JP2001277415A5 - - Google Patents
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- Publication number
- JP2001277415A5 JP2001277415A5 JP2000092329A JP2000092329A JP2001277415A5 JP 2001277415 A5 JP2001277415 A5 JP 2001277415A5 JP 2000092329 A JP2000092329 A JP 2000092329A JP 2000092329 A JP2000092329 A JP 2000092329A JP 2001277415 A5 JP2001277415 A5 JP 2001277415A5
- Authority
- JP
- Japan
- Prior art keywords
- pressure
- sensitive adhesive
- adhesive layer
- recording sheet
- vinyl acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 24
- 239000010410 layer Substances 0.000 claims description 12
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 8
- 229920006026 co-polymeric resin Polymers 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 8
- 229920001519 homopolymer Polymers 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 238000002788 crimping Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 240000003183 Manihot esculenta Species 0.000 description 1
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
Description
【００１０】
【課題を解決するための手段】本発明者らは、鋭意研究した結果、課題を解決することができる本発明の圧着記録用紙を発明するに至った。即ち、本発明の圧着記録用紙は、支持体の少なくとも片面に、通常状態では粘着性、接着性とも示さず、加圧により剥離可能な接着性を示す感圧接着層を有する圧着記録用紙において、該感圧接着層がゴム成分、および酢酸ビニルモノマーを用いて得られた単独重合体樹脂、または共重合体樹脂を含有し、ゴム成分に対して酢酸ビニルモノマーを用いて得られた単独重合体樹脂または共重合体樹脂が重量部で１００対１〜１２０の割合で存在することを特徴とする圧着記録用紙である。[0010]
Means for Solving the Problems As a result of intensive studies, the present inventors have come to invent the pressure-sensitive adhesive recording sheet of the present invention which can solve the problems. That is, the pressure-sensitive adhesive recording sheet according to the present invention is a pressure-sensitive adhesive recording sheet having a pressure-sensitive adhesive layer which does not exhibit adhesiveness or adhesiveness in a normal state and exhibits adhesiveness which can be peeled off under pressure. The pressure-sensitive adhesive layer contains a rubber component, and a homopolymer resin or copolymer resin obtained using a vinyl acetate monomer, and a homopolymer obtained using a vinyl acetate monomer for the rubber component The pressure -sensitive adhesive recording sheet is characterized in that the resin or copolymer resin is present in a ratio of 100 to 1 to 120 by weight .
【００１１】
また、本発明の圧着記録用紙は、該感圧接着層に用いられるゴム成分に対して酢酸ビニルモノマーを用いて得られた単独重合体樹脂または共重合体樹脂が重量部で１００対５〜５０の割合で存在することを特徴とする圧着記録用紙である。[0011]
In the pressure-sensitive adhesive recording sheet of the present invention, 100 to 5 to 50 parts by weight of homopolymer resin or copolymer resin obtained by using a vinyl acetate monomer to the rubber component used for the pressure-sensitive adhesive layer . The pressure-sensitive adhesive recording sheet is characterized by being present at a ratio of
【００１２】
また、本発明の圧着記録用紙は、該感圧接着層に用いられるゴム成分、および酢酸ビニルモノマーを用いて得られた単独重合体樹脂または共重合体樹脂がエマルションであることを特徴とする圧着記録用紙である。[0012]
The pressure-sensitive adhesive recording sheet of the present invention is characterized in that the rubber component used in the pressure-sensitive adhesive layer and the homopolymer resin or copolymer resin obtained using the vinyl acetate monomer are an emulsion. It is a recording sheet.
【００３０】
実施例１
Example 1
【００３１】
実施例２
ＭＭＡ２５％グラフト天然ゴム １００部
エチレン・酢酸ビニル共重合体エマルション（有効成分） ２５部
合成シリカ ５０部
水 ３００部
上記配合により感圧接着層形成用塗工液を調整後、支持体として坪量１２７．９ｇ／ｍ2の上質紙を用い、その片面に乾燥塗工量７ｇ／ｍ2になるようにエアナイフコーターを用いて塗工、乾燥して目的とする圧着記録用紙を得た。[0031]
Example 2
MMA 25% Grafted natural rubber 100 parts Ethylene / vinyl acetate copolymer emulsion (active ingredient) 25 parts Synthetic silica 50 parts Water 300 parts After adjusting the coating liquid for pressure-sensitive adhesive layer formation according to the above composition, a basis weight of 127 as a support used wood-free paper of .9g / m 2, to obtain a coating crimping recording paper dried to an object by means of an air knife coater so that the dry coating amount 7 g / m 2 on one surface.
【００３３】
比較例２
ＭＭＡ２５％グラフト天然ゴム １００部
アクリル酸エステル系エマルション（有効成分） ５，１０、５０部
合成シリカ ５０部
タピオカデンプン ５０部
水 ３００部
上記配合により感圧接着層形成用塗工液を調整後、支持体として坪量８１．４ｇ／ｍ2の上質紙を用い、その片面に乾燥塗工量７ｇ／ｍ2になるようにエアナイフコーターを用いて塗工、乾燥した後、反対の面に乾燥塗工量８ｇ／ｍ2になるようにエアナイフコーターを用いて塗工、乾燥して目的とする圧着記録用紙を得た。[0033]
Comparative example 2
MMA 25% Grafted natural rubber 100 parts acrylic acid ester emulsion (active ingredient) 5, 10, 50 parts Synthetic silica 50 parts Tapioca starch 50 parts water 300 parts After adjusting the coating fluid for pressure-sensitive adhesive layer formation by the above-mentioned combination, support Using a high-quality paper with a basis weight of 81.4 g / m 2 as the body, it is coated using an air knife coater on one side to a dry coating amount of 7 g / m 2 and dried, and then dried coated on the opposite side Coating was carried out using an air knife coater to an amount of 8 g / m 2 and dried to obtain the intended pressure-sensitive adhesive recording sheet.
【００４２】
−圧着加工−
評価方法（１）〜（５）にかけて印刷、および印字を行った実施例の圧着記録用紙、および比較例のサンプルを、同一面上の感圧接着層同士を対向するようにはがき大（１０．１６ｃｍ×１５．２４ｃｍ）に３つ折り（Ｚ字状）に圧着して貼合わせ記録用紙とした。圧着加工は、圧着シーラー（日本ＡＭＤ製ＭＳ９１００）を使用し、加圧条件は該シーラーの調整目盛りで２２，２４，２６の３点にて行った。調整目盛りの値が小さい方が圧着圧力が高い。
評価方法（６）
［圧着作業性］
圧着加工中に、重送するなどして停機した回数を記録した。なお、停機頻度が余りにも多い場合は所定数量に満たなくとも圧着通紙不可として圧着作業を中止した。[0042]
-Crimping process-
The pressure-sensitive adhesive layers on the same side of the pressure-sensitive adhesive recording sheet of the embodiment and the samples of the comparative example printed and printed according to the evaluation methods (1) to (5) have a postcard size (10. The resultant was crimped in 16 cm × 15.24 cm) in three folds (Z shape) to obtain a laminated recording sheet. Crimping was performed using a crimp sealer (MS9100 manufactured by AMD Japan) under pressure conditions at three points of 22, 24, 26 on the adjustment scale of the sealer. The smaller the value of the adjustment scale, the higher the crimping pressure.
Evaluation method (6)
Crimping workability
During the crimping process, the number of times the machine was stopped by double feeding etc. was recorded. In addition, when the stop frequency was too high, the pressure-bonding operation was stopped as the pressure-sensitive sheet could not be passed even if the predetermined number was not reached.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000092329A JP2001277415A (en) | 2000-03-29 | 2000-03-29 | Press bonding recording paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000092329A JP2001277415A (en) | 2000-03-29 | 2000-03-29 | Press bonding recording paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2001277415A JP2001277415A (en) | 2001-10-09 |
| JP2001277415A5 true JP2001277415A5 (en) | 2004-09-24 |
Family
ID=18607679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000092329A Withdrawn JP2001277415A (en) | 2000-03-29 | 2000-03-29 | Press bonding recording paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2001277415A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4753564B2 (en) * | 2004-10-29 | 2011-08-24 | 北越紀州製紙株式会社 | Removable pressure-sensitive recording paper |
| JP4738850B2 (en) * | 2005-03-14 | 2011-08-03 | 北越紀州製紙株式会社 | Removable pressure-sensitive recording paper |
| JP5134771B2 (en) * | 2005-09-30 | 2013-01-30 | アイカ工業株式会社 | Water-based adhesive composition and information carrying sheet using the same |
| JP4607065B2 (en) * | 2006-07-20 | 2011-01-05 | 紀州製紙株式会社 | Crimp postcard base paper |
| JP5008934B2 (en) * | 2006-09-27 | 2012-08-22 | アイカ工業株式会社 | Removable water-based adhesive composition and information carrying sheet using the same |
-
2000
- 2000-03-29 JP JP2000092329A patent/JP2001277415A/en not_active Withdrawn
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