JP2000160270A - Anvil for forging - Google Patents
Anvil for forgingInfo
- Publication number
- JP2000160270A JP2000160270A JP10333218A JP33321898A JP2000160270A JP 2000160270 A JP2000160270 A JP 2000160270A JP 10333218 A JP10333218 A JP 10333218A JP 33321898 A JP33321898 A JP 33321898A JP 2000160270 A JP2000160270 A JP 2000160270A
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- Prior art keywords
- anvil
- resistance
- forging
- steel
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、鍛造の際に使用さ
れる金敷として適用され、鍛造用金敷に要求される高温
強度、耐摩耗性、耐高温へたり性、対ヒートクラック性
等に優れていると同時に、経済性に優れた鍛造用金敷に
関するものである。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention is applied as an anvil used for forging, and is excellent in high-temperature strength, abrasion resistance, high-temperature set resistance, heat crack resistance, etc. required for forging anvil. At the same time, it relates to an economical forging anvil.
【0002】[0002]
【従来の技術】鋼の熱間加工の一つである鍛造には、鍛
伸、据え込み、タップ成形、背切、穿孔等が有るが、こ
れらの鍛造に際しては金敷と称される鍛圧工具すなわち
鍛造型が使用される。この金敷には、高温強度、耐摩耗
性、耐高温へたり性、対ヒートクラック性等に優れてい
る特性が要求される。従来、この金敷の素材には、機械
構造用炭素鋼(SC)、機械構造用合金鋼(SCM
等)、熱間金型用工具鋼(SKD,SKT等)、Ni基
耐熱超合金(Nimonic80A等)さらには前記鋼
等に対してステライト肉盛したもの、特公平5−476
11号公報に開示されている合金等が使用されていた。2. Description of the Related Art Forging, which is one of the hot working of steel, includes forging, upsetting, tap forming, spine cutting, perforation, etc. In these forgings, a forging tool called an anvil is used. Forging dies are used. The anvil is required to have excellent properties such as high-temperature strength, abrasion resistance, high-temperature resistance, and heat crack resistance. Conventionally, the materials for this anvil include carbon steel for machine structure (SC) and alloy steel for machine structure (SCM).
Etc.), hot die tool steel (SKD, SKT, etc.), Ni-base heat-resistant superalloy (Nimonic 80A, etc.)
No. 11 discloses an alloy or the like.
【0003】[0003]
【発明が解決しようとする課題】上述したような、従来
の金敷素材の内、機械構造用炭素鋼(SC)、機械構造
用合金鋼(SCM等)、熱間金型用工具鋼(SKD,S
KT等)等は、素材が安価で、素材から金敷としての加
工も容易かつ加工費用が安価では有るものの、高温強
度、耐摩耗性、耐高温へたり性等が十分でなく、Ni基
耐熱超合金(Nimonic80A等)は、高温強度、
耐摩耗性、耐高温へたり性、対ヒートクラック性等の金
敷に要求される特性を十分に満足しているものの、素材
が高価で、素材から金敷としての加工が困難かつ加工費
用が高価である。Among the conventional anvil materials as described above, carbon steel for machine structure (SC), alloy steel for machine structure (SCM, etc.), tool steel for hot mold (SKD, S
KT, etc.) are inexpensive, easy to process as anvil from the material, and inexpensive in processing cost, but have insufficient high temperature strength, abrasion resistance, high temperature resistance, etc. Alloys (Nimonic 80A etc.) have high temperature strength,
Although it fully satisfies the characteristics required for anvil such as wear resistance, high temperature resistance, heat crack resistance, etc., the material is expensive, processing from material to anvil is difficult and processing cost is expensive. is there.
【0004】また、Ni基耐熱超合金では、金敷重量が
3tを超える大型の金敷の製造は、素材製造の困難さか
ら一般的なものではない。さらには、ステライト肉盛し
た場合には、ヒートクラックが金敷表面に著しく発生し
やすいため、ヒートクラックが鍛造品に転写され、製品
表面に有害な凹凸がつくという問題があった。また、上
述した特公平5−47611号公報に開示されている合
金製の鍛造用金敷は、金敷全体がその合金よりなるた
め、Ni基耐熱超合金(Nimonic80A等)と同
じく素材高価かつ加工も困難であり、金敷作成の費用が
高額となる問題点があった。[0004] In the case of Ni-base heat-resistant superalloys, the production of large-sized anvils having an anvil weight of more than 3 tons is not common because of difficulty in producing the material. Furthermore, when stellite is overlaid, heat cracks are easily generated on the surface of the anvil, so that the heat cracks are transferred to the forged product, and there is a problem that harmful irregularities are formed on the product surface. Further, the forging anvil made of an alloy disclosed in the above-mentioned Japanese Patent Publication No. 5-47611 is expensive and difficult to work with, as is the case with Ni-based heat-resistant superalloys (Nimonic 80A, etc.) because the entire anvil is made of the alloy. However, there was a problem that the cost of making the anvil was high.
【0005】[0005]
【課題を解決するための手段】本発明は、上述のような
課題を解決するためになされたもので、金敷に要求され
る高温強度、耐摩耗性、耐高温へたり性、対ヒートクラ
ック性等の諸特性に優れていると同時に、特に経済性に
優れた金敷を提供することを目的としている。本発明の
要旨とするところは、鍛造用金敷として、素材が安価か
つ加工が容易な機械構造用炭素鋼(SC)、機械構造用
合金鋼(SCM等)、熱間金型用工具鋼(SKD,SK
T等)等で形成された基部に、鍛造材との接触面へ重量
%で、C:0.05%以下、Si:0.01〜1.0
%、Mn:0.5%以下、Cr:10〜25%、Al:
1.5〜3.0%、Ti:1.0〜3.5%、Co:1
0〜13%、Fe:1.5%以下、Mo:5.5%〜
6.5%、W:0.5%〜2.0%、残部実質的にNi
の化学成分範囲を持ち、かつAl−Ti:5.0%であ
る耐熱性、耐摩耗性、耐高温へたり性に優れた合金粉体
を厚さ10〜30mmで肉盛溶接を行った鍛造用金敷に
ある。本発明による合金は、前述の特公平5−4761
1号公報に開示されている合金に対し、高温強度および
耐摩耗性を向上させるためMoの含有量を高めた点、時
効効果性を向上させるためAl−Ti含有量を溶接限界
である5.0%に限定した点を特徴とする。DISCLOSURE OF THE INVENTION The present invention has been made to solve the above-mentioned problems, and is intended to provide high-temperature strength, abrasion resistance, high-temperature set resistance, and heat crack resistance required for anvils. It is an object of the present invention to provide an anvil that is excellent in various characteristics such as the above and at the same time is particularly excellent in economic efficiency. The gist of the present invention is that forging anvils, carbon steel for machine structure (SC), alloy steel for machine structure (SCM, etc.), tool steel for hot mold (SKD), which is inexpensive and easy to process, are used as forgings. , SK
T), etc., on the contact surface with the forging material in weight%, C: 0.05% or less, Si: 0.01 to 1.0
%, Mn: 0.5% or less, Cr: 10 to 25%, Al:
1.5-3.0%, Ti: 1.0-3.5%, Co: 1
0 to 13%, Fe: 1.5% or less, Mo: 5.5% or more
6.5%, W: 0.5% to 2.0%, balance substantially Ni
Alloy powder with a chemical composition range of 5% and Al-Ti: 5.0%, which is excellent in heat resistance, abrasion resistance, and high-temperature resistance, is subjected to overlay welding with a thickness of 10 to 30 mm. It is in the anvil. The alloy according to the present invention is as described in the above-mentioned Japanese Patent Publication No. 5-4761.
With respect to the alloy disclosed in Japanese Unexamined Patent Publication (Kokai) No. 1 (Kokai), the content of Mo was increased in order to improve the high-temperature strength and wear resistance, and the Al-Ti content was the welding limit in order to improve the aging effect. It is characterized by being limited to 0%.
【0006】図1は、その模式図である。基部1は機械
構造用炭素鋼(SC)、機械構造用合金鋼(SCM
等)、熱間金型用工具鋼(SKD,SKT等)等で形成
され、肉盛部2は重量%で、C:0.05%以下、S
i:0.01〜1.0%、Mn:0.5%以下、Cr:
10〜25%、A :1.5〜3.0%、Ti:1.0
〜3.5%、Co:10〜13%、Fe:1.5%以
下、Mo:5.5%〜6.5%、W:0.5%〜2.0
%、残部実質的にNiの化学成分範囲を持ち、かつAl
−Ti:5.0%である耐熱性、耐摩耗性、耐高温へた
り性に優れた合金粉体で形成されており、肉盛部の厚み
tは10〜30mmである。また、この方法で鍛造用金
敷を作成すれば、従来方法では作成することが困難であ
った大型の鍛造用金敷、たとえば幅1000mm×長さ
1600mm×厚み500mmの平金敷も容易かつ安価
に作成可能である。FIG. 1 is a schematic diagram thereof. The base 1 is made of carbon steel for machine structure (SC), alloy steel for machine structure (SCM
Etc.), tool steel for hot molds (SKD, SKT, etc.), etc., and the overlay portion 2 is in weight%, C: 0.05% or less, S
i: 0.01 to 1.0%, Mn: 0.5% or less, Cr:
10 to 25%, A: 1.5 to 3.0%, Ti: 1.0
To 3.5%, Co: 10 to 13%, Fe: 1.5% or less, Mo: 5.5% to 6.5%, W: 0.5% to 2.0
%, The balance substantially having a chemical composition range of Ni, and Al
-Ti: 5.0%, made of an alloy powder having excellent heat resistance, wear resistance, and high temperature resistance, and the thickness t of the built-up portion is 10 to 30 mm. Also, if a forging anvil is made by this method, a large forging anvil, which is difficult to make by the conventional method, for example, a flat anvil of 1,000 mm in width, 1600 mm in length and 500 mm in thickness can be easily and inexpensively made. It is.
【0007】[0007]
【発明の実施の形態】以下、本発明について詳細に説明
する。本発明による鍛造用金敷は、上金敷、下金敷のい
ずれにも適用可能であり、また、平金敷、タップ金敷、
V型金敷等のいずれにも適用可能である。ここで、本発
明による鍛造用金敷肉盛部の肉盛溶接厚さの限定理由に
ついて説明する。鍛造用金敷に要求される耐熱性、耐摩
耗性、耐高温へたり性を満足させるためには、10mm
以上の厚さで肉盛する必要が有る。しかし、厚すぎれば
肉盛材量費用また肉盛部の加工費用が増大するため30
mm以下とした。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail. The forging anvil according to the present invention can be applied to any of the upper anvil and the lower anvil, and also a flat anvil, a tap anvil,
It can be applied to any of V-shaped anvils and the like. Here, the reason for limiting the overlay welding thickness of the forging anvil overlay according to the present invention will be described. In order to satisfy the heat resistance, abrasion resistance, and high temperature resistance required for forging anvils, 10 mm
It is necessary to build up with the above thickness. However, if the thickness is too large, the cost of the overlay material and the processing cost of the overlay will increase, so that
mm or less.
【0008】次に、本発明による鍛造用金敷肉盛部の成
分範囲(重量%)の限定理由について説明する。 C:0.05%以下 Cは炭化物を形成し、高温強度および高温硬さを高める
のに有効な元素である。しかし、多すぎると靭延性が低
下し、耐割損性が劣化するため0.05%以下とした。 Si:0.01〜1.0% Siは溶製時の脱酸材として作用すると共に耐酸化性を
向上させるのに有効な元素であるため、その効果を出す
ためには、0.01%以上含有させることが必要であ
る。しかし、多すぎれば靭延性が低下するため上限を
1.0%とした。[0008] Next, the reasons for limiting the component range (% by weight) of the forging anvil overlay according to the present invention will be described. C: 0.05% or less C is an element effective for forming carbides and increasing high-temperature strength and high-temperature hardness. However, if the content is too large, the toughness and ductility are reduced, and the fracture resistance is deteriorated. Si: 0.01 to 1.0% Since Si acts as a deoxidizing material during melting and is an element effective for improving oxidation resistance, it is necessary to use 0.01% It is necessary to contain the above. However, if the content is too large, the toughness decreases, so the upper limit is set to 1.0%.
【0009】Mn:0.5%以下 Mnは、溶製時の脱酸材として作用すると共に、SをM
nSとして固定させてSによる害を低減させるのに有効
な元素である。しかし、多量に含有させると耐酸化性が
劣化するので0.5%以下とした。 Cr:10〜25% CrはM耐酸化性を向上させるのに有効な元素であり、
特に粒界酸化を防止するためには10%以上含有させる
必要が有る。しかし、多すぎれば強度および靭延性が劣
化するので25%以下とした。Mn: not more than 0.5% Mn acts as a deoxidizing agent during melting, and forms S
It is an element effective for fixing as nS and reducing harm caused by S. However, if contained in a large amount, the oxidation resistance deteriorates, so the content was made 0.5% or less. Cr: 10 to 25% Cr is an element effective for improving M oxidation resistance.
Particularly, in order to prevent grain boundary oxidation, it is necessary to contain 10% or more. However, if the content is too large, the strength and the ductility are deteriorated.
【0010】Al:1.5〜3.0% Alは、NiおよびTiと結合し、γ’相を形成して高
温強度を向上させるのに有効な元素であるが、その効果
を出すために1.5%以上含有させる必要が有る。しか
し、多すぎれば靭延性を劣化させるので3.0%以下と
した。 Ti:1.0〜3.5% TiはAlと共に高温強度を高めるのに有効な元素であ
り、Alとのバランスにより1.0%以上含有させる。
しかし、多すぎれば靭延性が低下するため3.5%以下
とした。ただし、時効硬化性を高めるAl−Tiの溶接
限界値は5.0%であるため、Al:2.0%、Ti:
3.0%が最適である。Al: 1.5-3.0% Al is an effective element for improving the high-temperature strength by forming a γ 'phase by combining with Ni and Ti. It is necessary to contain 1.5% or more. However, if the content is too large, the ductility is deteriorated. Ti: 1.0 to 3.5% Ti is an element effective for increasing the high-temperature strength together with Al, and is contained in an amount of 1.0% or more in balance with Al.
However, if the content is too large, the ductility decreases, so that the content is set to 3.5% or less. However, since the welding limit value of Al-Ti for improving age hardening is 5.0%, Al: 2.0%, Ti:
3.0% is optimal.
【0011】Co:10〜13% Coは、高温強度を確保すると共に耐酸化性を向上させ
るのに有効な元素であるため、その効果を出すため10
%以上含有させる。しかし、高価であるためNiでの置
換を考慮し13%以下とした。 Fe:1.5%以下 Feは不純物として含まれるものであるが、多すぎれば
耐酸化性を劣化するので1.5%以下とする。Co: 10 to 13% Co is an element effective in securing high-temperature strength and improving oxidation resistance.
% Or more. However, since it is expensive, the content is set to 13% or less in consideration of substitution with Ni. Fe: 1.5% or less Fe is contained as an impurity, but if it is too much, the oxidation resistance deteriorates.
【0012】Mo:5.5%〜6.5% MoはCと結合して炭化物を形成し、高温強度ならびに
耐摩耗性を向上させるのに有効な元素である。その効果
を出すため5.5%以上含有させるが、多すぎれば靭延
性および耐酸化性を劣化させるので6.5%以下とし
た。 W:0.5%〜2.0% WはCと結合して炭化物を形成し、高温強度ならびに耐
摩耗性を向上させるのに有効な元素である。その効果を
出すため0.5%以上含有させるが、多すぎれば靭延性
および耐酸化性を劣化させるので2.0%以下とした。 Ni:残部 NiはCoと共に鍛造用金敷材料として重要な元素であ
り、特にAl,Tiと結合してγ’相Ni3 (A ,T
i)を析出し、高温における強度を高めるので残部とし
た。Mo: 5.5% to 6.5% Mo is an element effective for improving high-temperature strength and abrasion resistance by combining with C to form a carbide. In order to obtain the effect, the content is made 5.5% or more. However, if it is too much, the toughness and the oxidation resistance deteriorate, so the content is made 6.5% or less. W: 0.5% to 2.0% W combines with C to form a carbide, and is an element effective for improving high-temperature strength and wear resistance. To achieve this effect, the content is made 0.5% or more. However, if it is too much, the toughness and oxidation resistance deteriorate, so the content is made 2.0% or less. Ni: balance Ni is an important element together with Co as an anvil material for forging. In particular, γ ′ phase Ni 3 (A, T
i) was precipitated and increased in strength at high temperatures, so the balance was left.
【0013】[0013]
【実施例】表1に示す化学成分の合金および鋼を用意し
て鍛造用金敷を作成し、能力3000Tonのプレスに設
置して、鍛造材にJIS G 4105のクロムモリブデ
ン鋼を温度800〜1250℃で鍛造をおこなった。こ
こで、使用した金敷の耐用寿命(時間)は表2に示す結
果であった。また、金敷の作成費用が安価であるものを
○、やや高価であるものを△、高価であるものを×、使
用した金敷の表面肌が良好であるものを○、不良である
ものを×として表2に示すEXAMPLES Alloys and steels having the chemical components shown in Table 1 were prepared to form an anvil for forging, installed on a press having a capacity of 3000 Ton, and chromium molybdenum steel of JIS G 4105 was used as a forged material at a temperature of 800 to 1250 ° C. Was forged. Here, the service life (hour) of the used anvil was the result shown in Table 2. In addition, those for which the cost of making the anvil are inexpensive are indicated by ○, those which are slightly expensive are indicated by Δ, those which are expensive are indicated by X, those whose surface skin used is good are indicated by ○, and those which are defective are indicated by ×. See Table 2
【0014】[0014]
【表1】 [Table 1]
【0015】[0015]
【表2】 [Table 2]
【0016】表に示すように、本発明の合金組成と構造
をもつ鍛造金敷では、耐用寿命が比較的長く金敷の交換
頻度が少なくてすむと共に、作成費用が比較的安価であ
るため、経済性に非常に優れているという結果が得られ
た。また、金敷基部に発明例であるNo1〜5は熱間金
型用鋼(SKD61相当)を、No6、7は機械構造用
炭素鋼(S45C)を、No8、9は機械構造用合金鋼
(SCM440)を用いたものであるが、金敷基部の熱
間強度の差により耐用寿命に差が生じる結果となった。
また、金敷基部素材価格および加工性の違いにより、金
敷の作成費用の高価な順に発明例No1〜5、発明例N
o8、9、発明例No6、7という結果となった。As shown in the table, the forged anvil having the alloy composition and structure of the present invention has a relatively long service life, requires less frequent replacement of the anvil, and is relatively inexpensive in production cost. The result was very excellent. In addition, No. 1 to No. 5 of the invention example are hot die steel (equivalent to SKD61), No. 6 and No. 7 are carbon steel for machine structure (S45C), and No. 8 and 9 are alloy steel for machine structure (SCM440) at the metal base. ) Was used, but the service life was different due to the difference in the hot strength of the anvil base.
In addition, due to differences in anvil base material price and workability, invention examples No. 1 to 5 and invention example N
o8, 9 and Invention Examples No. 6 and 7.
【0017】これに対して比較例の構造用炭素鋼および
合金工具鋼ではいずれも安価に作成できるものの耐用寿
命が著しく短く、使用後の表面肌が良くないという好ま
しくない結果であった。さらに、Ni基耐熱超合金およ
び、特公平5−47611号公報の例では、耐用寿命が
本発明と比べ長いものの作成費用が著しく高く、総合的
に好ましくない結果となった。On the other hand, both the structural carbon steel and the alloy tool steel of the comparative example can be produced at low cost, but have an unfavorable result in that the service life is extremely short and the surface texture after use is not good. Furthermore, in the case of the Ni-base heat-resistant superalloy and the example of Japanese Patent Publication No. 5-47611, although the service life was longer than that of the present invention, the production cost was extremely high, and the result was totally unfavorable.
【0018】[0018]
【発明の効果】上述したように、この発明による鍛造金
敷は、鍛造金敷として要求される諸特性、例えば高温強
度、耐高温へたり性、耐割損性、耐ヒートクラック性に
優れており、特に金敷作成費用が安価であるため、金敷
補修回数の低減、金敷寿命の増大、金敷交換頻度、鍛造
プレス休止時間の減少、鍛造品寸法精度の向上を安価に
実現することができ、鍛造作業効率の向上はもちろんの
こと、鍛造コストの著しい低減をはかることができると
いう非常に優れた効果をもたらすのである。As described above, the forged anvil according to the present invention is excellent in various properties required for the forged anvil, such as high-temperature strength, high-temperature set resistance, splitting resistance, and heat crack resistance. In particular, since the cost of making the anvil is low, it is possible to reduce the number of times of repairing the anvil, increase the life of the anvil, reduce the frequency of replacing the anvil, reduce the downtime of the forging press, and improve the dimensional accuracy of the forged product. This leads to a very excellent effect that not only can the forging be improved, but also the forging cost can be significantly reduced.
【図1】本発明による鍛造金敷の構造を示す図である。FIG. 1 is a view showing the structure of a forged metal anvil according to the present invention.
1 金敷基部 2 肉盛部 1 Anvil base 2 Overlay
Claims (1)
炭素鋼(SC)、機械構造用合金鋼(SCM等)、熱間
金型用工具鋼(SKD,SKT等)等で形成された基部
に、鍛造材との接触面へ重量%で、 C:0.05%以下、 Si:0.01〜1.0%、 Mn:0.5%以下、 Cr:10〜25%、 Al:1.5〜3.0%、 Ti:1.0〜3.5%、 Co:10〜13%、 Fe:1.5%以下、 Mo:5.5%〜6.5%、 W:0.5%〜2.0%、 残部実質的にNiの化学成分範囲を持ち、かつAl−T
i:5.0%である耐熱性、耐摩耗性、耐高温へたり性
に優れた合金粉体を厚さ10〜30mmで肉盛溶接を行
った鍛造用金敷。1. The material is made of carbon steel for machine structure (SC), alloy steel for machine structure (SCM, etc.), tool steel for hot die (SKD, SKT, etc.), etc., which are inexpensive and easy to process. C: 0.05% or less, Si: 0.01 to 1.0%, Mn: 0.5% or less, Cr: 10 to 25%, Al: 1.5-3.0%, Ti: 1.0-3.5%, Co: 10-13%, Fe: 1.5% or less, Mo: 5.5% -6.5%, W: 0 0.5% to 2.0%, the balance substantially having a chemical composition range of Ni, and Al-T
i: An anvil for forging obtained by overlay-welding an alloy powder having excellent heat resistance, abrasion resistance and high-temperature set resistance of 5.0% to a thickness of 10 to 30 mm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10333218A JP2000160270A (en) | 1998-11-24 | 1998-11-24 | Anvil for forging |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10333218A JP2000160270A (en) | 1998-11-24 | 1998-11-24 | Anvil for forging |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2000160270A true JP2000160270A (en) | 2000-06-13 |
Family
ID=18263645
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10333218A Withdrawn JP2000160270A (en) | 1998-11-24 | 1998-11-24 | Anvil for forging |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2000160270A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010037564A (en) * | 2008-07-31 | 2010-02-18 | Sumitomo Metal Ind Ltd | Method for manufacturing anvil for forging |
JP2012024779A (en) * | 2010-07-20 | 2012-02-09 | Hitachi Metals Ltd | Manufacturing method for anvil, and anvil |
CN104797728A (en) * | 2012-10-31 | 2015-07-22 | 福田金属箔粉工业株式会社 | Ni-cr-co-based alloy having high-temperature corrosion resistance properties, and poppet valve having surface modified with same |
-
1998
- 1998-11-24 JP JP10333218A patent/JP2000160270A/en not_active Withdrawn
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010037564A (en) * | 2008-07-31 | 2010-02-18 | Sumitomo Metal Ind Ltd | Method for manufacturing anvil for forging |
JP2012024779A (en) * | 2010-07-20 | 2012-02-09 | Hitachi Metals Ltd | Manufacturing method for anvil, and anvil |
CN104797728A (en) * | 2012-10-31 | 2015-07-22 | 福田金属箔粉工业株式会社 | Ni-cr-co-based alloy having high-temperature corrosion resistance properties, and poppet valve having surface modified with same |
US9441287B2 (en) | 2012-10-31 | 2016-09-13 | Fukuda Metal Foil & Powder Co., Ltd. | Ni-Cr-Co-based alloy having high-temperature corrosion resistance, and poppet valve surface-modified with the same |
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