JP2000219983A - Method for pickling stainless steel cold rolled steel strip - Google Patents
Method for pickling stainless steel cold rolled steel stripInfo
- Publication number
- JP2000219983A JP2000219983A JP11022445A JP2244599A JP2000219983A JP 2000219983 A JP2000219983 A JP 2000219983A JP 11022445 A JP11022445 A JP 11022445A JP 2244599 A JP2244599 A JP 2244599A JP 2000219983 A JP2000219983 A JP 2000219983A
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- Japan
- Prior art keywords
- nitric acid
- pickling
- tank
- steel strip
- stainless steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、ステンレス鋼冷間
圧延鋼帯の酸洗方法に関し、特に良好な表面性状が要求
されるステンレス鋼冷間圧延鋼帯の酸洗方法に関する。The present invention relates to a method for pickling a stainless steel cold-rolled steel strip, and more particularly to a method for pickling a stainless steel cold-rolled steel strip which requires good surface properties.
【０００２】[0002]
【従来の技術】冷間圧延後のステンレス鋼帯は、一般的
には焼鈍後、スケールを除去するために酸洗処理が施さ
れる。上記した酸洗ラインの構成は、酸洗槽の前にソル
トバス（塩浴槽）または中性塩電解槽を備え、フェライ
ト系ステンレス鋼帯、マルテンサイト系ステンレス鋼帯
の場合は、硝酸酸洗槽により酸洗処理が施され、オース
テナイト系ステンレス鋼帯の場合は、硝酸と弗酸との混
酸槽およびその後工程である硝酸酸洗槽により酸洗処理
が施される。2. Description of the Related Art A stainless steel strip after cold rolling is generally subjected to an acid washing treatment after annealing to remove scale. The above pickling line has a salt bath (salt bath) or a neutral salt electrolytic bath in front of the pickling bath. In the case of a ferritic stainless steel strip or a martensitic stainless steel strip, a nitric acid pickling tank is used. In the case of an austenitic stainless steel strip, the pickling treatment is performed in a mixed acid tank of nitric acid and hydrofluoric acid and a nitric acid pickling tank which is a subsequent step.
【０００３】ステンレス鋼冷間圧延鋼帯は、通常の冷間
圧延鋼帯に比較して特に表面性状の良さが求められる。
このため、これらの酸洗の条件を適正に制御することに
より、表面へのスケールの残存をなくし、良好な表面性
状の鋼帯を得るべく、種々の技術が提案されている。[0003] Stainless steel cold-rolled steel strips are required to have particularly good surface properties as compared with ordinary cold-rolled steel strips.
For this reason, various techniques have been proposed in order to eliminate scale remaining on the surface and obtain a steel strip having good surface properties by appropriately controlling the conditions of the pickling.
【０００４】例えば、特開平９−38714 号公報では、Al
を含有するフェライト系ステンレス鋼帯について、弗酸
濃度が20〜160g/l、硝酸濃度が40〜200g/lの混酸で、Fe
イオン濃度が30g/l 以下の範囲で酸洗することにより、
スケールの残存と過酸洗によるエッチピットが防止でき
る技術が開示されている。しかし、上記混酸によるデス
ケーリングの後、最終処理として硝酸による不動態化処
理を行うと、ステンレス鋼帯の表面にスマットと呼ばれ
る反応物が付着し、鋼帯表面の汚れおよび模様の原因と
なる。[0004] For example, in Japanese Patent Application Laid-Open No. 9-38714,
In a ferritic stainless steel strip containing Fe, a mixed acid with a hydrofluoric acid concentration of 20 to 160 g / l and a nitric acid concentration of 40 to 200 g / l,
By pickling at an ion concentration of 30 g / l or less,
There is disclosed a technique capable of preventing etch pits due to residual scale and acid pickling. However, when passivation treatment with nitric acid is performed as a final treatment after descaling with the mixed acid, a reactant called smut adheres to the surface of the stainless steel strip, causing stains and patterns on the steel strip surface.
【０００５】これらの汚れおよび模様は、製品の美観を
著しく損ね、表面光沢度の劣化により品質不良率が増大
する問題があった。また、上記の汚れおよび模様は、同
一の浴中で再酸洗を行っても十分に除去することができ
ず、さらに再付着が懸念されるため、鋼帯の光沢度改善
として表面研削が必要となり、多大なコストを要すると
いう問題点があった。[0005] These stains and patterns significantly impair the aesthetics of the product, and cause a problem of an increased rate of defective quality due to deterioration of the surface glossiness. In addition, the above-mentioned stains and patterns cannot be sufficiently removed even by re-pickling in the same bath, and there is a fear of re-adhesion. Therefore, surface grinding is required to improve the glossiness of the steel strip. Thus, there is a problem that a great cost is required.
【０００６】[0006]
【発明が解決しようとする課題】本発明は、前記した従
来技術の問題点を解決し、特に良好な表面光沢度が得ら
れるステンレス鋼冷間圧延鋼帯の酸洗方法を提供するこ
とを目的とする。SUMMARY OF THE INVENTION An object of the present invention is to solve the above-mentioned problems of the prior art and to provide a method for pickling a stainless steel cold-rolled steel strip which can obtain particularly good surface glossiness. And
【０００７】[0007]
【課題を解決するための手段】本発明者は、ステンレス
鋼冷間圧延鋼帯を酸洗する硝酸槽におけるスマット汚れ
の発生メカニズムについて調査した結果、硝酸水溶液中
の鉄イオン濃度を一定の範囲内に制御することにより、
ステンレス鋼帯表面へのスマットの付着量が著しく減少
でき、ステンレス鋼帯表面の光沢度を改善することが可
能であることを見出した。The present inventors have investigated the mechanism of smut contamination in a nitric acid tank for pickling a stainless steel cold-rolled steel strip, and found that the iron ion concentration in the aqueous nitric acid solution was within a certain range. By controlling to
It has been found that the amount of smut adhered to the surface of the stainless steel strip can be significantly reduced, and the glossiness of the surface of the stainless steel strip can be improved.
【０００８】さらに、その効果は、ステンレス鋼帯のCr
の含有量が15wt％以下であるマルテンサイト系ステンレ
ス鋼などのステンレス鋼において顕著であることを見出
した。本発明は、これらの知見に基づいてなされたもの
である。すなわち、本発明は、ステンレス鋼の冷間圧延
鋼帯を焼鈍した後、硝酸酸洗を行うステンレス鋼冷間圧
延鋼帯の酸洗方法において、硝酸酸洗槽内の硝酸水溶液
の鉄イオン濃度を2.0wt ％以下に制御することを特徴と
するステンレス鋼冷間圧延鋼帯の酸洗方法である。[0008] Further, the effect is the effect of Cr on the stainless steel strip.
Was found to be remarkable in stainless steel such as martensitic stainless steel having a content of 15 wt% or less. The present invention has been made based on these findings. That is, the present invention provides a method for pickling a stainless steel cold-rolled steel strip, in which a cold-rolled steel strip of stainless steel is annealed and then pickled with nitric acid. A pickling method for a stainless steel cold-rolled steel strip, wherein the pickling is controlled to 2.0 wt% or less.
【０００９】前記した本発明は、好ましくはCr含有量が
15wt％以下のステンレス鋼冷間圧延鋼帯の酸洗方法とし
て用いられ、さらに好ましくは、Cr含有量が15wt％以下
でかつＣ含有量が0.1 wt％以上のステンレス鋼冷間圧延
鋼帯の酸洗方法として用いられる（本発明の第１の好適
態様）。また、前記した本発明、本発明の第１の好適態
様においては、前記硝酸酸洗槽が硝酸電解酸洗槽である
ことが好ましい（本発明の第２の好適態様、第３の好適
態様）。In the present invention described above, the Cr content is preferably
It is used as a method for pickling stainless steel cold-rolled steel strips of 15 wt% or less, and more preferably acid of stainless steel cold-rolled steel strips having a Cr content of 15 wt% or less and a C content of 0.1 wt% or more. Used as a washing method (first preferred embodiment of the present invention). In the present invention and the first preferred embodiment of the present invention, the nitric acid pickling tank is preferably a nitric acid electrolytic pickling tank (second preferred embodiment and third preferred embodiment of the present invention). .
【００１０】さらに、前記した本発明、本発明の各好適
態様においては、ステンレス鋼の冷間圧延鋼帯を焼鈍し
た後、中性塩電解槽で予備的に脱スケールを行い、得ら
れた鋼帯を硝酸電解酸洗槽で酸洗するか、もしくは、上
記焼鈍後、中性塩電解槽で予備的に脱スケールを行い、
得られた鋼帯を硝酸・弗酸混酸槽で酸洗した後、硝酸電
解酸洗槽で酸洗することが好ましい。Further, in the above-described present invention and the preferred embodiments of the present invention, after the stainless steel cold-rolled steel strip is annealed, preliminary descaling is performed in a neutral salt electrolytic tank to obtain a steel sheet. Pickling the zone in a nitric acid electrolytic pickling tank, or after the above annealing, pre-scale descaling in a neutral salt electrolytic tank,
It is preferable that the obtained steel strip is pickled in a nitric acid / hydrofluoric acid mixed acid bath and then pickled in a nitric acid electrolytic pickling bath.
【００１１】[0011]
【発明の実施の形態】以下、本発明をさらに詳細に説明
する。図２に、ステンレス鋼冷間圧延鋼帯の焼鈍、酸洗
ラインの一例を工程図（側面図）で示す。なお、図２に
おいて、１はペイオフリール、２は溶接機、３は脱脂装
置、４は入側ルーパ、５は焼鈍炉、６は冷却装置、７は
酸洗設備、８は出側ルーパ、９はシャー、10はテンショ
ンリール、11は鋼帯、ｆは鋼帯の搬送方向を示す。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail. FIG. 2 is a process diagram (side view) showing an example of an annealing and pickling line for a stainless steel cold-rolled steel strip. In FIG. 2, 1 is a pay-off reel, 2 is a welding machine, 3 is a degreasing device, 4 is an entrance looper, 5 is an annealing furnace, 6 is a cooling device, 7 is a pickling facility, 8 is an exit looper, 9 Denotes a shear, 10 denotes a tension reel, 11 denotes a steel strip, and f denotes a conveying direction of the steel strip.
【００１２】また、図３に、図２における本発明に係る
酸洗設備７の工程図（側面図）の一例を示す。なお、図
３において、12は中性塩電解槽、13は硝酸・弗酸混酸
槽、14は硝酸電解酸洗槽である硝酸酸洗槽、15はブラシ
スタンドを示し、その他の符号は図２と同一の内容を示
す。FIG. 3 shows an example of a process diagram (side view) of the pickling facility 7 according to the present invention in FIG. In FIG. 3, reference numeral 12 denotes a neutral salt electrolytic bath, 13 denotes a nitric acid / hydrofluoric acid mixed bath, 14 denotes a nitric acid pickling bath which is a nitric acid electrolytic pickling bath, and 15 denotes a brush stand. Indicates the same content as.
【００１３】硝酸・弗酸混酸は、仕上酸洗に使用される
硝酸電解酸洗液に比較して、スケールの除去などの酸洗
能力が優れており、硝酸・弗酸混酸槽13においてはスマ
ットは発生しない。しかし、酸洗ラインの最後に不動態
化処理が施される硝酸酸洗槽14では、Feイオンの溶解度
が上記の混酸に比較して小さいことから、スマットの発
生、鋼帯への付着が生じる。A mixed acid of nitric acid and hydrofluoric acid has an excellent pickling ability such as scale removal compared to a nitric acid electrolytic pickling solution used for finish pickling. Does not occur. However, in the nitric acid pickling tank 14 where the passivation treatment is performed at the end of the pickling line, since the solubility of Fe ions is smaller than that of the above mixed acid, smut is generated and adhesion to the steel strip occurs. .
【００１４】スマットの発生の抑制に最も重要な因子
は、硝酸酸洗槽の硝酸水溶液のFeイオン濃度である。す
なわち、Feイオン濃度が低い程、スマットの発生量を抑
制することが可能である。特にその効果が顕著なのは、
後記する実施例に示されように、2.0 wt％以下のFeイオ
ン濃度範囲である。The most important factor for suppressing the generation of smut is the Fe ion concentration of the aqueous nitric acid solution in the nitric acid washing tank. That is, the lower the Fe ion concentration, the more the amount of smut generated can be suppressed. In particular, the effect is remarkable,
As shown in Examples described later, the Fe ion concentration range is 2.0 wt% or less.
【００１５】これに対して、Feイオン濃度が2.0 wt％を
超えると、硝酸水溶液中のFeイオンの溶解度が小さいた
め、FeイオンがFeの水酸化物を主成分として溶液中に析
出し易くなる。析出した水酸化物は、スマットとして硝
酸酸洗槽中のステンレス鋼帯表面に付着し易く、鋼帯の
表面に汚れまたは模様として残留する。On the other hand, when the Fe ion concentration exceeds 2.0 wt%, the solubility of Fe ions in the aqueous nitric acid solution is low, so that the Fe ions are likely to precipitate in the solution with the hydroxide of Fe as a main component. . The precipitated hydroxide easily adheres to the surface of the stainless steel strip in the nitric acid washing tank as a smut, and remains on the surface of the steel strip as dirt or a pattern.
【００１６】したがって、鋼帯表面の性状を良好に保つ
ためには、硝酸酸洗槽内の硝酸水溶液のFeイオン濃度を
2.0 wt％以下に制御する必要がある。該Feイオン濃度
は、より好ましくは、1.5 wt％以下である。本発明にお
いては、例えば、硝酸酸洗槽14内の硝酸水溶液のFeイオ
ン濃度を、連続的あるいはバッチ的に機器分析などによ
り分析し、その結果に基づき、硝酸水溶液の入れ替えあ
るいは新硝酸による希釈を行うことによって、Feイオン
濃度を2.0 wt％以下に制御することができる。Therefore, in order to maintain good properties of the surface of the steel strip, the Fe ion concentration of the aqueous nitric acid solution in the nitric acid washing tank must be reduced.
It must be controlled to 2.0 wt% or less. The Fe ion concentration is more preferably 1.5 wt% or less. In the present invention, for example, the Fe ion concentration of the nitric acid aqueous solution in the nitric acid pickling tank 14 is analyzed continuously or batchwise by instrumental analysis, and based on the result, replacement of the nitric acid aqueous solution or dilution with new nitric acid is performed. By doing so, the Fe ion concentration can be controlled to 2.0 wt% or less.
【００１７】硝酸酸洗槽14の硝酸水溶液の硝酸濃度は、
特に限定しないが、50g/l 以上が好ましい。50g/l 未満
の場合、Feイオンの溶解度が低いためスマットが発生し
易くなる他、酸洗能力が十分ではなく、不動態皮膜の形
成も十分ではない。逆に、硝酸濃度が高すぎると、硝酸
酸洗槽の排気処理、装置の腐食などの設備上および工程
上の問題が発生する。The nitric acid concentration of the aqueous nitric acid solution in the nitric acid washing tank 14 is as follows:
Although not particularly limited, 50 g / l or more is preferable. If it is less than 50 g / l, the solubility of Fe ions is low, so that smut is easily generated, and the pickling ability is not sufficient and the formation of a passive film is not sufficient. On the other hand, if the nitric acid concentration is too high, problems in facilities and processes such as exhaust treatment of the nitric acid washing tank and corrosion of the device occur.
【００１８】このため、硝酸酸洗槽14の硝酸水溶液の硝
酸濃度は、より好ましくは、80〜120g/lの範囲である。
硝酸酸洗槽14の硝酸水溶液の液温は、酸洗効率などに影
響を及ぼす因子である。液温が40℃未満の場合、酸洗が
不十分となり、不動態皮膜の形成も十分ではなく、逆
に、液温が60℃を超える場合、硝酸酸洗槽の排気処理な
どの設備上の問題が生じる。For this reason, the nitric acid concentration of the aqueous nitric acid solution in the nitric acid washing tank 14 is more preferably in the range of 80 to 120 g / l.
The temperature of the nitric acid aqueous solution in the nitric acid pickling tank 14 is a factor that affects pickling efficiency and the like. When the liquid temperature is lower than 40 ° C, the pickling becomes insufficient, and the formation of the passivation film is not sufficient. Conversely, when the liquid temperature exceeds 60 ° C, the equipment such as the exhaust treatment of the nitric acid pickling tank is used. Problems arise.
【００１９】このため、硝酸酸洗槽の硝酸水溶液の液温
は40〜60℃とすることが好ましい。本発明におけるステ
ンレス鋼冷間圧延鋼帯の鋼材としては、オーステナイト
系ステンレス鋼、フェライト系ステンレス鋼、マルテン
サイト系ステンレス鋼のいずれにも適用することができ
る。一方、その原因は明確ではないが、ステンレス鋼の
成分により、スマットの発生量は異なり、Cr含有量が15
wt％以下と少なく、Ｃ含有量が0.1 wt％以上と多い程、
スマットの発生量が増加する。For this reason, the temperature of the aqueous nitric acid solution in the nitric acid washing tank is preferably set to 40 to 60 ° C. As the steel material of the stainless steel cold-rolled steel strip in the present invention, any of austenitic stainless steel, ferritic stainless steel, and martensitic stainless steel can be applied. On the other hand, although the cause is not clear, the amount of smut generated differs depending on the components of stainless steel, and the Cr content is 15%.
wt% or less and the C content is as high as 0.1 wt% or more,
The amount of smut generated increases.
【００２０】このため、本発明は、好ましくはCr含有量
が15wt％以下のステンレス鋼冷間圧延鋼帯、さらにはCr
含有量が15wt％以下でかつＣ含有量が0.1 wt％以上のス
テンレス鋼冷間圧延鋼帯の硝酸酸洗に特に効果的であ
る。また、本発明においては、硝酸酸洗槽が、硝酸電解
酸洗槽であることが好ましい。Therefore, the present invention preferably provides a cold-rolled stainless steel strip having a Cr content of 15 wt% or less,
This is particularly effective for nitric acid pickling of a cold rolled stainless steel strip having a content of 15 wt% or less and a C content of 0.1 wt% or more. In the present invention, the nitric acid pickling tank is preferably a nitric acid electrolytic pickling tank.
【００２１】これは、中性塩電解槽において除去できな
かった鋼帯表面のSi酸化物層を電解除去するためであ
る。上記した硝酸電解酸洗槽における電流密度は、200
〜1000mA/cm2が好ましい。これは、電流密度が200mA/cm
2 未満の場合、Si酸化物層の除去が困難となり、電流密
度が1000mA/cm2超えの場合、過電解により表面にエッチ
ピットが発生するためである。This is for electrolytically removing the Si oxide layer on the surface of the steel strip which could not be removed in the neutral salt electrolytic cell. The current density in the above-mentioned nitric acid electrolytic pickling tank is 200
10001000 mA / cm 2 is preferred. This means that the current density is 200 mA / cm
If it is less than 2 , it becomes difficult to remove the Si oxide layer, and if the current density exceeds 1000 mA / cm 2 , etch pits are generated on the surface due to overelectrolysis.
【００２２】さらに、本発明においては、前記した図
２、図３に例示するように、焼鈍炉の後工程として、中
性塩電解槽、硝酸・弗酸混酸槽および硝酸電解酸洗槽
を、該工程順序で配設するか、もしくは、焼鈍炉の後工
程として、中性塩電解槽および硝酸電解酸洗槽を、該工
程順序で配設し、ステンレス鋼の冷間圧延鋼帯を焼鈍し
た後、中性塩電解槽で予備的に脱スケールを行い、得ら
れた鋼帯を硝酸・弗酸混酸槽で酸洗した後、硝酸電解酸
洗槽で酸洗するか、もしくは上記焼鈍後、中性塩電解槽
で予備的に脱スケールを行い、得られた鋼帯を硝酸電解
酸洗槽で酸洗することが特に好ましい。Further, in the present invention, as exemplified in FIGS. 2 and 3 described above, a neutral salt electrolytic tank, a nitric acid / hydrofluoric acid mixed acid tank and a nitric acid electrolytic pickling tank are provided as post-steps of the annealing furnace. Either disposed in the process order, or as a post-process of the annealing furnace, a neutral salt electrolytic bath and a nitric acid electrolytic pickling bath were disposed in the process sequence, and a stainless steel cold-rolled steel strip was annealed. After that, preliminary descaling is performed in a neutral salt electrolytic tank, and the obtained steel strip is pickled in a nitric acid / hydrofluoric acid mixed acid tank, and then pickled in a nitric acid electrolytic pickling tank, or after the above annealing, It is particularly preferable that descaling is performed in advance in a neutral salt electrolytic tank and the obtained steel strip is pickled in a nitric acid electrolytic pickling tank.
【００２３】これは、Cr含有量が15wt％以下でかつＣ含
有量が0.1 wt％以上のマルテンサイト系ステンレス鋼冷
間圧延鋼帯などのステンレス鋼冷間圧延鋼帯を、焼鈍
後、中性塩電解槽で予備的に脱スケールを行い、必要に
応じて硝酸・弗酸混酸槽で酸洗した後、硝酸電解酸洗槽
内の硝酸水溶液の鉄イオン濃度を2.0wt ％以下に制御し
た条件下で硝酸電解酸洗することによって、中性塩電解
槽、硝酸・弗酸混酸槽による脱スケールおよび硝酸電解
酸洗槽におけるスマットの発生を防止した優れた仕上酸
洗の両者の相乗効果によって、極めて良好な表面光沢度
を有するステンス鋼冷間圧延鋼帯を製造することができ
るためである。This is because a stainless steel cold-rolled steel strip such as a martensitic stainless steel cold-rolled steel strip having a Cr content of 15 wt% or less and a C content of 0.1 wt% or more is neutralized after annealing. Preliminary descaling in a salt electrolyzer and, if necessary, pickling in a nitric acid / hydrofluoric acid mixed acid bath, and then controlling the iron ion concentration of the nitric acid aqueous solution in the nitric acid electrolytic pickling bath to 2.0 wt% or less. By performing nitric acid electrolytic pickling under, the synergistic effect of both neutral salt electrolytic tank, descaling with nitric acid and hydrofluoric acid mixed tank and excellent finish pickling that prevents the generation of smut in nitric acid electrolytic pickling tank, This is because a stainless steel cold-rolled steel strip having extremely good surface glossiness can be manufactured.
【００２４】[0024]
【実施例】以下、本発明を実施例に基づいてさらに具体
的に説明する。 （実施例１）マルテンサイト系ステンレス鋼であるSUS4
20J2(13Cr-0.3C) の冷間圧延鋼帯を、800 ℃で焼鈍後、
図３に示す中性塩電解槽12において予備的に脱スケール
を行い、その後、硝酸電解酸洗槽14により酸洗処理を行
った。EXAMPLES The present invention will be described below more specifically based on examples. (Example 1) SUS4 which is a martensitic stainless steel
After annealing a cold rolled 20J2 (13Cr-0.3C) steel strip at 800 ° C,
The scale was preliminarily descaled in the neutral salt electrolytic cell 12 shown in FIG. 3, and then pickled in the nitric acid electrolytic pickling tank 14.
【００２５】なお、本実施例においては、鋼帯は硝酸・
弗酸混酸槽13をバイパスした。硝酸電解酸洗槽14の硝酸
濃度：100g/l、酸洗液液温：50℃、電流密度：400mA/cm
2 の条件下で、硝酸水溶液のFeイオン濃度を０〜4.0wt
％の範囲で変化させ、鋼帯表面へのスマットの付着量に
及ぼすFeイオン濃度の影響を調査した。鋼帯表面へのス
マットの付着量の評価は、酸洗後の鋼帯の表面に対し20
°の角度で光を照射し、160 °の角度で反射してくる光
の反射量に基づき光沢度を測定し、光沢度で評価した。In this embodiment, the steel strip is made of nitric acid.
The hydrofluoric acid mixed acid tank 13 was bypassed. Nitric acid concentration in nitric acid electrolytic pickling tank 14: 100 g / l, pickling liquid temperature: 50 ° C, current density: 400 mA / cm
Under the conditions of 2 , the Fe ion concentration of the nitric acid aqueous solution is 0 to 4.0 wt.
%, And the effect of Fe ion concentration on the amount of smut adhering to the steel strip surface was investigated. The evaluation of the amount of smut adhering to the steel strip surface was carried out on the steel strip surface after pickling.
The light was irradiated at an angle of °, the gloss was measured based on the amount of light reflected at an angle of 160 °, and the gloss was evaluated.
【００２６】したがって、光沢度が高い程スマットの付
着量は少なく、良好な表面性状であると言える。得られ
た結果を図１に示す。本発明におけるFeイオン濃度が2.
0 wt％以下の領域では、スマットの発生が抑制され、鋼
帯表面の光沢度が700(Gs20°) 以上の極めて良好な表面
性状が得られた。Therefore, it can be said that the higher the gloss, the smaller the amount of smut adhered and the better the surface properties. The results obtained are shown in FIG. The Fe ion concentration in the present invention is 2.
In the region of 0 wt% or less, the occurrence of smut was suppressed, and extremely good surface properties of the steel strip surface with a gloss of 700 (Gs20 °) or more were obtained.
【００２７】（実施例２〜実施例９、比較例）マルテン
サイト系ステンレス鋼であるSUS420J1(13Cr-0.6C) の冷
間圧延鋼帯を、800 ℃で焼鈍後、図３に示す中性塩電解
槽12、硝酸・弗酸混酸槽13により酸洗を施し、仕上酸洗
として硝酸電解酸洗槽14により酸洗処理を行った。すな
わち、電流密度：400mA/cm2 の条件下、硝酸電解酸洗槽
の硝酸水溶液のFeイオン濃度、硝酸濃度および液温を表
１の範囲で変化させ、酸洗後の鋼帯の表面の光沢度を、
前記した実施例１の方法で測定し、下記評価基準に基づ
き評価した。(Examples 2 to 9, Comparative Example) A cold-rolled steel strip of SUS420J1 (13Cr-0.6C), a martensitic stainless steel, was annealed at 800 ° C., and then neutral salts shown in FIG. Pickling was performed in an electrolytic tank 12 and a mixed acid tank 13 of nitric acid and hydrofluoric acid, and pickling treatment was performed in a nitric acid electrolytic pickling tank 14 as finish pickling. That is, under the condition of a current density of 400 mA / cm 2 , the Fe ion concentration, the nitric acid concentration, and the liquid temperature of the nitric acid aqueous solution in the nitric acid electrolytic pickling tank were changed within the ranges shown in Table 1, and the surface gloss of the steel strip after the pickling was changed. Degree
It measured by the method of the above-mentioned Example 1, and evaluated based on the following evaluation criteria.
【００２８】本評価においては、下記評価基準に基づく
Ａ〜Ｃの鋼帯について表面性状が良好であると評価し
た。 〔表面性状評価基準：〕 Ａ：光沢度≧800(Gs20°) Ｂ：800(Gs20°) ＞光沢度≧750(Gs20°) Ｃ：750(Gs20°) ＞光沢度≧700(Gs20°) Ｄ：700(Gs20°) ＞光沢度 得られた結果を、製造条件と併せて表１に示す。In this evaluation, the steel strips A to C based on the following evaluation criteria were evaluated as having good surface properties. [Surface Texture Evaluation Criteria:] A: Gloss ≥ 800 (Gs20 °) B: 800 (Gs20 °)> Gloss ≧ 750 (Gs20 °) C: 750 (Gs20 °)> Gloss ≧ 700 (Gs20 °) D : 700 (Gs20 °)> gloss The obtained results are shown in Table 1 together with the production conditions.
【００２９】[0029]
【表１】 [Table 1]
【００３０】[0030]
【発明の効果】以上説明したとおり、ステンレス鋼冷間
圧延鋼帯を本発明方法によって酸洗することによって、
スマットの付着がなく、良好な表面光沢度を有するステ
ンレス鋼冷間圧延鋼帯を製造することが可能となった。
さらに、本発明によれば、極めて良好な表面性状が得ら
れることから、次工程の表面研削が不要となり、工程の
簡易化が達成でき、製造コストの面から経済性にも優れ
ている。As described above, by pickling a stainless steel cold-rolled steel strip by the method of the present invention,
It has become possible to produce a stainless steel cold-rolled steel strip having good surface gloss without adhesion of smut.
Furthermore, according to the present invention, extremely good surface properties can be obtained, so that surface grinding in the next step is not required, simplification of the step can be achieved, and the production cost is economically excellent.
【図１】硝酸電解酸洗槽の硝酸水溶液のFeイオン濃度と
酸洗後の鋼帯表面の光沢度との関係を示す相関図であ
る。FIG. 1 is a correlation diagram showing the relationship between the Fe ion concentration of a nitric acid aqueous solution in a nitric acid electrolytic pickling tank and the glossiness of a steel strip surface after pickling.
【図２】ステンレス鋼冷間圧延鋼帯の焼鈍、酸洗ライン
の一例を示す工程図（側面図）である。FIG. 2 is a process diagram (side view) showing an example of an annealing and pickling line for a stainless steel cold-rolled steel strip.
【図３】本発明に係るステンレス鋼冷間圧延鋼帯の酸洗
設備の一例を示す工程図（側面図）である。FIG. 3 is a process diagram (side view) showing an example of a pickling facility for a stainless steel cold-rolled steel strip according to the present invention.
１ ペイオフリール ２ 溶接機 ３ 脱脂装置 ４ 入側ルーパ ５ 焼鈍炉 ６ 冷却装置 ７ 酸洗設備 ８ 出側ルーパ ９ シャー 10 テンションリール 11 鋼帯 12 中性塩電解槽 13 硝酸・弗酸混酸槽 14 硝酸酸洗槽（：硝酸電解酸洗槽） 15 ブラシスタンド ｆ 鋼帯の搬送方向 DESCRIPTION OF SYMBOLS 1 Payoff reel 2 Welding machine 3 Degreasing device 4 Inlet looper 5 Annealing furnace 6 Cooling device 7 Pickling equipment 8 Outlet looper 9 Shear 10 Tension reel 11 Steel strip 12 Neutral salt electrolytic tank 13 Nitric acid / hydrofluoric acid mixed acid tank 14 Nitric acid Pickling tank (: nitric acid electrolytic pickling tank) 15 Brush stand f Steel strip transport direction
Claims (1)
後、硝酸酸洗を行うステンレス鋼冷間圧延鋼帯の酸洗方
法において、硝酸酸洗槽内の硝酸水溶液の鉄イオン濃度
を2.0wt ％以下に制御することを特徴とするステンレス
鋼冷間圧延鋼帯の酸洗方法。1. A method for pickling a stainless steel cold-rolled steel strip, wherein the stainless steel cold-rolled steel strip is annealed and then subjected to nitric acid pickling. A pickling method for a stainless steel cold-rolled steel strip, wherein the pickling is controlled to wt% or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP02244599A JP3370618B2 (en) | 1999-01-29 | 1999-01-29 | Pickling method for stainless steel cold rolled steel strip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP02244599A JP3370618B2 (en) | 1999-01-29 | 1999-01-29 | Pickling method for stainless steel cold rolled steel strip |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002274999A Division JP4221984B2 (en) | 2002-09-20 | 2002-09-20 | Martensitic stainless steel cold rolled-annealed-pickled steel strip with extremely good surface gloss |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000219983A true JP2000219983A (en) | 2000-08-08 |
| JP3370618B2 JP3370618B2 (en) | 2003-01-27 |
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ID=12082919
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003027294A (en) * | 2001-07-13 | 2003-01-29 | Kawasaki Steel Corp | Method for pickling martensitic stainless steel sheet |
| JP2009167465A (en) * | 2008-01-16 | 2009-07-30 | Nisshin Steel Co Ltd | Pickling method and pickling device for cold rolled stainless steel strip |
| WO2013097271A1 (en) * | 2011-12-25 | 2013-07-04 | 许继集团有限公司 | Hermetic evaporative cooling tower for direct-current electricity transmission, manufacturing method and rinsing method of same |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101903173B1 (en) * | 2016-12-23 | 2018-10-01 | 주식회사 포스코 | Austenitic stainless steel having excellent hot workability and corrosion resistance and method of manufacturing the same |
-
1999
- 1999-01-29 JP JP02244599A patent/JP3370618B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003027294A (en) * | 2001-07-13 | 2003-01-29 | Kawasaki Steel Corp | Method for pickling martensitic stainless steel sheet |
| JP4720036B2 (en) * | 2001-07-13 | 2011-07-13 | Ｊｆｅスチール株式会社 | Pickling method for martensitic stainless steel sheet |
| JP2009167465A (en) * | 2008-01-16 | 2009-07-30 | Nisshin Steel Co Ltd | Pickling method and pickling device for cold rolled stainless steel strip |
| WO2013097271A1 (en) * | 2011-12-25 | 2013-07-04 | 许继集团有限公司 | Hermetic evaporative cooling tower for direct-current electricity transmission, manufacturing method and rinsing method of same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3370618B2 (en) | 2003-01-27 |
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