JP2002102637A - Flue gas cleaning apparatus - Google Patents
Flue gas cleaning apparatusInfo
- Publication number
- JP2002102637A JP2002102637A JP2000299861A JP2000299861A JP2002102637A JP 2002102637 A JP2002102637 A JP 2002102637A JP 2000299861 A JP2000299861 A JP 2000299861A JP 2000299861 A JP2000299861 A JP 2000299861A JP 2002102637 A JP2002102637 A JP 2002102637A
- Authority
- JP
- Japan
- Prior art keywords
- exhaust gas
- water
- gas
- tank
- cleaning apparatus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Treating Waste Gases (AREA)
- Separation Of Particles Using Liquids (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】この発明は、焼却炉や各種燃
焼装置等から排出される排ガスを洗浄する排ガス洗浄装
置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an exhaust gas cleaning apparatus for cleaning exhaust gas discharged from an incinerator, various types of combustion equipment, and the like.
【0002】[0002]
【従来の技術】従来公知の排ガス洗浄装置は、気密に構
成された通気管の内部へ、洗浄水あるいは薬液をシャワ
ーして排ガスを接触させて洗浄したり、排ガスをトレー
の貯留水の中を通気させて洗浄している。また、充填物
を介して気液接触させることで排ガスを洗浄する装置も
知られている。2. Description of the Related Art A conventionally known exhaust gas cleaning apparatus cleans water by showering cleaning water or a chemical solution and bringing exhaust gas into contact with the inside of an airtight ventilation pipe, or washing exhaust gas in a tray stored water. It is aerated and cleaned. Further, there is also known an apparatus for cleaning exhaust gas by making gas-liquid contact through a filler.
【0003】[0003]
【発明が解決しようとする課題】しかし、従来公知の排
ガス洗浄装置は、限られた貯留水で排ガスを洗浄してい
るため、排ガスと貯留水を十分に気液接触させるために
は、気液接触塔を大きくして、接触時間を長くしなけれ
ばならないという問題があった。更に、貯留水を循環し
てシャワーリングする従来公知の排ガス洗浄装置は、貯
留水の温度が70〜80℃にも上昇し、該貯留水の温度
上昇により、排ガス中の有害成分の吸収も悪くなり、排
気に同伴する蒸気も多いという問題があった。本発明
は、これらの問題に鑑みなされたものであり、本発明の
課題は、排ガスを貯留水と短い塔で気液接触させるにも
拘わらず、排ガスの洗浄を十分行うことができる排ガス
洗浄装置を提供することにある。本発明の他の課題は、
貯留水を通過する排気ガス自体で該貯留水に十分な撹拌
を行わしめることができ、気液接触時間も長くすること
ができる排ガス洗浄装置を提供することにある。本発明
の他の課題は、貯留水を冷却することができ、排ガス中
の有害成分の吸収を多くし、排気に同伴する蒸気を少な
くすることができる排ガス洗浄装置を提供することにあ
る。However, the known exhaust gas cleaning apparatus cleans the exhaust gas with a limited amount of stored water. Therefore, in order to bring the exhaust gas and the stored water into sufficient gas-liquid contact, the gas-liquid There was a problem that the contact time had to be increased by enlarging the contact tower. Furthermore, in a conventionally known exhaust gas cleaning apparatus that circulates and showers stored water, the temperature of the stored water rises to 70 to 80 ° C., and due to the rise in the temperature of the stored water, absorption of harmful components in the exhaust gas is poor. Therefore, there is a problem that a large amount of steam accompanies the exhaust. The present invention has been made in view of these problems, and an object of the present invention is to provide an exhaust gas cleaning apparatus capable of sufficiently performing exhaust gas cleaning despite the fact that exhaust gas is brought into gas-liquid contact with stored water in a short tower. Is to provide. Another subject of the present invention is:
It is an object of the present invention to provide an exhaust gas cleaning apparatus capable of sufficiently agitating the stored water by the exhaust gas itself passing through the stored water and increasing the gas-liquid contact time. Another object of the present invention is to provide an exhaust gas cleaning device that can cool stored water, increase the absorption of harmful components in exhaust gas, and reduce the amount of steam accompanying exhaust gas.
【0004】[0004]
【課題を解決するための手段】上記課題を解決するため
の本発明の排ガス洗浄装置は、焼却炉等から排出される
排ガスを洗浄する排ガス洗浄装置において、該排ガス洗
浄装置は、水を貯留するタンクを有し、該タンクは、そ
の上方部分に上記排ガスが導入されるガス導入室及び排
気手段に接続されたガス吸引室を有し、上記ガス導入室
及びガス吸引室は、上記タンクの天板から垂下する仕切
り板により互いに区画されており、上記ガス導入室側の
貯留水の水位は、ガス吸引前は上記仕切り板の下端より
上でガス吸引時には上記仕切り板の下端より下になるよ
うに設けられ、上記タンクは、上記仕切り板から連続し
てガス吸引室側方向に伸びる上面誘導板と、上記仕切り
板の下端のさらに下方位置からガス吸引室側方向に伸び
る下面誘導板を有し、該上面誘導板及び/または下面誘
導板は、それらの間に突出する波立て板を有している、
ことを特徴とするものである。An exhaust gas cleaning apparatus according to the present invention for solving the above problems is an exhaust gas cleaning apparatus for cleaning exhaust gas discharged from an incinerator or the like, wherein the exhaust gas cleaning apparatus stores water. A tank having a gas introduction chamber into which the exhaust gas is introduced and a gas suction chamber connected to an exhaust unit, and the gas introduction chamber and the gas suction chamber are provided at an upper portion of the tank. Partitioned from the plate is separated from each other, so that the level of the stored water on the gas introduction chamber side is above the lower end of the partition plate before gas suction and lower than the lower end of the partition plate during gas suction. The tank has an upper surface guide plate extending continuously from the partition plate in the gas suction chamber side, and a lower surface guide plate extending in a gas suction chamber side direction from a position further below the lower end of the partition plate. , The top surface guide plate and / or bottom guide plate has a wave stand plate which projects between them,
It is characterized by the following.
【0005】上記排ガス洗浄装置の好ましい実施形態に
おいては、上記仕切り板の下端及び/または上記波立て
板の先端に凹凸の切り込みを形成するのが適切であり、
上記上面誘導板は、ほぼ水平に設けられ、上記下面誘導
板は、上方へ傾斜して設けられているのが適切である。
上記排ガス洗浄装置の上記下面誘導板は、上方へ傾斜し
た傾斜部が上記上面誘導板の長さを越えてガス吸引室の
水面上方まで伸びており、該傾斜部は、ガス吸引室の水
面付近の位置に洗浄水通過口を有しているのが適切であ
る。また、上記排ガス洗浄装置の上記ガス導入室は、ダ
ンパを設けた大気導入口に接続されているのが適切であ
り、上記タンクは、タンク内の水位を検出する水位検出
器、及び該水位検出器からの信号に基づきタンク内の水
位を調節する給水制御弁を有しているのが適切である。
また、上記排ガス洗浄装置の上記タンクは、ガス吸引室
の水面に浮かせた油を抜き取るための抜き取り管を有
し、該抜き取り管は油が流入する開口の位置を油と水の
界面の位置に調節できる調節器を有しているのが適切で
あり、更に上記タンクは、貯留水に中和液を添加する装
置を有したり、タンクの底部に沈殿浮遊する煤塵を含む
水を燃焼炉に送るポンプ手段を有しているのが適切であ
る。[0005] In a preferred embodiment of the exhaust gas cleaning device, it is appropriate to form an uneven cut at the lower end of the partition plate and / or the tip of the corrugated plate.
Suitably, the upper surface guide plate is provided substantially horizontally, and the lower surface guide plate is suitably provided to be inclined upward.
The lower guide plate of the exhaust gas cleaning apparatus has an upwardly inclined portion extending above the water surface of the gas suction chamber beyond the length of the upper guide plate, and the inclined portion is located near the water surface of the gas suction chamber. It is appropriate to have a washing water passage at the position of. Further, the gas introduction chamber of the exhaust gas cleaning device is suitably connected to an air introduction port provided with a damper, and the tank is provided with a water level detector for detecting a water level in the tank, and a water level detector for detecting the water level. It is appropriate to have a water supply control valve for adjusting the water level in the tank based on the signal from the vessel.
Further, the tank of the exhaust gas cleaning device has a drain pipe for draining the oil floating on the water surface of the gas suction chamber, and the drain pipe has a position of an opening through which oil flows in a position of an interface between oil and water. It is appropriate to have a regulator that can be adjusted, and furthermore, the tank has a device for adding a neutralizing solution to the stored water, or water containing dust that precipitates and floats at the bottom of the tank is supplied to the combustion furnace. Suitably, it has a pump means for feeding.
【0006】[0006]
【作用】排気手段によりガス吸引室のガスが排気される
と、ガス吸引室は負圧になるから、仕切り板により互い
に区画されたガス導入室とガス吸引室とに圧力差が発生
する。該ガス導入室とガス吸引室は、仕切り板により互
いに区画されており、仕切り板の下端より下方では仕切
りがないために水面下で互いに連通している。したがっ
て、ガス導入室とガス吸引室とに圧力差が発生すると、
ガス導入室側の貯留水は押し下げられて、仕切り板の下
端を通ってガス吸引室側に移動し、ガス導入室側の水位
は下がる。そして、ガス吸引室のガスが排気されること
によりガス導入室側の貯留水の水位が上記仕切り板の下
端より下がると、ガス導入室に導入された排ガスは該仕
切り板の下端からガス吸引室側に押し出され、波立て板
を有している上面誘導板と下面誘導板により誘導されな
がら貯留水を掻き揚げて上昇し、ガス吸引室へ飛沫とな
って奔流する。When the gas in the gas suction chamber is exhausted by the exhaust means, the gas suction chamber becomes negative pressure, so that a pressure difference is generated between the gas introduction chamber and the gas suction chamber which are separated from each other by the partition plate. The gas introduction chamber and the gas suction chamber are separated from each other by a partition plate, and communicate with each other below the water surface because there is no partition below the lower end of the partition plate. Therefore, when a pressure difference occurs between the gas introduction chamber and the gas suction chamber,
The stored water on the gas introduction chamber side is pushed down, moves to the gas suction chamber side through the lower end of the partition plate, and the water level on the gas introduction chamber side falls. Then, when the gas in the gas suction chamber is exhausted and the level of the stored water on the gas introduction chamber side falls below the lower end of the partition plate, the exhaust gas introduced into the gas introduction chamber flows from the lower end of the partition plate into the gas suction chamber. The stored water is extruded to the side and is lifted by being lifted up by the stored water while being guided by the upper surface guide plate and the lower surface guide plate having the corrugated plate, and splashes into the gas suction chamber as a torrent.
【0007】本発明の排ガス洗浄装置は、排ガスが仕切
り板の下端を通ってガス吸引室側に押し出され、上面誘
導板と下面誘導板により誘導されながら上昇する過程に
おいて、貯留水を通過する排気ガス自体で該貯留水に十
分な撹拌を行わしめることができるから、該攪拌により
排ガスを細かい泡にしたり貯留水を水滴にしたりして排
ガスと貯留水を十分に気液接触させることができ、気液
接触している時間も長くすることができる。仕切り板の
下端及び/または上記波立て板に凹凸の切り込みを形成
すると、排気ガスと貯留水との攪拌をさらに十分に行う
ことができる。また、上記上面誘導板をほぼ水平に設
け、上記下面誘導板を上方へ傾斜して設けると、仕切り
板の下端を通って貯留水と共にガス吸引室側に押し出さ
れた排ガス及び貯留水を適切に誘導することができ、気
液接触効果が更に上がる。[0007] In the exhaust gas cleaning apparatus of the present invention, the exhaust gas passing through the stored water in the process of being pushed out through the lower end of the partition plate toward the gas suction chamber and rising while being guided by the upper surface guide plate and the lower surface guide plate. Since sufficient stirring can be performed on the stored water by the gas itself, the stirring can make the exhaust gas into fine bubbles or the stored water into water droplets, thereby allowing the exhaust gas and the stored water to come into sufficient gas-liquid contact, The time of gas-liquid contact can also be lengthened. When the cuts of the unevenness are formed in the lower end of the partition plate and / or the corrugated plate, the exhaust gas and the stored water can be more sufficiently stirred. Further, when the upper surface guide plate is provided substantially horizontally and the lower surface guide plate is provided inclined upward, the exhaust gas and the stored water pushed out to the gas suction chamber side together with the stored water through the lower end of the partition plate can be appropriately formed. Can be induced, and the gas-liquid contact effect is further enhanced.
【0008】仕切り板の下端を通って排ガスと共にガス
吸引室側に押し出された貯留水は、下面誘導板の傾斜部
に設けた洗浄水通過口を通って、下面誘導板より下方に
流れ込み、下面誘導板の下方に開設した通水路を通って
ガス導入室側に循環する。また、大気導入口に接続され
たダンパを調節してガス導入室内の排ガスに大気を混入
させると、貯留水を冷却することができるから、排ガス
中の有害成分の吸収を多くし、排気に同伴する蒸気は冷
却凝縮によって貯留水に補足され、大気へ放出される過
飽和蒸気を少なくすることができる。タンク内の貯留水
は、排気に同伴する蒸気や飛沫によって減少するが、常
時水位が水位検出器により検出され、該水位検出器から
の信号に基づきタンク内の水位を調節する給水制御弁に
より適切な水位に調節される。The stored water, which has been pushed out to the gas suction chamber side together with the exhaust gas through the lower end of the partition plate, flows below the lower surface guide plate through the washing water passage opening provided in the inclined portion of the lower surface guide plate. It circulates to the gas introduction chamber side through a water channel established below the guide plate. In addition, if the damper connected to the air inlet is adjusted to mix the air with the exhaust gas in the gas introduction chamber, the stored water can be cooled, thereby increasing the absorption of harmful components in the exhaust gas and entraining the exhaust gas. The generated steam is captured in the stored water by cooling and condensing, and the amount of supersaturated steam released to the atmosphere can be reduced. The water stored in the tank is reduced by steam and splashes accompanying the exhaust, but the water level is always detected by a water level detector, and the water level is appropriately controlled by a water supply control valve that adjusts the water level in the tank based on a signal from the water level detector. Water level is adjusted.
【0009】ガス吸引室の貯留水面に粘調な油を浮かせ
ることにより、排ガス中の油性煤麈を効率的に捕捉でき
るが、該油性煤麈を捕捉した油は、該油が流入する開口
の位置を油と水の界面の位置に調節できる調節器を有す
る抜き取り管により抜き取られる。また、排ガスの洗浄
効果をより高めるために、上記タンクに設けた添加装置
から中和液が貯留水に添加される。また、排ガスの洗浄
により貯留水に吸着した煤塵は、タンクの底部に沈殿浮
遊する煤塵懸濁液となるが、該煤塵懸濁液は上記タンク
に設けたポンプ手段により焼却炉に少量ずつ送られ、該
焼却炉内にスプレーされることにより焼却される。The oily dust in the exhaust gas can be efficiently captured by floating viscous oil on the storage surface of the gas suction chamber, but the oil that has captured the oily dust is located in the opening through which the oil flows. It is withdrawn by a withdrawal tube having an adjuster whose position can be adjusted to the position of the oil-water interface. Further, in order to further enhance the cleaning effect of the exhaust gas, a neutralizing solution is added to the stored water from an adding device provided in the tank. Dust adsorbed to the stored water by the exhaust gas washing becomes a dust suspension that precipitates and floats at the bottom of the tank, and the dust suspension is sent little by little to an incinerator by a pump provided in the tank. Is incinerated by being sprayed into the incinerator.
【0010】[0010]
【発明実施の形態】図面は本発明に係る排ガス洗浄装置
の実施例を示している。この排ガス洗浄装置1は、洗浄
水2を貯留するタンク10を有し、該タンク10は、天
板10a、側板10b、底板10cで囲まれた容器であ
り、該タンク10の上方部分にガス導入室11及びガス
吸引室12を有し、該ガス導入室11及びガス吸引室1
2は、上記タンク10の天板10aから上方に突出する
ガス導入口13及びガス排出口14に接続され、該ガス
導入口13には焼却炉等から排出される排ガスが排ガス
供給管3を介して導入され、該ガス排出口14は吸引管
5を介して吸引ファン4に接続され、該吸引ファン4の
駆動により洗浄された排ガスが排出される。上記ガス導
入口13内には気液接触器35が設けられており、該気
液接触器35はスプレー手段を複数有する複数の配管
(図示せず)を有し、該配管はタンク10内の貯留水を
供給するポンプ(図示せず)に接続され、該配管を通っ
て貯留水が焼却炉等から排出される排ガスにスプレーさ
れる。したがって、焼却炉等から排出される排ガスは、
この気液接触器35を有する短い気液接触塔で気液接触
してから、上記ガス導入室11へ流入する。上記ガス排
出口14には、排ガス中の水滴を捕集するための複数の
水滴衝突板36が設けられている。また、上記吸引ファ
ン4は、回転数が制御可能な駆動モータ及び該吸引ファ
ン4の排気口に設けられた開度が制御可能なダンパ(図
示せず)を有しており、排出するガス量を制御できるよ
うになっている。BRIEF DESCRIPTION OF THE DRAWINGS The drawings show an embodiment of the exhaust gas cleaning apparatus according to the present invention. The exhaust gas cleaning apparatus 1 has a tank 10 for storing the cleaning water 2, the tank 10 is a container surrounded by a top plate 10 a, a side plate 10 b, and a bottom plate 10 c, and gas is introduced into an upper portion of the tank 10. It has a chamber 11 and a gas suction chamber 12, and the gas introduction chamber 11 and the gas suction chamber 1
2 is connected to a gas inlet 13 and a gas outlet 14 projecting upward from the top plate 10a of the tank 10, and exhaust gas discharged from an incinerator or the like is connected to the gas inlet 13 via an exhaust gas supply pipe 3. The gas outlet 14 is connected to the suction fan 4 via the suction pipe 5, and the exhaust gas that has been cleaned by driving the suction fan 4 is discharged. A gas-liquid contactor 35 is provided in the gas inlet 13, and the gas-liquid contactor 35 has a plurality of pipes (not shown) having a plurality of spray means. The pump is connected to a pump (not shown) for supplying the stored water, and the stored water is sprayed to exhaust gas discharged from an incinerator or the like through the pipe. Therefore, exhaust gas discharged from incinerators, etc.
After the gas-liquid contact in the short gas-liquid contact tower having the gas-liquid contactor 35, the gas flows into the gas introduction chamber 11. The gas outlet 14 is provided with a plurality of water droplet collision plates 36 for collecting water droplets in the exhaust gas. The suction fan 4 has a drive motor whose rotation speed can be controlled and a damper (not shown) provided at an exhaust port of the suction fan 4 and whose opening can be controlled. Can be controlled.
【0011】上記ガス導入室11及びガス吸引室12
は、上記タンク10の天板10aから垂下する仕切り板
15により互いに区画されており、仕切り板15の下端
15aより下方では仕切りがないために水面下で互いに
連通している。上記ガス導入室11側の貯留水の水位
は、ガス吸引前はガス吸引室12側の水位と同じで上記
仕切り板15の下端15aより上(図1でPで示す水
位)にあるが、上記吸引ファン4の駆動により排ガスが
吸引される時には、ガスの吸引によりその水位が低下し
て上記仕切り板15の下端15aより下(図1でQで示
す水位)になるように設けられている。また、上記仕切
り板15の両端及び上端はタンク10の両側板10b及
び天板10aに溶接等により気密に固定されている。上
記タンク10は、上記仕切り板15の下端15aより上
方で該仕切り板15から連続してガス吸引室12側方向
にほぼ水平に伸びる上面誘導板16と、上記仕切り板1
5の下端15aのさらに下方位置からガス吸引室12側
方向に上方へ傾斜して伸びる下面誘導板17を有し、該
下面誘導板17はその上面に波立て板17aを適当な間
隔で複数起立させ、上記上面誘導板16はその先端に波
立て板16aを垂下させている。The gas introduction chamber 11 and the gas suction chamber 12
Are separated from each other by a partition plate 15 hanging down from the top plate 10a of the tank 10, and communicate with each other below the water surface because there is no partition below the lower end 15a of the partition plate 15. Before the gas suction, the water level of the stored water on the gas introduction chamber 11 side is the same as the water level on the gas suction chamber 12 side and above the lower end 15a of the partition plate 15 (the water level indicated by P in FIG. 1). When the exhaust gas is sucked by driving the suction fan 4, the water level is lowered by the suction of the gas, and the partition plate 15 is provided so as to be lower than the lower end 15a (the water level indicated by Q in FIG. 1). Further, both ends and the upper end of the partition plate 15 are air-tightly fixed to both side plates 10b and the top plate 10a of the tank 10 by welding or the like. The tank 10 is provided with an upper surface guide plate 16 extending substantially horizontally above the partition plate 15 in the direction of the gas suction chamber 12 above the lower end 15a of the partition plate 15;
5 has a lower surface guide plate 17 which extends obliquely upward in the direction of the gas suction chamber 12 from a position further below the lower end 15a, and the lower surface guide plate 17 has a plurality of undulating plates 17a standing on the upper surface thereof at appropriate intervals. The upper surface guide plate 16 has a corrugated plate 16a hanging at its tip.
【0012】上記仕切り板15の下縁に、凹凸部15b
(図2参照)を切り欠いて形成したり、波立て板16
a、17aの先端に、同様の凹凸部を切り欠いて形成し
ても良い。上記仕切り板15の下縁に、凹凸部15bを
切り欠いて形成した場合には、貯留水は該仕切り板の凹
部切り欠きを通って流れることができるから、仕切り境
界を決める仕切り板の実質的な下端は、仕切り板15の
凹凸部15bの凹形切り欠き上端になる。したがって、
上記仕切り板15の下縁に、凹凸部15bを切り欠いて
形成した場合には、上記ガス吸引前のガス導入室11側
の貯留水の水位Pは、少なくとも上記仕切り板15の凹
形切り欠き上端より上に設け、上記上面誘導板16は、
少なくとも上記仕切り板15の凹形切り欠き上端より上
の部分からガス吸引室12側方向に伸びるようにする。
また、上記下面誘導板17と上記仕切り板15の下端と
の距離は、上記仕切り板15の凹凸部の切り欠き寸法の
倍程度が望ましい。また、上記下面誘導板17は、上方
へ傾斜した傾斜部が上記上面誘導板の長さを十分に越え
た部分で更に急角度で傾斜しており、該急角度で傾斜し
た部分17bはガス吸引室の水面上方まで伸びており、
該傾斜部分17bのガス吸引室の水面付近の位置、具体
的には排ガス洗浄装置1が運転されていない状態での水
面真上に、貯留水通過口17cが設けられている。An uneven portion 15b is formed on the lower edge of the partition plate 15.
(See FIG. 2).
A similar concavo-convex portion may be cut out and formed at the tips of a and 17a. When the concave and convex portions 15b are cut out on the lower edge of the partition plate 15, the stored water can flow through the concave cutouts of the partition plate. The lower end is the upper end of the concave cutout of the uneven portion 15b of the partition plate 15. Therefore,
In the case where the concave and convex portions 15b are cut out at the lower edge of the partition plate 15, the water level P of the stored water on the gas introduction chamber 11 side before the gas suction is at least the concave notch of the partition plate 15. Provided above the upper end, the upper surface guide plate 16
At least a portion of the partition plate 15 above the upper end of the concave cutout extends toward the gas suction chamber 12.
Further, the distance between the lower surface guide plate 17 and the lower end of the partition plate 15 is desirably about twice as large as the notch size of the uneven portion of the partition plate 15. Further, the lower guide plate 17 is further inclined at a steep angle at a portion where the inclined portion inclined upwardly exceeds the length of the upper guide plate sufficiently, and the portion 17b inclined at the steep angle is a gas suction portion. Extending above the surface of the room,
A storage water passage 17c is provided at a position near the water surface of the gas suction chamber of the inclined portion 17b, specifically, just above the water surface when the exhaust gas cleaning device 1 is not operating.
【0013】ガス導入室11とガス吸引室12は、仕切
り板15により互いに区画されており、仕切り板15の
下端15aより下方では仕切りがないために水面下で互
いに連通しているから、排ガス洗浄装置1が運転されて
いない状態においては、ガス導入室11及びガス吸引室
12における貯留水2の水位は、仕切り板15の下端1
5aより上方の同じ水位にある。排ガス洗浄装置1の運
転が開始され、ガス導入室11に排気ガスが導入され、
吸引ファン4によりガス吸引室12のガスが排気される
と、ガス吸引室12は負圧になり、仕切り板15により
互いに区画されたガス導入室11とガス吸引室12とに
圧力差が発生し、ガス導入室11側の貯留水2は押し下
げられて、仕切り板15の下端15aを通ってガス吸引
室12側に移動し、ガス導入室11側の貯留水の水位は
下がる。The gas introduction chamber 11 and the gas suction chamber 12 are separated from each other by a partition plate 15, and since there is no partition below the lower end 15a of the partition plate 15, they communicate with each other below the water surface. When the device 1 is not operating, the water level of the stored water 2 in the gas introduction chamber 11 and the gas suction chamber 12 is lower than the lower end 1 of the partition plate 15.
At the same water level above 5a. The operation of the exhaust gas cleaning device 1 is started, and exhaust gas is introduced into the gas introduction chamber 11,
When the gas in the gas suction chamber 12 is exhausted by the suction fan 4, the gas suction chamber 12 has a negative pressure, and a pressure difference is generated between the gas introduction chamber 11 and the gas suction chamber 12 partitioned by the partition plate 15. Then, the stored water 2 on the gas introduction chamber 11 side is pushed down, moves to the gas suction chamber 12 side through the lower end 15a of the partition plate 15, and the water level of the stored water on the gas introduction chamber 11 side falls.
【0014】そして、ガス吸引室12のガスが排気され
ることによりガス導入室11側の貯留水の水位が上記仕
切り板15の下端15aより下がると、ガス導入室11
に導入された排ガスは該仕切り板15の下端15aから
ガス吸引室12側に押し出され、上面誘導板16と複数
の波立て板17aを有している下面誘導板17により誘
導され、かつ攪拌混合されながら貯留水を掻き揚げて上
昇し、ガス吸引室12へ飛沫となって奔流する。この排
ガス洗浄装置1においては、排ガスが仕切り板15の下
端15aを通ってガス吸引室側12に押し出され、上面
誘導板16と複数の波立て板17aを有している下面誘
導板17により誘導されながら上昇する過程において、
貯留水を通過する排気ガス自体で該貯留水に十分な撹拌
を行わしめることができるから、該攪拌により排ガスを
細かい泡にしたり貯留水を水滴にしたりして排ガスと貯
留水を十分に気液接触させることができ、気液接触して
いる時間も長くすることができる。When the gas in the gas suction chamber 12 is exhausted and the level of the stored water on the gas introduction chamber 11 side falls below the lower end 15a of the partition plate 15, the gas introduction chamber 11
The exhaust gas introduced into the chamber is pushed out from the lower end 15a of the partition plate 15 toward the gas suction chamber 12, is guided by the upper surface guide plate 16 and the lower surface guide plate 17 having a plurality of corrugated plates 17a, and is stirred and mixed. Then, the stored water is lifted up by being scooped up, and splashes into the gas suction chamber 12 as a torrent. In the exhaust gas cleaning apparatus 1, the exhaust gas is pushed out to the gas suction chamber side 12 through the lower end 15a of the partition plate 15, and is guided by the lower surface guide plate 17 having the upper surface guide plate 16 and the plurality of corrugated plates 17a. In the process of rising while being
Since the exhaust gas itself passing through the stored water itself can sufficiently agitate the stored water, the agitation turns the exhaust gas into fine bubbles or makes the stored water droplets to sufficiently separate the exhaust gas and the stored water from the gas. Contact can be made, and the time of gas-liquid contact can be prolonged.
【0015】そして、タンク内の貯留水との効率的攪拌
によって、排ガス中の有害物質を貯留水に溶解して除去
することができる。また、この排ガス洗浄装置1におい
ては、注入量調節機構を備えた薬注器34をタンク10
に付設しており、排ガス中の有害物質を吸収しやすい物
質や中和用のアルカリ液を該薬注器34によって貯留水
に添加することで排ガスの洗浄効果をより高めると共
に、排ガス処理によって酸性化する循環貯留水を中和し
て排ガス中の有害成分の吸収効果を高めている。仕切り
板15の下端15a及び/または上記波立て板16a、
17aに凹凸の切り込みを形成すると、排気ガスと貯留
水との攪拌をさらに十分に行うことができる。また、上
記上面誘導板16をほぼ水平に設け、上記下面誘導板1
7を上方へ傾斜して設けると、波返し効果を発現し攪拌
作用を高め、気液接触効果が更に上がる。仕切り板15
の下端15aを通って排ガスと共にガス吸引室12側に
押し出された貯留水は、下面誘導板17の傾斜部に設け
た貯留水通過口17cを通って、側板10bに突き当た
りタンクの底部をガス導入室11側へ循環し、タンク内
の貯留水の性状と温度を均一にする。The harmful substances in the exhaust gas can be dissolved in the stored water and removed by efficient stirring with the stored water in the tank. Further, in the exhaust gas cleaning device 1, the chemical injector 34 having the injection amount adjusting mechanism is connected to the tank 10.
A chemical substance that easily absorbs harmful substances in the exhaust gas and an alkaline solution for neutralization are added to the stored water by the chemical injector 34 to enhance the cleaning effect of the exhaust gas, and the acid treatment is performed by the exhaust gas treatment. Neutralizing the circulating stored water, which is becoming liquefied, enhances the effect of absorbing harmful components in the exhaust gas. The lower end 15a of the partition plate 15 and / or the wavy plate 16a,
When the cuts of the irregularities are formed in 17a, the exhaust gas and the stored water can be more sufficiently stirred. Further, the upper surface guide plate 16 is provided substantially horizontally, and the lower surface guide plate 1 is provided.
When 7 is inclined upward, a wave-return effect is exhibited, the stirring effect is enhanced, and the gas-liquid contact effect is further increased. Partition plate 15
Water pushed out to the gas suction chamber 12 side together with the exhaust gas through the lower end 15a of the lower surface guide plate 17 passes through a stored water passage opening 17c provided in the inclined portion of the lower surface guide plate 17, hits the side plate 10b, and gas is introduced into the bottom of the tank. Circulates to the chamber 11 side to make the properties and temperature of the water stored in the tank uniform.
【0016】また、仕切り板15で区画されたガス吸引
室12側の貯留水面に粘調な油を浮かせると共に、水の
撹拌と共に気液接触させることで排ガス中の油性煤麈を
効率的に捕捉することができる。この場合には、貯留水
の上に浮かした油31を抜き取るために、吸引ファン4
の停止時の油と水の界面の位置を開口位置とすることが
できる調節器32aを設けた抜き取り管32をタンク1
0の下から立ち上げる。抜き取り管32の下端はタンク
10の外でバルブ33に接続し、油31が汚れてきたら
抜き取りが出来るようにする。上記調節器32aは、そ
の周壁に油が流入する開口を有し、該開口の位置を吸引
ファン4の停止時の油と水の界面の位置に調節できるよ
うに抜き取り管32の上端外周に設けた螺子に螺合され
ており、該調節器32aに支持腕32bを固定し、該支
持腕32bをタンク10の天板10aに設けたソケット
32cに旋回自在に螺着して構成する。そして、上記支
持腕32bの上端に設けた取手32dを回して上記調節
器32aを回動し、上記調節器32aを抜き取り管32
に螺出または螺入させることにより上下させ、油が流入
する開口の位置が吸引ファン4の停止時の油と水の界面
の位置になるように調節する。In addition, the viscous oil is floated on the storage water surface on the side of the gas suction chamber 12 partitioned by the partition plate 15, and the oily soot and dust in the exhaust gas is efficiently captured by bringing the oil into gas-liquid contact with the stirring of the water. can do. In this case, in order to extract the oil 31 floating on the stored water, the suction fan 4
The extraction pipe 32 provided with the adjuster 32a capable of setting the position of the oil-water interface at the time of stoppage as the opening position is connected to the tank 1
Start up from below 0. The lower end of the extraction pipe 32 is connected to a valve 33 outside the tank 10 so that the oil 31 can be extracted when the oil 31 becomes dirty. The adjuster 32a has an opening into its peripheral wall through which oil flows, and is provided on the outer periphery of the upper end of the extraction pipe 32 so that the position of the opening can be adjusted to the position of the interface between oil and water when the suction fan 4 is stopped. The support arm 32b is fixed to the adjuster 32a, and the support arm 32b is rotatably screwed to a socket 32c provided on the top plate 10a of the tank 10. Then, the adjuster 32a is rotated by turning a handle 32d provided at the upper end of the support arm 32b, and the adjuster 32a is pulled out of the pipe 32.
The suction fan 4 is moved up and down by being screwed or screwed into the opening, so that the position of the opening through which the oil flows in is adjusted to the position of the oil-water interface when the suction fan 4 is stopped.
【0017】また、上記ガス導入室11の天板10aに
は、仕切り板15に近接してダンパ21を設けた大気導
入口22が接続されており、該ダンパ21を調節してガ
ス導入室11から仕切り板15の下端を通過する排ガス
に大気を混入させると、気液接触間に貯留水2の温度を
下げることができるから、排ガス中の有害成分の吸収を
多くし、排気に同伴する蒸気を少なくすることができ
る。また、上記タンク10は、タンク10内の水位を検
出する水位検出器23、及び該水位検出器23からの信
号に基づきタンク10内の水位を調節する給水制御弁2
4を有している。上記水位検出器23は、タンク10の
側板10bを貫通して取り付けた上下2箇所の通水管2
3a、23bに非導電性の管23cを取り付け、該管2
3cの中に導電性のフロート23dを入れ、該管23c
の外側にフロート23dの位置を検出する環状の磁性体
検知器23eを上下2個間隔をあけて設け、該磁性体検
知器23eは上側が停止時の液面位置、下側が運転時の
液面位置となるように設けられている。上記給水制御弁
24は、上記水位検出器23からの信号に基づきタンク
10内の水位を調節し、排ガス洗浄によって蒸発する貯
留水を安定して補充する。The top plate 10a of the gas introduction chamber 11 is connected to an air introduction port 22 provided with a damper 21 close to the partition plate 15. When the atmosphere is mixed with the exhaust gas passing through the lower end of the partition plate 15, the temperature of the stored water 2 can be lowered during the gas-liquid contact, so that the absorption of harmful components in the exhaust gas is increased, and the steam accompanying the exhaust gas is increased. Can be reduced. The tank 10 includes a water level detector 23 for detecting a water level in the tank 10, and a water supply control valve 2 for adjusting the water level in the tank 10 based on a signal from the water level detector 23.
Four. The water level detector 23 includes two upper and lower water pipes 2 that are attached through the side plate 10 b of the tank 10.
Attach a non-conductive tube 23c to each of the tubes 3a and 23b.
3c, a conductive float 23d is placed in the tube 23c.
An annular magnetic detector 23e for detecting the position of the float 23d is provided at two intervals above and below the float, and the upper surface of the magnetic detector 23e is a liquid level position at the time of stop, and a lower surface is the liquid level at the time of operation. It is provided so that it may become a position. The water supply control valve 24 adjusts the water level in the tank 10 based on a signal from the water level detector 23, and stably replenishes the stored water evaporated by exhaust gas cleaning.
【0018】[0018]
【実施例】この排ガス洗浄装置1の排ガス導入口13に
焼却炉からの排ガスを導入し、該排ガスに該排ガス導入
口13に設けた気液接触器35により貯留水をスプレー
してから、該排ガスをガス導入室11へ流入させた。ガ
ス排出口14には複数の水滴衝突板36を装着し、静圧
80mm、毎分80m3のターボブロワー4の吸い込み
口を接続した。ターボブロワー4を運転すると、仕切り
板15の水位は約60mm下がり、仕切り板15からガ
ス吸引室12へ貯留水を掻き揚げて飛沫となって奔流す
るガスの流れが覗き窓から確認された。貯留水は2
m3、導入排ガスは380℃で、毎分40m3の排ガス
吸引量に対し、40m3の外気を吸引させたところ、2
時間の運転で貯留水温度は57℃、排ガス温度は56℃
で安定した。EXAMPLE An exhaust gas from an incinerator is introduced into an exhaust gas inlet 13 of the exhaust gas cleaning apparatus 1, and the exhaust gas is sprayed with stored water by a gas-liquid contactor 35 provided at the exhaust gas inlet 13; The exhaust gas was caused to flow into the gas introduction chamber 11. The gas discharge port 14 fitted with a plurality of droplet collision plate 36, the static pressure 80 mm, was connected a suction port of the turbo blower 4 per minute 80 m 3. When the turbo blower 4 was operated, the water level of the partition plate 15 was lowered by about 60 mm, and the flow of the gas that was scattered from the partition plate 15 to the gas suction chamber 12 to be splashed and torrent was confirmed from the viewing window. 2 for stored water
m 3 , the introduced exhaust gas was 380 ° C., and 40 m 3 of outside air was sucked in with respect to the exhaust gas suction amount of 40 m 3 per minute.
The temperature of the stored water is 57 ℃ and the temperature of the exhaust gas is 56 ℃
And stable.
【0019】このことから、タンク10内の貯留水が外
気で冷却される効果が確認された。ターボブロワー4の
出口からは、僅かな蒸気の放出が認められたのみであっ
た。通常焼却炉の煙突から放出される黒煙は殆ど認めら
れず、燃焼物(古タイヤ)の投入後に極く瞬間的に確認
されたのみであった。運転を停止して水面に浮かした油
を点検したところ、真っ黒にカーボンで汚れており、黒
煙煤麈の吸着が行われたことが確認できた。貯留水に
は、0.1%以下の界面活性剤を添加した。貯留水の底
の水位から取得したサンプルは、微細な煤麈の懸濁液で
あり、気液接触が充分行われたことを示しており、排ガ
スの浄化効果が向上したことが確認された。大気放出の
ダイオキシン分析の結果は、1.7〜3.0ng,TE
Q/m3Nであり、法規制の5.0ng,TEQ/m3
Nをクリアすることができた。From this, it was confirmed that the stored water in the tank 10 was cooled by the outside air. Only a slight release of steam was observed from the outlet of the turbo blower 4. Almost no black smoke emitted from the chimney of the incinerator was recognized, and it was confirmed only instantaneously after the incineration (used tires) was charged. When the operation was stopped and the oil floating on the surface of the water was inspected, it was confirmed that the oil was completely black and was contaminated with carbon, and that black smoke dust was adsorbed. 0.1% or less surfactant was added to the stored water. The sample obtained from the water level at the bottom of the stored water was a suspension of fine dust and dust, indicating that the gas-liquid contact was sufficiently performed, and it was confirmed that the purification effect of the exhaust gas was improved. The results of dioxin analysis of atmospheric release were 1.7-3.0 ng, TE
Q / m 3 N, and 5.0 ng of TEQ / m 3
N was able to be cleared.
【0020】[0020]
【発明の効果】以上詳述したように、本発明の排ガス洗
浄装置は、排ガスを貯留水と短い塔で気液接触させるに
も拘わらず、排ガスの洗浄を十分行うことができる。更
に、本発明の排ガス洗浄装置は、貯留水を通過する排気
ガス自体で該貯留水に十分な撹拌を行わしめることがで
き、気液接触時間も長くすることができ、貯留水を冷却
することができ、排ガス中の有害成分の吸収を多くし、
排気に同伴する蒸気を少なくすることができる。As described above in detail, the exhaust gas cleaning apparatus of the present invention can sufficiently clean the exhaust gas even though the exhaust gas is brought into gas-liquid contact with the stored water in a short tower. Further, the exhaust gas cleaning apparatus of the present invention can sufficiently agitate the stored water by the exhaust gas itself passing through the stored water, can increase the gas-liquid contact time, and can cool the stored water. To increase the absorption of harmful components in the exhaust gas,
Steam accompanying the exhaust gas can be reduced.
【図1】本発明の排ガス洗浄装置の一実施例を示す縦断
面図である。FIG. 1 is a longitudinal sectional view showing one embodiment of an exhaust gas cleaning apparatus of the present invention.
【図2】図1のA−A線における部分断面図である。FIG. 2 is a partial cross-sectional view taken along line AA of FIG.
1 排ガス洗浄装置 2 貯留水 4 排気手段 10 タンク 11 ガス導入室 12 ガス吸引室 15 仕切り板 15a 仕切り板の下端 16 上面誘導板 17 下面誘導板 DESCRIPTION OF SYMBOLS 1 Exhaust gas cleaning apparatus 2 Reservoir 4 Exhaust means 10 Tank 11 Gas introduction chamber 12 Gas suction chamber 15 Partition plate 15a Lower end of partition plate 16 Upper surface guide plate 17 Lower surface guide plate
Claims (9)
排ガス洗浄装置において、 該排ガス洗浄装置は、水を貯留するタンクを有し、 該タンクは、その上方部分に上記排ガスが導入されるガ
ス導入室及び排気手段に接続されたガス吸引室を有し、 上記ガス導入室及びガス吸引室は、上記タンクの天板か
ら垂下する仕切り板により互いに区画されており、 上記ガス導入室側の貯留水の水位は、ガス吸引前は上記
仕切り板の下端より上でガス吸引時には上記仕切り板の
下端より下になるように設けられ、 上記タンクは、上記仕切り板から連続してガス吸引室側
方向に伸びる上面誘導板と、上記仕切り板の下端のさら
に下方位置からガス吸引室側方向に伸びる下面誘導板を
有し、 該上面誘導板及び/または下面誘導板は、それらの間に
突出する波立て板を有している、ことを特徴とする排ガ
ス洗浄装置。1. An exhaust gas cleaning apparatus for cleaning exhaust gas discharged from an incinerator or the like, wherein the exhaust gas cleaning apparatus has a tank for storing water, and the tank has an upper portion into which the exhaust gas is introduced. A gas suction chamber connected to a gas introduction chamber and an exhaust unit, wherein the gas introduction chamber and the gas suction chamber are separated from each other by a partition plate hanging down from a top plate of the tank; The water level of the stored water is provided so as to be higher than the lower end of the partition plate before gas suction and to be lower than the lower end of the partition plate during gas suction. The tank is continuously connected to the gas suction chamber from the partition plate. A lower surface guide plate extending in a direction toward the gas suction chamber from a position further below the lower end of the partition plate, and the upper surface guide plate and / or the lower surface guide plate protrude therebetween. And a vertical plate, the exhaust gas cleaning apparatus characterized by.
て、 上記仕切り板の下端及び/または上記波立て板の先端に
凹凸の切り込みを形成した、ことを特徴とする排ガス洗
浄装置。2. The exhaust gas cleaning apparatus according to claim 1, wherein an uneven cut is formed at a lower end of the partition plate and / or a tip of the corrugated plate.
浄装置において、 上記上面誘導板は、ほぼ水平に設けられ、上記下面誘導
板は、上方へ傾斜して設けられている、ことを特徴とす
る排ガス洗浄装置。3. The exhaust gas cleaning apparatus according to claim 1, wherein the upper surface guide plate is provided substantially horizontally, and the lower surface guide plate is provided to be inclined upward. Exhaust gas cleaning equipment.
て、 上記下面誘導板は、上方へ傾斜した傾斜部が上記上面誘
導板の長さを越えてガス吸引室の水面上方まで伸びてお
り、 該傾斜部は、ガス吸引室の水面付近の位置に洗浄水通過
口を有している、ことを特徴とする排ガス洗浄装置。4. The exhaust gas cleaning apparatus according to claim 3, wherein the lower guide plate has an upwardly inclined portion extending above the water surface of the gas suction chamber beyond the length of the upper guide plate. The exhaust gas cleaning apparatus, wherein the inclined portion has a cleaning water passage port at a position near a water surface of the gas suction chamber.
ガス洗浄装置において、 上記ガス導入室は、ダンパを設けた大気導入口に接続さ
れている、ことを特徴とする排ガス洗浄装置。5. The exhaust gas cleaning apparatus according to claim 1, wherein the gas introduction chamber is connected to an air introduction port provided with a damper. .
ガス洗浄装置において、 上記タンクは、タンク内の水位を検出する水位検出器、
及び該水位検出器からの信号に基づきタンク内の水位を
調節する給水制御弁を有している、ことを特徴とする排
ガス洗浄装置。6. The exhaust gas cleaning device according to claim 1, wherein the tank is a water level detector that detects a water level in the tank.
And a water supply control valve for adjusting a water level in the tank based on a signal from the water level detector.
ガス洗浄装置において、 上記タンクは、ガス吸引室の水面に浮かせた油を抜き取
るための抜き取り管を有し、該抜き取り管は油が流入す
る開口の位置を油と水の界面の位置に調節できる調節器
を有している、ことを特徴とする排ガス洗浄装置。7. The exhaust gas cleaning apparatus according to claim 1, wherein the tank has a drain pipe for draining oil floating on the water surface of the gas suction chamber. An exhaust gas cleaning device comprising an adjuster capable of adjusting a position of an opening through which oil flows into an interface between oil and water.
ガス洗浄装置において、 上記タンクは、貯留水に中和液を添加する装置を有して
いる、ことを特徴とする排ガス洗浄装置。8. The exhaust gas cleaning apparatus according to claim 1, wherein the tank has a device for adding a neutralizing solution to the stored water. apparatus.
ガス洗浄装置において、 上記タンクは、その底部に沈殿浮遊する煤塵を含む水を
燃焼炉に送るポンプ手段を有している、ことを特徴とす
る排ガス洗浄装置。9. The exhaust gas cleaning apparatus according to any one of claims 1 to 8, wherein the tank has a pump means for sending water containing dust precipitated and floating to a combustion furnace at a bottom portion thereof. An exhaust gas cleaning device characterized by the above-mentioned.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000299861A JP2002102637A (en) | 2000-09-29 | 2000-09-29 | Flue gas cleaning apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000299861A JP2002102637A (en) | 2000-09-29 | 2000-09-29 | Flue gas cleaning apparatus |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2002102637A true JP2002102637A (en) | 2002-04-09 |
Family
ID=18781612
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2000299861A Pending JP2002102637A (en) | 2000-09-29 | 2000-09-29 | Flue gas cleaning apparatus |
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JP (1) | JP2002102637A (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005329370A (en) * | 2004-05-21 | 2005-12-02 | Nakayama Iron Works Ltd | Wet dust precipitator |
JP2011523898A (en) * | 2008-06-09 | 2011-08-25 | ジェイ オウク ジュン | Cooling dedusting device |
CN103170219A (en) * | 2011-12-26 | 2013-06-26 | 森川产业株式会社 | Gas cleaning device |
CN105268273A (en) * | 2015-11-05 | 2016-01-27 | 无锡新人居科贸有限公司 | Multifunctional waste gas treatment device |
CN105344192A (en) * | 2015-11-05 | 2016-02-24 | 无锡新人居科贸有限公司 | Recyclable waste gas treatment device |
CN107259644A (en) * | 2017-07-28 | 2017-10-20 | 张志平 | Quickly dissipate cigarette water pipe |
JP2019041646A (en) * | 2017-08-31 | 2019-03-22 | フタバ産業株式会社 | Carbon dioxide application device |
JP2019041643A (en) * | 2017-08-31 | 2019-03-22 | フタバ産業株式会社 | Carbon dioxide application device |
-
2000
- 2000-09-29 JP JP2000299861A patent/JP2002102637A/en active Pending
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005329370A (en) * | 2004-05-21 | 2005-12-02 | Nakayama Iron Works Ltd | Wet dust precipitator |
JP2011523898A (en) * | 2008-06-09 | 2011-08-25 | ジェイ オウク ジュン | Cooling dedusting device |
CN103170219A (en) * | 2011-12-26 | 2013-06-26 | 森川产业株式会社 | Gas cleaning device |
JP2013132577A (en) * | 2011-12-26 | 2013-07-08 | Morikawa Sangyo Kk | Gas cleaning apparatus |
CN103170219B (en) * | 2011-12-26 | 2017-03-01 | 森川产业株式会社 | Gas purifier |
CN105268273A (en) * | 2015-11-05 | 2016-01-27 | 无锡新人居科贸有限公司 | Multifunctional waste gas treatment device |
CN105344192A (en) * | 2015-11-05 | 2016-02-24 | 无锡新人居科贸有限公司 | Recyclable waste gas treatment device |
CN107259644A (en) * | 2017-07-28 | 2017-10-20 | 张志平 | Quickly dissipate cigarette water pipe |
CN107259644B (en) * | 2017-07-28 | 2023-10-03 | 河北鼎硕玻璃制品有限公司 | Quick-smoke-dispersing water pipe |
JP2019041646A (en) * | 2017-08-31 | 2019-03-22 | フタバ産業株式会社 | Carbon dioxide application device |
JP2019041643A (en) * | 2017-08-31 | 2019-03-22 | フタバ産業株式会社 | Carbon dioxide application device |
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