JP2001089793A - Resin removing agent, cleaning preparation using the resin removing agent and favorite food for removing resin - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a resin removing agent capable of effectively removing the resin originated from tobacco or the like. SOLUTION: The rein removing agent contains, as an essential component, at least one out of the following component (A) and component (B) : (A) benzyl alcohol; and (B) acetoin. Further, a cleaning preparation which contains the resin removing agent, and a favorite food for removing resin which contains the resin removing agent.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a sheath remover for removing tobacco such as tobacco, and more effectively to remove tobacco such as tobacco adhering to walls and furniture. The present invention relates to a cleaning chemical that can be removed and a luxury product that can effectively remove tobacco and the like attached to teeth and dentures.

[0002]

2. Description of the Related Art Conventionally, it is known that smoking has an adverse effect on the human body of another person due to sidestream smoke. It is also known that smoking indoors has adverse effects such as discoloring walls and furniture to yellow and attaching smell. Furthermore, for the smoker himself, it is said to be one of the causes of lung cancer, and when attached to the surface of teeth and dentures during smoking, the tooth surface turns brown and impairs the appearance, Moreover, it also causes bad breath.

[0003] Therefore, it is important to remove ash such as tobacco, and various ash removal methods have been proposed. For example, in a room, the dust is removed by a conventionally known cleaning agent. However, although the cleaning chemicals generally have an effect of removing the particles, the cleaning chemicals may rather spread the dirt when wiping them, cause the cleaning chemicals themselves to stain, peel off the pattern or color, etc. There is a disadvantage of doing so.

[0004] In the oral cavity, some dentifrices have been used to remove dents. However, since the dentifrice rubs away the dentifrice adhered to the tooth surface due to the physical abrasion force of the abrasive, which is a component of the dentifrice, it may damage enamel which cannot be regenerated. Since damage to enamel can lead to oral disease, it is important to develop a method for removing enamel without damaging it. In addition, dentifrices are effective by habitually brushing the teeth immediately after smoking.When left after smoking, the dentifrice adheres firmly to the tooth surface and accumulates over the years and is completely removed. It is difficult to remove.
However, since smoking enjoys the afterglow after smoking, it is difficult to practice brushing immediately after smoking.

[0005]

In order to solve this problem, for example, a tobacco composition containing (ethanol, propanol), a polyhydric alcohol derivative, and (amino acid, benzyl benzoate) as active ingredients is used. An article has been proposed (Japanese Patent Publication No. 3-40008). However, this tobacco or tonic composition, when used in the form of a mouthwash, dentifrice, etc., exhibits an effective removal effect, but for example, in the case of a chewy gum or the like, an essential component. However, there is a disadvantage that the surface of a favorite product such as chewing gum must be coated with a coating material such as a polyvinyl alcohol film in order to prevent the scattering of ethanol. In particular, in the case of chewing gum, there is also a disadvantage that it is difficult to design the original texture and flavor of the chewing gum because each component in the composition affects the physical properties of the gum base. Further, there is a disadvantage that the active ingredient in the composition is easily adsorbed in the gum base for cigarettes and tobacco, so that it needs to be used in combination with a substance having an abrasive effect such as calcium phosphate.

The present invention has been made in view of such circumstances, and an object of the present invention is to provide a remover capable of effectively removing tobacco and the like. It is another object of the present invention to provide a cleaning agent capable of effectively removing tobacco and the like adhered to walls and furniture without damaging them. It is still another object of the present invention to provide a luxury item for removal that can effectively remove tobacco and the like attached to the teeth or dentures without damaging the surface thereof.

[0007]

In order to achieve the above-mentioned object, the present invention provides a method in which at least one of the following components (A) and (B) is used as an essential component,
The summary of the (A) Benzyl alcohol. (B) Acetoin.

[0008] A second aspect of the present invention is a cleaning agent containing the above-mentioned removing agent. Further, the present invention provides a third aspect of the present invention, in which the remover contains a remover.

That is, the present inventor has conducted intensive studies in order to develop a product which can effectively remove tobacco and the like adhering to walls, furniture and the like, or teeth and dentures without damaging them. Was. In the process, as a result of repeated experimental studies focusing on the discovery of compounds that have a removing effect, it was found that benzyl alcohol (A component) and acetoin (B component) had a removing effect. Was. as a result,
It has been found that if at least one of benzyl alcohol (component A) and acetoin (component B) is an essential component and the remover is used as soon as possible, the intended purpose can be achieved,
The present invention has been reached. And if it is a cleaning agent containing the remover, it is possible to effectively remove tobacco and the like attached to them without damaging walls and furniture, and also contains the remover. It has also been found that if it is a removal item, it is possible to effectively remove tobacco and the like adhering to the teeth and dentures without damaging them.

[0010]

Next, an embodiment of the present invention will be described.

In the present invention, the removing agent contains at least one of benzyl alcohol (component A) and acetoin (component B) as essential components.

The benzyl alcohol (phenylcarbinol) as the component A is a compound represented by the following chemical formula (1). This compound is a colorless liquid with a weak aroma. And in addition to ylang-ylang oil, tuberose and acacia flower essential oil etc. in free form,
It is present as an ester in the essential oils of jasmine and gardenia flowers, Peruvian and true palsum, soybean scent, clove oil and the like, and is produced by rectifying these essential oils or separating and purifying them as acidic phthalate esters.

[0013]

Embedded image

The acetoin (acetylmethylcarbinol, dimethylketol) as the component B is a compound represented by the following chemical formula (2). This compound is an odorless liquid immediately after its production, but since the commercially available product is partially oxidized to diacetyl, it has a flavor reminiscent of sweet cream or butter. And butter, sake, soy sauce,
It is present in bread and the like, and is industrially produced by reducing diacetyl with sulfuric acid and zinc.

[0015]

Embedded image CH ₃ CH (OH) COCH ₃ (2)

As the removing agent of the present invention, the above-mentioned benzyl alcohol (component A) and acetoin (component B) are used singly or in a mixture of two kinds. And used in various product forms. The various products are not particularly limited, and include, for example, cleaning agents, foods, mouthwashes, dentifrices,
Drugs such as tablets and powders, and quasi-drugs are exemplified. Foods include, but are not particularly limited to, various foods, among which luxury items that stay in the mouth by chewing long, such as chewing gum, soft candy,
Preferred products such as tablet confections and gummy candy are suitable.

In addition, the method of the present invention is not limited to the method used by adding it to the raw material of the product as described above. May be coated or coated. Further, the remover of the present invention may be directly consumed without using it with various products.

In the present invention, it is not always necessary to purify and use benzyl alcohol (component A) and acetoin (component B), which are essential components in the above removing agent. You may use each raw material contained as it is. That is, the A component and the B component are commercially available in the form of a fragrance, a solvent, a retaining agent, and the like, respectively.
These commercially available products may be used by being added to the above various products without purification.

In the present invention, in addition to the above essential components (components A and B), other additives such as excipients are added in addition to the above essential components (components A and B). May be.

Next, the cleaning agent of the present invention will be described.

The cleaning agent of the present invention contains at least one of the above-mentioned benzyl alcohol (component A) and acetoin (component B) as an essential component and contains a remover as soon as possible.

Therefore, benzyl alcohol (component A), acetoin (B)
Component) is used alone or in combination of two types. Among them, it is particularly preferable to use at least acetoin (component B) from the viewpoint of the removal effect.

The cleaning agent of the present invention is usually obtained by dissolving or dispersing the above removing agent in water, an aqueous ethanol solution or ethanol, and applying the obtained agent as it is to a wall or furniture. Used by wiping. Thereby, it is possible to effectively remove the smell of tobacco and the like attached to the walls and furniture without damaging them. In addition, you may use a plant dry distillation component, various cleaning agents, a solvent, etc. as an arbitrary component of a cleaning chemical. By using these optional components, a further cleaning effect and a deodorizing effect are added, which is preferable.

The cleaning agent obtained and used in this manner contains the essential components (components A and B) in the above-mentioned cleaning agent at a rate of 30% by volume or more in the entire cleaning agent. It is preferred that More preferably, 50 to
It is in the range of 80% by volume. That is, when the content is less than 30% by volume, the essential components (A component and B component) in the remover are too small, and it is difficult to remove any adhering components to the wall or furniture without damaging them. This is because there is a possibility of becoming.

Next, a description will be given of the taste removing product of the present invention.

According to the present invention, there is provided a taste-removing product comprising at least one of the above-mentioned benzyl alcohol (component A) and acetoin (component B) as an essential component. It has been added.

The above-mentioned favorite items are not particularly limited, and include various items. Among them, those items which stay in the mouth for a long time by chewing, such as chewing gum, soft candy, tablet candy, gummy candy and the like are preferable. It is. In particular, chewing gum is most suitable because it can take in the ash removed from the surface of teeth, dentures, etc. and remove it effectively outside the body (outside the mouth) without reattaching.

As described above, benzyl alcohol (component A) and acetoin (component B), which are essential components in the above-mentioned removing agent, are used alone or in combination of two types. From the viewpoint of suppressing irritation, it is preferable to use at least benzyl alcohol (component A) as a main component. Here, the main component refers to a component that accounts for 50% by weight or more of the entire essential component of the removing agent, and includes a case where only the component is included. Specifically, when benzyl alcohol (component A), which is the main component, accounts for 50% by weight or more of the essential components of the remover (including the case where only the component A is included), irritation to the mouth is caused. Is particularly preferred because it is possible to suppress

[0029] The luxury remover according to the present invention is prepared by, for example, mixing the above remover with various raw materials for the luxury, and using the resulting mixture to produce various conventionally known refinements. Obtained by following. Eating the thus-obtained fragrance remover can effectively remove the halitosis of cigarettes and the like attached to them without damaging the teeth and dentures. More specifically, for example,
When chewing gum is used as a luxury item, first, a usual gum base material is put into a kneader and melt-mixed to prepare a gum base. Next, sugars, pigments, and the like are added to the gum base and mixed, and further, a remover, a fragrance, and the like are further added and mixed. Then, by shaping the obtained mixture into an appropriate shape, a chewing gum containing a remover is obtained. The chewing gum thus obtained is contained in the mouth, and by chewing, it is possible to effectively remove bad breath such as cigarettes and the like attached to the teeth and dentures without damaging them.

[0030] The above-mentioned palliative removal product contains essential components (A component and B component) in the palliative removal agent at a rate of 0.01% by weight or more in the entirety of the palliative removal product. Is preferred. That is, if the content is less than 0.01% by weight, the essential components (A component and B component) in the removing agent are too small, and the ash adhered to the teeth or dentures without being damaged is removed. This may be difficult. And, more preferably, it is in the range of 0.01 to 10% by weight, and in viscoelastic taste products such as chewing gum,
0.1 to 10 in that the effect of the removal is developed earlier.
It is preferable to set it in the range of weight%. Also, optimally,
It is in the range of 0.5 to 5.0% by weight. That is, in this range, in addition to the removing effect, the effect of suppressing irritation to the mouth and not impairing the original flavor and texture of the favorite item is surely obtained.

In addition, benzyl alcohol (component A) and acetoin (component B) are essential components in the above-mentioned removing agent.
When used in combination, acetoin (component B) may be present in an amount of 0.05% by weight or more, more preferably 0.05% to 10% by weight, and most preferably 0.1% to 1% by weight in the entire removal preference product. 0.0% by weight
Is preferred from the viewpoint that a removal effect is obtained without impairing the flavor.

The taste removing product of the present invention is a taste product having various kinds of tastes as a core material and a coating layer formed on the outer surface thereof, wherein the above-mentioned removing agent is contained in the coating layer. They may be compounded. Such a remover can be produced by, for example, applying or removing a remover (such as a liquid) on the outer surface of a prefabricated chewing gum or the like. it can. This embodiment has the advantage that when it is contained in the mouth, the coating layer containing the removing agent first comes into contact with the teeth, dentures and the like, so that the removal can be performed more effectively. For example, chewing gum is first included in the mouth, then chewed for a long time, and finally exhaled from the mouth.Therefore, at the time of chewing, a coating layer containing a remover is slightly attached to teeth or dentures. There is an advantage that the contact can be made preferentially, and the removal can be performed more effectively.

Next, examples will be described together with comparative examples.

[0034]

Examples 1 to 3 and Comparative Example 1 A 50% by volume ethanol solution was prepared to have the following concentrations. That is, a 30% by volume solution of benzyl alcohol (Example 1), a 30% by volume solution of acetoin (Example 2), a solution containing 15% by volume of each of benzyl alcohol and acetoin (Example 3), and water (Comparative Example) 1) was prepared, and these were sprayed by spraying so as to spread over 20 cm squares of the adhered wallpaper as cleaning agents, and wiped off with a cotton cloth one minute later. In addition, the wallpaper attached to the wall was produced by spraying smoke of 10 cigarettes onto a wallpaper made of vinyl chloride.

The surface of the adhering wallpaper treated as described above was judged by visual observation according to the following criteria, and the results are shown in Table 1 below. In addition, as a control, a wallpaper made of vinyl chloride before sticking (not spraying 10 cigarettes of smoke) was used. (Judgment criteria) A: The state is equivalent to that of the control (slightly removed). ：: The state is substantially the same as the control (slightly removed). ×: Stain was severe (slightly removed).

[0036]

[Table 1]

From the results shown in Table 1 above, all the cleaning chemicals of the example product could be easily wiped off without applying any force to the wallpaper, and an unpleasant odor could be removed. On the other hand, the cleaning agent of Comparative Example 1 could hardly remove any adhering to the wallpaper and could not remove an unpleasant odor.

[0038]

Examples 4 to 9 and Comparative Example 2 Each of the raw materials shown in Table 2 below was mixed using a kneader, and then mixed in a block shape (20 mm ×
(13 mm × 10 mm) to give a weight of about 3.0 g / piece to prepare a chewing gum. In each of the examples and comparative examples, each of the components shown in the same table was used for the removing agent, and the total content was 4% by weight (Example 4), 1% by weight (Example 5), Those prepared at 1% by weight (Example 6), 0.1% by weight (Example 7), 1% by weight (Example 8), and 10% by weight (Example 9) were used. Further, Comparative Example 2 containing no remover was used.

With respect to the thus obtained chewing gums of Examples and Comparative Examples, 20 expert panelists ate for 10 minutes, and performed sensory evaluation on flavor and texture. The results are shown in the same table. Indicated. In addition, the evaluation criteria of the sensory evaluation were as follows. [Evaluation Criteria for Flavor and Texture] A: The original flavor and texture of the chewing gum are not impaired and very good. ：: The original flavor and texture of the chewing gum are not impaired and are good. Δ: Chewing gum original flavor and texture are not impaired, but slightly inferior in flavor and texture. However, there is no discomfort. ×: The original flavor and texture of chewing gum are impaired, and the flavor and texture are poor.

The removal effect was evaluated as follows. That is, firstly, 21 addicted smokers (male) were arbitrarily selected and divided into 7 groups of 3 smokers, and all were allowed to brush their teeth normally. Thereafter, one cigarette of the designated brand was smoked, and after smoking, one group was given one of the chewing gums of the example product and the comparative example product, and each was eaten for 5 minutes. This was repeated until the total number of cigarettes reached 5. The toothbrush was not applied from the second toothbrush. Thereafter, the front and back surfaces (both sides) of the upper and lower front teeth of all the members were rubbed with gauze, and the particles adhering to the tooth surfaces were collected, and the degree of coloring of the gauze was evaluated by visual observation according to the following evaluation criteria. The results are shown in the same table. [Evaluation Criteria] A: No coloring at all. ：: Slightly colored. Δ: Coloring is somewhat conspicuous. X: Coloring is very conspicuous.

[0041]

[Table 2]

From the results shown in Table 2 above, all of the chewing gums of the examples were excellent in removing effect, and were good without impairing the original flavor and texture of the chewing gum. In addition, comparing Example 5, Article 6, and Article 8 with the same total removal agent content, Example 6 containing more acetoin had the highest removal effect. On the other hand, the chewing gum of Comparative Example 2 did not contain a removing agent, and thus had little removing effect, which was not preferable.

[0043]

Examples 10 to 13 and Comparative Example 3 Each of the raw materials shown in Table 3 below was tableted and formed into a triangular shape having a side of 9 mm × 3 sides and a thickness of 4 mm and weighing 0.34 g / piece. Then, a tablet was prepared. In each of the examples and comparative examples, the components shown in the same table were used for the removing agent.
The total content was 0.01 parts by weight (Example 1).
0), 0.2 parts by weight (Example 11), 0.5 parts by weight (Example 12), and 1.0 parts by weight (Example 13) were used. Further, Comparative Example 3 containing no remover was used.

With respect to the tablets of Example and Comparative Examples thus obtained, 20 expert panelists licked the two tablets in their mouths for 5 minutes, and performed sensory evaluation on the flavor and texture. The results are shown in the same table. In addition, the evaluation criteria of the sensory evaluation were as follows. [Evaluation criteria for flavor and texture] ◎: The original flavor and texture of the tablet are not impaired.
Very good. ○: The original flavor and texture of the tablet are not impaired.
Good. Δ: The original flavor and texture of the tablet were not impaired, but the flavor and texture were slightly inferior. However, there is no discomfort. ×: The original flavor and texture of the tablet were impaired, and the flavor and texture were poor.

The removal effect was evaluated in the same manner except that two tablets were used instead of the chewing gum. The results are shown in the same table. The evaluation criteria were the same.

[0046]

[Table 3]

From the results shown in Table 3 above, all of the tablets of the examples were excellent in removing effect, and were good without impairing the original flavor and texture of the tablet. On the other hand, since the tablet of Comparative Example 3 did not contain the removing agent, the tablet had little removing effect and was not preferable.

[0048]

Example 14 First, a coating liquid was prepared in which benzyl alcohol and acetoin were mixed at a ratio of 1: 1 (weight ratio). Also, according to a conventional method, the gum base 40
A chewing gum was prepared having a ratio of 1% by weight, sugars 59% by weight, and mint flavor 1% by weight. Then, the outer surface of the obtained chewing gum was coated with the above coating liquid, and then dried to form a coating layer. The thus-obtained chewing gum with a coating layer was subjected to the same sensory evaluation (flavor, texture) as described above, and good results were obtained. In addition, when the removal effect was evaluated in the same manner as above, very good results were obtained.

[0049]

As described above, the removing agent of the present invention comprises:
At least one of benzyl alcohol (component A) and acetoin (component B) is an essential component, and both components have a removing effect. It is possible to effectively remove ash such as cigarettes attached to them without damaging them or dentures. Therefore, if it is added to various products such as cleaning chemicals and luxury goods, it is possible to easily provide a product having a removing effect. And the above-mentioned benzyl alcohol (A component) and acetoin (B component)
Since it is not a volatile component, there is an advantage that ordinary packaging is sufficient without using a special packaging for preventing volatilization, for example, a coating material such as a polyvinyl alcohol film as in the related art.

With the cleaning agent containing the above-mentioned removing agent, it is possible to effectively remove tobacco and the like attached to the walls and furniture without damaging them.
In addition, if it is a luxury item for removal that contains the above-mentioned remover, it is possible to effectively remove tobacco and the like adhering to the teeth and dentures without damaging them. In addition, if it is the above-mentioned removal item, it is possible to remove the residue without using water, such as a dentifrice. There is an advantage that can be. In addition, if the taste removal product is a taste product that stays in the mouth for a long time such as chewing gum containing the remover, the chewing gum or the like will stay in the mouth for a long time due to chewing or the like, There is an advantage that the removal effect becomes particularly high.

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Claims (3)

[Claims] 1. A removing agent comprising at least one of the following components (A) and (B) as an essential component. (A) Benzyl alcohol. (B) Acetoin. 2. A cleaning agent comprising the cleaning agent according to claim 1 and a cleaning agent. 3. A removal product according to claim 1, further comprising a removing agent.