JP2002018385A - Contaminant disposal method for existing waste treating plant - Google Patents
Contaminant disposal method for existing waste treating plantInfo
- Publication number
- JP2002018385A JP2002018385A JP2000201334A JP2000201334A JP2002018385A JP 2002018385 A JP2002018385 A JP 2002018385A JP 2000201334 A JP2000201334 A JP 2000201334A JP 2000201334 A JP2000201334 A JP 2000201334A JP 2002018385 A JP2002018385 A JP 2002018385A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- soil
- agitating vane
- mushroom beds
- bacterial bed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000002699 waste material Substances 0.000 title claims abstract description 21
- 239000000356 contaminant Substances 0.000 title abstract description 22
- 239000002689 soil Substances 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 19
- 230000001580 bacterial effect Effects 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 9
- 239000003344 environmental pollutant Substances 0.000 claims description 8
- 231100000719 pollutant Toxicity 0.000 claims description 8
- 238000002347 injection Methods 0.000 claims description 3
- 239000007924 injection Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- 235000001674 Agaricus brunnescens Nutrition 0.000 abstract description 8
- 238000000354 decomposition reaction Methods 0.000 abstract description 2
- 230000035515 penetration Effects 0.000 abstract description 2
- 238000009412 basement excavation Methods 0.000 abstract 1
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 5
- 241000233866 Fungi Species 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 3
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 3
- 150000004045 organic chlorine compounds Chemical class 0.000 description 3
- 229950011008 tetrachloroethylene Drugs 0.000 description 3
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 3
- FMMWHPNWAFZXNH-UHFFFAOYSA-N Benz[a]pyrene Chemical compound C1=C2C3=CC=CC=C3C=C(C=C3)C2=C2C3=CC=CC2=C1 FMMWHPNWAFZXNH-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 101100325793 Arabidopsis thaliana BCA2 gene Proteins 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- -1 aromatic carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Abstract
Description
【0001】[0001]
【発明の属する技術分野】この発明は、既設の廃棄物処
理場に存在し環境に悪影響を及ぼす難分解性の汚染物質
を、汚染物質分解能力を有する菌床を用いて分解処理す
る方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for decomposing hard-to-decompose contaminants existing in an existing waste disposal site and adversely affecting the environment by using a bacterial bed capable of decomposing contaminants.
【0002】[0002]
【従来の技術】従来、汚染物質を微生物によって分解し
無害化する技術として、バイオレメディエーションとい
う手法が知られている。これは細菌やカビの分解能力を
利用して汚染物質を分解するというものである。たしか
にこのバイオレメディエーション法では、薬剤を一切使
用しないので、低コストで安全に汚染物質を分解するこ
とができる。2. Description of the Related Art Conventionally, a technique called bioremediation is known as a technique for decomposing contaminants with microorganisms to render them harmless. It uses the ability of bacteria and mold to decompose and decomposes pollutants. Certainly, in this bioremediation method, no drug is used, and contaminants can be decomposed safely at low cost.
【0003】ところで、既設の廃棄物処理場において
は、ダイオキシン、トリクロロエチレン、テトラクロロ
エチレン等の有機塩素化合物や、その他の難分解性物質
が汚染物質として大量に存在することが問題となってい
る。これらの汚染物質をそのままの状態に放置しておく
と、有害ガスが周辺に拡散したり、雨水によって汚染物
質が地下水に混入したりして、周辺環境に悪影響を及ぼ
しかねない。[0003] In existing waste treatment plants, there is a problem in that organic chlorine compounds such as dioxin, trichloroethylene and tetrachloroethylene and other hardly decomposable substances are present in large quantities as pollutants. If these contaminants are left as they are, harmful gases may diffuse to the surroundings, or the contaminants may be mixed into groundwater by rainwater, which may adversely affect the surrounding environment.
【0004】[0004]
【発明が解決しようとする課題】しかしながら、バイオ
レメディエーション法で使用される細菌やカビによって
は、上述したようなダイオキシン、トリクロロエチレ
ン、テトラクロロエチレン等の有機塩素系化合物や、そ
の他の難分解性物質である汚染物質を分解することはで
きなかった。このため、このような汚染物質は既設の廃
棄物処理場においては処理されずに放置されてきたのが
実状である。However, depending on the bacterium and mold used in the bioremediation method, the aforementioned organic chlorine-based compounds such as dioxin, trichloroethylene and tetrachloroethylene, and other pollutants that are difficult to decompose. The substance could not be decomposed. For this reason, such pollutants have been left untreated at existing waste disposal sites.
【0005】ところで、キノコ類、例えば白色腐朽菌類
を植菌し、その菌糸を生育させるために、オガクズと、
培地添加物と、水とを混合した菌床が従来より用いられ
てきた。なお、本明細書では食用キノコを植菌・育成す
るための菌床を特に食用菌菌床と称する。さて、本発明
者らは、この菌床を、上記汚染物質(例えばダイオキシ
ン等の有機塩素系化合物、基板洗浄用溶剤、ベンゾピレ
ン等の芳香族炭水化物、水銀系物質等の難分解性物質)
や汚染物質を含む汚染土に混ぜ込むと、発育する菌糸
と、菌が発生する分解酵素との相乗効果により上記汚染
物質が分解されるという事実を知見した。また、上記菌
床で成長したキノコを採取しおわった利用済みの菌床で
あって、従来は廃棄されてきた廃菌床を上記汚染物質や
汚染土に混ぜた場合にも、同様に汚染物質が分解される
ことが分かった。By the way, in order to inoculate mushrooms, for example, white rot fungi, and grow their hyphae,
Bacterial beds in which a culture medium additive and water are mixed have conventionally been used. In this specification, a bacterial bed for inoculating and growing edible mushrooms is particularly referred to as an edible bacterial bed. Now, the present inventors use this bacterial bed as the contaminants (for example, organic chlorine compounds such as dioxin, solvents for cleaning substrates, aromatic carbohydrates such as benzopyrene, and hardly decomposable substances such as mercury materials).
It has been found that when mixed into contaminated soil containing water and contaminants, the contaminants are decomposed by the synergistic effect of the growing mycelium and the decomposing enzyme generated by the fungi. Also, when the used fungus bed obtained by collecting the mushrooms grown on the above-mentioned fungus bed, and the waste fungus bed that has been conventionally discarded is mixed with the above-mentioned contaminant or contaminated soil, the contaminant is similarly used. Was found to be decomposed.
【0006】一方、本発明者らは、粉体噴射撹拌(DJ
M)工法に着目した。この工法は、柱列杭工法やアース
オーガ工法に用いられるスクリュー式の機材を土壌中に
この機材を挿入し、機材を通じて改良材などの粉粒等を
土壌中に噴射供給して、供給した粉粒等と土壌とを撹拌
混合するというものである。[0006] On the other hand, the present inventors have proposed powder injection stirring (DJ
M) Focused on the construction method. In this method, screw-type equipment used for the pillar pile method and the earth auger method is inserted into the soil, and powder and the like such as an improving material are injected into the soil through the equipment to supply the supplied powder. This is to stir and mix the grains and the soil.
【0007】そこで本発明は、食用菌菌床や廃菌床等の
菌床を、例えば上記DJM工法のような工法に用いて、
既設の廃棄物処理場の土壌中に大量に含まれる汚染物質
を効果的に分解処理することを目的とする。Accordingly, the present invention provides a method of using a bacterial bed such as an edible bacterial bed or a waste bacterial bed in a method such as the DJM method.
The objective is to effectively decompose the pollutants contained in the soil at the existing waste disposal site in large quantities.
【0008】[0008]
【課題を解決するための手段】本発明は、粉体を噴射し
つつ撹拌する粉体噴射撹拌手段を用いて、既存の廃棄物
処理場の、汚染物質を含む汚染土および廃棄物等に、菌
床あるいはその粉砕物または溶解液を混入することによ
って汚染物質を処理する方法を提唱するものである。な
お、この方法において、前記菌床は食用菌菌床または廃
菌床であってもよい。SUMMARY OF THE INVENTION The present invention uses powder injection and agitation means for agitating a powder while injecting the same into a contaminated soil and waste containing contaminants at an existing waste treatment plant. The present invention proposes a method for treating contaminants by mixing a bacterial bed or a crushed or dissolved solution thereof. In this method, the bacterial bed may be an edible bacterial bed or a waste bacterial bed.
【0009】[0009]
【発明の実施の形態】以下に説明する本発明の汚染物質
処理方法の一実施形態では、図1に示すような改良機1
を用いたDJM工法により既設の廃棄物処理場に存在す
る汚染物質を処理する。DESCRIPTION OF THE PREFERRED EMBODIMENTS In one embodiment of the method for treating pollutants of the present invention described below, an improved machine 1 as shown in FIG.
Of contaminants existing in existing waste disposal sites by the DJM method using
【0010】はじめに、汚染物質処理能力のある菌床
(食用菌菌床または廃菌床)を粉砕して例えば直径5m
m程度の粉体状にしておき、改良機1にこの粉体菌床を
供給するための粉体供給手段に貯蔵しておく。なお、こ
の「5mm」という直径は、DJM工法の改良機1が扱
うことのできる粉体の最大直径である。First, a bacterial bed (edible bacterial bed or waste bacterial bed) capable of treating contaminants is crushed, for example, to a diameter of 5 m.
m, and stored in a powder supply means for supplying the powdered bacterial bed to the improvement machine 1. The diameter of “5 mm” is the maximum diameter of the powder that can be handled by the improved machine 1 of the DJM method.
【0011】一方、粉体菌床を供給すべき位置に改良機
1を固定する。そして改良機1の上下移動可能な撹拌翼
部2を回転させ、撹拌翼部2の底面に設けた掘削用ビッ
ト(図示せず)により汚染土壌を下方向に掘削して撹拌
翼部2を土中に貫入させる。貫入完了後、粉体供給手段
に貯蔵しておいた粉体菌床と空気とを改良機1に供給
し、撹拌翼部2を回転させつつ引き抜きながら粉体菌床
を土中に均等に散布する。このような作業を、ダイオキ
シン、トリクロロエチレン、テトラクロロエチレン等の
有機塩素化合物やその他の難分解性物質が汚染物質とし
て含まれる既設の廃棄物処理場において繰り返しおこな
い、処理場の汚染土壌全体に粉体菌床が分布するように
する。On the other hand, the improvement machine 1 is fixed at a position where the powdered bacterial bed is to be supplied. Then, the vertically movable stirring blade section 2 of the improvement machine 1 is rotated, and the contaminated soil is excavated downward by a drill bit (not shown) provided on the bottom surface of the stirring blade section 2 so that the stirring blade section 2 is soiled. Let it penetrate inside. After the penetration is completed, the bed of powdered bacteria and the air stored in the powder supply means are supplied to the improvement machine 1, and the bed of powdered bacteria is evenly dispersed in the soil while pulling out while rotating the stirring blade section 2. I do. Such work is repeated at existing waste treatment plants where organic chlorine compounds such as dioxin, trichloroethylene and tetrachloroethylene and other hardly decomposable substances are contained as contaminants. Are distributed.
【0012】その後数週間経過すると、土壌に撹拌・混
合した粉体菌床から菌糸が成長するとともに、この増殖
過程で分解酵素が発生する。そして成長した菌糸と分解
酵素との相乗効果により、汚染土中の汚染物質が分解さ
れ無害化される。例えば、アントラセン、ピレン、フェ
ナントレンであれば1ヶ月で200ppmが90%減少
し、ベンツピレンであれば60%減少する。ダイオキシ
ンに関しては20000pg TEQ/gが2ヶ月で60%程度
減少する。After several weeks, the mycelium grows from the powdered bacterial bed stirred and mixed with the soil, and a decomposing enzyme is generated in the growth process. The contaminants in the contaminated soil are decomposed and made harmless by the synergistic effect of the grown mycelium and the decomposing enzyme. For example, in the case of anthracene, pyrene and phenanthrene, 200 ppm is reduced by 90% in one month, and in case of benzpyrene, it is reduced by 60%. For dioxin, 20,000 pg TEQ / g is reduced by about 60% in 2 months.
【0013】なお、菌糸の成長や汚染物質の分解を促進
するために、必要に応じて、廃棄物処理場の土壌中にエ
アレーション用のパイプ等の給気手段を設けてもよい。
また、上記実施形態では、粉体菌床を供給するのにDJ
M工法を用いたが、菌床を廃棄物処理場の汚染土中に供
給・混合できるような方法であれば、どのような方法を
用いてもよい。さらに、廃棄物処理場の汚染土中に供給
する菌床は、必ずしも粉体状でなくてもよく、粉砕前の
状態の菌床を供給してもよいし、あるいは菌床の溶解液
を注入するようにしてもよい。[0013] In order to promote the growth of hyphae and the decomposition of pollutants, air supply means such as aeration pipes may be provided in the soil of the waste treatment plant as needed.
Further, in the above embodiment, DJ powder is supplied to supply the powdered bacterial bed.
Although the M method was used, any method may be used as long as it can supply and mix the bacterial bed into the contaminated soil of the waste treatment plant. Furthermore, the bacterial bed to be supplied into the contaminated soil at the waste disposal site does not necessarily need to be in the form of powder, and the bacterial bed before pulverization may be supplied, or a solution of the bacterial bed may be injected. You may make it.
【0014】[0014]
【発明の効果】本発明によれば、既設の廃棄物処理場の
汚染土壌中に菌床を供給・混合するだけで、汚染土壌に
大量に含まれる汚染物質を簡単な作業のみで分解するこ
とができる。According to the present invention, it is possible to decompose a large amount of contaminants contained in contaminated soil only by supplying and mixing bacterial beds into contaminated soil at an existing waste disposal site. Can be.
【図1】本発明をDJM工法に適用した実施形態の概略
図である。FIG. 1 is a schematic view of an embodiment in which the present invention is applied to a DJM method.
1 改良機 2 撹拌翼部 1 improved machine 2 stirring blade
───────────────────────────────────────────────────── フロントページの続き (72)発明者 岡田 俊也 東京都清瀬市下清戸4丁目640番地 株式 会社大林組技術研究所内 Fターム(参考) 4D004 AA41 AA46 AC07 BB03 CA15 CA18 CB27 CC07 ────────────────────────────────────────────────── ─── Continued on the front page (72) Inventor Toshiya Okada 4-640 Shimoseito, Kiyose-shi, Tokyo F-term in Obayashi Corporation Technical Research Institute Co., Ltd. 4D004 AA41 AA46 AC07 BB03 CA15 CA18 CB27 CC07
Claims (2)
手段を用いて、既存の廃棄物処理場の汚染土および廃棄
物等に、菌床あるいはその粉砕物または溶解液を混入す
ることによる汚染物質処理方法。1. Mixing a bacterial bed or its crushed material or a solution into contaminated soil and waste at an existing waste disposal site by using powder injection and stirring means for stirring while injecting powder. Pollutant treatment method.
あることを特徴とする請求項1に記載の汚染物質処理方
法。2. The method according to claim 1, wherein the bacterial bed is an edible bacterial bed or a waste bacterial bed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000201334A JP2002018385A (en) | 2000-07-03 | 2000-07-03 | Contaminant disposal method for existing waste treating plant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000201334A JP2002018385A (en) | 2000-07-03 | 2000-07-03 | Contaminant disposal method for existing waste treating plant |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2002018385A true JP2002018385A (en) | 2002-01-22 |
Family
ID=18699048
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000201334A Pending JP2002018385A (en) | 2000-07-03 | 2000-07-03 | Contaminant disposal method for existing waste treating plant |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2002018385A (en) |
-
2000
- 2000-07-03 JP JP2000201334A patent/JP2002018385A/en active Pending
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