JP2002155211A5 - - Google Patents
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- JP2002155211A5 JP2002155211A5 JP2001137746A JP2001137746A JP2002155211A5 JP 2002155211 A5 JP2002155211 A5 JP 2002155211A5 JP 2001137746 A JP2001137746 A JP 2001137746A JP 2001137746 A JP2001137746 A JP 2001137746A JP 2002155211 A5 JP2002155211 A5 JP 2002155211A5
- Authority
- JP
- Japan
- Prior art keywords
- flame
- flame retardant
- retardant
- tables
- resin composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003063 flame retardant Substances 0.000 description 25
- 239000011342 resin composition Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 239000001205 polyphosphate Substances 0.000 description 5
- 229920000388 Polyphosphate Polymers 0.000 description 4
- 239000002313 adhesive film Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 235000011176 polyphosphates Nutrition 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920001225 Polyester resin Polymers 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 125000003010 ionic group Chemical group 0.000 description 2
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-N-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 description 1
- ZRIUUUJAJJNDSS-UHFFFAOYSA-N Ammonium phosphates Chemical group [NH4+].[NH4+].[NH4+].[O-]P([O-])([O-])=O ZRIUUUJAJJNDSS-UHFFFAOYSA-N 0.000 description 1
- 229920001276 Ammonium polyphosphate Polymers 0.000 description 1
- 239000004114 Ammonium polyphosphate Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N CTK2H8874 Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- YSRVJVDFHZYRPA-UHFFFAOYSA-N melem Chemical compound NC1=NC(N23)=NC(N)=NC2=NC(N)=NC3=N1 YSRVJVDFHZYRPA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
Description
【特許請求の範囲】
【請求項１】リンと窒素を含むノンハロゲン系難燃剤（Ｘ）と有機樹脂（Ｙ）を含有し、該有機樹脂（Ｙ）がポリエステル系樹脂及び／又は変性ポリエステル樹脂である難燃性樹脂組成物。
【請求項２】 前記難燃剤（Ｘ）がリン酸メラミン塩（下記式１）であることを特徴とする請求項１に記載の難燃性樹脂組成物。
【化１】
【請求項４】 前記ポリリン酸塩が、ポリリン酸メラミン複塩（下記式２）、ポリリン酸メラム複塩（下記式３）、ポリリン酸メレム複塩（下記式４）（式中ｎは２〜２０００の整数）から選択される少なくとも一種であることを特徴とする請求項３に記載の難燃性樹脂組成物。
【化２】
（ＮＨ4ＰＯ3）ｎ（式５）
＊）式中ｎは２〜２０００の整数
【請求項６】 前記有機樹脂（Ｙ）がイオン性基を導入された樹脂であることを特徴とする請求項１〜５いずれかに記載の難燃性樹脂組成物。
【請求項７】 基材上に請求項１〜６に記載の難燃性樹脂組成物のいずれかが積層されていることを特徴とする難燃性積層体。
【請求項８】 基材上に少なくとも難燃性中間層とその上に接着層とが設けられている難燃性積層体において、難燃性中間層が請求項１〜６に記載の難燃性樹脂組成物のいずれかであることを特徴とする難燃性積層体。
[Claims]
1. PhosphorusAnd nitrogenContains halogen-free flame retardant (X) and organic resin (Y)The organic resin (Y) is a polyester resin and / or a modified polyester resin.Flame retardant resin composition.
Claim2] AboveFlame retardants(X)Is a melamine phosphate (formula 1 below)1The flame-retardant resin composition as described in 2.
[Chemical 1]
Claim4] AboveThe polyphosphate is selected from melamine polyphosphate double salt (following formula 2), melam polyphosphate double salt (following formula 3), polyphosphate melem double salt (following formula 4) (where n is an integer of 2 to 2000) And at least one type of claim3The flame-retardant resin composition as described in 2.
[Chemical formula 2]
(NHFourPOThree)n(Formula 5)
*) Where n is an integer from 2 to 2000
[Claim 6] The flame retardant resin composition according to claim 1, wherein the organic resin (Y) is a resin into which an ionic group is introduced.
7. A flame retardant laminate, wherein any one of the flame retardant resin compositions according to claim 1 is laminated on a base material.
8. The flame retardant laminate according to claim 1, wherein the flame retardant intermediate layer is provided with at least a flame retardant intermediate layer and an adhesive layer thereon. A flame-retardant laminate, which is any of the heat-resistant resin compositions.
以下、表６〜表８に示す組成により同様にして、実施例２〜１２、比較例１〜２の難燃性接着性フィルムを作成した。得られた難燃性接着性フィルムの試験結果を表５〜表７に示す。ただし、配合比は固形分換算で表示した。 Hereinafter, the flame retardant adhesive films of Examples 2 to 12 and Comparative Examples 1 to 2 were similarly prepared using the compositions shown in Tables 6 to 8. The test results of the obtained flame- retardant adhesive film are shown in Tables 5 to 7. However, the compounding ratio was displayed in terms of solid content.
実施例１３〜２２、比較例３〜４、参考例１
実施例１と同様にして、実施例１３〜２２、比較例３〜４、参考例１を行った。結果は表１２〜１４に示す。
Examples 13-22, Comparative Examples 3-4, Reference Example 1
In the same manner as in Example 1, Examples 13 to 22, Comparative Examples 3 to 4, and Reference Example 1 were performed. The results are shown in Tables 12-14.
以下、表１８〜２３に示す組成により同様にして、実施例３５〜５６、比較例７〜１０、参考例２の難燃性接着性フィルムを作成した。得られた難燃性接着性フィルムの試験結果を表１８〜２３に示す。ただし、配合比は固形分換算で表示した。 Hereafter, the flame-retardant adhesive film of Examples 35-56 , Comparative Examples 7-10, and the reference example 2 was created similarly by the composition shown to Tables 18-23. The test results of the obtained flame- retardant adhesive film are shown in Tables 18-23. However, the compounding ratio was displayed in terms of solid content.
【０１１８】表１８〜２３において商標名他は前記各表と同じである。
【発明の効果】本発明は、リンを含むノンハロゲン系難燃剤（Ｘ）を有機樹脂（Ａ）に分散させた組成物であり、この難燃剤分散体を塗布又は積層することにより難燃性、発煙抑制効果に優れ、基材成形体又は基材フィルムとの密着性が良好な難燃性樹脂組成物を提供できる。また、有機樹脂にイオン性基を導入することにより、卓越した分散性を与えることができ、難燃性、密着性等の諸特性をさらに大きく向上させることができる。本発明の難燃性樹脂組成物を塗布又は積層することにより、安価で優れた難燃性積層体を提供するもので家電製品等の分野における高い要求品質に答えることができる。
In Tables 18 to 23, the trade names and the like are the same as those in the above tables.
The present invention is a composition in which a halogen-free flame retardant (X) containing phosphorus is dispersed in an organic resin (A), and the flame retardant dispersion is obtained by applying or laminating this flame retardant dispersion. It is possible to provide a flame retardant resin composition which is excellent in smoke generation suppression effect and has good adhesion to a substrate molded body or a substrate film. Further, by introducing an ionic group into the organic resin, excellent dispersibility can be given, and various properties such as flame retardancy and adhesion can be further improved. By coating or the product layer to Rukoto flame retardant resin composition of the present invention, it is possible to meet high quality requirements in the field, such as home appliances in intended to provide a flame retardant laminate with excellent inexpensive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2001137746A JP4967198B2 (en) | 2000-09-06 | 2001-05-08 | Flame retardant resin composition and flame retardant laminate coated or laminated with the same |
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000-270243 | 2000-09-06 | ||
| JP2000270244 | 2000-09-06 | ||
| JP2000270243 | 2000-09-06 | ||
| JP2000270244 | 2000-09-06 | ||
| JP2000270243 | 2000-09-06 | ||
| JP2000-270244 | 2000-09-06 | ||
| JP2001137746A JP4967198B2 (en) | 2000-09-06 | 2001-05-08 | Flame retardant resin composition and flame retardant laminate coated or laminated with the same |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2002155211A JP2002155211A (en) | 2002-05-28 |
| JP2002155211A5 true JP2002155211A5 (en) | 2009-07-23 |
| JP4967198B2 JP4967198B2 (en) | 2012-07-04 |
Family
ID=27344563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001137746A Expired - Lifetime JP4967198B2 (en) | 2000-09-06 | 2001-05-08 | Flame retardant resin composition and flame retardant laminate coated or laminated with the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4967198B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5138332B2 (en) * | 2007-10-09 | 2013-02-06 | 旭化成建材株式会社 | Flame retardant phenolic resin foam laminate and its manufacturing method |
| JP5138331B2 (en) * | 2007-10-09 | 2013-02-06 | 旭化成建材株式会社 | Flame retardant phenolic resin foam laminate and its manufacturing method |
| JP2009197123A (en) * | 2008-02-21 | 2009-09-03 | Nisshin Chem Ind Co Ltd | Fire-resistant additive |
| CN102131640B (en) * | 2009-09-10 | 2015-02-25 | 贝迪国际集团 | Flame retardant multi-layer label |
| JP2013049858A (en) * | 2012-10-11 | 2013-03-14 | Nisshin Chem Ind Co Ltd | Coating composition for vehicular interior material, and vehicular interior material |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000212419A (en) * | 1999-01-28 | 2000-08-02 | Toyobo Co Ltd | Polyester composition and molded product using the same |
-
2001
- 2001-05-08 JP JP2001137746A patent/JP4967198B2/en not_active Expired - Lifetime
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