliably propagated between the external electric circuit or the crystal oscillator and the semiconductor element.

【0009】本発明は上記欠点に鑑み案出されたもので
あり、その目的は、基体に搭載した半導体素子により水
晶振動子の温度補償を有効に行なうことができ、かつ水
晶振動子の基準信号を外部電気回路に正確かつ確実に供
給することができる水晶デバイスを提供することにあ
る。
The present invention has been devised in view of the above-mentioned drawbacks, and an object thereof is to enable temperature compensation of a crystal unit effectively by a semiconductor element mounted on a base and to provide a reference signal for the crystal unit. It is an object of the present invention to provide a crystal device that can accurately and surely supply a liquid crystal to an external electric circuit.

【0010】[0010]

【課題を解決するための手段】本発明は、上下両面に搭
載部を有し、該各搭載部から外表面にかけて配線層が導
出されている基体と、該基体の搭載部に固定材を介して
固定されている水晶振動子と、前記基体下面の搭載部に
搭載され、前記水晶振動子の温度補償を行なう半導体素
子とから成る水晶デバイスであって、前記基体はSi成
分がSiO2に換算して25〜80重量%、Ba成分が
BaOに換算して15〜70重量%、B成分がB23
換算して1.5〜5重量%、Al成分がAl23に換算
して1〜30重量%、Ca成分がCaOに換算して0重
量%を超え30重量%以下含まれる焼結体で、配線層が
2.5μΩ・cm(20℃)以下の比電気抵抗を有する
金属材で形成されており、かつ前記固定材の弾性率が
2.8GPa以下であることを特徴とするものである。
According to the present invention, there is provided a substrate having mounting portions on both upper and lower surfaces, and a wiring layer extending from each of the mounting portions to the outer surface, and a fixing member interposed between the mounting portions of the substrate. A crystal device comprising a fixed crystal oscillator and a semiconductor element mounted on the lower surface of the base for temperature compensation of the crystal oscillator, wherein the base has a Si component converted to SiO 2 . 25 to 80% by weight, Ba component converted to BaO 15 to 70% by weight, B component converted to B 2 O 3 1.5 to 5% by weight, Al component converted to Al 2 O 3 . 1 to 30% by weight, and the Ca component is more than 0% by weight and 30% by weight or less in terms of CaO, and the wiring layer has a specific electric resistance of 2.5 μΩ · cm (20 ° C.) or less. Is formed of a metal material having the elastic modulus of 2.8 GPa or less It is characterized by being.

【0011】また本発明は、前記固定材がゴム粒子を添
加したエポキシ樹脂から成ることを特徴とするものであ
る。
Further, the present invention is characterized in that the fixing material is made of an epoxy resin containing rubber particles.

【0012】本発明の水晶デバイスによれば、基体をS
i成分がSiO2に換算して25〜80重量%、Ba成
分がBaOに換算して15〜70重量%、B成分がB2
3に換算して1.5〜5重量%、Al成分がAl23
に換算して1〜30重量%、Ca成分がCaOに換算し
て0重量%を超え30重量%以下含まれる焼結体で形成
し、かかる焼結体の焼成温度が約800〜1000℃と
低いことから、基体と同時焼成により形成される配線層
を比電気抵抗が2.5μΩ・cm(20℃)以下と低い
銅や銀、金で形成することができ、その結果、配線層に
水晶振動子の基準信号や半導体素子の駆動信号等を伝搬
させた場合、基準信号や駆動信号に大きな減衰を生じる
ことはなく、基準信号や駆動信号を外部電気回路や水晶
振動子と半導体素子との間に正確、かつ確実に伝搬させ
ることが可能となる。
According to the crystal device of the present invention, the substrate is S
The i component is 25 to 80% by weight in terms of SiO 2 , the Ba component is 15 to 70% by weight in terms of BaO, and the B component is B 2
1.5 to 5% by weight in terms of O 3 , Al component is Al 2 O 3
1 to 30% by weight in terms of Ca, and a Ca component in the range of more than 0% to 30% by weight in terms of CaO and formed at a firing temperature of about 800 to 1000 ° C. Since it is low, the wiring layer formed by co-firing with the substrate can be formed of copper, silver, or gold whose specific electric resistance is as low as 2.5 μΩ · cm (20 ° C.) or less. When the reference signal of the oscillator or the drive signal of the semiconductor element is propagated, the reference signal or the drive signal is not greatly attenuated, and the reference signal or the drive signal is transmitted between the external electric circuit or the crystal oscillator and the semiconductor element. It is possible to accurately and surely propagate in the meantime.

【0013】また本発明の水晶デバイスによれば、基体
に水晶振動子を固定する固定材として、例えば、ゴム粒
子を添加したエポキシ樹脂等から成る弾性率が2.8G
Pa以下のものを使用したことから、水晶振動子の温度
補償を行なう半導体素子が作動時に熱を発生し、その熱
が基体と水晶振動子に繰り返し作用して基体と水晶振動
子との間に両者の熱膨張係数差に起因する熱応力が繰り
返し発生したとしても、その熱応力は固定材を適度に変
形させることによって吸収され、固定材に機械的な破壊
が招来することはなく、その結果、基体に水晶振動子を
長期間にわたり確実、強固に固定することが可能とな
り、水晶デバイスの長期信頼性を高いものとなすことが
できる。
Further, according to the crystal device of the present invention, as a fixing material for fixing the crystal unit to the substrate, for example, an elastic modulus made of epoxy resin or the like with rubber particles added is 2.8 G.
Since the semiconductor element having a temperature of Pa or less is used, the semiconductor element that performs temperature compensation of the crystal unit generates heat during operation, and the heat repeatedly acts on the base and the crystal unit between the base and the crystal unit. Even if the thermal stress due to the difference in the thermal expansion coefficient between the two repeatedly occurs, the thermal stress is absorbed by deforming the fixing material appropriately, and the fixing material is not mechanically broken. The crystal unit can be securely and firmly fixed to the base for a long period of time, and the long-term reliability of the crystal device can be enhanced.

【0014】[0014]

【発明の実施の形態】次に本発明の水晶デバイスについ
て添付の図面を基にして詳細に説明する。図1は本発明
の水晶デバイスの一実施例を示す断面図であり、図1に
おいて、1は基体、2は配線層、3は蓋体である。この
基体1と蓋体3とにより形成される容器4内に水晶振動
子5を気密に収容するとともに、基体1下面に半導体素
子6を搭載収容することにより水晶デバイス7が形成さ
れる。
BEST MODE FOR CARRYING OUT THE INVENTION Next, a crystal device of the present invention will be described in detail with reference to the accompanying drawings. 1 is a sectional view showing an embodiment of the crystal device of the present invention. In FIG. 1, 1 is a base, 2 is a wiring layer, and 3 is a lid. A crystal device 5 is formed by hermetically housing a crystal resonator 5 in a container 4 formed by the base 1 and the lid 3, and mounting and housing a semiconductor element 6 on the lower surface of the base 1.

【0015】前記基体1は、Si成分がSiO2に換算
して25〜80重量%、Ba成分がBaOに換算して1
5〜70重量%、B成分がB23に換算して1.5〜5
重量%、Al成分がAl23に換算して1〜30重量
%、Ca成分がCaOに換算して0重量%を超え30重
量%以下含まれる焼結体で形成されており、その上下両
面に凹部1a、1bが設けてあり、上面の凹部1a内に
は水晶振動子5が収容され、下面の凹部1bには前記水
晶振動子5の温度補償を行なうための半導体素子6がロ
ウ材、ガラス、有機樹脂等の接着材を介して接着固定さ
れ、搭載収容される。
In the substrate 1, the Si component is 25 to 80% by weight in terms of SiO 2 , and the Ba component is 1 in terms of BaO.
5 to 70% by weight, B component converted to B 2 O 3 is 1.5 to 5
%, The Al component is 1 to 30 wt% in terms of Al 2 O 3 , and the Ca component is more than 0 wt% and 30 wt% in terms of CaO. Recesses 1a and 1b are provided on both sides, a crystal resonator 5 is accommodated in the recess 1a on the upper surface, and a semiconductor element 6 for performing temperature compensation of the crystal resonator 5 is brazed in the recess 1b on the lower surface. It is mounted and housed by being fixedly adhered via an adhesive such as glass, organic resin or the like.

【0016】また前記基体1は、上下の凹部1a、1b
の表面から外表面にかけて配線層2が導出されており、
配線層2の基体1上面側の凹部1a表面に露出する部位
に水晶振動子5の電極が導電性接着材等の固定材8を介
して接着固定され、基体1下面側の凹部1bに露出する
部位には半導体素子6の電極がボンディングワイヤ等の
導電性接続部材9を介して接続される。
The base body 1 has upper and lower recesses 1a, 1b.
The wiring layer 2 is led from the surface to the outer surface of
The electrode of the crystal unit 5 is adhered and fixed to a portion of the wiring layer 2 exposed on the surface of the concave portion 1a on the upper surface of the substrate 1 through a fixing material 8 such as a conductive adhesive, and is exposed in the concave portion 1b on the lower surface of the substrate 1. The electrode of the semiconductor element 6 is connected to the portion via a conductive connecting member 9 such as a bonding wire.

【0017】前記焼結体から成る基体1は、例えば、S
iO2、BaO、B23、Al23、CaO等の原料粉
末にアクリル樹脂を主成分とするバインダー及び分散
剤、可塑剤、有機溶媒を加えて泥漿物を作るとともに該
泥漿物をドクターブレード法やカレンダーロール法を採
用することによってグリーンシート(生シート)とな
し、しかる後、前記グリーンシートに適当な打ち抜き加
工を施すとともにこれを複数枚積層し、約800℃〜1
000℃の温度で焼成することによって製作される。
The base 1 made of the sintered body is, for example, S
A raw material powder such as iO 2 , BaO, B 2 O 3 , Al 2 O 3 and CaO is added with a binder and a dispersant having an acrylic resin as a main component, a plasticizer and an organic solvent to prepare a sludge and the sludge is A green sheet (raw sheet) is formed by adopting the doctor blade method or the calendar roll method. After that, the green sheet is appropriately punched and a plurality of these are laminated, and the temperature is about 800 ° C to 1 ° C.
It is manufactured by firing at a temperature of 000 ° C.

【0018】前記基体1はその焼成温度が約800〜1
000℃と低いことから、基体1と同時焼成により形成
される配線層2を比電気抵抗が2.5μΩ・cm(20
℃)以下と低い銅や銀、金で形成することができ、その
結果、配線層2に水晶振動子5の基準信号や半導体素子
6の駆動信号を伝搬させた場合、基準信号や駆動信号に
大きな減衰が生じることはなく、基準信号や駆動信号を
外部電気回路や水晶振動子と半導体素子との間に正確、
かつ確実に伝搬させることが可能となる。
The substrate 1 has a firing temperature of about 800-1.
Since it is as low as 000 ° C., the wiring layer 2 formed by co-firing with the substrate 1 has a specific electric resistance of 2.5 μΩ · cm (20
C.) or lower, copper, silver, or gold can be formed. As a result, when the reference signal of the crystal unit 5 or the drive signal of the semiconductor element 6 is propagated to the wiring layer 2, the reference signal or the drive signal is changed. No significant attenuation occurs, and the reference signal and drive signal are accurately measured between the external electric circuit or crystal unit and the semiconductor element,
And, it is possible to surely propagate.

【0019】なお、前記基体1を構成する焼結体は、S
iO2が25重量%未満であると誘電損失が大きくなっ
て配線層2を伝搬する水晶振動子の基準信号や半導体素
子の駆動信号に減衰や遅延を招来してしまい、また80
重量%を超えると基体1の機械的強度が大きく低下して
しまうと同時に焼成温度が高いものとなって銅等の金属
材から成る配線層2と同時焼成するのが困難となる。従
って、SiO2の量は25〜80重量%の範囲に特定さ
れる。
The sintered body constituting the base 1 is S
When iO 2 is less than 25% by weight, the dielectric loss becomes large, and the reference signal of the crystal unit propagating in the wiring layer 2 and the drive signal of the semiconductor element are attenuated or delayed.
If it exceeds 5% by weight, the mechanical strength of the substrate 1 is significantly reduced, and at the same time, the firing temperature becomes high and it becomes difficult to co-fire with the wiring layer 2 made of a metal material such as copper. Therefore, the amount of SiO 2 is specified in the range of 25-80% by weight.

【0020】また前記基体1を構成する焼結体は、Ba
Oが15重量%未満であると焼成温度が高いものとなっ
て銅等の金属材からなる配線層2と同時焼成するのが困
難となり、また70重量%を超えると誘電損失が大きく
なって配線層2を伝搬する水晶振動子の基準信号や半導
体素子の駆動信号に減衰や遅延を招来してしまう。従っ
て、BaOの量は15〜70重量%の範囲に特定され
る。
The sintered body forming the base 1 is made of Ba.
If O is less than 15% by weight, the firing temperature becomes high, making it difficult to co-fire with the wiring layer 2 made of a metal material such as copper. The reference signal of the crystal unit propagating in the layer 2 and the driving signal of the semiconductor element are attenuated or delayed. Therefore, the amount of BaO is specified in the range of 15 to 70% by weight.

【0021】更に前記基体1を構成する焼結体は、B2
3が1.5重量%未満となると焼成温度が高いものと
なって銅等の金属材から成る配線層2と同時焼成するの
が困難となり、また5重量%を超えると基体1の機械的
強度が大きく低下してしまう。従って、B23の量は
1.5〜5重量%の範囲に特定される。
Further, the sintered body constituting the base 1 is B 2
When O 3 is less than 1.5% by weight, the firing temperature becomes high and it becomes difficult to co-fire with the wiring layer 2 made of a metal material such as copper, and when it exceeds 5% by weight, the mechanical strength of the substrate 1 is increased. The strength is greatly reduced. Therefore, the amount of B 2 O 3 is specified in the range of 1.5 to 5% by weight.

【0022】また更に前記基体1を構成する焼結体は、
Al23が1重量%未満となると焼成温度が高いものと
なって銅等の金属材からなる配線層2と同時焼成するの
が困難となり、また30重量%を超えると誘電損失が大
きくなって配線層2を伝搬する水晶振動子の基準信号や
半導体素子の駆動信号に減衰や遅延を招来してしまう。
従って、Al23の量は1〜30重量%の範囲に特定さ
れる。
Further, the sintered body constituting the base 1 is
When Al 2 O 3 is less than 1% by weight, the firing temperature becomes high and it becomes difficult to co-fire with the wiring layer 2 made of a metal material such as copper, and when it exceeds 30% by weight, the dielectric loss becomes large. As a result, the reference signal of the crystal unit and the drive signal of the semiconductor element propagating through the wiring layer 2 are attenuated or delayed.
Therefore, the amount of Al 2 O 3 is specified in the range of 1 to 30% by weight.

【0023】更にまた前記基体1を構成する焼結体は、
CaOが含有されない時には焼結性が低下して機械的強
度が低下してしまい、また30重量%を超えると焼成温
度が高いものとなって銅等の金属材から成る配線層2と
同時焼成するのが困難となる。従って、CaOの量は0
重量%を超えて30重量%以下の範囲に特定される。
Further, the sintered body constituting the base 1 is
When CaO is not contained, the sinterability is lowered and the mechanical strength is lowered, and when it exceeds 30% by weight, the firing temperature becomes high and the firing is performed simultaneously with the wiring layer 2 made of a metal material such as copper. Becomes difficult. Therefore, the amount of CaO is 0
It is specified in the range of more than 30% by weight and more than 30% by weight.

【0024】また前記基体1に形成されている配線層2
は、凹部1a、1b内に収容される水晶振動子5および
半導体素子6と外部電気回路基板の配線導体とを電気的
に接続する作用をなし、例えば、金、銀、銅等の比電気
抵抗が2.5μΩ・cm(20℃)以下の金属材により
形成されており、銅から成る場合であれば、銅粉末に適
当な有機溶剤、有機バインダー等を添加混合して得た金
属ペーストを、基体1となるグリーンシートの表面にス
クリーン印刷法等で所定パターンに印刷塗布しておくこ
とによって形成される。
The wiring layer 2 formed on the substrate 1
Has a function of electrically connecting the crystal resonator 5 and the semiconductor element 6 housed in the recesses 1a and 1b to the wiring conductor of the external electric circuit board. For example, the specific electric resistance of gold, silver, copper, or the like. Is formed of a metal material of 2.5 μΩ · cm (20 ° C.) or less, and when it is made of copper, a metal paste obtained by adding and mixing an appropriate organic solvent, an organic binder, etc. to copper powder, It is formed by printing and applying a predetermined pattern on the surface of the green sheet to be the substrate 1 by a screen printing method or the like.

【0025】前記配線層2は、その露出する表面をニッ
ケル、金等の耐食性およびロウ材との濡れ性の良好な金
属から成るめっき層(不図示)で被覆しておくと、配線
層2の酸化腐食を良好に防止することができるととも
に、配線層2に対する半田等のロウ材の濡れ性を良好と
することができ、外部電気回路基板の配線導体に対する
配線層2の接続をより一層容易、かつ確実なものとする
ことができる。従って、前記配線層2は、その露出する
表面をニッケル、金等のめっき層、例えば、順次被着さ
れた厚み1μm〜10μmのニッケルまたはニッケル合
金めっき層、厚み0.1〜3μmの金めっき層で被覆し
ておくことが好ましい。
When the exposed surface of the wiring layer 2 is covered with a plating layer (not shown) made of a metal having good corrosion resistance such as nickel and gold and good wettability with the brazing material, the wiring layer 2 will be covered. Oxidation and corrosion can be satisfactorily prevented, the soldering property of the brazing material such as solder to the wiring layer 2 can be improved, and the connection of the wiring layer 2 to the wiring conductor of the external electric circuit board can be further facilitated. And it can be assured. Therefore, the wiring layer 2 has a plating layer of nickel, gold or the like on its exposed surface, for example, a nickel or nickel alloy plating layer having a thickness of 1 μm to 10 μm and a gold plating layer having a thickness of 0.1 to 3 μm, which are sequentially deposited. It is preferable to coat with.

【0026】また前記配線層2の表面をニッケル、金等
のめっき層で被覆する場合、その最表面の算術平均粗さ
(Ra)を1.5μm以下、自乗平均平方根粗さ(Rm
s)を1.8μm以下としておくと最表面の光の反射率
が40%以上となって水晶振動子5の電極を配線層2に
固定材8を介して固定する際、および半導体素子6の電
極を配線層2にボンディングワイヤ等の導電性接続部材
9を介して電気的接続する際、その位置決め等の作業が
容易となる。従って、前記配線層2の表面をニッケル、
金等のめっき層で被覆する場合、その最表面の算術平均
粗さ(Ra)を1.5μm以下、自乗平均平方根粗さ
(Rms)を1.8μm以下としておくことが好まし
い。
When the surface of the wiring layer 2 is coated with a plating layer of nickel, gold or the like, the arithmetic mean roughness (Ra) of the outermost surface thereof is 1.5 μm or less and the root mean square roughness (Rm).
When s) is set to 1.8 μm or less, the reflectance of light on the outermost surface becomes 40% or more, and when fixing the electrode of the crystal unit 5 to the wiring layer 2 via the fixing material 8, and of the semiconductor element 6. When electrically connecting the electrode to the wiring layer 2 via the conductive connecting member 9 such as a bonding wire, the work such as positioning thereof is facilitated. Therefore, the surface of the wiring layer 2 is nickel,
When coating with a plating layer of gold or the like, it is preferable to set the arithmetic mean roughness (Ra) of the outermost surface to 1.5 μm or less and the root mean square roughness (Rms) to 1.8 μm or less.

【0027】更に前記配線層2の表面を被覆するニッケ
ル、金等からなるめっき層の最表面の算術平均粗さ(R
a)を1.5μm以下、自乗平均平方根粗さ(Rms)
を1.8μm以下とするには配線層2を従来周知のワッ
ト浴にイオウ化合物等の光沢剤を添加した電解ニッケル
めっき液に浸漬して配線層2の表面にニッケルめっき層
を被着させ、しかる後、シアン系の電解金めっき液中に
浸漬し、ニッケルめっき層表面に金めっき層を被着させ
ることによって行なわれる。
Further, the arithmetic mean roughness (R) of the outermost surface of the plating layer made of nickel, gold or the like covering the surface of the wiring layer 2
a) is 1.5 μm or less, root mean square roughness (Rms)
In order to reduce the thickness to 1.8 μm or less, the wiring layer 2 is immersed in an electrolytic nickel plating solution in which a brightening agent such as a sulfur compound is added to a conventionally well-known Watt bath to deposit a nickel plating layer on the surface of the wiring layer 2. After that, it is performed by immersing it in a cyan electrolytic gold plating solution and depositing the gold plating layer on the surface of the nickel plating layer.

【0028】前記配線層2のうち基体1上面側の凹部1
a表面に露出する部位には水晶振動子5が固定材8を介
して固定されており、該固定材8は例えば、ゴム粒子を
添加したエポキシ樹脂等の弾性率が2.8GPa以下の
もので形成されている。
The concave portion 1 of the wiring layer 2 on the upper surface side of the substrate 1
The crystal resonator 5 is fixed to a portion exposed on the surface a through a fixing member 8. The fixing member 8 is made of, for example, an epoxy resin containing rubber particles and having an elastic modulus of 2.8 GPa or less. Has been formed.

【0029】前記固定材8はその弾性率が2.8GPa
以下であり、変形し易いことから、水晶振動子5の温度
補償を行なう半導体素子6が作動時に熱を発生し、その
熱が基体1と水晶振動子5に繰り返し作用して基体1と
水晶振動子5との間に両者の熱膨張係数差に起因する熱
応力が繰り返し発生したとしても、その熱応力は固定材
8を適度に変形させることによって吸収され、固定材8
に機械的な破壊が招来することはなく、その結果、基体
1に水晶振動子5を長期間にわたり確実、強固に固定す
ることが可能となり、水晶デバイス7の長期信頼性を高
いものとなすことができる。
The fixing material 8 has an elastic modulus of 2.8 GPa.
The semiconductor element 6 for temperature compensation of the crystal unit 5 generates heat during operation because it is easily deformed, and the heat repeatedly acts on the base unit 1 and the crystal unit 5 to cause vibration of the base unit 1 and the crystal unit 5. Even if the thermal stress caused by the difference in the thermal expansion coefficient between the child 5 and the child 5 is repeatedly generated, the thermal stress is absorbed by appropriately deforming the fixing material 8, and the fixing material 8
No mechanical damage is caused, and as a result, the crystal unit 5 can be securely and firmly fixed to the base body 1 for a long period of time, and the long-term reliability of the crystal device 7 is enhanced. You can

【0030】前記固定材8はその弾性率が2.8GPa
を超えると水晶振動子5の温度補償を行なう半導体素子
6の発した熱が基体1と水晶振動子5の両者に繰り返し
作用し、基体1と水晶振動子5との熱膨張係数差に起因
する熱応力が固定材8に繰り返し作用した場合に固定材
8に機械的な破壊を招来して水晶振動子5の固定材8を
介しての固定が破れ、水晶デバイス7の信頼性が大きく
低下してしまう。従って、前記固定材8はその弾性率が
2.8GPa以下のものに特定され、2GPa以下のも
のであることがより一層好ましい。
The fixing member 8 has an elastic modulus of 2.8 GPa.
When the temperature exceeds 1.0, the heat generated by the semiconductor element 6 that performs temperature compensation of the crystal unit 5 repeatedly acts on both the base body 1 and the crystal unit 5, resulting in a difference in thermal expansion coefficient between the base unit 1 and the crystal unit 5. When thermal stress repeatedly acts on the fixing material 8, mechanical destruction of the fixing material 8 is caused, the fixation of the crystal unit 5 through the fixing material 8 is broken, and the reliability of the crystal device 7 is greatly reduced. Will end up. Therefore, the fixing material 8 is specified to have an elastic modulus of 2.8 GPa or less, and more preferably 2 GPa or less.

【0031】前記弾性率が2.8GPa以下の固定材8
としては、例えば、アクリルゴム、イソプレンゴム等の
ゴム粒子を添加したエポキシ樹脂に対して、銀粉末等の
導電性粉末を15乃至60重量%の割合で添加したもの
が好適に使用される。
Fixing material 8 having an elastic modulus of 2.8 GPa or less
For example, a conductive powder such as silver powder added at a ratio of 15 to 60% by weight to an epoxy resin added with rubber particles such as acrylic rubber or isoprene rubber is preferably used.

【0032】また前記エポキシ樹脂としては、ビスフェ
ノールA型、ビスフェノールF型、ゴム変性型、ウレタ
ン変性型等のエポキシ樹脂、特に未硬化時に粘液状(室
温)のものが好適に使用される。この場合、エポキシ樹
脂へのゴム粒子の添加量を増加させることにより固定材
8の弾性率を低下させることができ、エポキシ樹脂の状
態(構造、架橋度、重合度、硬化剤の種類等)に応じて
適宜ゴム粒子の添加量を制御することにより固定材の弾
性率を2.8GPa以下とすることができる。なお、エ
ポキシ樹脂へのゴム粒子の添加量が50重量%を超える
と、未硬化の樹脂組成物の流動性が大きく低下し、水晶
振動子5の電極と配線層2との間に固定材8を均一に介
在させることが困難となり、水晶振動子5を基体1に強
固に固定することが困難となる傾向にある。従って、エ
ポキシ樹脂中にゴム粒子を添加する場合、その添加量
は、固定材8の弾性率を2.8GPa以下とする範囲
で、50重量%以下としておくことが好ましい。
As the epoxy resin, epoxy resins of bisphenol A type, bisphenol F type, rubber modified type, urethane modified type, etc., particularly those which are viscous liquid (room temperature) when uncured are preferably used. In this case, the elastic modulus of the fixing material 8 can be lowered by increasing the amount of rubber particles added to the epoxy resin, and the state of the epoxy resin (structure, degree of crosslinking, degree of polymerization, type of curing agent, etc.) can be changed. The elastic modulus of the fixing material can be set to 2.8 GPa or less by appropriately controlling the addition amount of the rubber particles. When the amount of rubber particles added to the epoxy resin exceeds 50% by weight, the fluidity of the uncured resin composition is significantly reduced, and the fixing material 8 is provided between the electrode of the crystal unit 5 and the wiring layer 2. Tends to be difficult to intervene uniformly, and it becomes difficult to firmly fix the crystal unit 5 to the substrate 1. Therefore, when rubber particles are added to the epoxy resin, the amount of addition is preferably 50% by weight or less within a range in which the elastic modulus of the fixing material 8 is 2.8 GPa or less.

【0033】前記固定材8は、またその弾性率が0.1
GPa未満になると、変形し易くなりすぎるため水晶振
動子5を基体1の凹部1a内の所定位置に確実に接着固
定しておくことが困難となる傾向がある。従って、前記
固定材8はその弾性率を2.8GPa以下の範囲で、
0.1GPa以上としておくことが好ましい。
The fixing member 8 has an elastic modulus of 0.1.
If the pressure is less than GPa, the crystal resonator 5 tends to be deformed too easily, and it tends to be difficult to securely bond and fix the crystal unit 5 to a predetermined position in the recess 1 a of the base 1. Therefore, the fixing material 8 has an elastic modulus in the range of 2.8 GPa or less,
It is preferably set to 0.1 GPa or more.

【0034】なお、前記弾性率が2.8GPa以下の固
定材8は、上述のエポキシ樹脂組成物に限らず、シリコ
ーン樹脂等の低弾性率の熱硬化性樹脂、またはシリコー
ン樹脂等にシリカ等のフィラー成分を添加した樹脂組成
物に導電性粉末を添加することにより形成してもよい。
The fixing material 8 having an elastic modulus of 2.8 GPa or less is not limited to the epoxy resin composition described above, but a thermosetting resin having a low elastic modulus such as silicone resin, or silicone resin such as silica. You may form by adding electroconductive powder to the resin composition which added the filler component.

【0035】また前記水晶振動子5が固定材8を介して
接着固定されている基体1は、その上面に蓋体3が取着
され、これによって基体1と蓋体3とから成る容器4内
部に水晶振動子5が気密に収容される。
Further, the base body 1 to which the crystal unit 5 is adhered and fixed via the fixing material 8 has the lid body 3 attached to the upper surface thereof, whereby the inside of the container 4 composed of the base body 1 and the lid body 3. The crystal unit 5 is hermetically housed therein.

【0036】前記蓋体3は、鉄−ニッケル−コバルト合
金、鉄−ニッケル合金等の金属材料や、酸化アルミニウ
ム質焼結体等のセラミック材料により形成され、例え
ば、鉄−ニッケル−コバルト合金のインゴット(塊)に
圧延加工、打ち抜き加工等の周知の金属加工を施すこと
によって形成される。
The lid 3 is made of a metal material such as an iron-nickel-cobalt alloy or an iron-nickel alloy, or a ceramic material such as an aluminum oxide sintered body. For example, an iron-nickel-cobalt alloy ingot. It is formed by subjecting the (lump) to well-known metal processing such as rolling and punching.

【0037】更に前記蓋体3の基体1への取着は、ロウ
材、ガラス、有機樹脂接着剤等の接合材を介して行う方
法や、シーム溶接等の溶接法により行うことができ、例
えば、蓋体3をシーム溶接にて取着する場合は通常、基
体1上面の凹部1a周囲に枠状のロウ付け用メタライズ
層11を配線層2と同様の方法で被着させておくととも
に、該ロウ付け用メタライズ層11に金属枠体12を銀
ロウ等のロウ材を介してロウ付けし、しかる後、前記金
属枠体12に金属製の蓋体3を載置させるとともに蓋体
3の外縁部をシーム溶接することによって行われる。こ
の場合、金属枠体12は、その上面と側面との間の角部
に曲率半径が5〜30μmの丸みを形成しておくと金属
枠体12の上面側にバリが形成されることがなく、この
金属枠体12の上面に蓋体3をシーム溶接する際に両者
を信頼性高く気密に、かつ強固に接合させることができ
る。従って、前記金属枠体12はその上面と側面との間
の角部を曲率半径が5〜30μmの丸みをもたせるよう
にしておくことが好ましい。
Further, the lid 3 can be attached to the base body 1 by a method such as a brazing material, glass, an organic resin adhesive or the like, or a welding method such as seam welding. When the lid 3 is attached by seam welding, a frame-shaped brazing metallizing layer 11 is usually attached around the recess 1a on the upper surface of the substrate 1 in the same manner as the wiring layer 2, and The metal frame body 12 is brazed to the brazing metallization layer 11 via a brazing material such as silver braze, and then the metal lid body 3 is placed on the metal frame body 12 and the outer edge of the lid body 3 is placed. This is done by seam welding the parts. In this case, if the metal frame 12 is rounded with a radius of curvature of 5 to 30 μm at the corner between the upper surface and the side surface, burrs are not formed on the upper surface of the metal frame 12. When the lid body 3 is seam welded to the upper surface of the metal frame body 12, the both can be joined reliably and airtightly and firmly. Therefore, it is preferable that the corner portion between the upper surface and the side surface of the metal frame 12 has a roundness with a radius of curvature of 5 to 30 μm.

【0038】また更に、前記金属枠体12は、その下面
と側面との間の角部に曲率半径が40〜80μmの丸み
を形成しておくと、該金属枠体12をロウ付け用メタラ
イズ層11にロウ材を介して接合する際、ロウ付け用メ
タライズ層11と金属枠体12の下面側角部との間に空
間が形成されるとともに該空間にロウ材の大きな溜まり
が形成されて金属枠体12のロウ付け用メタライズ層1
1への接合が強固となる。従って、前記金属枠体12を
ロウ付け用メタライズ層11にロウ材を介して強固に接
合させるには金属枠体12の下面と側面との間の角部に
曲率半径が40〜80μmの丸みを形成しておくことが
好ましい。
Furthermore, when the metal frame 12 is rounded with a radius of curvature of 40 to 80 μm at the corner between the lower surface and the side surface, the metal frame 12 is brazed to the metallization layer. When joining to 11 via the brazing material, a space is formed between the brazing metallization layer 11 and the corner portion on the lower surface side of the metal frame body 12, and a large pool of the brazing material is formed in the space to form a metal. Brazing metallization layer 1 of frame 12
Bonding to 1 becomes strong. Therefore, in order to firmly bond the metal frame 12 to the brazing metallization layer 11 via the brazing material, a roundness having a radius of curvature of 40 to 80 μm is formed at the corner between the lower surface and the side surface of the metal frame 12. It is preferably formed.

【0039】また一方、前記基体1の下面に設けた凹部
1bには水晶振動子5の温度補償を行なうための半導体
素子6が収容固定されており、該半導体素子6によって
水晶振動子5の振動周波数が温度変化によって変動する
のを制御し、常に一定とする作用をなす。
On the other hand, a semiconductor element 6 for compensating the temperature of the crystal unit 5 is housed and fixed in the recess 1b provided on the lower surface of the base body 1, and the semiconductor unit 6 vibrates the crystal unit 5. It controls that the frequency fluctuates due to temperature changes, and has the function of keeping it constant.

【0040】前記半導体素子6はガラス、樹脂、ロウ材
等の接着材を介して基体1の下面に設けた凹部1bの底
面に接着固定され、半導体素子6の各電極はボンディン
グワイヤ等の導電性接続部材9を介して基体1の凹部1
bに露出する配線層2に電気的に接続されている。
The semiconductor element 6 is adhered and fixed to the bottom surface of the recess 1b provided on the lower surface of the substrate 1 through an adhesive material such as glass, resin or brazing material, and each electrode of the semiconductor element 6 is made of a conductive material such as a bonding wire. The recess 1 of the base body 1 via the connecting member 9
It is electrically connected to the wiring layer 2 exposed at b.

【0041】また前記基体1の凹部1b内に収容されて
いる半導体素子6は凹部1b内に充填させた封止樹脂1
0によって気密に封止されている。
The semiconductor element 6 housed in the recess 1b of the base 1 is the sealing resin 1 filled in the recess 1b.
It is hermetically sealed by 0.

【0042】なお、前記半導体素子6の封止は封止樹脂
10で行なうものに限定されるものではなく、基体1の
下面に蓋体を、凹部1bを塞ぐように取着させることに
よって行なってもよい。
The sealing of the semiconductor element 6 is not limited to the sealing with the sealing resin 10, and a lid is attached to the lower surface of the base 1 so as to close the recess 1b. Good.

【0043】かくして上述の水晶デバイス7によれば、
配線層2を外部電気回路に接続し、水晶振動子5の電極
に所定の電圧を印加させることによって水晶振動子5が
所定の振動数で振動するとともに、半導体素子6により
水晶振動子5の温度補償が行なわれ、コンピュータ等の
情報処理装置や携帯電話等の電子装置において時間およ
び周波数の高精度の基準源として使用される。
Thus, according to the above-mentioned crystal device 7,
By connecting the wiring layer 2 to an external electric circuit and applying a predetermined voltage to the electrodes of the crystal resonator 5, the crystal resonator 5 vibrates at a predetermined frequency, and the semiconductor element 6 causes the temperature of the crystal resonator 5 to rise. It is compensated and used as a highly accurate reference source of time and frequency in information processing devices such as computers and electronic devices such as mobile phones.

【0044】なお、本発明は上述の実施例に限定される
ものではなく、本発明の要旨を逸脱しない範囲であれば
種々の変更は可能であり、例えば、図2に示すように、
配線層2の一部に突起13を形成しておくと、この突起
13がスペーサーとなって配線層2と水晶振動子5との
間に一定のスペースが確保され、このスペースに十分な
固定材8が入り込んで水晶振動子5を配線層2に極めて
強固に接着固定することができる。
The present invention is not limited to the above-described embodiments, and various modifications can be made without departing from the gist of the present invention. For example, as shown in FIG.
When the protrusion 13 is formed on a part of the wiring layer 2, the protrusion 13 serves as a spacer to secure a certain space between the wiring layer 2 and the crystal unit 5, and a sufficient fixing material for this space. The crystal resonator 5 can be extremely firmly adhered and fixed to the wiring layer 2 by inserting 8 therein.

【0045】また上述の水晶デバイス7では基体1上面
に凹部1aを設け、該凹部1a内に水晶振動子5を収容
するようになしたが、これを図3に示す如く、平坦な基
体1上に水晶振動子5を搭載固定し、該固定された水晶
振動子5を椀状の蓋体3で気密に封止するようになした
水晶デバイス7にも適用し得る。
Further, in the above-mentioned crystal device 7, the concave portion 1a is provided on the upper surface of the base body 1 and the crystal resonator 5 is accommodated in the concave portion 1a. As shown in FIG. The present invention can also be applied to a crystal device 7 in which the crystal resonator 5 is mounted and fixed, and the fixed crystal resonator 5 is hermetically sealed with the bowl-shaped lid 3.

【0046】[0046]

【発明の効果】本発明の水晶デバイスによれば、基体を
Si成分がSiO2に換算して25〜80重量%、Ba
成分がBaOに換算して15〜70重量%、B成分がB
23に換算して1.5〜5重量%、Al成分がAl23
に換算して1〜30重量%、Ca成分がCaOに換算し
て0重量%を超え30重量%以下含まれる焼結体で形成
し、かかる焼結体の焼成温度が約800〜1000℃と
低いことから、基体と同時焼成により形成される配線層
を比電気抵抗が2.5μΩ・cm(20℃)以下と低い
銅や銀、金で形成することができ、その結果、配線層に
水晶振動子の基準信号や半導体素子の駆動信号等を伝搬
させた場合、基準信号や駆動信号に大きな減衰を生じる
ことはなく、基準信号や駆動信号を外部電気回路や水晶
振動子と半導体素子との間に正確、かつ確実に伝搬させ
ることが可能となる。
According to the crystal device of the present invention, the substrate contains 25 to 80% by weight of Si component converted to SiO 2 , and Ba
Ingredients are 15-70% by weight in terms of BaO, B ingredients are B
1.5 to 5% by weight in terms of 2 O 3 , Al component is Al 2 O 3
1 to 30% by weight in terms of Ca, and a Ca component in the range of more than 0% to 30% by weight in terms of CaO and formed at a firing temperature of about 800 to 1000 ° C. Since it is low, the wiring layer formed by co-firing with the substrate can be formed of copper, silver, or gold whose specific electric resistance is as low as 2.5 μΩ · cm (20 ° C.) or less. When the reference signal of the oscillator or the drive signal of the semiconductor element is propagated, the reference signal or the drive signal is not greatly attenuated, and the reference signal or the drive signal is transmitted between the external electric circuit or the crystal oscillator and the semiconductor element. It is possible to accurately and surely propagate in the meantime.

【0047】また本発明の水晶デバイスによれば、基体
に水晶振動子を固定する固定材として、例えば、ゴム粒
子を添加したエポキシ樹脂等から成る弾性率が2.8G
Pa以下のものを使用したことから、水晶振動子の温度
補償を行なう半導体素子が作動時に熱を発生し、その熱
が基体と水晶振動子に繰り返し作用して基体と水晶振動
子との間に両者の熱膨張係数差に起因する熱応力が繰り
返し発生したとしても、その熱応力は固定材を適度に変
形させることによって吸収され、固定材に機械的な破壊
が招来することはなく、その結果、基体に水晶振動子を
長期間にわたり確実、強固に固定することが可能とな
り、水晶デバイスの長期信頼性を高いものとなすことが
できる。
Further, according to the crystal device of the present invention, as the fixing material for fixing the crystal oscillator to the base, for example, an elastic modulus made of epoxy resin or the like with rubber particles added is 2.8 G.
Since the semiconductor element having a temperature of Pa or less is used, the semiconductor element that performs temperature compensation of the crystal unit generates heat during operation, and the heat repeatedly acts on the base and the crystal unit between the base and the crystal unit. Even if the thermal stress due to the difference in the thermal expansion coefficient between the two repeatedly occurs, the thermal stress is absorbed by deforming the fixing material appropriately, and the fixing material is not mechanically broken. The crystal unit can be securely and firmly fixed to the base for a long period of time, and the long-term reliability of the crystal device can be enhanced.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の水晶デバイスの一実施例を示す断面図
である。
FIG. 1 is a sectional view showing an embodiment of a crystal device of the present invention.

【図2】本発明の水晶デバイスの他の実施例を示す要部
断面図である。
FIG. 2 is a cross-sectional view of an essential part showing another embodiment of the crystal device of the present invention.

【図3】本発明の水晶デバイスの他の実施例を示す断面
図である。
FIG. 3 is a cross-sectional view showing another embodiment of the crystal device of the present invention.

【符号の説明】[Explanation of symbols]

1・・・・・基体 1a・・・・凹部 1b・・・・凹部 2・・・・・配線層 3・・・・・蓋体 4・・・・・容器 5・・・・・水晶振動子 6・・・・・半導体素子 7・・・・・水晶デバイス 8・・・・・固定材 9・・・・・導電性接続部材 10・・・・封止樹脂 11・・・・ロウ付け用メタライズ層 12・・・・金属枠体 13・・・・突起 1 ... Base 1a ... Recess 1b ... Recess 2 ... Wiring layer 3 ... Lid 4 ... Container 5 ... Crystal oscillator 6 ... Semiconductor element 7: Crystal device 8 ... Fixing material 9 ... Conductive connection member 10 ... Encapsulating resin 11 ... Metallization layer for brazing 12 ... Metal frame 13 ... Protrusion

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) H03H 9/19 C04B 35/00 J ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) H03H 9/19 C04B 35/00 J

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】上下両面に搭載部を有し、該各搭載部から
外表面にかけて配線層が導出されている基体と、該基体
の搭載部に固定材を介して固定されている水晶振動子
と、前記基体下面の搭載部に搭載され、前記水晶振動子
の温度補償を行なう半導体素子とから成る水晶デバイス
であって、 前記基体はSi成分がSiO2に換算して25〜80重
量%、Ba成分がBaOに換算して15〜70重量%、
B成分がB23に換算して1.5〜5重量%、Al成分
がAl23に換算して1〜30重量%、Ca成分がCa
Oに換算して0重量%を超え30重量%以下含まれる焼
結体で、配線層が2.5μΩ・cm以下の比電気抵抗を
有する金属材で形成されており、かつ前記固定材の弾性
率が2.8GPa以下であることを特徴とする水晶デバ
イス。
1. A substrate having mounting portions on both upper and lower surfaces, a wiring layer extending from each of the mounting portions to the outer surface, and a crystal oscillator fixed to the mounting portion of the substrate via a fixing material. And a semiconductor device that is mounted on a mounting portion on the lower surface of the base body and performs temperature compensation of the crystal resonator, wherein the base body has a Si component converted into SiO 2 of 25 to 80 wt%. The Ba component is converted to BaO in an amount of 15 to 70% by weight,
B component is 1.5 to 5 wt% in terms of B 2 O 3 , Al component is 1 to 30 wt% in terms of Al 2 O 3 , and Ca component is Ca.
A sintered body containing more than 0% by weight and 30% by weight or less in terms of O, the wiring layer being formed of a metal material having a specific electric resistance of 2.5 μΩ · cm or less, and the elasticity of the fixing material. A crystal device having a rate of 2.8 GPa or less.
【請求項2】前記固定材がゴム粒子を添加したエポキシ
樹脂から成ることを特徴とする請求項1に記載の水晶デ
バイス。
2. The crystal device according to claim 1, wherein the fixing material is made of an epoxy resin added with rubber particles.
JP2001338988A 2001-11-05 2001-11-05 Crystal device Expired - Fee Related JP3906062B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001338988A JP3906062B2 (en) 2001-11-05 2001-11-05 Crystal device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001338988A JP3906062B2 (en) 2001-11-05 2001-11-05 Crystal device

Publications (2)

Publication Number Publication Date
JP2003142974A true JP2003142974A (en) 2003-05-16
JP3906062B2 JP3906062B2 (en) 2007-04-18

Family

ID=19153397

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001338988A Expired - Fee Related JP3906062B2 (en) 2001-11-05 2001-11-05 Crystal device

Country Status (1)

Country Link
JP (1) JP3906062B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009267885A (en) * 2008-04-26 2009-11-12 Kyocera Kinseki Corp Piezoelectric device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009267885A (en) * 2008-04-26 2009-11-12 Kyocera Kinseki Corp Piezoelectric device

Also Published As

Publication number Publication date
JP3906062B2 (en) 2007-04-18

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