JP2000315486A - Manganese dry battery - Google Patents

Manganese dry battery

Info

Publication number
JP2000315486A
JP2000315486A JP11125135A JP12513599A JP2000315486A JP 2000315486 A JP2000315486 A JP 2000315486A JP 11125135 A JP11125135 A JP 11125135A JP 12513599 A JP12513599 A JP 12513599A JP 2000315486 A JP2000315486 A JP 2000315486A
Authority
JP
Japan
Prior art keywords
thin portion
inner cylinder
center
sealed body
battery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11125135A
Other languages
Japanese (ja)
Inventor
Hiroshi Hase
洋志 長谷
Ryohei Ashihara
良平 芦原
Keiji Ogino
桂治 荻野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP11125135A priority Critical patent/JP2000315486A/en
Publication of JP2000315486A publication Critical patent/JP2000315486A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Sealing Battery Cases Or Jackets (AREA)
  • Gas Exhaust Devices For Batteries (AREA)

Abstract

PROBLEM TO BE SOLVED: To improve leakage resistance and to certainly operate the battery in abnormal rising of inner pressure in the battery, by providing a notch in the outer surface of the upper part of an inner cylinder of a sealed body to form a thin portion, and positioning a welding line of a molding in the center of the thin portion. SOLUTION: A part of the outer surface of the upper half of an inner cylinder 11 is notched to form a thin portion 11a, and a welding line is positioned in the center 14 of the thin portion 11a. A gate of a die for molding a sealed body 10 is located at a position deviated from the center of the die, during molding, molten resin filled into the die is intruded from the gate to the opposite side of the central hole of the sealed body, the welding line occurs on the opposite side of the gate with spaced by the central hole, and furthermore, the center 14 of the thin portion 11a is further thinned. In this structure, when inner pressure of this battery abnormally rises, gas presses up a connecting portion 13 of the sealed body 10, and generates a clearance between the inner cylinder 11 and a carbon bar to go outward. Therefore, a crack occurs in the thin portion 11a, gas goes through this crack part over the sealed body 10, and goes out of a gas exhausting hole in a positive electrode terminal plate.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、負極亜鉛缶の開口
部を合成樹脂成形物からなる封口体により密封したマン
ガン乾電池の封口部の改良に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an improvement in a sealed portion of a manganese dry battery in which an opening of a negative electrode zinc can is sealed with a sealing member made of a synthetic resin molded product.

【0002】[0002]

【従来の技術】メタルジャケットを廃し、熱収縮性合成
樹脂フィルムを基材とするラベルまたはチューブで外装
するマンガン乾電池は、負極亜鉛缶を封口する封口体の
まわりから漏液すると、すぐさま外表面に出てしまうの
で、封口体による密封性を高めている。そのため誤使
用、例えば充電したり逆接続したりすると、ガスがたま
り、それが突出する危険性が大きくなる。そこで、従来
は、封口体の一部に薄肉部を設け、電池内圧上昇時にそ
こを破断させる防爆構造を採っている。ところが封口体
の成形に際して均質な薄肉部を得るのが困難であり、防
爆機構としての信頼性が低いという問題があった。
2. Description of the Related Art A manganese dry battery in which a metal jacket is abolished and is packaged with a label or a tube made of a heat-shrinkable synthetic resin film as a base material, when liquid leaks from around a sealing body for sealing a negative electrode zinc can, the manganese dry battery is immediately exposed to the outer surface. Because it comes out, the sealing performance by the sealing body is enhanced. Therefore, when misused, for example, when the battery is charged or reversely connected, gas accumulates and the danger of projecting the gas increases. Therefore, conventionally, an explosion-proof structure has been adopted in which a thin portion is provided in a part of the sealing body and the thin portion is broken when the internal pressure of the battery increases. However, there is a problem that it is difficult to obtain a uniform thin portion at the time of molding the sealing body, and the reliability as an explosion-proof mechanism is low.

【0003】[0003]

【発明が解決しようとする課題】本発明は、以上に鑑
み、耐漏液性に優れ、しかも誤使用などにより万一電池
内圧が異常に上昇したときには、確実に作動する防爆機
構を備えたマンガン乾電池を提供することを目的とす
る。
SUMMARY OF THE INVENTION In view of the above, the present invention provides a manganese dry battery having an explosion-proof mechanism which is excellent in liquid leakage resistance and which operates reliably when the internal pressure of the battery rises abnormally due to misuse. The purpose is to provide.

【0004】[0004]

【課題を解決するための手段】本発明のマンガン乾電池
は、負極亜鉛缶の開口部を封口する合成樹脂成形物から
なる封口体が、炭素棒を貫通させる内筒、及び内筒と連
結部により連結された外筒を有し、前記外筒が炭素棒の
頂部に嵌合する正極端子板の周縁部と負極亜鉛缶の開口
端との間に締め付けられて負極亜鉛缶を密封したマンガ
ン乾電池であって、前記封口体の内筒の上部外面に切り
欠き部を設けて薄肉部を形成し、かつ前記成形物のウエ
ルドラインがこの薄肉部の略中心部に位置することを特
徴とする。前記薄肉部におけるウエルドライン形成部
は、さらに薄肉となっていることが好ましい。
According to the manganese dry battery of the present invention, a sealing body made of a synthetic resin molding for sealing an opening of a negative electrode zinc can is formed by an inner cylinder through which a carbon rod passes, and an inner cylinder and a connecting portion. A manganese dry battery having a connected outer cylinder, wherein the outer cylinder is fastened between the peripheral edge of the positive electrode terminal plate fitted to the top of the carbon rod and the open end of the negative electrode zinc can to seal the negative electrode zinc can. In addition, a cutout portion is provided on the upper outer surface of the inner cylinder of the sealing body to form a thin portion, and a weld line of the molded product is located substantially at the center of the thin portion. It is preferable that the weld line forming portion in the thin portion is further thinner.

【0005】[0005]

【発明の実施の形態】本発明のマンガン乾電池は、上記
のように、負極亜鉛缶の開口部を封口する封口体の炭素
棒を貫通させた内筒の上部に薄肉部を設け、電池内圧上
昇時にその薄肉部に亀裂を生じさせ、そこからガスを放
出する防爆機構を採っている。そして、前記薄肉部のほ
ぼ中心に、封口体成形物のウエルドラインが位置するよ
うにしている。このウエルドラインの部分は、局部的に
亀裂に対する強度が下がっているから、内圧が異常に上
昇したときには容易に亀裂を生じガスを逃がすことがで
きる。前記の薄肉部は、ウエルドラインの部分でさらに
薄肉になっていると、圧力上昇時の亀裂発生がより容易
となる。
BEST MODE FOR CARRYING OUT THE INVENTION The manganese dry battery of the present invention is provided with a thin portion at the upper part of the inner cylinder through which the carbon rod of the sealing body for sealing the opening of the negative electrode zinc can is inserted, as described above, to increase the internal pressure of the battery. An explosion-proof mechanism that sometimes cracks the thin part and releases gas from it. The weld line of the molded product of the sealing body is positioned substantially at the center of the thin portion. Since the weld line portion has a locally reduced strength against cracks, when the internal pressure rises abnormally, cracks can easily occur to allow gas to escape. If the thin portion is further thinned at the weld line, cracks can easily be generated when the pressure increases.

【0006】以下、本発明の実施の形態を詳細に説明す
る。図1は本発明による乾電池を示す。1は有底円筒形
の負極亜鉛缶を表す。この亜鉛缶1内にはセパレータ2
を介して二酸化マンガンを主とする正極合剤3が充填さ
れている。正極合剤3の中心部には炭素棒4が挿入され
ている。5は正極合剤上に載せた鍔紙である。亜鉛缶1
の開口部を封口するポリエチレンなどからなる封口体1
0は、内筒11、外筒12及び内筒と外筒を連結する連
結部13から構成され、外筒12の上端部が、炭素棒4
の頂部に嵌合させた正極端子板6の外周縁部と亜鉛缶1
の開口端のかしめ部とにより締めつけられ、亜鉛缶1の
開口部を密封している。内筒11の下端と炭素棒4との
間及び外筒12の下端と亜鉛缶1の内壁面との間にはア
スファルトなどのシール剤8が塗着されている。正極端
子板6は、ガス排出孔7を有する。
Hereinafter, embodiments of the present invention will be described in detail. FIG. 1 shows a battery according to the present invention. Reference numeral 1 denotes a bottomed cylindrical negative electrode zinc can. In the zinc can 1, a separator 2 is provided.
Through which the positive electrode mixture 3 mainly composed of manganese dioxide is filled. A carbon rod 4 is inserted into the center of the positive electrode mixture 3. Reference numeral 5 denotes a flange paper placed on the positive electrode mixture. Zinc can 1
1 made of polyethylene or the like to seal the opening
Reference numeral 0 denotes an inner cylinder 11, an outer cylinder 12, and a connecting portion 13 connecting the inner cylinder and the outer cylinder.
Outer peripheral edge of positive electrode terminal plate 6 fitted to the top of
Of the zinc can 1 to seal the opening of the zinc can 1. A sealant 8 such as asphalt is applied between the lower end of the inner cylinder 11 and the carbon rod 4 and between the lower end of the outer cylinder 12 and the inner wall surface of the zinc can 1. The positive electrode terminal plate 6 has a gas discharge hole 7.

【0007】封口体10についてさらに詳しく説明する
と、従来例では連結部13の一部、例えば13aで示す
環状の部分の肉厚を図よりさらに薄くしていたが、本発
明では内筒11の上半分の外面の一部を切り欠いて薄肉
部11aを設けている。そして、薄肉部11aの中心部
14にウエルドラインが位置するようにしている。すな
わち、封口体10を成形するための金型のゲート位置1
5を、図2に示すように、金型の中心を外れた位置に設
け、成形時に、金型に注入された溶融状態の樹脂が、ゲ
ート位置15から図2に示す封口体の中心孔の反対側に
回り込むように流れさせる。そうすると、前記中心孔を
挟んでゲート位置15の反対側に、図2に一点鎖線で示
す位置にウエルドラインが発生する。この例では、薄肉
部11aの中心部14がさらに薄肉となるようにしてい
る。このような構成の乾電池においては、電池内圧が異
常に上昇すると、ガスは封口体10の連結部13を押し
上げ、内筒11と炭素棒4との間に隙間をつくって出よ
うとし、これがために薄肉部11aに亀裂が生じる。従
って、ガスはその亀裂部分から封口体上に抜け、正極端
子板6のガス排出孔7から外部へ出る。
The sealing body 10 will be described in more detail. In the prior art, the thickness of a part of the connecting portion 13, for example, the annular portion indicated by reference numeral 13 a is made thinner than the figure, but in the present invention, the thickness of the inner cylinder 11 is increased. A thin portion 11a is provided by cutting out a part of the half outer surface. The weld line is located at the center 14 of the thin portion 11a. That is, the gate position 1 of the mold for molding the sealing body 10
2 is provided at a position off the center of the mold as shown in FIG. 2, and the molten resin injected into the mold during molding is moved from the gate position 15 to the center hole of the sealing body shown in FIG. Let it flow around the other side. Then, a weld line is generated at a position indicated by a dashed line in FIG. 2 on the opposite side of the gate position 15 across the center hole. In this example, the central portion 14 of the thin portion 11a is made thinner. In the dry battery having such a configuration, when the battery internal pressure rises abnormally, the gas pushes up the connecting portion 13 of the sealing body 10 and tries to leave a gap between the inner cylinder 11 and the carbon rod 4, and this causes a problem. Then, a crack occurs in the thin portion 11a. Therefore, the gas escapes from the cracked portion onto the sealing body and exits through the gas exhaust hole 7 of the positive electrode terminal plate 6.

【0008】上記のように封口体10の炭素棒4を抱持
する内筒11の上部に、成形物のウエルドラインがほぼ
中心に位置するように薄肉部11aを設けることによ
り、ガス圧上昇時には、連結部13が押し上げられるこ
とと相俟って、薄肉部11aは確実に亀裂を発生して防
爆機構として機能する。単4形乾電池を例にすると、ポ
リエチレン製封口体の場合、薄肉部11aの肉圧は0.
5〜0.8mm、幅は1.0〜3.0mm、長さは内筒
の長さ2.0〜3.5mmに対して0.5〜1.8mm
の範囲が好ましい。ウェルドラインが位置する薄肉部の
中心部14の肉厚は0.45〜0.75mmの範囲が適
当である。
As described above, the thin portion 11a is provided on the upper portion of the inner cylinder 11 holding the carbon rod 4 of the sealing body 10 so that the weld line of the molded product is located substantially at the center. Combined with the fact that the connecting portion 13 is pushed up, the thin portion 11a surely cracks and functions as an explosion-proof mechanism. Taking a AAA battery as an example, in the case of a polyethylene sealing body, the wall pressure of the thin portion 11a is 0.1 mm.
5 to 0.8 mm, width 1.0 to 3.0 mm, length 0.5 to 1.8 mm for the length of the inner cylinder 2.0 to 3.5 mm
Is preferable. The thickness of the central portion 14 of the thin portion where the weld line is located is suitably in the range of 0.45 to 0.75 mm.

【0009】[0009]

【発明の効果】以上のように本発明によれば、耐漏液性
に優れるとともに、万一電池内圧が異常に上昇したとき
には、確実に作動する防爆機構を備えたマンガン乾電池
が得られる。
As described above, according to the present invention, it is possible to obtain a manganese dry battery having an excellent explosion-proof mechanism which is excellent in liquid leakage resistance and operates reliably when the internal pressure of the battery rises abnormally.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の一実施例におけるマンガン乾電池の一
部を切り欠いた正面図である。
FIG. 1 is a partially cutaway front view of a manganese dry battery according to one embodiment of the present invention.

【図2】同乾電池の封口体の平面図である。FIG. 2 is a plan view of a sealing body of the dry battery.

【図3】同封口体の要部の斜視図である。FIG. 3 is a perspective view of a main part of the sealing body.

【符号の説明】[Explanation of symbols]

1 負極亜鉛缶 2 セパレータ 3 正極合剤 4 炭素棒 5 鍔紙 6 正極端子板 7 ガス排出孔 8 シール剤 9 外装ラベル 10 封口体 11 内筒、11a 薄肉部 12 外筒 13 連結部 14 薄肉部の中心部 DESCRIPTION OF SYMBOLS 1 Negative electrode zinc can 2 Separator 3 Positive electrode mixture 4 Carbon rod 5 Flange paper 6 Positive electrode terminal board 7 Gas exhaust hole 8 Sealing agent 9 Exterior label 10 Sealing body 11 Inner cylinder, 11a Thin part 12 Outer cylinder 13 Connection part 14 Thin part Central part

───────────────────────────────────────────────────── フロントページの続き (72)発明者 荻野 桂治 大阪府門真市大字門真1006番地 松下電器 産業株式会社内 Fターム(参考) 5H011 AA13 FF02 GG01 HH02 JJ03 JJ04 5H012 AA01 BB04 DD02 DD03 DD05 DD17 EE01 FF01 GG01 JJ01 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Keiji Ogino 1006 Kazuma Kadoma, Kadoma City, Osaka Prefecture F-term (reference) 5H011 AA13 FF02 GG01 HH02 JJ03 JJ04 5H012 AA01 BB04 DD02 DD03 DD05 DD17 EE01 FF01 GG01 JJ01

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 負極亜鉛缶の開口部を封口する合成樹脂
成形物からなる封口体が、炭素棒を貫通させる内筒、及
び内筒と連結部により連結された外筒を有し、前記外筒
が炭素棒の頂部に嵌合する正極端子板の周縁部と負極亜
鉛缶の開口端との間に締め付けられて負極亜鉛缶を密封
したマンガン乾電池であって、前記封口体の内筒の上部
外面に切り欠き部を設けて薄肉部を形成し、かつ前記成
形物のウエルドラインがこの薄肉部の略中心部に位置す
ることを特徴とするマンガン乾電池。
1. A sealing body made of a synthetic resin molded article for closing an opening of a negative electrode zinc can having an inner cylinder through which a carbon rod penetrates, and an outer cylinder connected to the inner cylinder by a connecting portion. A manganese dry battery in which a tube is fastened between a peripheral portion of a positive electrode terminal plate fitted to a top portion of a carbon rod and an open end of a negative electrode zinc can to seal a negative electrode zinc can, and a top portion of an inner cylinder of the sealing body A manganese dry battery, wherein a notch portion is provided on an outer surface to form a thin portion, and a weld line of the molded product is located substantially at the center of the thin portion.
【請求項2】 前記薄肉部におけるウエルドライン形成
部がさらに薄肉となっている請求項1記載のマンガン乾
電池。
2. The manganese dry battery according to claim 1, wherein a weld line forming portion in the thin portion is further thinned.
JP11125135A 1999-04-30 1999-04-30 Manganese dry battery Pending JP2000315486A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11125135A JP2000315486A (en) 1999-04-30 1999-04-30 Manganese dry battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11125135A JP2000315486A (en) 1999-04-30 1999-04-30 Manganese dry battery

Publications (1)

Publication Number Publication Date
JP2000315486A true JP2000315486A (en) 2000-11-14

Family

ID=14902737

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11125135A Pending JP2000315486A (en) 1999-04-30 1999-04-30 Manganese dry battery

Country Status (1)

Country Link
JP (1) JP2000315486A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002084762A1 (en) * 2001-04-11 2002-10-24 Matsushita Electric Industrial Co., Ltd. Manganese dry battery
JP2004134168A (en) * 2002-10-09 2004-04-30 Fdk Corp Alkaline dry battery
CN106997027A (en) * 2017-04-29 2017-08-01 合肥国轩高科动力能源有限公司 Lithium cell explosion-proof valve resistance to compression testing arrangement
JP2019053934A (en) * 2017-09-18 2019-04-04 タイガースポリマー株式会社 Explosion-proof valve body for sealed electrochemical device
CN109920953A (en) * 2019-03-27 2019-06-21 蜂巢能源科技有限公司 Battery pack explosion-proof valve, battery pack and vehicle
JP2020072051A (en) * 2018-11-02 2020-05-07 タイガースポリマー株式会社 Explosion proof valve structure of closed electrochemical device
WO2023162333A1 (en) * 2022-02-25 2023-08-31 日本碍子株式会社 Secondary battery and secondary battery module

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002084762A1 (en) * 2001-04-11 2002-10-24 Matsushita Electric Industrial Co., Ltd. Manganese dry battery
US7169507B2 (en) 2001-04-11 2007-01-30 Matsushita Electric Industrial Co., Ltd. Manganese dry battery
JP2004134168A (en) * 2002-10-09 2004-04-30 Fdk Corp Alkaline dry battery
JP4677168B2 (en) * 2002-10-09 2011-04-27 Fdk株式会社 Alkaline battery
CN106997027A (en) * 2017-04-29 2017-08-01 合肥国轩高科动力能源有限公司 Lithium cell explosion-proof valve resistance to compression testing arrangement
JP2019053934A (en) * 2017-09-18 2019-04-04 タイガースポリマー株式会社 Explosion-proof valve body for sealed electrochemical device
JP2020072051A (en) * 2018-11-02 2020-05-07 タイガースポリマー株式会社 Explosion proof valve structure of closed electrochemical device
JP7182995B2 (en) 2018-11-02 2022-12-05 タイガースポリマー株式会社 Explosion-proof valve structure for closed electrochemical devices
CN109920953A (en) * 2019-03-27 2019-06-21 蜂巢能源科技有限公司 Battery pack explosion-proof valve, battery pack and vehicle
CN109920953B (en) * 2019-03-27 2021-11-19 蜂巢能源科技有限公司 Battery pack explosion-proof valve, battery pack and vehicle
WO2023162333A1 (en) * 2022-02-25 2023-08-31 日本碍子株式会社 Secondary battery and secondary battery module

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