JP2001507745A - ポリオレフィンとポリ(エチレンオキシド)とのブレンド及び該ブレンドの製造方法 - Google Patents
ポリオレフィンとポリ(エチレンオキシド)とのブレンド及び該ブレンドの製造方法Info
- Publication number
- JP2001507745A JP2001507745A JP53034398A JP53034398A JP2001507745A JP 2001507745 A JP2001507745 A JP 2001507745A JP 53034398 A JP53034398 A JP 53034398A JP 53034398 A JP53034398 A JP 53034398A JP 2001507745 A JP2001507745 A JP 2001507745A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- ethylene oxide
- polyolefin
- poly
- blend
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 90
- 229920003171 Poly (ethylene oxide) Polymers 0.000 title claims abstract description 88
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 88
- 238000004519 manufacturing process Methods 0.000 title description 6
- 238000000034 method Methods 0.000 claims abstract description 70
- 239000000178 monomer Substances 0.000 claims abstract description 54
- 239000003999 initiator Substances 0.000 claims abstract description 41
- -1 polyethylene Polymers 0.000 claims description 39
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical group CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 22
- 229920000573 polyethylene Polymers 0.000 claims description 16
- 239000004698 Polyethylene Substances 0.000 claims description 15
- 229920001684 low density polyethylene Polymers 0.000 claims description 12
- 239000004702 low-density polyethylene Substances 0.000 claims description 12
- 239000002202 Polyethylene glycol Substances 0.000 claims description 10
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 10
- 239000000155 melt Substances 0.000 claims description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims description 10
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- 239000004743 Polypropylene Substances 0.000 claims description 9
- 229920001903 high density polyethylene Polymers 0.000 claims description 9
- 239000004700 high-density polyethylene Substances 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 239000005977 Ethylene Substances 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 5
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 5
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
- LIZVXGBYTGTTTI-UHFFFAOYSA-N 2-[(4-methylphenyl)sulfonylamino]-2-phenylacetic acid Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(C(O)=O)C1=CC=CC=C1 LIZVXGBYTGTTTI-UHFFFAOYSA-N 0.000 claims description 4
- GLVYLTSKTCWWJR-UHFFFAOYSA-N 2-carbonoperoxoylbenzoic acid Chemical compound OOC(=O)C1=CC=CC=C1C(O)=O GLVYLTSKTCWWJR-UHFFFAOYSA-N 0.000 claims description 4
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 claims description 4
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims 6
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 claims 4
- PAOHAQSLJSMLAT-UHFFFAOYSA-N 1-butylperoxybutane Chemical compound CCCCOOCCCC PAOHAQSLJSMLAT-UHFFFAOYSA-N 0.000 claims 3
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 claims 3
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims 3
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 claims 3
- 150000001336 alkenes Chemical class 0.000 claims 2
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 claims 2
- 238000002360 preparation method Methods 0.000 claims 2
- 229930194542 Keto Natural products 0.000 claims 1
- 208000037062 Polyps Diseases 0.000 claims 1
- 238000004925 denaturation Methods 0.000 claims 1
- 230000036425 denaturation Effects 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 17
- 239000000463 material Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000000047 product Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 229920001577 copolymer Polymers 0.000 description 9
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 4
- 239000005022 packaging material Substances 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012968 metallocene catalyst Substances 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 239000004708 Very-low-density polyethylene Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 230000004043 responsiveness Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229920001866 very low density polyethylene Polymers 0.000 description 2
- 239000002982 water resistant material Substances 0.000 description 2
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- 206010021639 Incontinence Diseases 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- MKXKFYHWDHIYRV-UHFFFAOYSA-N flutamide Chemical compound CC(C)C(=O)NC1=CC=C([N+]([O-])=O)C(C(F)(F)F)=C1 MKXKFYHWDHIYRV-UHFFFAOYSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/931—Blend of stated incompatibility
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/777,226 | 1996-12-31 | ||
| US08/777,226 US5700872A (en) | 1996-12-31 | 1996-12-31 | Process for making blends of polyolefin and poly(ethylene oxide) |
| PCT/US1997/024246 WO1998029509A1 (en) | 1996-12-31 | 1997-12-19 | Blends of polyolefin and poly(ethylene oxide) and process for making the blends |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001507745A true JP2001507745A (ja) | 2001-06-12 |
| JP2001507745A5 JP2001507745A5 (enExample) | 2005-08-11 |
Family
ID=25109646
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53034398A Abandoned JP2001507745A (ja) | 1996-12-31 | 1997-12-19 | ポリオレフィンとポリ(エチレンオキシド)とのブレンド及び該ブレンドの製造方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US5700872A (enExample) |
| EP (1) | EP0951509B1 (enExample) |
| JP (1) | JP2001507745A (enExample) |
| KR (1) | KR100523502B1 (enExample) |
| CN (1) | CN1222575C (enExample) |
| AU (1) | AU729432B2 (enExample) |
| BR (1) | BR9713641A (enExample) |
| CA (1) | CA2275702A1 (enExample) |
| DE (1) | DE69720523T2 (enExample) |
| IL (1) | IL130568A (enExample) |
| WO (1) | WO1998029509A1 (enExample) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5916969A (en) * | 1996-11-22 | 1999-06-29 | Kimberly-Clark Corporation | Article and composition of matter made from polyolefins and PEO blend and method of making the same |
| US6255386B1 (en) | 1996-12-31 | 2001-07-03 | Kimberly-Clark Worldwide, Inc. | Blends of polyolefin and poly(ethylene oxide) and process for making the blends |
| US6111014A (en) * | 1996-12-31 | 2000-08-29 | Kimberly-Clark Worldwide, Inc. | Film of monomer-grafted polyolefin and poly(ethylene oxide) |
| US5912076A (en) | 1996-12-31 | 1999-06-15 | Kimberly-Clark Worldwide, Inc. | Blends of polyethylene and peo having inverse phase morphology and method of making the blends |
| US6100330A (en) * | 1996-12-31 | 2000-08-08 | Kimberly-Clark Worldwide, Inc. | Water-degradable film of monomer grafted to polyolefin and poly(ethylene oxide) |
| US6063866A (en) * | 1996-12-31 | 2000-05-16 | Kimberly-Clark Worldwide, Inc. | Blends of polyolefin and poly(ethylene oxide) and process for making the blends |
| US5976694A (en) | 1997-10-03 | 1999-11-02 | Kimberly-Clark Worldwide, Inc. | Water-sensitive compositions for improved processability |
| US6172177B1 (en) * | 1997-12-31 | 2001-01-09 | Kimberly-Clark Worldwide, Inc. | Grafted poly(ethylene oxide) compositions |
| US6090472A (en) * | 1997-12-31 | 2000-07-18 | Kimberly-Clark Worldwide, Inc. | Nonwoven, porous fabric produced from polymer composite materials |
| US6071451A (en) * | 1997-12-31 | 2000-06-06 | Kimberly-Clark Worldwide, Inc. | Process for making a nonwoven, porous fabric from polymer composite materials |
| US6372850B2 (en) | 1997-12-31 | 2002-04-16 | Kimberly-Clark Worldwide, Inc. | Melt processable poly (ethylene oxide) fibers |
| AU2022599A (en) * | 1997-12-31 | 1999-07-19 | Kimberly-Clark Worldwide, Inc. | Method of reducing molecular weights and polydispersity indices of polymers of ethylene oxide |
| WO1999034042A1 (en) | 1997-12-31 | 1999-07-08 | Kimberley-Clark Worldwide, Inc. | Flushable fiber compositions comprising modified polypropylene and modified poly(ethylene oxide) and process for making the same |
| WO1999033922A1 (en) * | 1997-12-31 | 1999-07-08 | Kimberly-Clark Worldwide, Inc. | Method of modifying poly(ethylene oxide) |
| US6117947A (en) * | 1997-12-31 | 2000-09-12 | Kimberly-Clark Worldwide, Inc. | Method of modifying poly(ethylene oxide) |
| AU2208299A (en) * | 1997-12-31 | 1999-07-19 | Kimberly-Clark Worldwide, Inc. | Flushable poly(ethylene oxide) films with balanced mechanical properties |
| US6350518B1 (en) | 1998-06-01 | 2002-02-26 | Kimberly-Clark Worldwide, Inc. | Methods of making blend compositions of an unmodified poly vinyl alcohol and a thermoplastic elastomer |
| US6410823B1 (en) * | 1998-06-30 | 2002-06-25 | Kimberly-Clark Worldwide, Inc. | Apertured film covers with localized wettability and method for making the same |
| US6369293B1 (en) | 1998-11-04 | 2002-04-09 | Kimberly-Clark Worldwide, Inc. | Absorbent composition including an uncrosslinked polymer |
| KR20010099995A (ko) * | 1998-12-29 | 2001-11-09 | 로날드 디. 맥크레이 | 열-활성화 접착제 |
| AR022140A1 (es) | 1998-12-31 | 2002-09-04 | Kimberly Clark Co | Una composicion de materia, una pelicula y un articulo que comprenden dicha composicion y el proceso para hacer dicha composicion |
| AU4681899A (en) * | 1999-06-07 | 2000-12-28 | Kimberly-Clark Worldwide, Inc. | Inverse phase blends of poly(ethylene oxide) and polyolefin and reactive extrusion method of making inverse phase blends |
| AU5897000A (en) * | 1999-06-29 | 2001-01-31 | Kimberly-Clark Worldwide, Inc. | Compositions comprising a blend of poly(ethylene oxide) and grafted polyolefin and method of making the same |
| US6580015B2 (en) * | 1999-09-14 | 2003-06-17 | Kimberly-Clark Worldwide, Inc. | Absorbent composition including an uncrosslinked polymer |
| US6444761B1 (en) | 1999-12-28 | 2002-09-03 | Kimberly-Clark Worldwide, Inc. | Water-soluble adhesive compositions |
| US6576576B1 (en) | 1999-12-29 | 2003-06-10 | Kimberly-Clark Worldwide, Inc. | Multicomponent fibers |
| US6610793B1 (en) | 2000-05-26 | 2003-08-26 | Kimberly-Clark Worldwide, Inc. | Modified poly(ethylene oxide), method of making same and articles using same |
| US6790519B1 (en) | 2000-05-26 | 2004-09-14 | Kimberly-Clark Worldwide, Inc. | Moisture-induced poly(ethylene oxide) gel, method of making same and articles using same |
| US6767961B1 (en) | 2000-06-19 | 2004-07-27 | Kimberly-Clark Worldwide, Inc. | Blends of poly (vinyl alcohol) and poly (ethylene oxide) and articles made therewith |
| US6958371B1 (en) | 2000-06-19 | 2005-10-25 | Kimberly-Clark Worldwide, Inc. | Method of making blends of poly(vinyl alcohol) and poly(ethylene oxide) |
| US6403706B1 (en) | 2000-12-28 | 2002-06-11 | Kimberly-Clark Worldwide, Inc. | Methods of making polymer/dispersed modifier compositions |
| US6607819B2 (en) | 2000-12-28 | 2003-08-19 | Kimberly-Clark Worldwide, Inc. | Polymer/dispersed modifier compositions |
| US6500897B2 (en) | 2000-12-29 | 2002-12-31 | Kimberly-Clark Worldwide, Inc. | Modified biodegradable compositions and a reactive-extrusion process to make the same |
| US6552124B2 (en) | 2000-12-29 | 2003-04-22 | Kimberly-Clark Worldwide, Inc. | Method of making a polymer blend composition by reactive extrusion |
| US6579934B1 (en) | 2000-12-29 | 2003-06-17 | Kimberly-Clark Worldwide, Inc. | Reactive extrusion process for making modifiied biodegradable compositions |
| US7053151B2 (en) | 2000-12-29 | 2006-05-30 | Kimberly-Clark Worldwide, Inc. | Grafted biodegradable polymer blend compositions |
| US6835708B2 (en) | 2001-03-07 | 2004-12-28 | Nippon Shokubai Co., Ltd. | Graft polymer composition and its production process and uses |
| US6890989B2 (en) | 2001-03-12 | 2005-05-10 | Kimberly-Clark Worldwide, Inc. | Water-responsive biodegradable polymer compositions and method of making same |
| US6509419B1 (en) * | 2001-07-12 | 2003-01-21 | Kimberly-Clark Worldwide, Inc. | Chemically modified polyethylene oxide compositions with improved environmental stability |
| US6515075B1 (en) | 2001-07-12 | 2003-02-04 | Kimberly-Clark Worldwide, Inc. | Films, fibers and articles of chemically modified polyethylene oxide compositions with improved environmental stability and method of making same |
| KR20030026459A (ko) * | 2001-09-25 | 2003-04-03 | 현대자동차주식회사 | 차량 범퍼 도장방법 |
| BR112015011656A2 (pt) * | 2012-12-04 | 2017-07-11 | Braskem Sa | método de compatibilização de blendas de polipropileno, blenda de polipropileno preparada, uso de uma blenda de polipropileno, produto de material processado, e, agente iniciador de compatibilização de blenda de polipropileno |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3323978A (en) * | 1963-05-09 | 1967-06-06 | Phillips Petroleum Co | Artificial textile fibres and their production |
| US3539666A (en) * | 1968-06-18 | 1970-11-10 | Grace W R & Co | Method for preparing a nonwoven fabriclike member |
| FR2045934A1 (enExample) * | 1969-06-09 | 1971-03-05 | Union Carbide Corp | |
| US3717541A (en) * | 1970-06-30 | 1973-02-20 | Grace W R & Co | Non-woven fabric-like member |
| US3954928A (en) * | 1970-07-28 | 1976-05-04 | Teijin Ltd. | Process for making sheet-formed reticulated fibrous structures |
| US3666737A (en) * | 1970-08-06 | 1972-05-30 | Goodyear Tire & Rubber | Method and process of preparing improved polyethers |
| BE789277A (fr) * | 1971-09-27 | 1973-03-26 | Union Carbide Corp | Composition de polymere d'ethylene degradable sous l'action desintemperies |
| JPS521740B2 (enExample) * | 1973-04-06 | 1977-01-18 | ||
| US4018729A (en) * | 1974-10-01 | 1977-04-19 | Union Carbide Corporation | Shaped article for conditioning hair a blend of water-soluble and water-insoluble polymers with interpenetrating networks |
| FR2336422A1 (fr) * | 1975-12-23 | 1977-07-22 | Ato Chimie | Procede de modification chimique de polyolefines en vue d'ameliorer leur mouillabilite |
| US4186233A (en) * | 1978-03-27 | 1980-01-29 | The Dow Chemical Company | Disposable composite insensitive to surface moisture but disintegratable in aqueous liquid |
| US4528334A (en) * | 1978-11-24 | 1985-07-09 | Union Carbide Corporation | Carboxylated poly(oxyalkylenes) |
| US4624051A (en) * | 1984-12-07 | 1986-11-25 | The Gillette Company | Shaving unit |
| JPS61272217A (ja) * | 1985-05-29 | 1986-12-02 | Ube Ind Ltd | ポリオレフイン樹脂組成物 |
| US4868222A (en) * | 1985-06-10 | 1989-09-19 | The Dow Chemical Company | Preparation of asymmetric membranes by the solvent extraction of polymer components from polymer blends |
| US5095619A (en) * | 1990-09-28 | 1992-03-17 | The Gillette Company | Shaving system |
| CA2050021C (en) * | 1990-10-16 | 2002-07-02 | Kimberly-Clark Worldwide, Inc. | Environmentally friendly polymeric web compositions |
| EP0503909A1 (en) * | 1991-03-14 | 1992-09-16 | Chevron Research And Technology Company | Substantially non-crosslinked maleic anhydride-modified ethylene polymers and process for preparing same |
| CA2065966A1 (en) * | 1991-04-23 | 1992-10-24 | Robert J. Petcavich | Disposable recyclable plastic articles and moldable synthetic resin blends for making the same |
| AU666592B2 (en) * | 1991-04-23 | 1996-02-15 | Robert J. Petcavich | Disposable degradable recyclable plastic articles and synthetic resin blends for making the same |
| NZ242597A (en) * | 1991-05-14 | 1995-07-26 | Grace W R & Co | Co-extruded water soluble laminated polymeric film and methods of extruding it |
| HK1006423A1 (en) * | 1991-06-26 | 1999-02-26 | The Procter & Gamble Company | Disposable absorbent articles with biodegradable backsheets |
| US5571878A (en) * | 1991-09-24 | 1996-11-05 | Chevron Chemical Company | Ethylene-alkyl acrylate copolymers and derivatives having improved melt-point temperatures and adhesive strength and processes for preparing same |
| EP0555197A3 (en) * | 1992-01-29 | 1993-11-18 | Monsanto Co | Antistatic agent for thermoplastic polymers |
| US5209849A (en) * | 1992-04-24 | 1993-05-11 | Gelman Sciences Inc. | Hydrophilic microporous polyolefin membrane |
| KR100262356B1 (ko) * | 1992-06-26 | 2000-09-01 | 데이비드 엠 모이어 | 생분해성 액체 불투과성 다층 필름 조성물 |
| CA2138121C (en) * | 1992-06-26 | 1999-02-23 | Andrew Julian Wnuk | Biodegradable, liquid impervious monolayer film compositions |
| US5369168A (en) * | 1992-08-03 | 1994-11-29 | Air Products And Chemicals, Inc. | Reactive melt extrusion grafting of thermoplastic polyvinyl alcohol/polyolefin blends |
| US5468259A (en) * | 1992-12-07 | 1995-11-21 | Sheth; Paresh J. | Dyeable polyolefin compositions and dyeing polyolefin compositions |
| DE4312753A1 (de) * | 1993-04-20 | 1994-10-27 | Basf Ag | Verwendung von Polyacetalen zur Herstellung von kompostierbaren Formkörpern, als Beschichtungsmittel und als Klebstoff |
| US5395308A (en) * | 1993-09-24 | 1995-03-07 | Kimberly-Clark Corporation | Thermoplastic applicator exhibiting accelerated breakup when immersed in water |
| US5415905A (en) * | 1993-09-29 | 1995-05-16 | Exxon Chemical Patents Inc. | Dispersible film |
| WO1995011929A1 (en) * | 1993-10-27 | 1995-05-04 | Chevron Chemical Company | Low-haze ionomers of copolymers of alpha-olefins, carboxylic acid esters, and optional comonomers, and processes for making and acidifying these ionomers |
| CA2128483C (en) * | 1993-12-16 | 2006-12-12 | Richard Swee-Chye Yeo | Flushable compositions |
| US5498785A (en) * | 1994-01-14 | 1996-03-12 | Chevron Chemical Company | Continuous process for the aminolysis of ethylene copolymers |
| SG49096A1 (en) * | 1994-01-28 | 1998-05-18 | Procter & Gamble | Biodegradable 3-polyhydtoxybuyrate/3- polyhydroxyhexanoate copolymer films |
| ZA95627B (en) * | 1994-01-28 | 1995-10-05 | Procter & Gamble | Biodegradable copolymers and plastic articles comprising biodegradable copolymers |
| ID23491A (id) * | 1994-01-28 | 1995-09-07 | Procter & Gamble | Kopolimer-kopolimer yang dapat dibiodegradasi dan baha-bahan plastik yang terdiri dari kopolimer-kopolimer yang dapat dibiodegradasi |
| BR9506664A (pt) * | 1994-01-28 | 1997-09-16 | Procter & Gamble | Copolímeros biodegradâveis e artigos plásticos compreendendo copolímeros biodegradâveis de 3-hidroxihexanoato |
| HUT78003A (hu) * | 1994-02-28 | 1999-05-28 | The Procter & Gamble Co. | Keverési eljárások biológiailag lebontható rostszálacskák, ezeket tartalmazó szövés nélküli anyagok és a szövés nélküli anyagokat tartalmazó cikkek előállítására |
| SG44660A1 (en) * | 1994-02-28 | 1997-12-19 | Procter & Gamble | Spray processes using a gaseous flow for preparing biodegradable fibrils nonwoven fabrics comprising biodegradable fibrils and articles comprising such nonwoven fabrics |
| US5549791A (en) * | 1994-06-15 | 1996-08-27 | The Procter & Gamble Company | Individualized cellulosic fibers crosslinked with polyacrylic acid polymers |
| US5472518A (en) * | 1994-12-30 | 1995-12-05 | Minnesota Mining And Manufacturing Company | Method of disposal for dispersible compositions and articles |
| US5759569A (en) * | 1995-01-10 | 1998-06-02 | The Procter & Gamble Company | Biodegradable articles made from certain trans-polymers and blends thereof with other biodegradable components |
| GB2295553B (en) * | 1995-02-09 | 1997-05-21 | Ecoprogress Ltd | A water dispersible bodily liquid absorbent composite |
-
1996
- 1996-12-31 US US08/777,226 patent/US5700872A/en not_active Expired - Lifetime
-
1997
- 1997-05-16 US US08/857,411 patent/US5807930A/en not_active Expired - Lifetime
- 1997-12-19 WO PCT/US1997/024246 patent/WO1998029509A1/en not_active Ceased
- 1997-12-19 JP JP53034398A patent/JP2001507745A/ja not_active Abandoned
- 1997-12-19 BR BR9713641-7A patent/BR9713641A/pt not_active IP Right Cessation
- 1997-12-19 AU AU57293/98A patent/AU729432B2/en not_active Ceased
- 1997-12-19 CA CA002275702A patent/CA2275702A1/en not_active Abandoned
- 1997-12-19 KR KR10-1999-7005915A patent/KR100523502B1/ko not_active Expired - Fee Related
- 1997-12-19 CN CNB971819351A patent/CN1222575C/zh not_active Expired - Fee Related
- 1997-12-19 IL IL13056897A patent/IL130568A/en not_active IP Right Cessation
- 1997-12-19 DE DE69720523T patent/DE69720523T2/de not_active Expired - Lifetime
- 1997-12-19 EP EP97953574A patent/EP0951509B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5700872A (en) | 1997-12-23 |
| DE69720523D1 (de) | 2003-05-08 |
| EP0951509B1 (en) | 2003-04-02 |
| WO1998029509A1 (en) | 1998-07-09 |
| CN1222575C (zh) | 2005-10-12 |
| EP0951509A1 (en) | 1999-10-27 |
| IL130568A (en) | 2001-10-31 |
| IL130568A0 (en) | 2000-06-01 |
| US5807930A (en) | 1998-09-15 |
| DE69720523T2 (de) | 2004-04-29 |
| AU5729398A (en) | 1998-07-31 |
| CN1247550A (zh) | 2000-03-15 |
| KR20000069776A (ko) | 2000-11-25 |
| AU729432B2 (en) | 2001-02-01 |
| BR9713641A (pt) | 2001-09-18 |
| KR100523502B1 (ko) | 2005-10-25 |
| CA2275702A1 (en) | 1998-07-09 |
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