JP2001295021A - 金属基体に保護皮膜を形成する方法および得られた物品 - Google Patents
金属基体に保護皮膜を形成する方法および得られた物品Info
- Publication number
- JP2001295021A JP2001295021A JP2001028936A JP2001028936A JP2001295021A JP 2001295021 A JP2001295021 A JP 2001295021A JP 2001028936 A JP2001028936 A JP 2001028936A JP 2001028936 A JP2001028936 A JP 2001028936A JP 2001295021 A JP2001295021 A JP 2001295021A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- atomic
- substrate
- aluminum
- cobalt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 72
- 239000000758 substrate Substances 0.000 title claims abstract description 37
- 238000000151 deposition Methods 0.000 title abstract description 7
- 230000001681 protective effect Effects 0.000 title abstract description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000000463 material Substances 0.000 claims abstract description 48
- 239000000203 mixture Substances 0.000 claims abstract description 45
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 39
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 34
- 239000000956 alloy Substances 0.000 claims abstract description 32
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 27
- 239000010941 cobalt Substances 0.000 claims abstract description 27
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 25
- 239000011651 chromium Substances 0.000 claims abstract description 25
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 22
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 22
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 21
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000010703 silicon Substances 0.000 claims abstract description 20
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 238000010290 vacuum plasma spraying Methods 0.000 claims abstract description 14
- 238000007749 high velocity oxygen fuel spraying Methods 0.000 claims abstract 6
- 238000000576 coating method Methods 0.000 claims description 25
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- 239000011248 coating agent Substances 0.000 claims description 20
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 19
- 238000009792 diffusion process Methods 0.000 claims description 17
- 230000007797 corrosion Effects 0.000 claims description 16
- 238000005260 corrosion Methods 0.000 claims description 16
- 239000000446 fuel Substances 0.000 claims description 16
- 229910000601 superalloy Inorganic materials 0.000 claims description 16
- 229910052742 iron Inorganic materials 0.000 claims description 11
- 239000011253 protective coating Substances 0.000 claims description 11
- 230000007613 environmental effect Effects 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 claims 1
- 238000012360 testing method Methods 0.000 description 17
- 230000003647 oxidation Effects 0.000 description 13
- 238000007254 oxidation reaction Methods 0.000 description 13
- 239000000843 powder Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 238000005269 aluminizing Methods 0.000 description 8
- 239000012071 phase Substances 0.000 description 8
- 239000007921 spray Substances 0.000 description 8
- 230000035515 penetration Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000008439 repair process Effects 0.000 description 4
- 239000002737 fuel gas Substances 0.000 description 3
- 229910001092 metal group alloy Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910002515 CoAl Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910000943 NiAl Inorganic materials 0.000 description 2
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000112 cooling gas Substances 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009760 electrical discharge machining Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LNMBCRKRCIMQLW-UHFFFAOYSA-N 2-tert-butylsulfanyl-2-methylpropane Chemical compound CC(C)(C)SC(C)(C)C LNMBCRKRCIMQLW-UHFFFAOYSA-N 0.000 description 1
- 229910000951 Aluminide Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 101100032932 Mus musculus Raly gene Proteins 0.000 description 1
- 229910001347 Stellite Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910001235 nimonic Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910000753 refractory alloy Inorganic materials 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000000992 sputter etching Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- -1 superalloys Chemical class 0.000 description 1
- 238000005382 thermal cycling Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910000843 ultimet Inorganic materials 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/18—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/499165 | 2000-02-07 | ||
| US09/499,165 US20020098294A1 (en) | 2000-02-07 | 2000-02-07 | Method of providing a protective coating on a metal substrate, and related articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2001295021A true JP2001295021A (ja) | 2001-10-26 |
Family
ID=23984108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001028936A Withdrawn JP2001295021A (ja) | 2000-02-07 | 2001-02-06 | 金属基体に保護皮膜を形成する方法および得られた物品 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20020098294A1 (ko) |
| EP (1) | EP1122329A1 (ko) |
| JP (1) | JP2001295021A (ko) |
| KR (1) | KR20010078361A (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015063752A (ja) * | 2013-08-27 | 2015-04-09 | 公立大学法人大阪府立大学 | Ｎｉ基金属間化合物合金の溶射皮膜、溶射皮膜被覆部材および溶射皮膜の製造方法 |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6575349B2 (en) * | 2001-02-22 | 2003-06-10 | Hickham Industries, Inc. | Method of applying braze materials to a substrate |
| JP3905724B2 (ja) * | 2001-06-13 | 2007-04-18 | 三菱重工業株式会社 | Ｎｉ基合金製部品の補修方法 |
| US6571472B2 (en) * | 2001-08-14 | 2003-06-03 | General Electric Company | Restoration of thickness to load-bearing gas turbine engine components |
| US6673467B2 (en) | 2001-10-01 | 2004-01-06 | Alstom (Switzerland) Ltd | Metallic component with protective coating |
| US6998151B2 (en) * | 2002-05-10 | 2006-02-14 | General Electric Company | Method for applying a NiAl based coating by an electroplating technique |
| EP1380672A1 (en) * | 2002-07-09 | 2004-01-14 | Siemens Aktiengesellschaft | Highly oxidation resistant component |
| US7157151B2 (en) * | 2002-09-11 | 2007-01-02 | Rolls-Royce Corporation | Corrosion-resistant layered coatings |
| US6887529B2 (en) * | 2003-04-02 | 2005-05-03 | General Electric Company | Method of applying environmental and bond coatings to turbine flowpath parts |
| US20050098243A1 (en) | 2003-11-06 | 2005-05-12 | General Electric Company | Method for HVOF or LPPS restoration coating repair of a nickel-base superalloy article |
| EP1541713A1 (de) * | 2003-12-11 | 2005-06-15 | Siemens Aktiengesellschaft | Metallische Schutzschicht |
| US20080057214A1 (en) * | 2004-09-14 | 2008-03-06 | Ignacio Fagoaga Altuna | Process For Obtaining Protective Coatings Against High Temperature Oxidation |
| US8367963B2 (en) * | 2004-10-29 | 2013-02-05 | United Technologies Corporation | Method and apparatus for microplasma spray coating a portion of a turbine vane in a gas turbine engine |
| EP1837485B8 (en) * | 2006-03-24 | 2010-09-22 | Siemens Aktiengesellschaft | Component with a protective layer |
| ES2305920T3 (es) * | 2005-02-18 | 2008-11-01 | Siemens Aktiengesellschaft | Aleacion de mcralx, capa protectora de aleacion de mcralx, y procedimiento para su obtencion. |
| ATE471395T1 (de) | 2005-04-01 | 2010-07-15 | Siemens Ag | Schichtsystem |
| US20080102291A1 (en) * | 2006-10-31 | 2008-05-01 | Caterpillar Inc. | Method for coating a substrate |
| FR2902693A1 (fr) * | 2006-12-22 | 2007-12-28 | Siemens Ag | Systeme stratifie ayant une couche ceramique en pyrochlore. |
| US7946471B2 (en) * | 2007-02-06 | 2011-05-24 | Siemens Aktiengesellschaft | Brazing composition and brazing method for superalloys |
| US20080299306A1 (en) * | 2007-05-30 | 2008-12-04 | Caterpillar Inc. | Multi-layer substrate and method of fabrication |
| US20100080921A1 (en) * | 2008-09-30 | 2010-04-01 | Beardsley M Brad | Thermal spray coatings for reduced hexavalent and leachable chromuim byproducts |
| CN104894505A (zh) * | 2015-06-15 | 2015-09-09 | 中国南方航空工业(集团)有限公司 | 超厚涂层真空等离子喷涂成型方法 |
| CN105671471B (zh) * | 2016-01-26 | 2018-08-28 | 北京工业大学 | 一种用于制备镍基高铝涂层的粉芯丝材及其涂层制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3837894A (en) * | 1972-05-22 | 1974-09-24 | Union Carbide Corp | Process for producing a corrosion resistant duplex coating |
| US4198442A (en) * | 1977-10-31 | 1980-04-15 | Howmet Turbine Components Corporation | Method for producing elevated temperature corrosion resistant articles |
| US4585481A (en) * | 1981-08-05 | 1986-04-29 | United Technologies Corporation | Overlays coating for superalloys |
| US4714624A (en) * | 1986-02-21 | 1987-12-22 | Textron/Avco Corp. | High temperature oxidation/corrosion resistant coatings |
| US4705203A (en) * | 1986-08-04 | 1987-11-10 | United Technologies Corporation | Repair of surface defects in superalloy articles |
| JPH0432546A (ja) * | 1990-05-28 | 1992-02-04 | Mitsubishi Heavy Ind Ltd | ガスタービン動翼補修方法 |
| GB2264446A (en) * | 1992-02-27 | 1993-09-01 | Turbine Blading Ltd | Turbine blade repair |
| GB9302978D0 (en) * | 1993-02-15 | 1993-03-31 | Secr Defence | Diffusion barrier layers |
| US6102656A (en) * | 1995-09-26 | 2000-08-15 | United Technologies Corporation | Segmented abradable ceramic coating |
-
2000
- 2000-02-07 US US09/499,165 patent/US20020098294A1/en not_active Abandoned
-
2001
- 2001-01-31 EP EP01300859A patent/EP1122329A1/en not_active Withdrawn
- 2001-02-06 JP JP2001028936A patent/JP2001295021A/ja not_active Withdrawn
- 2001-02-07 KR KR1020010005916A patent/KR20010078361A/ko not_active Application Discontinuation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2015063752A (ja) * | 2013-08-27 | 2015-04-09 | 公立大学法人大阪府立大学 | Ｎｉ基金属間化合物合金の溶射皮膜、溶射皮膜被覆部材および溶射皮膜の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20020098294A1 (en) | 2002-07-25 |
| KR20010078361A (ko) | 2001-08-20 |
| EP1122329A1 (en) | 2001-08-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A300 | Application deemed to be withdrawn because no request for examination was validly filed |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20080513 |