JP2001240459A - Artificial stone and method for producing the same - Google Patents
Artificial stone and method for producing the sameInfo
- Publication number
- JP2001240459A JP2001240459A JP2000053238A JP2000053238A JP2001240459A JP 2001240459 A JP2001240459 A JP 2001240459A JP 2000053238 A JP2000053238 A JP 2000053238A JP 2000053238 A JP2000053238 A JP 2000053238A JP 2001240459 A JP2001240459 A JP 2001240459A
- Authority
- JP
- Japan
- Prior art keywords
- sand
- glass powder
- artificial stone
- sand material
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B32/00—Artificial stone not provided for in other groups of this subclass
- C04B32/005—Artificial stone obtained by melting at least part of the composition, e.g. metal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は人工石とその製造方
法に関し、詳しくは、建築物の内外装用材その他に用い
る美観性に優れた人工石とその製造方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an artificial stone and a method for producing the same, and more particularly, to an artificial stone having excellent aesthetics and used for interior and exterior materials of buildings and a method for producing the same.
【0002】[0002]
【従来の技術】これまで、建築物の内外装材として各種
材料が採用されてきた。特に、美観性を重視した素材と
して、天然の素材をそのまま使用する場合の他に、人工
的な素材、例えば人工大理石、各種タイルなども多用さ
れている。このうち人工大理石は、無機粉末に主として
アクリル系樹脂を混在させたものが開発され、キッチン
天板、各種カウンタートップ、洗面化粧台、床材、壁
材、間仕切り板などに使用されている。2. Description of the Related Art Hitherto, various materials have been employed as interior and exterior materials for buildings. In particular, in addition to a case where a natural material is used as it is as a material with an emphasis on aesthetics, an artificial material such as artificial marble and various tiles are often used. Among them, artificial marble has been developed in which an acrylic resin is mainly mixed with inorganic powder, and is used for kitchen top plates, various counter tops, vanities, flooring materials, wall materials, partition boards, and the like.
【0003】更に、陶磁器の表面に施ユウ後、焼成され
る等して製造される装飾タイルも、彩飾の容易さ、安価
である等のため建築物の内外装材として多用されてい
る。[0003] Further, decorative tiles manufactured by applying a material to the surface of ceramics and then firing the ceramics are also widely used as interior and exterior materials for buildings because of their ease of coloring and low cost.
【0004】[0004]
【発明が解決しようとする課題】しかしながら、人工大
理石は、無機粉末に樹脂を混在させたものであるため、
径年変化を受け易く、しかも長年使用されている間に機
械的に弱い樹脂部分に傷がつくなど、実使用時に美観性
の維持に問題がある。However, since artificial marble is a mixture of inorganic powder and resin,
There is a problem in maintaining aesthetics during actual use, such as being susceptible to aging, and mechanically weak resin parts being damaged during long-term use.
【0005】又、従来の装飾タイルの表面を構成する表
層は釉薬のみで形成されているため、表面が一様に光沢
を有することもあって色調が単調となり、美観性にはな
お改良の余地があり、しかも粘土などを用いているため
耐久性にも問題があった。Further, since the surface layer constituting the surface of the conventional decorative tile is formed only of glaze, the color tone is monotonous due to the uniform gloss of the surface, and there is still room for improvement in aesthetics. However, there is also a problem in durability due to the use of clay and the like.
【0006】そこで、本発明の目的は、上記従来技術の
有する問題点に鑑みて、素材の持ち味からくる素朴な美
観を表層に形成可能で、色調が単調となり難く、それで
いて強度的にも優れた新規な人工石とその製造方法を提
供することにある。In view of the above-mentioned problems of the prior art, the object of the present invention is to make it possible to form a simple aesthetic appearance on the surface layer due to the characteristics of the material, to make it difficult for the color tone to be monotonous, and to be excellent in strength. An object of the present invention is to provide a new artificial stone and a method for producing the same.
【0007】[0007]
【課題を解決するための手段】上記目的は各請求項記載
の発明により達成される。すなわち、本発明に係る人工
石の特徴構成は、砂材とガラス粉末との混合物が加熱融
着され一体化されたことにある。The above object is achieved by the invention described in each claim. That is, the characteristic configuration of the artificial stone according to the present invention resides in that the mixture of the sand material and the glass powder is heat-fused and integrated.
【0008】この構成によれば、光沢の少ない砂材と光
沢のあるガラス材とが混合されて、砂材の有する素材の
持ち味を発揮しつつガラス質のもつ光沢部分とが適度に
分布すると共に、砂材が劈開面を有することが多いこと
から、見る角度によって異なる色調を発揮するようにす
ることもでき、従来存在しなかった新規かつ美麗な人工
石を提供できる。しかも、砂材間のガラス粉末により強
固に固着結合され強度的にも優れ、耐久性のある人工石
となり得るものである。According to this configuration, the sand material having a low gloss and the glossy glass material are mixed, and the glossy portion of the vitreous material is appropriately distributed while exhibiting the characteristics of the material of the sand material. Since a sand material often has a cleavage plane, a different color tone can be exhibited depending on a viewing angle, and a new and beautiful artificial stone which has not existed conventionally can be provided. In addition, it is firmly bonded and bonded by the glass powder between the sand materials, and is excellent in strength and can be a durable artificial stone.
【0009】尚、本明細書において「砂材」は、天然砂
のみならず岩石などを粉砕した人工砂(砕砂)を含む概
念とし用いる。In the present specification, the term "sand material" is used as a concept including not only natural sand but also artificial sand (crushed sand) obtained by crushing rocks and the like.
【0010】前記砂材とガラス粉末とが、1:8〜1:
0.5の配合割合であることが好ましい。The above-mentioned sand material and glass powder are mixed in a ratio of 1: 8 to 1:
The mixing ratio is preferably 0.5.
【0011】この構成によれば、砂材の有する素材の持
ち味を発揮し、かつガラス質の光沢部分が適度に混在
し、美観性に優れた人工石を提供できる。前記砂材とガ
ラス粉末の配合割合が、1:8を越える場合には、砂材
の素材としての持ち味が形成され難くなって好ましくな
く、配合割合が1:0.5未満の場合は、ガラス粉末に
よる砂粒子の結合作用が弱くなり、強度が低下して好ま
しくない。According to this configuration, it is possible to provide an artificial stone which exhibits the characteristics of the material possessed by the sand material, has a suitable mixture of vitreous gloss portions, and is excellent in aesthetic appearance. When the mixing ratio of the sand material and the glass powder is more than 1: 8, it is not preferable because the taste of the sand material is hardly formed, and when the mixing ratio is less than 1: 0.5, the glass material is glass. The binding action of the sand particles by the powder is weakened, and the strength is undesirably reduced.
【0012】前記砂材とガラス粉末との混合物に対し
て、更にアルミナ粉末を10〜40%含むことが好まし
い。Preferably, the mixture of the sand material and the glass powder further contains 10 to 40% of alumina powder.
【0013】この構成によれば、光沢が抑えられて白色
度が高められ、強度の一層高い仕上材を製造することが
できて都合がよい。この場合、アルミナ粉末の粒径は砂
材より幾分微細なものを選択することが好ましい。そし
て、砂材とガラス粉末との混合物に対するアルミナ粉末
の配合割合が10%未満の場合は、アルミナの有する特
性を発揮することができず、40%を越えて配合する
と、かえって強度が低くなり好ましくない。尚、本明細
書において%は全て重量%を意味する。According to this configuration, the gloss can be suppressed, the whiteness can be increased, and a finishing material having higher strength can be manufactured, which is convenient. In this case, it is preferable that the particle size of the alumina powder is selected to be slightly smaller than that of the sand material. When the compounding ratio of the alumina powder to the mixture of the sand material and the glass powder is less than 10%, the properties of alumina cannot be exhibited, and when the compounding ratio exceeds 40%, the strength is rather lowered, which is preferable. Absent. In addition, in this specification, all% means weight%.
【0014】更に、本発明に係る人工石の製造方法の特
徴構成は、砂材とガラス粉末とを混合し、この混合物を
加熱融着して前記砂材とガラス粉末とを一体化させるこ
とにある。Further, a characteristic feature of the method for producing an artificial stone according to the present invention is that a sand material and a glass powder are mixed, and this mixture is heated and fused to integrate the sand material and the glass powder. is there.
【0015】この構成によれば、素材の持ち味からくる
素朴な美観を表層に形成可能で、色調が単調となり難い
新規な人工石の製造方法を提供することができる。According to this configuration, it is possible to provide a novel method of manufacturing an artificial stone in which a simple aesthetic appearance derived from the characteristics of the material can be formed on the surface layer and the color tone is unlikely to be monotonous.
【0016】前記砂材とガラス粉末とを1:8〜1:
0.5の配合割合で混合し、少なくとも1100℃以上
に加熱することが好ましい。The sand material and the glass powder are mixed in a ratio of 1: 8 to 1:
It is preferable to mix at a mixing ratio of 0.5 and heat to at least 1100 ° C. or higher.
【0017】この構成によれば、砂材の有する素材の持
ち味を発揮し、かつガラス質の光沢部分が適度に混在
し、美観性に優れ、しかも強度的に優れた人工石を製造
できる。According to this configuration, it is possible to produce an artificial stone exhibiting the characteristics of the material of the sand material, having a vitreous glossy portion mixed appropriately, and having excellent aesthetics and excellent strength.
【0018】前記砂材とガラス粉末との加熱融着を、7
00〜900℃に所定時間加熱して成形した後、ガラス
粉末を表面に付着させ、少なくとも1100℃以上に加
熱することが好ましい。The heat fusion between the sand material and the glass powder is performed by
After heating at 00 to 900 ° C. for a predetermined time to form the glass powder, it is preferable that the glass powder be adhered to the surface and heated to at least 1100 ° C. or higher.
【0019】この構成によれば、砂粒子どうしの結合を
強化でき、強度的に一層優れたものを製造できると共
に、ガラス質特有の美麗な表面仕上げを強調した外観に
形成できて商品価値が高まり都合がよい。According to this structure, the bond between the sand particles can be strengthened, and a material having a more excellent strength can be manufactured. In addition, a beautiful surface finish peculiar to vitreous material can be formed in an appearance that emphasizes it, thereby increasing the commercial value. convenient.
【0020】[0020]
【発明の実施の形態】本発明の実施の形態を、以下に詳
細に説明する。本実施形態の人工石は、各種砂材とガラ
ス粉末とを混合して、これを型枠内に均一になるように
配置した後、所定温度に加熱焼成することにより形成さ
れる。砂材としては、特に限定されるものではなく、通
常の0.074〜2.4mm程度の粒径のものが好まし
いが、これより大径あるいは小径のものが混在していて
もよい。更に、海砂、川砂、山砂、あるいは石英分、長
石分の多い砂、その他の各種砂材、色砂など、更には砕
砂のような人工砂材を使用することもできる。又、比較
的均一な粒径の砂、あるいは異なる粒径の混在した砂な
どであってもよく、比較的大径の砕石、じゃり等が混在
していてもよい。DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described in detail below. The artificial stone of the present embodiment is formed by mixing various sand materials and glass powder, arranging them uniformly in a mold, and firing them at a predetermined temperature. The sand material is not particularly limited, and preferably has a normal particle size of about 0.074 to 2.4 mm, but may have a larger diameter or a smaller diameter. Furthermore, sea sand, river sand, mountain sand, sand containing a large amount of quartz or feldspar, other various sand materials, colored sand, and artificial sand materials such as crushed sand can also be used. Also, sand having a relatively uniform particle size, sand having a different particle size, or the like may be used.
【0021】ガラス粉末は、砂材よりも細かい小径のも
のを使用することが好ましいが、その成分については、
通常の珪酸ガラス、ソーダ石灰ガラス等の他、各種組成
のガラス粉末を使用することができ、着色ガラス粉末な
どを使用してもよい。It is preferable to use a glass powder having a small diameter finer than a sand material.
In addition to ordinary silicate glass, soda-lime glass and the like, glass powders of various compositions can be used, and colored glass powders and the like may be used.
【0022】砂材とガラス粉末を焼成する場合、型枠は
必ずしも必要ではないが、所定形状の型枠内に砂材とガ
ラス粉末とを配置して焼成すると、所定形状に仕上げる
ことができて好ましい。型枠については、焼成すること
を考慮して耐熱性を備えた鋳鉄、その他の金属、セラミ
ック、カーボン等から所定形状に形成されたものを使用
でき、その際、焼成後型から取り外し容易になるような
形状にしておくことが作業効率を高めることができて便
利である。例えば、底板と側板(囲い枠)とからなる型
枠を使用し、焼成後、まず底板を外すようにすると離型
が容易となる。もっとも、離型剤を型枠表面に塗布して
から焼成するようにしてもよい。When firing the sand material and the glass powder, a mold is not necessarily required. However, if the sand material and the glass powder are arranged and fired in a mold having a predetermined shape, it can be finished to a predetermined shape. preferable. Regarding the mold, it is possible to use a cast iron having heat resistance in consideration of baking, other metal, ceramic, carbon, etc. formed in a predetermined shape, in which case it is easy to remove from the mold after baking Having such a shape is convenient because the working efficiency can be increased. For example, if a mold formed of a bottom plate and a side plate (enclosing frame) is used, and the bottom plate is first removed after firing, the mold release becomes easy. Needless to say, the release agent may be applied to the surface of the mold and then fired.
【0023】砂材とガラス粉末を型枠内に配置する際、
予めこれらを十分に乾燥して、含有する水分を除去して
おく。この乾燥が不十分であると、強度的に強い結合が
し難くなり、クラックを生じたり、焼成中に気泡が発生
して表面に不揃いな凹凸が形成されたりして好ましくな
い。When arranging the sand material and the glass powder in the mold,
These are sufficiently dried in advance to remove contained water. If the drying is insufficient, strong bonding in terms of strength becomes difficult, and cracks are generated, and bubbles are generated during firing, so that irregularities are formed on the surface, which is not preferable.
【0024】砂材とガラス粉末を型枠内に配置した後、
以下のようにして焼成する。すなわち、大気中にて少な
くとも1100℃以上に加熱することにより、砂粒子ど
うしが融着したガラス材により強固に固着接合されて、
強度的に十分な内外装材を製造することができる。この
場合、加熱を急速に行うとクラックが生じるおそれがあ
るので、徐熱することが好ましい。After placing the sand material and the glass powder in the mold,
It is fired as follows. That is, by heating to at least 1100 ° C. or more in the atmosphere, the sand particles are firmly bonded and joined by the fused glass material,
It is possible to manufacture interior and exterior materials having sufficient strength. In this case, if heating is performed rapidly, cracks may occur.
【0025】又、一旦700〜900℃に数時間加熱し
た(素焼工程)後、再度1100℃程度の高温で数時間
加熱する(本焼工程)ようにすると、砂粒子どうしが一
層強固に結合される。一段目の加熱が終了してから室温
に冷却し、その後ガラス粉末を表面に付着させて、2段
目の高温加熱を行うようにすると、表面層にガラス質特
有の色調を表わすことができ、異なる美観を呈するよう
になり、商品価値の高いものとすることもできる。更
に、多段に加熱するようにしてもよく、加熱形式につい
ては特に限定されるものではない。雰囲気を酸素を遮断
する無酸化の状態にしてもよく、特定のガスを加熱雰囲
気中に導入することにより、ガラス質の反応性に変化を
与えて種々の美観を素材表面に出現させることもでき
る。Further, once heating is performed at 700 to 900 ° C. for several hours (unbaking step), and then heating is performed again at a high temperature of about 1100 ° C. for several hours (final firing step), the sand particles are more strongly bonded to each other. You. When the first-stage heating is completed, the mixture is cooled to room temperature, and then the glass powder is adhered to the surface, and the second-stage high-temperature heating is performed. It comes to have a different aesthetic appearance and can have high commercial value. Furthermore, heating may be performed in multiple stages, and the heating method is not particularly limited. The atmosphere may be in a non-oxidizing state in which oxygen is blocked, and by introducing a specific gas into the heating atmosphere, it is possible to change the reactivity of the vitreous material to make various appearances appear on the material surface. .
【0026】[0026]
【実施例】砂材としては、表1の粒度径分布を有する海
砂を用いた。又、ガラス粉末は、0.15μm以下の粒
径が96%を占める珪酸ガラス粉末((株)ユニオン
製。商品名UP−09L)を用いた。これら海砂とガラ
ス粉末を乾燥炉で加熱し、十分乾燥させた後、約1:1
の割り合いで混合すると共に、これを耐熱性の金属型枠
内に略一定高さになるように配置した。この型枠は、縦
約200×横約200×高さ約10mmの平板状の中凹
みを有していて、1300℃程度の高温に耐えられるよ
うになっている。EXAMPLES As sand material, sea sand having a particle size distribution shown in Table 1 was used. As the glass powder, silicate glass powder (manufactured by Union Corporation, trade name: UP-09L) having a particle size of 0.15 μm or less occupying 96% was used. After heating these sea sand and glass powder in a drying furnace and drying them sufficiently, about 1: 1
, And placed in a heat-resistant metal mold so as to have a substantially constant height. This mold has a flat central recess of about 200 × 200 × 10 mm, and can withstand a high temperature of about 1300 ° C.
【0027】型枠内に、混合した海砂とガラス粉末を挿
入した後、これらを加熱炉中に配置し、徐熱しながら5
60℃に約3.5時間加熱保持し、更に800℃にて約
1.5時間加熱保持して型枠に対応した成形体を作成し
た。その後、1270℃まで約10時間かけて加熱し、
この温度で約0.5時間保持してから、炉中にて徐冷し
た。After the mixed sea sand and glass powder are inserted into the mold, they are placed in a heating furnace and gradually heated for 5 minutes.
It was heated and maintained at 60 ° C. for about 3.5 hours, and further heated and maintained at 800 ° C. for about 1.5 hours to prepare a molded body corresponding to the mold. Thereafter, it is heated to 1270 ° C. for about 10 hours,
After maintaining at this temperature for about 0.5 hour, it was gradually cooled in a furnace.
【0028】その結果、白色の砂粒子の間隙を光沢のあ
るガラス質が適度に配置され、全体として真珠様の色調
を有し、かつ強度的にも強固な人工石材を製造すること
ができた。もとより、この人工石にクラックその他の欠
陥は視認できなかった。As a result, it was possible to produce an artificial stone material in which glossy vitreous material was appropriately arranged in the gaps between the white sand particles, had a pearl-like color tone as a whole, and was strong in strength. . Naturally, no cracks or other defects were visible in this artificial stone.
【0029】[0029]
【表1】 〔別実施の形態〕 (1) 上記実施形態では、砂材とガラス粉末のみを混
合させた例を示したが、これに発泡剤などを加えて焼成
することにより、発泡性を持たせて軽量性、断熱性、耐
火性などを高めるようにしてもよい。[Table 1] [Other Embodiments] (1) In the above embodiment, an example was shown in which only a sand material and glass powder were mixed. You may make it improve the property, heat insulation, fire resistance, etc.
【0030】(2) 上記実施形態における砂材とガラ
ス粉末に、更にアルミナ粉末などのセラミック粉末を加
えてもよい。例えば、砂材:ガラス粉末:アルミナ粉末
=1:2:1に割合で混在させて上記したような条件で
焼成すると、光沢が抑えられて白色度が高められ、強度
の一層高い人工石材を製造することができた。この場
合、アルミナ粉末の粒径は砂材より幾分微細なものを選
択することが好ましく、その配合割合は、砂材とガラス
粉末の混合物に対して10〜40%程度であることが好
ましい。(2) Ceramic powder such as alumina powder may be further added to the sand material and glass powder in the above embodiment. For example, when the mixture is mixed at a ratio of sand material: glass powder: alumina powder = 1: 2: 1 and baked under the above-described conditions, gloss is suppressed, whiteness is increased, and an artificial stone material having higher strength is manufactured. We were able to. In this case, the particle size of the alumina powder is preferably selected to be slightly finer than that of the sand material, and the compounding ratio is preferably about 10 to 40% with respect to the mixture of the sand material and the glass powder.
【0031】(3) 本発明の人工石は、天井材、内壁
材、床材などの内装材の表面に施工され配されるもの
や、外壁材や屋根材などの外装材の表面に施工され配さ
れるもの、更には家具、調度品などの壁面、表面、脚
部、天板などに広く使用可能であり、他の材料と複合し
て使用され、あるいは単独で使用されてもよい。(3) The artificial stone of the present invention is constructed and arranged on the surface of an interior material such as a ceiling material, an inner wall material and a floor material, or is constructed on the surface of an exterior material such as an outer wall material or a roof material. It can be widely used for things to be arranged, and also for walls, surfaces, legs, top plates and the like of furniture, furniture, etc., and may be used in combination with other materials or used alone.
Claims (6)
され一体化された人工石。An artificial stone in which a mixture of a sand material and a glass powder is heat-fused and integrated.
1:0.5の配合割合である請求項1の人工石。2. The method according to claim 1, wherein the sand material and the glass powder are 1: 8 to
2. The artificial stone according to claim 1, wherein the mixing ratio is 1: 0.5.
て、更にアルミナ粉末を10〜40%含む請求項1又は
2の人工石。3. The artificial stone according to claim 1, further comprising 10 to 40% of an alumina powder based on the mixture of the sand material and the glass powder.
物を加熱融着して前記砂材とガラス粉末とを一体化させ
る人工石の製造方法。4. A method of manufacturing an artificial stone in which a sand material and a glass powder are mixed, and the mixture is heated and fused to integrate the sand material and the glass powder.
0.5の配合割合で混合し、少なくとも1100℃以上
に加熱する請求項4の人工石の製造方法。5. The method according to claim 1, wherein the sand material and the glass powder are mixed in a ratio of 1: 8 to 1:
The method for producing an artificial stone according to claim 4, wherein the mixture is mixed at a mixing ratio of 0.5 and heated to at least 1100 ° C.
700〜900℃に所定時間加熱して成形した後、ガラ
ス粉末を表面に付着させ、少なくとも1100℃以上に
加熱する請求項4又は5の人工石の製造方法。6. The heat fusion between the sand material and the glass powder,
The method for producing an artificial stone according to claim 4, wherein after heating and molding at 700 to 900 ° C. for a predetermined time, glass powder is adhered to the surface and heated to at least 1100 ° C. or higher.
Priority Applications (1)
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JP2000053238A JP2001240459A (en) | 2000-02-29 | 2000-02-29 | Artificial stone and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000053238A JP2001240459A (en) | 2000-02-29 | 2000-02-29 | Artificial stone and method for producing the same |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2001240459A true JP2001240459A (en) | 2001-09-04 |
Family
ID=18574653
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000053238A Pending JP2001240459A (en) | 2000-02-29 | 2000-02-29 | Artificial stone and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2001240459A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102583971A (en) * | 2012-02-28 | 2012-07-18 | 徐日宏 | Hot-melting glass with bowlder effect and manufacturing method of hot-melting glass |
-
2000
- 2000-02-29 JP JP2000053238A patent/JP2001240459A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102583971A (en) * | 2012-02-28 | 2012-07-18 | 徐日宏 | Hot-melting glass with bowlder effect and manufacturing method of hot-melting glass |
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