JP2000513044A

JP2000513044A - カリウムイオンを含む中鎖分岐界面活性剤

カリウムイオンを含む中鎖分岐界面活性剤

Info

Publication number: JP2000513044A
Authority: JP; Japan
Prior art keywords: integer; sulfate; alkyl; surfactant; potassium
Prior art date: 1997-10-10
Legal status : Pending

Application number

JP11500624A

Other languages

English (en)

Japanese (ja)

Inventor

倫子勝田

Current Assignee

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date

1997-10-10

Filing date

1997-10-10

Publication date

2000-10-03

1997-10-10 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

2000-10-03 Publication of JP2000513044A publication Critical patent/JP2000513044A/ja

Status Pending legal-status Critical Current

Links

239000004094 surface-active agent Substances 0.000 title claims abstract description 283
229910001414 potassium ion Inorganic materials 0.000 title claims abstract description 22
NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 title claims description 10
239000000203 mixture Substances 0.000 claims abstract description 402
239000003599 detergent Substances 0.000 claims abstract description 175
125000000217 alkyl group Chemical group 0.000 claims abstract description 172
-1 polyoxyethylene Polymers 0.000 claims description 237
QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 105
150000001875 compounds Chemical class 0.000 claims description 67
229910052799 carbon Inorganic materials 0.000 claims description 66
239000001257 hydrogen Substances 0.000 claims description 63
229910052739 hydrogen Inorganic materials 0.000 claims description 63
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 58
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 55
239000002609 medium Chemical group 0.000 claims description 49
239000000126 substance Substances 0.000 claims description 46
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 44
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 44
239000002253 acid Substances 0.000 claims description 44
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 41
239000003795 chemical substances by application Substances 0.000 claims description 36
239000003112 inhibitor Substances 0.000 claims description 32
235000014113 dietary fatty acids Nutrition 0.000 claims description 28
239000000194 fatty acid Substances 0.000 claims description 28
229930195729 fatty acid Natural products 0.000 claims description 28
239000006260 foam Substances 0.000 claims description 28
229910052700 potassium Inorganic materials 0.000 claims description 27
150000001412 amines Chemical group 0.000 claims description 26
150000002148 esters Chemical class 0.000 claims description 26
239000011591 potassium Substances 0.000 claims description 26
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 25
230000002209 hydrophobic effect Effects 0.000 claims description 22
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 21
239000012190 activator Substances 0.000 claims description 21
150000004665 fatty acids Chemical class 0.000 claims description 21
150000001298 alcohols Chemical class 0.000 claims description 19
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical group [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 19
150000002431 hydrogen Chemical class 0.000 claims description 18
235000019832 sodium triphosphate Nutrition 0.000 claims description 17
235000011187 glycerol Nutrition 0.000 claims description 16
229920001451 polypropylene glycol Polymers 0.000 claims description 14
229910019142 PO4 Inorganic materials 0.000 claims description 12
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 12
159000000001 potassium salts Chemical class 0.000 claims description 12
125000003545 alkoxy group Chemical group 0.000 claims description 11
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 11
150000007942 carboxylates Chemical class 0.000 claims description 10
159000000000 sodium salts Chemical class 0.000 claims description 9
CNDWHJQEGZZDTQ-UHFFFAOYSA-N 2-(2-amino-2-oxoethoxy)acetamide Chemical compound NC(=O)COCC(N)=O CNDWHJQEGZZDTQ-UHFFFAOYSA-N 0.000 claims description 8
125000005907 alkyl ester group Chemical group 0.000 claims description 8
229920000223 polyglycerol Polymers 0.000 claims description 8
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical group [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 8
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
229920000388 Polyphosphate Polymers 0.000 claims description 7
239000001205 polyphosphate Substances 0.000 claims description 7
235000011176 polyphosphates Nutrition 0.000 claims description 7
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
239000003513 alkali Substances 0.000 claims description 6
SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 6
239000010452 phosphate Substances 0.000 claims description 6
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 6
RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 claims description 5
RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims description 5
MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 5
150000002500 ions Chemical group 0.000 claims description 5
239000002689 soil Substances 0.000 claims description 5
150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
150000001408 amides Chemical class 0.000 claims description 4
229910000027 potassium carbonate Inorganic materials 0.000 claims description 4
235000019353 potassium silicate Nutrition 0.000 claims description 4
230000001568 sexual effect Effects 0.000 claims description 4
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 3
239000004111 Potassium silicate Chemical group 0.000 claims description 3
150000004996 alkyl benzenes Chemical class 0.000 claims description 3
239000004519 grease Substances 0.000 claims description 3
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical group [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 3
229910052913 potassium silicate Inorganic materials 0.000 claims description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 2
238000005260 corrosion Methods 0.000 claims description 2
230000007797 corrosion Effects 0.000 claims description 2
KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical compound [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 claims description 2
CQAIPTBBCVQRMD-UHFFFAOYSA-L dipotassium;phosphono phosphate Chemical compound [K+].[K+].OP(O)(=O)OP([O-])([O-])=O CQAIPTBBCVQRMD-UHFFFAOYSA-L 0.000 claims description 2
229920000620 organic polymer Polymers 0.000 claims description 2
239000001103 potassium chloride Substances 0.000 claims description 2
235000011164 potassium chloride Nutrition 0.000 claims description 2
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
235000011151 potassium sulphates Nutrition 0.000 claims description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims 4
229940071089 sarcosinate Drugs 0.000 claims 3
ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 claims 3
239000004471 Glycine Substances 0.000 claims 2
APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 claims 2
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims 1
VKELSQNRSVJHGR-UHFFFAOYSA-N 4-oxo-4-sulfooxybutanoic acid Chemical compound OC(=O)CCC(=O)OS(O)(=O)=O VKELSQNRSVJHGR-UHFFFAOYSA-N 0.000 claims 1
229940126062 Compound A Drugs 0.000 claims 1
NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims 1
229910000402 monopotassium phosphate Inorganic materials 0.000 claims 1
235000019796 monopotassium phosphate Nutrition 0.000 claims 1
HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 claims 1
GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical compound [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 claims 1
LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims 1
239000010458 rotten stone Substances 0.000 claims 1
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims 1
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims 1
238000004140 cleaning Methods 0.000 abstract description 33
125000001165 hydrophobic group Chemical group 0.000 abstract description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 90
150000008051 alkyl sulfates Chemical class 0.000 description 79
125000004432 carbon atom Chemical group C* 0.000 description 71
239000000047 product Substances 0.000 description 66
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 65
238000005406 washing Methods 0.000 description 65
239000011734 sodium Substances 0.000 description 54
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 54
102000004190 Enzymes Human genes 0.000 description 52
108090000790 Enzymes Proteins 0.000 description 52
229940088598 enzyme Drugs 0.000 description 52
238000000034 method Methods 0.000 description 50
229910052757 nitrogen Inorganic materials 0.000 description 46
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 45
239000007844 bleaching agent Substances 0.000 description 41
239000000463 material Substances 0.000 description 41
150000003839 salts Chemical class 0.000 description 39
229910052708 sodium Inorganic materials 0.000 description 39
150000003467 sulfuric acid derivatives Chemical class 0.000 description 38
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 34
238000006243 chemical reaction Methods 0.000 description 33
230000000694 effects Effects 0.000 description 33
239000003054 catalyst Substances 0.000 description 31
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 30
108010065511 Amylases Proteins 0.000 description 27
102000013142 Amylases Human genes 0.000 description 27
150000001768 cations Chemical class 0.000 description 26
239000004744 fabric Substances 0.000 description 26
238000004519 manufacturing process Methods 0.000 description 26
235000019418 amylase Nutrition 0.000 description 24
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 24
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 23
229920001223 polyethylene glycol Polymers 0.000 description 23
150000001336 alkenes Chemical class 0.000 description 21
239000004382 Amylase Substances 0.000 description 20
108091005804 Peptidases Proteins 0.000 description 20
239000002202 Polyethylene glycol Substances 0.000 description 20
229920000642 polymer Polymers 0.000 description 20
125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 19
239000000243 solution Substances 0.000 description 19
239000003921 oil Substances 0.000 description 18
239000002245 particle Substances 0.000 description 18
239000004365 Protease Substances 0.000 description 17
230000015572 biosynthetic process Effects 0.000 description 17
238000005187 foaming Methods 0.000 description 17
235000019198 oils Nutrition 0.000 description 17
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 16
230000019635 sulfation Effects 0.000 description 16
238000005670 sulfation reaction Methods 0.000 description 16
238000004061 bleaching Methods 0.000 description 15
239000011575 calcium Substances 0.000 description 15
239000011541 reaction mixture Substances 0.000 description 15
108090001060 Lipase Proteins 0.000 description 14
102000004882 Lipase Human genes 0.000 description 14
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 14
WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 14
239000007859 condensation product Substances 0.000 description 14
239000000975 dye Substances 0.000 description 14
238000007046 ethoxylation reaction Methods 0.000 description 14
239000002736 nonionic surfactant Substances 0.000 description 14
230000008569 process Effects 0.000 description 14
239000010457 zeolite Substances 0.000 description 14
125000003342 alkenyl group Chemical group 0.000 description 13
229920001577 copolymer Polymers 0.000 description 13
229920005646 polycarboxylate Polymers 0.000 description 13
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 13
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 12
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 12
239000004367 Lipase Substances 0.000 description 12
150000007513 acids Chemical class 0.000 description 12
125000000129 anionic group Chemical group 0.000 description 12
239000008187 granular material Substances 0.000 description 12
235000019421 lipase Nutrition 0.000 description 12
239000000178 monomer Substances 0.000 description 12
102000035195 Peptidases Human genes 0.000 description 11
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
150000003863 ammonium salts Chemical class 0.000 description 11
125000002091 cationic group Chemical group 0.000 description 11
239000000460 chlorine Substances 0.000 description 11
238000003756 stirring Methods 0.000 description 11
229910021653 sulphate ion Inorganic materials 0.000 description 11
238000012546 transfer Methods 0.000 description 11
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 10
229920002323 Silicone foam Polymers 0.000 description 10
229910021536 Zeolite Inorganic materials 0.000 description 10
229910052783 alkali metal Inorganic materials 0.000 description 10
150000001721 carbon Chemical group 0.000 description 10
239000002738 chelating agent Substances 0.000 description 10
229910052801 chlorine Inorganic materials 0.000 description 10
239000007789 gas Substances 0.000 description 10
239000012071 phase Substances 0.000 description 10
235000021317 phosphate Nutrition 0.000 description 10
238000002360 preparation method Methods 0.000 description 10
239000013514 silicone foam Substances 0.000 description 10
238000003786 synthesis reaction Methods 0.000 description 10
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 9
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 9
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 9
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 9
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 9
150000001450 anions Chemical class 0.000 description 9
125000003118 aryl group Chemical group 0.000 description 9
229910017052 cobalt Inorganic materials 0.000 description 9
239000010941 cobalt Substances 0.000 description 9
WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 9
239000002270 dispersing agent Substances 0.000 description 9
239000000706 filtrate Substances 0.000 description 9
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 9
230000003287 optical effect Effects 0.000 description 9
150000003138 primary alcohols Chemical class 0.000 description 9
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 9
239000007787 solid Substances 0.000 description 9
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
125000001931 aliphatic group Chemical group 0.000 description 8
108090000637 alpha-Amylases Proteins 0.000 description 8
102000004139 alpha-Amylases Human genes 0.000 description 8
239000008346 aqueous phase Substances 0.000 description 8
239000004927 clay Substances 0.000 description 8
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 8
238000004851 dishwashing Methods 0.000 description 8
239000003925 fat Substances 0.000 description 8
238000009472 formulation Methods 0.000 description 8
229930195733 hydrocarbon Natural products 0.000 description 8
150000002430 hydrocarbons Chemical class 0.000 description 8
238000005984 hydrogenation reaction Methods 0.000 description 8
239000004615 ingredient Substances 0.000 description 8
238000006384 oligomerization reaction Methods 0.000 description 8
229910052760 oxygen Inorganic materials 0.000 description 8
229920001296 polysiloxane Polymers 0.000 description 8
239000000843 powder Substances 0.000 description 8
239000002244 precipitate Substances 0.000 description 8
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 8
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 8
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 7
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 7
102000003992 Peroxidases Human genes 0.000 description 7
KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 7
229940024171 alpha-amylase Drugs 0.000 description 7
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
229960001760 dimethyl sulfoxide Drugs 0.000 description 7
VFNGKCDDZUSWLR-UHFFFAOYSA-N disulfuric acid Chemical compound OS(=O)(=O)OS(O)(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-N 0.000 description 7
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
235000019197 fats Nutrition 0.000 description 7
239000003205 fragrance Substances 0.000 description 7
230000006870 function Effects 0.000 description 7
125000002768 hydroxyalkyl group Chemical group 0.000 description 7
239000007788 liquid Substances 0.000 description 7
229910052744 lithium Inorganic materials 0.000 description 7
239000011777 magnesium Substances 0.000 description 7
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 7
229910052751 metal Inorganic materials 0.000 description 7
239000002184 metal Substances 0.000 description 7
239000001301 oxygen Substances 0.000 description 7
239000012188 paraffin wax Substances 0.000 description 7
229920000728 polyester Polymers 0.000 description 7
239000011347 resin Substances 0.000 description 7
229920005989 resin Polymers 0.000 description 7
150000004760 silicates Chemical class 0.000 description 7
239000000344 soap Substances 0.000 description 7
239000000758 substrate Substances 0.000 description 7
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