JP2001278708A - Cockroach attractant - Google Patents

Cockroach attractant

Info

Publication number
JP2001278708A
JP2001278708A JP2000096329A JP2000096329A JP2001278708A JP 2001278708 A JP2001278708 A JP 2001278708A JP 2000096329 A JP2000096329 A JP 2000096329A JP 2000096329 A JP2000096329 A JP 2000096329A JP 2001278708 A JP2001278708 A JP 2001278708A
Authority
JP
Japan
Prior art keywords
hydroxy
furanone
attractant
cockroaches
cockroach attractant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000096329A
Other languages
Japanese (ja)
Other versions
JP4596595B2 (en
Inventor
Michishige Maekawa
道栄 前川
Masahiro Kono
昌弘 河野
Mikio Ono
幹夫 小野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Flavor Co Ltd
Japan Tobacco Inc
Original Assignee
Fuji Flavor Co Ltd
Japan Tobacco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Flavor Co Ltd, Japan Tobacco Inc filed Critical Fuji Flavor Co Ltd
Priority to JP2000096329A priority Critical patent/JP4596595B2/en
Publication of JP2001278708A publication Critical patent/JP2001278708A/en
Application granted granted Critical
Publication of JP4596595B2 publication Critical patent/JP4596595B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a cockroach attractant that strongly attracts cockroaches and retains the durable and stabilized effect. SOLUTION: The objective cockroach attractant includes, as an active ingredient, at least one selected from the group consisting of 2-ethyl-5-methyl-4- hydroxy-3(2H)-furanone, 2-methyltetrahydro-furan-3-one and 4,5-dimethyl-3- hydroxy-2(5H)-dihydro-furanone.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、特定種類のフラノ
ン誘導体を含有するゴキブリ誘引剤に関するものであ
る。このゴキブリ誘引剤によりゴキブリを特定の場所に
集めることができるので、これを利用してゴキブリの発
生状況をモニタリングすることができる。また、殺昆虫
剤と併用することによりゴキブリの防除を行うことも可
能である。
The present invention relates to a cockroach attractant containing a specific type of furanone derivative. The cockroach attractant allows the cockroaches to be collected at a specific place, and the cockroach can be used to monitor the occurrence of cockroaches. It is also possible to control cockroaches by using them together with insecticides.

【0002】[0002]

【従来の技術】従来から、マルトール、エチルマルトー
ル(特開昭52-38024号公報)、植物抽出物中のアルコー
ル類、アルデヒド類及びラクトン類(特開昭52-82729号
公報)、メープル、シラカバ、イースト抽出物、カルメ
ラ(特開昭52-82728号公報)等がゴキブリ類を誘引する
ことが知られている。しかし、これらは活性が低く、効
果的に使用するには濃度を高くする必要であった。
2. Description of the Related Art Conventionally, maltol, ethyl maltol (JP-A-52-38024), alcohols, aldehydes and lactones in plant extracts (JP-A-52-82729), maple, birch , Yeast extract, carmella (JP-A-52-82728) and the like are known to attract cockroaches. However, they had low activity and required high concentrations for effective use.

【0003】また、フラノン系誘導体がゴキブリに対し
誘引作用を持つことが報告(特開昭50-49434号公報)さ
れて以来、次々に誘引力の強いフラノン系誘導体及びシ
クロペンテノン誘導体が合成された(特開昭56-133201
号;特公平7-121845号;特開平10-101513号)。これら
の成分はある程度の誘引力を持つものの、効果の持続性
や安定性の欠くものがあり、実用上問題があった。
Further, since it has been reported that a furanone derivative has an attraction effect on cockroaches (Japanese Patent Application Laid-Open No. 50-49434), a furanone derivative and a cyclopentenone derivative having strong attraction have been synthesized one after another. (JP-A-56-133201
No .: Japanese Patent Publication No. 7-218845; Japanese Patent Laid-Open No. 10-101513). Although these components have a certain degree of attraction, there are some which lack the sustainability and stability of the effect, and have a practical problem.

【0004】[0004]

【発明が解決しようとする課題】本発明はこのような背
景のもとになされたものであり、その目的とするところ
は、ゴキブリ類を強力に誘引し、かつ効果の持続性、安
定性が高いゴキブリ誘引剤を提供することにある。
SUMMARY OF THE INVENTION The present invention has been made under such a background, and an object of the present invention is to strongly attract cockroaches, and to maintain the effect and the stability of the effect. It is to provide a high cockroach attractant.

【0005】[0005]

【課題を解決するための手段】本発明者は、上記課題を
解決すべく、ゴキブリ類に対する高い誘引効果を持つ物
質を見出すため、多種のフラノン系誘導体及びシクロペ
ンテノン誘導体について、誘引物質のスクリーニングを
行った。その結果、3種の有力な誘引物質を見出した。
これらは高い誘引効力を有し、液状のため徐放性デバイ
スに封入可能で、しかも、安定性の高い物質である。本
発明は、かかる知見に基づいてなされたものである。
Means for Solving the Problems In order to solve the above-mentioned problems, the present inventor has screened attractants for various kinds of furanone derivatives and cyclopentenone derivatives in order to find a substance having a high attracting effect to cockroaches. Was done. As a result, we found three potential attractants.
These are substances having a high attracting effect, being liquid, can be encapsulated in a sustained-release device, and have high stability. The present invention has been made based on such findings.

【0006】即ち、本発明は、2-エチル-5-メチル-4-ハ
イドロキシ-3(2H)-フラノン、2-メチルテトラハイドロ
フラン-3-オン、及び4,5-ジメチル-3-ハイドロキシ-2(5
H)-ジヒドロフラノンからなる群より選ばれる少なくと
も1種を有効成分として含有するゴキブリ誘引剤であ
る。
That is, the present invention relates to 2-ethyl-5-methyl-4-hydroxy-3 (2H) -furanone, 2-methyltetrahydrofuran-3-one, and 4,5-dimethyl-3-hydroxy- 2 (5
A cockroach attractant comprising at least one selected from the group consisting of H) -dihydrofuranone as an active ingredient.

【0007】また、本発明は、2-エチル-5-メチル-4-ハ
イドロキシ-3(2H)-フラノン、2-メチルテトラハイドロ
フラン-3-オン、及び4,5-ジメチル-3-ハイドロキシ-2(5
H)-ジヒドロフラノンからなる群より選ばれる少なくと
も1種、並びに殺昆虫成分とを含有することを特徴とす
るゴリブリ防除剤である。
The present invention also relates to 2-ethyl-5-methyl-4-hydroxy-3 (2H) -furanone, 2-methyltetrahydrofuran-3-one and 4,5-dimethyl-3-hydroxy- 2 (5
H.-dihydrofuranone is an agent for controlling a golibli contains at least one selected from the group consisting of H) -dihydrofuranone and an insecticidal component.

【0008】[0008]

【発明の実施の形態】以下、本発明を詳細に説明する。
本発明のゴキブリ誘引剤は、2-エチル-5-メチル-4-ハイ
ドロキシ-3(2H)-フラノン、2-メチルテトラハイドロフ
ラン-3-オン、及び4,5-ジメチル-3-ハイドロキシ-2(5H)
-ジヒドロフラノンからなる群より選ばれる少なくとも
1種を有効成分として含有するものである。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
The cockroach attractant of the present invention is 2-ethyl-5-methyl-4-hydroxy-3 (2H) -furanone, 2-methyltetrahydrofuran-3-one, and 4,5-dimethyl-3-hydroxy-2 (5H)
-At least one selected from the group consisting of -dihydrofuranone as an active ingredient.

【0009】本発明のゴキブリ誘引剤は、上述のフラノ
ン誘導体を適当な溶媒、例えば水、アセトン、メタノー
ル、エタノール、グリセリン、プロピレングリコールな
どに溶解し、その溶液を適当な担体、例えば、紙類、布
類、不織布などに保持させて用いることができる。この
際、有効成分とするフラノン誘導体の量は、特に限定さ
れないが、担体当たり1〜100mg程度とするのが適当であ
る。また、該誘引剤の保持担体をプラスチックフイルム
に包んで徐放性を加味することができる。さらに粘着剤
や樹脂に含有させたり、殺虫剤と共に使用したり、ベイ
ト剤中に配合するなどして、誘引粘着シートや誘引ベイ
ト剤などを製造することができる。
The cockroach attractant of the present invention is obtained by dissolving the above-mentioned furanone derivative in a suitable solvent, for example, water, acetone, methanol, ethanol, glycerin, propylene glycol, etc., and converting the solution into a suitable carrier, for example, paper, It can be used by holding it on a cloth, nonwoven fabric, or the like. At this time, the amount of the furanone derivative as the active ingredient is not particularly limited, but is suitably about 1 to 100 mg per carrier. Further, the carrier for holding the attractant can be wrapped in a plastic film to give a sustained release property. Further, an attracting pressure-sensitive adhesive sheet, an attracting bait and the like can be produced by being contained in an adhesive or a resin, used together with an insecticide, or blended in a bait.

【0010】共用する殺虫剤としては、有機リン系殺虫
剤(ジクロルボス、フェニトロチオン、ダイアジノ
ン)、カーバメート系殺虫剤(セビン、プロポクサ
ー)、ピレスロイド系殺虫剤(ペルメトリン、レスメト
リン、フェノトリン)、及びこれらの各異性体、類縁体
が挙げられる。以上の他に、ヒドラゾン系殺虫剤、オキ
サジアゾール系殺虫剤、昆虫幼若ホルモン剤、硼酸など
の公知薬剤を目的により選択利用できる。
Commonly used insecticides include organophosphorus insecticides (dichlorvos, fenitrothion, diazinon), carbamate insecticides (sevin, propoxer), pyrethroid insecticides (permethrin, resmethrin, phenothrin), and their respective isomers. And analogs. In addition to the above, known agents such as hydrazone-based insecticides, oxadiazole-based insecticides, insect juvenile hormone agents, and boric acid can be selectively used for the purpose.

【0011】本発明の誘引剤は、ゴキブリに対して種
類、発育ステージ、雌雄などに制限されることなく適用
することができる。また乳化剤、分散剤、浸透剤、懸濁
剤、湿潤剤、展着剤、賦形剤、安定化剤などを用いて、
油剤、水和剤、粉剤、顆粒剤、丸剤、錠剤、エアゾール
剤、加熱蒸散剤、燻煙剤などの誘引剤を製造することも
できる。
The attractant of the present invention can be applied to cockroaches without being limited by species, developmental stage, sex, and the like. Also, using emulsifiers, dispersants, penetrants, suspending agents, wetting agents, spreading agents, excipients, stabilizers, etc.,
Attractants such as oils, wettable powders, powders, granules, pills, tablets, aerosols, heat transpirations, and smokers can also be produced.

【0012】[0012]

〔実施例1〕[Example 1]

(1)試験方法 図1に示されるように、プラスチックケージ(100×100
×30cm)内の片側にシェルターを形成させ、そこにチャ
バネゴキブリ120頭(30頭の4回反復)を放飼して落ち着
かせ、次いで本発明の誘引剤(5mg/デバイス、2種混合
剤は2.5mgずつ混合)を備える粘着紙(トラップA)をシ
ェルターの対面に配置した。対照として誘引剤のない粘
着紙、もしくは市販粘着紙トラップを配置した(トラッ
プB)。1時間後に捕獲された両トラップ上のゴキブリを
計数した。なおケージの上部は開放されているので、供
飼虫が逃亡しないように、内壁にオイルを塗布した。 (2)試験結果
(1) Test method As shown in Fig. 1, a plastic cage (100 x 100
A shelter was formed on one side within 120 cm), and 120 German cockroaches (30 repeats 4 times) were released and allowed to settle down, and then the attractant of the present invention (5 mg / device, 2.5 kinds of mixed agent was used). The adhesive paper (Trap A) provided with the mixture (mixed in mg units) was placed on the opposite side of the shelter. Adhesive paper without attractant or a commercial adhesive paper trap was placed as a control (Trap B). One hour later, cockroaches on both traps captured were counted. Since the top of the cage was open, oil was applied to the inner wall so that the insects did not escape. (2) Test results

【0013】[0013]

【表1】 [Table 1]

【0014】〔実施例2〕試験方法は実施例1と同様で
あるが、誘引剤は調製後1ヶ月間放置したものを供試し
た。
Example 2 The test method was the same as in Example 1, except that the attractant was left standing for one month after preparation.

【0015】[0015]

【表2】 [Table 2]

【0016】〔実施例3〕米糠(2g)とトウモロコシ粉
(2g)の等量混合品にフェニトロチオンマイクロカプセ
ル(市販品)5%を加えてねりあげたものに、本発明の
誘引剤(各2.5mg/デバイス)を貼付してベイト剤とし
た。40頭のチャバネゴキブリを放飼したケージ(図1)
の中央に上記ベイト剤を配置し、1週間後に死虫を計数
した。対照としてフェニトロチオンマイクロカプセル製
剤のみ、または供試剤なしで同様に試験を行い、死虫数
を比較した。
Example 3 A mixture of equal amounts of rice bran (2 g) and corn flour (2 g) was added with 5% of fenitrothion microcapsules (commercially available), and the mixture was stirred. mg / device) to give a bait. Cage with 40 German cockroaches released (Figure 1)
The bait was placed at the center of the sample, and the dead insects were counted one week later. As a control, the same test was performed without using the fenitrothion microcapsule preparation alone or without the test agent, and the number of dead insects was compared.

【0017】[0017]

【表3】 [Table 3]

【0018】〔実施例4〕チャバネゴキブリの発生が予
見される飲食店において、本発明の誘引剤(10mg/デバ
イス)を各1種備える粘着式トラップを床に配置し、翌
日調査した結果、いずれのトラップにも多くのチャバネ
ゴキブリが捕獲された。
Example 4 In a restaurant where the occurrence of German cockroaches is expected, sticky traps each equipped with one attractant of the present invention (10 mg / device) are placed on the floor, and as a result of investigation on the next day, Many German cockroaches were also captured in the trap.

【0019】[0019]

【表4】 [Table 4]

【0020】[0020]

【発明の効果】本発明は、新規なゴキブリ誘引剤を提供
する。このゴキブリ誘引剤は、ゴキブリ類を強力に誘引
し、かつ効果の持続性、安定性が高く、既存のゴキブリ
誘引剤に比べ優れた特性を示す。
The present invention provides a novel cockroach attractant. This cockroach attractant strongly attracts cockroaches, has high effect persistence and high stability, and exhibits excellent properties as compared with existing cockroach attractants.

【図面の簡単な説明】[Brief description of the drawings]

【図1】実施例1、実施例2、実施例3の試験に用いた
装置示す図である。
FIG. 1 is a diagram showing an apparatus used in tests of Example 1, Example 2, and Example 3.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 河野 昌弘 東京都羽村市緑ヶ丘3−5−8 富士フレ ーバー株式会社内 (72)発明者 小野 幹夫 東京都羽村市緑ヶ丘3−5−8 富士フレ ーバー株式会社内 Fターム(参考) 4H011 AC01 AC07 BA06 BA08 BB08 BB17 DA17 DB03 DC05 DD05 DG13  ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Masahiro Kono 3-5-8 Midorigaoka, Hamura-shi, Tokyo Inside Fuji Flavor Co., Ltd. (72) Mikio Ono 3-5-8 Midorigaoka, Hamura-shi, Tokyo Fuji flavor F term in reference (reference) 4H011 AC01 AC07 BA06 BA08 BB08 BB17 DA17 DB03 DC05 DD05 DG13

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 2-エチル-5-メチル-4-ハイドロキシ-3(2
H)-フラノン、2-メチルテトラハイドロフラン-3-オン、
及び4,5-ジメチル-3-ハイドロキシ-2(5H)-ジヒドロフラ
ノンからなる群より選ばれる少なくとも1種を有効成分
として含有するゴキブリ誘引剤。
(1) 2-ethyl-5-methyl-4-hydroxy-3 (2
H) -furanone, 2-methyltetrahydrofuran-3-one,
And a cockroach attractant containing at least one selected from the group consisting of 4,5-dimethyl-3-hydroxy-2 (5H) -dihydrofuranone as an active ingredient.
【請求項2】 2-エチル-5-メチル-4-ハイドロキシ-3(2
H)-フラノン、2-メチルテトラハイドロフラン-3-オン、
及び4,5-ジメチル-3-ハイドロキシ-2(5H)-ジヒドロフラ
ノンからなる群より選ばれる少なくとも1種、並びに殺
昆虫成分とを含有することを特徴とするゴリブリ防除
剤。
(2) 2-ethyl-5-methyl-4-hydroxy-3 (2
H) -furanone, 2-methyltetrahydrofuran-3-one,
And at least one selected from the group consisting of 4,5-dimethyl-3-hydroxy-2 (5H) -dihydrofuranone, and an insecticidal component.
JP2000096329A 2000-03-31 2000-03-31 Cockroach attractant Expired - Lifetime JP4596595B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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JP4596595B2 JP4596595B2 (en) 2010-12-08

Family

ID=18611111

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Country Status (1)

Country Link
JP (1) JP4596595B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3270692A4 (en) * 2015-03-18 2019-02-13 The Regents of the University of California Anthropod repellent chemicals
US10768168B2 (en) 2013-03-15 2020-09-08 The Regents Of The University Of California Methods for identifying arthropod repellents and attractants, and compounds and compositions identified by such methods
CN115777710A (en) * 2022-10-14 2023-03-14 虫捕头(苏州)生物科技有限公司 Active component and attractant of diabrotica virgifera attractant

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01207285A (en) * 1987-12-07 1989-08-21 American Cyanamid Co Insect inducer

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01207285A (en) * 1987-12-07 1989-08-21 American Cyanamid Co Insect inducer

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JPN6009068643, 日本農芸化学会誌, 1983, Vol.57, No.7, p.649−653 *
JPN6009068646, Bioscience, Biotechnology, and Biochemistry, 1993, Vol.57, No.12, p.2026−2030 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10768168B2 (en) 2013-03-15 2020-09-08 The Regents Of The University Of California Methods for identifying arthropod repellents and attractants, and compounds and compositions identified by such methods
EP3270692A4 (en) * 2015-03-18 2019-02-13 The Regents of the University of California Anthropod repellent chemicals
US11186560B2 (en) 2015-03-18 2021-11-30 The Regents Of The University Of California Arthropod repellent chemicals
CN115777710A (en) * 2022-10-14 2023-03-14 虫捕头(苏州)生物科技有限公司 Active component and attractant of diabrotica virgifera attractant

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