JP2002018422A - Formed body for treating pollutant - Google Patents
Formed body for treating pollutantInfo
- Publication number
- JP2002018422A JP2002018422A JP2000201337A JP2000201337A JP2002018422A JP 2002018422 A JP2002018422 A JP 2002018422A JP 2000201337 A JP2000201337 A JP 2000201337A JP 2000201337 A JP2000201337 A JP 2000201337A JP 2002018422 A JP2002018422 A JP 2002018422A
- Authority
- JP
- Japan
- Prior art keywords
- bacterial bed
- shape
- bed
- bacterial
- pollutant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003344 environmental pollutant Substances 0.000 title abstract description 9
- 231100000719 pollutant Toxicity 0.000 title abstract description 9
- 230000001580 bacterial effect Effects 0.000 claims abstract description 44
- 239000002699 waste material Substances 0.000 claims abstract description 10
- 239000000356 contaminant Substances 0.000 claims description 23
- 239000000126 substance Substances 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 24
- 241000894006 Bacteria Species 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 239000004745 nonwoven fabric Substances 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229920003002 synthetic resin Polymers 0.000 abstract description 2
- 239000000057 synthetic resin Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 12
- 241000233866 Fungi Species 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 102000004190 Enzymes Human genes 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 3
- 102220201851 rs143406017 Human genes 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 2
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 2
- 239000003708 ampul Substances 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000004045 organic chlorine compounds Chemical class 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- -1 aromatic carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
Landscapes
- Apparatus Associated With Microorganisms And Enzymes (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】この発明は、廃棄物や汚染土
壌に含まれて環境に悪影響を及ぼす難分解性物質を分解
処理する汚染物質処理成形体および汚染物質処理材に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pollutant-treated molded article and a pollutant-treating material for decomposing and treating hard-to-decompose substances contained in waste or contaminated soil and adversely affecting the environment.
【0002】[0002]
【従来の技術】近年、廃棄物焼却場の近辺土壌が、焼却
灰に含まれるダイオキシン、トリクロロエチレン、テト
ラクロロエチレン等の有機塩素系化合物で汚染されてい
るとして大きな社会問題となっている。また、有機塩素
系化合物のほか、基板洗浄用溶剤、ベンゾピレン等の芳
香族炭水化物や、水銀系物質等の難分解性物質である汚
染物質により土壌が汚染されているとして問題となって
いるところもある。2. Description of the Related Art In recent years, soil near a waste incineration plant has become a major social problem because it is contaminated with organochlorine compounds such as dioxin, trichloroethylene and tetrachloroethylene contained in incineration ash. In addition to organic chlorine compounds, solvents for cleaning substrates, aromatic carbohydrates such as benzopyrene, and other substances that are contaminated with contaminants that are hardly decomposable substances, such as mercury substances, have also caused problems. is there.
【0003】この問題に取り組むにあたり、本発明者ら
は、キノコ類、例えば白色腐朽菌類を植菌してその菌糸
を生育させるためにオガクズ、培地添加物および水を混
合した菌床を、上記汚染物質やそれら汚染物質を含む汚
染土に混ぜ込むと、発育する菌糸と、菌が発生する分解
酵素との相乗効果により上記汚染物質が分解されるとい
う事実を知見した。なお、本明細書では食用キノコを植
菌・育成するための菌床を特に食用菌菌床と称する。ま
た、本発明者らは、上記菌床で成長したキノコを採取し
おわった利用済みの菌床であって、従来は廃棄されてき
た廃菌床を上記汚染物質や汚染土に混ぜた場合にも、同
様に汚染物質が分解されることも知見した。[0003] In addressing this problem, the present inventors have developed a bacterial bed containing a mixture of sawdust, medium additives and water in order to inoculate mushrooms, for example, white-rot fungi, and to grow their hyphae. It has been found that when mixed with contaminated soil containing substances or contaminants, the contaminants are decomposed by the synergistic effect of the growing mycelium and the decomposing enzyme generated by the fungi. In this specification, a bacterial bed for inoculating and growing edible mushrooms is particularly referred to as an edible bacterial bed. In addition, the present inventors have collected used mushrooms grown on the above-mentioned fungus bed, and used the fungus bed, which was conventionally discarded when the waste fungus bed was mixed with the contaminants or contaminated soil. Also found that pollutants were similarly degraded.
【0004】そこで、これら食用菌菌床および廃菌床等
の菌床や、これを粉砕した粉砕物、あるいはこの粉砕物
を水に溶かしてスラリー状にしたものを汚染土壌に混
合、撹拌または注入することにより添加して汚染物質を
分解処理してきた。[0004] Therefore, bacterial beds such as edible bacterial beds and waste bacterial beds, crushed materials obtained by crushing them, or slurries obtained by dissolving the crushed materials in water are mixed, stirred or injected into contaminated soil. This has been added to decompose contaminants.
【0005】[0005]
【発明が解決しようとする課題】ところが、前述のよう
な方法で菌床を汚染土壌に添加する場合、土壌改良用や
整地用の機械を用いて大量の菌床を土壌に混ぜ込む作業
が必要であり、作業に多大な労力を要した。また、菌床
と汚染土とを単に混ぜ合わせるだけの上記方法によって
は、特に法面のような傾斜地において、降雨等により菌
床が土壌表面から流れ出てしまい、汚染物質を十分に分
解処理することができなかった。However, when a bacterial bed is added to contaminated soil by the method described above, it is necessary to mix a large amount of the bacterial bed into the soil using a soil improvement or leveling machine. This required a lot of work. In addition, according to the above method of merely mixing the bacterial bed with the contaminated soil, the bacterial bed may flow out of the soil surface due to rainfall and the like, particularly on a slope such as a slope, and the pollutant is sufficiently decomposed. Could not.
【0006】そこで、本発明は、汚染物質処理能力を有
する菌床を、取扱い易く、且つ降雨等により土壌表面か
ら流出したり、型くずれしたりしないような態様で提供
することを目的とする。Accordingly, an object of the present invention is to provide a fungal bed having a contaminant treating ability in a form that is easy to handle and does not flow out of the soil surface or lose its shape due to rainfall or the like.
【0007】[0007]
【課題を解決するための手段】上記目的を達成するため
に、本発明は、汚染物質処理能力のある菌床をマット
状、バー状、ブロック状ないしは球状の適宜な形状に成
形してなる汚染物質処理成形体を提供する。この汚染物
質処理成形体は、その外側または内部に設けられ、当該
成形体の形状を保形する保形手段を用いていてもよい。
また、前記菌床は、食用菌菌床または廃菌床であること
が好ましい。In order to achieve the above-mentioned object, the present invention provides a method of forming a bacterial bed having a capability of treating contaminants into a mat, bar, block or spherical shape. A material-treated molded article is provided. The contaminated material-treated molded body may be provided on the outside or inside thereof, and may use shape keeping means for keeping the shape of the molded body.
Further, it is preferable that the bacterial bed is an edible bacterial bed or a waste bacterial bed.
【0008】[0008]
【発明の実施の形態】以下、本発明の汚染物質処理成形
体について実施例をあげて説明する。例えば、汚染物質
処理能力のある食用菌菌床および廃菌床等の菌床を粉砕
し、この粉体菌床を水に溶かしてスラリー状の懸濁液に
する。この懸濁液に、菌床の形状を保形する保形手段と
して廃植物繊維等(例えば藁)の補強用長繊維を混練
し、これを適宜な形状・大きさの成形型にてマット状、
バー状、ブロック状や球状等に成形して、汚染物質処理
成形体を作成する。BEST MODE FOR CARRYING OUT THE INVENTION The contaminated substance-treated molded article of the present invention will be described below with reference to examples. For example, bacterial beds such as an edible bacterial bed and a waste bacterial bed capable of treating contaminants are pulverized, and the powdered bacterial bed is dissolved in water to form a slurry suspension. This suspension is kneaded with reinforcing long fibers such as waste plant fibers (for example, straw) as a shape-retaining means for maintaining the shape of the bacterial bed, and the resulting mixture is matted in a mold having an appropriate shape and size. ,
It is shaped into a bar, block, or sphere to form a contaminated material-treated molded body.
【0009】一方、図1は、合成樹脂や可撓性の金属等
により作成した適宜な形状・大きさのラビリンス構造1
の間隙にほぐした菌床2を入れ込み、全体をマット状に
成形した例を示している。さらに、このように作成した
成形体の表面を不織布で被覆して、菌床の流出を防止す
る効果を更に高めてもよい。また、ラビリンス構造1の
間隙にほぐした菌床2を入れ込み、バー状、ブロック
状、球状等に成形することもできる。On the other hand, FIG. 1 shows a labyrinth structure 1 of an appropriate shape and size made of a synthetic resin, a flexible metal or the like.
2 shows an example in which the loosened bacterial bed 2 is put into the gap and is entirely formed into a mat shape. Furthermore, the surface of the molded body thus formed may be covered with a nonwoven fabric to further enhance the effect of preventing the outflow of the bacterial bed. Alternatively, the loosened bacterial bed 2 may be inserted into the gap of the labyrinth structure 1 and formed into a bar shape, a block shape, a spherical shape, or the like.
【0010】マット状の汚染物質処理成形体の場合、汚
染物質が含まれる汚染土壌の表面にこのマット状の成形
体を敷設してもよいし、汚染物質が含まれる汚染土中に
このマット状の汚染物質処理成形体を投げ込んでいき、
汚染土と成形体とが積層状態になるようにしてもよい。
バー状、ブロック状や球状の汚染物質処理成形体の場合
は、汚染物質が含まれる汚染土壌にこの成形体を押し込
んで挿入したり、あるいはこの成形体を汚染土に適宜投
げ込んだりして供給すればよい。[0010] In the case of a mat-shaped contaminated substance-treated molded article, the mat-shaped molded article may be laid on the surface of contaminated soil containing the contaminant, or the mat-shaped contaminated soil may be placed in the contaminated soil containing the contaminant. Throwing the pollutant-treated molded body of
The contaminated soil and the compact may be in a laminated state.
In the case of a bar-shaped, block-shaped or spherical contaminated material-treated compact, the compact must be supplied by pushing it into the contaminated soil containing the pollutant, or by throwing the compact into the contaminated soil as appropriate. I just need.
【0011】上述したように、菌床をマット状、バー
状、ブロック状または球状等に成形して汚染物質処理成
形体とすることにより、菌床を供給するにあたりその取
扱いが容易になり、菌床を汚染土全体に均等に分布させ
ることができる。また、菌床を成形してあるので、法面
のような傾斜地においても降雨等により菌床が流出しに
くくなるだけでなく、嵩比重を小さくでき、運搬コスト
を低減することもできる。特にマット状の汚染物質処理
成形体にあっては、菌床の流出抑制効果に優れる。As described above, the bacterial bed is formed into a mat-like, bar-like, block-like, or spherical shape to obtain a contaminated material-treated molded body, which facilitates handling of the bacterial bed when supplying the bacterial bed. The floor can be evenly distributed over the contaminated soil. In addition, since the microbial bed is formed, the microbial bed hardly flows out due to rainfall and the like even on a slope such as a slope, the bulk specific gravity can be reduced, and the transportation cost can be reduced. Particularly, the mat-shaped contaminant-treated molded article is excellent in the effect of suppressing the outflow of the bacterial bed.
【0012】数週間経過すると、汚染土に混合した菌床
から菌糸が成長するとともに、この増殖過程で分解酵素
が発生する。そして成長した菌糸と分解酵素との相乗効
果により、廃棄物中の汚染物質が分解され無害化され
る。例えば、アントラセン、ピレン、フェナントレンで
あれば1ヶ月で200ppmが90%減少し、ベンツピレ
ンであれば60%減少する。ダイオキシンに関しては2
0000pg TEQ/gが2ヶ月で60%程度減少する。After several weeks, hyphae grow from the bacterial bed mixed with the contaminated soil, and decomposing enzymes are generated during this growth process. The contaminants in the waste are decomposed and made harmless by the synergistic effect of the grown hypha and the decomposing enzyme. For example, in the case of anthracene, pyrene and phenanthrene, 200 ppm is reduced by 90% in one month, and in case of benzpyrene, it is reduced by 60%. About dioxin 2
0000pg TEQ / g decreases by about 60% in 2 months.
【0013】なお、汚染物質処理能力のある食用菌菌床
および廃菌床等の菌床や、これを粉砕することにより得
られる粉体菌床を、水や空気を流通させることができ且
つ成長した菌糸が通過することのできる適宜な大きさの
袋に封入して汚染物質処理材を作成したり、粉砕した菌
床を水等の溶液に溶解した溶解液をアンプル等の適宜な
形状の容器に封入して汚染物質処理材として用いたりす
ることもできる。[0013] The germ beds, such as edible bacterial beds and waste bacterial beds, capable of treating contaminants, and powdered bacterial beds obtained by pulverizing the same, have been made to be able to flow water and air and have grown. A contaminant treatment material is prepared by enclosing in a bag of an appropriate size through which mycelium can pass, or a solution obtained by dissolving a crushed bacterial bed in a solution such as water in a container of an appropriate shape such as an ampule. It can also be sealed and used as a contaminant treatment material.
【0014】このような汚染物質処理材を袋ごと汚染土
壌中に埋めたり、袋から菌床を取り出して、または、ア
ンプルを切断して菌床の溶解液を取り出して土壌に撒い
たりすることにより、菌床から成長した菌糸と分解酵素
との相乗効果により、汚染土壌中の汚染物質を分解処理
することができる。By burying such a contaminant-treating material together with the bag in the contaminated soil, taking out the bacterial bed from the bag, or cutting the ampoule to take out the solution of the bacterial bed and spraying it on the soil. The contaminants in the contaminated soil can be decomposed by the synergistic effect of the hypha and the decomposing enzyme grown from the bacterial bed.
【0015】[0015]
【発明の効果】本発明の汚染物質処理成形体および汚染
物質処理材によれば、汚染物質処理能力を有する菌床
は、マット状、バー状、ブロック状ないしは球状の適宜
な形状に成形されていたり、ラビリンス構造、補強用繊
維や不織布等の保形手段によって保形されていたり、袋
や容器に封入されていたりするので、菌床を供給するに
あたりその取扱いが容易になるとともに、菌床が降雨等
により土壌表面から流出したり、型くずれしたりするの
を防ぐことができる。また、本発明の汚染物質処理成形
体は菌床を成形してなるので、嵩比重を小さくでき、運
搬コストを低減することができる。According to the contaminant-treated molded article and the contaminant-treated material of the present invention, the bacterial bed having the contaminant-treating ability is formed into an appropriate mat, bar, block or spherical shape. Or it is kept in a shape such as labyrinth structure, reinforcing fiber or non-woven fabric, or enclosed in a bag or container. It can be prevented from flowing out of the soil surface due to rainfall and the like, and from being out of shape. Further, since the contaminant-treated molded article of the present invention is formed by forming a bacterial bed, the bulk specific gravity can be reduced, and the transportation cost can be reduced.
【図1】本発明の汚染物質処理成形体の一実施形態を示
す斜視図である。FIG. 1 is a perspective view showing one embodiment of a contaminant-treated molded article of the present invention.
1 ラビリンス構造 2 菌床 1 Labyrinth structure 2 Bacteria bed
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C12R 1:645) C12R 1:645) (C12N 1/00 B09B 3/00 E C12R 1:645) ZABA (72)発明者 岡田 俊也 東京都清瀬市下清戸4丁目640番地 株式 会社大林組技術研究所内 (72)発明者 大出 英子 東京都清瀬市下清戸4丁目640番地 株式 会社大林組技術研究所内 (72)発明者 辻 博和 東京都清瀬市下清戸4丁目640番地 株式 会社大林組技術研究所内 Fターム(参考) 4B029 AA03 AA08 BB09 CC03 CC10 4B065 AA71X AC20 BA22 BB04 BC41 BD05 CA56 4D004 AA41 AA46 AB03 AB05 AB06 AB07 AC07 CA18 CA50 CC07 CC08 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C12R 1: 645) C12R 1: 645) (C12N 1/00 B09B 3/00 E C12R 1: 645) ZABA ( 72) Inventor Toshiya Okada 4-640 Shimoseito, Kiyose-shi, Tokyo Inside the Obayashi-Gumi Technical Research Institute (72) Inventor Eiko Oide 4-640 Shimoseito, Kiyose-shi, Tokyo In the Obayashi-Gumi Technical Research Institute (72) Inventor Tsuji Hirowa 4-640 Shimoseito, Kiyose-shi, Tokyo F-term in Obayashi Corporation Technical Research Institute Co., Ltd. (reference)
Claims (3)
状、バー状、ブロック状ないしは球状の適宜な形状に成
形してなる汚染物質処理成形体。1. A contaminant-treated molded article obtained by molding a bacterial bed capable of treating contaminants into an appropriate shape such as a mat, a bar, a block, or a sphere.
部に設けられ、当該成形体の形状を保形する保形手段を
備えてなる請求項1に記載の汚染物質処理成形体。2. The contaminated substance-treated molded article according to claim 1, further comprising a shape-retaining means provided outside or inside the contaminated substance-treated molded article to retain the shape of the molded article.
あることを特徴とそる請求項1〜2のいずれかに記載の
汚染物質処理成形体。3. The contaminant-treated molded article according to claim 1, wherein the bacterial bed is an edible bacterial bed or a waste bacterial bed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000201337A JP2002018422A (en) | 2000-07-03 | 2000-07-03 | Formed body for treating pollutant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000201337A JP2002018422A (en) | 2000-07-03 | 2000-07-03 | Formed body for treating pollutant |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2002018422A true JP2002018422A (en) | 2002-01-22 |
Family
ID=18699051
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000201337A Pending JP2002018422A (en) | 2000-07-03 | 2000-07-03 | Formed body for treating pollutant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2002018422A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007030671A2 (en) * | 2005-09-07 | 2007-03-15 | Amcol International Corporation | Bioremediation mat and method of manufacture and use |
US7575682B2 (en) | 2003-11-19 | 2009-08-18 | Amcol International Corporation | Contaminant-reactive geocomposite mat and method of manufacture and use |
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US7419593B2 (en) | 2003-11-19 | 2008-09-02 | Amcol International Corp. | Bioremediation mat and method of manufacture and use |
US7575682B2 (en) | 2003-11-19 | 2009-08-18 | Amcol International Corporation | Contaminant-reactive geocomposite mat and method of manufacture and use |
US7854330B2 (en) | 2003-11-19 | 2010-12-21 | Amcol International Corporation | Contaminant-reactive geocomposite mat and method of manufacture and use |
WO2007030671A2 (en) * | 2005-09-07 | 2007-03-15 | Amcol International Corporation | Bioremediation mat and method of manufacture and use |
WO2007030671A3 (en) * | 2005-09-07 | 2007-09-07 | Amcol International Corp | Bioremediation mat and method of manufacture and use |
US8262318B2 (en) | 2007-04-30 | 2012-09-11 | Amcol International Corporation | Contaminant-reactive gabion cage or grid structure and method of manufacture and use |
JP2010253421A (en) * | 2009-04-27 | 2010-11-11 | Daiwa House Industry Co Ltd | Activated carbon mat and method for purifying soil contaminated with hydrocarbon |
CN105964685A (en) * | 2016-07-01 | 2016-09-28 | 山东浩阳新型工程材料股份有限公司 | Device and method using microorganisms for treating petroleum pollution soil |
CN105964685B (en) * | 2016-07-01 | 2022-04-19 | 浩阳环境股份有限公司 | Device and method for treating petroleum-polluted soil by using microorganisms |
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