JP2003043219A - Method for correcting projection defect in light diffusing member and light diffusing member and transfer film by using the same - Google Patents

Method for correcting projection defect in light diffusing member and light diffusing member and transfer film by using the same

Info

Publication number
JP2003043219A
JP2003043219A JP2001227926A JP2001227926A JP2003043219A JP 2003043219 A JP2003043219 A JP 2003043219A JP 2001227926 A JP2001227926 A JP 2001227926A JP 2001227926 A JP2001227926 A JP 2001227926A JP 2003043219 A JP2003043219 A JP 2003043219A
Authority
JP
Japan
Prior art keywords
light diffusing
diffusing member
film
base film
thin film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001227926A
Other languages
Japanese (ja)
Inventor
Keiko Kizawa
桂子 木沢
Takeshi Yoshida
健 吉田
Toshikatsu Shimazaki
俊勝 嶋崎
Yasuo Tsuruoka
恭生 鶴岡
Nobuaki Takane
信明 高根
Hidekuni Tomono
秀邦 伴野
Toshikazu Takamatsu
利和 高松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Showa Denko Materials Co Ltd
Original Assignee
Hitachi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd filed Critical Hitachi Chemical Co Ltd
Priority to JP2001227926A priority Critical patent/JP2003043219A/en
Publication of JP2003043219A publication Critical patent/JP2003043219A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To efficiently correct projection defects and to provide a light diffusing member and a transfer film to be used for a diffusing reflector or the like of a reflection type LCD having preferable reflection characteristics. SOLUTION: The method for correcting projection defects of a light diffusing member or a base film is carried out by irradiating the projection defects of the rugged face of the light diffusing member or the projection defects in the base film forming the rugged face of the light diffusing member with laser light at least once to correct the projection defects.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、バックライトを必
要としない反射型液晶表示装置や表示装置前面に配置し
映り込みを防止するアンチグレアフィルムや高効率を必
要とされる太陽電池などに使用される光拡散部材の突起
欠陥修正方法、及びこれを用いた光拡散部材、光拡散部
材の製造に使用される転写フィルムに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is used for a reflection type liquid crystal display device which does not require a backlight, an anti-glare film which is arranged on the front surface of the display device to prevent glare, and a solar cell which requires high efficiency. The present invention relates to a method for correcting protrusion defects of a light diffusing member, a light diffusing member using the same, and a transfer film used for manufacturing the light diffusing member.

【0002】[0002]

【従来の技術】液晶ディスプレイ(以下LCDと略す)
は、薄型、小型、低消費電力などの特長を生かし、現
在、時計、電卓、TV、パソコン等の表示部に用いられ
ている。更に近年、カラーLCDが開発されOA・AV
機器を中心にナビゲーションシステム、ビュウファイン
ダー、パソコンのモニター用など数多くの用途に使われ
始めており、その市場は今後、急激に拡大するものと予
想されている。特に、外部から入射した光を反射させて
表示を行う反射型LCDは、バックライトが不要である
ために消費電力が少なく、薄型、軽量化が可能である点
で携帯用端末機器用途として注目されている。
2. Description of the Related Art Liquid crystal display (hereinafter abbreviated as LCD)
Taking advantage of its thinness, small size, and low power consumption, is currently used for display parts of watches, calculators, TVs, personal computers and the like. Furthermore, in recent years, color LCDs have been developed and OA / AV
It is beginning to be used in many applications such as navigation systems, viewfinders, personal computer monitors, etc., centering on equipment, and the market is expected to expand rapidly in the future. In particular, a reflective LCD that reflects light incident from the outside to display an image is attracting attention as a portable terminal device application because it does not require a backlight and thus consumes less power and can be made thinner and lighter. ing.

【0003】従来から反射型LCDにはツイステッドネ
マティック方式並びにスーパーツイステッドネマティッ
ク方式が採用されているが、これらの方式では直線偏光
子により入射光の1/2が表示に利用されないことにな
り表示が暗くなってしまう。そこで、偏光子を1枚に減
らし、位相差板と組み合わせた方式や相転移型ゲスト・
ホスト方式の表示モードが提案されている。
Conventionally, a twisted nematic system and a super twisted nematic system have been adopted for reflective LCDs, but in these systems, half of the incident light is not used for display due to the linear polarizer, and the display is dark. turn into. Therefore, we reduced the number of polarizers to one and combined it with a retardation film or a phase transition type guest.
Host-based display modes have been proposed.

【0004】反射型LCDにおいて外光を効率良く利用
して明るい表示を得るためには、更にあらゆる角度から
の入射光に対して、表示画面に垂直な方向に散乱する光
の強度を増加させる必要がある。そのために、反射板上
の反射膜を適切な反射特性が得られるように制御するこ
とが必要である。基板に感光性樹脂を塗布しフォトマス
クを用いてパターン化して凹凸を形成し、金属薄膜を形
成して拡散反射板を形成する方法(特開平4−2432
26号公報)が提案されている。一方、特開2000−
267088号公報には、製造効率が高く反射型LCD
用拡散反射板等の光拡散特性を良好にする光拡散面を持
つ光拡散部材、その製造に使用される転写フィルムが提
案されている。この方法は金属メッキ膜表面の凹凸形状
を転写した面あるいは金属メッキ膜表面の凹凸形状を転
写した面をさらに転写して光拡散部材として使用する。
In order to efficiently use external light in a reflective LCD to obtain a bright display, it is necessary to further increase the intensity of light scattered in a direction perpendicular to the display screen with respect to incident light from all angles. There is. Therefore, it is necessary to control the reflection film on the reflection plate so as to obtain appropriate reflection characteristics. A method in which a substrate is coated with a photosensitive resin, patterned using a photomask to form irregularities, and a metal thin film is formed to form a diffuse reflector (Japanese Patent Laid-Open No. 4-2432).
No. 26) is proposed. On the other hand, JP 2000-
Japanese Patent No. 267088 discloses a reflective LCD with high manufacturing efficiency.
There has been proposed a light diffusing member having a light diffusing surface such as a light diffusing reflector for improving light diffusing characteristics, and a transfer film used for manufacturing the light diffusing member. In this method, the surface to which the uneven shape of the metal plating film surface is transferred or the surface to which the uneven shape of the metal plating film surface is transferred is further transferred and used as a light diffusing member.

【0005】[0005]

【発明が解決しようとする課題】前記の方法では、金属
メッキ膜表面に異物や傷による異常突起が存在すると、
その転写面である光拡散部材や転写フィルムに凹みまた
は突起が生じる。例えば、突起を有する光拡散部材を反
射型LCD用拡散反射板に使用すると、突起部において拡
散反射板上に積層された平坦化膜やカラーフィルタの平
坦性に悪影響を及ぼし、さらに、液晶のセルギャップが
変わるため液晶の配向乱れを生じ表示むらとなり良好な
ディスプレイを得られないという問題がある。カラーフ
ィルタの欠陥を修正する方法については(特開平05−
07111号公報)が提案されている。しかし、多種の
薄膜が積層された段階での欠陥修正は薄膜間の剥がれや
修正時に発生した異物によってさらに表示ムラを起こす
可能性がある。反射型LCDにおいては、光拡散部材を
作製する工程の中で突起欠陥を修正することが必要であ
る。本発明は、突起欠陥を効率良く修正し、良好な反射
特性を有する反射型LCD用拡散反射板等に使用される
光拡散部材、転写フィルムを提供する。
In the above method, if there is an abnormal protrusion due to a foreign substance or a scratch on the surface of the metal plating film,
A dent or a protrusion is formed on the light diffusion member or the transfer film which is the transfer surface. For example, when a light diffusing member having a protrusion is used for a diffuse reflection plate for a reflective LCD, it adversely affects the flatness of a flattening film or a color filter laminated on the diffusion reflection plate at the protrusion, and further the liquid crystal cell. Since the gap is changed, the liquid crystal is disordered in alignment, resulting in display unevenness, which makes it impossible to obtain a good display. For the method of correcting the defect of the color filter, see JP-A 05-
No. 07111) has been proposed. However, the defect correction at the stage where various thin films are stacked may cause further display unevenness due to peeling between the thin films and foreign substances generated during the correction. In the reflective LCD, it is necessary to correct the protrusion defect in the process of manufacturing the light diffusion member. The present invention provides a light diffusing member and a transfer film which are used for a reflective diffusing plate for a reflective LCD, etc., which has a good reflecting property by efficiently correcting protrusion defects.

【0006】[0006]

【課題を解決するための手段】本発明は、[1]光拡散
部材の凹凸面または光拡散部材の凹凸面を形成するベー
スフィルムの突起欠陥にレーザーを少なくとも1回照射
して突起欠陥を修正することを特徴とする光拡散部材ま
たはベースフィルムの突起欠陥修正方法を提供する。ま
た、[2] 上記[1]に記載の方法で突起欠陥を修正
した凹凸形状の光拡散面を備える光拡散部材を提供す
る。また、[3] 上記[1]に記載の方法で突起欠陥
を修正したベースフィルムの凹凸形状を転写した面の光
拡散面を備える光拡散部材を提供する。また、[4]
光拡散面に反射膜を形成した上記[2]又は上記[3]
に記載の光拡散部材を提供する。また、[5] 上記
[2]ないし上記[4]のいずれかに記載の光拡散部材
を仮支持体とし、この仮支持体の凹凸面側に薄膜層を積
層し、前記薄膜層の前記仮支持体に積層されていない面
が被転写基板への接着面を構成する転写フィルムを提供
する。また、[6] 上記[2]ないし上記[4]のい
ずれかに記載の光拡散部材を反射型液晶表示装置用拡散
反射板として用いる光拡散部材を提供する。本発明は、
光拡散部材またはベースフィルムの突起欠陥を修正する
ことにより、良好な光拡散部材を提供するものである。
具体的には、光拡散部材の凹凸面またはベースフィルム
の突起欠陥をレーザー照射によって修正する。突起欠陥
を顕微鏡で確認し、欠陥の高さが正常な凹凸形状と同等
になるまでYAGレーザー等を用いて1つの突起欠陥に
つき少なくとも1回〜数回照射し、欠陥の高さが正常な
凹凸形状と同等になるレベルに修正する。
According to the present invention, [1] a projection defect of a light diffusing member or a projection defect of a base film forming the projection and depression surface of a light diffusing member is irradiated with laser at least once to correct the projection defect. There is provided a method for repairing a projection defect of a light diffusing member or a base film. [2] There is also provided a light diffusing member having an uneven light diffusing surface in which protrusion defects are corrected by the method described in [1] above. [3] There is also provided a light diffusing member having a light diffusing surface that is the surface of the base film on which the projection defects have been corrected by the method according to the above [1], to which the concavo-convex shape is transferred. Also, [4]
The above [2] or [3] in which a reflecting film is formed on the light diffusion surface.
The light diffusing member according to 1. is provided. [5] The light diffusion member according to any one of [2] to [4] above is used as a temporary support, and a thin film layer is laminated on the uneven surface side of the temporary support. Provided is a transfer film in which a surface not laminated on a support constitutes an adhesive surface to a transfer target substrate. [6] A light diffusing member using the light diffusing member according to any one of the above [2] to [4] as a diffuse reflection plate for a reflective liquid crystal display device. The present invention is
An excellent light diffusing member is provided by correcting a protrusion defect of the light diffusing member or the base film.
Specifically, the uneven surface of the light diffusion member or the projection defect of the base film is corrected by laser irradiation. Check the protrusion defects with a microscope and irradiate each protrusion defect at least once to several times with a YAG laser etc. until the height of the defect becomes the same as the normal irregular shape. Modify to a level that is equivalent to the shape.

【0007】[0007]

【発明の実施の形態】本発明の突起欠陥の修正方法によ
り、凹凸形状を備えた金属ロールを用いて光拡散部材の
凹凸面または光拡散部材の凹凸面を形成するベースフィ
ルムの凹凸形状の欠陥を修正し反射型LCD用拡散反射
板等の光拡散部材に良好な反射特性を有するようにす
る。光拡散部材の凹凸の面形状は特に限定されないが、
複合平面だけでなく凹曲面あるいは凸曲面、凹凸複合の
曲面、さらには球面や放物面に近似した凹曲面あるいは
凸曲面、凹凸複合の曲面であることが好ましい。特に反
射型LCD用拡散反射板の場合、LCDセル内に光拡散
面を形成する必要から、平均高低差Hは、セルギャップ
やΔndを考慮し、小さいほど好ましい。凹凸形状とし
ては、凹部と凸部の高さの差が0.1μm〜15μm、
さらには、0.1μm〜5μm、凸部のピッチが0.7
μm以上150μmあるいは画素ピッチのいずれか小さ
い方以下、さらには2μm以上、150μmあるいは画
素ピッチのいずれか小さい方以下であることが好まし
い。
BEST MODE FOR CARRYING OUT THE INVENTION According to the method for repairing protrusion defects of the present invention, the uneven surface of the light diffusing member or the uneven surface of the light diffusing member is formed by using the metal roll having the uneven shape. Is corrected so that a light diffusing member such as a diffusive reflection plate for a reflective LCD has good reflection characteristics. The surface shape of the unevenness of the light diffusion member is not particularly limited,
Not only the composite plane, but also a concave or convex surface, a concavo-convex composite curved surface, and a concave or convex surface similar to a spherical surface or a paraboloid, or a concavo-convex composite curved surface is preferable. In particular, in the case of a diffuse reflection plate for a reflective LCD, it is necessary to form a light diffusing surface in the LCD cell. Therefore, the average height difference H is preferably as small as possible in consideration of the cell gap and Δnd. As the uneven shape, the difference in height between the concave portion and the convex portion is 0.1 μm to 15 μm,
Furthermore, 0.1 μm to 5 μm, the pitch of the convex portions is 0.7.
It is preferable that the thickness is not less than μm and not more than 150 μm or the pixel pitch, whichever is smaller, and further preferably not less than 2 μm and not more than 150 μm or the pixel pitch, whichever is smaller.

【0008】本発明の光拡散部材の突起欠陥修正方法
は、図1に示すように、突起欠陥にレーザーを少なくと
も1回照射し突起欠陥を修正する。この場合、凹凸面の
凸部はレーザーにより修正できるが、凹部は困難となり
肉盛りしてから更にレーザーにより修正することができ
る。効率の良い方法として凹凸面の凸部を修正し、更
に、その凹凸面を転写したベースフィルムを作製する
と、凹凸面の形状が反対に転写されるため、原型の凹凸
面の修正が困難な凹面がベースフィルムでは、凸面とな
り、レーザーにより修正しやすくなると共に、修正した
ベースフィルムを用いこれを型として、更に転写すると
凹凸面の欠陥の少ない原型と同じ凹凸面を有する光拡散
部材を得ることができる。本発明の光拡散部材の突起欠
陥修正方法により作製した光拡散部材は、図2に示すよ
うにベースフィルムの表面に下塗り層を設け、この下塗
り層に突起欠陥を修正した凹凸面を押し付けて転写し、
更に、下塗り層の修正した凹凸面が転写された側に薄膜
層を形成して表面の保護のためカバーフィルムを設けて
転写フィルムを得ることができる。この場合、ベースフ
ィルムに下塗り層を設けて凹凸面を転写した拡散部材を
仮支持体としており、この仮支持体の凹凸面側に薄膜層
を積層した構成となっている。そして、図3に示すよう
に、カバーフィルムを剥がし、転写フィルムの薄膜層の
仮支持体(ベースフィルム、下塗り層)に積層されてい
ない面を被転写基板となるガラス基板にラミネートして
積層し紫外線を照射して薄膜層の硬化を行いベースフィ
ルムと下塗り層を剥離することにより、ガラス基板に凹
凸形状が転写された薄膜層が形成された光拡散部材を得
ることができる。さらに、図4に示すように得られた光
拡散部材の凹凸形成面に反射膜を設けることにより、反
射特性を向上させることができる。反射膜としては、反
射したい波長領域によって材料を適切に選択すれば良
く、例えば反射型LCD表示装置では、可視光波長領域
である300nmから800nmにおいて反射率の高い
金属、例えばアルミニウムや金、銀等、を真空蒸着法ま
たはスパッタリング法等によって形成する。また反射増
加膜(光学概論2(辻内順平、朝倉書店、1976年発
行)に記載)を上記の方法で積層してもよい。反射膜の
厚みは、0.01μm〜50μmが好ましい。また反射
膜は、必要な部分だけフォトリソグラフィー法、マスク
蒸着法等によりパターン形成してもよい。
As shown in FIG. 1, the method for repairing the projection defect of the light diffusing member of the present invention repairs the projection defect by irradiating the projection defect with laser at least once. In this case, the convex portion of the uneven surface can be corrected by laser, but the concave portion becomes difficult and can be further corrected by laser after overlaying. As a highly efficient method, the convex part of the uneven surface is corrected, and when the base film to which the uneven surface is transferred is made, the shape of the uneven surface is transferred in the opposite way, so it is difficult to correct the uneven surface of the prototype concave surface. However, the base film has a convex surface, which makes it easy to correct by a laser, and by using this modified base film as a mold, it is possible to obtain a light diffusing member having the same uneven surface as the original mold with less defects on the uneven surface. it can. The light diffusing member produced by the method for correcting a projection defect of a light diffusing member of the present invention is provided with an undercoat layer on the surface of a base film as shown in FIG. Then
Further, a transfer film can be obtained by forming a thin film layer on the side of the undercoat layer to which the modified uneven surface is transferred and providing a cover film for protecting the surface. In this case, a diffusion member obtained by providing an undercoat layer on the base film and transferring the uneven surface is used as a temporary support, and a thin film layer is laminated on the uneven surface side of the temporary support. Then, as shown in FIG. 3, the cover film is peeled off, and the surface of the thin film layer of the transfer film which is not laminated on the temporary support (base film, undercoat layer) is laminated on the glass substrate to be the substrate to be transferred. By irradiating ultraviolet rays to cure the thin film layer and peeling off the base film and the undercoat layer, it is possible to obtain a light diffusing member on which a thin film layer having a concavo-convex shape transferred to a glass substrate is formed. Furthermore, by providing a reflection film on the unevenness forming surface of the light diffusion member obtained as shown in FIG. 4, the reflection characteristics can be improved. For the reflective film, a material may be appropriately selected depending on the wavelength region to be reflected. For example, in a reflective LCD display device, a metal having a high reflectance in the visible light wavelength region of 300 nm to 800 nm, such as aluminum, gold or silver. Are formed by a vacuum deposition method, a sputtering method, or the like. Further, a reflection-increasing film (described in Optical Outline 2 (Junpei Tsujiuchi, Asakura Shoten, 1976)) may be laminated by the above method. The thickness of the reflective film is preferably 0.01 μm to 50 μm. Further, the reflection film may be formed by patterning only a necessary portion by a photolithography method, a mask vapor deposition method or the like.

【0009】本発明の光拡散部材としては有機組成物を
用い、好ましくは支持体上に塗布し活性光線あるいは熱
により硬化し、0.1μm〜15.0μmの薄膜化が可
能な、ネガ型感光性樹脂組成物あるいはポジ型感光性樹
脂組成物、あるいは熱硬化性樹脂組成物を活性光線ある
いは熱、あるいは活性光線と熱により硬化した有機組成
物を用いると好ましい。例えばポリエチレン、ポリプロ
ピレンなどのポリオレフィン、エチレンと酢酸ビニル共
重合体、エチレンとアクリル酸エステル共重合体、エチ
レンとビニルアルコールのようなエチレン共重合体、ポ
リ塩化ビニル、塩化ビニルと酢酸ビニルの共重合体、塩
化ビニルとビニルアルコールの共重合体、ポリ塩化ビニ
リデン、ポリスチレン、スチレンと(メタ)アクリル酸
エステルのようなスチレン共重合体、ポリビニルトルエ
ン、ビニルトルエンと(メタ)アクリル酸エステルのよ
うなビニルトルエン共重合体、ポリ(メタ)アクリル酸
エステル、(メタ)アクリル酸ブチルと酢酸ビニルのよ
うな(メタ)アクリル酸エステルの共重合体、合成ゴ
ム、セルローズ誘導体等から選ばれた、少なくとも1種
類以上の有機高分子を用いることができる。凹凸形成後
硬化させるために必要に応じて光開始剤やエチレン性二
重結合を有するモノマ等を添加することができる。また
この中に必要に応じて、染料、有機顔料、無機顔料、粉
体及びその複合物を単独または混合して用いてもよい。
これら光拡散部材の膜厚、誘電率、硬度、屈折率、分光
透過率は特に限定されない。これら光拡散部材は、支持
体としての機能を保持していてもよい。またこれら光拡
散部材は、有機組成物の積層としてもよい。
As the light diffusing member of the present invention, an organic composition is used, which is preferably coated on a support and cured by actinic rays or heat to form a thin film having a thickness of 0.1 μm to 15.0 μm. It is preferable to use an organic composition obtained by curing a photosensitive resin composition or a positive photosensitive resin composition, or a thermosetting resin composition with actinic rays or heat, or with actinic rays and heat. For example, polyolefins such as polyethylene and polypropylene, ethylene and vinyl acetate copolymers, ethylene and acrylate copolymers, ethylene copolymers such as ethylene and vinyl alcohol, polyvinyl chloride, vinyl chloride and vinyl acetate copolymers. , Copolymers of vinyl chloride and vinyl alcohol, polyvinylidene chloride, polystyrene, styrene copolymers such as styrene and (meth) acrylic acid ester, polyvinyltoluene, vinyltoluene such as vinyltoluene and (meth) acrylic acid ester At least one or more selected from copolymers, poly (meth) acrylic acid esters, copolymers of (meth) acrylic acid esters such as butyl (meth) acrylate and vinyl acetate, synthetic rubbers, and cellulose derivatives. These organic polymers can be used. If necessary, a photoinitiator, a monomer having an ethylenic double bond, or the like can be added for curing after forming the unevenness. If necessary, dyes, organic pigments, inorganic pigments, powders and composites thereof may be used alone or in combination.
The film thickness, dielectric constant, hardness, refractive index, and spectral transmittance of these light diffusion members are not particularly limited. These light diffusion members may retain the function as a support. Further, these light diffusing members may be laminated layers of organic compositions.

【0010】ベースフィルムとしては、化学的、熱的に
安定であり、凹凸形状が施されていて、シートまたは板
状に成形できるものを用いることができる。具体的に
は、ポリエチレン、ポリプロピレン等のポリオレフィ
ン、ポリ塩化ビニル、ポリ塩化ビニリデン等のポリハロ
ゲン化ビニル類、セルロースアセテート、ニトロセルロ
ース、セロハン等のセルロース誘導体、ポリアミド、ポ
リスチレン、ポリカーボネート、ポリイミド、ポリエス
テル、あるいはアルミニウム、銅等の金属薄膜、金属箔
等である。これらのなかで特に好ましいのは寸法安定性
に優れた2軸延伸ポリエチレンテレフタレートである。
As the base film, one that is chemically and thermally stable, has an uneven shape, and can be formed into a sheet or plate can be used. Specifically, polyolefins such as polyethylene and polypropylene, polyvinyl chloride, polyvinyl halides such as polyvinylidene chloride, cellulose acetate, nitrocellulose, cellulose derivatives such as cellophane, polyamide, polystyrene, polycarbonate, polyimide, polyester, or It is a metal thin film such as aluminum or copper, a metal foil, or the like. Of these, particularly preferred is biaxially stretched polyethylene terephthalate, which has excellent dimensional stability.

【0011】さらに凹凸形状が施されていないベースフ
ィルムに下塗り層を形成し、下塗り層に凹凸形状を形成
してベースフィルムとしても良い。下塗り層としては、
ポリエチレン、ポリプロピレンなどのポリオレフィン、
エチレンと酢酸ビニル共重合体、エチレンとアクリル酸
エステル共重合体、エチレンとビニルアルコールのよう
なエチレン共重合体、ポリ塩化ビニル、塩化ビニルと酢
酸ビニルの共重合体、塩化ビニルとビニルアルコールの
共重合体、ポリ塩化ビニリデン、ポリスチレン、スチレ
ンと(メタ)アクリル酸エステルのようなスチレン共重
合体、ポリビニルトルエン、ビニルトルエンと(メタ)
アクリル酸エステルのようなビニルトルエン共重合体、
ポリ(メタ)アクリル酸エステル、(メタ)アクリル酸
ブチルと酢酸ビニルのような(メタ)アクリル酸エステ
ルの共重合体、合成ゴム、セルローズ誘導体から選ばれ
た少なくとも1種類以上の有機高分子を用いることがで
きる。凹凸形状付与後硬化させるために必要に応じて光
開始剤やエチレン性二重結合を有するモノマ等を添加す
ることができる。またネガ型またはポジ型感光性樹脂を
使用しても良い。
Further, a base film may be formed by forming an undercoat layer on a base film which is not provided with an uneven shape and forming an uneven shape on the undercoat layer. As the undercoat layer,
Polyolefins such as polyethylene and polypropylene,
Ethylene and vinyl acetate copolymer, ethylene and acrylic ester copolymer, ethylene copolymer such as ethylene and vinyl alcohol, polyvinyl chloride, vinyl chloride and vinyl acetate copolymer, vinyl chloride and vinyl alcohol copolymer Polymers, polyvinylidene chloride, polystyrene, styrene and styrene copolymers such as (meth) acrylic acid esters, polyvinyltoluene, vinyltoluene and (meth)
Vinyltoluene copolymers such as acrylates,
At least one organic polymer selected from poly (meth) acrylic acid ester, a copolymer of butyl (meth) acrylate and (meth) acrylic acid ester such as vinyl acetate, synthetic rubber, and cellulose derivative is used. be able to. A photoinitiator, a monomer having an ethylenic double bond, or the like can be added, if necessary, for curing after giving the uneven shape. Alternatively, a negative or positive photosensitive resin may be used.

【0012】本発明の光拡散部材またはベースフィルム
の突起欠陥の修正方法は、レーザー照射で除去する手法
を用いる。レーザー光としては、YAGレーザー、ガラ
スレーザー、He-Neレーザー、He-Xeレーザー、He-C
dレーザー、イオンレーザー、Nレーザー、CO
ーザー、可変波長レーザー、ArClやArFやKrC
lなど希ガスハライドのヘテロエキシマレーザー、F
やArなどの希ガスエキシマレーザー等が挙げられ
る。
The method of correcting the projection defect of the light diffusing member or the base film of the present invention uses a method of removing by laser irradiation. The laser light is YAG laser, glass laser, He-Ne laser, He-Xe laser, He-C.
d laser, ion laser, N 2 laser, CO 2 laser, variable wavelength laser, ArCl, ArF, KrC
Heteroexcimer laser of rare gas halide such as L, F 2
And rare gas excimer lasers such as Ar 2 and the like.

【0013】また、凹凸形状を転写した面を有するベー
スフィルムの凹凸面に光拡散部材となる有機組成物の薄
膜層が積層されており、前記薄膜層の前記ベースフィル
ムに積層されていない面が被転写基板への接着面を構成
する転写フィルムを用いて光拡散部材を作製しても良
い。図3に示すように表面に多数の微細な凹凸を有する
金属メッキ膜を押し当てることによって表面に多数の微
細な凹凸を有する状態に加工処理されたベースフィル
ム、下塗り層、薄膜層、カバーフィルムが順次積層され
た転写フィルムを用いて、カバーフィルムを剥がしなが
ら基板に薄膜層が接するようにラミネートして基板上に
薄膜層、下塗り層とベースフィルムを積層し、前記ベー
スフィルムと下塗り層を剥離することで基板上の薄膜層
表面に多数の微細な凹凸を有する光拡散部材を形成する
ことができる。これに更にアルミニウム等の金属薄膜の
反射膜を形成すれば所望の光拡散部材である拡散反射板
が得られる(図4)。また、反射膜の代わりに光拡散面
を形成する媒質間に屈折率差を備えさせられれば、所望
の光拡散板が得られる。また、あらかじめ薄膜層とベー
スフィルムの間に反射膜を積層した転写フィルムを用い
て、カバーフィルムを剥がしながら基板に薄膜層が接す
るようにラミネートし、基板上に薄膜層、反射膜、ベー
スフィルムを積層し、前記ベースフィルムのみを剥離す
ると所望の拡散反射板が得られる。
Further, a thin film layer of an organic composition to be a light diffusing member is laminated on the uneven surface of the base film having a surface on which the uneven shape is transferred, and the surface of the thin film layer not laminated on the base film is The light diffusing member may be manufactured by using a transfer film that constitutes an adhesive surface to the substrate to be transferred. As shown in FIG. 3, a base film, an undercoat layer, a thin film layer, and a cover film processed to have a large number of fine irregularities on the surface by pressing a metal plating film having a large number of fine irregularities on the surface are Using the transfer films sequentially laminated, the cover film is laminated while the thin film layer is in contact with the substrate, the thin film layer, the undercoat layer and the base film are laminated on the substrate, and the base film and the undercoat layer are peeled off. As a result, a light diffusing member having a large number of fine irregularities can be formed on the surface of the thin film layer on the substrate. By further forming a reflection film of a metal thin film of aluminum or the like on this, a diffusion reflection plate which is a desired light diffusion member can be obtained (FIG. 4). Further, if a difference in refractive index is provided between the media forming the light diffusing surface instead of the reflecting film, a desired light diffusing plate can be obtained. In addition, using a transfer film in which a reflective film is laminated between the thin film layer and the base film in advance, the cover film is peeled off and laminated so that the thin film layer contacts the substrate, and the thin film layer, the reflective film, and the base film are placed on the substrate. A desired diffuse reflection plate is obtained by laminating and peeling only the base film.

【0014】薄膜層としては変形可能な有機重合体を含
む組成物または無機化合物、金属を用いることができる
が、好ましくは支持体上に塗布しフィルム状に巻き取る
ことが可能な有機重合体組成物を用いる。またこの中に
必要に応じて、染料、有機顔料、無機顔料、粉体及びそ
の複合物を単独または混合して用いてもよい。
As the thin film layer, a composition containing a deformable organic polymer, an inorganic compound or a metal can be used, but an organic polymer composition which can be coated on a support and wound into a film is preferable. Use things. If necessary, dyes, organic pigments, inorganic pigments, powders and composites thereof may be used alone or in combination.

【0015】薄膜層には感光性樹脂組成物、熱硬化性樹
脂組成物を用いることもできる。これら薄膜層の誘電
率、硬度、屈折率、分光透過率は特に限定されない。
A photosensitive resin composition or a thermosetting resin composition may be used for the thin film layer. The dielectric constant, hardness, refractive index, and spectral transmittance of these thin film layers are not particularly limited.

【0016】そのようなものの中で、被転写基板に対す
る密着性が良好で、ベースフィルムからの剥離性がよい
ものを用いるのが好ましい。たとえばアクリル樹脂、ポ
リエチレン、ポリプロピレン等のポリオレフィン、ポリ
塩化ビニル、ポリ塩化ビニリデン等のポリハロゲン化ビ
ニル類、セルロースアセテート、ニトロセルロース、セ
ロハン等のセルロース誘導体、ポリアミド、ポリスチレ
ン、ポリカーボネート、ポリイミド、ポリエステル等を
用いることができる。また感光性を有するものを用いる
ことができる。場合によっては基板の凹凸が必要な部分
だけを残し、不要な部分を除けるように、アルカリ等で
現像可能な感光性樹脂を用いることもできる。耐熱性、
耐溶剤性、形状安定性を向上させるために、凹凸形成後
に熱または光によって硬化可能な樹脂組成物を用いるこ
ともできる。さらに、カップリング剤、接着性付与剤を
添加することで基板との密着を向上させることもでき
る。接着を向上させる目的で基板または薄膜層の接着面
に接着性付与剤を塗布することも含まれる。以下、実施
例により本発明を具体的に説明する。
Among such materials, it is preferable to use one having good adhesion to the substrate to be transferred and good peelability from the base film. For example, acrylic resin, polyolefin such as polyethylene and polypropylene, polyvinyl halide such as polyvinyl chloride and polyvinylidene chloride, cellulose derivative such as cellulose acetate, nitrocellulose, cellophane, polyamide, polystyrene, polycarbonate, polyimide, polyester and the like are used. be able to. Further, a photosensitive material can be used. In some cases, it is possible to use a photosensitive resin that can be developed with an alkali or the like so that only the portions of the substrate where the irregularities are necessary are left and the unnecessary portions are removed. Heat-resistant,
In order to improve solvent resistance and shape stability, it is also possible to use a resin composition that can be cured by heat or light after forming the unevenness. Further, the adhesion with the substrate can be improved by adding a coupling agent and an adhesiveness-imparting agent. It also includes applying an adhesion promoter to the adhesive surface of the substrate or thin film layer for the purpose of improving adhesion. Hereinafter, the present invention will be specifically described with reference to examples.

【0017】[0017]

【実施例】(実施例1)直径130mmの円筒形の鉄製基
材を回転させながら、銅メッキを行って、鉄に銅が20
0μm積層された原型基材を得た。これを研磨して表面
が鏡面となるように加工した。次にこれを回転させなが
らダイヤモンドバイトで連続的に押圧し、四角錐の先端
が平坦な形状を押し付けた形状が隣接して並んだロール
型を得た。次にこれを回転させながら以下に示す銅メッ
キ液に浸漬し、電流密度(メッキ面積10平方センチメ
ートルあたりの電流値)が8Aとなるように電流を調節
し、光沢メッキを行った後、同じメッキ液中で電流密度
を2Aとなるように電流を調整し、粗化メッキを行った
後、メッキ液を除去する目的で純水で洗浄した。次に銅
の酸化を抑えるために、以下に示すニッケルメッキ液に
浸漬しながら、電流密度2Aとなるように電流を調整し
て光沢ニッケルメッキを行って、転写原型を得た。 (銅メッキ液): 硫酸銅 210g/リットル 硫酸 60g/リットル チオ尿素 0.01g/リットル デキストリン 0.01g/リットル 塩酸 0.01g/リットル 液温 30℃ (ニッケルメッキ液): 硫酸ニッケル 240g/リットル 塩化ニッケル 45g/リットル 硼酸 30g/リットル 浴温 50℃
(Example) (Example 1) While a cylindrical iron base material having a diameter of 130 mm was rotated, copper plating was performed to obtain 20 iron on the iron.
A prototype substrate laminated with 0 μm was obtained. This was polished and processed so that the surface became a mirror surface. Next, this was rotated and continuously pressed with a diamond bite to obtain a roll type in which the shapes in which the tips of the quadrangular pyramids were pressed were arranged side by side. Next, while rotating this, dip it in the copper plating solution shown below, adjust the current so that the current density (current value per 10 square centimeters of plating area) is 8 A, perform bright plating, and then use the same plating solution. The current was adjusted so that the current density was 2 A, and roughening plating was performed, followed by washing with pure water for the purpose of removing the plating solution. Next, in order to suppress the oxidation of copper, while immersing in the nickel plating solution shown below, the current was adjusted so that the current density was 2 A, and bright nickel plating was performed to obtain a transfer master. (Copper plating solution): Copper sulfate 210 g / liter Sulfuric acid 60 g / liter Thiourea 0.01 g / liter Dextrin 0.01 g / liter Hydrochloric acid 0.01 g / liter Liquid temperature 30 ° C. (Nickel plating solution): Nickel sulfate 240 g / liter chloride Nickel 45 g / liter Boric acid 30 g / liter Bath temperature 50 ° C

【0018】ベースフィルムに厚さ100μmのポリエ
チレンテレフタレートフィルムを用い、このベースフィ
ルム上に下塗り層として下記の光硬化性樹脂溶液をコン
マコーターで20μmの膜厚になるよう塗布乾燥しベー
スフィルム上に光硬化性樹脂からなる下塗り層を形成し
た。次に前記転写原型を押しあて、紫外線を照射し光硬
化性樹脂を硬化し転写原型から分離し、転写原型の穴の
反転形状が光硬化性樹脂層の表面に転写されたベースフ
ィルムを得た。 (光硬化性樹脂溶液): アクリル酸-ブチルアクリレート-ビニルアセテート共重合体 5重量部 ブチルアセテート(モノマー) 8重量部 ビニルアセテート(モノマー) 2重量部 アクリル酸(モノマー) 0.3重量部 ヘキサンジオールアクリレート(モノマー) 0.2重量部 ベンゾインイソブチルエーテル(開始剤) 2.5重量%
A polyethylene terephthalate film having a thickness of 100 μm is used as a base film, and the following photo-curable resin solution is applied as an undercoat layer on the base film by a comma coater so as to have a thickness of 20 μm and dried, and then light is applied onto the base film. An undercoat layer made of a curable resin was formed. Next, the transfer mold was pressed, and the photocurable resin was cured by irradiating with ultraviolet rays and separated from the transfer mold, and the inverted shape of the holes of the transfer mold was transferred to the surface of the photocurable resin layer to obtain a base film. . (Photocurable resin solution): Acrylic acid-butyl acrylate-vinyl acetate copolymer 5 parts by weight Butyl acetate (monomer) 8 parts by weight Vinyl acetate (monomer) 2 parts by weight Acrylic acid (monomer) 0.3 parts by weight Hexanediol Acrylate (monomer) 0.2 parts by weight Benzoin isobutyl ether (initiator) 2.5% by weight

【0019】ベースフィルムには、転写原型の傷または
転写原型に異物がついたままメッキが開始されメッキ途
中にその異物により発生した突起欠陥が発生した。突起
欠陥は直径1μm〜500μm、高さ1μm〜100μmで
あった。これらの突起欠陥は顕微鏡で位置を確認し、欠
陥の高さが正常な凹凸形状と同等になるまでYAGレー
ザーを出力100〜800Vで1つの突起欠陥につき数
回照射し、欠陥の高さが正常な凹凸形状と同等になるレ
ベルに修正した。このように修正された突起欠陥は適度
な凹凸形状を持ち、正常な凹凸形状部分と比べて十分微
小な大きさであるため反射特性に影響を与えない。
On the base film, plating was started with scratches on the transfer master or foreign matter on the transfer master, and projection defects caused by the foreign matter were generated during plating. The protrusion defects had a diameter of 1 μm to 500 μm and a height of 1 μm to 100 μm. After confirming the position of these protrusion defects with a microscope, a YAG laser is irradiated several times for each protrusion defect at an output of 100 to 800 V until the height of the defects becomes equivalent to a normal uneven shape, and the defect height is normal. Corrected to a level that is equivalent to the rough shape. The projection defect thus corrected has an appropriate uneven shape and is sufficiently smaller than a normal uneven shape portion, so that it does not affect the reflection characteristics.

【0020】(実施例2)ガラス基板上に下記組成の薄
膜層形成用溶液を、スピンコートし2μmの膜厚の薄膜
層を得た。次に前記実施例1の補修後のベースフィルム
を薄膜層に凹凸面が接するようにラミネータ(ロールラ
ミネータHLM1500、日立化成テクノプラント株式
会社製商品名)を用いて基板温度90℃、ロール温度8
0℃、ロール圧力0.686MPa(7kg/c
2)、速度0.5m/分でラミネートし、ガラス基板
上に薄膜層、下地樹脂層、ベースフィルムが積層された
基板を得た。次に、高圧水銀ランプによってH線で10
0mJの露光後、ベースフィルムと下塗り層を剥離し、
ガラス基板上に不規則な凹凸形状表面の薄膜層を得た。
これを、オーブンで230℃、30分間の熱硬化をし
た。凹凸形状が形成された薄膜層には、転写原型に異物
がついたままメッキされたことよる転写原型の突起欠
陥、転写原型のメッキ粒子の異常成長、ベースフィルム
の傷、ガラス基板上に薄膜層を形成する工程で発生した
異物等による直径約1μm〜500μm、高さ約1μm〜
100μmの突起欠陥があった。それらの突起欠陥は顕
微鏡で位置を確認し、YAGレーザーを出力100〜8
00Vで1つの突起欠陥につき数回照射し、欠陥の高さ
が正常な凹凸形状と同等になるレベルに修正した。この
ように修正された突起欠陥は適度な凹凸形状を持ち、正
常な凹凸形状部分と比べて十分微小な大きさであるため
反射特性に影響を与えない。上記薄膜層に真空蒸着法
で、アルミニウム薄膜を0.2μmの膜厚になるよう積
層し反射層を形成した。得られた光拡散反射板を用いて
LCDパネルを作製した場合、表示にムラのない良好な
ディスプレイが得られた。 (薄膜層形成用溶液):ポリマーとしてスチレン、メチ
ルメタクリレート、エチルアクリレート、アクリル酸、
グリシジルメタクリレート共重合樹脂を用いた(ポリマ
ーA)。分子量は約35000、酸価は110である。 ポリマーA 70重量部 ペンタエリスリトールテトラアクリレート(モノマー) 30重量部 イルガキュアー369(チバスペシャルティーケミカルズ)(開始剤)2.2重量部 N,N-テトラエチル-4,4'-ジアミノベンゾフェノン(開始剤) 2.2重量部 プロピレングリコールモノメチルエーテル(溶剤) 492重量部 p−メトキシフェノール(重合禁止剤) 0.1重量部 パーフルオロアルキルアルコキシレート(界面活性剤) 0.01重量部
Example 2 A thin film layer forming solution having the following composition was spin-coated on a glass substrate to obtain a thin film layer having a thickness of 2 μm. Next, using the laminator (roll laminator HLM1500, trade name of Hitachi Chemical Techno Plant Co., Ltd.) so that the uneven surface of the base film after repair of Example 1 is in contact with the thin film layer, the substrate temperature is 90 ° C. and the roll temperature is 8
0 ° C, roll pressure 0.686 MPa (7 kg / c
m 2 ), and the speed was 0.5 m / min, to obtain a substrate in which a thin film layer, a base resin layer, and a base film were laminated on a glass substrate. Next, using a high pressure mercury lamp, 10
After the exposure of 0 mJ, the base film and the undercoat layer are peeled off,
A thin film layer having an irregularly-shaped surface was obtained on a glass substrate.
This was heat-cured in an oven at 230 ° C. for 30 minutes. In the thin film layer on which the uneven shape is formed, projection defects of the transfer master due to plating with foreign matter on the transfer master, abnormal growth of plating particles on the transfer master, scratches on the base film, thin film layer on the glass substrate Diameter of about 1μm-500μm, height of about 1μm-
There was a protrusion defect of 100 μm. The position of these protrusion defects is confirmed with a microscope, and the YAG laser is output 100 to 8
Irradiation was performed several times for each protrusion defect at 00 V, and the height of the defect was corrected to a level equivalent to that of a normal uneven shape. The projection defect thus corrected has an appropriate uneven shape and is sufficiently smaller than a normal uneven shape portion, so that it does not affect the reflection characteristics. An aluminum thin film was laminated on the above thin film layer by a vacuum deposition method so as to have a thickness of 0.2 μm to form a reflective layer. When an LCD panel was produced using the obtained light diffusing and reflecting plate, a good display without unevenness in display was obtained. (Solution for forming thin film layer): Styrene, methyl methacrylate, ethyl acrylate, acrylic acid as a polymer,
A glycidyl methacrylate copolymer resin was used (Polymer A). It has a molecular weight of about 35,000 and an acid value of 110. Polymer A 70 parts by weight Pentaerythritol tetraacrylate (monomer) 30 parts by weight Irgacure 369 (Ciba Specialty Chemicals) (initiator) 2.2 parts by weight N, N-tetraethyl-4,4'-diaminobenzophenone (initiator) 2.2 parts by weight Propylene glycol monomethyl ether (solvent) 492 parts by weight p-methoxyphenol (polymerization inhibitor) 0.1 parts by weight Perfluoroalkylalkoxylate (surfactant) 0.01 parts by weight

【0021】(実施例3)ガラス基板上に上記の薄膜層
形成用溶液を、スピンコートし2μmの膜厚の薄膜層を
得た。ベースフィルムに厚さ100μmのポリエチレン
テレフタレートフィルムを用い、このベースフィルム上
に上記実施例1に示した下塗り層の光硬化性樹脂溶液を
コンマコーターで20μmの膜厚になるよう塗布乾燥し
た。次に前記実施例1の転写原型の突起欠陥の位置を予
め転写して確認しておき、その部分の位置を顕微鏡で確
認し欠陥の高さが正常な凹凸形状と同等になるようにレ
ーザの出力を調整して数回照射し欠陥の高さが正常な凹
凸形状とほぼ同等になるレベルに修正した。そして、こ
の修正した転写原型をベースフィルム上に形成した下塗
り層に押しあて、紫外線を照射し下塗り層の光硬化性樹
脂を硬化し転写原型から分離し、転写原型の穴の反転形
状が光硬化性樹脂層の表面に転写されたベースフィルム
を得た。この凹凸形状が転写されたベースフィルムの突
起欠陥を顕微鏡で位置を確認し、欠陥の高さが正常な凹
凸形状と同等になるまでYAGレーザーを出力100〜
800Vで1つの突起欠陥につき数回照射し、欠陥の高
さが正常な凹凸形状と同等になるレベルに修正した。そ
して、この突起欠陥が修正されたベースフィルムを薄膜
層に凹凸面が接するようにラミネータ(ロールラミネー
タHLM1500、日立化成テクノプラント株式会社製
商品名)を用いて基板温度90℃、ロール温度80℃、
ロール圧力0.686MPa(7kg/cm2)、速度
0.5m/分でラミネートし、ガラス基板上に下地樹脂
層、ベースフィルムが積層された基板を得た。次に、高
圧水銀ランプによってH線で100mJの露光後、ベー
スフィルムと下塗り層を剥離し、ガラス基板上に不規則
な凹凸形状の表面の薄膜層を得た。次に、オーブンで2
30℃、30分間の熱硬化をした。このように修正され
た突起欠陥は適度な凹凸形状を持ち、正常な凹凸形状部
分と比べて十分微小な大きさであるため特に優れた反射
特性を示した。
(Example 3) The above-mentioned thin film layer forming solution was spin-coated on a glass substrate to obtain a thin film layer having a film thickness of 2 μm. A polyethylene terephthalate film having a thickness of 100 μm was used as a base film, and the photocurable resin solution of the undercoat layer shown in Example 1 was applied and dried on the base film with a comma coater to a film thickness of 20 μm. Next, the positions of the projection defects of the transfer pattern of Example 1 are transferred and confirmed in advance, and the positions of the parts are confirmed with a microscope so that the height of the defects becomes equal to a normal uneven shape. The output was adjusted and irradiated several times, and the height of the defect was corrected to a level approximately equal to the normal uneven shape. Then, the modified transfer mold is pressed against the undercoat layer formed on the base film, and the photocurable resin in the undercoat layer is cured by irradiating ultraviolet rays to separate it from the transfer mold, and the inverted shape of the holes of the transfer mold is photocured. A base film transferred to the surface of the conductive resin layer was obtained. The position of the protrusion defect of the base film to which this uneven shape is transferred is confirmed with a microscope, and the YAG laser is output until the height of the defect becomes equal to the normal uneven shape.
Irradiation was performed several times at one projection defect at 800 V, and the height of the defect was corrected to a level equivalent to a normal uneven shape. Then, using a laminator (roll laminator HLM1500, trade name of Hitachi Chemical Technoplant Co., Ltd.) such that the uneven surface of the base film in which the protrusion defects are corrected is in contact with the thin film layer, the substrate temperature is 90 ° C., the roll temperature is 80 ° C.,
Lamination was performed at a roll pressure of 0.686 MPa (7 kg / cm 2 ) and a speed of 0.5 m / min to obtain a substrate in which a base resin layer and a base film were laminated on a glass substrate. Next, after exposure to 100 mJ with a H line using a high pressure mercury lamp, the base film and the undercoat layer were peeled off to obtain a thin film layer having a surface with irregular irregularities on the glass substrate. Then 2 in the oven
It was heat-cured at 30 ° C. for 30 minutes. The thus-corrected protrusion defect had an appropriate uneven shape, and had a sufficiently small size as compared with a normal uneven shape portion, and thus exhibited particularly excellent reflection characteristics.

【0022】[0022]

【発明の効果】本発明の突起欠陥修正方法によれば、光
拡散部材を作製する工程の中で転写原型の突起欠陥を効
率良く修正することにより、良好な反射特性を有する拡
散反射板等の光拡散部材を効率良く製造することができ
る。
According to the projection defect repairing method of the present invention, by efficiently repairing the projection defects of the transfer master during the process of manufacturing the light diffusing member, it is possible to obtain a diffuse reflection plate having good reflection characteristics. The light diffusing member can be efficiently manufactured.

【0023】[0023]

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明の突起欠陥修正前後の光拡散部材の一
例を示す断面図。
FIG. 1 is a cross-sectional view showing an example of a light diffusing member before and after a protrusion defect is corrected according to the present invention.

【図2】 本発明の転写フィルムの一例を示す断面図。FIG. 2 is a sectional view showing an example of the transfer film of the present invention.

【図3】 本発明の転写フィルムを使用した光拡散部材
の製造例を示す断面図。
FIG. 3 is a cross-sectional view showing a production example of a light diffusing member using the transfer film of the present invention.

【図4】 本発明の拡散反射板の一例を示す断面図。FIG. 4 is a sectional view showing an example of a diffuse reflection plate of the present invention.

【符号の説明】[Explanation of symbols]

1.カバーフィルム 2.薄膜層 3.下塗り層 4.ベースフィルム 5.ガラス基板 6.YAGレーザー光 7.反射膜 1. Cover film 2. Thin film layer 3. Undercoat layer 4. Base film 5. Glass substrate 6. YAG laser light 7. Reflective film

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) G02F 1/1335 520 G02B 1/10 A (72)発明者 鶴岡 恭生 茨城県つくば市和台48 日立化成工業株式 会社総合研究所内 (72)発明者 高根 信明 茨城県つくば市和台48 日立化成工業株式 会社総合研究所内 (72)発明者 伴野 秀邦 茨城県つくば市和台48 日立化成工業株式 会社総合研究所内 (72)発明者 高松 利和 茨城県つくば市和台48 日立化成工業株式 会社総合研究所内 Fターム(参考) 2H042 BA04 BA15 BA20 DA02 DA11 DA21 DC02 DC08 DC12 DE04 2H091 FA08X FA08Z FA11X FA11Z FA14Z FA16Z FA37X FA41Z FB02 FC01 FC02 FD06 HA07 HA08 HA10 LA30 2K009 AA12 BB02 CC23 CC24 CC34 CC38 DD05 DD15 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) G02F 1/1335 520 G02B 1/10 A (72) Inventor Kyoo Tsuruoka 48 Wadai, Tsukuba, Ibaraki Prefecture Hitachi Chemical Co., Ltd. Stock Research Institute (72) Inventor Nobuaki Takane 48 Wadai, Tsukuba City, Ibaraki Prefecture Hitachi Chemical Co., Ltd. (72) Inventor Hidekuni Banno 48 Taidai, Tsukuba City, Ibaraki Hitachi Chemical Co., Ltd. 72) Inventor Toshikazu Takamatsu 48 Wadai, Tsukuba City, Ibaraki Prefecture F-term in the Research Institute of Hitachi Chemical Co., Ltd. (reference) 2H042 BA04 BA15 BA20 DA02 DA11 DA21 DC02 DC08 DC12 DE04 2H091 FA08X FA08Z FA11X FA11Z FA14Z FA16Z FA37X FA41Z FB02 FC01 FC02FD06 HA07 HA08 HA10 LA30 2K009 AA12 BB02 CC23 CC24 CC34 CC38 DD05 DD15

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 光拡散部材の凹凸面または光拡散部材の
凹凸面を形成するベースフィルムの突起欠陥にレーザー
を少なくとも1回照射して突起欠陥を修正することを特
徴とする光拡散部材またはベースフィルムの突起欠陥修
正方法。
1. A light diffusing member or a base, characterized in that a projection defect of a light diffusing member or a projection defect of a base film forming the uneven surface of a light diffusing member is irradiated with laser at least once to correct the projection defect. Method for repairing film projection defects.
【請求項2】 請求項1に記載の方法で突起欠陥を修正
した凹凸形状の光拡散面を備える光拡散部材。
2. A light diffusing member having an uneven light diffusing surface, in which protrusion defects are corrected by the method according to claim 1.
【請求項3】 請求項1に記載の方法で突起欠陥を修正
したベースフィルムの凹凸形状を転写した面の光拡散面
を備える光拡散部材。
3. A light diffusing member having a light diffusing surface, which is a surface on which the uneven shape of the base film having the protrusion defects corrected by the method according to claim 1 is transferred.
【請求項4】 光拡散面に反射膜を形成した請求項2又
は請求項3に記載の光拡散部材。
4. The light diffusing member according to claim 2, wherein a reflecting film is formed on the light diffusing surface.
【請求項5】 請求項2ないし請求項4のいずれかに記
載の光拡散部材を仮支持体とし、この仮支持体の凹凸面
側に薄膜層を積層し、前記薄膜層の前記仮支持体に積層
されていない面が被転写基板への接着面を構成する転写
フィルム。
5. The light diffusing member according to claim 2 is used as a temporary support, and a thin film layer is laminated on the uneven surface side of the temporary support, and the temporary support of the thin film layer. A transfer film whose surface not laminated on the substrate constitutes an adhesive surface to the substrate to be transferred.
【請求項6】 請求項2ないし請求項4のいずれかに記
載の光拡散部材を反射型液晶表示装置用拡散反射板とし
て用いる光拡散部材。
6. A light diffusing member which uses the light diffusing member according to claim 2 as a diffusing reflector for a reflective liquid crystal display device.
JP2001227926A 2001-07-27 2001-07-27 Method for correcting projection defect in light diffusing member and light diffusing member and transfer film by using the same Pending JP2003043219A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001227926A JP2003043219A (en) 2001-07-27 2001-07-27 Method for correcting projection defect in light diffusing member and light diffusing member and transfer film by using the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001227926A JP2003043219A (en) 2001-07-27 2001-07-27 Method for correcting projection defect in light diffusing member and light diffusing member and transfer film by using the same

Publications (1)

Publication Number Publication Date
JP2003043219A true JP2003043219A (en) 2003-02-13

Family

ID=19060514

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001227926A Pending JP2003043219A (en) 2001-07-27 2001-07-27 Method for correcting projection defect in light diffusing member and light diffusing member and transfer film by using the same

Country Status (1)

Country Link
JP (1) JP2003043219A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100373187C (en) * 2004-12-14 2008-03-05 中华映管股份有限公司 Color filter substrate and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100373187C (en) * 2004-12-14 2008-03-05 中华映管股份有限公司 Color filter substrate and manufacturing method thereof

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