JP2000197578A - Manufacture of wet tissue having antibacterial and mildew resistant effect - Google Patents

Manufacture of wet tissue having antibacterial and mildew resistant effect

Info

Publication number
JP2000197578A
JP2000197578A JP10378373A JP37837398A JP2000197578A JP 2000197578 A JP2000197578 A JP 2000197578A JP 10378373 A JP10378373 A JP 10378373A JP 37837398 A JP37837398 A JP 37837398A JP 2000197578 A JP2000197578 A JP 2000197578A
Authority
JP
Japan
Prior art keywords
wet tissue
imazalil
antibacterial agent
antibacterial
manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10378373A
Other languages
Japanese (ja)
Inventor
Toshinobu Hori
俊宣 堀
Kimie Minemura
希実エ 峯村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daiwa Chemical Industries Ltd
Original Assignee
Daiwa Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiwa Chemical Industries Ltd filed Critical Daiwa Chemical Industries Ltd
Priority to JP10378373A priority Critical patent/JP2000197578A/en
Publication of JP2000197578A publication Critical patent/JP2000197578A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Landscapes

  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Paper (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

PROBLEM TO BE SOLVED: To prevent mildew from growing during the preservation period, from manufacturing to use, by a method wherein in imazalil or a mixture of imazalil and a cationic antibacterial agent and/or amphoteric antibacterial agent is applied to a wet tissue prepared by using a paper or non-woven fabric. SOLUTION: A processed chemical prepared by properly mixing a cationic antibacterial agent, amphoteric antibacterial agent or imazalil of 150-250 wt.% is sprayed on or impregnated into raw fabrics of wet tissue. Thus, mildew is prevented from growing during the preservation period of the wet tissue, and hence sanitary wet tissues can be manufactured.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、紙ならびに不織布等の
ウェットティシュー用の原反にイマザリル、あるいはイ
マザリルと塩化ベンザルコニウム等のカチオン抗菌剤、
又は、及び両性抗菌剤との配合製剤の抗菌剤を水希釈し
て処理する、ウェットティシュー製造法である。
The present invention relates to a raw antibacterial agent such as imazalil or imazalil and benzalkonium chloride for wet tissue such as paper and non-woven fabric;
Or, a wet tissue production method in which an antibacterial agent in a formulation formulated with an amphoteric antibacterial agent is diluted with water and treated.

【0002】更に加工されたウェットティシューは、通
常の洗浄、除菌効果だけでなく、保存期間中のカビの発
生を防ぐ能力を有する。
[0002] Further processed wet tissue has not only the usual washing and disinfecting effects, but also the ability to prevent the occurrence of mold during the storage period.

【0003】[0003]

【従来の技術】現在大量に製造されているウェットティ
シューにはカチオン性抗菌剤、両性抗菌剤、パラベン
類、安息香酸等の防腐剤、アルコール類、プロピレング
リコール等の多価アルコール類、その他が処理されてい
る。
2. Description of the Prior Art Catalytic antibacterial agents, amphoteric antibacterial agents, preservatives such as parabens, benzoic acid, etc., alcohols, polyhydric alcohols such as propylene glycol, etc. are processed in large quantities in wet tissues. Have been.

【0004】これらは使用する対象となる部分の洗浄、
除菌等の効力を持つものであるが、多量の水で希釈した
ものを処理しているため、カビに対しての効力が弱く、
保存期間中にカビが発生することも少なくない。
[0004] These are used for cleaning parts to be used,
It is effective in removing bacteria, but because it is treated with a large amount of water, it is less effective against mold.
Mold often occurs during the storage period.

【0005】[0005]

【発明が解決しようとする課題】本発明は従来のウェッ
トティシューの保存性の向上、および塩化ベンザルコニ
ウム等のカチオン物質の配合量を減少させることによ
り、カチオン性抗菌剤の持つ金属腐食性や皮膚刺激性等
の抑制を目的とする。
SUMMARY OF THE INVENTION The present invention improves the preservability of a conventional wet tissue and reduces the amount of a cationic substance such as benzalkonium chloride to reduce the metal corrosiveness of a cationic antibacterial agent. The purpose is to suppress skin irritation.

【0006】[0006]

【課題を解決するための手段】本発明はイマザリルを使
用することにより、従来の塩化ベンザルコニウムだけで
は抑えきれなかったカビに対して効力を発揮する。
According to the present invention, the use of imazalil is effective against fungi which cannot be suppressed by conventional benzalkonium chloride alone.

【0007】本発明の大きな特徴はイマザリルを使用す
ることにより、防カビ効果を向上させ、さらに塩化ベン
ザルコニウムの配合量を抑えることが出来るため、カチ
オン物質に特有のぬめり感や金属腐食性や皮膚刺激性を
抑制することである。
[0007] A major feature of the present invention is that the use of imazalil improves the antifungal effect and further reduces the amount of benzalkonium chloride to be added. It is to suppress skin irritation.

【0008】ウェットティシュー本来の機能としては、
抗菌剤として、塩化ベンザルコニウム、塩化ベンゼトニ
ウム、塩化セチルピリジニウム等の第四級アンモニウム
塩の構造を持つカチオン性抗菌剤、アルキルグリシン型
の両性抗菌剤が使用されている。
[0008] As the original function of wet tissue,
As antibacterial agents, cationic antibacterial agents having a quaternary ammonium salt structure such as benzalkonium chloride, benzethonium chloride, and cetylpyridinium chloride, and alkylglycine-type amphoteric antibacterial agents are used.

【0009】ウェットティシュー自体の保存を目的とす
る防腐剤として、安息香酸、安息香酸塩、パラオキシ安
息香酸エステル類(アルキルはC〜C)が使用され
ている。
As preservatives for the purpose of preserving the wet tissue itself, benzoic acid, benzoates, and paraoxybenzoates (alkyl is C 1 -C 4 ) are used.

【0010】本発明のイマザリルは、処理液に対して、
0.01〜0.2の配合量で、防カビ効果を発揮する。
ただし、この配合量に限定されるものではない。
[0010] The imazalil of the present invention is
When the compounding amount is 0.01 to 0.2, an antifungal effect is exhibited.
However, it is not limited to this blending amount.

【0011】本発明で使用する組成物については、安全
性を考慮し、食品添加物または化粧品原料基準に収載さ
れているものが望ましい。
The composition used in the present invention is desirably one listed in the standard of food additive or cosmetic raw material in consideration of safety.

【0012】加工方法は加工する紙ならびに不織布等
(以下、原反と称する)の重量に対し、150〜250
%の加工液をスプレーまたは含浸等の方法で加工する。
ただし加工する原反によって、適切な加工量は異なる。
The processing method is based on the weight of the paper to be processed and the nonwoven fabric or the like (hereinafter, referred to as raw material) in a range of 150 to 250.
% Of the working fluid by spraying or impregnation.
However, the appropriate amount of processing differs depending on the material to be processed.

【0013】本発明の組成物以外に香料、着色料等の成
分を配合することもできる。
[0013] In addition to the composition of the present invention, components such as fragrances and coloring agents can be blended.

【0014】[0014]

【作用】本発明のウェットティシュー加工組成物は、イ
マザリル、カチオン性抗菌剤、両性抗菌剤を配合した組
成物で、皮膚の清拭用として使用するものである。
The wet tissue processing composition of the present invention is a composition containing imazalil, a cationic antibacterial agent, and an amphoteric antibacterial agent, and is used for wiping the skin.

【0015】[0015]

【実施例】以下、実施例により詳細説明する。しかし本
発明は、これらの実施例に限定されるものではない。
The present invention will be described below in detail with reference to examples. However, the invention is not limited to these examples.

【0016】(実施例1)本発明の実施例に使用する、
イマザリル、カチオン性抗菌剤、両性抗菌剤、防腐剤等
の配合例を表1に記す。
(Embodiment 1) Used in the embodiment of the present invention,
Table 1 shows formulation examples of imazalil, cationic antibacterial agents, amphoteric antibacterial agents, preservatives and the like.

【0017】不織布に表1に記した配合薬剤を不織布重
量に対し200%ムラなく処理した。このウェットティ
シューについて抗菌・防カビ試験を行なった。比較とし
て、水のみを加工したものを試験した。この試験の結果
は、表2に記した。
The nonwoven fabric was treated with the compounding agents shown in Table 1 without unevenness by 200% based on the weight of the nonwoven fabric. An antibacterial and antifungal test was performed on this wet tissue. As a comparison, one processed only with water was tested. The results of this test are shown in Table 2.

【0018】試験方法 JIS L−1902繊維製品の抗菌性試験に準ずる。 JIS Z−2911カビ抵抗性試験に準ずる。 供試細菌 ・Escherichia coli IFO 330
1 (大腸菌) ・Staphylococcus aureus AT
CC 6538P (ブドウ球菌) 供試カビ JIS Z−2911カビ抵抗性試験 繊維試験指定繊
維黴 .Aspergillus niger FERM
S−1 .Penicillium citrinum FE
RM S−5 Chaetomium globosum FERM
S−11 Myrothecium verrucaria FE
RM S−13 以上3種の混合
Test method According to JIS L-1902, an antibacterial test for textile products. According to JIS Z-2911 mold resistance test. Test bacteria ・ Escherichia coli IFO 330
1 (E. coli) Staphylococcus aureus AT
CC 6538P (Staphylococcus) Test mold JIS Z-2911 Mold resistance test Fiber test designated fiber mold. Aspergillus niger FERM
S-1. Penicillium citrinum FE
RM S-5 Chaetomium globosum FERM
S-11 Myrotheium verrucaria FE
RM S-13 A mixture of three or more

【0019】 判定方法 細菌‥‥効果あり (−) 効果なし (+) カビ…JIS Z−2911 カビ抵抗性試験 表示方法による 3‥‥試料上にカビの発育なし 右側の数値は発育阻止巾のmm数 2‥‥試料上のカビの発育面積が全体の1/3以下 1‥‥ 〃 〃 〃 〃 1/3以上Judgment method Bacteria ‥‥ effect (-) no effect (+) Mold ... JIS Z-2911 Mold resistance test By the display method 3 な し No growth of mold on the sample Number 2 ‥‥ The growth area of the mold on the sample is 1/3 or less of the whole 1 ‥‥ 〃 〃 〃 以上 1/3 or more

【0020】[0020]

【表1】 [Table 1]

【0021】使用薬剤 化合物A:塩化ベンザルコニウム(日本油脂(株)カチ
オンF2−50) 化合物B:パラオキシ安息香酸メチル(上野製薬
(株)) 化合物C:イマザリル(ヤンセン(株)) 化合物D:アルキルアミノエチルグリシンNa塩(三洋
化成工業(株)) 化合物E:プロピレングリコール(昭和電工(株))
Chemicals used Compound A: Benzalkonium chloride (Cation F2-50, Nippon Oil & Fats Co., Ltd.) Compound B: Methyl parahydroxybenzoate (Ueno Pharmaceutical Co., Ltd.) Compound C: Imazalil (Jansen Co., Ltd.) Compound D: Alkylaminoethyl glycine Na salt (Sanyo Chemical Industries, Ltd.) Compound E: propylene glycol (Showa Denko KK)

【0022】[0022]

【表2】 [Table 2]

【0023】[0023]

【発明の効果】以上のごとく、イマザリルを加工したウ
ェットティシューは、優れた抗菌・防カビ効果を発揮す
る。
As described above, the wet tissue processed with imazalil exhibits excellent antibacterial and antifungal effects.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) D21H 21/36 D21H 21/36 // A01N 43/50 A01N 43/50 B ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) D21H 21/36 D21H 21/36 // A01N 43/50 A01N 43/50 B

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 1−[2−(2,4−ジクロロフェ
ニル)−2−(2−プロペニルオキシ)エチル]−1H
−イミダゾール(以下、イマザリルと記す)、あるいは
塩化ベンザルコニウム等のカチオン性抗菌剤、又は、及
び両性抗菌剤を配合し、抗菌・防カビ効果を持つウェッ
トティシューの製造法。
1. 1- [2- (2,4-dichlorophenyl) -2- (2-propenyloxy) ethyl] -1H
-A method for producing a wet tissue having an antibacterial and antifungal effect by blending a cationic antibacterial agent such as imidazole (hereinafter referred to as imazalil) or benzalkonium chloride or an amphoteric antibacterial agent.
JP10378373A 1998-12-28 1998-12-28 Manufacture of wet tissue having antibacterial and mildew resistant effect Pending JP2000197578A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10378373A JP2000197578A (en) 1998-12-28 1998-12-28 Manufacture of wet tissue having antibacterial and mildew resistant effect

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10378373A JP2000197578A (en) 1998-12-28 1998-12-28 Manufacture of wet tissue having antibacterial and mildew resistant effect

Publications (1)

Publication Number Publication Date
JP2000197578A true JP2000197578A (en) 2000-07-18

Family

ID=18509620

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10378373A Pending JP2000197578A (en) 1998-12-28 1998-12-28 Manufacture of wet tissue having antibacterial and mildew resistant effect

Country Status (1)

Country Link
JP (1) JP2000197578A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003020597A (en) * 2001-07-11 2003-01-24 Crecia Corp Wet tissue product using water-disintegrable nonwoven fabric
JP2004529148A (en) * 2001-04-24 2004-09-24 ザ プロクター アンド ギャンブル カンパニー Wet type antibacterial wipes
CN101810180A (en) * 2009-11-25 2010-08-25 陕西永泰生物工程有限责任公司 Crop bactericide composition and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004529148A (en) * 2001-04-24 2004-09-24 ザ プロクター アンド ギャンブル カンパニー Wet type antibacterial wipes
JP2003020597A (en) * 2001-07-11 2003-01-24 Crecia Corp Wet tissue product using water-disintegrable nonwoven fabric
CN101810180A (en) * 2009-11-25 2010-08-25 陕西永泰生物工程有限责任公司 Crop bactericide composition and preparation method thereof

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