JP2002214220A - Water quality checker circuit - Google Patents

Water quality checker circuit

Info

Publication number
JP2002214220A
JP2002214220A JP2001014866A JP2001014866A JP2002214220A JP 2002214220 A JP2002214220 A JP 2002214220A JP 2001014866 A JP2001014866 A JP 2001014866A JP 2001014866 A JP2001014866 A JP 2001014866A JP 2002214220 A JP2002214220 A JP 2002214220A
Authority
JP
Japan
Prior art keywords
voltage
operational amplifier
potential
input terminal
inverting input
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001014866A
Other languages
Japanese (ja)
Other versions
JP4658342B2 (en
Inventor
Kazuo Okinaga
一夫 翁長
Junko Yanagiya
順子 柳谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FIS Inc
Original Assignee
FIS Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FIS Inc filed Critical FIS Inc
Priority to JP2001014866A priority Critical patent/JP4658342B2/en
Publication of JP2002214220A publication Critical patent/JP2002214220A/en
Application granted granted Critical
Publication of JP4658342B2 publication Critical patent/JP4658342B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a water quality checker circuit capable of checking not only alkalinity but also the concentration of chlorine and capable of evaluating and displaying the concentration of chlorine and alkalinity by a display means even at the time of measurement of both of the concentration of chlorine and alkalinity when water quality is evaluated and displayed by the display means. SOLUTION: If a switch SW2 is closed at the time of measurement of alkalinity, a switch SW21 is closed in connection with the on-operation of the switch SW2 and, since the voltage at the non-reversal input terminal of an operational amplifier OP3 becomes voltage divided by a resistor R8 and a variable resistor VR2, the potential of the output terminal of the operational amplifier OP3 becomes lower than that of a line A in a negative direction as compared with the voltage at the time of measurement of the concentration of chlorine.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は水道水の塩素濃度
や、アルカリ生成水のアルカリ度合の何れのチェックに
も使える水質チェッカ回路に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water quality checker circuit which can be used for checking both the chlorine concentration of tap water and the alkalinity of alkaline water.

【0002】[0002]

【従来の技術】従来液中の塩素濃度或いはアルカリ度合
を一対の電極の起電圧によってチェックするものがある
が、塩素濃度を測定する場合と、アルカリ度合の測定時
とで電極間の起電圧の方向が逆であるため、塩素濃度が
略零、つまりきれいな水と、アルカリ度合が所定以上あ
る液とが共に”良”と評価するような場合において、同
一の発光ダイオードを用いて”良”であることを評価表
示しようとすると、起電圧の方向が逆であるため検知信
号処理のための回路構成が複雑になるという問題があっ
た。
2. Description of the Related Art Conventionally, there is a method in which the chlorine concentration or alkalinity in a liquid is checked by the electromotive voltage of a pair of electrodes. Since the directions are opposite, when the chlorine concentration is substantially zero, that is, when both clean water and a liquid having a predetermined alkalinity are evaluated as “good”, the same light emitting diode is used to determine “good”. If an attempt is made to evaluate and display that there is a problem, the direction of the electromotive voltage is reversed, so that there is a problem that the circuit configuration for processing the detection signal becomes complicated.

【0003】[0003]

【発明が解決しようとする課題】本発明は、上述の問題
点に鑑みて為されたもので、その目的とするところは、
アルカリ度合も塩素濃度もチェックすることができ、し
かも表示手段により、水質の評価表示する場合に、塩素
濃度、アルカリ度合の何れの測定時にも同じ表示手段に
よって評価表示することができる水質チェッカ回路を提
供することにある。
DISCLOSURE OF THE INVENTION The present invention has been made in view of the above-mentioned problems.
A water quality checker circuit that can check both the alkalinity and the chlorine concentration, and that can display and evaluate the water quality by the display unit when the chlorine concentration and the alkalinity are measured by the display unit. To provide.

【0004】[0004]

【課題を解決するための手段】上記の目的を達成するた
めに、請求項1の発明では、電源と、異種の金属により
構成され、検知対象の液中に浸けられたときに電圧を発
生して検知信号として出力する一対の電極と、塩素濃度
の検知対象の液中に浸けたときに起電圧のマイナス側と
なり、アルカリ度合の検知対象の液中に浸けたときに起
電圧のプラス側となる一方の電極を接続する接続ライン
の電位を上記電源のマイナスグランドから見て一定の電
位に保持する手段と、上記検知信号を非反転入力端に入
力し、出力端と反転入力端に接続した抵抗と反転入力端
とグランドとの間に接続した抵抗とで定まる利得で検知
信号を非反転増幅する信号増幅用の演算増幅器と、上記
電源のプラス極と上記接続ラインとの間に接続された複
数の抵抗の直列回路によって構成される分圧回路から出
力される複数の異なる分圧出力に対応して設けられて、
異なる分圧出力により基準電圧が夫々設定され、該基準
電圧と上記演算増幅器から出力される検知信号電圧とを
比較する複数のコンパレータと、該各コンパレータに対
応して設けられて各コンパレータの出力端と上記電源と
の間に接続され、上記対応するコンパレータの出力に応
じて駆動され、検知結果を表示する表示手段とを備える
とともに、上記演算増幅器のグランドの電位を塩素濃度
測定時には上記接続ラインの電位とし、アルカリ度合測
定時には上記接続ラインの電位よりもマイナス方向に低
く切換設定する手段を備えて測定するアルカリ度合が所
定以上高い場合から所定以下に至るまでと測定する塩素
濃度が略零の場合から所定濃度以上に至るまでの上記演
算増幅器から出力する検知信号電圧の変化が略同じとな
るように上記演算増幅器の利得を設定したことを特徴と
する。
In order to achieve the above object, according to the first aspect of the present invention, a power supply and a different kind of metal are used to generate a voltage when immersed in a liquid to be detected. A pair of electrodes that output as a detection signal, and a negative side of the electromotive voltage when immersed in the liquid to be detected of chlorine concentration, and a positive side of the electromotive voltage when immersed in the liquid to be detected of alkalinity. Means for maintaining the potential of a connection line connecting one of the electrodes at a constant potential when viewed from the negative ground of the power supply, and the detection signal is input to a non-inverting input terminal and connected to an output terminal and an inverting input terminal. An operational amplifier for signal amplification that non-invertingly amplifies the detection signal with a gain determined by the resistance and the resistance connected between the inverting input terminal and the ground, and is connected between the positive pole of the power supply and the connection line. Series connection of multiple resistors Provided corresponding to a plurality of different divided voltage output from the voltage division circuit constituted by,
Reference voltages are respectively set by different voltage division outputs, a plurality of comparators for comparing the reference voltage with a detection signal voltage output from the operational amplifier, and an output terminal of each comparator provided corresponding to each comparator. And a power supply connected between the power supply and the output of the corresponding comparator.The display means displays the detection result. When the alkali concentration is measured, the means for switching is set to be lower than the potential of the connection line in the minus direction when measuring the alkalinity. The above calculation is performed so that the change in the detection signal voltage output from the operational amplifier until the concentration reaches Characterized in that setting the gain of the width unit.

【0005】請求項2の発明では、請求項1の発明にお
いて、上記接続ラインの電位を一定に保持する手段を、
上記電源の電圧を所定電圧に降圧した電圧を非反転入力
端に入力して略同じ電圧を出力に発生するように利得が
設定された非反転増幅器を構成する別の演算増幅器によ
り構成し、該別の演算増幅器の出力端に上記接続ライン
を接続して成ることを特徴とする。
According to a second aspect of the present invention, in the first aspect, the means for maintaining the potential of the connection line constant is:
A voltage obtained by reducing the voltage of the power supply to a predetermined voltage is input to a non-inverting input terminal, and another operational amplifier constituting a non-inverting amplifier having a gain set so as to generate substantially the same voltage at an output is provided. The connection line is connected to the output terminal of another operational amplifier.

【0006】請求項3の発明では、請求項1又は2の発
明において、上記切換手段として、反転入力端と出力端
が接続された他の演算増幅器と、該他の演算増幅器の非
反転入力端に入力する電圧を上記接続ラインの電圧とこ
の接続ラインよりも低い電圧とに切り換える電圧切換手
段とから構成し、上記他の演算増幅器の出力端の電位を
上記信号増幅用の演算増幅器のグランド電位としたこと
を特徴とする。
According to a third aspect of the present invention, in the first or second aspect of the invention, as the switching means, another operational amplifier having an inverting input terminal and an output terminal connected thereto, and a non-inverting input terminal of the other operational amplifier. And voltage switching means for switching the voltage inputted to the connection line between the voltage of the connection line and the voltage lower than the connection line, and setting the potential of the output terminal of the other operational amplifier to the ground potential of the operational amplifier for signal amplification. It is characterized by having.

【0007】請求項4の発明では、請求項1乃至3の何
れかの発明において、上記各コンパレータの非反転入力
端に上記信号増幅用の演算増幅器からの検知信号電圧
を、上記各コンパレータの反転入力端に基準電圧を夫々
入力し、基準電圧より入力する検知信号電圧が低いコン
パレータをオンして上記表示手段を動作させることを特
徴とする。
According to a fourth aspect of the present invention, in any one of the first to third aspects of the present invention, the detection signal voltage from the operational amplifier for signal amplification is supplied to the non-inverting input terminal of each of the comparators. A reference voltage is input to each input terminal, and a comparator having a lower detection signal voltage than the reference voltage is turned on to operate the display means.

【0008】請求項5の発明では、請求項1乃至4の何
れかの発明において、上記電源が電池電源を安定化する
定電圧回路の出力により構成して成ることを特徴とす
る。
According to a fifth aspect of the present invention, in any one of the first to fourth aspects, the power supply is constituted by an output of a constant voltage circuit for stabilizing a battery power supply.

【0009】[0009]

【発明の実施の形態】以下本発明を一実施形態により説
明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described below with reference to an embodiment.

【0010】図1は本実施形態の回路を示しており、図
において、乾電池、二次電池等の電池電源1に対して塩
素濃度測定開始用スイッチSW1とアルカリ度合の測定
開始用スイッチSW2との並列回路を介して汎用IC等
からなる定電圧回路2を接続し、この定電圧回路2によ
り安定化した電源電圧を得、この電圧を抵抗R1,R2
の抵抗分圧回路により分圧して非反転増幅器を構成する
演算増幅器OP1の非反転入力端に印加し、この演算増
幅器OP1の出力端と反転入力端との間に接続した抵抗
R3、R4の直列回路の中点電位を、水質評価を段階的
に表示するための表示回路4のコンパレータCP1〜C
P5の基準電圧のグランドレベルとするとともに、セン
サ用電極3a、3b間に発生する起電力による検出信号
電圧のグランドレベルとしている。
FIG. 1 shows a circuit of this embodiment. In the figure, a switch SW1 for starting measurement of chlorine concentration and a switch SW2 for starting measurement of alkalinity are connected to a battery power source 1 such as a dry battery or a secondary battery. A constant voltage circuit 2 composed of a general-purpose IC or the like is connected via a parallel circuit, and a power supply voltage stabilized by the constant voltage circuit 2 is obtained.
Is applied to a non-inverting input terminal of an operational amplifier OP1 which is divided by a resistance voltage dividing circuit to constitute a non-inverting amplifier, and a series connection of resistors R3 and R4 connected between an output terminal and an inverting input terminal of the operational amplifier OP1. The comparators CP1 to CP of the display circuit 4 for displaying the midpoint potential of the circuit in a stepwise manner in the water quality evaluation.
The ground level of the reference voltage of P5 and the ground level of the detection signal voltage due to the electromotive force generated between the sensor electrodes 3a and 3b.

【0011】電極3a、3b間には抵抗R5,R6の直
列回路を接続し、該直列回路の中点を検出信号増幅用の
演算増幅器OP2の非反転入力端に接続してある。この
非反転入力端はコンデンサC1を介して上記定電圧回路
2の出力端のプラス極側にも接続してある。
A series circuit of resistors R5 and R6 is connected between the electrodes 3a and 3b, and a middle point of the series circuit is connected to a non-inverting input terminal of an operational amplifier OP2 for amplifying a detection signal. This non-inverting input terminal is also connected to the positive terminal side of the output terminal of the constant voltage circuit 2 via a capacitor C1.

【0012】演算増幅器OP2は非反転増幅器を構成
し、出力端と反転入力端との間には可変抵抗器VR1、
応答調整用のコンデンサC2からなる並列回路を接続し
てあり、この可変抵抗器VR1の抵抗値と、反転入力端
とグランド(基準)となる後述する演算増幅器OP3の
出力端との間に接続した抵抗R7とで利得が設定され、
該利得は可変抵抗器VR1で調整することができるよう
になっている。
The operational amplifier OP2 constitutes a non-inverting amplifier, and a variable resistor VR1 is connected between an output terminal and an inverting input terminal.
A parallel circuit composed of a response adjusting capacitor C2 is connected, and is connected between the resistance value of the variable resistor VR1 and the output terminal of an operational amplifier OP3, which will be described later, and serves as an inverting input terminal and ground (reference). The gain is set by the resistor R7,
The gain can be adjusted by the variable resistor VR1.

【0013】また一方上記抵抗R3,R4の直列回路の
中点と、電池電源1のマイナス極との間には抵抗R8を
介して可変抵抗器VR2とスイッチSW21の直列回路
を接続するとともに、可変抵抗器VR2,スイッチSW
21の直列回路にノイズ除去用コンデンサC3を接続
し、抵抗R8と可変抵抗器VR2の接続点に演算増幅器
OP3の非反転入力端を接続してある。
On the other hand, a series circuit of a variable resistor VR2 and a switch SW21 is connected between a middle point of the series circuit of the resistors R3 and R4 and the minus pole of the battery power supply 1 via a resistor R8. Resistor VR2, switch SW
The noise removing capacitor C3 is connected to the series circuit 21 and the non-inverting input terminal of the operational amplifier OP3 is connected to the connection point between the resistor R8 and the variable resistor VR2.

【0014】この演算増幅器OP3は、ボルテージフォ
ロアの非反転増幅器を構成し、非反転入力端の入力電圧
と、出力電圧とが等しく、その出力端を抵抗R7を介し
て上記演算増幅器OP2の反転入力端に接続し、演算増
幅器OP2のグランドの電位を出力端の電位に設定する
ようになっている。
The operational amplifier OP3 forms a non-inverting amplifier of a voltage follower. The input voltage at the non-inverting input terminal is equal to the output voltage, and the output terminal is connected to the inverting input terminal of the operational amplifier OP2 via a resistor R7. And the potential of the ground of the operational amplifier OP2 is set to the potential of the output terminal.

【0015】上記スイッチSW21はアルカリ度合測定
開始用スイッチSW2のオン/オフに連動してオン/オ
フするスイッチであって、演算増幅器OP2の入力電圧
の切換手段を構成する。
The switch SW21 is a switch that is turned on / off in conjunction with the on / off of the alkalinity measurement start switch SW2, and constitutes switching means for the input voltage of the operational amplifier OP2.

【0016】表示回路4は5つのコンパレータCP1〜
CP5、このコンパレータCP1〜CP5の出力端と定
電圧回路2の出力端のプラス極との間に限流抵抗R11
〜R15を介して接続された表示手段を構成する発光ダ
イオードL1〜L5等から構成されている。そして上記
定電圧回路2の出力端のプラス極と、上記抵抗R3,R
4の直列回路の中点との間に同一抵抗値の抵抗R16〜
R21の直列回路からなる分圧回路を接続し、抵抗R2
1と抵抗R20との接続点の分圧電圧をコンパレータC
P1の反転入力端に基準電圧として接続し、また抵抗R
20と抵抗R19との接続点の分圧電圧をコンパレータ
CP2の反転入力端に基準電圧として接続し、更に抵抗
R19と抵抗R18との接続点の分圧電圧をコンパレー
タCP3の反転入力端に基準電圧として接続し、同様に
抵抗R18と抵抗R17との接続点の分圧電圧をコンパ
レータCP4の反転入力端に基準電圧として接続し、更
に抵抗R17と抵抗R16との接続点の分圧電圧をコン
パレータCP5の反転入力端に基準電圧として接続して
おり、コンパレータCP1の基準電圧からコンパレータ
CP5の基準電圧までを順次段階的に高めてある。
The display circuit 4 has five comparators CP1 to CP1.
CP5, a current limiting resistor R11 between the output terminals of the comparators CP1 to CP5 and the positive terminal of the output terminal of the constant voltage circuit 2
, R1 to L5, etc., which constitute display means connected through R15 to R15. The positive pole at the output terminal of the constant voltage circuit 2 and the resistors R3 and R
4 and the middle point of the series circuit.
A voltage dividing circuit consisting of a series circuit of R21 is connected, and a resistor R2
The divided voltage at the connection point between the resistor 1 and the resistor R20 is determined by the comparator C
Connected as a reference voltage to the inverting input terminal of P1 and a resistor R
The divided voltage at the connection point between the resistor R20 and the resistor R19 is connected to the inverting input terminal of the comparator CP2 as a reference voltage, and the divided voltage at the connection point between the resistor R19 and the resistor R18 is connected to the inverting input terminal of the comparator CP3. Similarly, the divided voltage at the connection point between the resistors R18 and R17 is connected as a reference voltage to the inverting input terminal of the comparator CP4, and the divided voltage at the connection point between the resistors R17 and R16 is compared with the comparator CP5. Are connected as a reference voltage, and the reference voltage of the comparator CP1 to the reference voltage of the comparator CP5 are sequentially increased.

【0017】一方コンパレータCP1〜CP5の非反転
入力端には、夫々抵抗R22〜R26を介して上記演算
増幅器OP2の出力端を接続してあり、これら抵抗R2
2〜R26は同じ抵抗値のものが使用されている。
On the other hand, the non-inverting input terminals of the comparators CP1 to CP5 are connected to the output terminals of the operational amplifier OP2 via resistors R22 to R26, respectively.
2 to R26 have the same resistance value.

【0018】図2は本発明水質チェッカ回路を用いた水
質チェッカの外観を示すものであって、樹脂成形品から
なるハウジング5は図1で示す回路及び電池電源1を内
装するとともに、外面にスイッチSW1及びSW2の操
作部や表示回路4の発光ダイオードL1〜L5の発光部
が露設された本体部6と、本体部6の前部から前方に突
出するように形成された、先端部に一対の電極3a,3
bからなるセンサ部が設けられているヘッド部7とから
構成されている。
FIG. 2 shows the appearance of a water quality checker using the water quality checker circuit of the present invention. A housing 5 made of a resin molded product houses the circuit shown in FIG. The main body 6 is provided with the light emitting portions of the light emitting diodes L1 to L5 of the display circuit 4 and the operating portion of the SW1 and SW2, and a pair of the front end portion formed so as to protrude forward from the front portion of the main body portion 6. Electrodes 3a, 3
and a head section 7 provided with a sensor section made of b.

【0019】このハウジング5は外因性内分泌撹乱化学
物質(環境ホルモン)を含まない材質にて形成すること
が好ましく、例えばABS樹脂等のような樹脂成形品に
て形成される。
The housing 5 is preferably formed of a material that does not contain an exogenous endocrine disrupting chemical substance (environmental hormone), and is formed of a resin molded product such as an ABS resin.

【0020】またヘッド部7は前後方向に長い円筒状に
形成されており、その内部の中空部は後端側にて本体部
6内に連通し、前端側が前方に向けて開口している。こ
こで、ヘッド部7の前端部には、図4に示すように、開
口の周縁の全周に亘って、前方に突出すると共にヘッド
部7の外径寸法よりも小さい外径寸法を有する円筒状の
嵌合リブ8が設けられており、この嵌合リブ8の外周面
には全周に亘って嵌合凹部9が凹設されると共に、嵌合
凹部9よりも前端側は嵌合凹部9よりも外周側に突出し
た嵌合凸部10として形成されている。
The head portion 7 is formed in a cylindrical shape that is long in the front-rear direction. The hollow portion inside the head portion 7 communicates with the inside of the main body 6 at the rear end side, and the front end side is opened forward. As shown in FIG. 4, the front end of the head 7 has a cylindrical shape that projects forward and has an outer diameter smaller than the outer diameter of the head 7 over the entire periphery of the opening. The fitting rib 8 is provided, and a fitting recess 9 is formed on the outer peripheral surface of the fitting rib 8 over the entire circumference. 9 are formed as fitting projections 10 protruding further to the outer peripheral side.

【0021】ヘッド部7の先端部には、ヘッド部7の内
外の水密性を確保すると共に端子電極3a,3bを固定
するための固定部材11が装着されている。固定部材1
1は環境ホルモンを含まない材質にて形成することが好
ましく、例えばABS樹脂等のような樹脂成形品にて形
成されるものであり、円柱状に形成された係止部12の
前端側に係止部12よりも小径の円筒状の突出部13を
形成し、係止部12の後端側に係止部12よりも小径の
円筒状の挿入部14を形成したものである。
A fixing member 11 for securing watertightness inside and outside of the head portion 7 and fixing the terminal electrodes 3a and 3b is attached to a tip portion of the head portion 7. Fixing member 1
Numeral 1 is preferably formed of a material that does not contain environmental hormones, for example, is formed of a resin molded product such as ABS resin or the like, and is engaged with the front end side of the locking portion 12 formed in a cylindrical shape. A cylindrical projection 13 having a diameter smaller than that of the stopper 12 is formed, and a cylindrical insertion portion 14 having a diameter smaller than that of the locking part 12 is formed on the rear end side of the locking part 12.

【0022】このとき突出部13には前方に開口する前
側凹部15が形成され、挿入部14には後方に開口する
後側凹部22が形成されているものであり、この前側凹
部15と後側凹部22とは係止部12によって仕切られ
ている。
At this time, the protruding portion 13 is formed with a front recess 15 opening forward, and the insertion portion 14 is formed with a rear recess 22 opening rearward. The concave portion 22 is partitioned by the locking portion 12.

【0023】またこの係止部12には、前側凹部15と
後側凹部22とを連通する二つの挿通孔16が形成され
ている。また、固定部材11の挿入部14の外周面に
は、全周に亘る凹溝17が形成されている。
The engaging portion 12 has two insertion holes 16 communicating the front concave portion 15 and the rear concave portion 22. Further, a concave groove 17 is formed on the entire outer periphery of the insertion portion 14 of the fixing member 11.

【0024】この固定部材11は、図2に示すように挿
入部14をハウジング5のヘッド部7の前端開口から挿
入することによりヘッド部7の前端に取り付けられるも
のであり、このとき挿入部14にOリング18を取着す
ることにより挿入部14の外面とヘッド部7の内面との
間の水密性を確保することができる。
The fixing member 11 is attached to the front end of the head portion 7 by inserting the insertion portion 14 from the front end opening of the head portion 7 of the housing 5 as shown in FIG. The watertightness between the outer surface of the insertion portion 14 and the inner surface of the head portion 7 can be ensured by attaching the O-ring 18 to the O-ring 18.

【0025】また更に挿入部14の外面とヘッド部7の
内面との間の隙間に接着剤を充填してヘッド部7と固定
部材11とを接着することにより、固定部材11をヘッ
ド部7に対して強固に固定すると共に挿入部14の外面
とヘッド部7の内面との間の水密性を更に向上すること
ができる。
Further, the gap between the outer surface of the insertion portion 14 and the inner surface of the head portion 7 is filled with an adhesive, and the head portion 7 and the fixing member 11 are adhered to each other. On the other hand, it can be firmly fixed and the watertightness between the outer surface of the insertion portion 14 and the inner surface of the head portion 7 can be further improved.

【0026】ヘッド部7の中空部内には二本のリード線
19a,19bが配設されており、各リード線19a,
19bの後端部はハウジング5の本体部6に引き出され
て制御部に接続され、前端部は固定部材11に固定され
ている。また二本のリード線19a,19bの先端には
それぞれ電極3a,3bが接続されている。
Two lead wires 19a and 19b are provided in the hollow portion of the head portion 7, and each of the lead wires 19a and 19b is provided.
The rear end of 19 b is pulled out to the main body 6 of the housing 5 and connected to the control unit, and the front end is fixed to the fixing member 11. Electrodes 3a and 3b are connected to the tips of the two lead wires 19a and 19b, respectively.

【0027】ここで、リード線19a,19bは固定部
材11の係止部12の挿通孔16に挿通されて後端側が
挿入部14の後側凹部22内から後端開口を介して固定
部材11の後方に引き出されている。またリード線19
a,19bの先端の末端部には挿通孔16の内径よりも
大きい球状の瘤部20が形成されており、この瘤部20
によってリード線19a,19bの先端は突出部13の
前側凹部15内において係止部12の前面側に係止され
ている。このリード線19a,19bの先端の瘤部20
にはそれぞれ線状の電極3a,3bの後端が埋設されて
おり、これによりリード線19a,19bの先端には電
極3a,3bが接続されている。各電極3a,3bは先
端側は固定部材11の突出部13の前側凹部15の開口
から前方に突出するように配設されている。
Here, the lead wires 19a and 19b are inserted into the insertion holes 16 of the locking portions 12 of the fixing member 11, and the rear end side of the fixing members 11 is inserted from the rear recess 22 of the insertion portion 14 through the rear end opening. Has been pulled out behind. Lead wire 19
A spherical nodule 20 larger than the inside diameter of the insertion hole 16 is formed at the distal end of the tip of each of the a and 19b.
As a result, the tips of the lead wires 19 a and 19 b are locked on the front side of the locking portion 12 in the front recess 15 of the protruding portion 13. The bump 20 at the tip of the lead wires 19a, 19b
Are embedded with the rear ends of the linear electrodes 3a and 3b, respectively, whereby the electrodes 3a and 3b are connected to the front ends of the lead wires 19a and 19b. Each of the electrodes 3 a and 3 b is disposed such that the distal end protrudes forward from the opening of the front recess 15 of the protrusion 13 of the fixing member 11.

【0028】また固定部材11の挿入部14の後側凹部
22内には封止材21が充填されており、これにより固
定部材11の挿入部14の後側凹部22内においてリー
ド線19a,19bが固定されている。また固定部材1
1の突出部13の前側凹部15内にも封止材23が充填
されており、これによりこれ固定部材11の突出部13
の前側凹部15内において電極3a,3bが固定されて
いる。また、これらの封止材23,19によって、固定
部材11の前端側と後端側との間の水密性が確保され
る。
The sealing material 21 is filled in the rear concave portion 22 of the insertion portion 14 of the fixing member 11, so that the lead wires 19a, 19b are formed in the rear concave portion 22 of the insertion portion 14 of the fixing member 11. Has been fixed. Fixing member 1
The sealing material 23 is also filled in the front recess 15 of the first protrusion 13, whereby the protrusion 13 of the fixing member 11 is
The electrodes 3a and 3b are fixed in the front concave portion 15 of FIG. Further, the sealing members 23 and 19 ensure watertightness between the front end side and the rear end side of the fixing member 11.

【0029】一対の電極3a,3bは、一方の電極3b
が白金線、他方の電極3aが銀線にて形成されており、
この電極3a,3bによって、センサ部が構成されてい
る。各電極3a,3bは後端側は固定部材11の突出部
13の前側凹部15内において封止材23内に埋設され
ている埋設部として形成され、前端側はこの封止材23
から前方に向けて突出する検知部位として形成されてい
る。
The pair of electrodes 3a and 3b are connected to one electrode 3b
Is formed of a platinum wire, the other electrode 3a is formed of a silver wire,
The electrodes 3a and 3b constitute a sensor unit. Each of the electrodes 3a and 3b is formed as a buried portion embedded in the sealing material 23 in the front recess 15 of the protrusion 13 of the fixing member 11 on the rear end side, and the sealing material 23 is formed on the front end side.
Is formed as a detection portion projecting forward from the front.

【0030】銀線からなる電極3aには検知端子部7の
表面のみに塩化銀被膜が形成され、埋設部の表面には塩
化銀被膜は形成されていないものであり、このため、電
極3aとリード線19aとの接続部には塩化銀被膜は形
成されることがなく、電極3aとリード線19aとの電
気的接続が塩化銀被膜によって阻害されることがないも
のである。
The electrode 3a composed of a silver wire has a silver chloride film formed only on the surface of the detection terminal portion 7, and has no silver chloride film formed on the surface of the buried portion. No silver chloride coating is formed at the connection with the lead wire 19a, and the electrical connection between the electrode 3a and the lead wire 19a is not hindered by the silver chloride coating.

【0031】更に、ヘッド部7の先端には、固定部材1
1及び電極3a,3bの検知端子部7を覆うようにキャ
ップ体24が設けられ、これにより検知端子部7の保護
が行なわれる。このキャップ体24は図3に示すよう
に、前端側が閉塞すると共に後端側が開口した有底円筒
状に形成されており、その外径寸法はヘッド部7の外径
寸法と略同一に形成される。またキャップ体24の後端
部は、内径寸法が前端側よりも大きくかつ固定部材11
の係止部12の外径と略同一の寸法に形成された、被嵌
合リブ25として形成されており、この被嵌合リブ25
の後端部の内周面には全周に亘って、ヘッド部7の嵌合
リブ8の嵌合凸部10に合致する被嵌合凹部26が形成
されると共に、この被嵌合凹部26よりも更に後端側は
被嵌合凹部26よりも内周側に突出した、嵌合リブ8の
嵌合凹部9に合致する被嵌合凸部27として形成されて
いる。そしてキャップ体24の被嵌合リブ25を固定部
材11の係止部12の外周側からヘッド部7の嵌合リブ
8の外周側にかけて配置し、嵌合凹部9と被嵌合凸部2
7とを嵌合させると共に嵌合凸部10と被嵌合凹部26
とを嵌合させることにより、キャップ体24がヘッド部
7の前端に取り付けられるものであり、このとき嵌合リ
ブ8と被嵌合リブ25との間の隙間に接着剤を充填して
キャップ体24とヘッド部7とを接着することにより、
キャップ体24をヘッド部7に対して強固に固定すると
共に嵌合リブ8と被嵌合リブ25との間の水密性を確保
することができるものである。
Further, a fixing member 1 is attached to the tip of the head 7.
A cap body 24 is provided so as to cover the detection terminals 7 of the electrodes 1 and the electrodes 3a and 3b, thereby protecting the detection terminals 7. As shown in FIG. 3, the cap body 24 is formed in a closed-end cylindrical shape having a closed front end and an open rear end. The outer diameter of the cap 24 is substantially the same as the outer diameter of the head 7. You. The rear end of the cap body 24 has a larger inner diameter than the front end and
Is formed as a fitted rib 25 having substantially the same size as the outer diameter of the locking portion 12 of the fitting section 12.
On the inner peripheral surface of the rear end portion, a fitting concave portion 26 that matches the fitting convex portion 10 of the fitting rib 8 of the head portion 7 is formed over the entire circumference, and the fitted concave portion 26 is formed. Further, the rear end side is formed as a fitting convex portion 27 that protrudes inward from the fitting concave portion 26 and that matches the fitting concave portion 9 of the fitting rib 8. Then, the fitting rib 25 of the cap body 24 is arranged from the outer peripheral side of the locking portion 12 of the fixing member 11 to the outer peripheral side of the fitting rib 8 of the head 7, and the fitting concave portion 9 and the fitting convex portion 2 are arranged.
7 and the fitting projection 10 and the fitting recess 26.
The cap body 24 is attached to the front end of the head part 7 by filling the gap between the fitting rib 8 and the fitted rib 25 with an adhesive. By bonding the head 24 and the head 7,
The cap body 24 can be firmly fixed to the head portion 7 and the water tightness between the fitting rib 8 and the fitted rib 25 can be ensured.

【0032】このキャップ体24には、二つの平行並列
なスリット状の開口部28が形成されており、この開口
部28により、キャップ体24の内側と外側とが連通さ
れている。この開口部28はキャップ体24の側面から
前端面を通って反対側の側面に亘るように形成されてい
る。またキャップ体24には各開口部28の両端部に、
この開口部28と連通すると共にキャップ体24の内側
と外側とを連通する連通孔29が形成されており、この
連通孔29は各開口部28の幅よりも大径に形成されて
いる。
The cap body 24 is formed with two parallel and parallel slit-shaped openings 28, and the inside and outside of the cap body 24 are communicated by the openings 28. The opening 28 is formed to extend from the side surface of the cap body 24 to the opposite side surface through the front end surface. In addition, the cap body 24 has both ends of each opening 28,
A communication hole 29 communicating with the opening 28 and communicating the inside and the outside of the cap body 24 is formed. The communication hole 29 is formed to have a diameter larger than the width of each opening 28.

【0033】このキャップ体24のスリット状の開口部
28は、水質の測定時にキャップ体24の内側に水道水
等の検出対象の液体を侵入させて電極2の検知端子部7
をこの液体に浸漬させたり、水質の測定後にキャップ体
24の内側から液体を排出したりするためのものであ
る。
The slit-shaped opening 28 of the cap body 24 allows a liquid to be detected such as tap water to enter the inside of the cap body 24 when water quality is measured, thereby enabling the detection terminal 7 of the electrode 2 to be detected.
Is to be immersed in the liquid or to discharge the liquid from the inside of the cap body 24 after measuring the water quality.

【0034】また連通孔6は水質の測定時にキャップ体
24の内側から空気を排出してキャップ体24の内側に
検出対象の液体がスムーズに侵入するようにし、あるい
は水質の測定後にキャップ体24の内側に空気を侵入さ
せてキャップ体24の内側から液体がスムーズに排出さ
れるようにするためのものである。
The communication hole 6 discharges air from the inside of the cap body 24 at the time of measuring the water quality so that the liquid to be detected can smoothly enter the inside of the cap body 24, or the water of the cap body 24 is measured after measuring the water quality. This is to allow air to enter the inside so that the liquid is smoothly discharged from the inside of the cap body 24.

【0035】次に本実施形態の水質チェッカ回路の動作
について説明する。
Next, the operation of the water quality checker circuit of this embodiment will be described.

【0036】まず水道水の塩素濃度をチェックする場合
には、スイッチSW1をオンして、ヘッド部7を被検知
対象液である水道水に浸ける。水道水に漬けられたキャ
ップ体24内の電極3a、3b間には塩素濃度に応じて
起電圧が発生する。この場合電極3aがプラス極となっ
て、起電圧によって抵抗R6には電圧が発生し、この電
圧が検出信号でとして演算増幅器OP2に非反転入力端
に入力され、非反転増幅される。
First, when checking the chlorine concentration of tap water, the switch SW1 is turned on and the head section 7 is immersed in tap water which is a liquid to be detected. An electromotive voltage is generated between the electrodes 3a and 3b in the cap body 24 immersed in tap water according to the chlorine concentration. In this case, the electrode 3a becomes a positive pole, and a voltage is generated in the resistor R6 by the electromotive voltage, and this voltage is input to the operational amplifier OP2 as a detection signal at the non-inverting input terminal and is amplified in a non-inverting manner.

【0037】一方定電圧回路2からの出力電圧が抵抗R
1と、抵抗R2とで分圧されて降圧され、抵抗R2の両
端電圧が演算増幅器OP1により非反転増幅される。こ
こで演算増幅器OP1の出力端と反転入両端に接続され
た抵抗R4、R3の抵抗値を、その中点に接続されてい
る接続ラインAの電圧が略抵抗R2の両端電圧に略等し
入力電圧となるように設定してある。
On the other hand, the output voltage from the constant voltage circuit 2 is equal to the resistance R
1 and a resistor R2, which are divided and stepped down, and the voltage across the resistor R2 is non-inverted and amplified by the operational amplifier OP1. Here, the resistance values of the resistors R4 and R3 connected to the output terminal and the inverting input terminal of the operational amplifier OP1 are set so that the voltage of the connection line A connected to the middle point thereof is substantially equal to the voltage of both ends of the resistor R2. It is set to be voltage.

【0038】またスイッチSW21がオフ状態であるた
め演算増幅器OP3では出力端の電圧が非反転入力端に
入力している電圧、つまり接続ラインAの電圧と等しい
電圧となる。従ってこの出力端の電位と、接続ラインA
の電位とが等しいため、演算増幅器OP2は可変抵抗器
VR1の抵抗値と、反転入力端と演算増幅器OP3の出
力端との間に接続した抵抗R7の抵抗値とで定まる利得
により、抵抗R6の両端に発生する検出信号電圧を増幅
する。
Since the switch SW21 is off, the voltage at the output terminal of the operational amplifier OP3 becomes the voltage input to the non-inverting input terminal, that is, the voltage of the connection line A. Therefore, the potential of this output terminal and the connection line A
, The operational amplifier OP2 has a gain determined by the resistance of the variable resistor VR1 and the resistance of the resistor R7 connected between the inverting input terminal and the output terminal of the operational amplifier OP3. The detection signal voltage generated at both ends is amplified.

【0039】この演算増幅器OP3により増幅された検
出信号電圧は、表示回路4に入力されて、各コンパレー
タCP1〜CP5に設定される基準電圧と比較される。
そして検出信号電圧が基準電圧を越えていないコンパレ
ータにおいては、出力端を”L”レベルとし、出力端に
接続されている発光ダイオードに発光電流を流す。つま
り被測定水の塩素濃度が高ければ高い程、電極3a、3
b間に発生する起電圧が増加して、抵抗R6の両端電圧
が高くなり、そのため基準電圧を越えるコンパレータの
数が多くなり、発光する発光ダイオードの数が少なくな
る。従って発光ダイオードL1〜L5の全てが点灯して
いる場合には塩素濃度が略零に近くて水質評価は”良”
となり、その点灯数が少なくなればなるほど塩素濃度が
高く、水質評価は”悪”であることが分かる。またヘッ
ド部7を水道水に浸ける前に、スイッチSW1を投入し
た時点からコンデンサC1が充電されその充電に伴って
ゆっくりと発光ダイオードL1〜5が順次点灯し、この
点灯により動作チェックができることになるようになっ
ている。この動作は塩素濃度測定時のみで、後述するア
ルカリ度合の測定時ではこの点灯動作は無い。
The detection signal voltage amplified by the operational amplifier OP3 is input to the display circuit 4 and compared with reference voltages set in the comparators CP1 to CP5.
Then, in the comparator in which the detection signal voltage does not exceed the reference voltage, the output terminal is set to the “L” level, and the light emitting current flows through the light emitting diode connected to the output terminal. In other words, the higher the chlorine concentration of the water to be measured, the more the electrodes 3a, 3
The electromotive voltage generated during b increases, and the voltage across the resistor R6 increases. Therefore, the number of comparators exceeding the reference voltage increases, and the number of light emitting diodes that emit light decreases. Therefore, when all of the light emitting diodes L1 to L5 are lit, the chlorine concentration is nearly zero and the water quality evaluation is “good”.
It can be seen that the smaller the number of lightings, the higher the chlorine concentration and the worse the water quality evaluation. Also, before immersing the head unit 7 in tap water, the capacitor C1 is charged from the time when the switch SW1 is turned on, and the light-emitting diodes L1 to L5 are sequentially turned on slowly with the charging, so that the operation can be checked by this lighting. It has become. This operation is performed only when measuring the chlorine concentration, and is not performed when measuring the alkalinity described later.

【0040】さて本発明チェッカ回路は水道水の塩素濃
度以外に、アルカリ生成水のアルカリ度合もチェックす
る事ができるもので、この場合、スイッチSW2をオン
して検知対象液内に水道水の塩素濃度のチェックと同様
にヘッド部7を浸ければよい。
The checker circuit of the present invention can check not only the chlorine concentration of the tap water but also the degree of alkalinity of the alkali-produced water. In this case, the switch SW2 is turned on and the chlorine of the tap water is detected in the liquid to be detected. What is necessary is just to soak the head part 7 like the density check.

【0041】つまりスイッチSW2のオン動作に連動し
てスイッチSW21がオンし、演算増幅器OP3の非反
転入力端の電圧が、抵抗R8と可変抵抗器VR2で分圧
された電圧に切り換えられるため、塩素濃度測定時に比
して演算増幅器OP3の出力端の電位が接続ラインAの
電位よりもマイナス方向に低くなる。
That is, the switch SW21 is turned on in conjunction with the ON operation of the switch SW2, and the voltage at the non-inverting input terminal of the operational amplifier OP3 is switched to the voltage divided by the resistor R8 and the variable resistor VR2. The potential of the output terminal of the operational amplifier OP3 becomes lower in the minus direction than the potential of the connection line A as compared with the concentration measurement.

【0042】一方アルカリ測定時においては電極3a、
3b間の起電圧の方向が塩素濃度測定時とは反対方向と
なり、アルカリ度合が高くなれば成る程、演算増幅器O
P2の非反転入力端に入力する検出信号電圧は接続ライ
ンAの電位に対してマイナス方向に大きくなる。
On the other hand, during the alkali measurement, the electrodes 3a,
The direction of the electromotive voltage between the terminals 3b and 3b is opposite to the direction of the chlorine concentration measurement, and the higher the alkalinity, the higher the operational amplifier O
The detection signal voltage input to the non-inverting input terminal of P2 increases in the negative direction with respect to the potential of the connection line A.

【0043】ここでアルカリ度合が所定以上高い場合に
は発光ダイオードL1〜L5を全点灯させ、アルカリ度
合が所定度合より低い場合には全消灯させるように、上
記演算増幅器OP3の出力端の電位を、可変抵抗器VR
2により設定しておくことにより、アルカリ度合が所定
以上高い程と、演算増幅器OP3の非反転入力端に入力
する検出信号電圧が接続ラインAを基準としてマイナス
方向に増大するが、演算増幅器OP3の出力端の電位を
接続ラインAの電位よりもマイナス方向に十分大きくす
ることで、検知信号が入力する演算増幅器OP2の非反
転入力端と、グランドとの間の電位差が小さくなり、演
算増幅器OP2の出力端から出力される増幅された検出
信号電圧は接続ラインAの電圧に対して略近い値とな
る。これによって、アルカリ度合が所定以上ある場合に
は、全てのコンパレータCP1〜CP5の非反転入力端
の入力電圧が基準電圧を下回って、コンパレータCP1
〜CP5の出力が全て”L”レベルとなり、全発光ダイ
オードL1〜L5が点灯する。
Here, the potential at the output terminal of the operational amplifier OP3 is set so that the light emitting diodes L1 to L5 are fully turned on when the alkalinity is higher than a predetermined level, and are completely turned off when the alkalinity is lower than the predetermined level. , Variable resistor VR
2, the detection signal voltage input to the non-inverting input terminal of the operational amplifier OP3 increases in the negative direction with respect to the connection line A when the alkalinity is higher than a predetermined value. By making the potential of the output terminal sufficiently higher in the minus direction than the potential of the connection line A, the potential difference between the non-inverting input terminal of the operational amplifier OP2 to which the detection signal is input and the ground is reduced, and the potential of the operational amplifier OP2 is reduced. The amplified detection signal voltage output from the output terminal has a value substantially close to the voltage of the connection line A. As a result, when the alkalinity is equal to or higher than a predetermined value, the input voltages of the non-inverting input terminals of all the comparators CP1 to CP5 fall below the reference voltage, and the comparator CP1
To CP5 are all at "L" level, and all the light emitting diodes L1 to L5 are turned on.

【0044】また検知対象の液のアルカリ度合が低くな
れば成る程、マイナス方向の起電圧が小さくなり、演算
増幅器OP2の非反転入力端に入力するマイナス方向の
検出信号電圧は小さくなり、演算増幅器OP2の非反転
入力端と、グランドとの間の電位差が大きくなり、演算
増幅器OP3の出力端から出力される増幅された検出信
号電圧は大きくなる。従って被測定液のアルカリ度合が
高ければ高い程、非反転入力端の電圧が基準電圧を越え
るコンパレータの数が多くなって、発光する発光ダイオ
ードの数が少なくなる。つまり発光ダイオードL1〜L
5の全てが点灯している場合にはアルカリ度合が所定以
上あって水質評価が”良”で、逆にその点灯数が少なく
なればなるほどアルカリ度合が小さくなって水質評価
が”悪”となっていることが分かる。
Further, the lower the alkalinity of the liquid to be detected, the lower the electromotive voltage in the negative direction, and the lower the detection signal voltage in the negative direction input to the non-inverting input terminal of the operational amplifier OP2. The potential difference between the non-inverting input terminal of OP2 and the ground increases, and the amplified detection signal voltage output from the output terminal of the operational amplifier OP3 increases. Therefore, the higher the alkalinity of the liquid to be measured, the greater the number of comparators whose voltage at the non-inverting input terminal exceeds the reference voltage, and the less the number of light emitting diodes that emit light. That is, the light emitting diodes L1 to L
When all 5 are lit, the degree of alkalinity is higher than a predetermined level and the water quality evaluation is “good”. Conversely, the smaller the number of lights, the lower the degree of alkalinity and the water quality evaluation is “bad”. You can see that it is.

【0045】尚本実施形態では発光ダイオードL1〜L
5の点灯数で水質評価を表示するようになっているが、
液晶表示器等を用いて表示するようにしても良い。
In this embodiment, the light emitting diodes L1 to L
Although the water quality evaluation is displayed with the number of lights of 5,
The information may be displayed using a liquid crystal display or the like.

【0046】[0046]

【発明の効果】請求項1の発明は、電源と、異種の金属
により構成され、検知対象の液中に浸けられたときに電
圧を発生して検知信号として出力する一対の電極と、塩
素濃度の検知対象の液中に浸けたときに起電圧のマイナ
ス側となり、アルカリ度合の検知対象の液中に浸けたと
きに起電圧のプラス側となる一方の電極を接続する接続
ラインの電位を上記電源のマイナスグランドから見て一
定の電位に保持する手段と、上記検知信号を非反転入力
端に入力し、出力端と反転入力端に接続した抵抗と反転
入力端とグランドとの間に接続した抵抗とで定まる利得
で検知信号を非反転増幅する信号増幅用の演算増幅器
と、上記電源のプラス極と上記接続ラインとの間に接続
された複数の抵抗の直列回路によって構成される分圧回
路から出力される複数の異なる分圧出力に対応して設け
られて、異なる分圧出力により基準電圧が夫々設定さ
れ、該基準電圧と上記演算増幅器から出力される検知信
号電圧とを比較する複数のコンパレータと、該各コンパ
レータに対応して設けられて各コンパレータの出力端と
上記電源との間に接続され、上記対応するコンパレータ
の出力に応じて駆動され、検知結果を表示する表示手段
とを備えるとともに、上記演算増幅器のグランドの電位
を塩素濃度測定時には上記接続ラインの電位とし、アル
カリ度合測定時には上記接続ラインの電位よりもマイナ
ス方向に低く切換設定する手段を備えて測定するアルカ
リ度合が所定以上高い場合から所定以下に至るまでと測
定する塩素濃度が略零の場合から所定濃度以上に至るま
での上記演算増幅器の検知信号電圧の変化が略同じとな
るように上記演算増幅器の利得を設定したので、水道水
の塩素濃度の略零の場合から所定濃度に至るまでの水質
の評価表示と、アルカリ生成水などアルカリ度合の所定
以上から所定以下に至るまでの水質の評価表示とが同じ
表示手段により行うことができ、しかもコンパレータ等
を切替えることなく行えるため、同一の電極と簡単な回
路構成により塩素濃度の測定と、アルカリ度合の測定と
が行える水質チェッカ回路を実現できるという効果があ
る。
According to the first aspect of the present invention, there is provided a power supply, a pair of electrodes formed of different kinds of metals, and generates a voltage when immersed in a liquid to be detected and outputs the voltage as a detection signal; The potential of the connection line connecting one of the electrodes that is on the negative side of the electromotive voltage when immersed in the liquid to be detected and becomes the positive side of the electromotive voltage when immersed in the liquid for the alkalinity is A means for maintaining a constant potential when viewed from the negative ground of the power supply, and the detection signal is input to the non-inverting input terminal, and is connected between the inverting input terminal and the resistor connected to the output terminal and the inverting input terminal. A signal amplification operational amplifier that non-inverts and amplifies a detection signal with a gain determined by a resistor, and a voltage divider circuit configured by a series circuit of a plurality of resistors connected between the positive pole of the power supply and the connection line Output from A plurality of comparators are provided corresponding to the different divided voltage outputs, the reference voltages are respectively set by the different divided voltage outputs, and the comparators compare the reference voltage with the detection signal voltage output from the operational amplifier. A display means for displaying a detection result, which is provided between the output terminal of each comparator and the power supply, is driven in accordance with the output of the corresponding comparator, and is provided corresponding to the comparator; The potential of the ground is set to the potential of the connection line at the time of measuring the chlorine concentration, and at the time of measuring the alkalinity, there is provided a means for switching and setting the potential in the minus direction to be lower than the potential of the connection line. And the change of the detection signal voltage of the operational amplifier from the case where the measured chlorine concentration is substantially zero to the case where the measured chlorine concentration exceeds a predetermined concentration. Since the gain of the operational amplifier is set to be substantially the same, an evaluation display of water quality from a case where the chlorine concentration of tap water is substantially zero to a predetermined concentration, and a case where the alkalinity such as alkali-produced water is higher than a predetermined level. Since the same display means can be used to evaluate and display water quality up to a predetermined level without switching comparators, measurement of chlorine concentration and measurement of alkalinity with the same electrode and simple circuit configuration There is an effect that a water quality checker circuit capable of performing the above can be realized.

【0047】請求項2の発明は、請求項1の発明におい
て、上記接続ラインの電位を一定に保持する手段を、上
記電源の電圧を所定電圧に降圧した電圧を非反転入力端
に入力して略同じ電圧を出力に発生するように利得が設
定された非反転増幅器を構成する別の演算増幅器により
構成し、該別の演算増幅器の出力端に上記接続ラインを
接続してあるので、検知信号電圧のグランドの電位を一
定に保持する回路が簡単に実現できる。
According to a second aspect of the present invention, in the first aspect, the means for maintaining the potential of the connection line constant is provided by inputting a voltage obtained by reducing the voltage of the power supply to a predetermined voltage to a non-inverting input terminal. Since another operational amplifier constituting a non-inverting amplifier whose gain is set to generate substantially the same voltage at the output is formed, and the connection line is connected to the output terminal of the other operational amplifier, the detection signal A circuit for keeping the voltage ground potential constant can be easily realized.

【0048】請求項3の発明は、請求項1又は2の発明
において、上記切換手段として、反転入力端と出力端が
接続された他の演算増幅器と、該他の演算増幅器の非反
転入力端に入力する電圧を上記接続ラインの電圧とこの
接続ラインよりも低い電圧とに切り換える電圧切換手段
とから構成し、上記他の演算増幅器の出力端の電位を上
記信号増幅用の演算増幅器のグランド電位としたので、
演算増幅器と、簡単な電圧切換手段とで、塩素濃度測定
時とアルカリ度合の測定時とを同じ信号増幅用の演算増
幅器と、コンパレータと、同じ表示手段によって、同じ
ように水質の評価表示が行える回路を実現できる。
According to a third aspect of the present invention, in the first or second aspect of the invention, as the switching means, another operational amplifier having an inverting input terminal and an output terminal connected thereto, and a non-inverting input terminal of the other operational amplifier. And voltage switching means for switching the voltage inputted to the connection line between the voltage of the connection line and the voltage lower than the connection line, and setting the potential of the output terminal of the other operational amplifier to the ground potential of the operational amplifier for signal amplification. So,
With the operational amplifier and the simple voltage switching means, the water quality evaluation display can be performed in the same way by the same operational amplifier for signal amplification, the comparator, and the same display means when measuring the chlorine concentration and when measuring the alkalinity degree. A circuit can be realized.

【0049】請求項4の発明は、請求項1乃至3の何れ
かの発明において、上記各コンパレータの非反転入力端
に上記信号増幅用の演算増幅器からの検知信号電圧を、
上記各コンパレータの反転入力端に基準電圧を夫々入力
し、基準電圧より入力する検知信号電圧が低いコンパレ
ータをオンして上記表示手段を動作させるので、塩素濃
度測定時に測定前の動作チェックができるという効果が
ある。
According to a fourth aspect of the present invention, in any one of the first to third aspects of the present invention, a detection signal voltage from the operational amplifier for signal amplification is supplied to a non-inverting input terminal of each of the comparators.
A reference voltage is input to the inverting input terminal of each of the comparators, and a comparator having a lower detection signal voltage than the reference voltage is turned on to operate the display means, so that it is possible to check the operation before measurement when measuring the chlorine concentration. effective.

【0050】請求項5の発明では、請求項1乃至4の何
れかの発明において、上記電源が電池電源を安定化する
定電圧回路の出力により構成してあるので、電池電源に
よって動作する水質チェッカ回路を提供できる。
According to a fifth aspect of the present invention, in any one of the first to fourth aspects of the present invention, the power supply is constituted by an output of a constant voltage circuit for stabilizing the battery power supply. Circuit can be provided.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施形態の回路図である。FIG. 1 is a circuit diagram of one embodiment of the present invention.

【図2】同上を使用した水質チェッカの側面図である。FIG. 2 is a side view of a water quality checker using the above.

【図3】(a)は同上を使用した水質チェッカのヘッド
部の一部省略せる拡大断面図である。(b)は同上を使
用した水質チェッカのヘッド部の一部省略せる拡大側面
図である。
FIG. 3A is an enlarged cross-sectional view of a water quality checker using the same as above, in which a part of a head portion is omitted. (B) is an enlarged side view which can omit a part of head part of a water quality checker using the same as the above.

【符号の説明】[Explanation of symbols]

1 電池電源 2 定電圧回路 3a、3b 電極 4 表示回路 OP1〜OP3 演算増幅器 SW1、SW2、SW21 スイッチ CP1〜CP5 コンパレータ L1〜L5 発光ダイオード DESCRIPTION OF SYMBOLS 1 Battery power supply 2 Constant voltage circuit 3a, 3b electrode 4 Display circuit OP1 to OP3 Operational amplifier SW1, SW2, SW21 Switch CP1 to CP5 Comparator L1 to L5 Light emitting diode

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】電源と、異種の金属により構成され、検知
対象の液中に浸けられたときに電圧を発生して検知信号
として出力する一対の電極と、塩素濃度の検知対象の液
中に浸けたときに起電圧のマイナス側となり、アルカリ
度合の検知対象の液中に浸けたときに起電圧のプラス側
となる一方の電極を接続する接続ラインの電位を上記電
源のマイナスグランドから見て一定の電位に保持する手
段と、上記検知信号を非反転入力端に入力し、出力端と
反転入力端に接続した抵抗と反転入力端とグランドとの
間に接続した抵抗とで定まる利得で検知信号を非反転増
幅する信号増幅用の演算増幅器と、上記電源のプラス極
と上記接続ラインとの間に接続された複数の抵抗の直列
回路によって構成される分圧回路から出力される複数の
異なる分圧出力に対応して設けられて、異なる分圧出力
により基準電圧が夫々設定され、該基準電圧と上記演算
増幅器から出力される検知信号電圧とを比較する複数の
コンパレータと、該各コンパレータに対応して設けられ
て各コンパレータの出力端と上記電源との間に接続さ
れ、上記対応するコンパレータの出力に応じて駆動さ
れ、検知結果を表示する表示手段とを備えるとともに、
上記演算増幅器のグランドの電位を塩素濃度測定時には
上記接続ラインの電位とし、アルカリ度合測定時には上
記接続ラインの電位よりもマイナス方向に低く切換設定
する手段を備えて測定するアルカリ度合が所定以上高い
場合から所定以下に至るまでと測定する塩素濃度が略零
の場合から所定濃度以上に至るまでの上記演算増幅器か
ら出力する検知信号電圧の変化が略同じとなるように上
記演算増幅器の利得を設定したことを特徴とする水質チ
ェッカ回路。
1. A power source, a pair of electrodes made of different kinds of metals, and generating a voltage when immersed in a liquid to be detected and outputting the voltage as a detection signal; When viewed from the minus ground of the power supply, the potential of the connection line that connects one electrode that is on the minus side of the electromotive voltage when immersed and becomes the plus side of the electromotive voltage when immersed in the liquid to be detected for alkalinity is A means for maintaining a constant potential, and the detection signal is input to a non-inverting input terminal, and is detected by a gain determined by a resistor connected between the output terminal and the inverting input terminal and a resistor connected between the inverting input terminal and the ground. An operational amplifier for signal amplification for non-inverting amplification of a signal, and a plurality of different voltages output from a voltage dividing circuit configured by a series circuit of a plurality of resistors connected between a positive pole of the power supply and the connection line. For partial pressure output A plurality of comparators are provided corresponding to the respective comparators, and reference voltages are respectively set by different divided outputs, and a plurality of comparators are provided for comparing the reference voltage with a detection signal voltage output from the operational amplifier. And a display unit that is connected between the output terminal of each comparator and the power supply, is driven according to the output of the corresponding comparator, and displays a detection result.
When the potential of the ground of the operational amplifier is set to the potential of the connection line when measuring the chlorine concentration, and when measuring the alkalinity, there is provided a means for switching and setting the potential in the minus direction to be lower than the potential of the connection line. The gain of the operational amplifier was set so that the change in the detection signal voltage output from the operational amplifier from when the measured chlorine concentration was substantially zero to when the measured chlorine concentration reached the predetermined concentration or more was substantially the same. A water quality checker circuit, characterized in that:
【請求項2】上記接続ラインの電位を一定に保持する手
段を、上記電源の電圧を所定電圧に降圧した電圧を非反
転入力端に入力して略同じ電圧を出力に発生するように
利得が設定された非反転増幅器を構成する別の演算増幅
器により構成し、該別の演算増幅器の出力端に上記接続
ラインを接続して成ることを特徴とする請求項1記載の
水質チェッカ回路。
And a means for maintaining the potential of said connection line constant so that a voltage obtained by stepping down the voltage of said power supply to a predetermined voltage is inputted to a non-inverting input terminal so that substantially the same voltage is generated at an output. 2. The water quality checker circuit according to claim 1, wherein the circuit is constituted by another operational amplifier constituting the set non-inverting amplifier, and the connection line is connected to an output terminal of the another operational amplifier.
【請求項3】上記切換手段として、反転入力端と出力端
が接続された他の演算増幅器と、該他の演算増幅器の非
反転入力端に入力する電圧を上記接続ラインの電圧とこ
の接続ラインよりも低い電圧とに切り換える電圧切換手
段とから構成し、上記他の演算増幅器の出力端の電位を
上記信号増幅用の演算増幅器のグランド電位としたこと
を特徴とする請求項1又は2記載の水質チェッカ回路。
3. The switching means includes another operational amplifier having an inverting input terminal and an output terminal connected thereto, and a voltage input to a non-inverting input terminal of the other operational amplifier, the voltage of the connection line and the voltage of the connection line. 3. A voltage switching means for switching to a lower voltage, wherein the potential of the output terminal of the other operational amplifier is set to the ground potential of the operational amplifier for signal amplification. Water quality checker circuit.
【請求項4】上記各コンパレータの非反転入力端に上記
信号増幅用の演算増幅器からの検知信号電圧を、上記各
コンパレータの反転入力端に基準電圧を夫々入力し、基
準電圧より入力する検知信号電圧が低いコンパレータを
オンして上記表示手段を動作させることを特徴とする請
求項1乃至3の何れか記載の水質チェッカ回路。
4. A detection signal input from the operational amplifier for signal amplification to a non-inverting input terminal of each comparator, a reference voltage to an inverting input terminal of each comparator, and a detection signal input from the reference voltage. The water quality checker circuit according to any one of claims 1 to 3, wherein the display means is operated by turning on a comparator having a low voltage.
【請求項5】上記電源が電池電源を安定化する定電圧回
路の出力により構成して成ることを特徴とする請求項1
乃至4の何れか記載の記載の水質チェッカ回路。
5. The power supply according to claim 1, wherein said power supply comprises an output of a constant voltage circuit for stabilizing a battery power supply.
A water quality checker circuit according to any one of claims 1 to 4.
JP2001014866A 2001-01-23 2001-01-23 Water quality checker circuit Expired - Fee Related JP4658342B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (2)

Publication Number Publication Date
JP2002214220A true JP2002214220A (en) 2002-07-31
JP4658342B2 JP4658342B2 (en) 2011-03-23

Family

ID=18881497

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005047880A1 (en) * 2003-11-14 2005-05-26 Tanita Corporation Water examiner
WO2005080956A1 (en) * 2004-02-20 2005-09-01 Tanita Corporation Chlorometer
US7123019B2 (en) 2004-06-23 2006-10-17 Tanita Corporation Polarographic densitometer
JP2006317229A (en) * 2005-05-11 2006-11-24 Nikken System Kk Continuous monitoring method of water quality
JP2007057266A (en) * 2005-08-22 2007-03-08 Fis Inc Detector with temperature compensating function
JP2008078566A (en) * 2006-09-25 2008-04-03 Mitsubishi Materials Corp Manufacturing method of substrate for power module, substrate for power module, and power module
US7597789B2 (en) * 2004-05-21 2009-10-06 Tanita Corporation Oxidation-reduction potentiometer
US8025779B2 (en) 2003-11-14 2011-09-27 Tanita Corporation Water quality analyzer
JP2016114376A (en) * 2014-12-11 2016-06-23 国立大学法人横浜国立大学 Solid-state residual chlorine sensor and water meter having the same

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02309240A (en) * 1989-05-24 1990-12-25 Yokogawa Electric Corp Ph converter
JPH09105733A (en) * 1995-10-12 1997-04-22 Horiba Ltd Resistance conversion device
JPH10221285A (en) * 1997-01-31 1998-08-21 Horiba Ltd Measuring device for electric conductivity or ph
JP2002532716A (en) * 1998-12-16 2002-10-02 エンドレス ウント ハウザー コンダクタ ゲゼルシャフト フュア メス− ウント レーゲルテヒニク ミット ベシュレンクテル ハフツング ウント コンパニー Device for measuring ion concentration in measurement solution

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02309240A (en) * 1989-05-24 1990-12-25 Yokogawa Electric Corp Ph converter
JPH09105733A (en) * 1995-10-12 1997-04-22 Horiba Ltd Resistance conversion device
JPH10221285A (en) * 1997-01-31 1998-08-21 Horiba Ltd Measuring device for electric conductivity or ph
JP2002532716A (en) * 1998-12-16 2002-10-02 エンドレス ウント ハウザー コンダクタ ゲゼルシャフト フュア メス− ウント レーゲルテヒニク ミット ベシュレンクテル ハフツング ウント コンパニー Device for measuring ion concentration in measurement solution

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005047880A1 (en) * 2003-11-14 2005-05-26 Tanita Corporation Water examiner
US8025779B2 (en) 2003-11-14 2011-09-27 Tanita Corporation Water quality analyzer
WO2005080956A1 (en) * 2004-02-20 2005-09-01 Tanita Corporation Chlorometer
US7597789B2 (en) * 2004-05-21 2009-10-06 Tanita Corporation Oxidation-reduction potentiometer
US7123019B2 (en) 2004-06-23 2006-10-17 Tanita Corporation Polarographic densitometer
JP2006317229A (en) * 2005-05-11 2006-11-24 Nikken System Kk Continuous monitoring method of water quality
JP4652119B2 (en) * 2005-05-11 2011-03-16 日研システム株式会社 Water quality continuous monitoring method
JP2007057266A (en) * 2005-08-22 2007-03-08 Fis Inc Detector with temperature compensating function
JP4575861B2 (en) * 2005-08-22 2010-11-04 エフアイエス株式会社 Detector with temperature compensation function
JP2008078566A (en) * 2006-09-25 2008-04-03 Mitsubishi Materials Corp Manufacturing method of substrate for power module, substrate for power module, and power module
JP2016114376A (en) * 2014-12-11 2016-06-23 国立大学法人横浜国立大学 Solid-state residual chlorine sensor and water meter having the same

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