JP2003095879A - Hair cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a hair cosmetic which conditions the surface state of the damaged hair and keeps smoothness and gloss of the hair. SOLUTION: This hair cosmetic comprises (A) one or more kinds of amino acids selected from arginine, glycine, alanine, serine, proline, leucine and isoleucine and (B) one or more kinds of highly polymerized amino-modified silicones represented by general formula (1) (m and n are each an integer, m+n is 3,000-20,000 and n/m is 1/500 to 1/10,000).

Description

Description: BACKGROUND OF THE INVENTION [0001] 1. Field of the Invention
Such as chemical treatment, dryer heat, brushing etc.
Condition the damaged hair surface (cuticle)
Hair rinse to maintain smooth and shiny hair
Hair conditioning and hair treatment
It relates to cosmetics. [0002] Hair is used for daily hair washing and hair makeup.
More damage. Especially in hair washing, washing ingredients
Is a surfactant that reduces sebum and constituent proteins in hair
It is eluted and you can feel the hair
Feel the damage visually and tactilely
It is known that Recently, hair color, yellowtail
And chemical treatments have become commonplace,
I have a car. Dryer heat and black
The physical load on the hair surface
Cuticle rolls up, peels off (lifts up)
This can easily cause throat and further promotes hair damage.
For the purpose of eliminating such tactile defects of damaged hair
Hair rinse, hair conditioner, hair treatment
And others have been proposed. For example, keratin or kolar
Replenishes hair constituents and similar components such as gen derivatives to hair
A known method is known (Japanese Patent Laid-Open No. 57-88109,
JP-A-2-53712, JP-A-4-60083)
Has an improving effect on damaged hair and a lasting effect
That is not enough. Also used for smoothness
Ester oil, silicone oil, etc.
These methods are used to improve the feel.
The effect of improving and improving damaged hair
It is not enough in terms of persistence. On the other hand, in order to improve these problems,
It has been proposed to incorporate a mino-modified silicone.
(JP-A-5-85918) discloses that these modified silicone
The corn is not improved in terms of improving the feel and maintaining the effect.
Cleans and repairs damaged but visible hair
Fruit cannot be expected. SUMMARY OF THE INVENTION Accordingly, an object of the present invention
Adjusts the condition of the damaged hair surface (cuticle),
Provide hair cosmetics that maintain smooth and shiny hair
It is to be. [0005] Means for solving the problems and embodiments of the present invention
The inventors conducted intensive studies to achieve the above object.
Results, (A) arginine, glycine, alanine, seri
One selected from, proline, leucine and isoleucine
One or more amino acids, and (B) the following general formula:
One type of highly polymerized amino-modified silicone shown in (1)
Or by using two or more types in combination to improve hair damage
Gives good effect, smooth hair, no pasatsu
Found that hair cosmetics with such effects can be obtained
Thus, the present invention has been accomplished. Accordingly, the present invention relates to (A) arginine,
Lysine, alanine, serine, proline, leucine, iso
One or more amino acids selected from leucine,
(B) A highly polymerized amino-modified silicone represented by the following general formula (1)
It is characterized by containing one or more types of silicone.
The present invention provides hair cosmetics. [0007] (Where m and n are each integers, m
+ N is 3000 to 20000, and n / m is 1/50
0 to 1/10000. Hereinafter, the present invention will be described in more detail. [0010] The component (A) of the hair cosmetic composition of the present invention is algi.
Nin, glycine, alanine, serine, proline, leucine
And amino acids selected from isoleucine.
The species may be used alone or in combination of two or more. Compounding amount
Is less than 0.01% (mass%, same hereafter) of the total hair cosmetics
Above is preferable, and particularly preferably about 0.05 to 10%.
No. If the amount is too small, the effect may not be fully exhibited.
Yes, too much may degrade the stability of the formulation. On the other hand, the component (B) is represented by the following general formula (1).
It is the highly polymerized amino-modified silicone shown. Embedded image In the formula, m and n are each an integer, and m +
n is 3000 to 20000, preferably 4000
~ 20,000. If m + n is less than 3000, it becomes oily
And the conditioning performance at the time of finishing is insufficient
If it exceeds 20,000, other raw materials such as silicone oil
And it is difficult to mix. Also, n
/ M is from 1/500 to 1/10000, preferably
Is 1/500 to 1/2000. n / m is 1/50
If it exceeds 0, the content of amino groups in the high molecular silicone will increase.
High, causing a cross-linking reaction during production, or
It is not preferable from the viewpoint of odor, and if it is less than 1/10000,
Insufficient interaction with the hair
Continuation effect is worsened. The above-mentioned highly polymerized amino-modified silicone is
One type may be used alone or two or more types may be used in combination.
Is 0.001 to 5% of the total amount of the hair cosmetic, particularly
It is preferable to be 0.01 to 2%. Less compounding amount
If it is too short, it may not produce sufficient effect,
The feeling of use such as stickiness may deteriorate. The hair cosmetic composition of the present invention contains the above-mentioned essential components.
In addition to the conventional hair treatment, the object of the present invention is not impaired.
Various components commonly used in cosmetics can be blended as desired.
Can be. For example, cationic surfactants, anions
Surfactants, nonionic surfactants, amphoteric surfactants, etc.
Surfactants, highly polymerized silicone, citric acid, glycol
Organic acids such as acid and succinic acid and salts thereof, phosphoric acid, hydrochloric acid, T
PH adjusters such as IPA, parabens, benzoic acid / salt
Which preservatives, bactericides, UV absorbers, antioxidants, grease
Serine, polyglycerin, propylene glycol, 1,
3-butylene glycol, sorbitol, xylitol
Polyhydric alcohols, higher alcohols, hydrocarbons, etc.
Ester oil, colorant, fragrance, solvent (ethanol, water
), Fatty acids, anti-dandruff agents, etc.
Olamine, zinc pyrithione, etc.)
Or they can be used in combination. List of perfume raw materials used as perfume
Can be found in various references, such as "Perfume and F
labor Chemicals, "Vol. I an
d II, Steffen Arctander, Al
lured Pub. Co. (1994) and "Synthesis.
Perfume Chemistry and Product Knowledge, "Motoichi Indo, Chemical Daily
(1996) and "Perfume and Fla.
vor Materials of Natural
Origin ", Stepeffen Arctande
r, Allured Pub. Co. (1994) and
And "Encyclopedia of Fragrance", edited by the Japan Fragrance Association, Asakura Shoten (198
9) and "Perfumery Material
Performance V. 3.3 ", Boelen
s Aroma Chemical Information
ion Service (1996) and “Flow
er oils and Floral Compou
ndsIn Performance ", Danute L
ajaujis Anonis, Allured Pu
b. Co. (1993) and cite each
Is hereby incorporated by reference. The following are representative examples of fragrances.
It is not limited. <Hydrocarbon compounds> Ocimene, dihydro
Myrcene, farnesene, cedrene, α-pinene, β-
Pinene, limonene, dipentene, camphene, ferran
Drain, terpinene, 3-carene, terpinolene, bi
Savoren, β-caryophyllene, cadinene, valance
, Tsuyobsen, guaien, allosimen, myrse
, Longifolene, veldracin (1,3,5-unde
Catriene), p-cymene, 4-isopropyl-1-
Methyl-2-propenylbenzene, diphenyl, dife
Nilmethane, orange terpene, lemon terpene, bell
Gamut terpenes, peppermint terpenes, spearmin
Toterpen, lime terpene, vetiver terpene, low
Wax, jasmine wax, limonene dimer,
Pentane, hexane, heptane, octane, nonane, de
Can, undecane, dodecane, tridecane, tetradeca
Pentadecane, hexadecane, heptadecane, octane
Tadecan, Nonadecane, Ikosan, Henikosan, DOKO
Sun, Trichosan, Tetracosan, Pentacosan, Heki
Sacosan, heptacosan, octacosan, nonacosan,
Triacontan and the like. <Alcohol compound> 3-Methyl-1-
Pentanol, geraniol, cedrol, citronello
, Rosinol, nerol, dihydrolinalool,
Narole, tetrahydrolinalool, dimethyloctano
, Tetrahydromugol, mugol, myrseno
, Dihydromyrcenol, oximenol, tetrahydride
Romyrcenol, lavandulol, isodihydrolaba
Ndurol, hydroxycitronellol, nonadil
(6,8-dimethyl-2-nonanol), ethyl linalo
, Isopulegol, terpineol, dihydroter
Pinneol, terpineol-4, perilla alcohol,
4-tanol, 3-tanol, farnesol, ne
Lolidol, α-bisabolol, β-caryophyllena
Rucol, santa roll, vetiver roll, cedrenault
, Patchouli alcohol, dihydrocarbeol,
Tall, isophytol, sclareol, carveo
, Menthol, 1-heptanol, 2-heptanol
, 3-heptanol, 1-octanol, 2-octa
Nord, 3-octanol, 2-ethylhexanol,
1-nonanol, 2-nonanol, isononyl alcohol
(3,5,5-trimethyl-1-hexanol), 1
-Decanol, 1-undecanol, 2-undecanol
, 1-dodecanol, prenol (3-methyl-2-
Buten-1-ol), 2-methyl-3-buten-2-
All, β-pentenol (1-penten-3-O
), Leaf alcohol (cis-3-hexeno)
Trans) -2-hexenol, trans-3
-Hexenol, cis-4-hexenol, 2,4-
Hexadiene-1-ol, matsutakeol (1-octane
Ten-3-ol), cis-6-nonenonel, cucca
Alcohol (2,6-nonadienol), and
Roll (1-nonen-3-ol), Rosalba (9-de
Senol), 1-undesenol, undecabertole
(4-methyl-3-decene-5-ol), osylol
(3,7-dimethyl-7-methoxy-2-octano
), Santalinol (2-methyl-4- (2,2,3
-Trimethyl-3-cyclopenten-1-yl) -2-
Buten-1-ol), p, α-dimethylbenzylal
Cole, 2,2,6-trimethylcyclohexyl-3-
Hexanol, 1,2-pentanediol, benzyla
Alcohol, anis alcohol, β-phenylethyl alcohol
Chole, styralyl alcohol (1-phenyl-1-hi)
Droxyethane), hydratropa alcohol, methyl β
-Phenylethyl alcohol, α-propylphenyl
Tyl alcohol, vanillyl alcohol, decahydro β-
Naphthol, furfuryl alcohol, 3-methyl-1-
Phenyl-3-pentanol, amylcinnamic al
Coal, cinnamic alcohol, phenoxanol
(3-methyl-5-phenylpentanol), 1,2-
Pentanediol, 2-ethylhexanol, dimetho
(2,6-dimethylheptanol), 3,6-dimethyl
Ru-3-octanol, cohinol (3,4,5,6,
6-pentamethyl-2-heptanol), Brahamano
(Methyltrimethylcyclopentenyl butanol),
Bagdanol (2-ethyl-4- (2,2,3-trime
Tyl-3-cyclopenten-1-yl) -2-butene-
1-ol), sandalore (3-methyl-5- (2,
2,3-trimethylcyclopenta-3-en-yl)-
Pentan-2-ol), cyclohexylethyl alcohol
, Apopachon (p-isopropylcyclohexano
), Floralol (2,4-dimethyl-3-cyclo)
Hexene-1-methanol), Pacheon (p-tert)
-Butylcyclohexanol), belldol (o-te
rt-butylcyclohexanol), Mayol (p-
Isopropylcyclohexylmethanol), cyclomethyl
Rencitronellol, Ambrinol (2,5,5-to
Trimethyl-octahydro-2-naphthol), methylsa
Ndeflor (5'or6'-methylnorborn-5 '
-En-2-yl) -2-methylpent-1-en-3
-Ol), Timberol (2,2,6-trimethylsi
Clohexyl-3-hexanol), polysanthol
(3,3-dimethyl-5- (2,2,3-trimethyl-
3-cyclopenten-1-yl) -4-pentene-2-
Oar), hydroxycitronellol, nonadil
(6,8-dimethyl-2-nonanol), isopregou
, Isocyclogeraniol, myrtenol, nopol
(6,6-dimethylbicyclo [3.1.1] hept-2
-En-2-ethanol), pinocalveol, α-fu
Enchil alcohol, borneol, isoborneol
Le, pachomint (2- (3,3-dimethylbicyclo)
[2.2.1] Hept-2-ylidene) ethanol),
Camecol (trimethylnorbornanemethanol), di
Methylcyclomol, Santarex T (Isocampi)
Rucyclohexanol), geranyl linalool, cumin
Alcohol, 2-methoxyphenylethyl alcohol,
Phenoxyethyl alcohol (1-hydroxy-2-f
Enoxyethane), α, α-dimethylphenylethyla
Alcohol, isobutylbenzylcarbinol, p-methyl
Rubenzylcarbinol, hydrocinamic alcohol
Le, centiphor (1,1-dimethyl-3-phenyl)
Propanol-1), muget alcohol (2,2-
Dimethyl-3-phenylpropanol), phenylhexyl
Sanol, decahydro β-naphthol, AR-1 (3,
6-dimethyloctane-3-ol), abitol (H
Droabiethyl alcohol), α-propylphenyle
Tyl alcohol, p-methyldimethylbenzylcarbino
, Mugetanol (1- (4-isopropylcyclohexane)
Xyl) ethanol), Florol (2-isobutyl-
4-hydroxy-4-methyltetrahydropyran),
Propylene glycol, dipropylene glycol, hexyl
Len glycol and the like. <Phenol type and phenol ether type>
Compounds> Anisole, Estragole, Cavicol,
Anethole, cresol, carvacrol, p-cure
Sol, p-cresyl methyl ether, β-naphthol
Methyl ether, β-naphthol ethyl ether, β-
Naphthol isobutyl ether, veratrol (1,2
-Dimethoxybenzene), 1,3-dimethoxybenze
, 1,4-dimethoxybenzene, catechol, resor
Sinol, guaiacol, balspice (4-methyl
Ayacol), 4-ethyl guaiacol, orcinyl 3
(3-methoxy-5-methylphenol), thymol,
Methyl thymol, propenyl guaetol (trans
-2-ethoxy-5- (1-propenyl) -pheno
), O-ethylphenol, m-ethylphenol,
p-ethylphenol, 2-tert-butylphenol
, Syringol (2,6-dimethoxyphenol),
Hydroquinone dimethyl ether, resorcinol dimethyl
Ether, eugenol, isoeugenol, dihydro
Eugenol, methyl eugenol, methyl isoeugen
Nol, ethylisoeugenol, benzyleugenol
Benzylisoeugenol, diosphenol, arsenic
Nokitiol, banitrop (1-ethoxy-2-hydride
Roxy-4-propenylbenzene), shogaol,
Gingerol, acetyl eugenol, acetyl iso
Igenol safrole, isosafrole, diphenylo
Oxide, vetiver ether (tert-butyl hydride
Roquinone dimethyl ether) and the like. <Aldehyde compound> Citronellal,
Citral, 3,7-dimethyl-1-octanal, arsenic
Droxycitronellal, methoxycitronellal, pe
Rilaldehyde, Miltenal, Caryophyllene alde
Hyd, n-hexanal, 2-methylbutanal, iso
Valeraldehyde, n-valeraldehyde, acetoal
Aldehyde, n-heptanal, n-octanal, n-no
Nanal, 2-methyloctanal, 3,5,5-tri
Methyl hexanal, 1-decanal, undecanar
, Dodecanal, 2-methyldecanal, 2-methyl
Undecanal, tridecanal, tetradecanal,
2-pentenal, cis-3-hexenal, tra
ns-2-hexenal, trans-2-heptenor
, 4-heptenal, trans-2-octenar
, Trans-2-nonenal, cis-6-nonena
, Melonal (2,6-dimethyl-5-heptenor
), Trans-4-decenal, cis-4-decenyl
Nal, trans-2-decenal, grinal
(2,5,6-trimethyl-4-heptenal), 10
-Undecenal, trans-2-undecenal,
trans-2-dodecenal, mandarin aldehyde
(3-dodecenal), trans-2-tridecenal
Adoxal (2,6,10-trimethyl-9-u
Ndecene-1-al), 2,4-hexadienal,
2,4-heptadienal, 2,4-octadiener
Le, 2,4-nonadienal, 2,6-nonadienal
Le, 2,4-decadienal, 2,4-undecadienal
, 2,4-dodecadienal, geraldaldehyde (5,
9-dimethyl-4,8-decadienal), trimener
(3,7,9-trimethyl-2,6-decadiene-1
-Earl), oncidar (2,6,10-trimethyl)
-5,9-undecadienal), bergamal (α-
Methylene citronellal), camphorenaldehyde,
Cyclocitral, isocyclocitral, safraner
(2,6,6-trimethyl-1,3-cyclohexadi
En-1-carboxaldehyde), mugealdehyde
(6,10-dimethyl-3-oxa-9-undecener
Geranyloxyacetaldehyde, tripral
(Dimethyltetrahydrobenzaldehyde), chrysan
Tar (3-propylbicyclo [2,2,1] -5-
Pentene-2-carboxaldehyde), centenal
(Methoxydicyclopentadiene carboxyaldehyde
C), Dupical (4-tricyclodecylidenebutana)
), 4- (4-methyl-3-cyclohexenylidene)
-1) Pentanal, myrac aldehyde (4 (3)
-(4-methyl-3-penten-1-yl) -3-cycl
Rohexene-1-carboxaldehyde), setnal
(Trimethylcyclohexenemethylbutanal), ino
Nal (2-methyl-4- (2,6,6-trimethyl-
1 (2) -cyclohexenyl) -butenal), teres
Toral (4-cyclooctene-1-carboxyalde
Hydr), benzaldehyde, p-tolylaldehyde,
Phenylacetaldehyde, trifernal (3-Fe
Nilbutanal), cuminaldehyde, p-methylphen
Nylacetaldehyde, p-isopropylphenylacetate
Toaldehyde, hydratropaldehyde, p-methylhydr
Doratropaldehyde, p-isopropylhydratropa
Aldehyde, phenylpropionaldehyde, β-methyl
Lehydrocinnamic aldehyde, jasmorandi (2
-Methyl-3- (4-methylphenyl) -propaner
), Burgeonal (p-tert-butylhydro
Cinamic aldehyde), cyclamen aldehyde (2
-Methyl-3- (p-isopropylphenyl) -propyl
Onaldehyde), Florarozone (p-ethyl-α, α)
-Dimethylhydrocinnamic aldehyde), Suzala
(P-isobutyl-α-methylhydrocinamic acid)
Aldehyde), cinnamaldehyde, salicylaldehyde
Hyd, anisaldehyde, o-methoxybenzaldehyde
De, o-methoxycinnamic aldehyde, cantoxa
(2-methyl-3- (p-methoxyphenyl) -propyl
Ropanal), vanillin, ethyl vanillin, methyl vanillin
Phosphorus (3,4-dimethoxybenzaldehyde), helio
Tropine, helional (α-methyl-3,4-methyle
Dioxyhydrocinnamic aldehyde), phenoki
Siacetaldehyde, p-methylphenoxyacetal
Aldehyde, furfural, 5-methylfurfural, 5-
Hydroxymethyl-2-furfural, furyl acrole
In, liral (4 (3)-(4-hydroxy-4-me
Tylpentyl) -3-cyclohexene-1-carboxy
Aldehyde), Bernaldehyde (1-methyl-4-
(4-methylpentyl) -3-cyclohexenecarboxy
Aldehyde), homomyrac aldehyde (1-meth
-4 (4-methyl-3-pentenyl) -3-cyclohexyl
Xencarboxaldehyde), junipal (4
(5) -formyl-7,7,9-trimethylbicyclo
[4.3.0] -nonene), wertral (octahi)
Dro-4,7-methanoindenecarboxyaldehyde
Do), Lilyal (p-tert-butyl-α-methyl)
Hydrocinnamic aldehyde), mefranal (3-
Methyl-5-phenylvaleraldehyde), eglanter
(4-methyl-2-phenyl-2-pentenal),
Cocal (5-methyl-2-phenyl-2-hexena)
), Α-methylcinamic aldehyde, α-butyl
Cinnamic aldehyde, α-amylcinnamic al
Dehyde, α-hexylcinnamic aldehyde, holmi
Ruethyltetramethyltetralin (6-ethyl-7-f
Olmil-1,1,4,4-tetramethyl-1,2,2
3,4-tetrahydronaphthalene) and the like. <Acetal and ketal compounds>
Gunolan (2,4-dimethyl-4,4a, 5,9b-te
Trahydroindeno [1.2d] -1,3-dioxa
), Anthoxane (4-isopropyl-5,5-dimension)
Chill-1,3-dioxane), indoflor (dihid)
Loindenyl-2,4-dioxane), boasambrene
Forte (formaldehyde cyclododecylethyl ace
Tar), acetaldehyde diethyl acetal, lee
Facetal (acetaldehyde ethyl hexenyl ace
Tar), acetaldehyde ethylhexyl acetate
, Citronellyl methyl acetal, erin tar (A
Cetaldehyde ethyl linalyl acetal), Bonaro
(2,4-dioxane-3-methyl-7,10-mex)
Tanospiro [5.5] undecane), ephetal (A
Cetaldehyde ethyl phenyl acetal), acetoacetate
Aldehyde ethyl isoeugenyl acetal, acetal
R (acetaldehyde phenylethyl n-propylacetate
Tar), Fluoropearl (acetaldehyde 2-phenyl)
2,4-pentanediol acetal), spirof
Roll (3-ethyl-2,4-dioxaspiro [5.
5] undecen-8-ene), ethyldimethyldioxa
Spiroundecene, herboxane (2-butyl-4,
4,6-trimethyl-1,3-dioxane), carana
(2- (2,4-dimethylcyclohex-3-cene-1)
-Yl) -5-methyl-5 (1-methylpropyl) 1,
3-dioxane), hexanal dimethyl acetal,
Hexanal diethyl acetal, hexanal propyl
Renglycol acetal, carotene (4,7-dihi
Dro-2- (3-pentanyl) -1,3-dioxepi
), 2-hexenal diethyl acetal, cis-
3-hexenal diethyl acetal, heptanal di
Methyl acetal, heptanal diethyl acetal,
Heptanal ethylene glycol acetal, 2-hex
Sil-5-methyl-1,3-dioxolan, 5-methyl
-5-propyl-2- (1-methylbutyl) -1,3-
Dioxane, Octanal dimethyl acetal, Octa
Naral diethyl acetal, nonanal dimethyl aceta
, Nonanal diethyl acetal, decanal dime
Tyl acetal, decanal diethyl acetal, 2-
Methylundecanal dimethyl acetal, dodecana
Dimethyl acetal, citral dimethyl acetal
Citral diethyl acetal, citral propi
Len glycol acetal, citronellal cyclomono
Glycol acetal, hydroxycitronellal dime
Tilacetal, hydroxycitronellal diethyla
Cetal, cis-3-hexenal diethyl acetate
, Benzaldehyde dimethyl acetal, benzal
Dehyde diethyl acetal, benzaldehyde propyle
Glycol acetal, benzaldehyde glycerin
Acetal, phenylacetaldehyde dimethyl aceta
, Phenylacetaldehyde ethylene glycol
Cetal, phenylacetaldehyde diisobutyl ace
Tar, phenylacetaldehyde propylene glycol
Luacetal, phenylacetaldehyde 2,3-buty
Len glycol acetal, phenylacetaldehyde
Glyceryl acetal, Resedabody (phenylacetate
Aldehyde-2,4-dihydroxy-2-methylpentane
Acetal), 3-phenylpropionaldehydedi
Methyl acetal, hydratropaldehyde dimethyla
Cetal, hydratropaldehyde aldehyde
Acetal, Osminal DMA (Amircinamic
Aldehyde dimethyl acetal), osminal DEA
(Amylcinnamic aldehyde diethyl acetater
Le), heliotropin dimethyl acetal, heliotro
Pin diethyl acetal, vanillin propylene glycol
Luacetal, verdoxane (2,2,5,5-tetra
Methyl-4-isopropyl-1,3-dioxane),
Converse (4,7-dihydro-2-isopentyl-
2-methyl-1,3-dioxepin), acetoketal
(2,5,5-trimethyl-2-phenyl-1,3-di
Oxane), jasmonane (2-butyl-4-dioxa)
Spiro [4.4] nonanone), fraystone (ethyl-
2,4-dimethyl-1,3-dioxolan-2-acete
), Fructon (ethyl-2-methyl-1,3-di)
Oxolan-2-acetate) and the like. <Ketone Compound> Acetyl Caryo Fillet
, Carvone, pregon, piperitenone, piperiton,
Mentone, show brain, oxosedran, isolongifo
Ranone, nootkatone, 2-heptanone, 2-pentano
, 3-hexanone, 3-heptanone, 4-heptano
2-octanone, 3-octanone, 2-nonanone,
3-nonanone, 2-undecanone, 2-tridecanone,
Methyl isopropyl ketone, ethyl isoamyl ketone,
Mesityl oxide, butylideneacetone, methylhept
Tadienone, methylheptenone, dimethyloctenone,
Corebon (4-methylene-3,5,6,6-tetramethi)
2-heptanone), geranylacetone, farnesi
Luacetone, acetoin, butyroin (5-hydroxy
-4-octanone), methyl lavender ketone (3-h
Droxymethyl-2-nonane), diacetyl, 2,3-
Pentadione, 2,3-hexadione, 3,4-hexa
Dione, 2,3-heptadione, acetyl isovaleri
Amylcyclopentanone, amylcyclopenteno
, 2-cyclopentylcyclopentanone, hexyl
Clopentanone, fluuramon (2-n-heptylsic)
Lopentanone), cis-jasmon, dihydrojas
Mon, Isojasmon, Trimethylpentylcyclopen
Tanone, Sedamon (2-butylidene-3,5,5 (3,
3,5) -Trimethylcyclopentanone), Sandeck
(3-methyl-5- (2,2,3-trimethyl-3-
Cyclopentenyl) -3-penten-2-one), cyclo
Rotene, coronol (3,5-dimethyl-1,2-sic
Lopentadione), methylcorylone (3,4-dimethyl)
1,2-cyclopentadione), verdone (2-ter)
t-butylcyclohexanone), p-tert-butyl
Cyclohexanone, Hellbach (3,3-dimethylcycline)
Rohexyl methyl ketone), frescommente (2-se
c-butylcyclohexanone), artemon (1-acetone)
Tyl-3,3-dimethyl-1-cyclohexene), cell
Leeketone (3-methyl-5-propyl-2-cyclohe
Xenon), krypton (4-isopropyl-2-sic)
Rohexanone), oribbon (p-tert-pentilsi)
Clohexanone), methylcyclocitron (2,3,5)
-Trimethyl-4-cyclohexenyl-1-methylketo
), Nelon (1- (p-menten-6-yl) -1-
Propane), Vetival (4-cyclohexyl-4-meth)
Tyl-2-pentanone), havanol (2- (1-sic)
Rohexen-1-yl) -cyclohexanone), malto
, Ethyl maltol, oxide ketone (cis-
2-acetonyl-4-methyl-tetrahydropyran),
Emoxifuron (5-ethyl-3-hydroxy-4-me
Chill-2 [5H] -furanone), homofurol (2-E)
Tyl-4-hydroxy-5-methyl-3 [2H] -fura
Non and 5-ethyl-4-hydroxy-2-methyl
-3 [2H] -furanone), sotolone (3-hydroxy
C-4,5-dimethyl-2 [5H] -furanone), fura
Neol (2,5-dimethyl-4-hydroxy-3 [2
H] -furanone), acetyldimethylfuran, furfura
Acetone, 2-acetyl-5-methylfuran, 2-
Acetylfuran, methyltetrahydrofuranone, diben
Zyl ketone, benzophenone, methyl naphthyl ketone,
4-Damaschol (5-phenyl-5-methyl-3-he
Xanone), Veticone (4-methyl-4-phenyl-2)
-Pentanone), α-methylanisalacetone, helio
Tropylacetone, anisylideneacetone, anisylua
Seton, p-methoxyphenylacetone, raspberry
Ton (4- (p-hydroxyphenyl) -2-butano
), Labandone (3-methyl-4-phenyl-3-)
Buten-2-one), benzylideneacetone, p-meth
Xyacetophenone, p-methylacetophenone, pro
Piophenone, acetophenone, damacenone, damasco
, Isodamascon, α-dynascon (1- (5,5
-Dimethylcyclohexen-1-yl) -4-pentene
-1-one), iriton (4- (2,4,6-trimethyi)
Ru-3-cyclohexen-1-yl) -3-butene-2
-On and 4-3,5,6-trimethyl-3-si
Clohexen-1-yl) -3-buten-2-one),
Yonone, pseudoyonone, methylyonone, methylirito
(3-methyl-4- (2,4,6-trimethyl-3-
Cyclohexenyl) -3-buten-2-one), cyclo
Wood (2,4-di-tert-butylcyclohexano
), Iron, allylyonone, 2,6,6-trimethyl
-2-cyclohexene-1,4-dione, Kamek DH
(2-acetyl-3,3-dimethylnorbornane),
Rolex (6-ethylideneoctahydro-5,8-me
Tano-2H-1-benzopyran-2-one), plicato
(4-methyltricyclo [6.2.1.0 ^2,7 ] Eun
Decane-5-one), oxosedran, beltfic
(9-acetyl-2,6,6,8-tetramethyltri
Cyclo [5.3.1 ^1,7 . 0 ^1,5 -8-undecene),
Verbenone (4,6,6-trimethyl- (1R) -bis
Clohept-3-en-2-one), fencon, caro
(7-methyl-3,5-dihydro-2H-benzodione
Xepin-3-one), Trimofix O (2,6,
10-trimethyl-1-acetyl-2,5,9-cyclo
Dodecatriene), Vitalide (acetyl dimethyl teto)
Lahydroventindan), Epiton (7 (8) -ace
Tyl-5-isopropyl-2-methylbicyclo [2.
2.2] Oct-2-ene), atrinone (4 (5)-
Acetyl-7,7,9 (7,7,9) -trimethylbis
Black [4.3.0] -1-nonene), cashmeren
(6,7-dihydro-1,1,2,3,3-pentamethyl
-4 (5H) -indanone), muscone (3-methyl)
Cyclopentadecanone-1), cibetone (cyclohepta)
Deca-9-en-1-one), exaltone (cyclope
Ntadecanone), Musk TM-II (cyclohexadece
Non), phantolide (5-acetyl-1,1,2,2,
3,3,6-hexamethylindane), celestride
(4-acetyl-6-tert-butyl-1,1-dimethyl
Tilindane), traseolide (5-acetyl-3-
Isopropyl-1,1,2,6-tetramethylinda
), Tonalide (6-acetyl-1,1,2,4,4,4)
7-hexamethyltetrahydronaphthalene), Vitalai
(Acetyldimethyltetrahydrobenzindane),
IsoE Super (7-acetyl-1,2,3,
4,5,6,7,8-octahydro-1,1,6,7-
Tetramethylnaphthalene), dihydrocarbon, dios
Examples include phenol and zingerone. <Ether compounds> Methylhexyl ether
Ter, decyl methyl ether, decyl vinyl ether,
Diethylene glycol monomethyl ether, diethylene
Glycol monoethyl ether, citronellyl ethyl ether
-Tel, geranyl ethyl ether, α-terpinylmethy
Ruether, herber belt (3,3,5-trimethylsi
Clohexyl ethyl ether), isobornyl methyl ether
-Tel, tricyclodecenyl methyl ether, isopro
Xene (2-ethylidene-6-isopropoxybicyclo
[2.2.1] heptane), juniperome (methoxy
Dimethyltricyclo [5.2.1.0 ^2,6 ] Decane),
Cyclododecyl methyl ether, Madrox (1-
Tyl cyclododecyl methyl ether), fizeol
(2-ethoxy-2,6,6-trimethyl-9-methyle
Bicyclo [3.3.1] -nonane), cedlumbar
(Cedrol methyl ether), methylbenzyl ether
, Methylphenylethyl ether, ethyl 2-methoxy
Cibenzyl ether, allyl phenyl ethyl ether,
Isoamyl benzyl ether, Answer (isoamylph
Enyl ethyl ether), jacene (2-methyl-2-
Butenyl phenyl ethyl ether), dibenzyl ether
, Cyclohexyl phenyl ether, myroxide
(Ocimene epoxide), limonene oxide (p-meth
Nt-8-ene-1,2-epoxide), rubofix
(Spiro [1,4-methanonaphthalene-2 (1H),
2'-oxirane],-3,4,4a, 5,8,8a-
Hexahydro-3 ', 7-dimethyl and spiro
[1,4-methanonaphthalene-2 (1H), 2′-oxo
Silane],-3,4,4a, 5,8,8a-hexahydride
B-3 ', 6-dimethyl), trimethylcyclododecato
Liene epoxide, caryophyllene oxide, cedre
Epoxide, isolongifolene epoxide, linalo
Oxide, citrooxide (2,2-dimethyl
-5 (1-methyl-1-propenyl) -tetrahydrof
Run), herbooxide (5-isopropenyl-2-)
Methyl-2-vinyltetrahydrofuran), rose fura
(3-methyl-2- (3-methyl-2-butenyl)-
Furan), heptabelt (2-heptyltetrahydroph)
Orchid), mentfuran, theaspirane, oxybed
(2-oxaspiro [4,7] dodecane), muscogen
(3-oxabicyclo [103.0] -6-pentade
Sen), cyclambar (13-oxabicyclo [10.
3.0] pentadecane), ambroxane (decahydro
-3a, 6,6,9a-tetramethylnaphtho [2.1-
b] furan), grisalva (3a-ethyldodecahydro)
-6,6,9a-Trimethylnaphtho [2.1-b] fura
), 1,8-cineole, 1,4-cineole, gala
Xolide (1,3,4,6,7,8-hexahydro-
4,6,6,7,8,8-hexamethylcyclopenta-
γ-2-benzopyran), rose oxide, nerol
Oxide, Limetol (2,2,6-trimethyl-6
-Vinyl tetrahydropyran), dilan (2-butyl-
4,6-dimethyldihydropyran), dremox (te
Trahydro-4-methyl-2-phenyl-2H-pyra
), Rubofloor (9-ethylidene-3-oxatrici)
Black [6.2.1.0 ^2,7 ] Undecane), hexahide
Loindenopyran and the like. <Acid compound> Gellanic acid, acetic acid, propio
Acid, pyruvic acid, butyric acid, isobutyric acid, 2-methylbutyric acid,
2-ethylbutyric acid, valeric acid, isovaleric acid, 2-methylvaleric
Acid, 3-methylvaleric acid, hexanoic acid, isohexanoic acid,
2-hexanoic acid, 4-pentenoic acid, 2-methyl-2-pe
Acid, heptanoic acid, 2-methylheptanoic acid, octa
Acid, nonanoic acid, decanoic acid, 2-decenoic acid, undecylene
Acid, dodecanoic acid, myristic acid, palmitic acid,
Aric acid, anthranilic acid, oleic acid, levulinic acid,
Lactic acid, benzoic acid, phenylacetic acid, cinnamic acid, 3-phenylene
Lupropionic acid, vanillic acid, valine, abietic acid,
And sorbic acid. <Lactone compound> Pentalide (cyclo
Pentadecanolide), havanolide (oxacyclohexa)
Decene-2-one), ambrettolide, cyclohexa
Decanolide, 10-oxahexadecanolide, 11-o
Xahexadecanolide, 12-oxahexadecanolide
Do, ethylene dodecandioate, γ-butyrolact
Γ-valerolactone, angelica lactone, γ-f
Xalactone, γ-heptalactone, γ-octalactone
, Γ-nonalactone, whiskey lactone (3-meth
Le-4-octanolide), γ-decalactone, γ-un
Decalactone, γ-dodecalactone, γ-jasmorak
Tons, jasmine lactone, cis jasmon lactone,
Lactojasmon (4-methyl-4-decanolide), di
Jasmolactone (tetrahydro-6- (3-pentenyl)
Ru) -2H-pyran-2-one), mentalactone
(3,6-dimethyl-5,6,7,7a-tetrahydro
-2 (4H) -benzofuranone), n-butylphthalic
, Propylidenephthalide, butylidenephthalide, δ-
Hexalactone, δ-octalactone, trivalon
(4,6,6 (4,4,6) -trimethyltetrahydro
Pyran-2-one), δ-nonalactone, δ-decalact
Ton, δ-2-decenolactone, δ-undecalact
Δ-dodecalactone, δ-tridecalactone, δ-
Tetradecalactone, lactoscatone (decahydro-
4, α-hydroxy-2,8,8-trimethylnaphthali
2-carboxyacid-δ-lactone), Kumari
, Dihydrocoumarin, cyclohexyllactone, 6-
Methyl coumarin, ε-decalactone, ε-dodecalact
And the like. <Ester compounds> Ethyl formate, formic acid
Ropyl, butyl formate, amyl formate, isoamyl formate,
Hexyl acid, cis-3-hexenyl formate, octyl formate
, Linalyl formate, citronellyl formate, geranyl formate,
Neryl formate, rosinyl formate, terpinyl formate, sed formate
Ril, caryofeiren formate, afermat (α,
3,3-trimethylcyclohexanemethylforme
G), oxyoctaline formate, benzyl formate, syn formate
Namyl, phenylethyl formate, anisyl formate, oily formate
Genyl, decahydro-β-naphthyl formate, methyl acetate,
Ethyl acetate, propyl acetate, isopropyl acetate, butyl acetate
Butyl, isobutyl acetate, 2-methylbutyl acetate,
Soamyl, amyl acetate, prenyl acetate, hexyl acetate,
Cis-3-hexenyl acetate, trans-2-hexyl acetate
Xenyl, 2-ethylhexyl acetate, heptyl acetate, vinegar
Octyl acid, 3-octyl acetate, octenyl acetate, acetic acid
Nonyl, decyl acetate, trimethylhexyl acetate,
Cenyl, nonanediol acetate, dodecyl acetate, dimethyl acetate
Chillundecadienyl, diacetyl, diacetin, tri
Acetin, ethylene glycol diacetate, ethylene
Glycol monobutyl ether acetate, allylamido
Luglycolate, osimenyl acetate, myrsenyl acetate, vinegar
Dihydromyrcenyl acid, dimethyloctanyl acetate, acetic acid
Linalyl, citronellyl acetate, rosinyl acetate, galley acetate
Nyl, neryl acetate, tetrahydromugol acetate, acetic acid
Tillinalil, lavandulyl acetate, isohydrola acetate
Vanjuril, nerolidol acetate, carbyl acetate, acetic acid
Dihydrocarbyl, dihydrocuminyl acetate, terpi acetate
Nyl, isopulegol acetate, menthyl acetate, citri acetate
, Miltenyl acetate, nopyryl acetate, fenquil acetate, vinegar
Bornyl acid, isobornyl acetate, ceryl acetate, kario
Filen acetate, Santalyl acetate, Vetiveri acetate
Guaiac, methyl cyclopentylidene acetate,
Cyclohexyl acetate, p-isopropylcyclohexyl acetate
Sanil, tert-amylcyclohexyl acetate, di acetate
Hydroterpinyl, cyclohexylethyl acetate, Flora
Rate (2,4-dimethyl-3-cyclohexenyl acetate)
Methyl), rosamsk (α, 3,3-trimethyl acetate)
Clohexanemethyl), Vertenex (p-te acetate)
rt-butylcyclohexyl), Belldox (acetic acid o)
-Tert-butylcyclohexyl), 1-ethynyl acetate
Lecyclohexyl, dihydroambrate (1-acetoacetate)
Xy-2-sec-butyl-1-vinylcyclohexa
), Mirardil acetate (4 (3)-(4-methyl-3)
-Pentenyl) -3-cyclohexenylmethyl acetate
G), tricyclodecenyl acetate, tricyclodecyl acetate
Benzyl acetate, p-cresyl acetate, phenyl acetate
Chill, styryl acetate, p-methylbenzyl acetate, acetic acid
Anisyl, piperonyl acetate, acetyl vanillin, rose
Phenone, hydratropyl acetate, 2,4-dimethyl acetate
Benzyl, cinnamyl acetate, phenylpropyl acetate, vinegar
Cuminyl acid, dimethylbenzylcarbinyl acetate, phenyl
Leglycol diacetate, dimethylphenylethyl acetate
Rucarbyl, phenylethyl methylethyl carb
Nyl, beticol acetate (4-methyl-4-phenyl)
2-pentyl acetate), α-amylcinna acetate
Mimill, jasmarol (trans-decahydro-β
-Naphthyl acetate), furfuryl acetate, tetraacetate
Hydrofurfuryl, jasmar (3-pentylte acetate)
Trahydropyranyl), Jasmeria (5-methyl acetate)
-3-butyltetrahydropyranyl), ethyl acetoacetate
Gesate (ethyl 2-hexylacetoacetate),
Ethyl benzylacetoacetate, cyclohexyl acetate
, Cyclohexenyl isopropyl acetate, propionic acid
Ethyl, propyl propionate, allyl propionate,
Butyl propionate, isobutyl propionate, propionate
Isoamyl onion, hexyl propionate, propion
Acid cis-3-hexenyl, propionic acid trans-
2-hexenyl, decenyl propionate, propionic acid
Linalyl, citronellyl propionate, ropropionate
Zinyl, geranyl propionate, neryl propionate,
Carbyl propionate, terpinyl propionate, pro
Menthyl pionate, bornyl propionate, propion
Isobornyl acid, tricyclodecenyl propionate,
Benzyl lopionate, stiralyl propionate, propyl
Anisyl onion, phenylethyl propionate, propyl
Cinnamyl onate, phenylpropyl propionate,
Dimethylbenzylcarboxy lopionate, propionic acid
Phenoxyethyl, propylene glycol propionate
Dipropionate, Rabdanax (3-hydroxy-
Ethyl 3-phenylpropionate), furanpropionic acid
Isobutyl, methyl butyrate, ethyl butyrate, propyl butyrate,
Isopropyl butyrate, allyl butyrate, butyl butyrate, isobutyrate
Butyl, amyl butyrate, isoamyl butyrate, hexyl butyrate,
Heptyl butyrate, cis-3-hexenyl butyrate, tr butyrate
ans-2-hexenyl, octyl butyrate, propylene glycol
Recall dibutyrate, linalyl butyrate, citronelli butyrate
Rosinyl butyrate, geranyl butyrate, neryl butyrate,
Lupinyl, cyclohexyl butyrate, benzyl butyrate,
Nnamyl, phenylethyl butyrate, dimethylbenzyl butyrate
Carvinyl, tetrahydrofurfuryl butyrate, Santa butyrate
Ryl, methyl isobutyrate, ethyl isobutyrate, isobutyric acid pro
Pill, isopropyl isobutyrate, butyl isobutyrate, isobutyrate
Isobutylate, isoamyl isobutyrate, hexyl isobutyrate
Cis-3-hexenyl isobutyrate, 2,4 isobutyric acid
-Hexadienyl, isopentylate (1,3 isobutyric acid)
-Dimethyl-3-butenyl), octyl isobutyrate, iso-
Linalyl butyrate, citronellyl isobutyrate, rosini isobutyrate
, Geranyl isobutyrate, neryl isobutyrate, ter isobutyrate
Pinyl, tricyclodecenyl isobutyrate, benzyl isobutyrate
, P-cresyl isobutyrate, cinnamyl isobutyrate,
Phenylethyl butyrate, phenylpropyl isobutyrate, iso
Styralyl butyrate, dimethylcarbyl isobutyrate, isobutyrate
Acid dimethylphenylethylcarbinyl, floranol
(Phenoxyethyl isobutyrate), decahydro isobutyrate-
β-naphthyl, methyl 2-methylbutyrate, 2-methylbutyric acid
Ethyl, 2-methylbutyl 2-methylbutyrate, Sidran
(Hexyl 2-methylbutyrate), cis- 2-methylbutyrate
3-hexenyl, benzyl 2-methylbutyrate, 2-methyl
Phenylethyl butyrate, allyl 2-ethylbutyrate, 3-hydrido
Ethyl roxybutyrate, methyl valerate, ethyl valerate, valer
Butylate, isobutyl valerate, amyl valerate, valerate c
is-3-hexenyl, benzyl valerate, phenyl valerate
Ethyl, furfuryl valerate, methyl isovalerate, iso
Ethyl valerate, propyl isovalerate, isopisovalerate
Ropyl, allyl isovalerate, butyl isovalerate, isovaler
Isobutyl valerate, isoamyl isovalerate, isovalerate
Mill, 2-methylbutyl isovalerate, cis isovalerate
-3-hexenyl, hexyl isovalerate, o-isovalerate
Cutyl, linalyl isovalerate, citronelli isovalerate
, Geranyl isovalerate, menthyl isovalerate, isovaler
Terpinyl valerate, cyclohexyl isovalerate, isovalerate
Benzyl, phenylethyl isovalerate, isovalerate
Phenyl, cinnamyl isovalerate, manzanate
(Ethyl 2-methylvalerate), phenyl salicylate,
Peranato (2-methylpentylester 2-methylvalerate)
M), methyl hexanoate, ethyl hexanoate, hexane
Propyl acid, isopropyl hexanoate, ant hexanoate
Butyl, hexanoate, isobutyl hexanoate, hexa
Amyl phosphate, isoamyl hexanoate, hexyl hexanoate
Cis-3-hexenyl hexanoate, hexanoic acid t
trans-2-hexenyl, heptyl hexanoate, hexyl
Linalyl sanate, citronellyl hexanoate, hexanoic acid
Geranyl, citronellyl hexanoate, benzenohexanoate
, Methyl isohexanoate, methyl 2-hexenoate, t
trans-2-ethyl hexenoate, 3-hexenoic acid methyl
, Ethyl 3-hexenoate, 3-hydroxyhexanoic acid
Methyl, ethyl 3-hydroxyhexanoate, 2-ethyl
Ethyl hexanoate, Mersat (3,5,5-trimethyl
Ethyl hexanoate), beliflo (ethyl 6-acetoxy)
Cihexanoate), methyl heptanoate, heptanoate
Chill, propyl heptanoate, allyl heptanoate, hepta
Octyl phosphate, methyl octanoate, ethyl octanoate,
Amyl octoate, butyl octoate, octoate pro
Pill, allyl octanoate, isoamyl octanoate, octane
Hexyl tannate, heptyl octanoate, octanoic acid
Tyl, linalyl octanoate, benzyl octanoate, octane
Phenylethyl tannate, p-cresyl octoate, 2-
Ethyl octenoate, methyl nonanoate, ethyl nonanoate,
Phenylethyl nonanoate, Boubaltate (2-nonene
Acid), methyl 3-nonenoate, methyl decanoate, de
Ethyl citrate, isopropyl decanoate, butyrate decanoate
, Isoamyl decanoate, ethyl 2-decenoate, 2,4
-Ethyl decadienate, 2,4-decadienoate propyl
Methyl, undecylenate, butyl undecylenate,
Isoamyl undecylenate, methyl dodecanoate, dodecane
Ethyl acid, butyl dodecanoate, isoamyl dodecanoate,
Ethyl myristate, methyl myristate, myristine
Isopropyl acid, ethyl palmitate, stearic acid
Chill, butyl stearate, methyl oleate, oley
Ethyl phosphate, methyl benzoate, ethyl benzoate, benzoate
Propylate, isopropyl benzoate, allyl benzoate,
Isobutyl benzoate, isoamyl benzoate, benzoate
Renyl, hexyl benzoate, cis-3-hexyl benzoate
Cenyl, linalyl benzoate, geranyl benzoate, benzoate
Benzyl, phenylethyl benzoate, cinnabenzoate
Mill, methyl anisate, ethyl anisate, o-methoxy
Methyl benzoate, ethyl o-methoxybenzoate, tigly
Ethylate, hexyl tiglate, cis-tiglate
3-hexenyl, citronellyl tiglate, tiglic acid
Geranyl, benzyl tiglate, phenyl tiglate
Chill, cinnamyl tiglate, methyl angelica,
Butyl angelic acid, isobutyl angelic acid, angelic acid
Isoamyl catenate, prenyl angelic acid, angelic acid
cis-3-hexenyl, angelic acid 3-methyl pen
Chill, phenylethyl angelic acid, ethyl acrylate
Phenylethyl methacrylate, ethyl crotonate,
Isobutyl crotonate, cyclohexyl crotonate,
Rutinato (4-methyl-pentan-2-ol-croto
), Piroprunate (2-cyclopentyl-cyclo)
Pentyl crotonate), datilato (1-cyclohexyl)
Ethyl crotonate), ethyl levulinate, levulin
Butyl acid, isoamyl levulinate, methyl lactate, lactate
Chill, amyl lactate, isobutyl lactate, cis-3-lactate
Hexenyl, butyl butyryl lactate, ethyl pyruvate,
Methyl gellanate, ethyl gellanate, methyl cyclogelate
, Ethyl cyclogelanoate, furtate (ethyl trisyl
Black [5.2.1.0 ^2,6 ] Decan-2-yl carbo
Xylate), divescon (ethyl-2-ethyl-6,6)
6-dimethyl-2-cyclohexene-1-carboxyle
And & ethyl-2,3,6,6-tetramethyl-2
-Cyclohexene carboxylate), ethyl safrane
(Ethyl dehydrocyclogeranate), cyclohexyl
Allyl silpropionate, cyclogalvanate (allyl
Cyclohexyloxyacetate), calixol (d
Tyl-2-methyl-6-pentyl-4-oxocyclohe
Xy-2-enecarboxylate), taclisate (meth
Tyl-1-methyl-3-cyclohexenecarboxylate
G), floramate (ethyl-2-tert-butyloxy)
Clohexyl carbonate), jasma cyclate (meth
Tyl cyclooctyl carbonate), mahgonate (1
-Methyl-4-isopropyl-2-carbomethoxybis
Clo [2,2,2] -oct-5-ene), pivalic acid
Enylethyl, methyl jasmonate, hedion (Jihi
Methyl droyasmonate), veramos (methyl-3,6)
-Dimethyl-β-resorcylate), furancarboxylic acid
Methyl, ethyl furancarboxylate, furanacrylate
Lopir, Methyl heptinecarboxylate, Heptincarboxylic
Ethyl acid, isoamyl heptinecarboxylate, octinka
Methyl rubonate, ethyl octyne carboxylate, desinka
Methyl rubonate, glycol (3- (bicyclo [2.
2.1] Hept-5-en-2-yl) -3-methyloxo
Methyl ester of silane carboxyacid), phenyl
Methyl luglycidate, ethyl phenylglycidate, al
Dehydration C-16 (3-methyl-3-phenylglycidic acid
Ethyl), aldehyde C-20 (p-methyl-β-fe
Ethyl nylglycidate), methyl p-tolylglycidic acid
Ethyl, ethyl citronellyl oxalate, diethyl succinate
Dimethyl succinate, diethyl malonate, dietartrate
Chill, diethyl adipate, diethyl sebacate, que
Triethyl phosphate, dimethyl phthalate, diethyl phthalate
, Dibutyl phthalate, methyl phenylacetate, phenyl
Ethyl acetate, isopropyl phenylacetate, phenylacetic acid
Butyl, propyl phenylacetate, isobutyl phenylacetate
, Isoamyl phenylacetate, hexyl phenylacetate,
Cis-3-hexenyl phenylacetate, phenylacetate
Toneryl, Rosinyl phenylacetate, Gela phenylacetate
Nyl, menthyl phenylacetate, benzyl phenylacetate,
Phenylethyl phenylacetate, p-Credit phenylacetate
, Eugenyl phenylacetate, isoeugen phenylacetate
Nil, methyl cinnamate, ethyl cinnamate, cinnamate pro
Pill, isopropyl cinnamate, allyl cinnamate, cinnamon
Isobutyl acid, isoamyl cinnamate, linalic cinnamate
Benzyl cinnamate, cinnamyl cinnamate, cinnamic acid
Phenylethyl, methyl salicylate, ethyl salicylate
Butyl, salicylate, isobutyl salicylate, salicy
Amyl luate, isoamyl salicylate, hexyl salicylate
Cis-3-hexenyl salicylate, salicylic acid
Clohexyl, phenyl salicylate, benzyl salicylate
Phenylethyl salicylate, cyclopidene (methyl
Cyclopentylidene acetate), ethyl-2,2,6
-Trimethylcyclohexane carbonate, avaline
(Methyl aviate), herculin (methyl dihydro)
Aviate), p-cresyl salicylate, phenoxy
Allyl acetate, ethyl phenylpropionate, ethylene
Rasilate, triacetin and the like can be mentioned. <Nitrogen-containing compound> Methyl anthranilate
, Ethyl anthranilate, butyl anthranilate,
Cis-3-hexenyl anthranilate, anthranilic acid
Phenylethyl, cinnamyl anthranilate, N-methyl
Methyl luanthranilate, auran thiol (hydroxy
Schifftronellal-Methylanthranilate Schiffbe
), Mevantral (methyl propyl acetoalde)
Hyd-methylanthranilate Schiff base), ja
Sumentin (α-amylcinamic aldehyde-methyl
Luang Suranilate Schiff Base), Ligantrall
(Methyl- (3,5-dimethyl-3-cyclohexene-
1-yl) methylene anthranilate), indole,
Skatole, Clonal (dodecanenitrile), Tanji
Eneil (2-tridecennitrile), citraluba (ge
Ranilnitrile), citronellyl nitrile, lemonyl
(3,7-dimethyl-2,6-nonadienitrile),
Minyl nitrile, cinnamalva (cinnamyl nitrile
), Trimethylamine, pyridine, 3-ethylpyridyl
2-acetylpyridine, 3-acetylpyridine, 2
-Isobutylpyridine, 3-isobutylpyridine, 2-
n-pentylpyridine, 5-ethyl-2-methylpyridi
, Methyl nicotinate, 4- (1,4,8-trimethyl
-3,7-nonadienyl) pyridine, quinoline, isoki
Norin, p-methylquinoline, tetrahydro-p-methyl
Lucinoline, 6-isopropylquinoline, isobutyl
Norin, 2-isobutylquinoline, 6-sec-butyl
Quinoline, 8-sec-butylquinoline, 6 (p) -t
tert-butylquinoline, 2-tert-butylquinolin
, Pyrazine, 2-methylpyrazine, 2,5-dimethyl
Pyrazine, 2,6-dimethylpyrazine, 2,3,5-to
Limethylpyrazine, 2-ethylpyrazine, 2-ethyl-
3-methylpyrazine, 2-ethyl-5-methylpyrazine
2-ethyl-3,5 (3,6) -dimethylpyrazine
2,3-diethylpyrazine, 2,3-diethyl-5
-Methylpyrazine, tetramethylpyrazine, 2-methyl
-5-vinylpyrazine, methoxypyrazine, 2-methoxy
Ci-3-methylpyrazine, 2-methoxy-3-ethylpi
Azine, 2-methoxy-3-isopropylpyrazine, 2
-Isobutyl-3-methoxypyrazine, 2-acetylpyrazine
Razine, 2-acetyl-3-ethylpyrazine, methylthio
Omethylpyrazine, corylonepyrazine (5-methyl-
6,7-dihydrocyclopentapyrazine), 5-methyl
Quinoxaline, cyclohexapyrazine (5,6,7,8
-Tetrahydroquinoxaline), 1-methylpyrrole,
2-acetylpyrrole, pyrrolidine, indolene (in
Dol-hydroxycitronellal Schiff base),
2-methylbenzoxazole, decahydrocyclodode
Caoxazole, 5-methyl-3-heptanoneoxy
Bucoxime (bicyclo [3.2.1] octane-8
-One, 1,5-dimethyl-, oxime), Gardamai
(N-methyl-N-phenyl-2-methylbutylamido)
C), musk xylol, musk ketone, musk umbu
Lett, Muskti Betten, Mosken, 2,6-Lutiji
, Piperidine, 2- (1,4,8-trimethyl-3,
7-nonadienyl) pyridine, 2- (2-pinene-10)
-Ylmethyl) pyridine, 4- (2-pinene-10-i
Somethyl) pyridine, piperine, capsaicin, nonane
Acid vanillylamide, quinine, perillartin (L-peri
Laaldehyde α-anti-aldoxime), 2-a
Sopropyl-4-methylthiazole, 2-isobutylthio
Azole and the like. <Sulfur-containing compounds> Thiazole, 4-methyl
Luthiazole, 4,5-dimethylthiazole, trimethyl
Luthiazole, 2-methyl-5-methoxythiazole,
2-isopropyl-4-methylthiazole, 4-methyl
-5-vinylthiazole, 2-isobutylthiazole,
Sulfurol (4-methyl-5-thiazoleethanol
), Sulfuryl acetate (4-methyl-5-thia)
Sol-ethanol acetate), 2-acetylthiazolate
, 5-acetyl-2,4-dimethylthiazole, ben
Zothiazole, propyl mercaptan, hydrogen sulfide, iso
Propyl mercaptan, 2-methyl-3-butanethio
, Allyl mercaptan, isoamyl mercaptan,
Ogeraniol, limonene thiol, sulfox
(8-mercaptomentone) phenyl mercaptan, o
-Thiocresol, 2-ethylthiophenol, 2-na
Futyl mercaptan, furfuryl mercaptan, 2-me
Tyl-3-furanthiol, dimethyl sulfide, dime
Tyl disulfide, dimethyl trisulfide, methyl sulfide
Ropir disulfide, methylpropyl trisulfide,
Propyl disulfide, dipropyl trisulfide, di
Allyl sulfide, diallyl disulfide, dibutyls
Sulfide, methionol (3- (methylthio) -1-p
Ropanol), 3-methylthio-1-hexanol,
Thional (3- (methylthio) propionaldehyde
C), mint sulfide, dithiospirofuran, furf
Rylmethyl sulfide, 2-methyl-5-methylthiophene
Orchid, methylfurfuryl disulfide, furfuryldis
Sulfide, thiophene, tetrahydrothiophene, 3-
Thiophenecarboxaldehyde, 5-methyl-2-thio
Offencarboxaldehyde, tetrahydrothiophene
N-3-one, trithioacetone, thioglycolic acid,
Methyl methylthioacetate, ethyl methylthioacetate,
Rucaptopropionic acid, pineapple mercaptan (meth
Tylmercaptomethylpropionate), 3-methylthio
Ethyl thiopropionate, ethyl thioacetate, thioacetate full
Furyl, furfuryl thiopropionate, methylthiobutyrate
, Methyl methane thiosulfonate, isothiocyan
Allyl acid, benzyl isothiocyanate, thiardine
(2,4,6-trimethyl-4,5-dihydro-1,
3,5-dithiazone), oxane (2-methyl-4-p)
Ropyl-1,3-oxathiane) and the like. <Natural fragrance> Asafetidaresinoid,
Ajowan oil, Star anise oil, Abies oi
Le, Amyris oil, Ambrette seed oil, Ann
Berglist tincture, ylang-ylang oil, ylang-ylang
Absolute, Iris resinoid, Iris absolute
, Iris oil, winter green oil, ele
Myoleoresin, Elemiresinoid Absolute, D
Remit tincture, oak moss concrete, oak moss
Solut, oak moss resin, oak moss resinoi
De, okotia oil, osmanthus absolute,
Osmanthus Concrete, Opopanax Resinoi
Do, Opopanax Absolute, Opopanax
Il, Olivernum Resinoid, Olivernum Absolute
G, olivenum oil, allspice oil, orega
Oil, oregano oleoresin, orange oil, o
Range Flower Absolute, Orange Flower Con
Cleats, cananga oil, garjun balsam, gar
Junbal sam oil, cascari bark oil, kas
Thorium absolute, Cassie absolute, mosquito
Flower oil, cassia oil, gardenia
Bussolut, Carne Absolute, Cabru
Oil, chamomile oil, cardamom oil, gal
Banam Oil, Galvanum Resin, Galvanam Resinoi
De, caraway seed oil, carrot seed oy
Guaiac wood oil, guaiac resin, gua
Yack concrete, camphor oil, Kubeba oil,
Cumin oil, cumin absolute, cumin oleoresin
Gin, clary sage oil, grapefruit oil,
Clove oil, Costas oil, Copaiba balsam,
Copaiba balsam oil, copaiba balsam resin, cocoa
Leander oil, sassafras oil, sandalwood
Oil, Gene Absolute, Perilla oil, Citro
Nera oil, jasmine absolute, jasmine
Concrete, juniper berry oil, civet abso
Lute, civet tincture, john kill absolute
, Agarwood oil, ginger oil, cinnamon
Oil, cinnamon bark oil, cinnamon leaf oy
, Cedar oil, styrax oil, styraxle
Zinoid, spearmint oil, savory oil,
Oil, cedar oil, cedar leaf oil, zera
Nium oil, celery seed oil, thyme oil,
Tugget oil, tarragon oil, tuberose absolute
Lute, dill oil, tea tree oil, tree
Moss Absolute, True Balsam, Nutmeg Oy
Le, narcissus absolute, neroli oil, bio
Lett Absolute, Pine Oil, Basil O
Il, parsley relief oil, parsley seed oil, parsley
Reherb oil, patchouli oil, peppermint oil, bani
Ra Absolute, Honeysuckle Absolute, Pa
Lumarosa oil, valerian oil, bitter orange
Oil, hyssop oil, hiba oil, hyacinth abu
Solut, fennel oil, figabsolue
, Petitgren oil, Butch oil, Vetiva oil
Le, Penny Royal Oil, Pepper Oil, Peppermi
Oil, bergamot oil, Peruvian balsam,
Nzoin tincture, benzoin resinoid, boad rose
Oil, oil, hop oil, hopcon
Cleats, Hop Absolute, Marjoram Oy
, Mandarin oil, mandarin oil, mimosa concrete
, Mimosa Absolute, Mimosa Oil, Milregi
Noid, mill absolute, mill oil, musk abu
Solut, muskutuki, eucalyptus oil, yuzuoi
, Mugwort oil, lime oil, lab d'anum oil,
Lavdanum resinoid, lavender oil, lavender
Absolute, Lavandin oil, Lavandin Abso
Lute, linaloe oil, lemon oil, lemongrass
Oil, rose oil, rose absolute, raw
Concrete, rosemary oil, robeggioi
, Laurel oil, laurel leaf oil, worm
Oil, musk, spirit cat incense, dragon incense, sea tanuki incense, musk
・ Cibata and the like. <Mixed perfume> Also, a combination of perfume ingredients
There are the following fragrance-based bases that are compounded fragrances. Remo
Tone, lime tone, orange tone, sweet orange tone, ma
Citrus-type bases such as Darling and Bergamot
, Petitgren, Neroli, Lemongrass, Aggle
Men type, fresh type base, apple style, pi
Peach, strawberry, coconut, pineapple
Tone, raspberry tone, watermelon tone etc.
Type base, rose tone, jasmine tone, mug tone, rye
Rack tone, carnation tone, hyacinth tone, tubero
Tones, gardenia, mimosa, narciss, bio
Flora in red, Iranian, floral bouquet, etc.
Base, cinnamon bark, cinnamon leaf
Tone, clove tone, Pimento berry tone, nutmeg tone, pe
Par tone, cardamom tone, coriander tone, cumin tone etc.
Spicy type base, cedar wood style, vetiver
Tone, sandalwood tone, guaiac wood tone, woody
Woody type base such as amber and woody iris
Leather type such as su, smoky tone, quinoline tone, bani
La, Tonka, Honey, Pure Balsam
ゥ Eat type base, other Aldehi Dick Thailand
Base, amber type base, animal type base
, Anise type base, aromatic herbal tie
Base, agar type base, aqua type base,
Camphor Cineol Type Base, Green Type Base
Sauce, seed type base, herb type base, pie
Type base, patchouli type base, balsamic
Type base, mint type base, musk type base
, Moss type base, lavender type base, lina
Roll type base, resin type base, etc.
You. Further, as a solvent for the fragrance, ethanol,
Acetin (triacetin), MMB acetate (3-meth
Toxi-3-methylbutyl acetate), ethylene glycol
Choledibutyrate, hexylene glycol, dibutyl
Sebacate, Delchil Extra (Isopropyl Milli
State), methyl carbitol (diethylene glycol)
Monomethyl ether), carbitol (diethylene glycol)
Recohol monoethyl ether), TEG (triethylene
Glycol), benzyl benzoate, propylene glycol
, Diethyl phthalate, tripropylene glycol,
Borin (dimethyl phthalate), Deltyl Prime (I
Sopropyl palmitate), dipropylene glycol D
PG-FC (dipropylene glycol), farnese
Dioctyl adipate, tributyrin (glyceryl
Tributanoate), hydrolite-5 (1,2-pen
Tandiol), propylene glycol diacetate,
Cetyl acetate (hexadecyl acetate), ethyl
Aviate, Avaline (Methyl Aviate), Cit
Roflex A-2 (acetyltriethylcitrate
G), Citroflex A-4 (tributyl acetyl
Toreto), Citroflex No. 2 (triethylsi
Toreto), Citroflex No. 4 (tributyl
Tolate), Durafix (methyldihydroavier)
TET), MITD (isotridecyl myristate),
Polylimonene (limonene polymer), propylene glyco
And 1,3-butylene glycol. As a fragrance stabilizer, dibutyl hydrogen
Droxytoluene, butylhydroxyanisole, Vita
Min E and its derivatives, catechin compounds, flavonoids
Compounds, polyphenol compounds, etc., in the fragrance composition
0.0001 to 10% by mass, preferably
Is compounded in an amount of 0.001 to 5% by mass. Among these,
Preferred stabilizers include dibutylhydroxytoluene.
It is. The fragrance composition includes the fragrance component, the solvent,
It is a mixture comprising a fragrance stabilizer and the like. The amount of the solvent used in the perfume composition
0.1 to 99% by mass, preferably 1 to 5%
0 mass% is blended. The hair cosmetic composition of the present invention contains a fragrance composition.
Although 0.001 to 50% by mass is blended, preferably,
0.005 to 15% by mass is blended. In the following, formulation examples of the fragrance composition are shown.
Is not limited to this. The following fragrance composition
Products A to D are used in Examples described later. [Table 1] [Table 2] [Table 3] [Table 4] [Table 5] [Table 6] [Table 7] [Table 8] [Table 9] * 1: [Flower oils and
Floral CompoundsIn Perfu
Mary] Danute Lajaujis Ano
nis, Allured Pub. Co. Further, aluminum laminate is used for the container.
Tube, EVAL tube, aluminum tube, glass
In addition to tubes such as vapor-deposited plastic tubes, mechanical
Or dispenser container and squeeze by differential pressure
Containers, laminated film containers, dropper containers,
It can be filled in bottle containers, bottle containers and the like. Lami
Nate film usually has two or more layers and its material
Is polyethylene, polyethylene terephthalate, polyether
Stell, biaxially oriented polypropylene, non-oriented polypropylene
, Polyacrylonitrile, ethylene vinyl acetate copolymer
Body, synthetic resin, paper, aluminum-deposited plastic, etc.
It is composed. Considering strength, flexibility, weather resistance, etc., general
Typically, two to five layers are used. As the material of the bottle
Polyethylene, polypropylene, polyethylene terephthalate
Rate, polystyrene, polyvinyl chloride, ethylene-bi
Nyl alcohol resin, acrylonitrile / styrene tree
Resin, ABS resin, polyamide, glass, etc.
Two or more layers can be used in combination. Hereinafter, the present invention will be described specifically with reference to examples.
However, the present invention is not limited to the following examples.
No. [Examples 1 to 3 and Comparative Examples 1 to 3]
A rinsing agent having the composition of
Evaluation of fruit, smoothness and lack of pastsuki as follows
did. Table 10 shows the results. <Effect of improving damaged hair> Good surface condition of cuticle
Healthy hair (healthy hair), perm treatment, anionic interface
Damaged hair by repeating activator (LES) treatment 3 times
After fabrication, damage by scanning electron microscope (SEM)
Select damaged hair with the same level of condition and set this as the initial value.
The degree of improvement on the hair surface after treatment with each treatment
Compared to the state. Treatment conditions Using the rinsing agents shown in Table 10 and assuming actual use,
The damaged hair was treated by the following method. 15% LES water soluble
Solution, each rinse agent is diluted 10 times with water, and each aqueous solution is stirred
LES solution (1 minute) → Wash with water (1 minute) → Each treatment
Physiological solution (1 minute) → water washing (30 seconds) → drying as one cycle
After 5 cycles, observe the surface condition with SEM.
And compared it with the initial state. Evaluation criteria Notably improved: ◎, improved: ○, slightly modified
Good was seen: △, no improvement was seen: x. <Smoothness, no pastsuki> Shampoo the above rinse agent
-Use for 7 days with set, smoothness after drying, pasatsu
The absence of a key was confirmed by a questionnaire. Subjects are pre-prepared
Selected from women who felt hair damage by inspection
They returned 10 people. Each item is evaluated on a scale of 5
Average value is 4.5 points or more: 、 ３, 3 points or more: 、 ２, 2 points or more:
△, below: x. [Table 10] [Examples 4 to 15] Table 11 (rinse), Table 1
2 (rinse), the formulation shown in Table 13 (treatment)
A hair cosmetic was prepared. [Table 11] [Table 12] [Table 13] * 1: KF8020 (Shin-Etsu Chemical) * 2: KF8018 (Shin-Etsu Chemical) * 3: KF8017 (Shin-Etsu Chemical) * 4: KF6015 (Shin-Etsu Chemical) Examples 4 to 6: Filling in polypropylene containers Examples 7-9: Filling polypropylene-polyethylene containers
Filling Examples 10 to 12: In a polyethylene terephthalate container
Filling Examples 13 to 15: Aluminum evaporated polyethylene pouch container
Example 16-18: Filled into a two-layer polyethylene tube Example 19: Polypropylene-polyethylene bottle (de
Filling into dispenser container) [0057] In any of the embodiments, the properties of the hair surface are improved and used.
Finish performance (smoothness, no pastsuki)
Everything was good. EFFECT OF THE INVENTION The hair cosmetic composition of the present invention can be used for treating damaged hair.
Condition the face and maintain smooth and shiny hair.

Continuation of front page    (72) Inventor Yasuo Nagahara             Rio, 1-3-7, Honjo, Sumida-ku, Tokyo             Incorporated (72) Inventor Takashi Koyama             Rio, 1-3-7, Honjo, Sumida-ku, Tokyo             Incorporated F-term (reference) 4C083 AB012 AC072 AC112 AC122                       AC182 AC252 AC262 AC302                       AC312 AC352 AC422 AC442                       AC482 AC542 AC581 AC582                       AC612 AC662 AC692 AC742                       AD072 AD152 AD161 AD162                       AD282 BB41 CC31 CC33                       CC39 DD23 DD28 EE06 EE07                       EE28 EE29

Claims (1)

Claims: 1. An amino acid selected from the group consisting of (A) one or more amino acids selected from arginine, glycine, alanine, serine, proline, leucine and isoleucine, and (B) represented by the following general formula (1). A hair cosmetic comprising one or more highly polymerized amino-modified silicones. Embedded image (Wherein, m and n are each an integer, and m + n is 300)
0 to 20000, and n / m is 1/500 to 1/10
000. )