JP4596595B2 - Cockroach attractant - Google Patents

Cockroach attractant Download PDF

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JP4596595B2
JP4596595B2 JP2000096329A JP2000096329A JP4596595B2 JP 4596595 B2 JP4596595 B2 JP 4596595B2 JP 2000096329 A JP2000096329 A JP 2000096329A JP 2000096329 A JP2000096329 A JP 2000096329A JP 4596595 B2 JP4596595 B2 JP 4596595B2
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attractant
present
cockroaches
cockroach
cockroach attractant
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JP2001278708A (en
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道栄 前川
昌弘 河野
幹夫 小野
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富士フレーバー株式会社
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Description

【0001】
【発明の属する技術分野】
本発明は、特定種類のフラノン誘導体を含有するゴキブリ誘引剤に関するものである。このゴキブリ誘引剤によりゴキブリを特定の場所に集めることができるので、これを利用してゴキブリの発生状況をモニタリングすることができる。また、殺昆虫剤と併用することによりゴキブリの防除を行うことも可能である。
【0002】
【従来の技術】
従来から、マルトール、エチルマルトール(特開昭52-38024号公報)、植物抽出物中のアルコール類、アルデヒド類及びラクトン類(特開昭52-82729号公報)、メープル、シラカバ、イースト抽出物、カルメラ(特開昭52-82728号公報)等がゴキブリ類を誘引することが知られている。しかし、これらは活性が低く、効果的に使用するには濃度を高くする必要であった。
【0003】
また、フラノン系誘導体がゴキブリに対し誘引作用を持つことが報告(特開昭50-49434号公報)されて以来、次々に誘引力の強いフラノン系誘導体及びシクロペンテノン誘導体が合成された(特開昭56-133201号;特公平7-121845号;特開平10-101513号)。これらの成分はある程度の誘引力を持つものの、効果の持続性や安定性の欠くものがあり、実用上問題があった。
【0004】
【発明が解決しようとする課題】
本発明はこのような背景のもとになされたものであり、その目的とするところは、ゴキブリ類を強力に誘引し、かつ効果の持続性、安定性が高いゴキブリ誘引剤を提供することにある。
【0005】
【課題を解決するための手段】
本発明者は、上記課題を解決すべく、ゴキブリ類に対する高い誘引効果を持つ物質を見出すため、多種のフラノン系誘導体及びシクロペンテノン誘導体について、誘引物質のスクリーニングを行った。その結果、3種の有力な誘引物質を見出した。これらは高い誘引効力を有し、液状のため徐放性デバイスに封入可能で、しかも、安定性の高い物質である。本発明は、かかる知見に基づいてなされたものである。
【0006】
即ち、本発明は、2-エチル-5-メチル-4-ハイドロキシ-3(2H)-フラノン、2-メチルテトラハイドロフラン-3-オン、及び4,5-ジメチル-3-ハイドロキシ-2(5H)-ジヒドロフラノンからなる群より選ばれる少なくとも1種を有効成分として含有するゴキブリ誘引剤である。
【0007】
また、本発明は、2-エチル-5-メチル-4-ハイドロキシ-3(2H)-フラノン、2-メチルテトラハイドロフラン-3-オン、及び4,5-ジメチル-3-ハイドロキシ-2(5H)-ジヒドロフラノンからなる群より選ばれる少なくとも1種、並びに殺昆虫成分とを含有することを特徴とするゴリブリ防除剤である。
【0008】
【発明の実施の形態】
以下、本発明を詳細に説明する。
本発明のゴキブリ誘引剤は、2-エチル-5-メチル-4-ハイドロキシ-3(2H)-フラノン、2-メチルテトラハイドロフラン-3-オン、及び4,5-ジメチル-3-ハイドロキシ-2(5H)-ジヒドロフラノンからなる群より選ばれる少なくとも1種を有効成分として含有するものである。
【0009】
本発明のゴキブリ誘引剤は、上述のフラノン誘導体を適当な溶媒、例えば水、アセトン、メタノール、エタノール、グリセリン、プロピレングリコールなどに溶解し、その溶液を適当な担体、例えば、紙類、布類、不織布などに保持させて用いることができる。この際、有効成分とするフラノン誘導体の量は、特に限定されないが、担体当たり1〜100mg程度とするのが適当である。また、該誘引剤の保持担体をプラスチックフイルムに包んで徐放性を加味することができる。さらに粘着剤や樹脂に含有させたり、殺虫剤と共に使用したり、ベイト剤中に配合するなどして、誘引粘着シートや誘引ベイト剤などを製造することができる。
【0010】
共用する殺虫剤としては、有機リン系殺虫剤(ジクロルボス、フェニトロチオン、ダイアジノン)、カーバメート系殺虫剤(セビン、プロポクサー)、ピレスロイド系殺虫剤(ペルメトリン、レスメトリン、フェノトリン)、及びこれらの各異性体、類縁体が挙げられる。以上の他に、ヒドラゾン系殺虫剤、オキサジアゾール系殺虫剤、昆虫幼若ホルモン剤、硼酸などの公知薬剤を目的により選択利用できる。
【0011】
本発明の誘引剤は、ゴキブリに対して種類、発育ステージ、雌雄などに制限されることなく適用することができる。また乳化剤、分散剤、浸透剤、懸濁剤、湿潤剤、展着剤、賦形剤、安定化剤などを用いて、油剤、水和剤、粉剤、顆粒剤、丸剤、錠剤、エアゾール剤、加熱蒸散剤、燻煙剤などの誘引剤を製造することもできる。
【0012】
【実施例】
以下に実施例により本発明を具体的に説明する。ただし、本発明はこの実施例のみに限定されるものではない。
〔実施例1〕
(1)試験方法
図1に示されるように、プラスチックケージ(100×100×30cm)内の片側にシェルターを形成させ、そこにチャバネゴキブリ120頭(30頭の4回反復)を放飼して落ち着かせ、次いで本発明の誘引剤(5mg/デバイス、2種混合剤は2.5mgずつ混合)を備える粘着紙(トラップA)をシェルターの対面に配置した。対照として誘引剤のない粘着紙、もしくは市販粘着紙トラップを配置した(トラップB)。1時間後に捕獲された両トラップ上のゴキブリを計数した。なおケージの上部は開放されているので、供飼虫が逃亡しないように、内壁にオイルを塗布した。
(2)試験結果
【0013】
【表1】

Figure 0004596595
【0014】
〔実施例2〕
試験方法は実施例1と同様であるが、誘引剤は調製後1ヶ月間放置したものを供試した。
【0015】
【表2】
Figure 0004596595
【0016】
〔実施例3〕
米糠(2g)とトウモロコシ粉(2g)の等量混合品にフェニトロチオンマイクロカプセル(市販品)5%を加えてねりあげたものに、本発明の誘引剤(各2.5mg/デバイス)を貼付してベイト剤とした。40頭のチャバネゴキブリを放飼したケージ(図1)の中央に上記ベイト剤を配置し、1週間後に死虫を計数した。対照としてフェニトロチオンマイクロカプセル製剤のみ、または供試剤なしで同様に試験を行い、死虫数を比較した。
【0017】
【表3】
Figure 0004596595
【0018】
〔実施例4〕
チャバネゴキブリの発生が予見される飲食店において、本発明の誘引剤(10mg/デバイス)を各1種備える粘着式トラップを床に配置し、翌日調査した結果、いずれのトラップにも多くのチャバネゴキブリが捕獲された。
【0019】
【表4】
Figure 0004596595
【0020】
【発明の効果】
本発明は、新規なゴキブリ誘引剤を提供する。このゴキブリ誘引剤は、ゴキブリ類を強力に誘引し、かつ効果の持続性、安定性が高く、既存のゴキブリ誘引剤に比べ優れた特性を示す。
【図面の簡単な説明】
【図1】実施例1、実施例2、実施例3の試験に用いた装置示す図である。[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a cockroach attractant containing a specific kind of furanone derivative. Since this cockroach attractant can collect cockroaches in a specific place, it can be used to monitor the occurrence of cockroaches. It is also possible to control cockroaches when used in combination with insecticides.
[0002]
[Prior art]
Conventionally, maltol, ethyl maltol (JP-A 52-38024), alcohols in plant extracts, aldehydes and lactones (JP-A 52-82729), maple, birch, yeast extract, Carmela (Japanese Patent Laid-Open No. 52-82728) is known to attract cockroaches. However, these are low in activity and require a high concentration for effective use.
[0003]
In addition, since it was reported that furanone derivatives have an attracting action on cockroaches (Japanese Patent Laid-Open No. 50-49434), furanone derivatives and cyclopentenone derivatives with strong attraction were successively synthesized (special features). No. 56-133201; Japanese Patent Publication No. 7-21845; Japanese Patent Laid-Open No. 10-101513). Although these ingredients have a certain degree of attractiveness, there are some problems in practical use that are lacking in sustainability and stability.
[0004]
[Problems to be solved by the invention]
The present invention has been made based on such a background, and the object of the present invention is to provide a cockroach attractant that attracts cockroaches strongly and has a long-lasting and stable effect. is there.
[0005]
[Means for Solving the Problems]
In order to solve the above-mentioned problems, the present inventor screened attractants for various furanone derivatives and cyclopentenone derivatives in order to find a substance having a high attracting effect on cockroaches. As a result, we found three kinds of attractive attractants. These have a high attractive effect, are liquid, can be enclosed in a sustained-release device, and are highly stable. The present invention has been made based on such knowledge.
[0006]
That is, the present invention relates to 2-ethyl-5-methyl-4-hydroxy-3 (2H) -furanone, 2-methyltetrahydrofuran-3-one, and 4,5-dimethyl-3-hydroxy-2 (5H ) -Dihydrofuranone is a cockroach attractant containing at least one selected from the group consisting of dihydrofuranones as an active ingredient.
[0007]
The present invention also provides 2-ethyl-5-methyl-4-hydroxy-3 (2H) -furanone, 2-methyltetrahydrofuran-3-one, and 4,5-dimethyl-3-hydroxy-2 (5H ) -Dihydrofuranone is a cockroach control agent characterized by containing at least one selected from the group consisting of dihydrofuranone and an insecticidal component.
[0008]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the present invention will be described in detail.
The cockroach attractant of the present invention comprises 2-ethyl-5-methyl-4-hydroxy-3 (2H) -furanone, 2-methyltetrahydrofuran-3-one, and 4,5-dimethyl-3-hydroxy-2. It contains at least one selected from the group consisting of (5H) -dihydrofuranone as an active ingredient.
[0009]
The cockroach attractant of the present invention dissolves the above-mentioned furanone derivative in an appropriate solvent such as water, acetone, methanol, ethanol, glycerin, propylene glycol, etc., and the solution is used in an appropriate carrier such as paper, cloth, It can be used by being held in a nonwoven fabric or the like. At this time, the amount of the furanone derivative as an active ingredient is not particularly limited, but is suitably about 1 to 100 mg per carrier. In addition, the carrier for holding the attractant can be wrapped in a plastic film to add sustained release. Furthermore, an attracting adhesive sheet, an attracting bait agent, etc. can be manufactured by making it contain in an adhesive or resin, using it with an insecticide, or mix | blending in a bait agent.
[0010]
Common insecticides include organophosphorus insecticides (dichlorvos, fenitrothion, diazinon), carbamate insecticides (Sevin, propoxer), pyrethroid insecticides (permethrin, resmethrin, phenothrin), and their isomers The body is mentioned. In addition to the above, known drugs such as hydrazone insecticides, oxadiazole insecticides, insect juvenile hormone agents, and boric acid can be selected and used depending on the purpose.
[0011]
The attractant of the present invention can be applied to cockroaches without being limited by type, growth stage, male or female. Also, using emulsifiers, dispersants, penetrants, suspension agents, wetting agents, spreading agents, excipients, stabilizers, etc., oils, wettable powders, powders, granules, pills, tablets, aerosols It is also possible to produce attractants such as heat transpiration agents and smoke agents.
[0012]
【Example】
The present invention will be specifically described below with reference to examples. However, the present invention is not limited to this example.
[Example 1]
(1) Test method As shown in Fig. 1, a shelter was formed on one side of a plastic cage (100 x 100 x 30 cm), and 120 cockroaches (30 heads repeated 4 times) were released and calmed down. Then, an adhesive paper (Trap A) equipped with the attractant of the present invention (5 mg / device, two kinds of mixture were mixed at 2.5 mg each) was placed on the opposite side of the shelter. As a control, an adhesive paper without an attractant or a commercially available adhesive paper trap was placed (trap B). Cockroaches on both traps captured after 1 hour were counted. Since the upper part of the cage is open, oil was applied to the inner wall so that the insects could not escape.
(2) Test results [0013]
[Table 1]
Figure 0004596595
[0014]
[Example 2]
The test method was the same as in Example 1, except that the attractant was allowed to stand for 1 month after preparation.
[0015]
[Table 2]
Figure 0004596595
[0016]
Example 3
Attach the attractant of the present invention (each 2.5mg / device) to the mixture obtained by adding 5% fenitrothion microcapsule (commercial product) to an equal mixture of rice bran (2g) and corn flour (2g) Bait preparation. The bait agent was placed in the center of a cage (FIG. 1) where 40 German cockroaches were released, and dead insects were counted after one week. As a control, fenitrothion microcapsule preparation alone or no test agent was tested in the same manner, and the number of dead insects was compared.
[0017]
[Table 3]
Figure 0004596595
[0018]
Example 4
In restaurants where the occurrence of German cockroaches is predicted, adhesive traps with one kind of attractant (10 mg / device) of the present invention are placed on the floor, and the following day was investigated. As a result, many German cockroaches were captured in all traps. It was done.
[0019]
[Table 4]
Figure 0004596595
[0020]
【The invention's effect】
The present invention provides a novel cockroach attractant. This cockroach attractant strongly attracts cockroaches, has high durability and stability, and exhibits superior properties compared to existing cockroach attractants.
[Brief description of the drawings]
FIG. 1 is a diagram showing an apparatus used in tests of Example 1, Example 2, and Example 3. FIG.

Claims (2)

2-メチルテトラハイドロフラン-3-オンを有効成分として含有するゴキブリ誘引剤。  Cockroach attractant containing 2-methyltetrahydrofuran-3-one as an active ingredient. 請求項に記載のゴキブリ誘引剤及び殺昆虫成分を含有するゴキブリ防除剤。The cockroach control agent containing the cockroach attractant of Claim 1 and an insecticidal component.
JP2000096329A 2000-03-31 2000-03-31 Cockroach attractant Expired - Lifetime JP4596595B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2972299A4 (en) 2013-03-15 2017-01-25 The Regents of The University of California Methods for identifying arthropod repellents and attractants, and compounds and compositions identified by such methods
EP3270692A4 (en) * 2015-03-18 2019-02-13 The Regents of the University of California Anthropod repellent chemicals
CN115777710A (en) * 2022-10-14 2023-03-14 虫捕头(苏州)生物科技有限公司 Active component and attractant of diabrotica virgifera attractant

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01207285A (en) * 1987-12-07 1989-08-21 American Cyanamid Co Insect inducer

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01207285A (en) * 1987-12-07 1989-08-21 American Cyanamid Co Insect inducer

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