JP2002080763A5 - Ink, ink set, ink cartridge, recording unit, color image recording device, and image recording method - Google Patents

Ink, ink set, ink cartridge, recording unit, color image recording device, and image recording method Download PDF

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JP2002080763A5
JP2002080763A5 JP2000276218A JP2000276218A JP2002080763A5 JP 2002080763 A5 JP2002080763 A5 JP 2002080763A5 JP 2000276218 A JP2000276218 A JP 2000276218A JP 2000276218 A JP2000276218 A JP 2000276218A JP 2002080763 A5 JP2002080763 A5 JP 2002080763A5
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ink
image recording
color
color image
unit
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JP4510256B2 (en
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【特許請求の範囲】
【請求項1】 (M1)2SO4、CH3COO(M1)、Ph−COO(M1)、(M1)NO3、(M1)Cl、(M1)Br、(M1)I、(M1)2SO3および(M1)2CO3(但し、M1はアルカリ金属、アンモニウムまたは有機アンモニウムを表わし、Phはフェニル基を表わす。)から選ばれる少なくとも1種の塩と、表面官能基密度が1.8(μmol/m2)以上の自己分散型アニオンカーボンブラックとを含むことを特徴とするインク。
【請求項2】 塩を、インク全重量に対して0.05〜10重量%含む請求項1に記載のインク。
【請求項3】 塩を、インク全重量に対して0.1〜5重量%含む請求項2に記載のインク。
【請求項4】 自己分散型アニオンカーボンブラックが、表面に少なくとも1種の親水性基が直接もしくは他の原子団を介して結合しているものである請求項1〜3のいずれか1項に記載のインク。
【請求項5】 親水性基が、下記に列記した中から選択される請求項4に記載のインク。
−COO(M2)、−SO3(M2)2、−PO3H(M2)、−PO3(M2)2(但し、式中のM2は、水素原子、アルカリ金属、アンモニウムまたは有機アンモニウムを表わす。)
【請求項6】 他の原子団が、炭素原子数1〜12のアルキレン基、置換もしくは未置換のフェニレン基、置換もしくは未置換のナフチレン基である請求項4または5に記載のインク。
【請求項7】 親水性基が、下記に列記した中から選択され、且つ下記式中のM2が請求項1〜6のいずれか1項に記載の塩を示す式中のM1と同一である請求項4に記載のインク。
−COO(M2)、−SO3(M2)2、−PO3(M2)2
【請求項8】 (M1)2SO4、CH3COO(M1)、Ph−COO(M1)、(M1)NO3、(M1)Cl、(M1)Br、(M1)I、(M1)2SO3および(M1)2CO3(但し、M1はアルカリ金属、アンモニウムまたは有機アンモニウムを表わし、Phはフェニル基を表わす。)から選ばれる少なくとも1種の塩と、表面官能基密度が0.45(mmol/g)以上の自己分散型アニオンカーボンブラックとを含み、且つ60℃の環境下に1ケ月間保存したときにも実質的な粘度変化を生じないことを特徴とするインク。
【請求項9】 自己分散型アニオンカーボンブラックの平均粒径が、90nm以上である請求項1〜8のいずれか1項に記載のインク。
【請求項10】 インクが、インクジェット用インクである請求項1〜9のいずれか1項に記載のインク。
【請求項11】 請求項1〜9のいずれか1項に記載の黒色のインクと、シアン用、マゼンタ用、イエロー用、レッド用、グリーン用およびブルー用の色材から選ばれる少なくとも1つの色材を含む水性のカラーインクとが組み合わされていることを特徴とするインクセット。
【請求項12】 カラーインクの色材が酸性染料または直接染料である請求項11に記載のインクセット。
【請求項13】 カラーインクの色材が顔料である請求項11に記載のインクセット。
【請求項14】 インクセットが、インクジェット用である請求項11〜13のいずれか1項に記載のインク。
【請求項15】 請求項1〜10のいずれか1項に記載のインクを収容しているインクタンクを備えていることを特徴とするインクカートリッジ。
【請求項16】 請求項10に記載のインクを収容しているインク収容部および該インクを吐出させるためのヘッド部を備えていることを特徴とする記録ユニット。
【請求項17】 請求項10に記載のインクを収容しているインク収容部および該インクの吐出用記録ヘッドとを備えていることを特徴とする画像記録装置。
【請求項18】 請求項10に記載のインクを収容しているインク収容部、シアン用、マゼンタ用、イエロー用、レッド用、グリーン用およびブルー用の色材から選ばれる少なくとも1つの色材を含む水性のカラーインクを収容しているインク収容部、および各々のインク収容部に収容されているインクを各々吐出させるための記録ヘッド部を具備していることを特徴とするカラー画像記録装置。
【請求項19】 請求項10に記載のインクを記録媒体表面に向けて飛翔させて該表面に付着させることにより画像を記録する工程を有することを特徴とする画像記録方法。
[Claims]
1. (M 1 ) 2 SO 4 , CH 3 COO (M 1 ), Ph-COO (M 1 ), (M 1 ) NO 3 , (M 1 ) Cl, (M 1 ) Br, (M 1 ) 1 ) At least one kind selected from I, (M 1 ) 2 SO 3 and (M 1 ) 2 CO 3 (where M 1 represents an alkali metal, ammonium or organic ammonium, and Ph represents a phenyl group) An ink comprising a salt and a self-dispersing anionic carbon black having a surface functional group density of 1.8 (μmol / m 2 ) or more.
2. The ink according to claim 1, wherein the salt contains 0.05 to 10% by weight based on the total weight of the ink.
3. The ink according to claim 2, wherein the salt comprises 0.1 to 5% by weight based on the total weight of the ink.
4. The self-dispersing anionic carbon black according to any one of claims 1 to 3, wherein at least one hydrophilic group is bonded to the surface directly or via another atomic group. The ink described.
5. The ink according to claim 4, wherein the hydrophilic group is selected from the following.
-COO (M 2 ), -SO 3 (M 2 ) 2 , -PO 3 H (M 2 ), -PO 3 (M 2 ) 2 (where M 2 is a hydrogen atom, an alkali metal, ammonium Or represents an organic ammonium.)
6. The ink according to claim 4, wherein the other atomic group is an alkylene group having 1 to 12 carbon atoms, a substituted or unsubstituted phenylene group, or a substituted or unsubstituted naphthylene group.
7. The hydrophilic group is selected from those listed below, and M 2 in the following formula is the same as M 1 in the formula representing a salt according to any one of claims 1 to 6. The ink according to claim 4, which is:
-COO (M 2 ), -SO 3 (M 2 ) 2 , -PO 3 (M 2 ) 2
8. (M 1 ) 2 SO 4 , CH 3 COO (M 1 ), Ph-COO (M 1 ), (M 1 ) NO 3 , (M 1 ) Cl, (M 1 ) Br, (M 1 ) 1 ) At least one kind selected from I, (M 1 ) 2 SO 3 and (M 1 ) 2 CO 3 (where M 1 represents an alkali metal, ammonium or organic ammonium, and Ph represents a phenyl group) It contains a salt and a self-dispersing anionic carbon black having a surface functional group density of 0.45 (mmol / g) or more, and causes a substantial change in viscosity even when stored for one month in an environment of 60 ° C. Ink characterized by not having.
9. The ink according to claim 1, wherein the self-dispersion type anionic carbon black has an average particle size of 90 nm or more.
10. The ink according to claim 1, wherein the ink is an ink jet ink.
11. A black ink according to claim 1, and at least one color selected from cyan, magenta, yellow, red, green and blue color materials. An ink set characterized by being combined with an aqueous color ink containing a material.
12. The ink set according to claim 11, wherein the coloring material of the color ink is an acid dye or a direct dye.
13. The ink set according to claim 11, wherein the color material of the color ink is a pigment.
14. The ink according to claim 11, wherein the ink set is for ink jet.
15. An ink cartridge comprising an ink tank containing the ink according to claim 1. Description:
16. A recording unit, comprising: an ink storage unit that stores the ink according to claim 10; and a head unit that discharges the ink.
17. An image recording apparatus, comprising: an ink storage unit that stores the ink according to claim 10; and a recording head for discharging the ink.
18. An ink containing section containing the ink according to claim 10, wherein at least one color material selected from cyan, magenta, yellow, red, green, and blue color materials is used. A color image recording apparatus, comprising: an ink storage unit that stores aqueous color ink containing the ink; and a recording head unit that discharges the ink stored in each of the ink storage units.
19. An image recording method, comprising a step of recording an image by flying the ink according to claim 10 toward a recording medium surface and attaching the ink to the surface.

【0001】
【発明の属する技術分野】
本発明は、インク、インクセット、インクカートリッジ、記録ユニット、カラー画像記録装置および画像記録方法に関する。
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention also relates ink, ink set, ink cartridge, recording unit, the color image recording apparatus and an image recording how.

従って、本発明の目的は、上記従来技術の問題点を解決し、記録媒体の種類による影響を抑制し、画像品位に優れ、且つカラー画像の形成の際のブリードの発生が有効に抑制され、しかも、インクの長期保存安定に優れ、高品位の画像が安定して得られるインク、インクセット、インクカートリッジ、記録ユニット、カラー画像記録装置および画像記録方法を提供することにある。 Therefore, an object of the present invention is to solve the above-mentioned problems of the prior art, suppress the influence of the type of recording medium, excel in image quality, and effectively suppress the occurrence of bleeding when forming a color image, Moreover, excellent long-term storage stability of the ink, the ink high-quality image can be stably obtained, ink set, ink cartridge, recording unit, is to provide a color image recording apparatus and an image recording how.

JP2000276218A 1999-09-17 2000-09-12 Ink, ink set, ink cartridge, color image recording apparatus and image recording method Expired - Fee Related JP4510256B2 (en)

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JP26461899 1999-09-17
JP2000-189396 2000-06-23
JP11-264618 2000-06-23
JP2000189396 2000-06-23
JP2000276218A JP4510256B2 (en) 1999-09-17 2000-09-12 Ink, ink set, ink cartridge, color image recording apparatus and image recording method

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JP2002080763A5 true JP2002080763A5 (en) 2007-10-25
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JP2006002094A (en) 2004-06-18 2006-01-05 Brother Ind Ltd Ink set for ink-jet recording and method for producing the same
WO2006022456A1 (en) 2004-08-27 2006-03-02 Canon Kabushiki Kaisha Water-base ink, ink jet recording method, ink cartridge, recording unit, ink jet recording apparatus, and image forming method
US7503969B2 (en) * 2006-10-12 2009-03-17 E.I. Du Pont De Nemours & Company Inkjet ink
JP2011132497A (en) * 2009-11-25 2011-07-07 Canon Inc Ink for inkjet recording
JP5911215B2 (en) * 2010-08-03 2016-04-27 キヤノン株式会社 Ink, ink cartridge, ink jet recording method, and ink jet recording apparatus
JP5911211B2 (en) * 2010-08-03 2016-04-27 キヤノン株式会社 Ink, ink cartridge, and ink jet recording method
JP6210712B2 (en) 2012-05-09 2017-10-11 キヤノン株式会社 Aqueous ink, ink cartridge, and ink jet recording method
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