JP2000238443A - Thermal transfer acceptive paper - Google Patents

Thermal transfer acceptive paper

Info

Publication number
JP2000238443A
JP2000238443A JP11041713A JP4171399A JP2000238443A JP 2000238443 A JP2000238443 A JP 2000238443A JP 11041713 A JP11041713 A JP 11041713A JP 4171399 A JP4171399 A JP 4171399A JP 2000238443 A JP2000238443 A JP 2000238443A
Authority
JP
Japan
Prior art keywords
thermal transfer
paper
layer
intermediate layer
receiving
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11041713A
Other languages
Japanese (ja)
Inventor
Yasumichi Kuga
康通 久我
Katsunori Hiroishi
勝徳 広石
Motoi Orihara
基 折原
Yoshifumi Noge
由文 野毛
Yukihiro Yuyama
幸博 湯山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ricoh Co Ltd
Original Assignee
Ricoh Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ricoh Co Ltd filed Critical Ricoh Co Ltd
Priority to JP11041713A priority Critical patent/JP2000238443A/en
Publication of JP2000238443A publication Critical patent/JP2000238443A/en
Pending legal-status Critical Current

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  • Credit Cards Or The Like (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

PROBLEM TO BE SOLVED: To improve the resolution and solid uniformity (prevention of white voids of a solid section) of a thermal transfer acceptive paper and prevent the blocking of magnetic cards as one of the purposes of use. SOLUTION: In a thermal transfer acceptive paper formed of an intermediate layer composed mainly of a thermoplastic resin and an acceptive layer composed mainly of a white pigment and a thermoplastic resin laminated together successively on a base, or in a thermal transfer acceptive paper with a magnetic recording layer formed on the lower face of the base, a thermoplastic resin of 10 deg.C or lower glass transition temperature (Tg) is used for the intermediate layer. The ratio of the white pigment in the intermediate layer is 0.1-0.5 to 1 (one) thermoplastic resin.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、熱溶融型熱転写方
式に用いられる熱転写用受容紙に関し、特に乗車券、定
期券、通行券などの磁気カード類およびラベル類に適し
た熱転写用受容紙に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a thermal transfer receiving paper used in a hot-melt type thermal transfer system, and more particularly to a thermal transfer receiving paper suitable for magnetic cards and labels such as tickets, commuter passes, and pass tickets. .

【0002】[0002]

【従来の技術】熱溶融型熱転写記録方式は、支持体上に
熱転写インクを擁する熱転写リボンの上からサーマルヘ
ッドにより画像様にドット加熱し、該インクを溶融さ
せ、転写材上に転写するものである。近年、その用途は
益々広がり、バーコードラベル等のスーパー、コンビニ
等の商品ラベル、衣料品のラベル等にも応用され、これ
らはプリンター等と共に一大用途となっている。中でも
注目されているのは、磁気回数券、道路通行券、定期
券、プリペードカード等の磁気カード類である。これら
の構造は支持体の一方の面に磁気記録層を有し、他方の
面に熱転写用の受容層を有するもので、全層の厚味が百
〜数千μmと厚いのが特徴である。これら各用途におい
ては市場の要求が益々高度化しており、特に印字画像品
質、解像度、堅牢性について従来より更に高い品質が要
求されている。
2. Description of the Related Art In a thermal melting type thermal transfer recording system, dots are imagewise heated by a thermal head from above a thermal transfer ribbon having thermal transfer ink on a support, and the ink is melted and transferred onto a transfer material. is there. In recent years, its use has been increasingly widespread, and it has been applied to supermarkets such as barcode labels, merchandise labels such as convenience stores, clothing labels, and the like, and these have become a major use together with printers and the like. Of particular interest are magnetic cards such as magnetic coupons, road toll tickets, commuter passes, and prepaid cards. These structures have a magnetic recording layer on one side of the support and a receiving layer for thermal transfer on the other side, and are characterized in that the thickness of all layers is as thick as one hundred to several thousand μm. . In each of these applications, the market requirements are becoming increasingly sophisticated, and in particular, higher quality is required for the printed image quality, resolution, and robustness.

【0003】このような熱転写リボンのインクは、従
来、ワックスを主成分としたタイプが主流で、比較的熱
感度が高い反面、画像の堅牢性が低い欠点がある。一
方、画像堅牢性が高いインクとして熱可塑性樹脂を主成
分としたレジンタイプの熱転写リボンが提案されている
が、熱感度が低く、画像の欠損が発生するなど転写均一
性の問題があった。以上のことから熱転写リボン(イン
クシート)には二つの大きな技術の流れとして、ワック
スタイプにより画像の堅牢性の向上を図るものとレジン
タイプにより高感度化を図るものとがある。
Conventionally, the ink of such a thermal transfer ribbon is mainly of a type containing wax as a main component and has a relatively high thermal sensitivity, but has a drawback of low image fastness. On the other hand, a resin-type thermal transfer ribbon containing a thermoplastic resin as a main component has been proposed as an ink having high image fastness. However, there has been a problem with transfer uniformity such as low thermal sensitivity and image defects. From the above, there are two major technical flows of the thermal transfer ribbon (ink sheet), one is to improve the robustness of an image by a wax type, and the other is to increase the sensitivity by a resin type.

【0004】[0004]

【発明が解決しようとする課題】上述の問題に対して熱
転写リボン側からの検討、改良が加えられているが、加
工紙を用いることが許される応用分野に限られており、
受容紙側での改良、特に画像品質―ベタ画像均一性、解
像度に対しての改良が進められている。例えば、受容紙
に上質紙を用い、さらに上質紙をスーパーカレンダー等
を用いて平滑化することが行われている。通常の上質紙
は王研式平滑度が10〜50秒であるが、カレンダー処
理により、また元々100秒以上のものもあり、該平滑
度が100秒以上になると画像品質がかなり改良される
が、十分ではなかった。すなわち、100秒以上の上質
紙を用いても画像堅牢性が改良されたワックスタイプや
感度が改良されたレジンタイプの熱転写リボンを用いた
場合、いずれもベタ部の白抜けがあり、ベタ画像均一性
が悪く、解像度も悪かった。これらの問題は従来より高
解像のサーマルヘッドである16ドット/mm、32ド
ット/mmのヘッド下ではより顕著となる。また、前述
のように磁気カード類は厚みが厚いため、ヘッドとの密
着性が悪く、より顕著となる。
The above problems have been studied and improved from the side of the thermal transfer ribbon, but are limited to the application fields where processed paper is allowed.
Improvements have been made on the receiving paper side, especially on image quality-solid image uniformity and resolution. For example, high quality paper is used as the receiving paper, and the high quality paper is further smoothed using a super calender or the like. Normal high-quality paper has an Oken type smoothness of 10 to 50 seconds, but there are also those originally having a smoothness of 100 seconds or more due to calendar processing. When the smoothness exceeds 100 seconds, image quality is considerably improved. Was not enough. That is, when a wax type having improved image fastness or a resin type thermal transfer ribbon having improved sensitivity is used even when using high quality paper for 100 seconds or more, all of the solid portions have white spots and solid image uniformity. Poor quality and poor resolution. These problems become more remarkable under a 16-dot / mm or 32-dot / mm head which is a high-resolution thermal head. Further, as described above, since the magnetic cards are thick, they have poor adhesion to the head and become more remarkable.

【0005】このような問題を解決する方法として、特
開平8−183262号公報には、受容層に吸油量50
〜200ml/100gのフィラーを含有させた熱転写
記録磁気券紙が記載されている。これはインクの吸油性
および浸透性を上げるなど、インクの転写性を上げるた
めに吸油量の大きいフィラーを含有したバインダー層を
設けるもので、この構成により解像度、ベタ均一性を向
上させることができる。しかしながら、特に磁気カード
類ではまだ十分ではなかった。また、特開平9−216
474号公報には、多孔質炭酸カルシウムを含有する熱
転写プリンター用受容紙が記載されている。これも、解
像度、ベタ均一性(ベタ白抜け)がまだ十分ではなく、
特に磁気カード類では十分でなかった。ちなみに高速に
なり受容エネルギーが少なくなるとレジンタイプでは感
度が低下した。
[0005] As a method for solving such a problem, Japanese Patent Application Laid-Open No. 8-183262 discloses an oil absorbing amount of 50 in the receiving layer.
A thermal transfer recording magnetic ticket containing ~ 200 ml / 100 g of filler is described. This is to provide a binder layer containing a filler having a large amount of oil absorption in order to improve the transferability of the ink, such as increasing the oil absorbency and permeability of the ink. With this configuration, the resolution and solid uniformity can be improved. . However, magnetic cards were not yet enough. Also, JP-A-9-216
No. 474 describes a receiving paper for a thermal transfer printer containing porous calcium carbonate. Again, the resolution and solid uniformity (solid white spots) are not yet enough,
In particular, magnetic cards were not sufficient. Incidentally, when the speed was increased and the received energy was reduced, the sensitivity was lowered in the resin type.

【0006】一方、磁気カード、磁気券紙等の磁気カー
ド類における熱転写用受容紙は、保管時、機内装填時、
輸送時は、いずれも巻装された状態である。この場合、
磁気記録層と支持体層の背面とが圧縮されながら接する
ため、また、リボンが曲面状になっているため磁気記録
層表面と受容層表面とがくっつき易い場合、どちらかの
層が剥がれる現象が起こる。これをブロッキングとい
う。磁気記録層と支持体との接着状態がもろい場合は剥
がれ易く、ブロッキングが特に顕著となる。
On the other hand, the receiving paper for thermal transfer in magnetic cards such as a magnetic card and a magnetic ticket paper is used for storage, loading in the machine,
At the time of transportation, both are in a wound state. in this case,
When the surface of the magnetic recording layer and the surface of the receiving layer tend to stick together because the magnetic recording layer and the back surface of the support layer are in contact with each other while being compressed, and the ribbon is curved, the phenomenon that one of the layers peels off may occur. Occur. This is called blocking. When the adhesion state between the magnetic recording layer and the support is brittle, the magnetic recording layer is easily peeled off, and the blocking is particularly remarkable.

【0007】本発明は上記背景に鑑みてなされたもの
で、受容紙側からの画像品質の向上、すなわち、熱転写
用受容紙における解像度向上とベタ均一性の向上(ベタ
部白抜け防止)、また磁気カード類におけるブロッキン
グの防止を図ることを目的とする。
The present invention has been made in view of the above background, and improves the image quality from the receiving paper side, that is, improves the resolution and the solid uniformity of the receiving paper for thermal transfer (prevents the solid portion from being blanked out). An object of the present invention is to prevent blocking in magnetic cards.

【0008】[0008]

【課題を解決するための手段】本発明によれば、第一
に、基材上に熱可塑性樹脂を主成分とする中間層、白色
顔料と熱可塑性樹脂を主成分とする受容層を順次積層し
た熱転写用受容紙において、該中間層の熱可塑性樹脂が
ガラス転移温度(Tg)が10℃以下であることを特徴
とする熱転写用受容紙が提供される。
According to the present invention, first, an intermediate layer mainly composed of a thermoplastic resin and a receiving layer mainly composed of a white pigment and a thermoplastic resin are sequentially laminated on a base material. In the above-described receiving paper for thermal transfer, there is provided a receiving paper for thermal transfer, wherein the thermoplastic resin of the intermediate layer has a glass transition temperature (Tg) of 10 ° C. or less.

【0009】第二に、上記第一に記載した熱転写用受容
紙において、該中間層が白色顔料を含有することを特徴
とする熱転写用受容紙が提供される。
Secondly, there is provided a thermal transfer receiving paper according to the first aspect, wherein the intermediate layer contains a white pigment.

【0010】第三に、上記第二に記載した熱転写用受容
紙において、該中間層の白色顔料の割合が熱可塑性樹脂
1に対して0.1〜0.5であることを特徴とする熱転
写用受容紙が提供される。
Thirdly, in the thermal transfer receiving paper described in the second aspect, the ratio of the white pigment in the intermediate layer is 0.1 to 0.5 with respect to the thermoplastic resin 1. A receiving paper is provided.

【0011】第四に、上記第一に記載した熱転写用受容
紙において、該受容層の表面が王研式平滑度が300秒
以上であることを特徴とする熱転写用受容紙が提供され
る。
Fourthly, there is provided a thermal transfer receiving paper according to the first aspect, wherein the surface of the receiving layer has an Oken type smoothness of 300 seconds or more.

【0012】第一〜第四に記載した熱転写用受容紙にお
いて、該受容層側とは反対側に強磁性体と熱可塑性樹脂
を主成分とする磁気記録層を設けたことを特徴とする熱
転写用受容紙が提供される。
The thermal transfer receiving paper according to any one of the first to fourth aspects, characterized in that a magnetic recording layer mainly composed of a ferromagnetic material and a thermoplastic resin is provided on the side opposite to the side of the receiving layer. A receiving paper is provided.

【0013】以下に本発明を詳細に説明する。上述のよ
うに、本発明は基材上に熱可塑性樹脂を主成分とする中
間層、白色顔料と熱可塑性樹脂を主成分とする受容層を
順次積層した熱転写用受容紙において、該中間層の熱可
塑性樹脂としてガラス転移温度(Tg)が10℃以下の
ものを用いるものであり、この構成によれば該中間層の
緩衝作用によりサーマルヘッドと熱転写インクリボンと
の密着性が向上し、転写性が良好となり、ベタ均一性が
向上すると共に解像度が向上した熱転写用受容紙を得る
ことができる。また基材下面に磁気記録層を設けた構成
では該中間層の緩衝作用により保存時の曲面での圧縮接
触時の剥がれが防止され、また基材との接着性が向上す
ることによりブロッキングが防止され、磁気カードに応
用できる熱転写用受容紙を得ることができる。
Hereinafter, the present invention will be described in detail. As described above, the present invention relates to a thermal transfer receiving paper in which an intermediate layer mainly composed of a thermoplastic resin and a receiving layer mainly composed of a white pigment and a thermoplastic resin are sequentially laminated on a base material. A thermoplastic resin having a glass transition temperature (Tg) of 10 ° C. or less is used. According to this configuration, the adhesiveness between the thermal head and the thermal transfer ink ribbon is improved by the buffering action of the intermediate layer, and the transfer property is improved. , And a receiving paper for thermal transfer with improved solid uniformity and improved resolution can be obtained. In the configuration in which the magnetic recording layer is provided on the lower surface of the base material, the buffering action of the intermediate layer prevents peeling during compression contact on a curved surface during storage, and also prevents blocking due to improved adhesion with the base material. Thus, a thermal transfer receiving paper applicable to a magnetic card can be obtained.

【0014】また、上記中間層に白色顔料が含有される
ことにより、熱転写用受容紙がより高白色となり、熱転
写インクリボンからの転写層がより鮮明になる。該中間
層に白色顔料を添加してもよく、その場合は、白色顔料
の中間層における割合は、熱可塑性樹脂1に対し、0.
1〜0.5とすることにより接着性を損なわずにさらに
高白色化された熱転写用受容紙が得られる。そして受容
層表面を300秒以上とすることにより、より高解像度
の画像形成が可能となる。
Further, when the intermediate layer contains a white pigment, the receiving paper for thermal transfer becomes higher in white, and the transfer layer from the thermal transfer ink ribbon becomes clearer. A white pigment may be added to the intermediate layer. In that case, the ratio of the white pigment in the intermediate layer to the thermoplastic resin 1 is 0.1 to 0.1.
By setting the ratio to 1 to 0.5, it is possible to obtain a heat-transfer receiving paper having a higher whiteness without impairing the adhesiveness. By setting the surface of the receiving layer to 300 seconds or longer, it is possible to form a higher-resolution image.

【0015】ガラス転移温度(Tg)が10℃以下の熱
可塑性樹脂からなる中間層によれば、どのようにして上
記問題が解決されるかについて述べると、一つにはTg
が10℃以下の熱可塑性樹脂は常温でゴム状の弾性を有
する樹脂であり、このことにより熱転写用受容紙の巻装
時、受容層と支持体層の緩衝材として働き、保存時の曲
面での圧縮接触時の剥がれを防止する。また、中間層が
なければ顔料(フィラー)とバインダーからなる層が受
容層であり、フィラー(通常は無機粒子)がある分、接
着性が劣るのに対し、バインダーのみからなる層と支持
体と接するため、接着性が向上し、もって剥がれ、すな
わちブロッキングが起こらなくなる。また、中間層は弾
性層として働くため、厚みの厚いカード類においてもサ
ーマルヘッドの加圧に対してヘッドになじむような形で
微小変形するため密着性がよくなり転写性が向上し画像
濃度が上がり、ベタ均一性も上がるという効果が得られ
るものと思われる。
The following describes how the above problem can be solved according to the intermediate layer made of a thermoplastic resin having a glass transition temperature (Tg) of 10 ° C. or less.
Is a resin having a rubber-like elasticity at room temperature, which acts as a cushioning material between the receiving layer and the support layer when the receiving paper for thermal transfer is wound. Prevents peeling during compression contact. If there is no intermediate layer, the layer composed of the pigment (filler) and the binder is the receiving layer, and the filler (usually, inorganic particles) has poor adhesion because of the presence of the filler (usually inorganic particles). Due to the contact, the adhesiveness is improved, and peeling, that is, blocking does not occur. In addition, since the intermediate layer acts as an elastic layer, even for thick cards, it is slightly deformed in such a manner as to conform to the head when pressed by the thermal head, so that the adhesion is improved, the transferability is improved, and the image density is improved. It is considered that the effect of increasing the solid uniformity is obtained.

【0016】[0016]

【発明の実施の形態】以下に本発明の実施の形態につい
て説明する。図1は本発明の熱転写用受容紙の基本構成
を示すものである。図2は磁気記録方式に使用する場合
で、紙基材1上に中間層2、受容層3を設け、基材1の
下側に磁気記録層4が設けられている。これら各層につ
いて以下に詳しく説明する。
Embodiments of the present invention will be described below. FIG. 1 shows the basic configuration of the receiving paper for thermal transfer of the present invention. FIG. 2 shows a case where the magnetic recording system is used, in which an intermediate layer 2 and a receiving layer 3 are provided on a paper base material 1, and a magnetic recording layer 4 is provided below the base material 1. Each of these layers will be described in detail below.

【0017】(中間層)本発明における中間層の主成分
である熱可塑性樹脂としては、慣用の種々のものを使用
することができ、ポリアクリル系樹脂、ポリエステル系
樹脂、ポリスチレン系樹脂、ポリウレタン系樹脂、ポリ
ビニル系樹脂、エポキシ樹脂が挙げられ、これらのホモ
ポリマーおよび共重合体が使用できる。これらを単独、
あるいは2種類以上を混合してして用いることができる
が、熱可塑性樹脂のガラス転移温度(Tg)が10℃以
下のものを使用する。このような熱可塑性樹脂を採用す
ることにより熱転写インクリボンとの緩衝作用により、
また紙基材との接着性が付与されることによりブロッキ
ング防止が行われる。
(Intermediate layer) As the thermoplastic resin which is a main component of the intermediate layer in the present invention, various conventional resins can be used, and polyacrylic resin, polyester resin, polystyrene resin, polyurethane resin can be used. Resins, polyvinyl resins and epoxy resins can be used, and homopolymers and copolymers thereof can be used. These alone,
Alternatively, a mixture of two or more kinds can be used, and a thermoplastic resin having a glass transition temperature (Tg) of 10 ° C. or less is used. By adopting such a thermoplastic resin, due to the buffering action with the thermal transfer ink ribbon,
In addition, blocking is prevented by imparting adhesiveness to the paper substrate.

【0018】また、該中間層に接着性を損なわない程度
に白色顔料が含有されていてもよい。この場合、熱転写
用受容紙がより高白色となり、転写画像がより鮮明に表
示される。中間層に含有される白色の顔料(フィラー)
としては、例えば、炭酸カルシウム、シリカ、酸化チタ
ン、水酸化アルミニウム、クレー、焼成クレー、ケイ酸
マグネシウム、炭酸マグネシウム、ホワイトカーボン、
酸化亜鉛、硫酸バリウム、表面処理された炭酸カルシウ
ムやシリカ、尿素−ホルマリン樹脂、スチレン/メタク
リル酸共重合体、ポリスチレン等の微粉末等が使用可能
であり、これらの単独または2種以上混合して使用して
もよい。この中間層中の白色顔料の割合が熱可塑性樹脂
1に対し、0.1〜0.5とすることが最適であり、接
着性を損なわずに高白色化された熱転写用受容紙とな
る。白色顔料の割合が0.1未満の場合、白色性に効果
が少なく、0.5を超える場合は接着性が悪化してく
る。
The intermediate layer may contain a white pigment to such an extent that the adhesion is not impaired. In this case, the receiving paper for thermal transfer becomes higher white, and the transferred image is displayed more clearly. White pigment (filler) contained in the intermediate layer
As, for example, calcium carbonate, silica, titanium oxide, aluminum hydroxide, clay, calcined clay, magnesium silicate, magnesium carbonate, white carbon,
Fine powders such as zinc oxide, barium sulfate, surface-treated calcium carbonate and silica, urea-formalin resin, styrene / methacrylic acid copolymer, and polystyrene can be used. These powders can be used alone or in combination of two or more. May be used. Optimally, the ratio of the white pigment in the intermediate layer to the thermoplastic resin 1 is 0.1 to 0.5, so that the heat transfer receiving paper has a high whiteness without impairing the adhesiveness. When the ratio of the white pigment is less than 0.1, the effect on whiteness is small, and when it exceeds 0.5, the adhesiveness is deteriorated.

【0019】紙基材への中間層の付着量は、乾燥重量で
1g/m〜30g/mの範囲が好ましく、1g/m
未満では上記した本発明による効果が不十分であり、
30g/mを超えると受容層にひび割れ等の欠陥が発
生し易くブロッキングが逆に悪くなる。
The coating weight of the intermediate layer to the paper substrate is preferably in the range of 1g / m 2 ~30g / m 2 by dry weight, 1 g / m
If it is less than 2 , the effect of the present invention described above is insufficient,
If it exceeds 30 g / m 2 , defects such as cracks are liable to occur in the receiving layer, and blocking is worsened.

【0020】(受容層)本発明において、受容層に含有
される白色顔料としては、中間層と同様のものが使用可
能であり、吸油量が高いものが好ましい。また、それぞ
れ単独または2種類以上混合しても使用することができ
る。受容層を構成する樹脂もまた中間層と同様のものが
使用可能である。受容層に含有される樹脂は熱転写イン
クシートの種類や使用用途によって種々選択可能だが、
ガラス転移点が40℃未満では高温保存時、表面に接着
性を帯びる場合が多く、ブロッキングなどが発生し易い
ため、ガラス転移点が40℃を超えるものが望ましい。
(Receiving Layer) In the present invention, as the white pigment contained in the receiving layer, those similar to the intermediate layer can be used, and those having high oil absorption are preferable. Further, they may be used alone or in combination of two or more. The same resin as the intermediate layer can be used for the resin constituting the receiving layer. The resin contained in the receiving layer can be variously selected depending on the type and use of the thermal transfer ink sheet,
If the glass transition point is lower than 40 ° C., the surface often has adhesiveness during high-temperature storage, and blocking and the like are likely to occur. Therefore, those having a glass transition point higher than 40 ° C. are desirable.

【0021】受容層における前記白色顔料と樹脂の割合
は、熱感度、白色性、ブロッキング性に関わり、白色顔
料対樹脂の含有比は、1:0.2〜1とすることが好ま
しい。水溶性樹脂を用いる場合は耐水化剤を用いてもよ
い。耐水化剤の具体例としては、例えば、ホルムアルデ
ヒド、グリオキザール、クロムミョウバン、メラミン、
メラミン−ホルムアルデヒド樹脂、ポリアミド樹脂、ポ
リアミド−エピクロルヒドリン樹脂等が挙げられる。
The ratio of the white pigment and the resin in the receiving layer relates to heat sensitivity, whiteness and blocking property, and the content ratio of the white pigment to the resin is preferably 1: 0.2 to 1. When a water-soluble resin is used, a waterproofing agent may be used. Specific examples of the water-proofing agent include, for example, formaldehyde, glyoxal, chrome alum, melamine,
Melamine-formaldehyde resin, polyamide resin, polyamide-epichlorohydrin resin and the like can be mentioned.

【0022】受容層の付着量は、乾燥重量で2g/m
〜30g/mの範囲が好ましく、2g/m未満では
転写画像のベタ画像の濃度ムラが目立つようになり、3
0g/mを超えると受容層にひび割れ等の欠陥が発生
し易くなり、中間層との接着性が悪くなり巻装保管時、
受容層が剥がれるブロッキング現象が起こる。受容層を
形成した後、スーパーキャレンダーなどで表面処理をし
て、受容層表面を王研式平滑度で300秒以上とするこ
とにより、より高解像度の画像形成が可能となる。
The amount of the receptor layer deposited was 2 g / m 2 on a dry weight basis.
-30 g / m 2 is preferable, and when it is less than 2 g / m 2 , density unevenness of a solid image of a transferred image becomes conspicuous,
When it exceeds 0 g / m 2 , defects such as cracks are liable to occur in the receiving layer, and the adhesiveness to the intermediate layer is deteriorated.
A blocking phenomenon occurs in which the receiving layer peels off. After the formation of the receiving layer, the surface is treated with a super calender or the like to make the surface of the receiving layer 300 seconds or more in Oken-type smoothness, so that a higher-resolution image can be formed.

【0023】(磁気記録層)本発明の磁気記録層に用い
る磁性体としては、バリウムフェライト、ストロンチウ
ムフェライト、Co−γ−Fe、γ−Fe
等の強磁性体粉体が使用される。また、磁性記録層に用
いる樹脂としては、慣用のものを使用でき、前述の中間
層、受容層と同様のものが使用可能である。
Examples of the magnetic material used in the magnetic recording layer of the (magnetic recording layer) In the present invention, barium ferrite, strontium ferrite, Co-γ-Fe 2 O 3, γ-Fe 2 O 3
Etc. are used. Further, as the resin used for the magnetic recording layer, a conventional resin can be used, and the same resin as the above-mentioned intermediate layer and receiving layer can be used.

【0024】[0024]

【実施例】以下実施例により本発明をさらに具体的に説
明する。以下の実施例および比較例で作製する熱転写用
受容紙は、次の紙基材、受容層、および磁性層を用い
た。なお、以下で示す部および%はいずれも重量基準で
ある。
The present invention will be described more specifically with reference to the following examples. The following paper base material, receiving layer, and magnetic layer were used for the receiving paper for thermal transfer produced in the following Examples and Comparative Examples. All parts and percentages shown below are based on weight.

【0025】 紙基材:坪量170g/mの上質紙 受容層:シリカ(吸油量50ml/100g) 100部 ポリビニルアルコール(固形分10%水溶液) 200部 水 500部 以上の組成からなる液を作製し、塗布量は乾燥重量で5
g/mとした。 磁気層:《バリウムフェライト分散液の作製(固形分50%)》 バリウムフェライト (保持力:2700Oe、平均粒径:0.6μm) 100部 ポリアクリル酸ソーダ(固形分20%水溶液) 10部 カーボンブラック(固形分38%分散液) 20部 水 90部 以上の組成からなる液をサンドグラインダーで24時間
分散して、下記エマルジョンと調合する。 《磁気塗料の作製》 バリウムフェライト分散液(固形分50%) 200部 塩化ビニリデンエマルジョン(固形分49%) 100部 水 80部 塗布量:乾燥重量50g/m
Paper base material: Fine paper having a basis weight of 170 g / m 2 Receptive layer: Silica (oil absorption: 50 ml / 100 g) 100 parts Polyvinyl alcohol (solid content 10% aqueous solution) 200 parts Water 500 parts A liquid having the above composition is prepared. Prepared and applied in dry weight of 5
g / m 2 . Magnetic layer: << Preparation of barium ferrite dispersion (solid content 50%) >> barium ferrite (holding power: 2700 Oe, average particle size: 0.6 μm) 100 parts Sodium polyacrylate (20% solid content aqueous solution) 10 parts carbon black (Dispersion of solid content 38%) 20 parts Water 90 parts A liquid having the above composition is dispersed by a sand grinder for 24 hours to prepare the following emulsion. << Preparation of magnetic paint >> Barium ferrite dispersion (solid content 50%) 200 parts Vinylidene chloride emulsion (solid content 49%) 100 parts Water 80 parts Coating amount: dry weight 50 g / m 2

【0026】〔実施例1〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設けた。さらに前述の受容層を設け、該受容
層平滑度が300s.となるようキャレンダー処理を行
い、熱転写用受容紙とした。 《中間層》 スチレン−アクリルエマルジョン (ガラス転移温度10℃、固形分50%) 100部
Example 1 An aqueous solution for coating an intermediate layer described below was prepared and applied on a paper substrate so that the dry weight was 4 g / m 2 , thereby providing an intermediate layer. Further, the above-mentioned receiving layer was provided, and the receiving layer had a smoothness of 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Interlayer >> Styrene-acryl emulsion (glass transition temperature 10 ° C, solid content 50%) 100 parts

【0027】〔実施例2〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設けた。さらに前述の受容層を設け、該受容
層平滑度が300s.となるようキャレンダー処理を行
い、熱転写用受容紙とした。 《中間層》 スチレン−ブタジエンエマルジョン (ガラス転移温度10℃、固形分50%) 100部
Example 2 The following intermediate layer coating aqueous solution was prepared and applied on a paper substrate so that the dry weight was 4 g / m 2, to provide an intermediate layer. Further, the above-mentioned receiving layer was provided, and the receiving layer had a smoothness of 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Intermediate layer >> Styrene-butadiene emulsion (glass transition temperature 10 ° C, solid content 50%) 100 parts

【0028】〔実施例3〕下記中間層塗布水溶液を作製
し、前記紙基材上に乾燥重量が4g/mとなるように
塗布し中間層を設けた。さらに前述の受容層を設け、該
受容層平滑度が300s.となるようキャレンダー処理
を行い、熱転写用受容紙とした。 《中間層》 スチレン−ブタジエンエマルジョン (ガラス転移温度0℃、固形分50%) 100部
Example 3 The following intermediate layer coating aqueous solution was prepared and applied on the paper substrate so that the dry weight was 4 g / m 2 to provide an intermediate layer. Further, the above-mentioned receiving layer was provided, and the receiving layer had a smoothness of 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Interlayer >> Styrene-butadiene emulsion (glass transition temperature: 0 ° C., solid content: 50%) 100 parts

【0029】〔実施例4〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設け、さらに前述の受容層を設けた。また、
紙基材のもう一方前述の磁気層を設けた。次いで該受容
層平滑度が300s.となるようキャレンダー処理を行
い、熱転写用受容紙とした。 《中間層》 シリカ(吸油量50ml/100g) 10部 スチレン−アクリルエマルジョン (ガラス転移温度10℃、固形分50%) 90部
Example 4 The following aqueous solution for coating an intermediate layer was prepared, applied to a paper substrate so that the dry weight was 4 g / m 2 , provided with an intermediate layer, and further provided with the above-mentioned receiving layer. Also,
The other magnetic layer of the paper base was provided. Next, the smoothness of the receiving layer was 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Intermediate layer >> Silica (oil absorption 50ml / 100g) 10 parts Styrene-acryl emulsion (glass transition temperature 10 ° C, solid content 50%) 90 parts

【0030】〔実施例5〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設け、さらに前述の受容層を設けた。また、
紙基材のもう一方の面に前述の磁気層を設けた。次いで
該受容層の平滑度が300s.となるようキャレンダー
処理を行い、熱転写用受容紙とした。 《中間層》 シリカ(吸油量50ml/100g) 50部 スチレン−アクリルエマルジョン (ガラス転移温度10℃、固形分50%) 50部
Example 5 The following intermediate layer coating aqueous solution was prepared, applied on a paper substrate so that the dry weight was 4 g / m 2 , provided with an intermediate layer, and further provided with the above-mentioned receiving layer. Also,
The aforementioned magnetic layer was provided on the other side of the paper base. Next, the smoothness of the receiving layer was 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Intermediate layer >> Silica (oil absorption 50ml / 100g) 50 parts Styrene-acryl emulsion (glass transition temperature 10 ° C, solid content 50%) 50 parts

【0031】〔実施例6〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設け、さらに前述の受容層を設けた。また、
紙基材のもう一方の面に前述の磁気層を設けた。次いで
該受容層の平滑度が300s.となるようキャレンダー
処理を行い、熱転写用受容紙とした。 《中間層》 シリカ(吸油量50ml/100g) 60部 スチレン−アクリルエマルジョン (ガラス転移温度10℃、固形分50%) 40部
Example 6 The following intermediate layer coating aqueous solution was prepared, applied to a paper base material so that the dry weight was 4 g / m 2 , provided with an intermediate layer, and further provided with the above-mentioned receiving layer. Also,
The aforementioned magnetic layer was provided on the other side of the paper base. Next, the smoothness of the receiving layer was 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Intermediate layer >> Silica (oil absorption 50ml / 100g) 60 parts Styrene-acryl emulsion (glass transition temperature 10 ° C, solid content 50%) 40 parts

【0032】〔実施例7〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設け、さらに前述の受容層を設けた。また、
紙基材のもう一方の面に前述の磁気層を設けた。次いで
該受容層の平滑度が200s.となるようキャレンダー
処理を行い、熱転写用受容紙とした。 《中間層》 スチレン−アクリルエマルジョン (ガラス転移温度10℃、固形分50%) 100部
Example 7 The following intermediate layer coating aqueous solution was prepared, applied to a paper substrate so that the dry weight was 4 g / m 2 , provided with an intermediate layer, and further provided with the above-mentioned receiving layer. Also,
The aforementioned magnetic layer was provided on the other side of the paper base. Next, the smoothness of the receiving layer was 200 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Interlayer >> Styrene-acryl emulsion (glass transition temperature 10 ° C, solid content 50%) 100 parts

【0033】〔実施例8〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設け、さらに前述の受容層を設けた。また、
紙基材のもう一方の面に前述の磁気層を設けた。次いで
該受容層の平滑度が300s.となるようキャレンダー
処理を行い、熱転写用受容紙とした。 《中間層》 スチレン−アクリルエマルジョン (ガラス転移温度10℃、固形分50%) 100部
Example 8 The following intermediate layer coating aqueous solution was prepared, applied to a paper substrate so that the dry weight was 4 g / m 2 , provided with an intermediate layer, and further provided with the above-mentioned receiving layer. Also,
The aforementioned magnetic layer was provided on the other side of the paper base. Next, the smoothness of the receiving layer was 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Interlayer >> Styrene-acryl emulsion (glass transition temperature 10 ° C, solid content 50%) 100 parts

【0034】〔比較例1〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設けた。さらに前述の受容層を設け、該受容
層平滑度が300s.となるようキャレンダー処理を行
い、熱転写用受容紙とした。 《中間層》 スチレン−アクリルエマルジョン (ガラス転移温度20℃、固形分50%) 100部
[Comparative Example 1] The following intermediate layer coating aqueous solution was prepared and applied on a paper base material so as to have a dry weight of 4 g / m 2 to provide an intermediate layer. Further, the above-mentioned receiving layer was provided, and the receiving layer had a smoothness of 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Intermediate layer >> Styrene-acryl emulsion (glass transition temperature 20 ° C, solid content 50%) 100 parts

【0035】〔比較例2〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設けた。さらに前述の受容層を設け、該受容
層平滑度が300s.となるようキャレンダー処理を行
い、熱転写用受容紙とした。 《中間層》 スチレン−アクリルエマルジョン (ガラス転移温度45℃、固形分50%) 100部
[Comparative Example 2] The following intermediate layer coating aqueous solution was prepared and applied on a paper base material so that the dry weight was 4 g / m 2, to provide an intermediate layer. Further, the above-mentioned receiving layer was provided, and the receiving layer had a smoothness of 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Interlayer >> Styrene-acryl emulsion (glass transition temperature 45 ° C, solid content 50%) 100 parts

【0036】〔比較例3〕紙基材上に中間層を設けない
で前述の受容層を設けた。そして紙基材のもう一方の面
に前述の磁気層を設けた。次いで該受容層平滑度が30
0s.となるようキャレンダー処理を行い、熱転写用受
容紙とした。
Comparative Example 3 The above-described receiving layer was provided on a paper base without providing an intermediate layer. Then, the above-described magnetic layer was provided on the other surface of the paper substrate. Next, the receiving layer has a smoothness of 30.
0s. A calendering treatment was performed to obtain a thermal transfer receiving paper.

【0037】〔比較例4〕下記中間層塗布水溶液を作製
し、紙基材上に乾燥重量が4g/mとなるように塗布
し中間層を設け、さらに前述の受容層を設けた。また、
紙基材のもう一方の面に前述の磁気層を設けた。次いで
該受容層平滑度が300s.となるようキャレンダー処
理を行い、熱転写用受容紙とした。 《中間層》 スチレン−アクリルエマルジョン (ガラス転移温度45℃、固形分50%) 100部
Comparative Example 4 The following intermediate layer coating aqueous solution was prepared, applied on a paper substrate so that the dry weight was 4 g / m 2 , provided with an intermediate layer, and further provided with the above-mentioned receiving layer. Also,
The aforementioned magnetic layer was provided on the other side of the paper base. Next, the smoothness of the receiving layer was 300 s. A calendering treatment was performed to obtain a thermal transfer receiving paper. << Interlayer >> Styrene-acryl emulsion (glass transition temperature 45 ° C, solid content 50%) 100 parts

【0038】以上のようにして作製した実施例および比
較例の熱転写用受容紙について、次の試験条件により、
印字画像品質、すなわちベタ画像均一性、解像度、また
白色性およびブロッキング性の評価を行った。その結果
を表1に示す。 〈熱転写印字試験〉 プリンタ:TEC社製B−30 リボン:リコー製B110A サーマルヘッド:TEC社製(510Ω) 印字速度:2inch/sec 〈ブロッキング試験〉試料の磁気記録層表面と受容層表
面を重ねあわせて、0.5kg/cmの圧力をかけた
状態で、40℃、90%RH環境下に10時間放置した
後、重ね合わせ面を指で剥がし、ブロッキング状態を観
察する。 〈白色性〉ハンター白色度測定機にて白色度を測定し
た。
The thermal transfer receiving papers of the examples and comparative examples produced as described above were subjected to the following test conditions.
Printed image quality, that is, uniformity of solid image, resolution, whiteness and blocking property were evaluated. Table 1 shows the results. <Thermal transfer printing test> Printer: B-30 manufactured by TEC Ribbon: B110A manufactured by Ricoh Thermal head: 510 (manufactured by TEC) Printing speed: 2 inch / sec <Blocking test> The surface of the magnetic recording layer of the sample and the surface of the receiving layer are overlapped. Then, after being left under a pressure of 0.5 kg / cm 2 for 10 hours in an environment of 40 ° C. and 90% RH, the overlapping surface is peeled off with a finger, and the blocking state is observed. <Whiteness> Whiteness was measured with a Hunter whiteness meter.

【0039】[0039]

【表1】 [Table 1]

【0040】表中の各評価ランクは次の通りである。 〈ベタ画像均一性〉 ◎:ボイド・カスレが無く均一なベタ画像である。 ○:ボイド・カスレがほとんど無い。 △:ややボイド・カスレがあり濃度のバラツキが若干あ
る。 ×:ボイド・カスレが多く、画像が判読できない。 〈解像度〉 ◎:画像エッジがシャープである。 ○:画像エッジのシャープさがやや劣る。 △:画像エッジにややボケ、ビビリがある。 ×:画像エッジにボケ、ビビリがある。 〈白色性〉 ◎:白色度82%以上。 ○:白色度80%〜82%未満。 △:白色度78%〜80%未満。 ×:白色度78未満。 〈ブロッキング性〉 ◎:剥がすとき剥離音がなくブロッキングもない 。 ○:剥がすとき剥離音はあるがブロッキングはない 。 △:剥がすとき層がわずかにブロッキングする。 ×:剥がすとき全面に層がブロッキングする。
Each evaluation rank in the table is as follows. <Solid image uniformity> A: Uniform solid image without voids and blurring. :: There is almost no void or blur. Δ: There are slight voids and blurring, and there is some variation in density. ×: Many voids and blurring, and the image cannot be read. <Resolution> A: Image edge is sharp. :: Image edge sharpness is slightly inferior. Δ: Image edges are slightly blurred and chattered. ×: The image edge has blur and chatter. <Whiteness> A: Whiteness 82% or more. :: 80% to less than 82% whiteness. Δ: Whiteness 78% to less than 80%. X: Whiteness less than 78. <Blocking property> :: No peeling sound and no blocking when peeled. :: When peeled, there is a peeling sound but no blocking. Δ: The layer slightly blocks when peeled off. X: The layer blocks on the entire surface when peeled off.

【0041】[0041]

【発明の効果】以上のように請求項1の熱転写用受容紙
は、基材上に熱可塑性樹脂を主成分とする中間層、白色
顔料と熱可塑性樹脂を主成分とする受容層を順次積層し
た熱転写用受容紙において、該中間層の熱可塑性樹脂と
してガラス転移温度(Tg)が10℃以下のものを用い
るものであり、これによれば該中間層の緩衝作用により
印字時熱転写インクシートとの密着性が向上し、これに
よって転写性が向上し熱転写用受容紙のベタ均一性が向
上(ベタ部白抜け防止)すると共に解像度が向上する。
As described above, the receiving paper for thermal transfer according to the first aspect of the present invention has an intermediate layer composed mainly of a thermoplastic resin and a receptor layer composed mainly of a white pigment and a thermoplastic resin laminated on a substrate in this order. In the receiving paper for thermal transfer described above, the thermoplastic resin of the intermediate layer has a glass transition temperature (Tg) of 10 ° C. or less. This improves the transferability, improves the solid uniformity of the thermal transfer receiving paper (prevents solid white spots), and improves the resolution.

【0042】請求項2の熱転写用受容紙は、上記請求項
1の熱転写用受容紙において、該中間層に白色顔料を含
有させるものであり、これによれば熱転写用受容紙がよ
り高白色となり、転写画像をより鮮明にすることができ
る。
The thermal transfer receiving paper of claim 2 is the thermal transfer receiving paper of claim 1 wherein the intermediate layer contains a white pigment, whereby the thermal transfer receiving paper has a higher whiteness. Thus, the transferred image can be made clearer.

【0043】請求項3の熱転写用受容紙は、上記請求項
2の熱転写用受容紙において、該中間層の白色顔料の割
合を熱可塑性樹脂1に対して0.1〜0.5とするもの
であり、これによれば基材への接着性を損なわずに高白
色化された熱転写用受容紙を得ることができる。
The receiving paper for thermal transfer according to claim 3 is the receiving paper for thermal transfer according to claim 2, wherein the ratio of the white pigment in the intermediate layer is 0.1 to 0.5 with respect to the thermoplastic resin 1. According to this, it is possible to obtain a heat-transfer receiving paper having a high whiteness without impairing the adhesiveness to the substrate.

【0044】請求項4の熱転写用受容紙は、上記請求項
1の熱転写用受容紙において、該受容層表面の平滑度を
王研式平滑度で300秒以上とするものであり、これに
よればより高解像度の画像形成を行うことができる。
According to a fourth aspect of the present invention, there is provided a thermal transfer receiving paper according to the first aspect, wherein the surface of the receiving layer has a smoothness of 300 seconds or more in Oken type smoothness. In this case, a higher resolution image can be formed.

【0045】請求項5の熱転写用受容紙は、上記請求項
1〜4の熱転写用受容紙において、該受容層側とは反対
側に強磁性体と熱可塑性主成分とする磁気記録層を設け
るものであり、これによれば、本受容紙が該中間層の熱
可塑性樹脂としてガラス転移温度(Tg)が10℃以下
のものを用いたことから、該中間層が弾性体として働
き、上述のように印字画像品質が向上する一方、保存時
の曲面での磁気記録層表面と受容層表面との圧縮接触時
の剥がれが防止され、また該中間層によって紙基材との
接着性が向上することからブロッキングが起きなくな
る。そのため本受容紙を印字画像品質が優れるだけでな
くブロッキングに強い磁気カード類として使用すること
ができる。
A thermal transfer receiving paper according to a fifth aspect of the present invention is the thermal transfer receiving paper according to the first to fourth aspects, wherein a magnetic recording layer containing a ferromagnetic material and a thermoplastic main component is provided on the side opposite to the receiving layer side. According to this, the receiving paper uses a thermoplastic resin having a glass transition temperature (Tg) of 10 ° C. or less as the thermoplastic resin of the intermediate layer. As described above, while the quality of the printed image is improved, peeling of the magnetic recording layer surface and the receiving layer surface during compression contact on the curved surface during storage is prevented, and the intermediate layer improves the adhesion to the paper substrate. Therefore, blocking does not occur. Therefore, the present receiving paper can be used as magnetic cards having not only excellent print image quality but also strong blocking.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明に関わる熱転写用受容紙の例を示す概略
断面図。
FIG. 1 is a schematic sectional view showing an example of a thermal transfer receiving paper according to the present invention.

【図2】本発明に関わる熱転写用受容紙の例を示す概略
断面図。
FIG. 2 is a schematic sectional view showing an example of a thermal transfer receiving paper according to the present invention.

【符号の説明】[Explanation of symbols]

1 紙基材 2 中間層 3 受容層 4 磁気記録層 DESCRIPTION OF SYMBOLS 1 Paper base material 2 Intermediate layer 3 Reception layer 4 Magnetic recording layer

───────────────────────────────────────────────────── フロントページの続き (72)発明者 折原 基 東京都大田区中馬込1丁目3番6号 株式 会社リコー内 (72)発明者 野毛 由文 東京都大田区中馬込1丁目3番6号 株式 会社リコー内 (72)発明者 湯山 幸博 東京都大田区中馬込1丁目3番6号 株式 会社リコー内 Fターム(参考) 2C005 HA30 HB13 KA15 KA45 LA18 LA20 LA30 LB08 2H111 AA12 AA14 AA16 AA26 CA03 CA04 CA05 CA12 CA23 CA30 CA31 CA33 CA46  ──────────────────────────────────────────────────続 き Continued on the front page (72) Motoi Orihara 1-3-6 Nakamagome, Ota-ku, Tokyo Inside Ricoh Co., Ltd. (72) Yoshifumi Noge 1-3-6 Nakamagome, Ota-ku, Tokyo Inside Ricoh Co., Ltd. (72) Inventor Yukihiro Yuyama 1-3-6 Nakamagome, Ota-ku, Tokyo F-term inside Ricoh Co., Ltd. CA23 CA30 CA31 CA33 CA46

Claims (5)

【特許請求の範囲】[Claims] 【請求項1】 基材上に熱可塑性樹脂を主成分とする中
間層、白色顔料と熱可塑性樹脂を主成分とする受容層を
順次積層した熱転写用受容紙において、該中間層の熱可
塑性樹脂がガラス転移温度(Tg)が10℃以下である
ことを特徴とする熱転写用受容紙。
1. A receiving paper for thermal transfer in which an intermediate layer mainly composed of a thermoplastic resin and a receiving layer mainly composed of a white pigment and a thermoplastic resin are sequentially laminated on a base material. Has a glass transition temperature (Tg) of 10 ° C. or lower.
【請求項2】 請求項1記載の熱転写用受容紙におい
て、該中間層が白色顔料を含有することを特徴とする熱
転写用受容紙。
2. The thermal transfer receiving paper according to claim 1, wherein the intermediate layer contains a white pigment.
【請求項3】 請求項2記載の熱転写用受容紙におい
て、該中間層の白色顔料の割合が熱可塑性樹脂1に対し
て0.1〜0.5であることを特徴とする熱転写用受容
紙。
3. The receiving paper for thermal transfer according to claim 2, wherein the proportion of the white pigment in the intermediate layer is from 0.1 to 0.5 based on 1 of the thermoplastic resin. .
【請求項4】 請求項1記載の熱転写用受容紙におい
て、該受容層の表面が王研式平滑度が300秒以上であ
ることを特徴とする熱転写用受容紙。
4. The receiving paper for thermal transfer according to claim 1, wherein the surface of the receiving layer has an Oken type smoothness of 300 seconds or more.
【請求項5】 請求項1〜4記載の熱転写用受容紙にお
いて、該受容層側とは反対側に強磁性体と熱可塑性樹脂
を主成分とする磁気記録層を設けたことを特徴とする熱
転写用受容紙。
5. The receiving paper for thermal transfer according to claim 1, wherein a magnetic recording layer mainly composed of a ferromagnetic material and a thermoplastic resin is provided on a side opposite to the receiving layer side. Receiving paper for thermal transfer.
JP11041713A 1999-02-19 1999-02-19 Thermal transfer acceptive paper Pending JP2000238443A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11041713A JP2000238443A (en) 1999-02-19 1999-02-19 Thermal transfer acceptive paper

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11041713A JP2000238443A (en) 1999-02-19 1999-02-19 Thermal transfer acceptive paper

Publications (1)

Publication Number Publication Date
JP2000238443A true JP2000238443A (en) 2000-09-05

Family

ID=12616075

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11041713A Pending JP2000238443A (en) 1999-02-19 1999-02-19 Thermal transfer acceptive paper

Country Status (1)

Country Link
JP (1) JP2000238443A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003103943A (en) * 2001-10-01 2003-04-09 Daio Paper Corp Sheet to be transferred
JP2007080444A (en) * 2005-09-16 2007-03-29 Ricoh Co Ltd Magnetic recording material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003103943A (en) * 2001-10-01 2003-04-09 Daio Paper Corp Sheet to be transferred
JP2007080444A (en) * 2005-09-16 2007-03-29 Ricoh Co Ltd Magnetic recording material
JP4571565B2 (en) * 2005-09-16 2010-10-27 株式会社リコー Magnetic recording material

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