JP2001335434A - Cosmetic for make-up - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a make-up cosmetic that has excellent sense of the application, the high make-up retention and the high prevention from secondary adhesion. SOLUTION: The objective make-up cosmetic comprises a liquid oil component that dissolves in water in an amount of 1-15 wt.% and in glyceryl 2- ethylhexanoate in an amount of >=5 wt.% at 25 deg.C and is in liquid form at 25 deg.C and a surfactant.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a makeup cosmetic. More specifically, the present invention relates to a makeup cosmetic which is excellent in use feel when applying cosmetics, has excellent makeup, and has improved secondary adhesion to clothes and the like.

[0002]

2. Description of the Related Art In addition to the "aesthetic role" that makes cosmetics look more beautiful, the makeup cosmetics also have a "functionality" such as having makeup and preventing secondary adhesion and a "sensual role" that provides comfort.

In order to enhance the "functionality", it is generally known that a silicone compound is blended. However, there is a tendency that the "sensory role" such as stickiness, tingling, and slipperiness during coating is impaired. Was in

[0004] In order to fulfill the "sensory role",
Generally, spherical powder is blended to improve lubricity, mica,
Adhesion has been improved by blending plate-like powders such as talc and kaolin. However, when a large amount of the spherical powder is blended, there are drawbacks in that the adhesion to the skin is reduced and the moldability when the powder is pressed is deteriorated.

Furthermore, when a large amount of plate-like powders such as mica, talc, and kaolin are blended, lubricity is reduced, and fragrances and oils are deteriorated due to catalytic activity of the powder surface, causing unpleasant odor. There was a problem.

[0006]

As described above, it is very difficult for a makeup cosmetic to simultaneously have a satisfactory feeling of use, an excellent cosmetic holding effect, and a secondary adhesion preventing effect. There is a demand for a makeup cosmetic having two properties at the same time.

The inventors of the present invention have conducted intensive studies in view of the above-mentioned problems. As a result, when polyoxyethylene dicarboxylic acid ester and boron nitride powder are blended into a makeup cosmetic, the feeling of use, the effect of applying makeup, and the effect of preventing secondary adhesion are reduced. The inventors have found that an excellent makeup cosmetic can be obtained, and have completed the present invention.

[0008] An object of the present invention is to provide a makeup cosmetic which is imparted with a satisfactory feeling of use and has an excellent makeup holding effect and an excellent effect of preventing secondary adhesion.

[0009]

That is, the present invention provides a method of
Disclosed is a makeup cosmetic containing a liquid oil at 25 ° C. which is dissolved in water at 5 ° C. in an amount of 1 to 15% by weight and glyceryl tri-2-ethylhexanoate in an amount of 5% by weight or more.

In the present invention, the oil component may be a polyoxyethylene fatty acid polyhydric alcohol ester, a polyoxyethylene alkyl polyhydric alcohol ether, a dialkyl dipolyoxyethylene alkylene ether, a polyoxyethylene dialkyl ester, or a polyoxyethylene dialkyl ether. The present invention provides the above makeup cosmetic which is one or more oils selected from the group consisting of:

Further, the present invention provides a polyoxyethylene fatty acid polyhydric alcohol ester, wherein the polyoxyethylene fatty acid glycerin is represented by the following chemical formula (1):
The polyoxyethylene alkyl polyhydric alcohol ether is a polyoxyethylene glyceryl alkyl ether represented by the following chemical formula (2), and the dialkyl dipolyoxyethylene alkylene ether is a dialkyl dipolyoxyethylene alkylene represented by the following chemical formula (3). An ether, wherein the polyoxyethylene dialkyl ester is a polyoxyethylene dialkyl ester represented by the following chemical formula (4), and the polyoxyethylene dialkyl ether is a polyoxyethylene dialkyl ether represented by the following chemical formula (5): The present invention provides the makeup cosmetic.

[0012]

Embedded image (1) (In the formula, R1, R2, and R3 are hydrogen or an alkyl or branched alkyl group having 1 to 9 carbon atoms, l, m, and n are 0 to 5 and the total represents an integer of 3 to 15.)

Embedded image (2) (wherein, R1, R2, and R3 are hydrogen or carbon atoms having 1 to 10
Alkyl or branched alkyl groups of l, m and n are from 0 to 8
And the sum represents an integer of 9 to 21. )

Embedded image (3) (wherein, R 1 and R 2 are hydrogen or an alkyl or branched alkyl group having 1 to 4 carbon atoms, m and n are 0 to 8 and the total is an integer of 4 to 10, and X is an integer of 1 to 4 Represents.)

Embedded image (4) (wherein, R1 and R2 represent hydrogen or an alkyl or branched alkyl group having 1 to 7 carbon atoms, and n represents an integer of 3 to 20.)

Embedded image (5) (wherein, R1 and R2 represent hydrogen or an alkyl or branched alkyl group having 1 to 4 carbon atoms, and n represents an integer of 6 to 23.)

[0013] The present invention also relates to the present invention, wherein the oil component is a polyhydric alcohol ester, diethoxy polyoxyethyl dihydric carboxylate, ditertiary alkyl ester of dihydric carboxylic acid,
Dineopentyl dicarboxylic acid, polyhydric alcohol ester of carboxylic acid, alcohol ester of divalent carboxylic acid, 3
It is intended to provide the above-mentioned external preparation for skin, characterized in that it is one or more oils selected from the group consisting of polyhydric carboxylic acid alcohol esters and tetracarboxylic acid pentaerythritol.

Further, in the present invention, the polyhydric alcohol ester is represented by the following chemical formula (6), and the dihydric carboxylic acid diethoxypolyoxyethyl is represented by the following chemical formula (7).
The divalent alkyl carboxylic acid ester is represented by the following chemical formula (8), the dicarboxylic acid dineopentyl is represented by the following chemical formula (9), and the carboxylic acid polyhydric alcohol ester is represented by the following chemical formula (10). The ester is represented by the following chemical formula (11), the trihydric carboxylic acid alcohol ester is represented by the following chemical formula (12), and the tetracarboxylic acid pentaerythritol is represented by the following chemical formula (1)
3) The present invention provides the above-mentioned external preparation for skin.

Embedded image (6) (where n = 1 to 3, R1, R2, and R3 each have 2 to 5 carbon atoms)
Represents a monocarboxylic acid, hydroxymonocarboxylic acid, or oxymonocarboxylic acid residue, and R4 represents hydrogen or a hydroxyl group. )

Embedded image (7) (wherein, R is a dicarboxylic acid, hydroxydicarboxylic acid, or oxydicarboxylic acid residue having 2 to 6 carbon atoms, x and y are from 0 to 2, and the sum of x and y represents an integer of 4 or less. )

Embedded image (8) (wherein, R is a dicarboxylic acid having 2 to 6 carbon atoms, hydroxydicarboxylic acid, or oxydicarboxylic acid residue, and m and n are 0 to 0)
In 1, the sum of m and n represents an integer of 2 or less. )

Embedded image (9) (wherein, R represents a dicarboxylic acid, hydroxydicarboxylic acid, or oxydicarboxylic acid residue having 2 to 6 carbon atoms.)

Embedded image (10) (wherein, R1 and R3 are monocarboxylic acids having 2 to 5 carbon atoms,
Hydroxymonocarboxylic acid, oxymonocarboxylic acid residue residue, R2 is a dihydric or trihydric alcohol residue having 2 to 6 carbon atoms and may have a hydroxyl group in the molecule. )

Embedded image (11) (wherein, R1 and R3 are an alcohol having 2 to 5 carbon atoms and an ethoxyethanol or ethyl carbitol residue;
2 represents a dicarboxylic acid, hydroxydicarboxylic acid or oxydicarboxylic acid residue having 2 to 6 carbon atoms. )

Embedded image (12) (wherein, R1, R3, and R4 are linear or branched alcohols having 2 to 5 carbon atoms and may have an ether group in the molecule. R2 is a tricarboxylic acid having 2 to 5 carbon atoms.) , A hydroxytricarboxylic acid or an oxytricarboxylic acid residue.)

Embedded image (13) (In the formula, R1, R2, R3, and R4 represent a monocarboxylic acid, hydroxymonocarboxylic acid, or oxymonocarboxylic acid residue residue having 2 to 5 carbon atoms.)

Further, the present invention provides the above-mentioned makeup cosmetic further containing a boron nitride powder.

[0016]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The configuration of the present invention will be described below in detail.

The oil used in the present invention is a water-soluble oil which is liquid at 25 ° C. It must be soluble in water from 1 to 15% by weight and in glyceryl tri-2-ethylhexanoate at least 5% by weight.
If it is solid at 25 ° C., the intended use feeling cannot be obtained. In addition, if less than 1% by weight is dissolved in water, the stability of the system is deteriorated due to lack of hydrophilicity. Fifteen
If the oil is soluble in excess of 5% by weight or less than 5% by weight in glyceryl tri-2-ethylhexanoate, the lipophilicity is poor, and the feel in use, particularly the smoothness, is lost.

[Inventions of Claims 1, 2, 3 and 6] The oils satisfying the above conditions are preferably polyoxyethylene fatty acid polyhydric alcohol ester, polyoxyethylene alkyl polyhydric alcohol ether, dialkyldipolyoxyethylene. Examples include alkylene ether, polyoxyethylene dialkyl ester, and polyoxyethylene dialkyl ether.

More preferably, the fatty acid polyhydric alcohol ester is a polyoxyethylene fatty acid glycerin represented by the above chemical formula (1), and specifically, polyoxyethylene (9 mol) glyceryl propionate, polyoxyethylene ( 6 mol) glycerin caproate, polyoxyethylene (15 mol) glycerin caprylate,
And polyoxyethylene (9 mol) glyceryl caprate.

The polyoxyethylene alkyl polyhydric alcohol ether is a polyoxyethylene glyceryl alkyl ether represented by the chemical formula (2), and specifically, polyoxyethylene (9 mol) glyceryl methyl ether, polyoxyethylene (9 mol) Ethylene (12 mol) glyceryl ethyl ether, polyoxyethylene (15 mol) propyl ether, polyoxyethylene (18 mol) butyl ether, polyoxyethylene (21 mol)
Hexyl ether, polyoxyethylene (12 mol) glyceryl octyl ether and the like can be mentioned.

Further, the dialkyldipolyoxyethylene alkylene ether is a dialkyldipolyoxyethylene alkylene ether represented by the chemical formula (3), and specifically, dimethyldipolyoxyethylene (4 mol) ethylene ether, diethyl ether Examples thereof include dipolyoxyethylene (6 mol) propylene ether, dipropylene dipolyoxyethylene (8 mol) butylene ether, and dibutyldipolyoxyethylene (10 mol) ethylene ether.

The polyoxyethylene dialkyl ester is a polyoxyethylene dialkyl ester represented by the chemical formula (4), and specifically, polyoxyethylene (5 mol) dipropionate, polyoxyethylene (10 Mol) dicaproic acid ester and the like.

Further, the polyoxyethylene dialkyl ether is a polyoxyethylene dialkyl ether represented by the chemical formula (5), and specifically, polyoxyethylene (6 mol) methyl ether, polyoxyethylene (10 mol) Examples include ethyl ether, polyoxyethylene (12 mol) propyl ether, and polyoxyethylene (8 mol) butyl ether.

The amount of the oil component is not particularly limited, but is preferably 0.001-20.
0% by weight, more preferably 0.1 to 10.0% by weight. If less than 0.001% by weight, the effect is not exhibited,
If it exceeds 20.0% by weight, stickiness will be felt after use.

[Inventions of Claims 1, 4, 5 and 6] The oil satisfying the above conditions is preferably a polyhydric alcohol ester, diethoxy polyoxyethyl dihydric carboxylate, ditertiary alkyl ester of divalent carboxylic acid. , 2
The divalent carboxylic acid dineopentyl, the carboxylic acid polyhydric alcohol ester, the divalent carboxylic acid alcohol ester, the trivalent carboxylic acid alcohol ester, and the tetracarboxylic acid pentaerythritol are mentioned.

More preferably, the polyhydric alcohol ester is represented by the above chemical formula (6), and specific examples include triacetin, glyceryl tripropionate, glyceryl triacetate and glyceryl tributyrate.

The above-mentioned diethoxypolyoxyethyl dicarboxylate is represented by the above chemical formula (7). Specifically, diethoxypolyoxyethyl glutarate, diethoxypolyoxyethyl adipate, diethoxy tartrate And polyethoxyethyl glutaric acid diethoxypolyoxyethyl.

Furthermore, the divalent carboxylic acid di-tert-alkyl ester is represented by the above chemical formula (8), and specifically, di-t-butyl succinate, di-t-butyl glutarate, di-t-butyl adipate , Di-tert-butyl pimerate,
Examples include di-t-butyl suberate and di-t-butyl tartrate.

The divalent penicyl carboxylate is represented by the above chemical formula (9), and specifically includes dineopentyl succinate, dineopentyl glutarate, dineopentyl adipate, dineopentyl pimerate, dineopentyl suberate, dineopentyl tartrate, etc. Is mentioned.

The carboxylic acid polyhydric alcohol ester is represented by the above chemical formula (10). Specifically, diethylene glycol propanoate, propylene glycol propanoate, dibutylene glycol propanoate, diethylene glycol butanoate, diethylene glycol butanoate, Examples thereof include propylene glycol, dibutylene glycol butyrate, diethylene glycol dilevulinate, dipropylene glycol dilevulinate, and dibutylene glycol diblenate.

The dihydric carboxylic acid alcohol ester is represented by the above chemical formula (11). Specifically, diethylene glycol succinate, dipropylene glycol succinate, dibutylene succinate, diethylene glycol glutarate, glutaric acid Dipropylene glycol, dibutylene glycol glutarate, diethylene glycol adipate, dipropylene glycol adipate, dibutylene adipate, diethylene glycol pimerate, dipropylene glycol pimerate, dibutylene glycol pimerate, diethylene glycol suberate, dipropylene suberate Glycol, dibutylene suberate, diethylene glycol tartrate, dipropylene glycol tartrate, dibutylene glycol tartrate And the like.

The alcoholic ester of trivalent carboxylic acid is represented by the above formula (12), and specific examples include triethyl citrate, tripropyl citrate, tributyl citrate and the like.

The pentaerythritol tetracarboxylate is represented by the above chemical formula (13), and pentaerythrit tetra-2-ethylhexanoate, pentaerythrit tetrahydroxyethaneate, pentaerythrit tetrahydroxypropanoate, Pentaerythritol hydroxybutanoate and the like.

The amount of the oil component is not particularly limited, but is preferably 0.001-20.
0% by weight, more preferably 0.1 to 10.0% by weight. If less than 0.001% by weight, the effect is not exhibited,
If it exceeds 20.0% by weight, stickiness will be felt after use.

The boron nitride powder used in the present invention is a boron nitride powder usually used as a raw material for cosmetics, and is generally a powder synthesized by the following method. (1) Boron is fired at about 1500 ° C. in a nitrogen stream. (2) Firing ammonia and boron oxide, ammonium chloride and borax, or boric acid and urea at about 800 to 1600 ° C. The crystal structure includes hexagonal, wurtzite, rhombohedral, cubic, etc. The cubic and wurtzite are mainly used as abrasives, and the hexagonal is used as a lubricant. The rhombohedral shape is synthesized only by a special manufacturing method. Among them, hexagonal boron nitride is preferable because it can be easily synthesized, can be easily sized by pulverization or the like, and has the best feel when used in a cosmetic.

The boron nitride powder used in the present invention is obtained by stirring and washing the powder having the above crystal structure in a water-soluble organic solvent such as a lower alcohol or acetone or an aqueous solution thereof, or an aqueous solution of a surfactant under stirring at a low temperature ( 60 ° C. or less is desirable.) It is obtained by drying under a low oxygen atmosphere (under a nitrogen stream or in a vacuum). The boron nitride powder thus obtained may be directly incorporated into cosmetics, or may be coated with a material such as higher fatty acids, oils and fats, waxes, silicone compounds, fluorine compounds, hydrocarbons, surfactants, and dextrin fatty acid esters. Processing may be performed.

The average particle size of the boron nitride powder is not particularly limited, but is preferably 0.1 to 30 μm in terms of spherical average particle size. If it is less than 0.1 μ, lubricity is impaired and 30
If it is larger than μ, it is not preferable because it feels rough.

The compounding amount of boron nitride can be selected in a wide range from 0.1 to 99% by weight in the make-up cosmetic depending on the target product. When the content is less than 0.1% by weight, the above effects cannot be sufficiently obtained, which is not preferable.

The makeup cosmetic of the present invention contains, in addition to the above-mentioned essential components, other components usually used in cosmetics,
For example, powder components, liquid fats and oils, solid fats and oils, waxes, hydrocarbons, higher fatty acids, higher alcohols, esters, silicones, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, humectants, Water-soluble polymers, thickeners, film agents, ultraviolet absorbers, sequestering agents, lower alcohols, polyhydric alcohols, sugars, amino acids,
An organic amine, a polymer emulsion, a pH adjuster, a skin nutrient, a vitamin, an antioxidant, an antioxidant aid, a fragrance, water and the like are appropriately blended as necessary, and according to a desired dosage form, according to a conventional method. Can be manufactured. Specific ingredients that can be blended are listed below. The makeup cosmetic of the present invention can be prepared by blending the essential ingredients described above and one or more of the following components.

Examples of the powder component include inorganic powders (for example, talc, kaolin, mica, sericite (sericite),
Muscovite, phlogopite, synthetic mica, rhombite, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, Silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, metal soap (for example, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; organic Powders (eg, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene Powders, cellulose powders, etc.); inorganic white pigments (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigments (eg, iron oxide (iron oxide), iron titanate, etc.); inorganic brown pigments (eg, γ-oxidized) Inorganic yellow pigments (eg, yellow iron oxide, loess, etc.); inorganic black pigments (eg, black iron oxide, lower titanium oxide, etc.); inorganic purple pigments (eg, mango violet, cobalt violet, etc.) ); Inorganic green pigments (for example, chromium oxide,
Chromium hydroxide, cobalt titanate, etc .; inorganic blue pigments (eg, ultramarine, navy blue, etc.); pearl pigments (eg, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica) , Bismuth oxychloride, fish scale foil, etc.); metal powder pigments (eg, aluminum powder,
Organic pigments such as zirconium, barium or aluminum lake (for example, red 201)
No., Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405
Organic pigments such as No. 203, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401 and Blue No. 404;
No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange 205
No. 4, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203
, Green No. 3 and blue No. 1); natural pigments (eg, chlorophyll, β-carotene, etc.).

Examples of liquid fats and oils include avocado oil,
Camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, Examples include soybean oil, peanut oil, teaseed oil, kaya oil, rice bran oil, sinagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.

Examples of solid fats and oils include cocoa butter, coconut oil, horse fat, hardened coconut oil, palm oil, tallow, sheep fat, hardened tallow, palm kernel oil, lard, beef bone fat, mocro kernel oil, hardened kernel oil Oil, beef tallow, mocro, hardened castor oil and the like.

Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax,
Ibota wax, whale wax, montan wax, bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, P
OE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, PO
E hydrogenated lanolin alcohol ether and the like.

Examples of the hydrocarbon include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax and the like.

Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, tolic acid, isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid (EPA), Docosahexaenoic acid (DHA) and the like.

Examples of higher alcohols include straight-chain alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc.); and branched-chain alcohols (eg, monostearyl glycerin ether). (Bacyl alcohol), 2-
Decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldecanol,
Isostearyl alcohol, octyl dodecanol, etc.)
And the like.

As synthetic ester oils, isopropyl myristate, cetyl octanoate, octyl dodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate,
Decyl oleate, hexyl decyl dimethyl octoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, 12
-Cholesteryl hydroxystearate, ethylene glycol di-2-ethylhexanoate, fatty acid ester of dipentaerythritol, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptylundecanoate , Trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate,
Pentaerythritol tetra-2-ethylhexanoate, glycerin tri-2-ethylhexanoate, glycerin trioctanoate, glycerin triisopalmitate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, Glycerin trimyristate, glyceride tri-2-heptylundecanoate, methyl ester of castor oil fatty acid, oleyl oleate, acetoglyceride, palmitate 2-
Heptylundecyl, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester,
Di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-myristate
Hexyldecyl, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate,
2-ethylhexyl succinate, triethyl citrate and the like can be mentioned.

Examples of the silicone include linear polysiloxanes (eg, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (eg, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecasiloxane). Methylcyclohexasiloxane, etc.) Silicone resin, silicone rubber, and various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) forming a three-dimensional network structure, etc. Is mentioned.

Examples of the anionic surfactant include fatty acid soaps (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (For example,
POE-triethanolamine lauryl sulfate, POE-sodium lauryl sulfate, etc.); N-acyl sarcosine acids (for example,
Higher fatty acid amide sulfonates (eg, sodium N-myristoyl-N-methyltaurine, sodium coconut fatty acid methyltauride, sodium laurylmethyltauride, etc.); phosphate ester salts (POE-oleyl ether) Sodium phosphate, POE-stearyl ether phosphoric acid, etc.); sulfosuccinates (eg, sodium di-2-ethylhexylsulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.);
Alkylbenzene sulfonates (eg, sodium linear dodecylbenzenesulfonate, triethanolamine linear dodecylbenzenesulfonate, linear dodecylbenzenesulfonic acid, etc.); higher fatty acid ester sulfates (eg, hydrogenated coconut oil fatty acid sodium glycerin sulfate, etc.); N-acylglutamate (for example, monosodium N-lauroylglutamate, disodium N-stearoylglutamate, monosodium N-myristoyl-L-glutamate), sulfated oil (for example, funnel oil), and POE-alkyl ether carboxylic acid Acid; POE-alkyl allyl ether carboxylate; α-olefin sulfonate; higher fatty acid ester sulfonate; secondary alcohol sulfate; salt of higher fatty acid alkylolamide sulfate; lauroyl mono Sodium ethanolamidosuccinate; N-palmitoyl aspartate ditriethanolamine; sodium caseinate;

Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride); and alkylpyridinium salts (eg,
Cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride);
Alkyl quaternary ammonium salts; alkyl dimethyl benzyl ammonium salts; alkyl isoquinolinium salts; dialkyl morphonium salts; POE-alkylamines; alkyl amine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride And the like.

Examples of the amphoteric surfactant include imidazoline amphoteric surfactants (eg, 2-undecyl-N, N, N
-(Hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc .; betaine surfactants (eg, 2-heptadecyl-N- Carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryl dimethylaminoacetic acid betaine, alkyl betaine, amido betaine, sulfo betaine, etc.).

Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (eg, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan monostearate) Oleate, sorbitan trioleate, diglycerol penta-2-ethylhexylate sorbitan, diglycerol sorbitan tetra-2-ethylhexylate, etc .; glycerin polyglycerin fatty acids (for example, mono-cottonseed oil fatty acid glycerin, glycerin monoerucate, glycerin sesquioleate , Glyceryl monostearate, α, α '
-Glycerin pyroglutamate oleate, glycerin malate monostearate, etc.); propylene glycol fatty acid esters (eg, propylene glycol monostearate); hydrogenated castor oil derivatives; glycerin alkyl ether;

Examples of the hydrophilic nonionic surfactant include POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate). POE sorbit fatty acid esters (eg, POE-sorbit monolaurate, POE-sorbit monooleate, POE-sorbit pentaoleate, POE-sorbit monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin monostearate, POE-glycerin monoisostearate, PO
POE-monooleate such as E-glycerin triisostearate); POE-fatty acid esters (eg, POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (eg, POE-lauryl ether) , POE-oleyl ether, PO
E-stearyl ether, POE-behenyl ether, POE-2-
Octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic type (eg, Pluronic etc.); POE.POP-alkyl ethers (eg, POE.PO)
P-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether, etc.); Tetra P
OE.tetra-POP-ethylenediamine condensates (eg, tetronic); POE-castor oil-hardened castor oil derivatives (eg, POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE) -Hydrogenated castor oil triisostearate, POE-hydrogenated castor oil monopyroglutamic acid monoisostearate diester, POE-hydrogenated castor oil maleic acid, etc.); POE-beeswax lanolin derivative (eg, POE-sorbit beeswax, etc.); alkanolamide (For example, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid ester; PO
E-alkylamine; POE-fatty acid amide; sucrose fatty acid ester; alkylethoxydimethylamine oxide; trioleyl phosphoric acid and the like.

Examples of the humectant include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12- Examples include hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, adduct of diglycerin (EO) PO, extract of radish, extract of Achillea millefolium, and extract of melilot.

Examples of natural water-soluble polymers include plant polymers (eg, gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), alge colloid (cassow extract) ), Starch (rice, corn, potato, wheat), glycyrrhizic acid); microbial macromolecules (eg, xanthan gum, dextran, succinoglucan, burlan, etc.); animal macromolecules (eg, collagen, casein,
Albumin, gelatin, etc.).

The semi-synthetic water-soluble polymer includes, for example,
Starch-based polymers (for example, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose-based polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, Crystalline cellulose,
Alginic acid-based polymers (eg, sodium alginate, propylene glycol alginate, etc.);

Examples of the synthetic water-soluble polymer include vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, etc.); polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40,000, 6
Acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethylene imine; cationic polymers, and the like.

As the thickener, for example, gum arabic,
Carrageenan, karaya gum, tragacanth gum, carob gum, quince seed (quince), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose,
CMC, hydroxyethylcellulose, hydroxypropylcellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, dialkyldimethylammonium cellulose sulfate, xanthan gum, aluminum magnesium silicate, bentonite,
Hectorite, silicic acid A1Mg (bee gum), laponite, silicic anhydride and the like.

As the ultraviolet absorber, for example, benzoic acid-based ultraviolet absorbers (for example, para-aminobenzoic acid (hereinafter referred to as P
ABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N- Dimethyl PABA ethyl ester, etc.); anthranilic acid type ultraviolet absorbers (eg, homomenthyl-N-acetylanthranilate); salicylic acid type ultraviolet absorbers (eg, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate) Benzyl salicylate, p-isopropanol phenyl salicylate, etc.); cinnamic acid ultraviolet absorbers (eg, octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-
2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate Mate, octyl-p-methoxycinnamate
(2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-
p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, etc.); benzophenone UV absorbers (for example, 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4 ′ -Tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-
Methoxy-4'-methylbenzophenone, 2-hydroxy-4-
Methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone Etc.); 3- (4'-methylbenzylidene) -d, l-
Camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-
Methylphenylbenzotriazole; 2- (2'-hydroxy
-5'-t-octylphenyl) benzotriazole; 2- (2'-
Hydroxy-5'-methylphenylbenzotriazole;dibenzalazine;dianisoylmethane;4-methoxy-4'-t-
Butyldibenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one;

Examples of sequestering agents include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, edetate Tetrasodium acid, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid,
Ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyltriacetate and the like.

The lower alcohol includes, for example, ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

Examples of the polyhydric alcohol include dihydric alcohols (eg, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3- Butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trihydric alcohols (eg, glycerin, trimethylolpropane, etc.);
Tetrahydric alcohols (eg, pentaerythritol such as 1,2,6-hexanetriol); pentahydric alcohols (eg, xylitol); hexahydric alcohols (eg, sorbitol, mannitol); polyhydric alcohol polymers (eg, Diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); dihydric alcohol alkyl ethers (eg, ethylene glycol monomethyl ether, Ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol Coal mono 2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc.); dihydric alcohol alkyl ethers (eg, diethylene glycol monomethyl) Ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, pro Pyrene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether,
Dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc .; dihydric alcohol ether esters (eg, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl) Ether acetate, ethylene glycol diazibate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate , Propylene glycol monophenyl ether acetate); glycerol monoalkyl ethers (e.g., hexyl alcohol, selachyl alcohol, batyl alcohol); sugar alcohols (e.g.,
Sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch-degrading sugar, maltose, xylitol, starch-degrading sugar reducing alcohol, etc.); glysolid; tetrahydrofurfuryl alcohol; POE-tetrahydrofur Furyl alcohol; POP-butyl ether;
POP / POE-butyl ether; tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphoric acid; POP / POE-pentaneerythritol ether, polyglycerin and the like.

As the monosaccharide, for example, trisaccharide (for example,
D-glyceryl aldehyde, dihydroxyacetone, etc.);
Tetracarbons (eg, D-erythrose, D-erythrulose,
Pentose (eg, D-threose, erythritol, etc.)
L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc.); hexose (eg, D-glucose, D-talose, D- Bucose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); heptose sugars (eg, aldheptose, heptrose etc.); octose sugars (eg, octulose etc.); deoxy sugars (eg, , 2-deoxy-D-ribose, 6-deoxy-L-
Galactose, 6-deoxy-L-mannose, etc.); amino sugars (eg, D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); uronic acids (eg, D-glucuronic acid, D-mannuronic acid) , L-guluronic acid, D-galacturonic acid, L-iduronic acid, etc.).

Examples of the oligosaccharide include sucrose, guntianose, umbelliferose, lactose, planteose, isoliqunoses, α, α-trehalose,
Raffinose, liqunoses, umbilicin, stachyose bell bath courses and the like.

Examples of the polysaccharide include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran Keratosulfuric acid, locust bingham, succinoglucan, caronic acid and the like.

The amino acids include, for example, neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.). Examples of the amino acid derivative include acyl sarcosine sodium (sodium lauroyl sarcosine), acyl glutamate, sodium acyl β-alanine, glutathione, and pyrrolidone carboxylic acid.

Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1 -Propanol and the like.

Examples of the polymer emulsion include an acrylic resin emulsion, a polyethyl acrylate emulsion, an acrylic resin solution, a polyacryl alkyl ester emulsion, a polyvinyl acetate resin emulsion,
Natural rubber latex and the like.

Examples of the pH adjusting agent include lactic acid-sodium lactate, citric acid-sodium citrate, succinic acid-
Buffers such as sodium succinate and the like can be mentioned.

As vitamins, for example, vitamin A,
B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.

Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic esters and the like.

As the antioxidant aid, for example, phosphoric acid,
Examples thereof include citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

As other compoundable components, for example,
Antiseptics (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); whitening agents (eg, placenta extracts,
Various extracts (for example, oak, oak, syrup, peony, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, yoquinin, loofah, lily,
Saffron, Senkyu, Ginger, Hypericum,
Ononis, garlic, capsicum, pepper, toucan, seaweed, etc., activators (eg, royal jelly, photosensitizers, cholesterol derivatives, etc.); blood circulation promoters (eg, nonylate valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl) Esters, capsaicin, zingerone, cantaristin tincture, ittamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandate, cinnarizine, trazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol, etc.); Leakage agents (eg, sulfur, thiantol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.)
And the like.

The product form that the makeup cosmetic of the present invention can take is not particularly limited. For example, it can take a product form such as a makeup base, a foundation, a white powder, a blusher, a lipstick, a mascara, an eye shadow, an eye liner, and the like.

[0075]

EXAMPLES Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. The compounding amount is% by weight. First, test methods and evaluation methods employed in each of the examples and comparative examples will be described.

"Lightness on the skin" An actual use test was carried out on the lightness on the skin during use by 10 expert panelists. The evaluation criteria are as follows. A: Eight or more specialized panelists recognized that the spread on the skin during use was light. ○: 6 or more and less than 8 specialized panelists recognized that the spread on the skin during use was light. Δ: 3 or more and less than 6 specialized panelists recognized that the spread on the skin during use was light. ×: Less than three professional panelists recognized that the spread on the skin during use was light.

"Adhesion to Skin (Fitness)" After use, ten professional panelists conducted a practical use test on the adhesion to skin (fitness). The evaluation criteria are as follows. A: Eight or more specialized panelists recognized that there was adhesion (fit) to the skin after use. …: 6 or more and less than 8 specialized panelists recognized that there was adhesion (fit) to the skin after use. B: Three or more and less than six professional panelists recognized that there was adhesion (fit) to the skin after use. ×: Less than 3 professional panelists recognized that there was adhesion (fit) to the skin after use.

"No makeup collapse (make-up sticky effect)"
The actual use test was performed by name. The evaluation criteria are as follows. A: Eight or more specialized panelists recognized that the makeup did not collapse after use (makes good). …: 6 or more and less than 8 specialized panelists recognized that the makeup did not collapse after use (good makeup). Δ: 3 or more and less than 6 specialized panelists recognized that the makeup did not collapse after use (the makeup had good stickiness). X: Less than 3 professional panelists recognized that the makeup did not collapse after use (makeup is good).

"No secondary adhesion to clothing, etc. (secondary adhesion-less effect)" A practical use test was conducted by 10 expert panelists to evaluate the absence of secondary adhesion to clothing, etc. after use (secondary adhesion-less effect). Carried out. The evaluation criteria are as follows. ◎: Eight or more specialized panelists recognized that there was no secondary adhesion to clothes etc. after use. ○: 6 or more and less than 8 specialized panelists recognized that there was no secondary adhesion to clothes etc. after use. Δ: 3 or more and less than 6 specialized panelists recognized that there was no secondary adhesion to clothes etc. after use. ×: Less than 3 professional panelists recognized that there was no secondary adhesion to clothes etc. after use.

"No Stickiness on the Skin" A practical use test was conducted by 10 expert panelists on the absence of stickiness on the skin during and after use. The evaluation criteria are as follows. …: Eight or more specialized panelists recognized that they were not sticky during use and after use. ○: 6 or more and less than 8 specialized panelists recognized that the product was in use and non-sticky after use. Δ: Three or more and less than six specialized panelists recognized that the product was in use and non-sticky after use. ×: Less than 3 professional panelists recognized that they were not sticky during use and after use.

For the liquid oil used in the examples, water and 2
The solubility of glyceryl ethylhexanoate was confirmed as follows. “Solubility test” A sample mixed and stirred at room temperature (25 ° C.) was filled in a 50 ml sample tube (glass bottle), and the solubility (appearance) was visually confirmed to evaluate the solubility. ：: dissolves (clear) ×: does not dissolve (turbidity or oil droplets are observed)

[Inventions of Claims 1, 2, 3 and 6] The solubility of the liquid oils shown in Tables 1 to 3 was tested. The results are shown in each table.

[0083]

[Table 1]

[0084]

[Table 2]

[0085]

[Table 3]

From Tables 1 to 3, it is found that polyoxyethylene (9 mol) glyceryl caprate, polyoxyethylene (12 mol) glyceryl octyl ether, dipropylene dipolyoxyethylene (8 mol) butylene ether, It can be seen that oxyethylene (5 mol) dipropionate and polyoxyethylene (8 mol) butyl ether have a solubility that meets the requirements of the liquid oil used in the present invention.

The oil-in-water emulsified foundations of the formulas shown in Examples 1 to 4 and Comparative Example 1 were uniformly mixed with 1 to 6 shown in Table 4, and mixed and pulverized 7 to 11 were added thereto. And 12 to 23 dissolved by heating were added thereto, and the mixture was emulsified uniformly to prepare the mixture. Then, an evaluation test was performed for the above evaluation, and the results are shown in "Table 4".

[0088]

[Table 4]

The oil-in-water emulsified foundations of the formulations shown in Examples 5 to 8 and Comparative Example 2 were uniformly mixed with 1 to 6 shown in Table 5 and mixed and pulverized 7 to 12 were added thereto. , And the resulting mixture was added with 13-26 dissolved by heating to uniformly emulsify. An evaluation test was conducted for the above evaluation, and the results are shown in Table 5.

[0090]

[Table 5]

From the above results, it can be seen that the makeup cosmetic of the present invention has excellent effects in all evaluation items. Hereinafter, other examples of the present invention will be described.

Example 9 Solid Powder Foundation (1) Talc 15.0% by weight (2) Sericite 20.0 (3) Mica 10.0 (4) PMMA spherical powder 1.0 (5) Methylsiloxane network Polymerized powder 1.0 (6) Boron nitride 9.0 (7) Titanium dioxide 12.0 (8) Iron oxide 6.0 (9) Titanium mica 1.5 (10) Liquid paraffin residue (11) Polyoxyethylene (9 mol) Glycerin caprate 10.0 (12) Sorbitan sesquioleate 2.0 (13) Preservative suitable amount (14) Flavor proper amount (Production method and evaluation) , 10 to 14 were added, mixed with stirring, and molded into a container to obtain a solid powdery foundation. The obtained solid powdery foundation is
The feeling of use, the sticky effect, and the secondary adhesion preventing effect were excellent.

Example 10 Water-in-oil Emulsified Foundation (1) Nylon Spherical Powder 2.0% by Weight (2) Boron Nitride 10.0 (3) Silicone Treated Titanium Dioxide 10.0 (4) Silicone Treated Iron Oxide 5.0 (5) Silicone treated sericite 1.0 (6) Silicone treated mica 1.5 (7) Metal soap treated talc 5.5 (8) Purified water residue (9) Sodium hydroxymethoxybenzophenone sulfonate 0 (10) Glycerin 10.0 (11) Dipropylene glycol 5.0 (12) Decamethylcyclopentasiloxane 10.0 (13) Liquid paraffin 3.0 (14) Methylphenyl polysiloxane 1.0 (15) Silicone Resin 5.0 (16) Sorbitan monoisostearate 2.0 (17) Polyoxyethylene (12 mol) glyceryl octyl ether 4.5 (18) Preservative appropriate amount (19) Flavor appropriate amount (Production method and evaluation) The components of 1 to 7 were mixed and dissolved in the components of 12 to 19 uniformly. The crushed mixture was added and dispersed. Next, 8 to 11 mixed and stirred uniformly were added, emulsified, and filled in a container to obtain a water-in-oil emulsified foundation. The obtained water-in-oil emulsified foundation was excellent in use feeling, makeup effect and secondary adhesion preventing effect.

[Example 11] White powder (1) Talc residue (2) Sericite 10.0% by weight (3) Organopolysiloxane elastomer spherical powder 5.0 (4) Boron nitride 20.0 (5) Iron oxide 3.0 (6) Magnesium carbonate 3.0 (7) Spherical alumina powder 4.0 (8) Squalane 2.0 (9) Glycerin trioctanoate 3.0 (10) Dipropylene dipolyoxyethylene (8 mol) butylene Ether 1.5 (11) Sorbitan sesquioleate 1.0 (12) Preservative appropriate amount (13) Flavor appropriate amount (Production method and evaluation) When each component of 1 to 7 was mixed and pulverized, each of 8 to 13 was added. A mixture of the components was added, mixed and stirred, and filled in a container to obtain a white powder. The obtained white powder was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

Example 12 Eye Shadow (1) Talc Residue (2) Sericite 7.0% by Weight (3) Mica 15.0 (4) Boron Nitride 33.0 (5) Titanium Mica 2.0 ( 6) Titanium mica 1.5 coated with iron oxide 1.5 (7) Iron oxide 1.5 (8) Squalane 2.0 (9) Polyoxyethylene (5 mol) dipropionate 2.0 (10) Silicone resin 1.5 (11) Sorbitan monooleate 0.5 (12) Preservative appropriate amount (13) Flavor appropriate amount (Production method and evaluation) Each component of 1 to 7 was mixed and ground, and each component of 8 to 13 was mixed. These were added, mixed with stirring, and molded into a middle plate to obtain an eye shadow. The obtained eye shadow was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

Example 13 Lipstick (1) Carnauba wax 1.0% by weight (2) Candelilla wax 2.0 (3) Celesin 10.0 (4) Squalane residue (5) Glycerin triisooctanoate 9.0 (6) Glycerin diisostearate 13.0 (7) Polyoxyethylene (8 mol) butyl ether 5.0 (8) Silicone resin 8.0 (9) Hydroxypropyl-β-cyclodextrin 1.0 (10) Macadamia nut oil fatty acid Cholesteryl 3.5 (11) Synthetic sodium magnesium silicate 0.5 (12) Hydrophobic silica 0.5 (13) Purified water 2.0 (14) Boron nitride 10.0 (15) Colorant proper amount (16) Preservative proper amount (17) Flavor proper amount (Production method and evaluation) 11 to 12 were dispersed in 10 heated to 60 ° C. and uniformly dissolved therein. Add 9 and 13 and stir well. This was added to 1 to 8 which had been separately heated and dissolved, and the mixture was sufficiently stirred. Further, 14 to 17 was added and dispersed and stirred, and then the mixture was filled in a container to obtain a lipstick. The obtained lipstick was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

[Inventions of Claims 1, 4, 5 and 6] The solubility of the liquid oils shown in Tables 6 to 8 was tested. The results are shown in each table.

[0098]

[Table 6]

[0099]

[Table 7]

[0100]

[Table 8]

From Tables 6 to 8, triacetin,
Diethoxypolyoxyethyl glutarate, di-succinate
-Butyl, dineopentyl succinate, diethylene glycol dilevulinate, diethylene glycol glutarate,
It can be seen that triethyl citrate and pentaerythrit tetrahydroxybutanoate have a solubility that meets the requirements for the liquid oil used in the present invention.

The oil-in-water emulsified foundations of the formulations shown in Examples 14 to 17 and Comparative Example 3 were prepared as shown in Table 9 below.
No. 6 was uniformly mixed, and mixed and pulverized 7 to 11 were added thereto to uniformly disperse the mixture, and then heated and dissolved 12 to 23 were added to uniformly emulsify the mixture. Then, an evaluation test was conducted for the above evaluation, and the results are shown in "Table 9".

[0103]

[Table 9]

The oil-in-water emulsified foundations of the formulations shown in Examples 18 to 24 and Comparative Example 4 were prepared as shown in Table 10 below.
To 6 were uniformly mixed, and mixed and pulverized 7 to 12 were added to the mixture to uniformly disperse the mixture. Heat-dissolved 13 to 31 were added to uniformly emulsify the mixture. Then, an evaluation test was conducted for the above evaluation, and the result was referred to “Table 1”.
0 ".

[0105]

[Table 10]

From the above results, it can be seen that the makeup cosmetic of the present invention has excellent effects in all evaluation items. Hereinafter, other examples of the present invention will be described.

Example 25 Solid Powder Foundation (1) Talc 15.0% by weight (2) Sericite 20.0 (3) Mica 10.0 (4) PMMA spherical powder 1.0 (5) Methylsiloxane network Polymerized powder 1.0 (6) Boron nitride 9.0 (7) Titanium dioxide 12.0 (8) Iron oxide 6.0 (9) Titanium mica 1.5 (10) Liquid paraffin residue (11) Triethyl citrate 10.0 (12) Sorbitan sesquioleate 2.0 (13) Preservative appropriate amount (14) Flavor appropriate amount (Production method and evaluation) Where components 1 to 9 are mixed and ground, components 10 to 14 are added. Was added, stirred and mixed, and molded into a container to obtain a solid powdery foundation. The obtained solid powdery foundation is
The feeling of use, the sticky effect, and the secondary adhesion preventing effect were excellent.

Example 26 Water-in-oil Emulsification Foundation (1) Nylon spherical powder 2.0% by weight (2) Boron nitride 10.0 (3) Silicone-treated titanium dioxide 10.0 (4) Silicone-treated iron oxide 5.0 (5) Silicone treated sericite 1.0 (6) Silicone treated mica 1.5 (7) Metal soap treated talc 5.5 (8) Purified water residue (9) Sodium hydroxymethoxybenzophenone sulfonate 0 (10) Glycerin 10.0 (11) Dipropylene glycol 5.0 (12) Decamethylcyclopentasiloxane 10.0 (13) Liquid paraffin 3.0 (14) Methylphenyl polysiloxane 1.0 (15) Silicone Resin 5.0 (16) Sorbitan monoisostearate 2.0 (17) Dineopenp succinate 4.5 (18) Appropriate amount of preservative (19) Appropriate amount of fragrance (Production method and evaluation) A mixture prepared by uniformly mixing and dissolving the components of 12 to 19, and mixing and grinding the components of 1 to 7 In addition, it was dispersed. Next, 8 to 11 mixed and stirred uniformly were added, emulsified, and filled in a container to obtain a water-in-oil emulsified foundation. The obtained water-in-oil emulsified foundation was excellent in use feeling, makeup effect and secondary adhesion preventing effect.

[Example 27] White powder (1) Talc residue (2) Sericite 10.0% by weight (3) Organopolysiloxane elastomer spherical powder 5.0 (4) Boron nitride 20.0 (5) Iron oxide 3.0 (6) Magnesium carbonate 3.0 (7) Spherical alumina powder 4.0 (8) Squalane 2.0 (9) Glycerin trioctanoate 3.0 (10) Triacetin 1.5 (11) Sorbitan sesquioleate 1.0 (12) Preservative appropriate amount (13) Fragrance appropriate amount (Production method and evaluation) Where components 1 to 7 were mixed and pulverized, a mixture of components 8 to 13 was added and mixed and stirred. And filled in a container to obtain a white powder. The obtained white powder was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

[Example 28] Eye shadow (1) Talc residue (2) Sericite 7.0% by weight (3) Mica 15.0 (4) Boron nitride 33.0 (5) Titanium mica 2.0 ( 6) iron oxide-coated titanium mica 1.5 (7) iron oxide 1.5 (8) squalane 2.0 (9) diethylene glycol dilevulinate 2.0 (10) silicone resin 1.5 (11) sorbitan monooleate 0 .5 (12) Preservative appropriate amount (13) Flavor appropriate amount (Production method and evaluation) After mixing and pulverizing each component of 1 to 7, add a mixture of each component of 8 to 13 and stir and mix. An eye shadow was obtained by molding into a middle plate. The obtained eye shadow was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

Example 29 Lipstick (1) Carnauba wax 1.0% by weight (2) Candelilla wax 2.0 (3) Celesin 10.0 (4) Squalane residue (5) Glycerin triisooctanoate 9.0 (6) Glycerin diisostearate 13.0 (7) Di-t-butyl succinate 5.0 (8) Silicone resin 8.0 (9) Hydroxypropyl-β-cyclodextrin 1.0 (10) Macadamia nut oil fatty acid cholesteryl 3 (11) Synthetic sodium magnesium silicate 0.5 (12) Hydrophobic silica 0.5 (13) Purified water 2.0 (14) Boron nitride 10.0 (15) Coloring agent Appropriate amount (16) Preservative Appropriate amount (17) Appropriate amount of fragrance (Preparation method and evaluation) 11 to 12 were dispersed in 10 heated to 60 ° C. To 拌. This was added to 1 to 8 which had been separately heated and dissolved, and the mixture was sufficiently stirred. Further, 14 to 17 was added and dispersed and stirred, and then the mixture was filled in a container to obtain a lipstick. The obtained lipstick was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

[0112]

According to the present invention, when polyoxyethylene dicarboxylic acid ester and boron nitride powder are blended into a makeup cosmetic, a makeup cosmetic excellent in use feel, makeup sticking effect and secondary adhesion preventing effect is provided. Is done.

Continued on the front page (72) Inventor Hiroyuki Kagogi 2-2-1 Hayabuchi, Tsuzuki-ku, Yokohama-shi, Kanagawa Prefecture Inside Shiseido Research Center (Shin-Yokohama) (72) Inventor Tomiyuki Namba 2- Hayabuchi, Tsuzuki-ku, Yokohama-shi, Kanagawa 2-1 Shiseido Research Center Co., Ltd. (Shin-Yokohama) F term (reference) 4C083 AA122 AB032 AB052 AB151 AB152 AB172 AB222 AB232 AB242 AB382 AB432 AB442 AC012 AC022 AC072 AC122 AC181 AC182 AC242 AC372 AC391 AC392 AC401 AC402 AC422 AC441 AC442 AC482 AC542 AD042 AD072 AD092 AD152 AD172 AD252 AD492 BB13 CC05 CC12 CC13 CC14 DD11 DD21 DD33 EE03 EE06

Claims (6)

[Claims] 1. A makeup cosmetic containing a liquid oil at 25 ° C., which is soluble in water at 25 ° C. in an amount of 1 to 15% by weight and glyceryl tri-2-ethylhexanoate in an amount of 5% by weight or more. 2. The oil component is selected from the group consisting of polyoxyethylene fatty acid polyhydric alcohol esters, polyoxyethylene alkyl polyhydric alcohol ethers, dialkyl dipolyoxyethylene alkylene ethers, polyoxyethylene dialkyl esters, and polyoxyethylene dialkyl ethers. 2. The makeup cosmetic according to claim 1, which is one or more selected oil components. 3. The polyoxyethylene fatty acid polyhydric alcohol ester is polyoxyethylene fatty acid glycerin represented by the following chemical formula (1), and the polyoxyethylene alkyl polyhydric alcohol ether is represented by the following chemical formula (2). A polyoxyethylene glyceryl alkyl ether, wherein the dialkyl dipolyoxyethylene alkylene ether is a dialkyl dipolyoxyethylene alkylene ether represented by the following chemical formula (3), and the polyoxyethylene dialkyl ester is represented by the following chemical formula (4): The makeup cosmetic according to claim 2, wherein the polyoxyethylene dialkyl ester is a polyoxyethylene dialkyl ether represented by the following chemical formula (5). Embedded image (1) (In the formula, R1, R2, and R3 are hydrogen or an alkyl or branched alkyl group having 1 to 9 carbon atoms, l, m, and n are 0 to 5 and the total represents an integer of 3 to 15.) Embedded image (2) (wherein, R1, R2, and R3 are hydrogen or carbon atoms having 1 to 10
Alkyl or branched alkyl groups of l, m and n are from 0 to 8
And the sum represents an integer of 9 to 21. ) (3) (wherein, R 1 and R 2 are hydrogen or an alkyl or branched alkyl group having 1 to 4 carbon atoms, m and n are 0 to 8 and the total is an integer of 4 to 10, and X is an integer of 1 to 4 Represents the following.) (4) (wherein, R1 and R2 represent hydrogen or an alkyl or branched alkyl group having 1 to 7 carbon atoms, and n represents an integer of 3 to 20). (5) (wherein, R1 and R2 represent hydrogen or an alkyl or branched alkyl group having 1 to 4 carbon atoms, and n represents an integer of 6 to 23.) 4. The oil component is a polyhydric alcohol ester,
Diethoxypolyoxyethyl dicarboxylic acid, ditertiary alkyl dicarboxylic acid ester, dineopentyl dicarboxylic acid, polyhydric alcohol ester of carboxylic acid,
The makeup cosmetic according to claim 1, which is one or more oil components selected from the group consisting of dihydric carboxylic acid alcohol esters, trivalent carboxylic acid alcohol esters, and tetracarboxylic acid pentaerythritol. 5. The polyhydric alcohol ester is represented by the following chemical formula (6), the dihydric carboxylic acid diethoxypolyoxyethyl is represented by the following chemical formula (7), and the dihydric carboxylic acid dialkylalkyl is represented by the following chemical formula (8). ), The divalent penicyl carboxylate is represented by the following chemical formula (9):
The carboxylic acid polyhydric alcohol ester is represented by the following chemical formula (10), the dihydric carboxylic acid alcohol ester is represented by the following chemical formula (11), and the trivalent carboxylic acid alcohol ester is represented by the following chemical formula (12). The makeup cosmetic according to claim 4, wherein the erythrit is represented by the following chemical formula (13). Embedded image (6) (where n = 1 to 3, R1, R2, and R3 each have 2 to 5 carbon atoms)
Represents a monocarboxylic acid, hydroxymonocarboxylic acid, or oxymonocarboxylic acid residue, and R4 represents hydrogen or a hydroxyl group. ) (7) (wherein, R is a dicarboxylic acid, hydroxydicarboxylic acid, or oxydicarboxylic acid residue having 2 to 6 carbon atoms, x and y are from 0 to 2, and the sum of x and y represents an integer of 4 or less. ) (8) (wherein, R is a dicarboxylic acid having 2 to 6 carbon atoms, hydroxydicarboxylic acid, or oxydicarboxylic acid residue, and m and n are 0 to 0)
In 1, the sum of m and n represents an integer of 2 or less. ) (9) (In the formula, R represents a dicarboxylic acid, hydroxydicarboxylic acid or oxydicarboxylic acid residue having 2 to 6 carbon atoms.) (10) (wherein, R1 and R3 are monocarboxylic acids having 2 to 5 carbon atoms,
Hydroxymonocarboxylic acid, oxymonocarboxylic acid residue residue, R2 is a dihydric or trihydric alcohol residue having 2 to 6 carbon atoms and may have a hydroxyl group in the molecule. ) (11) (wherein, R1 and R3 are an alcohol having 2 to 5 carbon atoms and an ethoxyethanol or ethyl carbitol residue;
2 represents a dicarboxylic acid, hydroxydicarboxylic acid or oxydicarboxylic acid residue having 2 to 6 carbon atoms. ) (12) (wherein, R1, R3, and R4 are linear or branched alcohols having 2 to 5 carbon atoms and may have an ether group in the molecule. R2 is a tricarboxylic acid having 2 to 5 carbon atoms.) , Represents a hydroxytricarboxylic acid or oxytricarboxylic acid residue.) (13) (In the formula, R1, R2, R3, and R4 represent a monocarboxylic acid, hydroxymonocarboxylic acid, or oxymonocarboxylic acid residue residue having 2 to 5 carbon atoms.) 6. The makeup cosmetic according to claim 1, further comprising a boron nitride powder.