JP2001067719A - Optical information recording medium and method for recording/reproducing information - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a medium good in recording characteristic, reproducible by a CD player or a video disk player and excellent in environmental resistance by directly forming on a signal surface of a substrate a recording layer consisting of an alloy based on Au and at least, one element selected from an element group of Ge, Si and Sn and having a specified value of Au percentage content to be adjusted. SOLUTION: This optical information recording medium is constituted so that the recording layer 3 and a protecting layer 4 are successively laminated on the signal surface 2 of the substrate 1. A signal pattern 5 having a minutely uneven shape is formed on the surface 2. The layer 3 consists of the alloy based don at least, one element selected from the element group of Ge, Si and Sn and at least, one element selected from the element group of Au, Ag, Al and Cu. The layer 3 having 70 at.% Au percentage content to be adjusted, when Au is used, is directly formed on the surface 2. The optical information recording medium thus obtained has high reflectance, a large signal modulation degree and excellent oxidation resistance.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to FM-modulated analog signals such as video and audio signals, radiation data from electronic computers, facsimile signals and digital audio signals. The present invention relates to an optical information recording medium capable of recording digital information in real time and an information recording / reproducing method using the same.

[0002]

2. Description of the Related Art Conventionally, there has been known an optical information recording medium in which a thin film (recording layer) made of a heat mode recording material is carried on a substrate and information can be additionally recorded by a photothermal action of radiation.

There are various recording principles for recording on a thin film by radiation, and a recording thin film composed of a metal layer mainly composed of Te, Bi or the like or a dye layer of cyanine or the like, recording by deformation, sublimation, evaporation, etc., Te-Ge System, As-Te-Ge
There are known phase transitions (also referred to as phase changes) of a system, Te-O system, and the like, and recording by atomic arrangement change such as photodarkening.

[0004] On the other hand, read-only optical information recording media in which information is recorded in advance and information is not recorded or erased by radiation are widely used in audio and video departments. A CD (compact disk) is a typical optical information recording medium exclusively used for reproduction in the audio sector, and a video disk is a typical optical information recording medium exclusively used for reproduction in the video sector. It is. The specifications of the playback signal in these read-only optical information recording media are:
For example, it is standardized as a CD format.

Further, an optical information recording medium (recordable CD) in which information can be additionally recorded and information can be reproduced by a CD player.
Also, an optical information recording medium (write-once type video disc) in which information can be additionally written and a video disc player can reproduce the information has been actively developed.

[0006]

In order to put the write-once CD and write-once video disc to practical use, the reflectance and the degree of signal modulation of the recorded information should be adjusted to satisfy the conditions required by each player. There is a need. For example, with respect to a write-once CD, conditions such as a reflectance of 70% or more and a signal modulation degree of 11T signal recording of 60% or more must be satisfied.

[0007] The recording material used in the above-mentioned conventional recordable optical information recording medium is set so that the irradiated radiation is efficiently absorbed and the reflectivity is reduced in order to obtain high recording sensitivity. Therefore, it is impossible to reproduce information on a CD player or a video disc player. Also,
When an optical information recording medium is formed in a single-plate structure in the same manner as a conventional CD, it is particularly required to have excellent environmental resistance. However, all of the conventional write-once recording materials have difficulty in environmental resistance.
Also from this point, it is not suitable to use as a write-once CD.

The present invention has been made in view of the above-mentioned state of the art, and has good recording characteristics and can be reproduced by a CD player or a video disk player.
It is another object of the present invention to provide an optical information recording medium having excellent environmental resistance and a method for recording and reproducing information on the optical information recording medium.

[0009]

In order to achieve the above object, the present invention relates to an optical information recording medium having an optical information recording medium comprising a thin film including at least a recording layer on a signal surface of a substrate. In the above, [G
e, Si, Sn] A recording layer composed of an alloy containing at least one element selected from the group of elements and Au as a main component and having an Au content adjusted to 70 atomic% is directly formed. When the recording radiation beam is irradiated to the layer, the arrangement of atoms in the recording radiation beam irradiation section of the recording layer changes, and the substrate, which is the base of the recording radiation beam irradiation section, is deformed to generate information. Is recorded.

The optical information recording medium has a wavelength of 780 nm.
Can have a reflectance of 70% or more.

On the other hand, with respect to the information recording / reproducing method, at least one element selected from the [Ge, Si, Sn] element group and an alloy containing Au as a main component are formed on the signal surface of the substrate. Using an optical information recording medium on which a recording layer whose content is adjusted to 70 atomic% is directly formed, and when recording information, irradiating the recording layer with a recording radiation beam;
The heat causes a change in the atomic arrangement in the recording radiation beam irradiating section of the recording layer and causes deformation of the substrate that is the base of the recording radiation beam irradiating section,
At the time of reproducing information, a reproducing radiation beam is irradiated along the information recording part, and the change in the atomic arrangement generated in the recording layer and the change in the reflectance caused by the deformation generated in the substrate are optically read. I made it.

An alloy in which at least one element Au selected from the [Ge, Si, Sn] element group exists at an appropriate ratio has a reflectance of 70% or more. In addition, since this alloy has a eutectic structure and a relatively low melting point, not only recording sensitivity is good, but also changes in the atomic arrangement, such as a change from an amorphous phase to a crystalline phase, must be performed at high speed. Can be. Furthermore, this alloy has excellent environmental resistance, especially corrosion resistance. Therefore, it can be a recording layer suitable for a write-once CD or a write-once video disc.

On the other hand, even if a thin film mainly composed of the above-mentioned group A element and a thin film mainly composed of the group B element are laminated, a reflectance of 70% or more and high environmental resistance can be provided. Further, when both of the above thin films are melted and alloyed by light heat during recording, the reflectance changes as compared with the case where each thin film exists alone. Therefore, it can be a recording layer suitable for a write-once CD or a write-once video disc.

[0014] Further, by irradiating the recording radiation beam, the atomic arrangement of the recording layer is changed, and information is recorded by deforming the substrate or the thermally deformable layer of the underlying layer. When the information is reproduced by optically reading the change in the reflectance accompanying the deformation of the substrate or the thermally deformable layer, the information is recorded as compared with the case where the information is recorded by changing only the atomic arrangement of the recording layer. Since the change in reflectance of the part can be greatly increased,
Good reproduction characteristics can be obtained.

By irradiating a recording radiation beam, the thin film mainly composed of the group A element and the thin film mainly composed of the group B element are melted and mixed, and the substrate or the thermally deformable layer of the base is deformed. The same applies to the case where information is recorded by reading the information and the information is reproduced by optically reading out the change in the reflectance accompanying the mixing of the recording layers and the deformation of the substrate or the thermally deformable layer.

[0016]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A first embodiment of the present invention is shown in FIG.
This will be described with reference to FIG. FIG. 1 is a sectional view of a main part of an optical information recording medium according to the present embodiment, FIG. 2 is a plan view, and FIG. 3 is an explanatory diagram showing a method of recording and reproducing information using the optical information recording medium of the present embodiment.

As shown in FIG. 1, the optical information recording medium of the present embodiment is formed by sequentially laminating a recording layer 3 and a protective layer 4 on the signal surface 2 of a substrate 1 from the substrate 1 side.

The substrate 1 is formed into a desired shape and size using a transparent plastic material that is relatively easily deformed by heat, such as polycarbonate, polyolefin, epoxy, and acrylic.

On the signal surface 2, a signal pattern 5 such as a guide groove for guiding a light beam spot and a pre-pit row representing a header signal is formed in a fine uneven shape. The signal pattern 5 is formed in a concentric spiral or concentric shape with the substrate 1 as shown in FIG.

The recording layer 3 is made of at least one element selected from the group [Ge, Si, Sn] (group A element).
And at least one element (group B element) selected from the [Au, Ag, Al, Cu] element group.

Of course, Tl,
Co, Fe, Ni, Sc, Ti, V, Cr, Mn, Z
n, Y, Zr, Nb, Mo, Ru, Rh, Pd, Cd,
Hf, Ta, W, Re, Os, Ir, Pt, Te, S
e, Sb, S, Hg, As, B, C, N, P, O, a halogen element, an alkali metal element, an alkaline earth metal element,
It may contain at least one of an actinide element, a lanthanide element, an inert gas element and the like.

Of the above elements, Co, Ni, Sc, T
i, V, Cr, Mn, Zn, Y, Zr, Nb, Mo, R
u, Rh, Pd, Cd, Hf, Ta, W, Re, Os,
Ir, Pt, and Fe have an effect of facilitating absorption of long-wavelength light such as a semiconductor laser beam to increase recording sensitivity, and enable high-speed crystallization. Te, Se, Sb, and S have the effect of increasing the stability of the amorphous state and improving the oxidation resistance. Tl, a halogen element, and an alkali metal element have the effect of increasing the crystallization rate and increasing the stability of the amorphous state. N, O, and Ar have the effect of increasing the stability of the amorphous state. In addition, rare earth elements and the like can play a role such as increasing the crystallization temperature.

Among the above recording materials, [Ge or S
n], and an alloy mainly composed of Al and at least one of the above elements, and having an average composition in the thickness direction represented by the following general formula. SixMAaMBbMCcMDd where MA is the above-mentioned element of Group B [Au, Ag, Cu, A
l], at least one element selected from
B is at least one element selected from the [Te, Se, S] element group, MC is at least one element selected from the [B, C, P] element group, and MD is Si (silicon). ) And elements other than the elements represented by MA, MB, and MC. Examples of the element represented by MD include Tl, Pd, Ta, W, Ir, Sc, Y, T
i, Zr, V, Nb, Cr, Mo, Mn, Fe, Ru,
Co, Rh, Ni, Sb, Hg, As, Ge, Sn,
Examples include N, O, halogen elements, alkali metal elements, alkaline earth metal elements, actinide elements, lanthanide elements, and inert gas elements.

Subscripts x, a, b, and
c and d indicate the content of each component, and can be set in the following ranges. However, the unit is atomic%. 5 ≦ x ≦ 70 30 ≦ a ≦ 95 0 ≦ b ≦ 300 0 ≦ c ≦ 300 0 ≦ d ≦ 30.

When the content of each component is set in the following range, more preferable results can be obtained. 7 ≦ x ≦ 68 32 ≦ a ≦ 93 0 ≦ b ≦ 200 0 ≦ c ≦ 200 0 ≦ d ≦ 20.

When the content of each component is set in the following range, particularly preferable results can be obtained. 10 ≦ x ≦ 65 35 ≦ a ≦ 900 0 ≦ b ≦ 70 0 ≦ c ≦ 70 ≦ d ≦ 7.

Further, 0 ≦ b <5, 0 ≦ c <5, 0 ≦
It is most preferable if d <5.

In each of the above compositions, when the element represented by MA is at least one of Ag, Al and Cu, it is more preferable that 1 ≦ b + c + d ≦ 20 from the viewpoint of corrosion resistance. It is particularly preferable that 1 ≦ b + c + d ≦ 7.

The distribution of each component in the recording layer 3 may be uniform or may have a concentration gradient in the film thickness direction. For example, Se, Sb, and S are preferably distributed more in the surface layer of the recording layer 3.

The protective layer 4 is made of, for example, AlN, Al ₂ O ₃ ,
It is formed of an inorganic material such as SiN or SiO ₂ or an organic material such as a photocurable resin.

Hereinafter, a method for recording and reproducing information using the optical information recording medium of the above embodiment will be described with reference to FIG.

As shown in FIG. 3, when a recording radiation beam 6 signal-modulated by a predetermined method such as a CD format is focused on the recording layer 3, the light energy is converted into thermal energy by the recording layer 3. The heat changes the atomic arrangement of the recording radiation beam irradiating section 7 of the recording layer 3 and causes the substrate 1 under the section to undergo thermal deformation 8
Then, information is recorded. Therefore, information can be reproduced by optically reading out the change in the atomic arrangement and the change in the reflectance due to the thermal deformation of the substrate 1. The recording of information can be performed on the guide groove, or can be performed on a flat portion between adjacent guide grooves. However, since the heat storage effect is remarkable, the atomic arrangement of the recording layer 3 can be rapidly changed, and large thermal deformation can be caused in the substrate 1, so that recording on the groove is more effective in improving the recording / reproducing characteristics. It is advantageous.

As described above, the optical information recording medium of the first embodiment not only changes the atomic arrangement of the recording layer 3 but also records information by thermally deforming the substrate 1, so that large signal modulation is achieved. You can get the degree.

Next, a second embodiment of the present invention will be described with reference to FIGS. FIG. 4 is a sectional view of a main part of the optical information recording medium according to the present embodiment, and FIG.

As shown in FIG. 4, in the optical information recording medium of the present embodiment, the recording layer 3 is composed of a first thin film 3 mainly composed of a group A element.
a and a second thin film 3b containing a group B element as a main component. Others are the same as those of the first embodiment, and the description is omitted to avoid duplication.

Referring to FIG. 5, a method for recording and reproducing information using the optical information recording medium of the second embodiment will be described.

As shown in FIG. 5, when a recording radiation beam 6 signal-modulated by a predetermined method such as a CD format is focused on the recording layer 3, the light energy is converted into thermal energy by the recording layer 3. The heat causes the first thin film 3a and the second thin film 3b constituting the recording layer 3 to melt and mix with each other. Further, the substrate 1 underlying the recording radiation beam irradiation unit 7 is thermally deformed 8 by the heat, and information is recorded. Therefore, information can be reproduced by optically reading the mixture of the thin films 3a and 3b and the change in the reflectance due to the thermal deformation of the substrate 1.

The optical information recording medium of the second embodiment has the same effect as the optical information recording medium of the first embodiment.

Next, a third embodiment of the present invention will be described with reference to FIG. FIG. 6 is a sectional view of a main part of the optical information recording medium according to the present example.

As shown in FIG. 6, in the optical information recording medium of this embodiment, a heat deformation layer 11 made of a substance having lower heat resistance than the substrate 1 is provided between the substrate 1 and the recording layer 3. . The optical information recording medium of this example is particularly effective when a material having high heat resistance such as glass or a thermosetting resin is used as a substrate material. As a substance forming the heat deformation layer 11, a thermoplastic resin is particularly preferable.

Although the recording layer 3 is shown as a single layer in FIG. 6, the recording layer 3 is formed from a laminate of a plurality of thin films as in the optical information recording medium of the second embodiment. You can also. Others are the same as those of the first and second embodiments, and the description is omitted to avoid duplication.

The optical information recording medium of the third embodiment has the same effects as the optical information recording media of the first and second embodiments.

Next, a fourth embodiment of the present invention will be described with reference to FIG. FIG. 7 is a sectional view of a main part of the optical information recording medium according to the present example.

As shown in FIG. 7, the optical information recording medium of the present example has a light absorbing layer 1 on the back side of the recording layer 3 when viewed from the substrate 1 side.
2 are provided.

Although the recording layer 3 is shown as a single layer in FIG. 7, the recording layer 3 is formed from a laminate of a plurality of thin films as in the optical information recording medium of the second embodiment. You can also. Others are the same as those of the first and second embodiments, and the description is omitted to avoid duplication.

In the optical information recording medium of the fourth embodiment, since the light absorbing layer 12 is provided on the back side of the recording layer 3, the amount of generated heat is large and the recording sensitivity is further improved.

Next, a fifth embodiment of the present invention will be described with reference to FIG. FIG. 8 is a sectional view of a main part of the optical information recording medium according to this example.

As shown in FIG. 8, the optical information recording medium of the present example has a reflective layer 13 on the back side of the recording layer 3 when viewed from the substrate 1 side.
Is provided. As a material for forming the reflective layer 13, a metal material such as Au, Ag, or Al is particularly suitable.

Although the recording layer 3 is shown as a single layer in FIG. 8, the recording layer 3 is formed from a laminate of a plurality of thin films as in the optical information recording medium of the second embodiment. You can also. Others are the same as those of the first and second embodiments, and the description is omitted to avoid duplication.

In the optical information recording medium of the fifth embodiment, since the reflection layer 13 is provided on the back side of the recording layer 3, a multiple interference effect is generated between the recording layer 3 and the reflection layer 13 and higher reflection is obtained. Rate can be obtained.

Next, a sixth embodiment of the present invention will be described with reference to FIG. FIG. 9 is a sectional view of a main part of the optical information recording medium according to the present example.

As shown in FIG. 9, the optical information recording medium of the present example has an intermediate layer 14 on the back side of the recording layer 3 when viewed from the substrate 1 side.
And the reflection layer 13 are sequentially laminated.

As an example of the intermediate layer 14, Ce, La,
Si, In, Al, Ge, Pb, Sn, Bi, Te, T
oxides of at least one element selected from the group consisting of a, Sc, Y, Ti, Zr, V, Nb, Cr, W, Cd, Z
sulfide or selenide of at least one element selected from the group consisting of n, Ga, In, Sb, Ge, Sn, Pb, and Bi; fluorides such as Mg, Ce, and Ca; Si, Al;
It is made of nitrides such as Ta and B, carbides such as B and Si, borides such as Ti, boron, and carbon. For example, the main components are CeO ₂ , La ₂ O ₃ , SiO, and Si.
O ₂ , In ₂ O ₃ , Al ₂ O ₃ , GeO, GeO ₂ , P
bO, SnO, SnO ₂ , Bi ₂ O ₃ , TeO ₂ , Ta
₂ O ₅ , Sc ₂ O ₃ , Y ₂ O ₃ , TiO ₂ , ZrO ₂ ,
V ₂ O ₅ , Nb ₂ O ₅ , Cr ₂ O ₃ , WO ₂ , WO ₃ ,
CdS, ZnS, CdSe, ZnSe, In ₂ S ₃ , I
n ₂ Se ₃ , Sb ₂ S ₃ , Sb ₂ Se ₃ , Ga ₂ S ₃ ,
Ga ₂ Se ₃ , GeS, GeSe, GeSe ₂ , Sn
S, SnS ₂ , SnSe, SnSe ₂ , PbS, PbS
e, Bi ₂ Se ₃ , Bi ₂ S ₃ , MgF ₂ , CeF ₃ ,
CaF ₂ , TaN, Si ₃ N ₄ , AlN, BN, Si,
TiB ₂ , B ₄ C, SiC, B and C having a composition close to one of them, and a mixture thereof.

Of these, sulfides are close to ZnS
Are preferred because the refractive index is appropriate and the film is stable.
Good. With nitride, the surface reflectance is not very high,
Is stable and strong, so that TaN, Si₃N₄, Al
N (aluminum nitride) or AlSiN₂Pair close to
Those which are formed are preferred. In oxides, Y₂O₃, Sc₂O
₃, CeO₂, TiO₂, ZrO₂, SiO, Ta₂O
₅, In₂O₃, Al ₂O₃, SnO₂, SiO₂Close to
A composition having a low composition is preferred. Amorphous containing hydrogen of Si is also good.
Good. As a material for forming the reflective layer 13,
As in the fifth embodiment, metals such as Au, Ag, and Al
Materials are used.

Although the recording layer 3 is shown as a single layer in FIG. 9, the recording layer 3 is formed from a laminate of a plurality of thin films as in the optical information recording medium of the second embodiment. You can also. Others are the same as those of the first and second embodiments, and the description is omitted to avoid duplication.

In the optical information recording medium of the sixth embodiment, since the intermediate layer 14 and the reflective layer 13 are provided on the back side of the recording layer 3, the multiple interference effect can be further enhanced and a higher reflectivity can be obtained. it can. Further, the heat generated in the recording layer 3 can be suppressed by the intermediate layer 14 which diffuses to the reflective layer 13,
Higher recording sensitivity can be obtained.

In the optical information recording medium of the first embodiment, the recording layer 3 mainly records information by utilizing the change between the amorphous phase and the crystalline phase by the action of light and heat. However, it is not always necessary to use the change between the amorphous state and the crystalline state for recording, and the change in optical properties may be caused by any change in the atomic arrangement. For example, a change in crystal grain size or crystal form may be used. Regarding the change between the amorphous state and the crystalline state, the amorphous state is not completely amorphous, and a crystalline portion may be mixed. Also,
When the recording layer has a multi-layer structure, the recording may be performed by part of atoms forming each layer moving (diffusion, chemical reaction, or the like), or by both movement and phase change.

Hereinafter, more specific experimental examples will be described to clarify the effects of the present invention.

<Experimental Example 1> Diameter 12 cm, thickness 1.2 m
m polycarbonate substrate having a plurality of targets, and having a uniform thickness and a good reproducibility in a magnetron sputtering apparatus, a thin film of Au ₇₀ Ge ₃₀ having a thickness of about 80 nm as a recording layer was formed on the substrate. Then, a protective layer made of a UV-curable resin is formed on the thin film for 100 minutes.
It was spin-coated to a thickness of μm.

Using the disk created as described above,
Recording and reproduction of information were performed under the following conditions. First, the linear velocity of the disk was set to 1.2 m / s, and the semiconductor laser (wavelength 78
0 nm) was kept at a level (about 1 mW) at which recording was not performed. This light was condensed by a lens in the recording head, irradiated to the recording layer through the substrate, and the reflected light was detected, whereby the recording head was driven so that the center of the light spot coincided with the guide groove for tracking. While tracking was performed in this manner, automatic focusing was performed so that the recording layer was further focused, and pits were formed by irradiating a laser beam. Subsequently, while performing tracking and automatic focusing in the same manner as during recording, the intensity of reflected light was detected with the recorded low-power semiconductor laser light to reproduce information. In this experimental example, when the reproducing light power was 1 mW, a signal intensity of about 1.3 V was obtained. This is almost the same level as a commercially available CD. Also, the recording power is 7 m
When the signal was set to W and a signal (11T signal) having a frequency of 196 KHz was recorded, a signal modulation degree of about 70% was obtained.

A small piece including a track on which recording was performed by the above method was cut out from the disk, and the piece was immersed in tetrahydrofuran to dissolve the polycarbonate, and only the recording layer was taken out. As a result of observing this with a transmission electron microscope,
The unrecorded part was in a crystalline state, and the recorded part was in an amorphous state. Further, only the recording layer was removed from the small piece including the recorded track, and observed by a scanning electron microscope. As a result, deformation of the substrate at the recording portion was confirmed. As described above, one of the features of the present invention is that recording is performed by causing both the change in the atomic arrangement of the recording layer and the deformation of the substrate to obtain a large signal modulation degree.

When recording was performed between adjacent grooves by the same method as that performed on the guide grooves, very similar characteristics were obtained. However, the signal modulation degree was slightly smaller than that on the groove recording.

The medium of this experimental example was also excellent in environmental resistance, and the reflectance and the transmittance hardly changed even after being placed in an environment at a temperature of 80 ° C. and a relative humidity of 90% for 1,000 hours.

It should be noted that a part or all of Au is substituted to form A
Similar characteristics were obtained even when at least one element of g, Cu, and Al was added. Similar characteristics were obtained even when part or all of Ge was substituted and at least one element of Si and Sn was added.

In the above optical information recording medium, when a reflective layer was provided on the back side of the recording layer when viewed from the substrate side, the reproduced output signal was improved. When an intermediate layer was provided between the recording layer and the reflective layer, the recording sensitivity was improved. As the intermediate layer, CeO ₂ , La ₂ O ₃ , SiO, SiO ₂ , In
₂ O ₃ , Al ₂ O ₃ , GeO, GeO ₂ , PbO, Sn
O, SnO ₂ , Bi ₂ O ₃ , TeO ₂ , Ta ₂ O ₅ , S
c ₂ O ₃ , Y ₂ O ₃ , TiO ₂ , ZrO ₂ , V ₂ O ₅ ,
Nb ₂ O ₅ , Cr ₂ O ₃ , WO ₂ , WO ₃ , CdS, Z
nS, CdSe, ZnSe, In ₂ S ₃ , In ₂ S
e ₃ , Sb ₂ S ₃ , Sb ₂ Se ₃ , Ga ₂ S ₃ , Ga ₂
Se ₃ , GeS, GeSe, GeSe ₂ , SnS, Sn
S ₂ , SnSe, SnSe ₂ , PbS, PbSe, Bi
₂ Se ₃ , Bi ₂ S ₃ , MgF ₂ , CeF ₃ , Ca
F ₂ , TaN, Si ₃ N ₄ , AlN, BN, Si, Ti
When a material having a composition close to one of B ₂ , B ₄ C, SiC, B, and C and a mixture thereof are used,
Especially effective.

Further, substantially the same results as described above were obtained also when a polyolefin, epoxy, or acrylic resin having a signal pattern such as a guide groove formed directly on the surface thereof was used instead of polycarbonate as the substrate.

<Experimental Example 2> A number of the same polycarbonate substrates as in Experimental Example 1 were prepared, and a Si—Au-based recording layer having a different Si content was formed on each substrate in the same manner as in Experimental Example 1. Various disks having different Si contents in the recording layers were produced. However, each disk had a recording layer thickness of about 60 nm, and a protective layer made of an ultraviolet curable resin was spin-coated on the recording layer to a thickness of 100 μm.

The changes in the intensity of the reproduction output signal and the changes in the laser power required for recording when the content of Si in the recording layer is variously changed are shown below. The recording / reproducing conditions and the recording / reproducing method are the same as those described in Experimental Example 1 above.

Also, a number of polycarbonate substrates were prepared in the same manner as in Experimental Example 1, and the relative ratio between Si and Au was fixed at 25:75 for each substrate in the same manner as in Experimental Example 1; Si-Au-B-based recording layers having different contents were formed, and various disks having different B contents in the recording layers were produced. However, the recording layer thickness of each disc was about 6
On the recording layer, a protective layer made of an ultraviolet curable resin was spin-coated to a thickness of 100 μm.

The change in the intensity of the reproduced output signal and the change in the noise level when the B content in the recording layer is variously changed are shown below. The recording / reproducing conditions and the recording / reproducing method are the same as those described in Experimental Example 1 above.

A part or all of Au is substituted to form A
Similar characteristics were obtained even when at least one element of g, Cu, and Al was added. Similar characteristics were obtained even when part or all of B was substituted and at least one element of C and P was added. The same effect was obtained by adding at least one element of Se, Te, and S instead of B. Further, when the element represented by MD was added, the recording sensitivity was slightly improved.

Otherwise, the same results as in Experimental Example 1 were obtained.

In each of the above embodiments, the signal pattern 5 is formed over substantially the entire area of the substrate 1 so that information can be additionally recorded. However, as shown in FIG. The ROM area 21 is divided into an area 21 and a write-once area 22. ROM information is recorded in the form of pre-pits conforming to the CD format, and the above-mentioned signal pattern is formed on the write-once area 22 so that information can be additionally written. You can also.

In each of the above embodiments, a so-called write-once CD has been described as an example. However, the present invention can be applied to a disc which can record a video disc signal and can be reproduced by a video disc player.

[0075]

As described above, the optical information recording medium of the present invention is made of an alloy containing Au and at least one element selected from the [Ge, Si, Sn] element group as a main component. Since the recording layer in which the Au content is adjusted to 70 atomic% is formed directly on the signal surface of the substrate, the reflectivity is high, the signal modulation is large, and the oxidation resistance is excellent. Accordingly, it is possible to provide an optical information recording medium that enables information to be additionally recorded, allows information to be reproduced by a CD player or a video laser disk player, and has excellent environmental resistance.

The information recording / reproducing method of the present invention comprises:
An alloy mainly composed of at least one element selected from the [Ge, Si, Sn] element group and Au;
Using a phase-change optical information recording medium in which a recording layer whose u content is adjusted to 70 atomic% is formed directly on the signal surface of the substrate, the atomic arrangement of the recording layer is changed, and the substrate is thermally deformed. Therefore, the difference between the reflectances of the recording portion and the non-recording portion is large, and a large reproduction output signal can be obtained.

[Brief description of the drawings]

FIG. 1 is a sectional view of a main part of an optical information recording medium according to a first embodiment.

FIG. 2 is a plan view of the optical information recording medium according to the first embodiment.

FIG. 3 is an explanatory diagram of a recording / reproducing principle of the optical information recording medium according to the first embodiment.

FIG. 4 is a sectional view of a main part of an optical information recording medium according to a second embodiment.

FIG. 5 is an explanatory diagram of a recording / reproducing principle of an optical information recording medium according to a second embodiment.

FIG. 6 is a sectional view of a main part of an optical information recording medium according to a third embodiment.

FIG. 7 is a sectional view of a main part of an optical information recording medium according to a fourth embodiment.

FIG. 8 is a sectional view of a main part of an optical information recording medium according to a fifth embodiment.

FIG. 9 is a sectional view of a main part of an optical information recording medium according to a sixth embodiment.

FIG. 10 is a plan view of an optical information recording medium according to another embodiment.

[Explanation of symbols]

 DESCRIPTION OF SYMBOLS 1 Substrate 2 Signal surface 3 Recording layer 3a 1st thin film 3b 2nd thin film 4 Protective layer 11 Thermal deformation layer 12 Light absorption layer 13 Reflection layer 14 Intermediate layer

Claims (3)

[Claims] 1. An optical information recording medium having a signal surface of a substrate carrying a thin film including at least a recording layer on the signal surface of the substrate, wherein the signal surface of the substrate has at least one type selected from the group consisting of [Ge, Si, Sn] elements. Is directly formed, and the recording layer is formed by adjusting the content of Au to 70 atomic%. When the recording layer is irradiated with a recording radiation beam, the recording layer is An optical information recording medium, wherein an atomic arrangement is changed in the recording radiation beam irradiation unit, and information is recorded by deforming the substrate which is the base of the recording radiation beam irradiation unit. 2. The optical information recording medium according to claim 1, wherein a reflectance of light having a wavelength of 780 nm is 70% or more. 3. The method according to claim 1, wherein [Ge, Si, Sn] is provided on the signal surface of the substrate.
Using an optical information recording medium directly formed with a recording layer made of an alloy containing at least one element selected from the group of elements and Au as main components and having a content of Au adjusted to 70 at%, At the time of recording, the recording layer is irradiated with a recording radiation beam, and the heat causes a change in the atomic arrangement in the recording radiation beam irradiation section of the recording layer, and the base layer of the recording radiation beam irradiation section. The substrate is deformed, and at the time of reproducing information, a reproducing radiation beam is irradiated along the information recording portion, and the change in the atomic arrangement generated in the recording layer and the change in the reflectance accompanying the deformation generated in the substrate. A method for recording / reproducing information, characterized by reading out information optically.