JP2000191873A - Polyvinylchloride composition, preparation thereof and cable insulation method using it - Google Patents
Polyvinylchloride composition, preparation thereof and cable insulation method using itInfo
- Publication number
- JP2000191873A JP2000191873A JP10373674A JP37367498A JP2000191873A JP 2000191873 A JP2000191873 A JP 2000191873A JP 10373674 A JP10373674 A JP 10373674A JP 37367498 A JP37367498 A JP 37367498A JP 2000191873 A JP2000191873 A JP 2000191873A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- weight
- pvc
- per
- polyvinyl chloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 85
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 84
- 239000000203 mixture Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims description 11
- 238000009413 insulation Methods 0.000 title description 5
- 238000002360 preparation method Methods 0.000 title description 2
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 239000004014 plasticizer Substances 0.000 claims abstract description 18
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000000314 lubricant Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 10
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 8
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000008119 colloidal silica Substances 0.000 claims abstract description 8
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 8
- 239000011701 zinc Substances 0.000 claims abstract description 8
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 239000008116 calcium stearate Substances 0.000 claims abstract description 7
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 7
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract 3
- 239000003381 stabilizer Substances 0.000 claims description 9
- 239000000344 soap Substances 0.000 claims description 6
- 239000003063 flame retardant Substances 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- MGFRKBRDZIMZGO-UHFFFAOYSA-N barium cadmium Chemical compound [Cd].[Ba] MGFRKBRDZIMZGO-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 239000011810 insulating material Substances 0.000 claims 1
- 239000012188 paraffin wax Substances 0.000 claims 1
- 239000008029 phthalate plasticizer Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- -1 inserts Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 1
- 241000189662 Calla Species 0.000 description 1
- ZOBLCVKESRYZRS-UHFFFAOYSA-N Cl.Cl.Cl.S(=O)(=O)(O)O Chemical compound Cl.Cl.Cl.S(=O)(=O)(O)O ZOBLCVKESRYZRS-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- CMCJNODIWQEOAI-UHFFFAOYSA-N bis(2-butoxyethyl)phthalate Chemical compound CCCCOCCOC(=O)C1=CC=CC=C1C(=O)OCCOCCCC CMCJNODIWQEOAI-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- DRLFMBDRBRZALE-UHFFFAOYSA-N melatonin Chemical compound COC1=CC=C2NC=C(CCNC(C)=O)C2=C1 DRLFMBDRBRZALE-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001291 polyvinyl halide Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、ポリ塩化ビニル
（ＰＶＣ）組成物に関し、特に、重金属を基にした安定
剤を含まず、摩耗抵抗を小さくした高度の機械抵抗を有
する組成物に関する。FIELD OF THE INVENTION The present invention relates to polyvinyl chloride (PVC) compositions and, more particularly, to compositions which do not contain heavy metal based stabilizers and which have high abrasion resistance and high mechanical resistance.
【０００２】[0002]
【従来の技術】以下、ポリ塩化ビニルをＰＶＣと称す
る。当該技術分野において、ＰＶＣは、絶縁において広
く用いられる材料として知られており、その低価格及び
有用性のために、かつその誘電的かつ機械的特性並びに
その化学的かつ環境的抵抗性のために導電体ケーブルの
ためのカバーとして広く使用されている。2. Description of the Related Art Hereinafter, polyvinyl chloride is referred to as PVC. PVC is known in the art as a widely used material in insulation and because of its low cost and utility, and because of its dielectric and mechanical properties and its chemical and environmental resistance. Widely used as a cover for conductor cables.
【０００３】この種の製品に対し、ＰＶＣは、その本質
的な堅固性を除去しかつ所望の柔軟性を与えるために、
常に可塑剤を添加して用いられる。熱安定剤、潤滑剤、
顔料、挿入物、衝撃緩和剤及び炎抑制剤のような他の添
加剤も、所望の特性を有するＰＶＣを得るために製品に
混入される。For products of this type, PVC is used to remove its inherent rigidity and to provide the desired flexibility.
It is always used with a plasticizer added. Heat stabilizers, lubricants,
Other additives such as pigments, inserts, impact modifiers and flame retardants are also incorporated into the product to obtain PVC with the desired properties.
【０００４】ＰＶＣは、それ自体で熱的に不安定であ
る。なぜならば、１５０℃近くの温度において、ＨＣｌ
を放出し、ポリマー中に、飽和されない箇所を生成して
分解し、それにより連鎖網状組織及び破壊を起こし、ポ
リマー特性の品質低下をもたらすからである。ＰＶＣが
分解する間、樹脂は色が変わって硬直かつ脆弱になる。[0004] PVC itself is thermally unstable. Because, at temperatures near 150 ° C., HCl
And creates and decomposes unsaturated sites in the polymer, thereby causing a chain network and destruction, resulting in poor polymer properties. During the decomposition of PVC, the resin changes color and becomes rigid and brittle.
【０００５】熱的安定性を改善するためには、ＰＶＣ組
成物に安定剤が添加される。一般に用いられる安定剤
は、金属塩、有機または無機のフェノール、有機金属、
エポキシ組成物及び亜リン酸塩である。自動車の主ケー
ブルの絶縁用の組成物の場合において、パッカード・エ
レクトリック（ＰＡＣＫＡＲＤ ＥＬＥＣＴＲＩＣ）
ＥＳ−Ｍ ２３９７仕様は、仕様ＥＳ Ｍ ３０８９に
定められた薄肉ケーブルの製造のために用いる組成物に
は、鉛があってはならないと定められている。[0005] To improve the thermal stability, stabilizers are added to the PVC composition. Commonly used stabilizers include metal salts, organic or inorganic phenols, organometallics,
Epoxy compositions and phosphites. PACKARD ELECTRIC in the case of compositions for the insulation of automobile main cables
The ES-M 2397 specification stipulates that the composition used for the manufacture of thin-walled cables as specified in specification ES M 3089 must be free of lead.
【０００６】自動車産業は、次の要因によって影響され
る。現在の自動車によって提供される効率、安全性、豪
華性及び安楽性を増加させるために、その自動車が発生
する排気ガス及び車両の構造の両者に関して、自動車に
よる環境への影響をできるだけ少なくすることを強制す
る環境に関する法律の存在がそれである。The automotive industry is affected by the following factors: In order to increase the efficiency, safety, luxury and comfort offered by the current vehicle, it is important to minimize the environmental impact of the vehicle, both in terms of its emissions and the structure of the vehicle. That is the existence of mandatory environmental laws.
【０００７】このために、自動車の製造に用いられる材
料、並びに自動車の使用時における性能を、自動車の製
造者において、やむなく変更する必要が生じる。[0007] For this reason, it is necessary for automobile manufacturers to change the materials used in the production of automobiles and the performance of the automobiles in use.
【０００８】第１の変更は、重合体の組成物中の有毒な
成分、特に、経済的かつ電気的長所のために鉛を含んで
いるＰＶＣを除去することであった。A first modification has been to remove toxic components in the polymer composition, especially PVC containing lead for economic and electrical advantages.
【０００９】[0009]
【発明が解決しようとする課題】環境への影響を減らす
ために、燃料消費を最適化するべく、内燃機関に対して
改良が行われている。また、より小さい寸法及び重量の
車両が設計されており、種々の区画部における空間が小
さくなってきており、安全性及び豪華性の両者を改善す
るために、ますます増える装置やそれらの接続ハーネス
のためには、小さい空間しか残っていない。これらの理
由のために、車両の製造者はケーブルの設計を変更して
きており、絶縁壁の厚さを薄くして、重量及び直径を減
らし、同じ空間内で回路の数を増やせるようにしてい
る。もちろん、前記壁の厚さを薄くしても、性能に影響
を与えてはならない。Improvements have been made to internal combustion engines to optimize fuel consumption to reduce environmental impact. Also, vehicles of smaller size and weight are being designed, the space in various compartments is getting smaller, and more and more devices and their connecting harnesses are being improved to improve both safety and luxury. Only a small space remains. For these reasons, vehicle manufacturers have changed cable designs, reducing the thickness of insulating walls, reducing weight and diameter, and increasing the number of circuits in the same space. . Of course, reducing the wall thickness should not affect the performance.
【００１０】[0010]
【課題を解決するための手段】本発明によれば、自動車
用の薄肉主ケーブルの絶縁に適した、重金属を含まない
ハロゲン化ポリ塩化ビニル組成物であって、 ａ）ポリ塩化ビニル樹脂（ＰＶＣ）約６０〜１００重量
部、 ｂ）ＰＶＣ１００重量部につき、亜鉛を基にした熱安定
剤の重量での約１〜６重量部、 ｃ）ＰＶＣ１００重量部につき、オクタデシル−３，５
−ジテルブチル−４−ヒドロキシヒドロシナメート酸化
防止剤約０．２〜２．０重量部、 ｄ）ＰＶＣ１００重量部につき、ステアリン酸カルシウ
ム潤滑剤約０．１５〜０．２重量部、 ｅ）ＰＶＣ１００重量部につき、沈殿炭酸カルシウム充
填剤約１０〜５０重量部、 ｆ）ＰＶＣ１００重量部につき、コロイド状シリカ充填
剤約１０〜５０重量部、 ｇ）ＰＶＣ１００重量部つき三酸化アンチモン炎抑制剤
約２〜８重量部、 ｈ）ケーブルの要求に基づいて選択された適量の可塑
剤、 ｉ）ＰＶＣ融和性ウレタン・ポリマー中、ＰＶＣの量に
基づき、約１００％までの任意成分を含む混合物よりな
る、重金属を含まないハロゲン化ポリ塩化ビニル組成物
が提供される。According to the present invention, there is provided a halogenated polyvinyl chloride composition free of heavy metals, suitable for insulating thin main cables for automobiles, comprising: a) polyvinyl chloride resin (PVC); B) about 1 to 6 parts by weight of zinc-based heat stabilizer per 100 parts by weight of PVC; c) octadecyl-3,5 per 100 parts by weight of PVC.
About 0.2 to 2.0 parts by weight of diterbutyl-4-hydroxyhydrocinnamate antioxidant, d) about 0.15 to 0.2 parts by weight of a calcium stearate lubricant per 100 parts by weight of PVC, e) 100 parts by weight of PVC F) about 10 to 50 parts by weight of precipitated calcium carbonate filler, f) about 10 to 50 parts by weight of colloidal silica filler per 100 parts by weight of PVC, g) about 2 to 8 parts by weight of antimony trioxide flame inhibitor with 100 parts by weight of PVC Parts, h) an appropriate amount of plasticizer selected based on the requirements of the cable, i) a heavy metal comprising a mixture of up to about 100% optional components in the PVC compatible urethane polymer, based on the amount of PVC. No halogenated polyvinyl chloride composition is provided.
【００１１】[0011]
【発明の実施の形態】「発明が解決しようとする課題」
の項で述べた要件を達成するための１つの方法は、組成
物に増大した機械的特性を与えるために、大きな分子量
のＰＶＣ樹脂を用いることである。しかし、市場におい
て高分子量の樹脂が不足しているので、ＰＶＣを、摩耗
や穿刺のような機械的特性において強化するためには、
別の代用のポリマーが好ましい。DESCRIPTION OF THE PREFERRED EMBODIMENTS "Problems to be solved by the invention"
One way to achieve the requirements set forth in the section is to use a high molecular weight PVC resin to provide the composition with increased mechanical properties. However, due to the shortage of high molecular weight resins in the market, to enhance PVC in mechanical properties such as wear and puncture,
Another alternative polymer is preferred.
【００１２】他方、低温での破壊抵抗要件のために、か
つ高温にさらされているとを維持するために、11個及び
９個の炭素原子を有する共エステルのフタル酸型可塑剤
が選択されてきている。それは共エステル構造であるの
で、−６０℃の凝固点と高温での低い揮発性を有する。On the other hand, co-ester phthalic plasticizers having 11 and 9 carbon atoms have been selected for their fracture resistance requirements at low temperatures and to maintain exposure to high temperatures. Is coming. Because it is a co-ester structure, it has a freezing point of -60 ° C and low volatility at high temperatures.
【００１３】ケーブルが持っていなければならない主な
特性の中には、以下のものがある。 ・破壊強さ ・破壊伸び率 ・温度抵抗（炉内での経時硬化） ・ケーブルがさらされる異なる流体、すなわち、ガソリ
ン、モータ・オイル、変速機オイル、伝圧用流体、ブレ
ーキオイル、不凍液、バッテリ電解液に対する抵抗 ・摩耗抵抗 ・低温破壊抵抗 ・穿刺抵抗（スランプ抵抗） ・炎抵抗Some of the key characteristics that a cable must have are:・ Fracture strength ・ Elongation at break ・ Temperature resistance (hardening over time in furnace) ・ Different fluids to which the cable is exposed, ie gasoline, motor oil, transmission oil, pressure transmission fluid, brake oil, antifreeze, battery electrolysis Resistance to liquid ・ Abrasion resistance ・ Low temperature breakdown resistance ・ Puncture resistance (slump resistance) ・ Flame resistance
【００１４】摩耗、穿刺、自動車の流体に対して高抵抗
を有する本発明の組成物は、ＰＶＣもしくは一連の添加
剤が混合された別の同種の樹脂を基にしている。この製
品の成分の数は、樹脂もしくは追加の樹脂の１００部に
対する部で表現される。The compositions of the present invention, which have high resistance to abrasion, puncture and automotive fluids, are based on PVC or another similar resin mixed with a range of additives. The number of components of this product is expressed in parts per 100 parts of resin or additional resin.
【００１３】成分のすべては、以下の情報により品質が
保証された材料である。 ａ）ＰＶＣ ＲＥＳＩＮ ２５０、すなわち、媒体粘性
及び分子量、ＰＶＣケミカル・アブストラクト登録番号
００２−８６−２の樹脂に対応するＫ値＝７０ｖのホモ
ポリマーのＰＶＣ樹脂。 ｂ）「シンプロン（ＳＹＮＰＲＯＮ）」 １８９０、亜
鉛を基にした安定剤 ｃ）「モルタン（ＭＯＲＴＨＡＮＥ）」 ４５５−３０
０ 熱可塑性ポリウレタン樹脂 ｄ）三酸化アンチモン、ケミカル・アブストラクト登録
番号０１２０９−６４−４による炎抑制剤 ｅ）沈殿炭酸カルシウム、ケミカル・アブストラクト登
録番号１３１７−６５−３ ｆ）ＨＩ−ＳＩＬ ２３３ コロイド状沈殿非結晶シリ
カ。ケミカル・アブストラクト登録番号１１２９２６−
００−８ ｇ）「パラチノール（ＰＡＬＡＴＩＮＯＬ）」 １１
９Ｐ種の共エステルのフタル酸可塑剤 ｈ）「パラチモール（ＰＡＬＡＭＯＬＬ）」 ６５２、
アジピンポリマー可塑剤 ｉ）「イルガノックス（ＩＲＧＡＮＯＸ）」 １０７
６、ケミカル・アブストラクト登録番号２０８２−７９
−３による オクタデシル−３，５−ジテルブチル−４
−ヒドロキシヒドロシナメート ｊ）ステアリン酸カルシウム、ケミカル・アブストラク
ト登録番号１５９２−２３−０による潤滑剤 ｋ）「ポリエチレニック・ワックス（ＰＯＬＹＥＴＨＹ
ＬＥＮＩＣ ＷＡＸ）」 ＡＣ−６２９、酸化ポリエチ
レン・ホモポリマー、ケミカル・アブストラクト登録番
号９００２−８８−４All components are materials whose quality is guaranteed by the following information. a) PVC RESIN 250, a homopolymeric PVC resin with medium viscosity and molecular weight, K value = 70v corresponding to the resin with PVC Chemical Abstract Registry Number 002-86-2. b) "SYNPRON" 1890, a zinc-based stabilizer c) "MORTANE" 455-30
0 Thermoplastic polyurethane resin d) Antimony trioxide, flame retardant according to Chemical Abstract Registration No. 01209-64-4 e) Precipitated calcium carbonate, Chemical Abstract Registration No. 1317-65-3 f) HI-SIL 233 colloidal precipitate Amorphous silica. Chemical Abstract Registration No. 112926
00-8 g) "PALATINOL" 11
Phthalic acid plasticizers of 9P coesters h) "PALAMOLL" 652,
Adipine polymer plasticizer i) "IRGANOX" 107
6, Chemical abstract registration number 2082-79
Octadecyl-3,5-diterbutyl-4
-Hydroxyhydrocinnamate j) Calcium stearate, lubricant according to Chemical Abstracts Registry Number 1592-23-0 k) "Polyethylene wax"
LENIC WAX) "AC-629, polyethylene oxide homopolymer, Chemical Abstract Registration No. 9002-88-4
【００１４】ＰＶＣを基にした熱可塑性材料において、
二塩化フタル酸鉛及び三塩化硫酸鉛が、電気使用のため
の熱安定剤としてしばしば用いられる。しかし、自動車
のケーブルの絶縁用に生成された化合物の場合において
は、自動車の製造者の要求があるために、亜鉛を基にし
た安定剤が用いられてきた。もちろん、他の種類の安定
剤も用いることが出来る。それらの中には、バリウム・
ソープ（石鹸）、バリウム・カドミウム・ソープ、バリ
ウム・カドミウム・ソープよりなる「マークオーム（Ｍ
ＡＲＫ ＯＨＭ）」のような混合物がある。In a thermoplastic material based on PVC,
Lead diphthalate phthalate and lead trichloride sulphate are often used as thermal stabilizers for electrical use. However, in the case of compounds produced for the insulation of motor vehicle cables, zinc-based stabilizers have been used due to the requirements of motor vehicle manufacturers. Of course, other types of stabilizers can be used. Some of them include barium
Soap (bar soap), barium cadmium soap, barium cadmium soap "Mark Ohm (M
ARK OHM) ".
【００１５】同様に、「イルガノックス（ＩＲＧＡＮＯ
Ｘ）」１０７６に加えて、「トパノール（ＴＯＰＡＮＯ
Ｌ）」ＣＡ、及び「ビスフェノール（Ｂｉｓｆｅｎｏ
ｌ）」Ａのようなフェノール樹脂、その他の酸化防止剤
を用いることができる。Similarly, “IRGANOX (IRGANOX)
X) ”1076 and“ TOPANO (TOPANO)
L) "CA" and "bisphenol (Bisfeno)
l) Phenolic resins such as "A" and other antioxidants can be used.
【００１６】ステアリン酸カルシウムに加えて、ステア
リン酸のような、かつＡＣ６２９Ａまたはそれらの組成
物のようなパラフィニック、及びポリエチレン・ワック
スのような非常に多くの潤滑剤を用いることができる。In addition to calcium stearate, numerous lubricants such as stearic acid and paraffinic, such as AC629A or their compositions, and polyethylene waxes can be used.
【００１７】前述したように、高い温度における低い揮
発性及び低い凝固点のゆえに、共エステル可塑剤が選択
されてきた。しかし、ケーブルの最終的な要求によって
は、他の可塑剤を用いることができる。As mentioned above, co-ester plasticizers have been chosen because of their low volatility at high temperatures and low freezing points. However, other plasticizers can be used depending on the ultimate requirements of the cable.
【００１８】本発明の組成物の好適な実施形態を、質的
な用語を使用して以下に説明する。Preferred embodiments of the composition of the present invention are described below using qualitative terms.
【００１９】樹脂１００部につき、６０から１００部、
好ましくは７５から１００部の「プライメックス（ＰＲ
ＩＭＥＸ）」２５０樹脂のようなポリ塩化ビニル。For 100 parts of resin, 60 to 100 parts,
Preferably 75 to 100 parts of Primex (PR
IMEX) "polyvinyl chloride such as 250 resin.
【００２０】樹脂１００部につき、１から６部、好まし
くは３から４部の「シンプロン（ＳＹＮＰＲＯＮ）」１
８９０のような自動車のケーブルのためのＰＶＣ組成物
に使用される少なくとも一つの熱安定剤。1 to 6 parts, preferably 3 to 4 parts of "SYNPRON" 1 per 100 parts of resin
At least one heat stabilizer used in PVC compositions for automotive cables, such as 890.
【００２１】樹脂１００部につき、０．２から２．０部
までの全量において「イルガノックス（ＩＲＧＡＮＯ
Ｘ）」１０７６または同様なＰＶＣを基にした熱可塑性
材料のための少なくとも１つの効果的な酸化防止剤。[0021] Irganox (IRGANOX) is used in a total amount of 0.2 to 2.0 parts per 100 parts of resin.
X) "at least one effective antioxidant for 1076 or similar PVC based thermoplastics.
【００２２】樹脂１００部につき、０．１５から２．０
までの全量において、ステアリン酸カルシウムまたは同
様なもの、またはそれらの混合物のような、ＰＶＣを基
にした熱可塑性材料のために効果的な少なくとも一つの
潤滑剤。0.15 to 2.0 per 100 parts of resin
At least one lubricant effective for PVC-based thermoplastic materials, such as calcium stearate or the like, or mixtures thereof, in all amounts up to.
【００２３】樹脂１００部につき１０から５０部、好ま
しくは樹脂１００部につき１５から２５部の沈殿炭酸カ
ルシウム及びコロイド性シリカ装填剤。10 to 50 parts per 100 parts resin, preferably 15 to 25 parts per 100 parts resin, precipitated calcium carbonate and colloidal silica charge.
【００２４】機械的特性を改善するためのＰＶＣ樹脂融
和性のウレタン。[0024] PVC resin compatible urethane for improving mechanical properties.
【００２５】卓越した摩耗抵抗を有する自動車用の薄肉
主ケーブルを絶縁するための重金属を含まないいハロゲ
ン化ポリビニルの製品を得るための方法について述べ
る。A method for obtaining heavy metal-free polyvinyl halide products for insulating thin automotive main cables having excellent wear resistance is described.
【００２６】本発明の化合物は、化合物の製造に対して
当業者に公知である段階を用いることによって得られ
る。The compounds of the present invention are obtained by using steps known to those skilled in the art for preparing compounds.
【００２７】化合物の製造のために、乾燥ブレンドが得
られるまで高強度の切断ミキサを用い、その後、それを
以下の方法のいずれかによって可塑的にされる。For the preparation of the compound, a high-strength cutting mixer is used until a dry blend is obtained, after which it is plasticized by any of the following methods.
【００２８】１．決定された期間、決定された温度で、
「バンバリ（Ｂａｎｂｕｒｙ）」の内部混合機のローラ
ーミルで化合物を放出し、粒子状形態に切断されること
ができる化合物のストリップを得る。 ２．乾燥ブレンドを、連続的に可塑的とし、かつ粒状に
する機械、もしくは別の種類の組成物処理機械の中へ放
出する。1. For a determined period, at a determined temperature,
The compound is released on a roller mill of an internal mixer of "Banbury" to give a strip of the compound that can be cut into particulate form. 2. The dry blend is discharged into a continuously plasticizing and granulating machine or another type of composition processing machine.
【００２９】最初に、可塑剤は、追加の熱を必要としな
い高い強度の混合機で、安定剤とともにＰＶＣ樹脂に混
入した。高強度の混合機は、乾燥ブレンドが形成される
まで作動し、装填及び潤滑剤を２分間加え、次に乾燥ブ
レンドを、その温度を下げるために、水ジャケットを有
する冷却機に放出する。Initially, the plasticizer was mixed with the stabilizer in the PVC resin in a high intensity mixer that did not require additional heat. The high intensity mixer operates until a dry blend is formed, the charge and lubricant are added for 2 minutes, and then the dry blend is discharged to a cooler with a water jacket to reduce its temperature.
【００３０】乾燥ブレンドの温度が一旦低下すると、化
合物は、ブレンドを可塑的とし、かつ散乱させ、最後に
組成物を粒状にする押し出し粒状機械、もしくは温度が
１６０℃に達するまで組成物に働く「バンバリ（ｂａｎ
ｂｕｒｙ）」内部混合機のいずれかへ通す。次に、化合
物を、ローラーミル上へ放出すると、そこでストリップ
が得られ、最後に押し出し機械に供給されるべく粒状に
される。Once the temperature of the dry blend is reduced, the compound acts on the composition, extruding and granulating the blend to plasticize and scatter, and finally granulating the composition, or until the temperature reaches 160 ° C. Ban Bali
(bury) "through any of the internal mixers. The compound is then discharged onto a roller mill where a strip is obtained and finally granulated to be fed to an extrusion machine.
【００３１】実験 自動車のケーブルに適用するための最適化された本発明
の組成物を、先に述べたようにして調製した。EXPERIMENTAL An optimized composition of the present invention for application to automotive cables was prepared as described above.
【００３２】本発明の組成物によって得られたケーブル
は、組成物としてパッカード・エレクトリック（ＰＡＣ
ＫＡＲＤ ＥＬＥＣＴＲＩＣ）ＥＳ Ｍ ２３９７基準
に定められた試験に供され、かつケーブルとしてパッカ
ード・エレクトリック ＥＳＭ ３０８９の試験に供さ
れ、パッカード・エレクトリック・ジェネラル・モータ
ーズに供給されるケーブルのための絶縁用として認可を
得た。 ＥＳ Ｍ ２３９７ シート特性の評価 ＥＳ Ｍ ３０８９ ケーブル特性の評価The cable obtained by the composition of the present invention is a composition comprising Packard Electric (PAC)
KARD ELECTRIC) Subjected to the tests specified in the ESM 2397 standard and tested as a cable for Packard Electric ESM 3089 and approved for insulation for cables supplied to Packard Electric General Motors. Obtained. ESM2397 Evaluation of sheet properties ESM3089 Evaluation of cable properties
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ０８Ｋ 5/10 Ｃ０８Ｋ 5/10 5/13 5/13 Ｃ０８Ｌ 27/06 Ｃ０８Ｌ 27/06 //(Ｃ０８Ｌ 27/06 91:06） (72)発明者 アルフォンソ ペレス サンチェス メキシコ国 クロ ケレタロ 76120 フ ーリカ パルク インデュストリアル カ ル・ア エセ・エレ・ペ カ・エメ ９. ６ (72)発明者 アルトゥーロ ホルト デルガド メキシコ国 クロ ケレタロ 76120 フ ーリカ パルク インデュストリアル カ ル・ア エセ・エレ・ペ カ・エメ ９. ６ Ｆターム(参考） 4J002 AE033 AE053 BB033 BD041 BD181 CK032 DE120 DE239 DJ019 EF058 EG036 EG038 EG046 EH140 EJ017 EJ037 EJ067 FD019 FD020 FD066 FD073 FD077 FD090 FD178 GQ01 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C08K 5/10 C08K 5/10 5/13 5/13 C08L 27/06 C08L 27/06 // (C08L 27 / 06 91:06) (72) Inventor Alfonso Perez Sanchez, Mexico, Querétaro, Mexico 76120 Furica Parc Industrial Calla Ese Ele Peca Eme 9.6 (72) Inventor, Arturo Holt Delgado Mexico Country Black Queretaro 76120 Furica Parc Industrial Call A Ese Ele Peca Eme 9.6 F Term (Reference) 4J002 AE033 AE053 BB033 BD041 BD181 CK032 DE120 DE239 DJ019 EF058 EG036 EG038 EG046 EJ040 EG046 EH140EJ FD020 FD066 FD073 FD077 FD090 FD178 GQ01
Claims (20)
た、重金属を含まないハロゲン化ポリ塩化ビニル組成物
であって、 ａ）ポリ塩化ビニル樹脂（ＰＶＣ）約６０〜１００重量
部、 ｂ）ＰＶＣ１００重量部につき、亜鉛を基にした熱安定
剤約１〜６重量部、 ｃ）ＰＶＣ１００重量部につき、オクタデシル−３，５
−ジテルブチル−４−ヒドロキシヒドロシナメート酸化
防止剤約０．２〜２．０重量部、 ｄ）ＰＶＣ１００重量部につき、ステアリン酸カルシウ
ム潤滑剤の重量での約０．１５〜０．２重量部、 ｅ）ＰＶＣ１００重量部につき、沈殿炭酸カルシウム充
填剤約１０〜５０重量部、 ｆ）ＰＶＣ１００重量部につき、コロイド状シリカ充填
剤約１０〜５０重量部、 ｇ）ＰＶＣ１００重量部つき、三酸化アンチモン炎抑制
剤約２〜８重量部、 ｈ）ケーブルの要求に基づいて選択された適量の可塑
剤、 ｉ）ＰＶＣ融和性ウレタン・ポリマー中、ＰＶＣの量に
基づき、約１００％までの任意成分を含む混合物よりな
る、重金属を含まないハロゲン化ポリ塩化ビニル組成
物。1. A heavy metal-free halogenated polyvinyl chloride composition suitable for insulating thin main cables for automobiles, comprising: a) about 60 to 100 parts by weight of polyvinyl chloride resin (PVC); b) About 1 to 6 parts by weight of zinc-based heat stabilizer per 100 parts by weight of PVC; c) octadecyl-3,5 per 100 parts by weight of PVC.
About 0.2-2.0 parts by weight of diterbutyl-4-hydroxyhydrocinnamate antioxidant; d) about 0.15-0.2 parts by weight of calcium stearate lubricant per 100 parts by weight of PVC; e A) about 10 to 50 parts by weight of precipitated calcium carbonate filler per 100 parts by weight of PVC; f) about 10 to 50 parts by weight of colloidal silica filler per 100 parts by weight of PVC; g) antimony trioxide flame retardant with 100 parts by weight of PVC. About 2 to 8 parts by weight, h) an appropriate amount of plasticizer selected based on cable requirements, i) a mixture of up to about 100% optional ingredients in the PVC compatible urethane polymer, based on the amount of PVC. , A halogenated polyvinyl chloride composition free of heavy metals.
約３〜４重量部を含む請求項１に記載のハロゲン化ポリ
塩化ビニル組成物。2. A halogenated polyvinyl chloride composition according to claim 1, comprising about 3 to 4 parts by weight of a zinc stabilizer per 100 parts by weight of PVC.
ルシウム及びコロイド状シリカの各々約１５〜２５重量
部を含む請求項１に記載のハロゲン化ポリ塩化ビニル組
成物。3. The halogenated polyvinyl chloride composition of claim 1, comprising about 15 to 25 parts by weight of each of precipitated calcium carbonate and colloidal silica per 100 parts by weight of PVC.
チモン約３〜６重量部を含む請求項１に記載のハロゲン
化ポリ塩化ビニル組成物。4. The halogenated polyvinyl chloride composition according to claim 1, comprising about 3 to 6 parts by weight of antimony trioxide per 100 parts by weight of PVC.
する共エステルフタル酸可塑剤及びアジピンポリマー可
塑剤からなる群から選択された請求項１に記載のハロゲ
ン化ポリ塩化ビニル組成物。5. The halogenated polyvinyl chloride composition according to claim 1, wherein the plasticizer is selected from the group consisting of coester phthalate plasticizers having 11 and 9 carbon atoms and adipine polymer plasticizers.
ム・ソープ及びそれらの混合物からなる群から選択され
た熱安定剤をさらに含む請求項１に記載のハロゲン化ポ
リ塩化ビニル組成物。6. The halogenated polyvinyl chloride composition of claim 1, further comprising a heat stabilizer selected from the group consisting of barium soap, barium cadmium soap, and mixtures thereof.
びそれらの混合物からなる群から選択された潤滑剤をさ
らに含む請求項１に記載のハロゲン化ポリ塩化ビニル組
成物。7. The halogenated polyvinyl chloride composition of claim 1, further comprising a lubricant selected from the group consisting of stearic acid, paraffin wax and mixtures thereof.
ら選択された酸化防止剤をさらに含む請求項１に記載の
ハロゲン化ポリ塩化ビニル組成物。8. The halogenated polyvinyl chloride composition of claim 1, further comprising an antioxidant selected from the group consisting of topanol and phenol.
３〜４重量部を含む請求項１に記載のハロゲン化ポリ塩
化ビニル組成物。9. The halogenated polyvinyl chloride composition according to claim 1, comprising about 3 to 4 parts by weight of a heat stabilizer per 100 parts by weight of PVC.
シウム及びコロイド状シリカ約１５〜２５重量部を含む
請求項１に記載のハロゲン化ポリ塩化ビニル組成物。10. The halogenated polyvinyl chloride composition of claim 1, comprising about 15 to 25 parts by weight of calcium carbonate and colloidal silica per 100 parts by weight of PVC.
７５〜１００重量部含む請求項１に記載のハロゲン化ポ
リ塩化ビニル組成物。11. The halogenated polyvinyl chloride composition according to claim 1, comprising about 75 to 100 parts by weight of PVC per 100 parts by weight of PVC.
ステル型の熱可塑性ポリウレタンポリマーである請求項
１に記載のハロゲン化ポリ塩化ビニル組成物。12. The halogenated polyvinyl chloride composition according to claim 1, wherein the PVC-compatible urethane polymer is an ester-type thermoplastic polyurethane polymer.
ビニル組成物を製造するための方法であって、 （１）高強度の混合機で、前記ポリ塩化ビニル及び前記
可塑剤を混合する段階と、 （２）前記混合機に前記熱安定剤を添加し、乾燥ブレン
ドを形成する段階と、 （３）前記炭酸塩とシリカ充填剤と潤滑剤とを前記混合
機に添加する段階と、 （４）段階（３）による製品を、粉末の形態で冷却機に
放出し、温度を低下させる段階と、 （５）段階４による製品を、約１６０℃において、可塑
的かつ粒状に自動車の主ケーブルのための絶縁材料とし
て押し出すための適当な製品を得る段階、とを含む方
法。13. The method for producing a halogenated polyvinyl chloride composition according to claim 1, wherein: (1) mixing the polyvinyl chloride and the plasticizer with a high-strength mixer. (2) adding the heat stabilizer to the mixer to form a dry blend; (3) adding the carbonate, silica filler, and lubricant to the mixer; 4) discharging the product from step (3) in the form of a powder to a cooler to reduce the temperature; and Obtaining a suitable product to extrude as an insulating material for the process.
請求項１３に記載の方法。14. The method of claim 13, wherein no additional heat is applied to the high intensity mixer.
なくとも約２分である請求項１３に記載の方法。15. The method of claim 13, wherein the mixing time in step (3) is at least about 2 minutes.
法であって、 ａ）ｉ）ポリ塩化ビニル樹脂（ＰＶＣ）約６０〜１００
重量部、 ｉｉ）ＰＶＣ１００重量部につき、亜鉛を基にした熱安
定剤約１〜６重量部、 ｉｉｉ）ＰＶＣ１００重量部につき、オクタデシル−
３，５−ジテルブチル−４−ヒドロキシヒドロシナメー
ト酸化防止剤約０．２〜２．０重量部、 ｉｖ）ＰＶＣ１００重量部につき、ステアリン酸カルシ
ウム潤滑剤約０．１５〜０．２重量部、 ｖ）ＰＶＣ１００重量部につき、沈殿炭酸カルシウム充
填剤約１０〜５０重量部、 ｖｉ）ＰＶＣ１００重量部につき、コロイド状シリカ充
填剤約１０〜５０重量部、 ｖｉｉ）ＰＶＣ１００重量部につき三酸化アンチモン炎
抑制剤約２８重量部、 ｖｉｉｉ）ケーブルの要求に基づいて選択された適量の
可塑剤、 ｉｘ）ＰＶＣ融和性ウレタン・ポリマーのＰＶＣの量に
基づく重量により約１００％までの任意成分を含み、重
金属を含まないハロゲン化ポリ塩化ビニル組成物を適用
する段階、及び ｂ）ケーブルを高温度にさらす段階、を含む方法。16. A method for insulating automotive cables, comprising: a) i) polyvinyl chloride resin (PVC) of about 60-100.
Parts by weight, ii) about 1 to 6 parts by weight of a zinc-based heat stabilizer per 100 parts by weight of PVC, iii) octadecyl-
About 0.2-2.0 parts by weight of 3,5-diterbutyl-4-hydroxyhydrocinnamate antioxidant; iv) about 0.15-0.2 parts by weight of calcium stearate lubricant per 100 parts by weight of PVC; Per 100 parts by weight of PVC about 10 to 50 parts by weight of precipitated calcium carbonate filler; vi) about 100 to 50 parts by weight of colloidal silica filler per 100 parts by weight of vii) vii) about 28 antimony trioxide flame retardant per 100 parts by weight of PVC Parts by weight, viii) an appropriate amount of plasticizer selected based on the requirements of the cable, ix) halogen containing up to about 100% optional ingredients and no heavy metals by weight based on the amount of PVC of the PVC compatible urethane polymer. Applying a functionalized polyvinyl chloride composition; and b) exposing the cable to elevated temperatures.
き、亜鉛安定剤約３〜４重量部を含む請求項１６に記載
の方法。17. The method of claim 16, wherein the composition comprises about 3 to 4 parts by weight of a zinc stabilizer per 100 parts by weight of PVC.
き、沈殿炭酸カルシウム及びコロイド状シリカの各々を
約１５〜２５重量部を含む請求項１６に記載の方法。18. The method of claim 16, wherein the composition comprises about 15 to 25 parts by weight of each of precipitated calcium carbonate and colloidal silica per 100 parts by weight of PVC.
き、三酸化アンチモン約３〜６重量部を含む請求項１６
に記載の方法。19. The composition according to claim 16, comprising about 3 to 6 parts by weight of antimony trioxide per 100 parts by weight of PVC.
The method described in.
する共エステルフタル酸可塑剤及びアジピン重合体可塑
剤からなる群から選択された請求項１６に記載の方法。20. The method of claim 16, wherein the plasticizer is selected from the group consisting of a coester phthalate plasticizer having 11 and 9 carbon atoms and an adipine polymer plasticizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP37367498A JP4297537B2 (en) | 1998-12-28 | 1998-12-28 | Polyvinyl chloride composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP37367498A JP4297537B2 (en) | 1998-12-28 | 1998-12-28 | Polyvinyl chloride composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2000191873A true JP2000191873A (en) | 2000-07-11 |
| JP4297537B2 JP4297537B2 (en) | 2009-07-15 |
Family
ID=18502571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP37367498A Expired - Fee Related JP4297537B2 (en) | 1998-12-28 | 1998-12-28 | Polyvinyl chloride composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4297537B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100408624B1 (en) * | 2000-10-06 | 2003-12-06 | 엘지전선 주식회사 | Poly vinyl chloride insulator composition for wire and cable |
| CN109535598A (en) * | 2018-11-27 | 2019-03-29 | 杭州介通电缆保护管有限公司 | Power cable communicates protection pipe |
| CN112812461A (en) * | 2020-12-30 | 2021-05-18 | 苏州汇博塑化有限公司 | Semi-hard flame-retardant PVC (polyvinyl chloride) sheath material for optical fibers |
| CN112812460A (en) * | 2020-12-30 | 2021-05-18 | 苏州汇博塑化有限公司 | Environment-friendly high-flame-retardance sheath material for PVC optical cable |
| CN117079872A (en) * | 2023-10-16 | 2023-11-17 | 南方珠江科技有限公司 | Insulated branch cable and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5599942A (en) * | 1979-01-23 | 1980-07-30 | Shin Etsu Polymer Co Ltd | Flame-retardant resin composition |
| JPH0711084A (en) * | 1993-04-16 | 1995-01-13 | Ciba Geigy Ag | Stabilization of polyvinyl chloride |
| JPH07508066A (en) * | 1992-05-19 | 1995-09-07 | クロンプトン・コーポレーション | PVC resin compositions for electrical insulation stabilized using non-lead stabilizers |
| JPH07292196A (en) * | 1994-04-15 | 1995-11-07 | Ciba Geigy Ag | Stabilized polyvinyl chloride |
| JPH08503008A (en) * | 1992-10-30 | 1996-04-02 | シンセティック プロダクツ カンパニー | Vinyl halide resin composition for electrical insulation |
| JPH09132689A (en) * | 1995-09-05 | 1997-05-20 | Mitsui Toatsu Chem Inc | Vinyl chloride resin composition and covered wire using the same |
| JPH09302185A (en) * | 1996-05-15 | 1997-11-25 | Fujikura Ltd | Flexible vinyl chloride resin composition and ptc heating element |
| JPH10212386A (en) * | 1997-01-28 | 1998-08-11 | Sakai Chem Ind Co Ltd | Vinyl chloride resin composition for wire covering |
-
1998
- 1998-12-28 JP JP37367498A patent/JP4297537B2/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5599942A (en) * | 1979-01-23 | 1980-07-30 | Shin Etsu Polymer Co Ltd | Flame-retardant resin composition |
| JPH07508066A (en) * | 1992-05-19 | 1995-09-07 | クロンプトン・コーポレーション | PVC resin compositions for electrical insulation stabilized using non-lead stabilizers |
| JPH08503008A (en) * | 1992-10-30 | 1996-04-02 | シンセティック プロダクツ カンパニー | Vinyl halide resin composition for electrical insulation |
| JPH0711084A (en) * | 1993-04-16 | 1995-01-13 | Ciba Geigy Ag | Stabilization of polyvinyl chloride |
| JPH07292196A (en) * | 1994-04-15 | 1995-11-07 | Ciba Geigy Ag | Stabilized polyvinyl chloride |
| JPH09132689A (en) * | 1995-09-05 | 1997-05-20 | Mitsui Toatsu Chem Inc | Vinyl chloride resin composition and covered wire using the same |
| JPH09302185A (en) * | 1996-05-15 | 1997-11-25 | Fujikura Ltd | Flexible vinyl chloride resin composition and ptc heating element |
| JPH10212386A (en) * | 1997-01-28 | 1998-08-11 | Sakai Chem Ind Co Ltd | Vinyl chloride resin composition for wire covering |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100408624B1 (en) * | 2000-10-06 | 2003-12-06 | 엘지전선 주식회사 | Poly vinyl chloride insulator composition for wire and cable |
| CN109535598A (en) * | 2018-11-27 | 2019-03-29 | 杭州介通电缆保护管有限公司 | Power cable communicates protection pipe |
| CN112812461A (en) * | 2020-12-30 | 2021-05-18 | 苏州汇博塑化有限公司 | Semi-hard flame-retardant PVC (polyvinyl chloride) sheath material for optical fibers |
| CN112812460A (en) * | 2020-12-30 | 2021-05-18 | 苏州汇博塑化有限公司 | Environment-friendly high-flame-retardance sheath material for PVC optical cable |
| CN117079872A (en) * | 2023-10-16 | 2023-11-17 | 南方珠江科技有限公司 | Insulated branch cable and preparation method thereof |
| CN117079872B (en) * | 2023-10-16 | 2024-01-26 | 南方珠江科技有限公司 | Insulated branch cable and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| JP4297537B2 (en) | 2009-07-15 |
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