JP2001206812A - Makeup cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To prepare a makeup cosmetic excellent in use feeling, makeup lasting effects and secondary attachment-preventing effects. SOLUTION: This makeup cosmetic is characterized by a dicarboxylic acid ester of a polyoxyethylene represented by the chemical formula (1) (wherein, R1 and R2 are each H or a 1-4C alkyl or branched alkyl group; m, n, X and Y are each an integer of 0-5 with the proviso that they are not simultaneously 0; R3 is a 0-10C branched or linear alkylene group).

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

The present invention relates to a makeup cosmetic. More specifically, the present invention relates to a makeup cosmetic which is excellent in use feel when applying cosmetics, has excellent makeup, and has improved secondary adhesion to clothes and the like.

[0002]

2. Description of the Related Art In addition to the "aesthetic role" that makes cosmetics look more beautiful, the makeup cosmetics also have a "functionality" such as having makeup and preventing secondary adhesion and a "sensual role" that provides comfort.

In order to enhance the "functionality", it is generally known that a silicone compound is blended. However, there is a tendency that the "sensory role" such as stickiness, tingling, and slipperiness during coating is impaired. Was in

[0004] In order to fulfill the "sensory role",
Generally, spherical powder is blended to improve lubricity, mica,
Adhesion has been improved by blending plate-like powders such as talc and kaolin. However, when a large amount of the spherical powder is blended, there are drawbacks in that the adhesion to the skin is reduced and the moldability when the powder is pressed is deteriorated.

Furthermore, when a large amount of plate-like powders such as mica, talc, and kaolin are blended, lubricity is reduced, and fragrances and oils are deteriorated due to catalytic activity of the powder surface, causing unpleasant odor. There was a problem.

[0006]

As described above, it is very difficult for a makeup cosmetic to simultaneously have a satisfactory feeling of use, an excellent cosmetic holding effect, and a secondary adhesion preventing effect. There is a demand for a makeup cosmetic having two properties at the same time.

The inventors of the present invention have conducted intensive studies in view of the above-mentioned problems. As a result, when polyoxyethylene dicarboxylic acid ester and boron nitride powder are blended into a makeup cosmetic, the feeling of use, the effect of applying makeup, and the effect of preventing secondary adhesion are reduced. The inventors have found that an excellent makeup cosmetic can be obtained, and have completed the present invention.

[0008] An object of the present invention is to provide a makeup cosmetic which is imparted with a satisfactory feeling of use and has an excellent makeup holding effect and an excellent effect of preventing secondary adhesion.

[0009]

That is, the present invention provides a makeup cosmetic containing a polyoxyethylene dicarboxylic acid ester represented by the following chemical formula (1).

Embedded image (1) (wherein, R 1 and R 2 are hydrogen or an alkyl or branched alkyl group having 1 to 4 carbon atoms, m, n, X and Y are integers of 0 to 5 and are not simultaneously 0. R 3 is a carbon number. 0-10 branched or linear alkylene groups)

[0010] The present invention also provides the above external preparation for skin, wherein the polyoxyethylene dicarboxylic acid ester is diethoxyethyl succinate.

Further, the present invention provides the above-mentioned makeup cosmetic further containing a boron nitride powder.

[0012]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The configuration of the present invention will be described below in detail.

Although the polyoxyethylene dicarboxylic acid ester of the above formula (1) used in the present invention is a known substance, it is a novel compounding ingredient as a makeup cosmetic ingredient.

In the following chemical formula (1), R1 and R2 each represent an alkyl or branched alkyl group having 1 to 4 carbon atoms. If the number of carbon atoms exceeds 5, the stability of the system becomes poor. m,
n, X and Y represent an integer of 0 to 5, preferably 1 to
When the sum of m, n, X, and Y is 0, the stability of the system deteriorates. When the sum exceeds 15, the feeling of use, particularly the smooth feeling, is lost. R3 has 0 to 1 carbon atoms.
It represents a branched or straight-chain alkylene group of 0, and when the number of carbon atoms is 11 or more, the stability of the system is deteriorated.

[0015] When the polyoxyethylene dicarboxylic acid ester is diethoxyethyl succinate, a makeup cosmetic which is particularly excellent in the feeling of use, the moisturizing effect and the effect of preventing secondary adhesion can be obtained.

The amount of the polyoxyethylene dicarboxylic acid ester is not particularly limited, but is preferably 0.001 to 20.0% by weight, more preferably 0.1 to 10.0% by weight, based on the total amount of the makeup cosmetic. 0.001% by weight
If it is less than 20.0% by weight, the effect will not be exhibited, and if it exceeds 20.0% by weight, stickiness will be felt after use.

The boron nitride powder used in the present invention is a boron nitride powder usually used as a raw material for cosmetics, and is generally a powder synthesized by the following method. (1) Boron is fired at about 1500 ° C. in a nitrogen stream. (2) Firing ammonia and boron oxide, ammonium chloride and borax, or boric acid and urea at about 800 to 1600 ° C. The crystal structure includes hexagonal, wurtzite, rhombohedral, cubic, etc. The cubic and wurtzite are mainly used as abrasives, and the hexagonal is used as a lubricant. The rhombohedral shape is synthesized only by a special manufacturing method. Among them, hexagonal boron nitride is preferable because it can be easily synthesized, can be easily sized by pulverization or the like, and has the best feel when used in a cosmetic.

The boron nitride powder used in the present invention is obtained by stirring and washing the powder having the above crystal structure in a water-soluble organic solvent such as lower alcohol or acetone or an aqueous solution thereof, or an aqueous solution of a surfactant under stirring at a low temperature ( 60 ° C. or less is desirable.) It is obtained by drying under a low oxygen atmosphere (under a nitrogen stream or in a vacuum). The boron nitride powder thus obtained may be directly incorporated into cosmetics, or may be coated with a material such as higher fatty acids, oils and fats, waxes, silicone compounds, fluorine compounds, hydrocarbons, surfactants, and dextrin fatty acid esters. Processing may be performed.

The average particle size of the boron nitride powder is not particularly limited, but is preferably 0.1 to 30 μm in terms of spherical average particle size. If it is less than 0.1 μ, lubricity is impaired and 30
If it is larger than μ, it is not preferable because it feels rough.

The compounding amount of boron nitride can be selected from a wide range of 0.1 to 99% by weight in the make-up cosmetic according to the target product. When the content is less than 0.1% by weight, the above effects cannot be sufficiently obtained, which is not preferable.

In the makeup cosmetic of the present invention, in addition to the above-mentioned essential components, other components usually used in cosmetics,
For example, powder components, liquid fats and oils, solid fats and oils, waxes, hydrocarbons, higher fatty acids, higher alcohols, esters, silicones, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, humectants, Water-soluble polymers, thickeners, film agents, ultraviolet absorbers, sequestering agents, lower alcohols, polyhydric alcohols, sugars, amino acids,
An organic amine, a polymer emulsion, a pH adjuster, a skin nutrient, a vitamin, an antioxidant, an antioxidant aid, a fragrance, water and the like are appropriately blended as necessary, and according to a desired dosage form, according to a conventional method. Can be manufactured. Specific ingredients that can be blended are listed below. The makeup cosmetic of the present invention can be prepared by blending the essential ingredients described above and one or more of the following components.

As the powder component, for example, inorganic powders (for example, talc, kaolin, mica, sericite (sericite),
Muscovite, phlogopite, synthetic mica, rhombite, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, Silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, metal soap (for example, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; organic Powders (eg, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene Powders, cellulose powders, etc.); inorganic white pigments (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigments (eg, iron oxide (iron oxide), iron titanate, etc.); inorganic brown pigments (eg, γ-oxidized) Inorganic yellow pigments (eg, yellow iron oxide, loess, etc.); inorganic black pigments (eg, black iron oxide, lower titanium oxide, etc.); inorganic purple pigments (eg, mango violet, cobalt violet, etc.) ); Inorganic green pigments (for example, chromium oxide,
Chromium hydroxide, cobalt titanate, etc .; inorganic blue pigments (eg, ultramarine, navy blue, etc.); pearl pigments (eg, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica) , Bismuth oxychloride, fish scale foil, etc.); metal powder pigments (eg, aluminum powder,
Organic pigments such as zirconium, barium or aluminum lake (for example, red 201)
No., Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405
Organic pigments such as No. 203, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401 and Blue No. 404;
No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange 205
No. 4, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203
, Green No. 3 and blue No. 1); natural pigments (eg, chlorophyll, β-carotene, etc.).

Examples of liquid fats and oils include avocado oil,
Camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, Examples include soybean oil, peanut oil, teaseed oil, kaya oil, rice bran oil, sinagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.

Examples of solid fats and oils include cocoa butter, coconut oil, horse fat, hardened coconut oil, palm oil, tallow, sheep fat, hardened tallow, palm kernel oil, lard, beef tallow, mokuro kernel oil, hardened kernel oil Oil, beef tallow, mocro, hardened castor oil and the like.

Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax,
Ibota wax, whale wax, montan wax, bran wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, P
OE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, PO
E hydrogenated lanolin alcohol ether and the like.

Examples of the hydrocarbon include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax and the like.

Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, tolic acid, isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid (EPA), Docosahexaenoic acid (DHA) and the like.

Examples of higher alcohols include straight-chain alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc.); and branched-chain alcohols (eg, monostearyl glycerin ether). (Bacyl alcohol), 2-
Decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldecanol,
Isostearyl alcohol, octyl dodecanol, etc.)
And the like.

As synthetic ester oils, isopropyl myristate, cetyl octoate, octyl dodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate,
Decyl oleate, hexyl decyl dimethyl octoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, 12
-Cholesteryl hydroxystearate, ethylene glycol di-2-ethylhexanoate, fatty acid ester of dipentaerythritol, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptylundecanoate , Trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate,
Pentaerythritol tetra-2-ethylhexanoate, glycerin tri-2-ethylhexanoate, glycerin trioctanoate, glycerin triisopalmitate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, Glycerin trimyristate, glyceride tri-2-heptylundecanoate, methyl ester of castor oil fatty acid, oleyl oleate, acetoglyceride, palmitate 2-
Heptylundecyl, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester,
Di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-myristate
Hexyldecyl, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate,
2-ethylhexyl succinate, triethyl citrate and the like can be mentioned.

Examples of the silicone include linear polysiloxanes (eg, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (eg, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecasiloxane). Methylcyclohexasiloxane, etc.) Silicone resin, silicone rubber, and various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) forming a three-dimensional network structure, etc. Is mentioned.

Examples of the anionic surfactant include fatty acid soaps (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (For example,
POE-triethanolamine lauryl sulfate, POE-sodium lauryl sulfate, etc.); N-acyl sarcosine acids (for example,
Higher fatty acid amide sulfonates (eg, sodium N-myristoyl-N-methyltaurine, sodium coconut fatty acid methyltauride, sodium laurylmethyltauride, etc.); phosphate ester salts (POE-oleyl ether) Sodium phosphate, POE-stearyl ether phosphoric acid, etc.); sulfosuccinates (eg, sodium di-2-ethylhexylsulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.);
Alkylbenzene sulfonates (eg, sodium linear dodecylbenzenesulfonate, triethanolamine linear dodecylbenzenesulfonate, linear dodecylbenzenesulfonic acid, etc.); higher fatty acid ester sulfates (eg, hydrogenated coconut oil fatty acid sodium glycerin sulfate, etc.); N-acylglutamate (for example, monosodium N-lauroylglutamate, disodium N-stearoylglutamate, monosodium N-myristoyl-L-glutamate), sulfated oil (for example, funnel oil), and POE-alkyl ether carboxylic acid Acid; POE-alkyl allyl ether carboxylate; α-olefin sulfonate; higher fatty acid ester sulfonate; secondary alcohol sulfate; salt of higher fatty acid alkylolamide sulfate; lauroyl mono Sodium ethanolamidosuccinate; N-palmitoyl aspartate ditriethanolamine; sodium caseinate;

Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride); and alkylpyridinium salts (eg,
Cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride);
Alkyl quaternary ammonium salts; alkyl dimethyl benzyl ammonium salts; alkyl isoquinolinium salts; dialkyl morphonium salts; POE-alkylamines; alkyl amine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride And the like.

Examples of the amphoteric surfactant include imidazoline amphoteric surfactants (for example, 2-undecyl-N, N, N
-(Hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc .; betaine surfactants (eg, 2-heptadecyl-N- Carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryl dimethylaminoacetic acid betaine, alkyl betaine, amido betaine, sulfo betaine, etc.).

Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan monostearate) Oleate, sorbitan trioleate, diglycerol penta-2-ethylhexylate sorbitan, diglycerol sorbitan tetra-2-ethylhexylate, etc .; glycerin polyglycerin fatty acids (for example, mono-cottonseed oil fatty acid glycerin, glycerin monoerucate, glycerin sesquioleate , Glyceryl monostearate, α, α '
-Glycerin pyroglutamate oleate, glycerin malate monostearate, etc.); propylene glycol fatty acid esters (eg, propylene glycol monostearate); hydrogenated castor oil derivatives; glycerin alkyl ether;

Examples of the hydrophilic nonionic surfactant include POE-sorbitan fatty acid esters (eg, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate) POE sorbit fatty acid esters (eg, POE-sorbit monolaurate, POE-sorbit monooleate, POE-sorbit pentaoleate, POE-sorbit monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin monostearate, POE-glycerin monoisostearate, PO
POE-monooleate such as E-glycerin triisostearate, etc.); POE-fatty acid esters (eg, POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (eg, POE-lauryl ether) , POE-oleyl ether, PO
E-stearyl ether, POE-behenyl ether, POE-2-
Octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic type (eg, Pluronic etc.); POE.POP-alkyl ethers (eg, POE.PO)
P-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether, etc.); Tetra P
OE.tetra-POP-ethylenediamine condensates (eg, tetronic); POE-castor oil-hardened castor oil derivatives (eg, POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE) -Hydrogenated castor oil triisostearate, POE-hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, POE-hydrogenated castor oil maleic acid, etc.); POE-beeswax lanolin derivative (eg, POE-sorbit beeswax, etc.); alkanolamide (For example, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid ester; PO
E-alkylamine; POE-fatty acid amide; sucrose fatty acid ester; alkylethoxydimethylamine oxide; trioleyl phosphoric acid and the like.

Examples of the humectant include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12- Examples include hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, adduct of diglycerin (EO) PO, extract of radish, extract of Achillea millefolium, and extract of melilot.

Examples of natural water-soluble polymers include plant polymers (eg, gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), alge colloid (cassow extract) ), Starch (rice, corn, potato, wheat), glycyrrhizic acid); microbial polymers (eg, xanthan gum, dextran, succinoglucan, burlan, etc.); animal polymers (eg, collagen, casein,
Albumin, gelatin, etc.).

The semi-synthetic water-soluble polymer includes, for example,
Starch-based polymers (for example, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose-based polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, Crystalline cellulose,
Alginic acid-based polymers (eg, sodium alginate, propylene glycol alginate, etc.);

Examples of the synthetic water-soluble polymer include vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, etc.); polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40,000, 6
Acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethylene imine; cationic polymers, and the like.

As the thickener, for example, gum arabic,
Carrageenan, karaya gum, tragacanth gum, carob gum, quince seed (quince), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose,
CMC, hydroxyethylcellulose, hydroxypropylcellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, dialkyldimethylammonium cellulose sulfate, xanthan gum, aluminum magnesium silicate, bentonite,
Hectorite, silicic acid A1Mg (bee gum), laponite, silicic anhydride and the like.

As the ultraviolet absorber, for example, benzoic acid-based ultraviolet absorbers (for example, para-aminobenzoic acid (hereinafter referred to as P
ABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N- Dimethyl PABA ethyl ester, etc.); anthranilic acid type ultraviolet absorbers (eg, homomenthyl-N-acetylanthranilate); salicylic acid type ultraviolet absorbers (eg, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate) Benzyl salicylate, p-isopropanol phenyl salicylate, etc.); cinnamic acid ultraviolet absorbers (eg, octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-
2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate Mate, octyl-p-methoxycinnamate
(2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-
p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, etc.); benzophenone UV absorbers (for example, 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4 ′ -Tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-
Methoxy-4'-methylbenzophenone, 2-hydroxy-4-
Methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone Etc.); 3- (4'-methylbenzylidene) -d, l-
Camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-
Methylphenylbenzotriazole; 2- (2'-hydroxy
-5'-t-octylphenyl) benzotriazole; 2- (2'-
Hydroxy-5'-methylphenylbenzotriazole;dibenzalazine;dianisoylmethane;4-methoxy-4'-t-
Butyldibenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one;

Examples of sequestering agents include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, edetate Tetrasodium acid, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid,
Ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyltriacetate and the like.

The lower alcohol includes, for example, ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

Examples of the polyhydric alcohol include dihydric alcohols (eg, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3- Butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trihydric alcohols (eg, glycerin, trimethylolpropane, etc.);
Tetrahydric alcohols (eg, pentaerythritol such as 1,2,6-hexanetriol); pentahydric alcohols (eg, xylitol); hexahydric alcohols (eg, sorbitol, mannitol); polyhydric alcohol polymers (eg, Diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); dihydric alcohol alkyl ethers (eg, ethylene glycol monomethyl ether, Ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol Coal mono 2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc.); dihydric alcohol alkyl ethers (eg, diethylene glycol monomethyl) Ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, pro Pyrene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether,
Dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc .; dihydric alcohol ether esters (eg, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl) Ether acetate, ethylene glycol diazibate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate , Propylene glycol monophenyl ether acetate); glycerol monoalkyl ethers (e.g., hexyl alcohol, selachyl alcohol, batyl alcohol); sugar alcohols (e.g.,
Sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch-degrading sugar, maltose, xylitol, starch-degrading sugar reducing alcohol, etc.); glysolid; tetrahydrofurfuryl alcohol; POE-tetrahydrofur Furyl alcohol; POP-butyl ether;
POP / POE-butyl ether; tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphoric acid; POP / POE-pentaneerythritol ether, polyglycerin and the like.

As the monosaccharide, for example, tricarbonate (for example,
D-glyceryl aldehyde, dihydroxyacetone, etc.);
Tetracarbons (eg, D-erythrose, D-erythrulose,
Pentose (eg, D-threose, erythritol, etc.)
L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc.); hexose (eg, D-glucose, D-talose, D- Bucose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); heptose sugars (eg, aldheptose, heptrose etc.); octose sugars (eg, octulose etc.); deoxy sugars (eg, , 2-deoxy-D-ribose, 6-deoxy-L-
Galactose, 6-deoxy-L-mannose, etc.); amino sugars (eg, D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); uronic acids (eg, D-glucuronic acid, D-mannuronic acid) , L-guluronic acid, D-galacturonic acid, L-iduronic acid, etc.).

Examples of the oligosaccharide include sucrose, guntianose, umbelliferose, lactose, planteose, isoliqunoses, α, α-trehalose,
Raffinose, liqunoses, umbilicin, stachyose bell bath courses and the like.

Examples of the polysaccharide include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran Keratosulfuric acid, locust bingham, succinoglucan, caronic acid and the like.

Examples of amino acids include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.). Examples of the amino acid derivative include acyl sarcosine sodium (sodium lauroyl sarcosine), acyl glutamate, sodium acyl β-alanine, glutathione, and pyrrolidone carboxylic acid.

As the organic amine, for example, monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1 -Propanol and the like.

The polymer emulsion includes, for example, acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin solution, polyacryl alkyl ester emulsion, polyvinyl acetate resin emulsion,
Natural rubber latex and the like.

Examples of the pH adjusting agent include lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-
Buffers such as sodium succinate and the like can be mentioned.

As vitamins, for example, vitamin A,
B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.

Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic esters and the like.

Examples of the antioxidant aid include phosphoric acid,
Examples thereof include citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

As other compoundable components, for example,
Antiseptics (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); whitening agents (eg, placenta extracts,
Various extracts (for example, oak, oak, syrup, peony, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, yoquinin, loofah, lily,
Saffron, Senkyu, Ginger, Hypericum,
Ononis, garlic, capsicum, pepper, toucan, seaweed, etc., activators (eg, royal jelly, photosensitizers, cholesterol derivatives, etc.); blood circulation promoters (eg, nonylate valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl) Esters, capsaicin, zingerone, cantaristin tincture, ittamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandate, cinnarizine, trazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol, etc.); Leakage agents (eg, sulfur, thiantol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.)
And the like.

The form of the makeup cosmetic of the present invention is not particularly limited. For example, the form of the makeup base, foundation, white powder, blusher, lipstick, mascara, eyeshadow, eyeliner, etc. can be taken.

[0057]

EXAMPLES Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. The compounding amount is% by weight. First, test methods and evaluation methods employed in each of the examples and comparative examples will be described.

"Lightness on the skin" An actual use test was carried out on the lightness on the skin during use by 10 panelists. The evaluation criteria are as follows. A: Eight or more specialized panelists recognized that the spread on the skin during use was light. ○: 6 or more and less than 8 specialized panelists recognized that the spread on the skin during use was light. Δ: 3 or more and less than 6 specialized panelists recognized that the spread on the skin during use was light. ×: Less than three professional panelists recognized that the spread on the skin during use was light.

"Adhesion to Skin (Fitness)" A practical use test was conducted by 10 expert panelists on the adhesion to skin (fitness) after use. The evaluation criteria are as follows. A: Eight or more specialized panelists recognized that there was adhesion (fit) to the skin after use. …: 6 or more and less than 8 specialized panelists recognized that there was adhesion (fit) to the skin after use. B: Three or more and less than six professional panelists recognized that there was adhesion (fit) to the skin after use. ×: Less than 3 professional panelists recognized that there was adhesion (fit) to the skin after use.

"No makeup collapse (make-up sticky effect)"
The actual use test was performed by name. The evaluation criteria are as follows. A: Eight or more specialized panelists recognized that the makeup did not collapse after use (makes good). …: 6 or more and less than 8 specialized panelists recognized that the makeup did not collapse after use (good makeup). Δ: 3 or more and less than 6 specialized panelists recognized that the makeup did not collapse after use (the makeup had good stickiness). X: Less than 3 professional panelists recognized that the makeup did not collapse after use (makeup is good).

"No secondary adhesion to clothing, etc. (secondary adhesion-less effect)" A practical use test was conducted by 10 expert panelists to evaluate the absence of secondary adhesion to clothing, etc. after use (secondary adhesion-less effect). Carried out. The evaluation criteria are as follows. ◎: Eight or more specialized panelists recognized that there was no secondary adhesion to clothes etc. after use. ○: 6 or more and less than 8 specialized panelists recognized that there was no secondary adhesion to clothes etc. after use. Δ: 3 or more and less than 6 specialized panelists recognized that there was no secondary adhesion to clothes etc. after use. ×: Less than 3 professional panelists recognized that there was no secondary adhesion to clothes etc. after use.

"No Stickiness on Skin" A practical use test was conducted by 10 expert panelists on the absence of stickiness on the skin during and after use. The evaluation criteria are as follows. …: Eight or more specialized panelists recognized that they were not sticky during use and after use. ○: 6 or more and less than 8 specialized panelists recognized that the product was in use and non-sticky after use. Δ: Three or more and less than six specialized panelists recognized that the product was in use and non-sticky after use. ×: Less than 3 professional panelists recognized that they were not sticky during use and after use.

The oil-in-water emulsified foundations of the formulas shown in Examples 1 to 4 and Comparative Example 1 were uniformly mixed with 1 to 6 shown in Table 1, and mixed and pulverized 7 to 11 were added thereto to be uniformly dispersed. It was prepared by adding 12 to 23 dissolved by heating to this, and emulsifying uniformly. An evaluation test was conducted for the above evaluation, and the results are shown in Table 1.

[0064]

[Table 1]

The oil-in-water emulsified foundations of the formulas shown in Examples 5 to 8 and Comparative Example 2 were uniformly mixed with 1 to 6 shown in Table 2 and mixed and pulverized 7 to 12 were added thereto to be uniformly dispersed. It was prepared by adding 13-26 dissolved by heating to this and emulsifying uniformly. An evaluation test was conducted for the above evaluation, and the results are shown in Table 2.

[0066]

[Table 2]

From the above results, it can be seen that the makeup cosmetic of the present invention has excellent effects in all evaluation items. Hereinafter, other examples of the present invention will be described.

Example 9 Solid Powder Foundation (1) Talc 15.0% by weight (2) Sericite 20.0 (3) Mica 10.0 (4) PMMA spherical powder 1.0 (5) Methylsiloxane network Polymerized powder 1.0 (6) Boron nitride 9.0 (7) Titanium dioxide 12.0 (8) Iron oxide 6.0 (9) Titanium mica 1.5 (10) Liquid paraffin residue (11) Di succinate Ethoxyethyl 10.0 (12) Sorbitan sesquioleate 2.0 (13) Preservative suitable amount (14) Flavor proper amount (Production method and evaluation) The mixture of the components was added, mixed with stirring, and molded into a container to obtain a solid powdery foundation. The obtained solid powdery foundation is
The feeling of use, the sticky effect, and the secondary adhesion preventing effect were excellent.

Example 10 Water-in-oil Emulsification Foundation (1) Nylon spherical powder 2.0% by weight (2) Boron nitride 10.0 (3) Siliconized titanium dioxide 10.0 (4) Siliconized iron oxide 5.0 (5) Silicone treated sericite 1.0 (6) Silicone treated mica 1.5 (7) Metal soap treated talc 5.5 (8) Purified water residue (9) Sodium hydroxymethoxybenzophenone sulfonate 0 (10) Glycerin 10.0 (11) Dipropylene glycol 5.0 (12) Decamethylcyclopentasiloxane 10.0 (13) Liquid paraffin 3.0 (14) Methylphenyl polysiloxane 1.0 (15) Silicone Resin 5.0 (16) Sorbitan monoisostearate 2.0 (17) Diethoxy succinate Chill 4.5 (18) Preservative proper amount (19) Flavor proper amount (Production method and evaluation) A mixture obtained by uniformly mixing and dissolving each component of 12 to 19, and mixing and grinding each component of 1 to 7 In addition, it was dispersed. Next, 8 to 11 mixed and stirred uniformly were added, emulsified, and filled in a container to obtain a water-in-oil emulsified foundation. The obtained water-in-oil emulsified foundation was excellent in use feeling, makeup effect and secondary adhesion preventing effect.

[Example 11] White powder (1) Talc residue (2) Sericite 10.0% by weight (3) Organopolysiloxane elastomer spherical powder 5.0 (4) Boron nitride 20.0 (5) Iron oxide 3.0 (6) Magnesium carbonate 3.0 (7) Spherical alumina powder 4.0 (8) Squalane 2.0 (9) Glycerin trioctanoate 3.0 (10) Diethoxyethyl succinate 1.5 (11) Sorbitan sesquioleate 1.0 (12) Preservative appropriate amount (13) Flavor appropriate amount (Production method and evaluation) After mixing and pulverizing each component of 1 to 7, add a mixture of each component of 8 to 13 The mixture was mixed and stirred, and filled in a container to obtain a white powder. The obtained white powder was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

Example 12 Eye Shadow (1) Talc Residue (2) Sericite 7.0% by Weight (3) Mica 15.0 (4) Boron Nitride 33.0 (5) Mica Titanium 2.0 ( 6) Iron oxide-coated titanium mica 1.5 (7) Iron oxide 1.5 (8) Squalane 2.0 (9) Diethoxyethyl succinate 2.0 (10) Silicone resin 1.5 (11) Monooleic acid Sorbitan 0.5 (12) Preservatives proper amount (13) Flavor proper amount (Production method and evaluation) After mixing and pulverizing each of components 1 to 7, add a mixture of each of components 8 to 13 and stir and mix. Then, it was molded into a middle plate to obtain an eye shadow. The obtained eye shadow was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

Example 13 Lipstick (1) Carnauba wax 1.0% by weight (2) Candelilla wax 2.0 (3) Celesin 10.0 (4) Squalane residue (5) Glycerin triisooctanoate 9.0 (6) Glycerin diisostearate 13.0 (7) Diethoxyethyl succinate 5.0 (8) Silicone resin 8.0 (9) Hydroxypropyl-β-cyclodextrin 1.0 (10) Macadamia nut oil fatty acid cholesteryl 3. 5 (11) Synthetic sodium magnesium silicate 0.5 (12) Hydrophobic silica 0.5 (13) Purified water 2.0 (14) Boron nitride 10.0 (15) Colorant proper amount (16) Preservative suitable Amount (17) Appropriate amount of fragrance (Preparation and evaluation) 11 to 12 were dispersed in 10 heated to 60 ° C., and 9 and 13 which were uniformly dissolved were added thereto. Stir in minutes. This was added to 1 to 8 which had been separately heated and dissolved, and the mixture was sufficiently stirred. Further, 14 to 17 was added and dispersed and stirred, and then the mixture was filled in a container to obtain a lipstick. The obtained lipstick was excellent in use feeling, makeup sticking effect, and secondary adhesion preventing effect.

[0073]

According to the present invention, when polyoxyethylene dicarboxylic acid ester and boron nitride powder are blended into a makeup cosmetic, a makeup cosmetic excellent in use feel, makeup sticking effect and secondary adhesion preventing effect is provided. Is done.

 ──────────────────────────────────────────────────の Continued on the front page (72) Inventor Hiroyuki Kagogi 1050 Nippa-cho, Kohoku-ku, Yokohama, Kanagawa Prefecture Inside Shiseido Daiichi Research Center Co., Ltd. Address F-term in Shiseido Daiichi Research Center (reference) 4C083 AA122 AB032 AB151 AB152 AB232 AB242 AB322 AB432 AB442 AC012 AC022 AC072 AC122 AC242 AC342 AC372 AC401 AC422 AC442 AC542 AC792 AD042 AD072 AD092 AD152 AD172 AD252 AD492 CC11 CC12 CC13 CC21 DD DD33 EE06 EE07

Claims (3)

[Claims] 1. A makeup cosmetic comprising a polyoxyethylene dicarboxylic acid ester represented by the following chemical formula (1). Embedded image (1) (wherein, R 1 and R 2 are hydrogen or an alkyl or branched alkyl group having 1 to 4 carbon atoms, m, n, X and Y are integers of 0 to 5 and are not simultaneously 0. R 3 is a carbon number. 0-10 branched or linear alkylene groups) 2. The makeup cosmetic according to claim 1, wherein the polyoxyethylene dicarboxylic acid ester is diethoxyethyl succinate. 3. The makeup cosmetic according to claim 1, further comprising a boron nitride powder.