JP2000355828A - Minutely shrinkable polyester filament yarn and its production - Google Patents

Minutely shrinkable polyester filament yarn and its production

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Publication number
JP2000355828A
JP2000355828A JP11164986A JP16498699A JP2000355828A JP 2000355828 A JP2000355828 A JP 2000355828A JP 11164986 A JP11164986 A JP 11164986A JP 16498699 A JP16498699 A JP 16498699A JP 2000355828 A JP2000355828 A JP 2000355828A
Authority
JP
Japan
Prior art keywords
yarn
filament yarn
polyester filament
winding
shrinkage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11164986A
Other languages
Japanese (ja)
Other versions
JP3815120B2 (en
Inventor
Tatsuaki Matsuda
竜明 松田
Yoshiaki Sato
慶明 佐藤
Takashi Ochi
隆志 越智
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
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Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP16498699A priority Critical patent/JP3815120B2/en
Publication of JP2000355828A publication Critical patent/JP2000355828A/en
Application granted granted Critical
Publication of JP3815120B2 publication Critical patent/JP3815120B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To obtain the subject filament yarn satisfying specific physical properties and capable of giving woven/knitted fabrics with good puffiness, softness and resilience when blended filament yarns are produced using the yarn as a constituent, by treating an undrawn polyester filament yarn or the like at each specific draw ratio, draw temperature and heat-setting temperature. SOLUTION: This filament yarn is obtained by drawing and heat-setting an undrawn or semi-oriented polyester filament yarn at a draw ratio of 1.05-1.20, at a draw temperature of 90-110 deg.C and at a heat-setting temperature of 110-140 deg.C using a drawing machine having at least one pair of hot roller systems. This filament yarn thus obtained simultaneously satisfies the following characteristics: (A) elastic recovery percentage of elongation at 3% elongation is 60-8.5%, (B) boiling water shrinkage is 0-3%, and (C) dry heat shrinkage is equal to or lower than the boiling water shrinkage.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、伸長弾性率、及び
沸騰水収縮率が低いポリエステルフィラメント糸及びそ
の製造方法に関する。更に詳しくは、混繊糸とした際に
ふくらみ、ソフト感、反発感に優れた織編物を提供でき
る微収縮性ポリエステルフィラメント糸に関するもので
ある。
The present invention relates to a polyester filament yarn having a low elongation modulus and a low boiling water shrinkage ratio, and a method for producing the same. More specifically, the present invention relates to a finely shrinkable polyester filament yarn capable of providing a woven or knitted fabric excellent in swelling, softness and resilience when used as a mixed fiber.

【0002】[0002]

【従来の技術】ポリエステルフィラメント糸は、機械的
特性をはじめ様々な優れた特性から一般衣料用分野をは
じめ各種分野に広く利用されている。衣料用途では天然
繊維をターゲットとして品質の改良が行われてきている
が、特にふくらみ、ソフト感のある風合いを得るために
様々な検討が行われている。その手段のひとつとして、
熱による収縮特性の異なる繊維を混繊する収縮差混繊糸
が広く用いられている。このタイプの収縮差混繊糸を用
いれば織物組織の密度が増加しても十分な糸長差を染色
加工後に得ることができ、ふくらみ、ソフト感に優れた
布帛を得ることができる。この収縮差混繊糸の低収縮側
の糸として、沸騰水収縮率が極めて低い繊維(以下、微
収縮糸と称す)や熱処理時に熱処理前の糸に対して伸長
性を示す自発伸長糸が使用され、布帛のふくらみ、ソフ
ト感を引き出している。これら微収縮糸や自発伸長糸は
従来のポリエステルフィラメント糸に比べ、伸長弾性率
が低いという特徴を有する。
2. Description of the Related Art Polyester filament yarns are widely used in various fields including general garments because of their excellent properties including mechanical properties. In the use of clothing, the quality has been improved by using natural fibers as a target, but various studies have been made to obtain a swelling and soft texture. As one of the means,
Different shrinkage mixed yarns for mixing fibers having different shrinkage characteristics due to heat are widely used. If this type of shrinkage-differentiated yarn is used, a sufficient yarn length difference can be obtained after the dyeing process even if the density of the woven fabric increases, and a fabric excellent in swelling and softness can be obtained. As the yarn on the low shrinkage side of this shrinkage difference mixed yarn, a fiber having an extremely low boiling water shrinkage (hereinafter referred to as a fine shrinkage yarn) or a spontaneously elongated yarn showing extensibility with respect to the yarn before heat treatment during heat treatment is used. The swelling and softness of the fabric is brought out. These finely shrinkable yarns and spontaneously elongated yarns are characterized by having a lower elongation modulus than conventional polyester filament yarns.

【0003】自発伸長糸の製造方法は、例えば、特開平
4-352836号公報にはポリエステル部分配向糸(以下PO
Yと略す)を一旦延伸した後弛緩熱処理する方法、特開
平2-293410号公報にはPOYを弛緩熱処理する方法等が
開示されており、弛緩熱処理工程を要するのが一般的で
ある。また、特開平9-228167号公報や特開平9-21060号
公報には、POYの定長(緊張)熱処理による方法が開
示されている。しかしながら、これらの方法では、20
〜50%の弛緩熱処理が必要となるため工程安定性が悪
く、糸斑や染め斑の発生等品質面に問題があった。ま
た、加工速度が遅く、熱処理加工の際の巻き上げ、ドッ
フ後の加工再スタート成功率も低いため生産性が低く、
更に弛緩熱処理可能な特別な糸加工機が必要であり、生
産コストが高くなっていた。このため、特開平9-273043
号公報にはPOYを低張力で熱板を用いて接触熱処理す
ることにより低収縮糸を得る方法が提案されており、ド
ラム形状に巻き取る製造工程図が開示されている。しか
しながら、収縮率を十分低下させるためには熱処理時の
糸張力を0.12g/d以下まで低くする必要があり、
熱板での接触熱処理では走行糸条と熱板との擦過抵抗に
より糸走行が安定しないため、糸斑が大きくなり、ひい
ては断糸に至るといった問題があった。また、ドラム形
状に巻き取るという点で本発明の巻き取り方法とは異な
るものである。さらに、これら低収縮糸は伸長弾性率が
低いため、従来の延伸工程で用いられている巻き取り方
法では、巻取張力の変化により、パーン内での品質変化
やパーンでの糸ずれ、崩れの発生、高次工程での解舒不
良といった問題がある。従って、従来技術では品質面で
の不安定さやコスト高により、微収縮性ポリエステルフ
ィラメント糸を得ることが困難であるのが実状である。
A method for producing a spontaneously elongated yarn is described in, for example,
No. 4-352836 discloses a polyester partially oriented yarn (hereinafter referred to as PO).
Y (abbreviated as Y) and a relaxation heat treatment are disclosed in Japanese Patent Application Laid-Open No. 2-93410, and a relaxation heat treatment step is generally required. Further, Japanese Patent Application Laid-Open Nos. 9-228167 and 9-21060 disclose a method using a fixed-length (tensile) heat treatment of POY. However, in these methods, 20
Since a relaxation heat treatment of about 50% is required, process stability is poor, and there is a problem in quality, such as generation of thread spots and dye spots. In addition, the processing speed is slow, the winding during heat treatment, the success rate of processing restart after doff is low, so productivity is low,
Further, a special yarn processing machine capable of relaxation heat treatment was required, and the production cost was high. For this reason, Japanese Patent Application Laid-Open No. 9-273043
Japanese Patent Application Laid-Open Publication No. H11-163,199 proposes a method of obtaining low shrinkage yarn by subjecting POY to contact heat treatment using a hot plate with a low tension, and discloses a manufacturing process diagram of winding the same into a drum shape. However, in order to sufficiently reduce the shrinkage, it is necessary to reduce the yarn tension during heat treatment to 0.12 g / d or less.
In the contact heat treatment using a hot plate, the running of the yarn is not stable due to the abrasion resistance between the running yarn and the hot plate, so that there has been a problem that the yarn spots become large and eventually the yarn breaks. Further, the present invention is different from the winding method of the present invention in that it is wound into a drum shape. Furthermore, since these low shrinkage yarns have a low elongation modulus, the winding method used in the conventional drawing process may cause a change in the quality of the yarn inside the pirn, yarn displacement or breakage due to the change in the winding tension. There are problems such as generation and poor unwinding in higher-order processes. Therefore, in the prior art, it is difficult to obtain a finely shrinkable polyester filament yarn due to instability in quality and high cost.

【0004】[0004]

【発明が解決しようとする課題】本発明は、伸長弾性
率、及び沸騰水収縮率が低いポリエステルフィラメント
糸を弛緩熱処理、定長熱処理で製造する際に発生する様
々な問題を解決し、パッケージの崩れや高次工程での解
舒不良を起こすことなく、糸切れ等の発生しない安定し
た生産性で、かつ混繊糸とした際にふくらみ、ソフト
感、反発感に優れ、繊細なピーチタッチを有する織編物
を提供できる高品位の微収縮性ポリエステルフィラメン
ト糸を得ることを課題とする。
SUMMARY OF THE INVENTION The present invention solves various problems that occur when a polyester filament yarn having a low elongation modulus and a low boiling water shrinkage ratio is produced by relaxation heat treatment and constant-length heat treatment. It does not cause breakage or poor unwinding in high-order processes, has stable productivity with no yarn breakage, and has excellent swelling, softness and resilience when used as a mixed fiber, providing delicate peach touch. An object of the present invention is to obtain a high-quality finely shrinkable polyester filament yarn capable of providing a woven or knitted fabric having the same.

【0005】[0005]

【課題を解決するための手段】前記した課題は、以下の
特性を同時に満足することを特徴とする微収縮性ポリエ
ステルフィラメント糸によって達成できる。
The above object can be achieved by a micro-shrinkable polyester filament yarn characterized by simultaneously satisfying the following characteristics.

【0006】A.3%伸長時の伸長弾性率が60%以上
85%以下。
A. Elongation modulus at 3% elongation is 60% or more and 85% or less.

【0007】B.沸騰水収縮率が0%以上3%以下。B. Boiling water shrinkage is 0% or more and 3% or less.

【0008】C.乾熱収縮率が沸騰水収縮率と等しい
か、または沸騰水収縮率以下。
C. The dry heat shrinkage is equal to or less than the boiling water shrinkage.

【0009】[0009]

【発明の実施の形態】以下、本発明を詳細に説明する。
本発明でいう微収縮性ポリエステルフィラメント糸とは
ポリエチレンテレフタレート(以下PETと略す)、ポ
リプロピレンテレフタレート、ポリブチレンテレフタレ
ート等が原料として用いられるが、PETが最も汎用的
であり好ましい。また、ジオール成分および酸成分の一
部が各々15mol%以下の範囲で他の共重合可能な成
分で置換されたものであってもよい。ただし、ポリエチ
レングリコールの場合は10重量%以下が好ましい。ま
た、これらは他のポリマや、艶消剤、難燃剤、帯電防止
剤、顔料などの添加物を含有していてもよい。以下PE
Tを原料とした微収縮性ポリエステルフィラメント糸の
製造方法を説明する。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.
As the finely shrinkable polyester filament yarn referred to in the present invention, polyethylene terephthalate (hereinafter abbreviated as PET), polypropylene terephthalate, polybutylene terephthalate, or the like is used as a raw material, but PET is the most general and preferred. Further, a part of the diol component and a part of the acid component may be substituted with another copolymerizable component in a range of 15 mol% or less. However, in the case of polyethylene glycol, the content is preferably 10% by weight or less. They may also contain other polymers and additives such as matting agents, flame retardants, antistatic agents, pigments and the like. Below PE
A method for producing a slightly shrinkable polyester filament yarn using T as a raw material will be described.

【0010】本発明で得られるポリエステルフィラメン
ト糸の3%伸長時の伸長弾性率は、60〜85%である
ことが必須である。図1は、伸長弾性率測定での荷重−
伸長曲線の一例である。伸長弾性率は、伸長後の残留伸
びが大きい程、低くなる。つまり、低伸長弾性率ポリエ
ステルフィラメント糸は、伸長後の残留伸びが大きいた
め、収縮差混繊糸として布帛とする際の拘束力による伸
長がリラックス精錬等で緩和された後も糸長を保持でき
る。この糸長保持が収縮差混繊糸での糸長差を形成し、
布帛のふくらみ感やソフト感を引き出している。
The elongation modulus at 3% elongation of the polyester filament yarn obtained in the present invention must be 60 to 85%. Fig. 1 shows the load-
It is an example of an extension curve. The elongation modulus decreases as the residual elongation after elongation increases. In other words, since the low elongation modulus polyester filament yarn has a large residual elongation after elongation, the yarn length can be maintained even after the elongation due to the restraining force at the time of forming a fabric as a differential shrinkage mixed fiber yarn is relaxed by relaxing refining or the like. . This yarn length retention forms a yarn length difference in the shrinkage difference mixed yarn,
It brings out the swelling and softness of the fabric.

【0011】伸長弾性率が85%を超えると、布帛にし
た際のふくらみ感やソフト感が不足してしまう。また、
60%未満ということは、繊維構造がルーズであること
を意味し、寸法安定性が低下する結果となる。また、製
造工程においても糸条の走行が極めて不安定となり、安
定した生産が困難である。
If the elongation modulus exceeds 85%, the swelling feeling and the soft feeling when made into a fabric will be insufficient. Also,
Less than 60% means that the fiber structure is loose, resulting in reduced dimensional stability. Also, in the manufacturing process, the running of the yarn becomes extremely unstable, and stable production is difficult.

【0012】また、本発明で得られる微収縮性ポリエス
テルフィラメント糸の沸騰水収縮率は、0%以上3%以
下であることが必須であり、布帛にした際のふくらみ感
やソフト感を向上させるためには、0%以上1%以下で
あるのが好ましい。沸騰水収縮率が3%より高いと布帛
にした際、ふくらみ感やソフト感が不足する。一方、沸
騰水収縮率が0%より低くなると、伸長弾性率が60%
未満の場合と同様、寸法安定性が低下し、製造工程での
糸条走行も極めて不安定となる。
The boiling water shrinkage of the slightly shrinkable polyester filament yarn obtained in the present invention is essential to be 0% or more and 3% or less, and improves the swelling feeling and the soft feeling when made into a fabric. For this purpose, the content is preferably 0% or more and 1% or less. If the boiling water shrinkage ratio is higher than 3%, when the fabric is made, the swelling feeling and the soft feeling are insufficient. On the other hand, when the boiling water shrinkage is lower than 0%, the elongation modulus is 60%.
As in the case of less than 1, the dimensional stability is reduced, and the running of the yarn in the manufacturing process becomes extremely unstable.

【0013】本発明で得られる微収縮性ポリエステルフ
ィラメント糸の乾熱収縮率は、沸騰水収縮率と等しい
か、もしくは沸騰水収縮率以下であることが必要であ
る。乾熱収縮率が沸騰水収縮率より大きくなると、布帛
のリラックス精錬で形成されたクリンプや糸長差が中間
セット等の高次加工工程での熱処理により減少し、布帛
のふくらみ感やソフト感が不十分となる。
The dry heat shrinkage of the slightly shrinkable polyester filament yarn obtained in the present invention must be equal to or less than the boiling water shrinkage. When the dry heat shrinkage ratio is greater than the boiling water shrinkage ratio, the crimp and yarn length difference formed by relaxing refining of the fabric are reduced by heat treatment in a higher-order processing step such as an intermediate setting, and the swelling and softness of the fabric are reduced. Will be insufficient.

【0014】本発明で得られる微収縮性ポリエステルフ
ィラメント糸の単糸繊度は、0.2d程度の極細から5
d程度の太繊度まで任意に採用することができるが、単
糸繊度を1.0d以下の極細とすると、布帛に繊細なピ
ーチタッチを付与することができ、好適である。また、
フィラメント糸の断面形状は、丸断面以外にドライ感や
光沢を得るために三葉断面等の多葉断面を採用したり、
軽量感を得るために中空断面等を採用したりすることも
可能である。さらに、単糸繊度を極細にした場合、フィ
ラメント糸に交絡を付与することが、高次加工工程での
糸切れや毛羽発生を防止するために好ましい。また、高
収縮性ポリエステルフィラメント糸と交絡混繊させ収縮
差混繊糸とするためには、フィラメント糸の交絡度は2
0以下とすることが好ましい。
[0014] The fineness of the finely shrinkable polyester filament yarn obtained in the present invention is from a fineness of about 0.2 d to 5
A fineness of about d can be arbitrarily adopted, but it is preferable that the fineness of a single yarn be 1.0d or less, since a fine peach touch can be imparted to the fabric. Also,
The cross-sectional shape of the filament yarn adopts a multi-leaf cross-section such as a tri-lobal cross-section in order to obtain a dry feeling and luster other than a round cross-section,
It is also possible to adopt a hollow cross section or the like in order to obtain a lightweight feeling. Further, in the case where the single yarn fineness is extremely small, it is preferable to impart entanglement to the filament yarn in order to prevent yarn breakage and fuzz generation in the high-order processing step. In addition, in order to mix and entangle with a highly shrinkable polyester filament yarn to obtain a shrinkage difference mixed yarn, the degree of entanglement of the filament yarn is 2
It is preferably set to 0 or less.

【0015】図2は本発明の好ましい実施態様を示す延
伸、熱処理工程の概略図である。未延伸糸または部分配
向糸1はフィードロール2を経て第1ホットロール3と
セパレートロール4に数回巻き付けられ予備加熱され、
第1ホットロール3と第2ホットロール5の間で所定の
倍率で延伸され、且つ第2ホットロール5で熱処理され
延伸糸となる。次いで加熱していないストレッチロール
6、ラペットガイド7を経て、上下方向にトラバースす
るリング8上を滑走するトラベラ9によりパーン10と
して巻き取られる。
FIG. 2 is a schematic view of a stretching and heat treatment step showing a preferred embodiment of the present invention. The undrawn yarn or the partially oriented yarn 1 is wound around the first hot roll 3 and the separate roll 4 several times via the feed roll 2 and preheated,
It is stretched at a predetermined magnification between the first hot roll 3 and the second hot roll 5 and heat-treated by the second hot roll 5 to be a drawn yarn. Next, it is wound as a pan 10 by a traveler 9 sliding on a ring 8 traversing in the vertical direction through a stretch roll 6 and a lappet guide 7 that are not heated.

【0016】本発明の微収縮性ポリエステルフィラメン
ト糸の製造方法は、ポリエステルフィラメント糸の未延
伸糸または部分配向糸を少なくとも1対のホットローラ
ー系を有する延伸機を用いて、延伸倍率を1.05〜
1.20、延伸温度を90℃以上110℃以下、熱セッ
ト温度を110℃以上140℃以下で延伸、熱セットす
ることが肝要である。ホットローラーを有する延伸機で
熱セットを行うことにより、熱セット時の糸道が安定
し、断糸が減少するため大幅に工程安定性が向上する。
In the method for producing a slightly shrinkable polyester filament yarn of the present invention, an undrawn polyester yarn or a partially oriented yarn of a polyester filament yarn is drawn at a draw ratio of 1.05 using a drawing machine having at least one pair of hot roller systems. ~
It is important to perform stretching and heat setting at 1.20, a stretching temperature of 90 to 110 ° C., and a heat setting temperature of 110 to 140 ° C. By performing the heat setting with a drawing machine having a hot roller, the yarn path during the heat setting is stabilized, and the yarn breakage is reduced, so that the process stability is greatly improved.

【0017】本発明では、延伸倍率を1.05〜1.2
0倍とする必要がある。延伸倍率が1.05より低いと
ホットローラー上での糸揺れが増大し、糸条走行が安定
せず、均一な品質を得ることができず、ひいては断糸を
引き起こす。また、延伸倍率が1.20倍を超えると延
伸による歪みを抑制することができず、沸騰水収縮率を
低下させることが困難になる。
In the present invention, the draw ratio is set to 1.05 to 1.2.
Must be 0 times. If the draw ratio is lower than 1.05, the sway of the yarn on the hot roller increases, the running of the yarn is not stabilized, uniform quality cannot be obtained, and the yarn breaks. On the other hand, if the stretching ratio exceeds 1.20, distortion due to stretching cannot be suppressed, and it becomes difficult to reduce the boiling water shrinkage.

【0018】また、本発明では延伸、熱セットの際の温
度条件が重要である。本発明では延伸温度は延伸直前の
糸条の予熱温度を意味し、図2の実施態様では、延伸直
前の第1ホットロール温度を指すものである。本発明に
おいては、この延伸温度を90℃以上110℃以下とす
る必要がある。延伸温度が90℃以上であると、延伸前
に分子鎖のモビリティーが十分向上し、不均一延伸によ
る糸斑を抑制することが可能である。また、延伸前のP
OYの過度の結晶化を防止し、低収縮化に有利となる。
In the present invention, temperature conditions during stretching and heat setting are important. In the present invention, the drawing temperature refers to the preheating temperature of the yarn immediately before drawing, and in the embodiment of FIG. 2, refers to the first hot roll temperature immediately before drawing. In the present invention, the stretching temperature needs to be 90 ° C. or more and 110 ° C. or less. When the stretching temperature is 90 ° C. or higher, the mobility of molecular chains is sufficiently improved before stretching, and it is possible to suppress yarn spots due to uneven stretching. In addition, P before stretching
Excessive crystallization of OY is prevented, which is advantageous for reducing shrinkage.

【0019】本発明では熱セット温度は延伸後の糸条の
熱処理温度を意味し、図2の実施態様では、延伸後の第
2ホットローラー温度を指すものである。本発明におい
ては、この熱セット温度を110℃以上140℃以下と
する必要がある。熱セット温度を110℃以上とするこ
とで延伸糸の結晶化が十分進行し配向非晶分子鎖の固定
が十分となり、低収縮化に有利となるが、140℃より
高くなると、熱セットの際の糸揺れが大きくなり、熱セ
ット不良となる。
In the present invention, the heat setting temperature means the heat treatment temperature of the drawn yarn, and in the embodiment of FIG. 2, it refers to the temperature of the second hot roller after the drawing. In the present invention, the heat setting temperature needs to be 110 ° C. or more and 140 ° C. or less. By setting the heat setting temperature to 110 ° C. or higher, the crystallization of the drawn yarn proceeds sufficiently, fixing the oriented amorphous molecular chains becomes sufficient, and it is advantageous for reducing the shrinkage. Yarn shaking becomes large, resulting in poor heat setting.

【0020】さらに、本発明の製造方法では、パーンと
して巻き取る際に巻き上げ時のパーンの回転数(以下、
スピンドル回転数と称す)を巻き始めから巻き終わりま
で随時制御し、使用するトラベラを適正化し、巻取張力
を巻き始めから巻き終わりに亘るまでの間、巻き始めの
巻取張力に対して、±20%以内とすることが好適であ
り、これにより、低伸長弾性率繊維を品質が均一で、パ
ッケージの崩れや高次工程での解舒不良が発生させず安
定して生産することができる。品質の均一性や解舒性を
さらに向上させるには、巻取張力を巻き始めの巻取張力
に対して、±10%以内として巻き取ることがさらに好
ましい。
Further, according to the production method of the present invention, when winding as a pan, the number of rotations of the pan during winding (hereinafter, referred to as "pan").
Spindle rotation speed) is controlled at any time from the start of winding to the end of winding, the traveler used is optimized, and the winding tension from the winding start to the winding end is ± The content is preferably within 20%, so that the low elongation modulus fiber can be stably produced with uniform quality and without occurrence of package collapse or unwinding failure in a high-order process. In order to further improve the uniformity of quality and the unwinding property, it is more preferable to set the winding tension to within ± 10% of the winding tension at the start of winding.

【0021】巻取張力が巻き始めの巻取張力に対し±2
0%の範囲内で有ると、品質の均一性が良好となり、高
次工程での解舒時に解舒性が良好となる。
The winding tension is ± 2 with respect to the winding tension at the beginning of winding.
When it is within the range of 0%, the uniformity of quality becomes good, and the unwinding property becomes good at the time of unwinding in a higher-order process.

【0022】巻取張力を巻き始めから巻き終わりに亘っ
て巻き始めの巻取張力に対して、±20%以内とする手
段として、スピンドル回転数を巻き始めからの経過時間
に応じて設定し、巻取張力の変動を抑えることが有効で
ある。また、巻き始めから巻き終わりまでの間の品質変
化を抑えるために、低伸長弾性率ポリエステルフィラメ
ント糸の繊度に対応して、使用するトラベラを適正化す
ることも有効である。
As a means for keeping the winding tension within ± 20% of the winding tension from the beginning of winding to the end of winding, the spindle rotation speed is set according to the elapsed time from the start of winding. It is effective to suppress the fluctuation of the winding tension. It is also effective to optimize the traveler to be used according to the fineness of the low elongation modulus polyester filament yarn in order to suppress the quality change from the start to the end of winding.

【0023】伸長弾性率が95〜100%である通常の
ポリエステルフィラメント糸では、高次工程でのパーン
崩れを防止し、解舒性を向上させるため、巻取張力を暫
減させて巻き取っている。また、巻き始めから巻き終わ
りまでの巻取張力の暫減幅は、巻き始めの巻取張力に対
し50〜70%ほどである。巻取張力の暫減とパーン直
径の増加に伴い、スピンドル回転数も巻き終わりに向か
って暫減させている。
With a normal polyester filament yarn having an elongation modulus of 95% to 100%, winding is performed while temporarily reducing the winding tension in order to prevent buckling in a high-order process and improve unwinding properties. I have. Further, the temporary decrease in the winding tension from the start of winding to the end of winding is about 50 to 70% of the winding tension at the start of winding. As the winding tension decreases and the pan diameter increases, the spindle rotation speed also decreases toward the end of winding.

【0024】本発明の巻取方法についても巻き始めと巻
き終わりのスピンドル回転数を比較すると暫減させてい
るが、巻き取り中のパーン直径の増加割合が一定でない
ことによる巻取張力の局所的な増加を含めて、巻き始め
の巻取張力に対して±20%以内とするため、巻き時間
に対応してスピンドル回転数を設定している。また、巻
取張力による品質変化を抑制するため、巻き始めの巻取
張力は、0.08〜0.12g/dとすることが好まし
く、パーンの崩れや解舒不良を防止するため、パーン硬
度は60〜80゜とすることが好適である。
In the winding method of the present invention, the number of spindle rotations at the start and end of winding is reduced for a while, however, the local increase in the winding tension due to the non-constant increase in the pan diameter during winding. In order to keep the winding tension at the start of winding within ± 20%, including a slight increase, the spindle rotation speed is set according to the winding time. Further, the winding tension at the start of winding is preferably 0.08 to 0.12 g / d in order to suppress a change in quality due to the winding tension. Is preferably 60 to 80 °.

【0025】[0025]

【実施例】以下に、本発明を実施例により更に具体的に
説明する。なお、実施例中の測定方法、評価方法は以下
の方法を用いた。測定結果、評価結果は、表3の通りで
ある。 A.伸長弾性率 ORIENTEO社製RTC1210Aを用いて、初期
試料長=20mm、引っ張り速度=2mm/分とし、J
IS L1013 A法に従い3%伸長時の伸長弾性率
(%)を求めた。 B.交絡度 ROTHSCHILD社製ENTANGLEMENT−
TESTERを用いて、予備張力を0.1g/d、トリ
ップテンションを(予備張力+(延伸糸デニール/フィ
ラメント数))g、試料供給速度を4cm/秒として交
絡距離を50回測定し、その平均値を用いて以下の式に
より交絡度を算出した。
EXAMPLES The present invention will be described more specifically with reference to the following examples. In addition, the following methods were used for the measurement method and the evaluation method in the examples. Table 3 shows the measurement results and the evaluation results. A. Elongation modulus Using ORIENTEO's RTC1210A, the initial sample length was set to 20 mm and the pulling speed was set to 2 mm / min.
The elongation modulus (%) at 3% elongation was determined according to the IS L1013 A method. B. Entanglement degree ENTANGLEMENT- manufactured by ROTHSCHILD
Using a TESTER, the pre-tension was set to 0.1 g / d, the trip tension was set to (pre-tension + (number of drawn yarns / number of filaments)) g, the sample supply speed was set to 4 cm / sec, and the entangling distance was measured 50 times. Using the values, the degree of confounding was calculated by the following equation.

【0026】交絡度=1000/交絡距離の平均値 C.パーン硬度 高分子計器製HARDNESS TESTER ”Ty
pe C”を使いパーン中央部を測定した。 D.巻取張力と巻取張力変動幅 巻取張力は、金井工機社製テンションチェッカーCB型
を用いてラペットガイド上の走行糸張力を測定し、横河
電機製作所社製TYPE3047 2ペンレコーダにて
巻き取りの間、連続して記録した。
Degree of confounding = 1000 / Average value of confounding distance Pan hardness HARDNESS TESTER "Ty"
The center of the pan was measured using "pe C". D. Winding tension and width of fluctuation of winding tension The winding tension was measured by using a tension checker CB manufactured by Kanai Koki Co., Ltd. to measure the running yarn tension on the wrappet guide. Then, recording was continuously performed during winding by a TYPE 30472 2-pen recorder manufactured by Yokogawa Electric Corporation.

【0027】巻取張力変動幅は、巻き始めの巻取張力と
巻取張力の最大値、最小値を用いて次式により算出し
た。
The winding tension fluctuation range was calculated by the following equation using the winding tension at the start of winding and the maximum and minimum values of the winding tension.

【0028】 ΔTmax=(Tmax−Ts)/Ts ΔTmin=(Tmin−Ts)/Ts ΔTmax:巻取張力変動幅の最大値(%) ΔTmin:巻取張力変動幅の最小値(%) Ts:巻き始めの巻取張力(g) Tmax:巻取張力の最大値(g) Tmin:巻取張力の最小値(g) E.パーン内における品質の均一性評価 パーン内での品質の均一性を評価する尺度として、糸条
の長手方向における沸騰水収縮率の標準偏差を用いた。
東レエンジニアリング社製FTA−500を用いて、低
収縮糸の糸長手方向の沸騰水収縮率の連続測定を行っ
た。この時、糸の供給速度20m/分、走行糸応力0.
01g/dで長さ15.5cmの100℃に加熱した湿
熱処理装置に通した。そして10分間測定を行い、収縮
率の標準偏差を求めた。この時、測定糸長3.3cm毎
に生の収縮率をポイントデータとして取り込み、これを
6点合わせて平均して1データとした。そしてそのデー
タを1000個収集し標準偏差を計算し、0.25以下
を合格とした。 F.パッケージフォーム評価 巻き上がったパーンのパッケージフォームを目視により
観察し、糸層ずれやパッケージの崩れについて発生度合
いを評価した。評価方法は、○:糸層ずれ、パッケージ
の崩れなし、△:解舒不良発生につながる糸層ずれ有
り、×:パッケージの崩れ発生とし、○を合格とした。 G.解舒性評価 600m/minの解舒速度でパーンから糸条を解舒
し、輪抜けや解舒不良の発生度合いを観察し、解舒性を
評価した。 H.布帛評価 実施例、比較例で得られた低伸長弾性率ポリエステルフ
ィラメント糸を沸騰水収縮率が21.5%、乾熱収縮率
が19.5%である30デニール、12フィラメントの
高収縮性ホモポリエステルフィラメント糸とインターレ
ースノズルを用いてエア混繊し収縮差混繊糸を作製し、
これに300ターン/mのS撚りを施し平織りした。こ
れに、98℃でリラックス精錬を施し、180℃で中間
セットした。さらに常法により10重量%のアルカリ減
量を行い、染色、180℃での仕上げセットを行った。
以上の方法で得た布帛について、ふくらみ感、ソフト感
について1〜5級で官能評価し、3級以上を合格とし
た。 実施例1 三酸化アンチモンを重合触媒として用い、テレフタル酸
とエチレングリコールから常法に従い、極限粘度(オク
ソクロルフェノール溶媒中で25℃で測定)0.65の
ポリエチレンテレフタレート(PET)を得た。この
時、艶消し剤として平均一次粒径0.5μmの酸化チタ
ンを0.4wt%添加した。得られた重合体を紡糸温度
284℃、紡糸速度2500m/minで溶融紡糸を行い、
56.7デニール36フィラメントのPOYを巻き取っ
た。
ΔTmax = (Tmax−Ts) / Ts ΔTmin = (Tmin−Ts) / Ts ΔTmax: maximum value (%) of the winding tension fluctuation width ΔTmin: minimum value (%) of the winding tension fluctuation width Ts: winding E. Initial winding tension (g) Tmax: Maximum winding tension (g) Tmin: Minimum winding tension (g) Evaluation of uniformity of quality in the pan A standard deviation of the boiling water shrinkage in the longitudinal direction of the yarn was used as a scale for evaluating the uniformity of the quality in the pan.
Continuous measurement of the boiling water shrinkage in the yarn longitudinal direction of the low shrinkage yarn was performed using FTA-500 manufactured by Toray Engineering Co., Ltd. At this time, the yarn supply speed was 20 m / min, and the running yarn stress was 0.
The solution was passed through a wet heat treatment apparatus heated to 100 ° C. at 1 g / d and having a length of 15.5 cm. Then, the measurement was performed for 10 minutes, and the standard deviation of the shrinkage rate was obtained. At this time, the raw shrinkage was taken in as point data for every 3.3 cm of the measured yarn length, and these were combined into six points and averaged to obtain one data. Then, 1000 pieces of the data were collected, the standard deviation was calculated, and 0.25 or less was regarded as a pass. F. Package foam evaluation The package foam of the rolled-up pan was visually observed, and the degree of occurrence of yarn layer shift and package collapse was evaluated. The evaluation methods were as follows: :: yarn layer displacement, no package collapse, Δ: thread layer deviation leading to occurrence of unwinding failure, ×: package collapse occurrence, and ○ passed. G. FIG. Evaluation of unwinding property The yarn was unwound from the pirn at an unwinding speed of 600 m / min, and the degree of occurrence of wheel slippage or poor unwinding was observed to evaluate the unwinding property. H. Fabric Evaluation The low elongation modulus polyester filament yarns obtained in Examples and Comparative Examples were 30 denier, 12 filament high shrinkage homopolymers having a boiling water shrinkage of 21.5% and a dry heat shrinkage of 19.5%. Air mixed using polyester filament yarn and interlace nozzle to produce shrinkage differential mixed yarn,
This was S-twisted at 300 turns / m and plain woven. This was subjected to relaxation smelting at 98 ° C., and intermediately set at 180 ° C. Further, the alkali was reduced by 10% by weight according to a conventional method, dyed, and finished at 180 ° C.
Regarding the cloth obtained by the above method, the feeling of swelling and the feeling of softness were organoleptically evaluated on the 1st to 5th grades, and the 3rd or higher grade was accepted. Example 1 Using antimony trioxide as a polymerization catalyst, polyethylene terephthalate (PET) having an intrinsic viscosity (measured in an oxochlorophenol solvent at 25 ° C.) of 0.65 was obtained from terephthalic acid and ethylene glycol according to a conventional method. At this time, 0.4 wt% of titanium oxide having an average primary particle size of 0.5 μm was added as a matting agent. The obtained polymer is melt-spun at a spinning temperature of 284 ° C. and a spinning speed of 2500 m / min.
The 56.7 denier 36 filament POY was wound up.

【0029】上記POYを図2の1対のホットローラー
を有する延伸機を用い、第1ホットローラー3の温度を
95℃、第2ホットローラー5の温度を125℃、延伸
速度を970m/分として、延伸倍率を表1の如く設定
して延伸糸を得た。得られた微収縮性ポリエステルフィ
ラメント糸は、均一な品質を有する微収縮性ポリエステ
ルフィラメント糸であった。該ポリエステルフィラメン
ト糸から得られた収縮差混繊糸からなる布帛は、ふくら
み感、ソフト感が優れたものであった。 比較例1 延伸倍率を表1の如く設定した以外は、実施例1と同様
な条件で製糸を行った(実験No.4,5)。延伸倍率
を1.25倍とした実験No.4では、伸長弾性率、沸
騰水収縮率、乾熱収縮率がともに高くなり、布帛評価に
おいてもふくらみ感、ソフト感に欠けるものであった。
延伸倍率を1.02倍とした実験No.5では、伸長弾
性率、沸騰水収縮率が本発明の範囲より低く、繊維構造
がルーズで寸法安定性が低下するため、パッケージの崩
れが生じ、布帛評価を行うことができなかった。また、
収縮率の標準偏差も0.42と大きく、品質に大きなば
らつきを有するポリエステルフィラメント糸であった。
The POY was stretched using a stretching machine having a pair of hot rollers as shown in FIG. 2 with the temperature of the first hot roller 3 at 95 ° C., the temperature of the second hot roller 5 at 125 ° C., and the stretching speed of 970 m / min. The draw ratio was set as shown in Table 1 to obtain a drawn yarn. The obtained slightly shrinkable polyester filament yarn was a finely shrinkable polyester filament yarn having uniform quality. The cloth made of the differential shrinkage mixed fiber obtained from the polyester filament yarn had excellent swelling and softness. Comparative Example 1 A yarn was produced under the same conditions as in Example 1 except that the draw ratio was set as shown in Table 1 (Experiment Nos. 4 and 5). Experiment No. with a stretching ratio of 1.25 times. In No. 4, the elongation modulus, the boiling water shrinkage, and the dry heat shrinkage were all high, and the fabric evaluation lacked a swelling feeling and a soft feeling.
Experiment No. 1 in which the stretching ratio was 1.02 times. In No. 5, the elongation modulus and the boiling water shrinkage ratio were lower than the ranges of the present invention, the fiber structure was loose, and the dimensional stability was lowered, so that the package collapsed and the fabric could not be evaluated. Also,
The standard deviation of the shrinkage ratio was as large as 0.42, and the polyester filament yarn had a large variation in quality.

【0030】[0030]

【表1】 実施例2 POYの繊度を136.5デニール、フィラメント数を
144本と192本とし、延伸倍率を1.14倍、延伸
温度を100℃、熱セット温度を130℃とすること以
外は実施例1と同様な条件で製糸し、120デニール1
44フィラメントと120デニール192フィラメント
の延伸糸を得た(実験No.6、7)。得られたポリエ
ステルフィラメント糸を用いた収縮差混繊糸により得ら
れた布帛は、ふくらみ感、ソフト感に優れ、取扱い性も
良好であった。特に、単糸繊度が1.0d以下であるた
め、繊細なピーチタッチを有する布帛であった。 実施例3 延伸倍率を1.14倍、熱セット温度を表2の如く変更
した以外は実施例1と同様な方法で製糸し、50デニー
ル36フィラメントの延伸糸を得た(実験No.8〜1
0)。熱セット温度が110〜140℃であれば、伸長
弾性率、沸騰水収縮率、乾熱収縮率が本発明の範囲内と
なり、収縮率の標準偏差も0.17以下で均一な品質を
有する微収縮性ポリエステルフィラメント糸であり、収
縮差混繊糸で得られた布帛は、ふくらみ感、ソフト感が
優れたものであった。 比較例2 延伸倍率を1.14倍、熱セット温度を表2の如く変更
した以外は実施例1と同様な方法で製糸し、50デニー
ル36フィラメントの延伸糸を得た(実験No.11、
12)。熱セット温度を105℃とした実験No.11
は、沸騰水収縮率が不十分であった。また、得られたポ
リエステルフィラメント糸を用いた収縮差混繊糸により
得られた布帛は、ふくらみ感、ソフト感に欠けるもので
あった。熱セット温度を145℃とした実験No.12
は、沸騰水収縮率が−0.3%の自発伸長糸であり、収
縮率の標準偏差が0.37と大きく、品質に大きなばら
つきを有するポリエステルフィラメント糸であった。ま
た、糸条の走行状態が不安定であり、ホットロールやス
トレッチロール上で糸条の巻付きが発生し、布帛評価を
行うのに必要な量の延伸糸を得ることができなかった。
[Table 1] Example 2 Example 1 except that the POY fineness was 136.5 denier, the number of filaments was 144 and 192, the stretching ratio was 1.14 times, the stretching temperature was 100 ° C., and the heat setting temperature was 130 ° C. Spinning under the same conditions as in
A drawn yarn of 44 filaments and 120 denier 192 filaments was obtained (Experiment Nos. 6 and 7). The fabric obtained from the differential shrinkage mixed yarn using the obtained polyester filament yarn was excellent in swelling and softness, and also excellent in handleability. In particular, since the single-fiber fineness was 1.0 d or less, the fabric had a delicate peach touch. Example 3 A yarn was produced in the same manner as in Example 1 except that the draw ratio was changed to 1.14 times and the heat setting temperature was changed as shown in Table 2, to obtain a drawn yarn of 50 denier and 36 filaments (Experiment Nos. 8 to 10). 1
0). When the heat setting temperature is 110 to 140 ° C., the elongation modulus, boiling water shrinkage, and dry heat shrinkage fall within the range of the present invention, and the standard deviation of shrinkage is 0.17 or less, and uniform quality is obtained. The fabric obtained from the shrinkable polyester filament yarn, which is a shrinkage-differential mixed fiber, had excellent swelling and softness. Comparative Example 2 A yarn was drawn in the same manner as in Example 1 except that the draw ratio was changed to 1.14 times and the heat setting temperature was changed as shown in Table 2, to obtain a drawn yarn of 50 denier and 36 filaments (Experiment No. 11,
12). Experiment No. 1 in which the heat setting temperature was 105 ° C. 11
Had insufficient boiling water shrinkage. Further, the fabric obtained from the shrinkage difference mixed yarn using the obtained polyester filament yarn lacked a swelling feeling and a soft feeling. Experiment No. 1 in which the heat setting temperature was 145 ° C. 12
Was a spontaneously elongated yarn having a boiling water shrinkage of -0.3%, a large standard deviation of shrinkage of 0.37, and a polyester filament yarn having a large variation in quality. In addition, the running state of the yarn was unstable, and the winding of the yarn occurred on a hot roll or a stretch roll, and it was not possible to obtain an amount of stretched yarn necessary for evaluating the fabric.

【0031】[0031]

【表2】 実施例4 延伸倍率を1.14倍、熱セット温度を130℃、延伸
温度を表3の如く変更した以外は実施例1と同様な方法
で製糸し、50デニール36フィラメントの延伸糸を得
た(実験No.13、14)。延伸温度が90〜110
℃であれば、伸長弾性率、沸騰水収縮率、乾熱収縮率が
本発明の範囲内となり、収縮率の標準偏差も0.18以
下であり、均一な品質を有する微収縮性ポリエステルフ
ィラメント糸を得ることができた。また、得られたポリ
エステルフィラメント糸を用いた収縮差混繊糸により得
られた布帛は、ふくらみ感、ソフト感が優れたものであ
った。 比較例3 延伸倍率を1.14倍、熱セット温度を130℃、延伸
温度を表6の如く変更した以外は実施例1と同様な方法
で製糸し、50デニール36フィラメントの延伸糸を得
た(実験No.15、16)。延伸温度を85℃とした
実験No.15は、延伸直前の予熱が不十分であるた
め、収縮率の標準偏差が0.41と大きく、品質に大き
なばらつきを有するポリエステルフィラメント糸であっ
た。延伸温度を115℃とした実験No.16は、収縮
率の標準偏差が0.38と大きく、品質に大きなばらつ
きを有するポリエステルフィラメント糸であった。
[Table 2] Example 4 A yarn was produced in the same manner as in Example 1 except that the draw ratio was changed to 1.14 times, the heat setting temperature was changed to 130 ° C., and the draw temperature was changed as shown in Table 3, to obtain a drawn yarn having 50 denier and 36 filaments. (Experiment Nos. 13 and 14). Stretching temperature is 90-110
At 0 ° C., the elongation modulus, boiling water shrinkage, and dry heat shrinkage fall within the range of the present invention, and the standard deviation of the shrinkage is 0.18 or less, and the finely shrinkable polyester filament yarn having uniform quality. Could be obtained. Further, the fabric obtained from the shrinkage difference mixed yarn using the obtained polyester filament yarn was excellent in swelling feeling and soft feeling. Comparative Example 3 A yarn was produced in the same manner as in Example 1 except that the draw ratio was changed to 1.14 times, the heat setting temperature was changed to 130 ° C., and the draw temperature was changed as shown in Table 6, to obtain a drawn yarn having 50 denier and 36 filaments. (Experiment Nos. 15, 16). Experiment No. 1 in which the stretching temperature was 85 ° C. No. 15 was a polyester filament yarn having a large standard deviation of the shrinkage ratio of 0.41 due to insufficient preheating immediately before stretching, and a large variation in quality. Experiment No. 1 in which the stretching temperature was 115 ° C. No. 16 was a polyester filament yarn having a large standard deviation of shrinkage of 0.38 and a large variation in quality.

【0032】[0032]

【表3】 実施例5 三酸化アンチモンを重合触媒として用い、テレフタル酸
とエチレングリコールから常法に従い、極限粘度(オク
ソクロルフェノール溶媒中で25℃で測定)0.65の
ポリエチレンテレフタレート(PET)を得た。この
時、艶消し剤として平均一次粒径0.5μmの酸化チタ
ンを0.4wt%添加した。得られた重合体を紡糸温度
284℃、紡糸速度2500m/minで溶融紡糸を行い、
136.5デニール48フィラメントのPOYを巻き取
った。
[Table 3] Example 5 Using antimony trioxide as a polymerization catalyst, polyethylene terephthalate (PET) having an intrinsic viscosity (measured in an oxochlorophenol solvent at 25 ° C.) of 0.65 was obtained from terephthalic acid and ethylene glycol according to a conventional method. At this time, 0.4 wt% of titanium oxide having an average primary particle size of 0.5 μm was added as a matting agent. The obtained polymer is melt-spun at a spinning temperature of 284 ° C. and a spinning speed of 2500 m / min.
The 136.5 denier 48 filament POY was wound up.

【0033】上記POYを図2の1対のホットローラー
を有する延伸機を用い、第1ホットローラー3の温度を
100℃、第2ホットローラー5の温度を130℃、延
伸倍率を1.14倍、延伸速度を970m/分、トラベ
ラを金井重要工業(株)社製の#23として、スピンド
ル回転数を表4の如く設定して、3.0kg巻きのパー
ンに巻き取り、伸長弾性率が76%の120デニール4
8フィラメントの低伸長弾性率ポリエステルフィラメン
ト糸を得た。巻取張力変動幅が±20%の範囲内であれ
ば、沸騰水収縮率の標準偏差は0.18以下で均一な品
質を有し、かつ糸層ずれやパッケージの崩れ、解舒不良
も発生しなかった。また、布帛評価においてもふくらみ
感、ソフト感に優れた布帛が得られた(実験No.17
〜19)。巻取張力変動幅が±20%の範囲外となる
と、糸層ずれによる解舒性低下や収縮率のばらつきによ
る布帛でのヒケやスラブ状の欠点が生じた(実験No.
20〜22)。
Using a stretching machine having a pair of hot rollers as shown in FIG. 2, the temperature of the first hot roller 3 is set to 100 ° C., the temperature of the second hot roller 5 is set to 130 ° C., and the stretching ratio is set to 1.14. The stretching speed was set to 970 m / min, the traveler was # 23 manufactured by Kanai Kiko Kogyo Co., Ltd., and the spindle rotation speed was set as shown in Table 4. 120 denier 4%
An 8-filament low elongation modulus polyester filament yarn was obtained. If the fluctuation range of the winding tension is within the range of ± 20%, the standard deviation of the boiling water shrinkage rate is 0.18 or less, uniform quality, and yarn layer misalignment, package collapse, and unwinding failure also occur. Did not. In the evaluation of the cloth, a cloth excellent in swelling feeling and soft feeling was obtained (Experiment No. 17).
19). When the winding tension fluctuation range is out of the range of ± 20%, sinkage or slab-like defects in the fabric due to a decrease in unwinding property due to a yarn layer shift and a variation in shrinkage rate occurred (Experiment No. 1).
20-22).

【0034】[0034]

【表4】 [Table 4]

【0035】[0035]

【表5】 [Table 5]

【0036】[0036]

【発明の効果】本発明の微収縮性ポリエステルフィラメ
ント糸を用いることにより、従来自発伸長糸が有してい
た製造工程での問題や寸法安定性の不良を改善し、ふく
らみ感、ソフト感に優れたポリエステル布帛を製造する
ための微収縮性ポリエステルフィラメント糸を提供でき
る。
EFFECT OF THE INVENTION By using the finely shrinkable polyester filament yarn of the present invention, problems in the production process and poor dimensional stability, which were conventionally encountered with spontaneously elongated yarn, are improved, and the feeling of swelling and softness is excellent. The present invention can provide a slightly shrinkable polyester filament yarn for producing a polished polyester fabric.

【図面の簡単な説明】[Brief description of the drawings]

【図1】伸長弾性率測定時の荷重−伸長曲線の一例図FIG. 1 shows an example of a load-elongation curve at the time of elongation elastic modulus measurement.

【図2】本発明の実施態様を示す延伸、熱処理工程の概
略図
FIG. 2 is a schematic view of a stretching and heat treatment step showing an embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1.未延伸糸または部分配向糸 2.フィードロール 3.第1ホットロール 4.セパレートロール 5.第2ホットロール 6.ストレッチロール 7.ラペットガイド 8.リング 9.トラベラ 10.パーン 1. 1. Undrawn yarn or partially oriented yarn Feed roll 3. First hot roll 4. Separate roll 5. Second hot roll 6. Stretch roll 7. Lappet guide 8. Ring 9. Traveler 10. Pan

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】下記の特性を同時に満足することを特徴と
する微収縮性ポリエステルフィラメント糸。 (1)3%伸長時の伸長弾性率が60%以上85%以
下。 (2)沸騰水収縮率が0%以上3%以下。 (3)乾熱収縮率が沸騰水収縮率と等しいか、または沸
騰水収縮率以下。
1. A finely shrinkable polyester filament yarn which simultaneously satisfies the following characteristics. (1) The elongation modulus at 3% elongation is 60% or more and 85% or less. (2) The boiling water shrinkage is 0% or more and 3% or less. (3) The dry heat shrinkage is equal to or less than the boiling water shrinkage.
【請求項2】単糸繊度が1.0d以下で、交絡度が20
以下であることを特徴とする請求項1記載の微収縮性ポ
リエステルフィラメント糸。
2. The single yarn fineness is 1.0d or less, and the entanglement degree is 20
The slightly shrinkable polyester filament yarn according to claim 1, wherein:
【請求項3】ポリエステルフィラメント糸の未延伸糸ま
たは部分配向糸を少なくとも1対のホットローラー系を
有する延伸機で延伸、熱セットするに際し、延伸倍率を
1.05〜1.20、延伸温度を90℃以上110℃以
下、熱セット温度を110℃以上140℃以下とするこ
とを特徴とする微収縮性ポリエステルフィラメント糸の
製造方法。
3. An unstretched or partially oriented yarn of a polyester filament yarn is stretched and heat-set by a stretching machine having at least one pair of hot roller systems. A method for producing a slightly shrinkable polyester filament yarn, wherein the heat setting temperature is 110 ° C or more and 140 ° C or less.
【請求項4】微収縮性ポリエステルフィラメント糸を延
伸に引き続きパーンとして巻き取るに際し、巻取張力を
巻き始めから巻き終わりに亘るまでの間、巻き始めの巻
取張力に対して、±20%以内として巻き取ることを特
徴とする請求項3記載微収縮性ポリエステルフィラメン
ト糸の製造方法。
4. When winding a slightly shrinkable polyester filament yarn as a pirn following drawing, the winding tension is within ± 20% of the winding tension at the start of winding from the start of winding to the end of winding. The method for producing a slightly shrinkable polyester filament yarn according to claim 3, wherein the yarn is wound.
JP16498699A 1999-06-11 1999-06-11 Slightly shrinkable polyester filament yarn Expired - Fee Related JP3815120B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16498699A JP3815120B2 (en) 1999-06-11 1999-06-11 Slightly shrinkable polyester filament yarn

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16498699A JP3815120B2 (en) 1999-06-11 1999-06-11 Slightly shrinkable polyester filament yarn

Publications (2)

Publication Number Publication Date
JP2000355828A true JP2000355828A (en) 2000-12-26
JP3815120B2 JP3815120B2 (en) 2006-08-30

Family

ID=15803672

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16498699A Expired - Fee Related JP3815120B2 (en) 1999-06-11 1999-06-11 Slightly shrinkable polyester filament yarn

Country Status (1)

Country Link
JP (1) JP3815120B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1321230C (en) * 2002-06-10 2007-06-13 中国石油化工股份有限公司 Process for manufacturing high modulus low retraction type trueran industrial filament and trueran industrial filament thereof
WO2023087649A1 (en) * 2021-11-19 2023-05-25 平顶山神马帘子布发展有限公司 Tension heat-setting treatment device and high-modulus chinlon 66 industrial filament production method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1321230C (en) * 2002-06-10 2007-06-13 中国石油化工股份有限公司 Process for manufacturing high modulus low retraction type trueran industrial filament and trueran industrial filament thereof
WO2023087649A1 (en) * 2021-11-19 2023-05-25 平顶山神马帘子布发展有限公司 Tension heat-setting treatment device and high-modulus chinlon 66 industrial filament production method

Also Published As

Publication number Publication date
JP3815120B2 (en) 2006-08-30

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