JP2002363002A - Method for enhancing efficacy of insecticidal aerosol agent - Google Patents

Method for enhancing efficacy of insecticidal aerosol agent

Info

Publication number
JP2002363002A
JP2002363002A JP2001170399A JP2001170399A JP2002363002A JP 2002363002 A JP2002363002 A JP 2002363002A JP 2001170399 A JP2001170399 A JP 2001170399A JP 2001170399 A JP2001170399 A JP 2001170399A JP 2002363002 A JP2002363002 A JP 2002363002A
Authority
JP
Japan
Prior art keywords
efficacy
insecticidal
enhancing
weight
aerosol agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001170399A
Other languages
Japanese (ja)
Other versions
JP4335475B2 (en
Inventor
Katsuyoshi Kado
克好 加百
Teruki Yamamoto
輝樹 山本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Earth Corp
Original Assignee
Earth Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Earth Chemical Co Ltd filed Critical Earth Chemical Co Ltd
Priority to JP2001170399A priority Critical patent/JP4335475B2/en
Publication of JP2002363002A publication Critical patent/JP2002363002A/en
Application granted granted Critical
Publication of JP4335475B2 publication Critical patent/JP4335475B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a means effective for enhancing the knockdown efficacy and insecticidal efficacy of an insecticidal aerosol agent. SOLUTION: This method for enhancing the efficacy of the insecticidal aerosol agent is characterized by formulating water in an amount of 1-10 wt.% based on the total amount of the insecticidal aerosol agent and regulating the content of a propellant to >=65 wt.%.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、殺虫エアゾール剤
の効力増強方法に関する。
[0001] The present invention relates to a method for enhancing the efficacy of an insecticide aerosol.

【0002】[0002]

【従来の技術】従来から効果的に害虫を駆除するため、
ピペロニルブトキシド、オクタクロロジプロピルエーテ
ル等の共力剤、芳香族カルボン酸エステル、脂肪酸エス
テル、ある種の界面活性剤等を用いて殺虫効力を高める
ことが知られている。これらの手段は、用いる殺虫成分
の種類、製剤等によっては十分に殺虫効力を高めること
ができないという問題がある。そのため様々な手段につ
いて検討が行われているが充分ではなく、依然として検
討の余地があり、とくに害虫に対して即効的に作用する
ことが求められる殺虫エアゾール剤においては、殺虫効
力を高めるための有効な手段が望まれているのが現状で
ある。
2. Description of the Related Art Conventionally, in order to effectively control pests,
It is known to enhance insecticidal efficacy using synergists such as piperonyl butoxide and octachlorodipropyl ether, aromatic carboxylic acid esters, fatty acid esters, and certain surfactants. These means have a problem that the insecticidal efficacy cannot be sufficiently enhanced depending on the kind of insecticidal component used, the preparation, and the like. For this reason, various means have been studied, but are not sufficient, and there is still room for study. Particularly, in the case of insecticide aerosols that are required to act immediately on pests, it is effective to increase the insecticidal efficacy. It is the present situation that such means are desired.

【0003】[0003]

【発明が解決しようとする課題】そこで本発明の課題
は、上記のような状況に鑑みて、殺虫エアゾール剤のノ
ックダウン効力、殺虫効力を高めるための有効な手段を
提供することである。
SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide an effective means for enhancing the knockdown effect and insecticidal effect of an insecticide aerosol in view of the above situation.

【0004】[0004]

【課題を解決するための手段】本発明者等は、上記課題
を解決するために鋭意検討した結果、殺虫エアゾール剤
に特定量の水を配合し、噴射剤の含有量を所定量とする
ことで、共力剤等を用いることなく、ノックダウン効
力、殺虫効力を高めることができることを見出した。す
なわち本発明は、以下の構成により達成されるものであ
る。 (1)殺虫エアゾール剤全量に対して1〜10重量%の
水を配合し、噴射剤の含有量を65重量%以上とするこ
とを特徴とする殺虫エアゾール剤の効力増強方法。 (2)水に対して重量比で2〜5倍のパラフィン系溶剤
を配合することを特徴とする請求項1記載の殺虫エアゾ
ール剤の効力増強方法。
Means for Solving the Problems The present inventors have conducted intensive studies in order to solve the above-mentioned problems, and as a result, a specific amount of water has been added to the insecticide aerosol, and the content of the propellant has been set to a predetermined amount. It was found that the knockdown effect and the insecticidal effect can be enhanced without using a synergist or the like. That is, the present invention is achieved by the following configurations. (1) A method for enhancing the efficacy of an insecticide aerosol, wherein 1 to 10% by weight of water is mixed with respect to the total amount of the insecticide aerosol, and the content of the propellant is 65% by weight or more. (2) The method for enhancing the efficacy of an insecticidal aerosol according to claim 1, wherein a paraffin-based solvent is mixed in a weight ratio of 2 to 5 times with respect to water.

【0005】[0005]

【発明の実施の形態】本発明の殺虫エアゾール剤の効力
増強方法(以下、効力増強方法とも言う)は、水を殺虫
エアゾール剤全量に対して1〜10重量%、好ましくは
4〜8重量%となるように配合し、さらに噴射剤の含有
量を殺虫エアゾール剤全量に対して65重量%以上、好
ましくは70〜90重量%となるようにするものであ
る。
BEST MODE FOR CARRYING OUT THE INVENTION In the method for enhancing the efficacy of an insecticide aerosol of the present invention (hereinafter also referred to as the efficacy enhancing method), water is used in an amount of 1 to 10% by weight, preferably 4 to 8% by weight based on the total amount of the insecticide aerosol. And the content of the propellant is 65% by weight or more, preferably 70 to 90% by weight, based on the total amount of the insecticide aerosol.

【0006】水に対して重量比で2〜5倍となるように
パラフィン系溶剤を配合することで、より優れたノック
ダウン効果、殺虫効果を得ることができる。パラフィン
系溶剤を用いる場合には、殺虫成分を安定に乳化させる
ために界面活性剤を用いることが必要であり、殺虫エア
ゾール剤全量に対して0.01〜10重量%、好ましく
は0.5〜5重量%配合する。界面活性剤としては、グ
リセリン脂肪酸エステル、ソルビタン脂肪酸エステル、
ポリオキシエチレンアルキルエーテル、ポリオキシエチ
レンアルキルフェニルエーテル、ポリオキシエチレンポ
リオキシプロピレングリコール、ポリエチレングリコー
ル脂肪酸エステル、ポリエチレングリコールソルビタン
脂肪酸エステル等の非イオン系界面活性剤が挙げられ
る。特にテトラオレイン酸ポリオキシエチレンソルビッ
トとヤシ油脂肪酸ソルビタンとを組み合わせて用いる
と、殺虫エアゾール剤の乳化がより安定となり、またノ
ックダウン効果、殺虫効果も優れたものとなる。
[0006] By blending a paraffin-based solvent in a weight ratio of water to 2 to 5 times, more excellent knockdown effect and insecticidal effect can be obtained. When a paraffinic solvent is used, it is necessary to use a surfactant in order to stably emulsify the insecticidal component, and 0.01 to 10% by weight, preferably 0.5 to 10% by weight based on the total amount of the insecticide aerosol. 5% by weight is blended. As the surfactant, glycerin fatty acid ester, sorbitan fatty acid ester,
Nonionic surfactants such as polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene polyoxypropylene glycol, polyethylene glycol fatty acid ester, and polyethylene glycol sorbitan fatty acid ester are exemplified. In particular, when polyoxyethylene sorbite tetraoleate and sorbitan coconut oil fatty acid are used in combination, the emulsification of the insecticide aerosol becomes more stable, and the knockdown effect and the insecticidal effect become excellent.

【0007】本発明の効力増強方法は、殺虫成分、溶
剤、噴射剤を含む殺虫エアゾール剤に適用できる。この
ような殺虫エアゾール剤に用いる殺虫成分、溶剤、噴射
剤としては、以下のものが挙げられる。
[0007] The efficacy enhancing method of the present invention can be applied to insecticide aerosols containing insecticidal components, solvents and propellants. The following are mentioned as an insecticidal component, a solvent, and a propellant used for such an insecticide aerosol.

【0008】殺虫成分としては、天然ピレトリン、ピレ
トリン、アレスリン、フタルスリン、レスメトリン、フ
ラメトリン、ペルメトリン、フェノトリン、シフェノト
リン、プラレトリン、トランスフルトリン、イミプロト
リン、エンペントリン、エトフェンプロックス等のピレ
スロイド系化合物;プロポクサー、カルバリル等のカー
バメイト系化合物;フェニトロチオン、DDVP等の有
機リン系化合物;メトキサジアゾン等のオキサジアゾー
ル系化合物;フィプロニル等のピラゾール系化合物;フ
ィットンチッド、ハッカ油、オレンジ油、桂皮油、丁子
油等の精油類;IBTA;IBTE;四級アンモニウム
塩;サリチル酸ベンジル等が挙げられる。これらは1種
又は2種以上を用いることができ、殺虫エアゾール剤全
量に対して0.1〜1重量%、さらには0.1〜0.5
重量%となるように用いればよい。
Examples of the insecticidal component include pyrethroid compounds such as natural pyrethrin, pyrethrin, allethrin, phthalthrin, resmethrin, framethrin, permethrin, phenothrin, cyphenothrin, pralethrin, transfluthrin, imiprothrin, empentrin, etofenprox and the like; propoxer, carbaryl Organic phosphorus compounds such as fenitrothion and DDVP; oxadiazole compounds such as methoxadiazone; pyrazole compounds such as fipronil; fittintide, peppermint oil, orange oil, cinnamon oil and clove oil. Essential oils; IBTA; IBTE; quaternary ammonium salts; benzyl salicylate and the like. One or more of these can be used, and 0.1 to 1% by weight based on the total amount of the insecticide aerosol, and further 0.1 to 0.5%
It may be used so as to be% by weight.

【0009】溶剤としては、ノルマルパラフィン、イソ
パラフィン、これらの混合物等のパラフィン系溶剤;エ
タノール、変性アルコール等のアルコール;炭酸エステ
ル、乳酸エステル;ポリビニルピロリドン;グリコー
ル;シリコーン等が挙げられる。これらの1種又は2種
以上を用い、殺虫エアゾール剤全量に対して10〜30
重量%、好ましくは15〜30重量%となるように用い
る。
Examples of the solvent include paraffinic solvents such as normal paraffin, isoparaffin, and mixtures thereof; alcohols such as ethanol and denatured alcohol; carbonates and lactates; polyvinylpyrrolidone; glycol; Using one or more of these, 10 to 30 with respect to the total amount of the insecticide aerosol.
%, Preferably 15 to 30% by weight.

【0010】噴射剤としては、液化石油ガス、ジメチル
エーテル、ジフルオロモノクロロエタン等の液化ガス;
炭酸ガス、窒素、圧縮空気等の圧縮ガス等が挙げられ、
これらの1種又は2種以上を用いる。
[0010] As the propellant, liquefied petroleum gas, liquefied gas such as dimethyl ether, difluoromonochloroethane and the like;
Carbon dioxide gas, nitrogen, compressed gas such as compressed air and the like,
One or two or more of these are used.

【0011】さらに殺虫エアゾール剤には、ジエチルメ
タトルアミド、ジ−n−ブチルサクシネート、ヒドロキ
シアニソール等の忌避剤;PCMX、IPBC等の殺菌剤;
ラウリルメタクリレート、ゲラニルクロトネート、カテ
キン等の消臭剤;バラ油、ラベンダー油、ハッカ油等の
精油;ピネン、リモネン、リナロール、メントール、オ
イゲノール等の香料;非イオン系界面活性剤、陽イオン
系界面活性剤、陰イオン系界面活性剤、両性界面活性剤
等の界面活性剤;S421、サイネピリン等の共力剤;
BHT、BHA等の酸化防止剤等を配合してもよい。
Further, insecticide aerosols include repellents such as diethylmethtoluamide, di-n-butylsuccinate and hydroxyanisole; fungicides such as PCMX and IPBC;
Deodorants such as lauryl methacrylate, geranyl crotonate, and catechin; essential oils such as rose oil, lavender oil, and peppermint oil; fragrances such as pinene, limonene, linalool, menthol, and eugenol; nonionic surfactants; Surfactants such as surfactants, anionic surfactants and amphoteric surfactants; synergists such as S421 and sinepirin;
An antioxidant such as BHT or BHA may be blended.

【0012】本発明の効力増強方法は、ハエ、カ、ゴキ
ブリ、クモ、ダニ、ケムシ、ゲジゲジ、ダンゴムシ、ア
リ等の各種害虫に用いる殺虫エアゾール剤に適用するこ
とができる。
The efficacy enhancing method of the present invention can be applied to insecticidal aerosols used for various insect pests such as flies, mosquitoes, cockroaches, spiders, mites, pitworms, gegegeji, dam ants and ants.

【0013】[0013]

【実施例】以下、実施例により本発明を具体的に説明す
る。ただし本発明はこれらの実施例のみに限定されるも
のではない。
The present invention will be described below in detail with reference to examples. However, the present invention is not limited to only these examples.

【0014】(1)殺虫効力試験 表1記載の殺虫エアゾール剤(検体1〜3)を作成し、
ケージ(25cm×25cm×25cm)の中にイエバ
エ雌成虫20匹を入れ、1mの距離から1秒間噴射し
た。そしてKT90(90%ノックダウン時間(秒))と
24時間後の致死率(%)を求めた。比較として、水を
含有しない殺虫エアゾール剤(市販品A)と、噴射剤の
含有量が50重量%で水を含んだ殺虫エアゾール剤(市
販品B)を用いて同様の試験を行った。
(1) Insecticidal efficacy test Insecticidal aerosols (samples 1 to 3) shown in Table 1 were prepared.
Twenty adult female house flies were placed in a cage (25 cm × 25 cm × 25 cm) and sprayed for 1 second from a distance of 1 m. Then, KT90 (90% knockdown time (sec)) and mortality (%) after 24 hours were determined. As a comparison, the same test was carried out using an insecticide aerosol containing no water (commercially available product A) and an insecticide aerosol containing 50% by weight of a propellant and containing water (commercially available product B).

【0015】[0015]

【表1】 [Table 1]

【0016】測定結果は表2に示したとおり、本発明の
効力増強方法を用いた検体1及び2は、ノックダウン効
力、殺虫効力のいずれにおいても検体3及び市販品より
も優れたものであった。
As shown in Table 2, the samples 1 and 2 using the potency enhancing method of the present invention were superior to the sample 3 and the commercial product in both knockdown efficacy and insecticidal efficacy. Was.

【0017】[0017]

【表2】 [Table 2]

【0018】[0018]

【発明の効果】本発明の効力増強方法によって、共力剤
等を用いることなく、殺虫エアゾール剤のノックダウン
効力、殺虫効力を高めることができる。
EFFECT OF THE INVENTION According to the method for enhancing potency of the present invention, the knockdown effect and the insecticidal effect of the insecticide aerosol can be increased without using a synergist or the like.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 殺虫エアゾール剤全量に対して1〜10
重量%の水を配合し、噴射剤の含有量を65重量%以上
とすることを特徴とする殺虫エアゾール剤の効力増強方
法。
1 to 10 parts by weight based on the total amount of the insecticide aerosol.
A method for enhancing the efficacy of an insecticide aerosol, characterized in that water is blended in an amount of 65% by weight and a propellant content is 65% by weight or more.
【請求項2】 水に対して重量比で2〜5倍のパラフィ
ン系溶剤を配合することを特徴とする請求項1記載の殺
虫エアゾール剤の効力増強方法。
2. The method for enhancing the efficacy of an insecticide aerosol according to claim 1, wherein a paraffin-based solvent is mixed in a weight ratio of 2 to 5 times with respect to water.
JP2001170399A 2001-06-06 2001-06-06 Method for enhancing efficacy of insecticidal aerosols Expired - Fee Related JP4335475B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001170399A JP4335475B2 (en) 2001-06-06 2001-06-06 Method for enhancing efficacy of insecticidal aerosols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001170399A JP4335475B2 (en) 2001-06-06 2001-06-06 Method for enhancing efficacy of insecticidal aerosols

Publications (2)

Publication Number Publication Date
JP2002363002A true JP2002363002A (en) 2002-12-18
JP4335475B2 JP4335475B2 (en) 2009-09-30

Family

ID=19012327

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001170399A Expired - Fee Related JP4335475B2 (en) 2001-06-06 2001-06-06 Method for enhancing efficacy of insecticidal aerosols

Country Status (1)

Country Link
JP (1) JP4335475B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009221150A (en) * 2008-03-17 2009-10-01 Lion Corp Sanitary insect pest exterminator composition
JP2012232964A (en) * 2011-04-18 2012-11-29 Dainippon Jochugiku Co Ltd Creeping pest control powder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009221150A (en) * 2008-03-17 2009-10-01 Lion Corp Sanitary insect pest exterminator composition
JP2012232964A (en) * 2011-04-18 2012-11-29 Dainippon Jochugiku Co Ltd Creeping pest control powder

Also Published As

Publication number Publication date
JP4335475B2 (en) 2009-09-30

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