JP2002363002A - Method for enhancing efficacy of insecticidal aerosol agent - Google Patents
Method for enhancing efficacy of insecticidal aerosol agentInfo
- Publication number
- JP2002363002A JP2002363002A JP2001170399A JP2001170399A JP2002363002A JP 2002363002 A JP2002363002 A JP 2002363002A JP 2001170399 A JP2001170399 A JP 2001170399A JP 2001170399 A JP2001170399 A JP 2001170399A JP 2002363002 A JP2002363002 A JP 2002363002A
- Authority
- JP
- Japan
- Prior art keywords
- efficacy
- insecticidal
- enhancing
- weight
- aerosol agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000443 aerosol Substances 0.000 title claims abstract description 29
- 230000002708 enhancing effect Effects 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 13
- 230000000749 insecticidal effect Effects 0.000 title abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003380 propellant Substances 0.000 claims abstract description 9
- 239000002917 insecticide Substances 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 8
- 239000012188 paraffin wax Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 230000001105 regulatory effect Effects 0.000 abstract 1
- -1 fatty acid esters Chemical class 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 239000000306 component Substances 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 241000255925 Diptera Species 0.000 description 2
- 241000257303 Hymenoptera Species 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 235000019477 peppermint oil Nutrition 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 2
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 2
- 239000000341 volatile oil Substances 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 1
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 1
- FJDPATXIBIBRIM-QFMSAKRMSA-N (1R)-trans-cyphenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 FJDPATXIBIBRIM-QFMSAKRMSA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- LNJXZKBHJZAIKQ-UHFFFAOYSA-N 1,1,1,2-tetrachloro-3-(2,3,3,3-tetrachloropropoxy)propane Chemical compound ClC(Cl)(Cl)C(Cl)COCC(Cl)C(Cl)(Cl)Cl LNJXZKBHJZAIKQ-UHFFFAOYSA-N 0.000 description 1
- BHNZEZWIUMJCGF-UHFFFAOYSA-N 1-chloro-1,1-difluoroethane Chemical compound CC(F)(F)Cl BHNZEZWIUMJCGF-UHFFFAOYSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- YPZMPEPLWKRVLD-UHFFFAOYSA-N 2,3,4,5,6,7-hexahydroxyheptanal Chemical compound OCC(O)C(O)C(O)C(O)C(O)C=O YPZMPEPLWKRVLD-UHFFFAOYSA-N 0.000 description 1
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- OSDLLIBGSJNGJE-UHFFFAOYSA-N 4-chloro-3,5-dimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1Cl OSDLLIBGSJNGJE-UHFFFAOYSA-N 0.000 description 1
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- YUXIBTJKHLUKBD-UHFFFAOYSA-N Dibutyl succinate Chemical compound CCCCOC(=O)CCC(=O)OCCCC YUXIBTJKHLUKBD-UHFFFAOYSA-N 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- 239000005770 Eugenol Substances 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 description 1
- 235000005487 catechin Nutrition 0.000 description 1
- 229950001002 cianidanol Drugs 0.000 description 1
- 239000010630 cinnamon oil Substances 0.000 description 1
- 239000010634 clove oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000011928 denatured alcohol Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- 229960002217 eugenol Drugs 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
- VPRAQYXPZIFIOH-UHFFFAOYSA-N imiprothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)N(CC#C)CC1=O VPRAQYXPZIFIOH-UHFFFAOYSA-N 0.000 description 1
- 150000003903 lactic acid esters Chemical class 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003217 pyrazoles Chemical class 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、殺虫エアゾール剤
の効力増強方法に関する。[0001] The present invention relates to a method for enhancing the efficacy of an insecticide aerosol.
【0002】[0002]
【従来の技術】従来から効果的に害虫を駆除するため、
ピペロニルブトキシド、オクタクロロジプロピルエーテ
ル等の共力剤、芳香族カルボン酸エステル、脂肪酸エス
テル、ある種の界面活性剤等を用いて殺虫効力を高める
ことが知られている。これらの手段は、用いる殺虫成分
の種類、製剤等によっては十分に殺虫効力を高めること
ができないという問題がある。そのため様々な手段につ
いて検討が行われているが充分ではなく、依然として検
討の余地があり、とくに害虫に対して即効的に作用する
ことが求められる殺虫エアゾール剤においては、殺虫効
力を高めるための有効な手段が望まれているのが現状で
ある。2. Description of the Related Art Conventionally, in order to effectively control pests,
It is known to enhance insecticidal efficacy using synergists such as piperonyl butoxide and octachlorodipropyl ether, aromatic carboxylic acid esters, fatty acid esters, and certain surfactants. These means have a problem that the insecticidal efficacy cannot be sufficiently enhanced depending on the kind of insecticidal component used, the preparation, and the like. For this reason, various means have been studied, but are not sufficient, and there is still room for study. Particularly, in the case of insecticide aerosols that are required to act immediately on pests, it is effective to increase the insecticidal efficacy. It is the present situation that such means are desired.
【0003】[0003]
【発明が解決しようとする課題】そこで本発明の課題
は、上記のような状況に鑑みて、殺虫エアゾール剤のノ
ックダウン効力、殺虫効力を高めるための有効な手段を
提供することである。SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide an effective means for enhancing the knockdown effect and insecticidal effect of an insecticide aerosol in view of the above situation.
【0004】[0004]
【課題を解決するための手段】本発明者等は、上記課題
を解決するために鋭意検討した結果、殺虫エアゾール剤
に特定量の水を配合し、噴射剤の含有量を所定量とする
ことで、共力剤等を用いることなく、ノックダウン効
力、殺虫効力を高めることができることを見出した。す
なわち本発明は、以下の構成により達成されるものであ
る。 (1)殺虫エアゾール剤全量に対して1〜10重量%の
水を配合し、噴射剤の含有量を65重量%以上とするこ
とを特徴とする殺虫エアゾール剤の効力増強方法。 (2)水に対して重量比で2〜5倍のパラフィン系溶剤
を配合することを特徴とする請求項1記載の殺虫エアゾ
ール剤の効力増強方法。Means for Solving the Problems The present inventors have conducted intensive studies in order to solve the above-mentioned problems, and as a result, a specific amount of water has been added to the insecticide aerosol, and the content of the propellant has been set to a predetermined amount. It was found that the knockdown effect and the insecticidal effect can be enhanced without using a synergist or the like. That is, the present invention is achieved by the following configurations. (1) A method for enhancing the efficacy of an insecticide aerosol, wherein 1 to 10% by weight of water is mixed with respect to the total amount of the insecticide aerosol, and the content of the propellant is 65% by weight or more. (2) The method for enhancing the efficacy of an insecticidal aerosol according to claim 1, wherein a paraffin-based solvent is mixed in a weight ratio of 2 to 5 times with respect to water.
【0005】[0005]
【発明の実施の形態】本発明の殺虫エアゾール剤の効力
増強方法(以下、効力増強方法とも言う)は、水を殺虫
エアゾール剤全量に対して1〜10重量%、好ましくは
4〜8重量%となるように配合し、さらに噴射剤の含有
量を殺虫エアゾール剤全量に対して65重量%以上、好
ましくは70〜90重量%となるようにするものであ
る。BEST MODE FOR CARRYING OUT THE INVENTION In the method for enhancing the efficacy of an insecticide aerosol of the present invention (hereinafter also referred to as the efficacy enhancing method), water is used in an amount of 1 to 10% by weight, preferably 4 to 8% by weight based on the total amount of the insecticide aerosol. And the content of the propellant is 65% by weight or more, preferably 70 to 90% by weight, based on the total amount of the insecticide aerosol.
【0006】水に対して重量比で2〜5倍となるように
パラフィン系溶剤を配合することで、より優れたノック
ダウン効果、殺虫効果を得ることができる。パラフィン
系溶剤を用いる場合には、殺虫成分を安定に乳化させる
ために界面活性剤を用いることが必要であり、殺虫エア
ゾール剤全量に対して0.01〜10重量%、好ましく
は0.5〜5重量%配合する。界面活性剤としては、グ
リセリン脂肪酸エステル、ソルビタン脂肪酸エステル、
ポリオキシエチレンアルキルエーテル、ポリオキシエチ
レンアルキルフェニルエーテル、ポリオキシエチレンポ
リオキシプロピレングリコール、ポリエチレングリコー
ル脂肪酸エステル、ポリエチレングリコールソルビタン
脂肪酸エステル等の非イオン系界面活性剤が挙げられ
る。特にテトラオレイン酸ポリオキシエチレンソルビッ
トとヤシ油脂肪酸ソルビタンとを組み合わせて用いる
と、殺虫エアゾール剤の乳化がより安定となり、またノ
ックダウン効果、殺虫効果も優れたものとなる。[0006] By blending a paraffin-based solvent in a weight ratio of water to 2 to 5 times, more excellent knockdown effect and insecticidal effect can be obtained. When a paraffinic solvent is used, it is necessary to use a surfactant in order to stably emulsify the insecticidal component, and 0.01 to 10% by weight, preferably 0.5 to 10% by weight based on the total amount of the insecticide aerosol. 5% by weight is blended. As the surfactant, glycerin fatty acid ester, sorbitan fatty acid ester,
Nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene polyoxypropylene glycol, polyethylene glycol fatty acid ester, and polyethylene glycol sorbitan fatty acid ester are exemplified. In particular, when polyoxyethylene sorbite tetraoleate and sorbitan coconut oil fatty acid are used in combination, the emulsification of the insecticide aerosol becomes more stable, and the knockdown effect and the insecticidal effect become excellent.
【0007】本発明の効力増強方法は、殺虫成分、溶
剤、噴射剤を含む殺虫エアゾール剤に適用できる。この
ような殺虫エアゾール剤に用いる殺虫成分、溶剤、噴射
剤としては、以下のものが挙げられる。[0007] The efficacy enhancing method of the present invention can be applied to insecticide aerosols containing insecticidal components, solvents and propellants. The following are mentioned as an insecticidal component, a solvent, and a propellant used for such an insecticide aerosol.
【0008】殺虫成分としては、天然ピレトリン、ピレ
トリン、アレスリン、フタルスリン、レスメトリン、フ
ラメトリン、ペルメトリン、フェノトリン、シフェノト
リン、プラレトリン、トランスフルトリン、イミプロト
リン、エンペントリン、エトフェンプロックス等のピレ
スロイド系化合物;プロポクサー、カルバリル等のカー
バメイト系化合物;フェニトロチオン、DDVP等の有
機リン系化合物;メトキサジアゾン等のオキサジアゾー
ル系化合物;フィプロニル等のピラゾール系化合物;フ
ィットンチッド、ハッカ油、オレンジ油、桂皮油、丁子
油等の精油類;IBTA;IBTE;四級アンモニウム
塩;サリチル酸ベンジル等が挙げられる。これらは1種
又は2種以上を用いることができ、殺虫エアゾール剤全
量に対して0.1〜1重量%、さらには0.1〜0.5
重量%となるように用いればよい。Examples of the insecticidal component include pyrethroid compounds such as natural pyrethrin, pyrethrin, allethrin, phthalthrin, resmethrin, framethrin, permethrin, phenothrin, cyphenothrin, pralethrin, transfluthrin, imiprothrin, empentrin, etofenprox and the like; propoxer, carbaryl Organic phosphorus compounds such as fenitrothion and DDVP; oxadiazole compounds such as methoxadiazone; pyrazole compounds such as fipronil; fittintide, peppermint oil, orange oil, cinnamon oil and clove oil. Essential oils; IBTA; IBTE; quaternary ammonium salts; benzyl salicylate and the like. One or more of these can be used, and 0.1 to 1% by weight based on the total amount of the insecticide aerosol, and further 0.1 to 0.5%
It may be used so as to be% by weight.
【0009】溶剤としては、ノルマルパラフィン、イソ
パラフィン、これらの混合物等のパラフィン系溶剤;エ
タノール、変性アルコール等のアルコール;炭酸エステ
ル、乳酸エステル;ポリビニルピロリドン;グリコー
ル;シリコーン等が挙げられる。これらの1種又は2種
以上を用い、殺虫エアゾール剤全量に対して10〜30
重量%、好ましくは15〜30重量%となるように用い
る。Examples of the solvent include paraffinic solvents such as normal paraffin, isoparaffin, and mixtures thereof; alcohols such as ethanol and denatured alcohol; carbonates and lactates; polyvinylpyrrolidone; glycol; Using one or more of these, 10 to 30 with respect to the total amount of the insecticide aerosol.
%, Preferably 15 to 30% by weight.
【0010】噴射剤としては、液化石油ガス、ジメチル
エーテル、ジフルオロモノクロロエタン等の液化ガス;
炭酸ガス、窒素、圧縮空気等の圧縮ガス等が挙げられ、
これらの1種又は2種以上を用いる。[0010] As the propellant, liquefied petroleum gas, liquefied gas such as dimethyl ether, difluoromonochloroethane and the like;
Carbon dioxide gas, nitrogen, compressed gas such as compressed air and the like,
One or two or more of these are used.
【0011】さらに殺虫エアゾール剤には、ジエチルメ
タトルアミド、ジ−n−ブチルサクシネート、ヒドロキ
シアニソール等の忌避剤;PCMX、IPBC等の殺菌剤;
ラウリルメタクリレート、ゲラニルクロトネート、カテ
キン等の消臭剤;バラ油、ラベンダー油、ハッカ油等の
精油;ピネン、リモネン、リナロール、メントール、オ
イゲノール等の香料;非イオン系界面活性剤、陽イオン
系界面活性剤、陰イオン系界面活性剤、両性界面活性剤
等の界面活性剤;S421、サイネピリン等の共力剤;
BHT、BHA等の酸化防止剤等を配合してもよい。Further, insecticide aerosols include repellents such as diethylmethtoluamide, di-n-butylsuccinate and hydroxyanisole; fungicides such as PCMX and IPBC;
Deodorants such as lauryl methacrylate, geranyl crotonate, and catechin; essential oils such as rose oil, lavender oil, and peppermint oil; fragrances such as pinene, limonene, linalool, menthol, and eugenol; nonionic surfactants; Surfactants such as surfactants, anionic surfactants and amphoteric surfactants; synergists such as S421 and sinepirin;
An antioxidant such as BHT or BHA may be blended.
【0012】本発明の効力増強方法は、ハエ、カ、ゴキ
ブリ、クモ、ダニ、ケムシ、ゲジゲジ、ダンゴムシ、ア
リ等の各種害虫に用いる殺虫エアゾール剤に適用するこ
とができる。The efficacy enhancing method of the present invention can be applied to insecticidal aerosols used for various insect pests such as flies, mosquitoes, cockroaches, spiders, mites, pitworms, gegegeji, dam ants and ants.
【0013】[0013]
【実施例】以下、実施例により本発明を具体的に説明す
る。ただし本発明はこれらの実施例のみに限定されるも
のではない。The present invention will be described below in detail with reference to examples. However, the present invention is not limited to only these examples.
【0014】(1)殺虫効力試験 表1記載の殺虫エアゾール剤(検体1〜3)を作成し、
ケージ(25cm×25cm×25cm)の中にイエバ
エ雌成虫20匹を入れ、1mの距離から1秒間噴射し
た。そしてKT90(90%ノックダウン時間(秒))と
24時間後の致死率(%)を求めた。比較として、水を
含有しない殺虫エアゾール剤(市販品A)と、噴射剤の
含有量が50重量%で水を含んだ殺虫エアゾール剤(市
販品B)を用いて同様の試験を行った。(1) Insecticidal efficacy test Insecticidal aerosols (samples 1 to 3) shown in Table 1 were prepared.
Twenty adult female house flies were placed in a cage (25 cm × 25 cm × 25 cm) and sprayed for 1 second from a distance of 1 m. Then, KT90 (90% knockdown time (sec)) and mortality (%) after 24 hours were determined. As a comparison, the same test was carried out using an insecticide aerosol containing no water (commercially available product A) and an insecticide aerosol containing 50% by weight of a propellant and containing water (commercially available product B).
【0015】[0015]
【表1】 [Table 1]
【0016】測定結果は表2に示したとおり、本発明の
効力増強方法を用いた検体1及び2は、ノックダウン効
力、殺虫効力のいずれにおいても検体3及び市販品より
も優れたものであった。As shown in Table 2, the samples 1 and 2 using the potency enhancing method of the present invention were superior to the sample 3 and the commercial product in both knockdown efficacy and insecticidal efficacy. Was.
【0017】[0017]
【表2】 [Table 2]
【0018】[0018]
【発明の効果】本発明の効力増強方法によって、共力剤
等を用いることなく、殺虫エアゾール剤のノックダウン
効力、殺虫効力を高めることができる。EFFECT OF THE INVENTION According to the method for enhancing potency of the present invention, the knockdown effect and the insecticidal effect of the insecticide aerosol can be increased without using a synergist or the like.
Claims (2)
重量%の水を配合し、噴射剤の含有量を65重量%以上
とすることを特徴とする殺虫エアゾール剤の効力増強方
法。1 to 10 parts by weight based on the total amount of the insecticide aerosol.
A method for enhancing the efficacy of an insecticide aerosol, characterized in that water is blended in an amount of 65% by weight and a propellant content is 65% by weight or more.
ン系溶剤を配合することを特徴とする請求項1記載の殺
虫エアゾール剤の効力増強方法。2. The method for enhancing the efficacy of an insecticide aerosol according to claim 1, wherein a paraffin-based solvent is mixed in a weight ratio of 2 to 5 times with respect to water.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009221150A (en) * | 2008-03-17 | 2009-10-01 | Lion Corp | Sanitary insect pest exterminator composition |
JP2012232964A (en) * | 2011-04-18 | 2012-11-29 | Dainippon Jochugiku Co Ltd | Creeping pest control powder |
-
2001
- 2001-06-06 JP JP2001170399A patent/JP4335475B2/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009221150A (en) * | 2008-03-17 | 2009-10-01 | Lion Corp | Sanitary insect pest exterminator composition |
JP2012232964A (en) * | 2011-04-18 | 2012-11-29 | Dainippon Jochugiku Co Ltd | Creeping pest control powder |
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