JP2002038185A - Perfume composition and cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a new series of rose-like perfume composition corresponding to taste of current consumers and cosmetics containing the above perfume composition. SOLUTION: This perfume composition is characterized by including at least one kind of compound represented by general formula (1) (wherein R1 is H or OH) and at least one kind of compound represented by general formula (2) (wherein R2 is H or methyl group). The cosmetics comprise the above compound represented by general formula (1) and the above compound represented by general formula (2) as rose-like perfume components of new series.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a compound represented by the general formula (1):

Embedded image (Wherein R ¹ represents H or OH) and at least one compound represented by the general formula (2)

Embedded image (Wherein R ² represents H or a methyl group.) A fragrance composition containing at least one compound represented by the following formula:
In particular, it relates to a novel rose-like fragrance composition having a new rose-like excellent aroma obtained by breeding.

[0002]

2. Description of the Related Art Roses are said to be the queen of flowers, and have been loved by many people since ancient times for their beautiful appearance and fragrant fragrance. Is being developed. Representative varieties of roses are called damask rose (RosaDamascena) and cabbage rose (Rosa Centiforia), and rose oil (Rose oil Bulgarian) collected from damask rose
Contains citronellol, geraniol, nerol, linalool, phenylethyl alcohol, and the like as main components, and a rose-like fragrance composition is also prepared using these as main components. However, since the variety of recent roses has been repeatedly improved, the existing rose-like fragrance composition does not accurately represent the various fragrances of various roses currently existing in many varieties. There is a demand for the development of a rose perfume composition having a new fragrance without being caught by the fragrance of a conventional rose-like perfume composition.

[0003] Japanese Patent Publication No. 6-94417 has already disclosed:
Phenylethyl alcohol, citronellol, modern rose perfume composition is described by adding a dialkoxyalkylbenzene to a perfume composition based on an ancient rose-like aroma containing geraniol, but since the base tone is an ancient rose-like aroma, A new kind of rose-like fragrance is desired.

[0004]

SUMMARY OF THE INVENTION In view of the above circumstances, an object of the present invention is to provide a novel rose-like fragrance composition which meets modern consumer tastes.

[0005]

Means for Solving the Problems The inventors of the present invention have conducted intensive studies in order to meet the above-mentioned problems, and as a result, have found that the general formula (1)

Embedded image (Wherein R ¹ represents H or OH) and at least one compound represented by the general formula (2)

Embedded image (Wherein, R ² represents H or a methyl group). It has been found that a fragrance composition containing at least one compound represented by the following formula: Thus, the present invention has been completed. The present invention includes the following inventions.

(1) General formula (1)

Embedded image (Wherein R ¹ represents H or OH) and at least one compound represented by the general formula (2)

Embedded image (Wherein R ² represents H or a methyl group). A novel rose-like fragrance composition comprising at least one compound represented by the following formula:

(2) The compound of the above general formula (1)
The novel species according to (1), wherein the compound (2) is contained in a weight ratio of (1) :( 2) = 1 to 100: 1 and a total of 5 to 80% by weight of both compounds. Rose-like perfume composition.

(3) A novel rose-like fragrance component comprising at least one compound represented by the general formula (1) and at least one compound represented by the general formula (2). Washing cosmetics such as soaps, shampoos and rinses; hair cosmetics such as hair dyes and hair nourishes; and basic cosmetics such as creams, lotions, colognes and packs;
Make-up cosmetics such as whitening, foundation, blusher, etc., aromatic cosmetics such as perfume, tanning, sunscreen cosmetics, lip cosmetics such as lipstick, lip balm, oral cosmetics such as toothpaste, mouthwash, bath cosmetics etc. Various cosmetics, deodorants, fragrances such as indoor air fresheners; health and sanitary materials such as disinfectants and insecticides, bleaching agents, softeners, dishwashing detergents or laundry detergents.

[0009]

BEST MODE FOR CARRYING OUT THE INVENTION The new kind of rose-like fragrance referred to in the present invention means a fragrance reminiscent of the fragrance of a rose that currently exists. Rose varieties can be anything that currently exists, but specifically Rose Hero or Rose THELMA
And the like.

General formula used in the fragrance composition of the present invention
Specific examples of the compound (1) include 4-anisaldehyde and 4
-Anisic acid. These are known compounds and can be purchased. A specific compound of the general formula (2) is 4
-Vinylanisole and 4-vinylphenol. These are all known compounds, 4-vinylanisole can be purchased, and 4-vinylphenol is known, for example, JACS, (80), 3645 (1958) and JOC, (24),
1345 (1959).

JP-A-8-73885 discloses that vinylanisole has a fresh floral character and is excellent in natural feeling. Further, Japanese Patent Application Laid-Open
JP 31487 discloses that a fragrance composition characterized by containing vinylanisole has a sedative effect. However, there is no suggestion about a rose-like odor, and no mention is made of a combination with a compound represented by the general formula (1).

Compounds of the general formula (1) Any combination of the compounds of the general formula (2) may be used, but a combination of 4-anisaldehyde and 4-vinylanisole is particularly preferred from the viewpoint of freshness and palatability.

The content ratio and content of the compound of the general formula (1) and the general formula (2) in the fragrance composition of the present invention may be appropriately determined depending on the purpose of use, and are not particularly limited. In terms of the aroma of a new kind of rose, the total amount of the compound of the general formula (1) is 1: 1 with respect to the total amount of the compound of the general formula (2).
The weight ratio is preferably used in a ratio of 1 to 100: 1, more preferably 1: 1 to 10: 1.

Further, the general formula in the fragrance composition of the present invention
The total content of the total amount of the compound of (1) and the total amount of the compound of the general formula (2) is generally considered to be in the range of 5 to 80% by weight, but is preferably in the range of 5 to 50% by weight. And 5
Most preferred is a range of -30% by weight. By using an amount within this range, it is possible to give the fragrance composition a heliotrope-like freshness peculiar to a new rose, and a fragrance excellent in diffusivity and persistence, which is characteristic of a natural new rose. Outside of these ranges, the balance of the new rose-like aroma will be lost.

The fragrance composition of the present invention thus obtained is used for providing various cosmetics, fragrances, health and hygiene materials, etc. containing the fragrance composition as a fragrance component. That is, washing cosmetics such as soaps, shampoos and rinses, hair cosmetics such as hair dyes and hair nourishes, basic cosmetics such as creams, lotions, colognes and packs, make-up cosmetics such as whitening, foundations, blushers, perfumes, etc. Aroma cosmetics, suntan, sunscreen cosmetics, lip cosmetics such as lipstick, lip balm, oral cosmetics such as toothpaste, mouthwash, various cosmetics such as bath cosmetics; deodorants, indoor air fresheners and other fragrances; disinfectants Health and hygiene materials such as pesticides; other bleaching agents, softeners, dishwashing detergents, laundry detergents, etc., in an appropriate amount capable of imparting the scent, imparting and enhancing rose-like scent,
It can be strengthened and changed, and can enhance the commercial value of various cosmetics, fragrances, and other health and hygiene materials containing this as an aroma component.

[0016]

The present invention will be described below with reference to examples, but the present invention is not limited to these examples. Example 1 Each component was combined according to the formulation shown in Table 1 below, and stirred to prepare a new rose-like perfume base.

[0017]

[Table 1]

Comparative Examples 1 and 2 Each component was combined according to the formulation shown in Table 2 below and stirred to prepare a fragrance base.

[0019]

[Table 2]

The fragrance compositions prepared in Example 1 and Comparative Examples 1 and 2 were subjected to a sensory evaluation by five expert panelists, and the results are shown in Table 3.

[0021]

[Table 3]

Example 2 Ingredients were combined according to the formulation shown in Table 4 below and stirred to prepare a fragrance composition for shampoo having a new kind of fragrance.

[0023]

[Table 4]

Example 3 Ingredients were combined according to the formulation shown in Table 5 below and stirred to prepare a fragrance composition for cologne having a new kind of rose-like aroma.

[0025]

[Table 5]

Example 4 A perfume composition for skin care, a perfume composition for room fragrance, and a perfume composition for soap having a new kind of rose-like fragrance were prepared by mixing and stirring each component with the formulation shown in Table 6 below. did.

[0027]

[Table 6]

Example 5 A skin cosmetic (lotion) was prepared according to the formulation shown in Table 7 below by a conventional method.

[0029]

[Table 7]

Example 6 Make-up cosmetic (lipstick) according to the formulation shown in Table 8 below
Was prepared by a conventional method. As the fragrance in Table 8, a fragrance composition having a new kind of rose-like fragrance prepared by mixing and stirring each component with the formulation shown in Table 9 below was used.

[0031]

[Table 8]

[0032]

[Table 9]

A shampoo was prepared by a conventional method according to the formulation shown in Table 10 below.

[0034]

[Table 10]

[0035]

According to the present invention, a new kind of rose-like fragrance composition can be provided, and various cosmetics and fragrances having a new kind of rose-like fragrance containing the fragrance composition as a fragrance component , Health and hygiene materials, etc. can be provided.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification Symbol FI Theme Court ゛ (Reference) A61K 7/025 A61K 7/025 7/075 7/075 7/46 7/46 A 371 371 (72) Invention Person Masataka Miyasaka 1-4-11, Nishi-Hachiman, Hiratsuka-shi, Kanagawa Prefecture Inside the R & D Center, Takasago International Co., Ltd. (72) Inventor Ryoichi Komaki 5-28, Kotobukicho, Odawara-shi, Kanagawa Prefecture Kanebo Co., Ltd. (72) Inventor Yoshikuni Yamashita 5-28, Kotobuki-cho, Odawara-shi, Kanagawa Prefecture Kanebo Cosmetics Research Institute (72) Inventor Yasushi Suzuki 5-28, Kotobukicho, Odawara-shi, Kanagawa Kanebo Cosmetics Co., Ltd. F-term in the laboratory (reference) 4C083 AA032 AA122 AB242 AC012 AC022 AC102 AC122 AC352 AC422 AC442 AC471 AC472 AC482 AC642 AC712 AC792 AC852 AD022 AD072 AD152 AD162 AD642 BB41 BB60 CC0 4 CC13 DD23 EE06 4H059 BA14 BA17 BA20 BA26 BB14 BB45 DA09

Claims (3)

[Claims] [Claim 1] General formula (1) (Wherein R ¹ represents H or OH) and at least one compound represented by the general formula (2): (In the formula, R ² represents H or a methyl group.) A fragrance composition comprising at least one compound represented by the formula: 2. The compound of the general formula (1) and the compound of the general formula (2) are mixed at a weight ratio of (1) :( 2) = 1: 1 to 100: 1 and a total of 5 for both compounds. The fragrance composition according to claim 1, wherein the fragrance composition is contained in an amount of from 80 to 80% by weight. 3. A compound of the general formula (1) (Wherein R ¹ represents H or OH) and at least one compound represented by the general formula (2): (In the formula, R ² represents H or a methyl group.) A cosmetic comprising at least one compound represented by the formula: