JP2000144344A - Ferritic stainless hot rolled steel sheet excellent in surface roughening resistance after forming and high temperature fatigue characteristic - Google Patents

Ferritic stainless hot rolled steel sheet excellent in surface roughening resistance after forming and high temperature fatigue characteristic

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Publication number
JP2000144344A
JP2000144344A JP11361374A JP36137499A JP2000144344A JP 2000144344 A JP2000144344 A JP 2000144344A JP 11361374 A JP11361374 A JP 11361374A JP 36137499 A JP36137499 A JP 36137499A JP 2000144344 A JP2000144344 A JP 2000144344A
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JP
Japan
Prior art keywords
less
steel sheet
forming
ferritic stainless
hot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP11361374A
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Japanese (ja)
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JP3613387B2 (en
Inventor
Masaaki Kono
雅昭 河野
Atsushi Miyazaki
宮崎  淳
Susumu Sato
佐藤  進
Koji Yamato
康二 大和
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
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Priority claimed from JP7156440A external-priority patent/JP3064871B2/en
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP36137499A priority Critical patent/JP3613387B2/en
Publication of JP2000144344A publication Critical patent/JP2000144344A/en
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Publication of JP3613387B2 publication Critical patent/JP3613387B2/en
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Abstract

PROBLEM TO BE SOLVED: To produce a ferritic stainless hot rolled steel sheet good in surface roughening resistance after forming and high temp. fatigue characteristics and moreover free from deterioration in forming workability. SOLUTION: This steel sheet has a componential compsn. contg., by weight, <=0.03% C, <=2.0% Si, <=0.8% MA, <=0.03% S, 6 to 25% Cr, <=0.03% N, <=0.3% Al, <=0.4% Ti, 0.02 to 0.4% V, 0.0002 to 0.0050% B and <=0.5% Nb so as to satisfy Ti/48>N/14, Ti/48+Nb/92>N/14+C/12 and V/B>10, and the balance Fe with inevitable impurities.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は、成形加工用に用いて好
適であり、とくに成形加工後の耐肌荒れ性および疲労特
性に優れるフェライト系ステンレス熱延鋼板に関するも
のである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hot-rolled ferritic stainless steel sheet which is suitable for forming work and is particularly excellent in surface roughening resistance and fatigue properties after forming.

【0002】[0002]

【従来の技術】フェライト系ステンレス鋼は、オーステ
ナイト系ステンレス鋼に比べると加工性や耐食性の点で
はやや劣っているものの、耐応力腐食割れ性に優れると
ともに安価であることから各種厨房器具、自動車排気系
部品(エキゾーストマニホールド、エキゾーストパイ
プ、コンバーターシェル、マフラー等)などの分野で幅
広く使用されている。このような加工用途に用いられる
場合において、フェライト系ステンレス鋼の加工性を改
善するために、例えば特開昭51-14811号公報、特開昭51
-14812号公報、特開昭52-31919号公報などに開示されて
いるように、Ti,Nb といった元素を添加して鋼中に固溶
するCやNなどの不純物元素を固定する技術が広く行わ
れている。
2. Description of the Related Art Ferritic stainless steel is slightly inferior in workability and corrosion resistance compared with austenitic stainless steel, but is excellent in stress corrosion cracking resistance and inexpensive, so it can be used in various kitchen appliances and automobile exhausts. Widely used in fields such as system parts (exhaust manifolds, exhaust pipes, converter shells, mufflers, etc.). When used in such processing applications, in order to improve the workability of ferritic stainless steel, for example, JP-A-51-14811, JP-A-51-14811
As disclosed in JP-14812-A, JP-A-52-31919, etc., techniques for adding elements such as Ti and Nb to fix impurity elements such as C and N which form a solid solution in steel are widely used. Is being done.

【0003】さて、このフェライト系ステンレス鋼板
は、通常、連続鋳造鋳片を加熱した後、熱間圧延一熱延
板焼鈍・酸洗一冷間圧延一仕上げ焼鈍・酸洗の各工程を
経て製造される。そこで、これらのうちの一部の工程、
とくに冷間圧延以降の工程を省略して製造されるステン
レス熱延鋼板は、冷間圧延以降の設備費や運転費を大幅
に軽減できるため、オーステナイト系に比較して安価で
あるフェライト系ステンレス鋼板を一層安価にかつ短期
間に製造することができ、工業上のメリットは極めて大
きい。
[0003] Now, this ferritic stainless steel sheet is usually manufactured by heating a continuous cast slab, followed by steps of hot rolling, hot rolling sheet annealing, pickling, cold rolling, finish annealing, and pickling. Is done. Therefore, some of these steps,
In particular, hot-rolled stainless steel sheets manufactured by omitting the steps after cold rolling can significantly reduce equipment and operating costs after cold rolling, so ferritic stainless steel sheets are cheaper than austenitic steel sheets. Can be manufactured at lower cost and in a shorter time, and the industrial advantage is extremely large.

【0004】[0004]

【発明が解決しようとする課題】しかしながら、一般に
熱延鋼板は冷延鋼板と比較して焼鈍後の結晶粒が大き
く、成形加工後の表面の肌荒れが大きいという問題があ
った。この粗大結晶粒および成形加工後の肌荒れは、表
面の美観を損なうばかりでなく、自動車排気系部品(エ
キゾーストパイプなど)のように、高温下でエンジンな
どの振動を受ける部材においては高温疲労特性を低下さ
せるという問題もあった。この現象は、高温疲労環境下
において、粗大結晶粒を有する組織では、母材より強度
が低い粒界で容易に疲労破壊が発生すること、あるいは
表面肌荒れ部に応力集中し破壊の起点となることにより
説明される。ところで、このように加工後の肌荒れや疲
労破壊特性に大きな影響を及ぼす鋼板の結晶粒径は、焼
鈍の温度・時間などの条件によりある程度調整可能であ
るが、結晶粒径を微細にするために低温・短時間の焼鈍
を施した場合には、完全な再結晶組織は得られなくな
り、鋼板の板厚方向中央部付近は熱延時の展伸組織を残
したままのものとなる。その結果、伸び(El.)や深
絞り性の指標となるランクフォード値(r値)が小さく
なり、十分な成形加工性を得ることが出来ない。これら
のことが、フェライト系ステンレス熱延鋼板における良
好な成形加工性と優れた耐肌あれ性や高温疲労特性を両
立させることを困難にし、前記特性が要求される自動車
排気系部材へのフェライト系ステンレス熱延鋼板の適用
を妨げている大きな原因であった。
However, in general, hot-rolled steel sheets have a problem that crystal grains after annealing are large compared with cold-rolled steel sheets, and the surface roughness after forming is large. The coarse crystal grains and the rough surface after the forming process not only impair the appearance of the surface but also degrade the high-temperature fatigue characteristics of components that are subject to vibration at a high temperature, such as an engine, such as automobile exhaust system parts (exhaust pipes, etc.). There was also the problem of lowering. This phenomenon is that, in a high-temperature fatigue environment, in a structure with coarse crystal grains, fatigue fracture easily occurs at grain boundaries with lower strength than the base material, or stress concentrates on the rough surface surface and becomes the starting point of fracture Described by By the way, the crystal grain size of the steel sheet, which greatly affects the surface roughness and fatigue fracture characteristics after processing, can be adjusted to some extent by conditions such as annealing temperature and time. When annealing is performed at a low temperature and for a short time, a complete recrystallized structure cannot be obtained, and a portion near the center in the thickness direction of the steel sheet retains the expanded structure during hot rolling. As a result, the Rankford value (r value), which is an index of elongation (El.) And deep drawability, becomes small, and sufficient moldability cannot be obtained. These facts make it difficult to achieve both good formability and excellent surface roughening resistance and high-temperature fatigue characteristics in a hot-rolled ferritic stainless steel sheet. This was a major factor hindering the application of hot rolled stainless steel sheets.

【0005】そこで、本発明の目的は、成形加工後の耐
肌荒れ性および高温疲労特性が良好な、しかも成形加工
性を損なうことのない、フェライト系ステンレス熱延鋼
板を提供することにある。
Accordingly, an object of the present invention is to provide a hot-rolled ferritic stainless steel sheet having good surface roughness resistance and high-temperature fatigue characteristics after forming and without impairing formability.

【0006】[0006]

【課題を解決するための手段】さて、上掲の目的の実現
に向けて鋭意研究した結果、発明者らは、フェライト系
ステンレス鋼において、TiによるC,Nの固定、VとB
の複合添加などの化学組成を適正範囲に調整することに
より、成形加工後の耐肌荒れ性、高温疲労特性および成
形加工性のいずれもに優れるステンレス熱延鋼板を製造
可能であることを見いだし、本発明を完成するに至っ
た。
Means for Solving the Problems As a result of diligent research for realizing the above-mentioned object, the inventors have found that, in ferritic stainless steel, C and N are fixed by Ti, V and B are fixed.
It was found that by adjusting the chemical composition, such as the addition of a composite, to an appropriate range, it is possible to manufacture a hot-rolled stainless steel sheet with excellent surface roughness after forming, high-temperature fatigue properties, and formability. The invention has been completed.

【0007】本発明は、上記の考え方を具体化した下記
の構成を要旨とするものである。 (1) C:0.03wt%以下、 Si:2.0 wt%以下 Mn:0.8 wt%以下、 S:0.03wt%以下、 Cr: 6〜25wt%、 N:0.03wt%以下、 Al:0.3 wt%以下、 Ti:0.4 wt%以下、 V:0.02〜0.4 wt%、B:0.0002〜0.0050wt%、 Nb:0.5 wt%以下を含み、かつ下記式: Ti/48 >N/14 Ti/48 +Nb/92 >N/14 +C/12 V/B>10 を満たして含有し、残部がFeおよび不可避的不純物から
なることを特徴とする成形加工後の耐肌あれ性および高
温疲労特性に優れるフェライト系ステンレス熱延鋼板。
The gist of the present invention is as follows, embodying the above concept. (1) C: 0.03 wt% or less, Si: 2.0 wt% or less Mn: 0.8 wt% or less, S: 0.03 wt% or less, Cr: 6 to 25 wt%, N: 0.03 wt% or less, Al: 0.3 wt% or less , Ti: 0.4 wt% or less, V: 0.02-0.4 wt%, B: 0.0002-0.0050 wt%, Nb: 0.5 wt% or less, and the following formula: Ti / 48> N / 14 Ti / 48 + Nb / 92 > N / 14 + C / 12 V / B> 10, with the balance being Fe and unavoidable impurities, the ferrite-based stainless steel heat having excellent surface roughening resistance and high temperature fatigue properties after forming. Rolled steel sheet.

【0008】 (2) C:0.03wt%以下、 Si:2.0 wt%以下 Mn:0.8 wt%以下、 S:0.03wt%以下、 Cr: 6〜25wt%、 N:0.03wt%以下、 Al:0.3 wt%以下、 Ti:0.4 wt%以下、 V:0.02〜0.4 wt%、B:0.0002〜0.0050wt%、 Nb:0.5 wt%以下を含み、かつ下記式: Ti/48 >N/14 Ti/48 +Nb/92 >N/14 +C/12 V/B>10 を満たして含有し、さらに Ca:0.01wt%以下、 Mo:2.0 wt%以下 Cu:2.0 wt%以下 から選ばれるいずれか1種または2種以上を含有し、残
部がFeおよび不可避的不純物からなることを特徴とする
成形加工後の耐肌あれ性および高温疲労特性に優れるフ
ェライト系ステンレス熱延鋼板。
(2) C: 0.03 wt% or less, Si: 2.0 wt% or less Mn: 0.8 wt% or less, S: 0.03 wt% or less, Cr: 6 to 25 wt%, N: 0.03 wt% or less, Al: 0.3 wt% or less, Ti: 0.4 wt% or less, V: 0.02-0.4 wt%, B: 0.0002-0.0050 wt%, Nb: 0.5 wt% or less, and the following formula: Ti / 48> N / 14 Ti / 48 + Nb / 92> N / 14 + C / 12 V / B> 10 is contained, and any one or two selected from Ca: 0.01 wt% or less, Mo: 2.0 wt% or less Cu: 2.0 wt% or less A hot-rolled ferritic stainless steel sheet having excellent wear resistance and high-temperature fatigue properties after forming, characterized by containing at least one seed and the balance consisting of Fe and unavoidable impurities.

【0009】[0009]

【作用】以下、本発明における鋼の各化学成分値を上記
要旨構成のように限定した理由について説明する。 C:0.03wt%以下 Cは、成形加工性(r値)、耐食性を低下させる元素で
あるので、可能な限り低減させることが望ましい。ま
た、後述するようなVの効果を発揮させるためにも、固
溶する量を可能な限り低減することが望ましい。そのた
めに本発明においては、CをTiあるいはさらにNbの
添加により固定し、成形加工性およびフェライト安定性
への悪影響を軽減し、Vの効果を充分に発揮させる。し
かしながら、C含有量が0.03wt%を超えると、鋼板中の
析出物量が増加し加工性の低下および表面性状の悪化を
招くので、その含有範囲を0.03wt%以下、好ましくは0.
015wt%以下とする。
The reasons for limiting the respective chemical component values of the steel according to the present invention in the manner described above will now be described. C: 0.03 wt% or less C is an element that lowers the formability (r value) and the corrosion resistance, so that it is desirable to reduce it as much as possible. In order to exert the effect of V as described later, it is desirable to reduce the amount of solid solution as much as possible. Therefore, in the present invention, C is fixed by adding Ti or further Nb, the adverse effect on the formability and ferrite stability is reduced, and the effect of V is sufficiently exhibited. However, if the C content exceeds 0.03 wt%, the amount of precipitates in the steel sheet increases, leading to a decrease in workability and deterioration of surface properties, so that the content range is 0.03 wt% or less, preferably 0.3 wt%.
015 wt% or less.

【0010】Si:2.0 wt%以下 Siは、鋼の脱酸のために有効なほか、高温での耐酸化
性や高温塩害特性を向上させる元素である。しかし、2.
0 wt%を超えて含有すると伸び特性を劣化させるので、
2.0 wt%以下に限定する。なお、自動車排気系部材など
の用途で使用する場合には、0.6 wt%以上含有すること
が望ましい。
Si: 2.0 wt% or less Si is an element that is effective for deoxidizing steel and also improves oxidation resistance at high temperatures and high-temperature salt damage characteristics. But 2.
If the content exceeds 0 wt%, the elongation characteristics will be deteriorated.
Limited to 2.0 wt% or less. When used for applications such as automobile exhaust system members, it is desirable that the content be 0.6 wt% or more.

【0011】Mn:0.8 wt%以下 Mnは、鋼中のSを析出固定し、熱間圧延性を改善する
のに有効な元素であるが、成形加工性に有害な元素であ
る。従って、その添加範囲は0.8 wt%以下、好ましくは
0.5 wt%以下とする。
Mn: 0.8 wt% or less Mn is an element effective for precipitating and fixing S in steel and improving hot rollability, but is an element harmful to formability. Therefore, the addition range is 0.8 wt% or less, preferably
0.5 wt% or less.

【0012】S:0.03wt%以下 Sは、熱間加工性を劣化させる有害元素であるが、通常
Mnと結合してMnSを形成するため0.03wt%以下の含
有では影響は小さい。しかしながら、0.03wt%を超えて
含有すると析出したMnSが初錆の起点となり耐食性が
劣化するとともに、結晶粒界に偏析し粒界脆化を促進す
る。したがって含有量は、0.03wt%以下、好ましくは0.
005 wt%以下に制限する。
S: 0.03 wt% or less S is a harmful element that degrades hot workability. However, since it is usually combined with Mn to form MnS, the effect is small if the content is 0.03 wt% or less. However, when the content exceeds 0.03 wt%, the precipitated MnS becomes a starting point of initial rust and deteriorates corrosion resistance, and segregates at crystal grain boundaries to promote grain boundary embrittlement. Therefore, the content is 0.03 wt% or less, preferably 0.
Limit to 005 wt% or less.

【0013】Cr:6〜25wt% Crは、耐食性および高温下での耐酸化性を向上させる
ために不可欠な元素である。Crの添加量が6wt%未満
では十分な効果が得られず、一方25wt%を超えて添加
すると加工性が劣化し、素材コストの上昇をも招くた
め、添加量は6wt%〜25wt%とする。なお、成形加工
性を優先する用途への使用を目的とする場合には15wt%
以下とすることが、また常温での耐食性が求められる用
途に使用する場合には10wt%以上とすることが望まし
い。
Cr: 6 to 25 wt% Cr is an indispensable element for improving corrosion resistance and oxidation resistance at high temperatures. If the added amount of Cr is less than 6% by weight, a sufficient effect cannot be obtained. On the other hand, if the added amount exceeds 25% by weight, the workability is deteriorated and the material cost is increased. Therefore, the added amount is 6% by weight to 25% by weight. . 15% by weight for use in applications that prioritize moldability
When used for applications requiring corrosion resistance at room temperature, the content is preferably 10 wt% or more.

【0014】N:0.03wt%以下 Nは、Cと同様に、鋼板の成形加工性(r値)を低下さ
せる元素であるので、可能な限り低減させることが望ま
しい。また、後述するようなBの効果を発揮させるため
にも、固溶する量を可能な限り低減することが望まし
い。そのために本発明においては、NをTiあるいはさ
らにNbの添加により固定し、無害化するしかしなが
ら、その含有量が0.03wt%を超えると鋼板中の析出物量
が増加し、成形加工性の低下および表面性状の悪化を招
く。従って、Nの含有量は0.03wt%以下、好ましくは0.
01wt%以下に制限する。
N: 0.03 wt% or less N, like C, is an element that lowers the formability (r value) of a steel sheet, and therefore it is desirable to reduce it as much as possible. Also, in order to exert the effect of B as described later, it is desirable to reduce the amount of solid solution as much as possible. Therefore, in the present invention, N is fixed by adding Ti or further Nb to render it harmless. However, if its content exceeds 0.03 wt%, the amount of precipitates in the steel sheet increases, and the formability decreases and the surface becomes harder. This leads to deterioration of properties. Therefore, the content of N is 0.03 wt% or less, preferably 0.1 wt%.
Limit to 01 wt% or less.

【0015】Al:0.3 wt%以下 Alは、脱酸に有効な元素であるが、過剰に添加すると
熱延焼鈍板の加工性を劣化させるため、0.3 wt%以下、
好ましくは0.1 wt%以下とする。
Al: 0.3 wt% or less Al is an effective element for deoxidation. However, excessive addition of Al deteriorates the workability of the hot-rolled annealed sheet.
Preferably, it is 0.1 wt% or less.

【0016】Ti:0.4 wt%以下 Tiは、強力なC,N安定化元素であり、成形加工性を
改善する効果を有する。また、Cr炭窒化物の粒界析出
を抑制して耐食性を改善する効果も有する。これらの効
果を発揮させるためには、Tiの添加量は後述するよう
なC,Nとの関係を満たす必要がある。一方、Ti添加
量が0.4 wt%を超えると、成形加工性がかえって低下す
るとともに、溶接部の加工性が大きく低下する。また、
靭性の劣化を引き起こし製造性を低下させる。従って、
Ti添加量は0.4 wt%以下とする。
Ti: 0.4 wt% or less Ti is a powerful element for stabilizing C and N, and has an effect of improving moldability. Further, it also has an effect of suppressing grain boundary precipitation of Cr carbonitride and improving corrosion resistance. In order to exhibit these effects, the amount of Ti added needs to satisfy the relationship with C and N as described later. On the other hand, if the amount of Ti exceeds 0.4 wt%, the formability is rather deteriorated, and the workability of the weld is significantly reduced. Also,
It causes deterioration of toughness and lowers manufacturability. Therefore,
The amount of Ti added is set to 0.4 wt% or less.

【0017】V:0.02〜0.4 wt%、 B:0.0002〜0.0050wt%、かつ V/ B>10 VおよびBは、本発明において極めて重要な元素であ
る。VとBとを、それぞれ0.02〜0.4 wt%、0.0002〜0.
0050wt%、かつV/ B>10を満たして複合添加すること
により、熱延焼鈍板の結晶粒を微細化し、かつ再結晶後
の粒成長を抑制する効果を有する。このような効果が得
られる理由については必ずしも明確ではないが、Vはフ
ェライト粒内に固溶することにより焼鈍時の再結晶粒の
微細化および粒成長抑制し、Bは焼鈍再結晶後のフェラ
イト粒界に濃縮し粒界移動を遅らせることにより粒成長
抑制を補助するものと考えられる。また、VとBの含有
比により効果が異なるのは、フェライト結晶粒の体積と
フェライト粒界面積のバランスが関係するものと思われ
る。このように結晶粒の細粒化が達成されることによ
り、成形加工後の表面の肌荒れが著しく改善され、さら
に、自動車排気系部材(エキゾーストパイプなど)のよ
うに高温下で高サイクルの機械振動を受ける材料の疲労
特性も向上する。結晶粒の細粒化により、疲労特性が向
上する理由は、おおよそ次のような理由によるものと思
われる。 1)応力集中により破壊の起点となりやすい、成形加工
後の肌荒れが軽減できる。 2)粒界は応力集中が大きく亀裂の伝播経路になるが、
細粒化すれば、粒界面積の増加により単位粒界当たりの
応力集中が緩和される。 3)Bの粒界濃縮により、粒界強度が強化される。 ここで、Vは、Ti, NbによるCの析出固定が十分で
ない場合には、Cと反応してVCあるいはVCとし
て析出し粒成長抑制効果が低下する。一方、Bは、Ti
によるNの析出固定が十分でない場合には、Nと反応し
てBNとして析出し、逆に粒成長を促進させる。したが
って、Cは、Vより強力な炭化物形成元素であるTi,
Nbの十分な添加により、Nは、VおよびBより強力な
窒化物形成元素であるTiの十分な添加により析出固定
されなければならない。なお、Bの添加効果は、上記の
ほかに、熱延中の加工歪みの蓄積を促進し、焼鈍後の再
結晶集合組織に関して{111}面の集積を高め、成形
性を改善する効果も有するので、冷延鋼板と比較して成
形性の劣る熱延鋼板にとって添加の意義は大きい。上述
したV,Bの添加効果は、V量が0.02wt%以上、B量が
0.0002wt%以上、かつ各添加量の比V/ B>10を満たし
た場合に始めて発揮される。一方、VおよびBをそれぞ
れ0.4 wt%、0.0050wt%を超えて過剰に添加すると、焼
鈍中の結晶粒微細化および成長抑制、成形性改善の効果
が飽和するだけでなく、逆に材質が硬化し伸び特性が劣
化して成形加工性が低下する。したがって、V量は0.02
〜0.4 wt%、B量は0.0002〜0.0050wt%、かつV/ B>
10とする。
V: 0.02 to 0.4 wt%, B: 0.0002 to 0.0050 wt%, and V / B> 10 V and B are extremely important elements in the present invention. V and B are respectively 0.02 to 0.4 wt%, 0.0002 to 0.
The addition of the composite material in an amount of 0.5 wt% and V / B> 10 has an effect of refining the crystal grains of the hot-rolled annealed sheet and suppressing the grain growth after recrystallization. Although the reason why such an effect can be obtained is not clear, V forms a solid solution in the ferrite grains to suppress refining of the recrystallized grains and suppress grain growth during annealing, and B indicates the ferrite after the annealing recrystallization. It is considered that concentration at the grain boundaries and delay of grain boundary movement assists grain growth suppression. Further, it is considered that the effect differs depending on the content ratio of V and B, because the balance between the volume of ferrite crystal grains and the area of the ferrite grain boundary is related. As a result of the refinement of the crystal grains as described above, the surface roughness after the forming process is remarkably improved, and furthermore, high-temperature mechanical vibration such as automobile exhaust system members (exhaust pipes) at high temperatures. The fatigue properties of the material subjected to the heat are also improved. It is considered that the reason why the fatigue characteristics are improved by the refinement of the crystal grains is as follows. 1) The roughened surface after the forming process, which is likely to be a starting point of destruction due to stress concentration, can be reduced. 2) The grain boundary has a large stress concentration and becomes a crack propagation path.
If the grain size is reduced, stress concentration per unit grain boundary is reduced due to an increase in grain boundary area. 3) Grain boundary strength is enhanced by the grain boundary concentration of B. Here, when precipitation and fixation of C by Ti and Nb is not sufficient, V reacts with C and precipitates as V 2 C or VC, and the effect of suppressing grain growth is reduced. On the other hand, B is Ti
If the precipitation fixation of N is not sufficient, it reacts with N and precipitates as BN, which in turn promotes grain growth. Thus, C is a stronger carbide-forming element than V, Ti,
With sufficient addition of Nb, N must be precipitated and fixed by sufficient addition of Ti, a stronger nitride forming element than V and B. In addition to the above, the effect of the addition of B promotes the accumulation of processing strain during hot rolling, increases the accumulation of {111} planes in the recrystallization texture after annealing, and also has the effect of improving the formability. Therefore, the significance of addition is significant for hot-rolled steel sheets that are inferior in formability as compared with cold-rolled steel sheets. The effect of adding V and B described above is that the V content is 0.02 wt% or more and the B content is
It is exhibited only when 0.0002 wt% or more and the ratio V / B> 10 of each addition amount is satisfied. On the other hand, if V and B are added in excess of 0.4 wt% and 0.0050 wt%, respectively, the effects of grain refinement and growth suppression during annealing and the effect of improving formability are saturated, and conversely, the material hardens. The elongation characteristic deteriorates and the moldability decreases. Therefore, the amount of V is 0.02
~ 0.4 wt%, B content is 0.0002 ~ 0.0050wt%, and V / B>
Assume 10

【0018】Nb:0.5 wt%以下 Nbは、C,N安定化元素であり、Tiを補完して、成
形加工性を改善するとともに、Cr炭窒化物の粒界析出
を抑制して耐食性を改善する効果を有する。これらの効
果を発揮させるためには、Nbの添加量は後述するよう
なC,Nとの関係を満たす必要がある。一方、Nb添加
量が0.5 wt%を超えると、成形加工性がかえって低下す
るとともに、溶接部の加工性が大きく低下する。また、
靭性の劣化を引き起こし製造工程において支障をきた
す。従って、Nb添加量は0.4 wt%以下とする。なお、
Tiと複合添加する場合、Ti+Nbで0.6 wt%以下に
制限するのが好ましい。
Nb: 0.5 wt% or less Nb is a C and N stabilizing element, complements Ti to improve formability and suppresses grain boundary precipitation of Cr carbonitride to improve corrosion resistance. It has the effect of doing. In order to exhibit these effects, the amount of Nb added needs to satisfy the relationship with C and N as described later. On the other hand, if the amount of Nb exceeds 0.5 wt%, the formability is rather deteriorated, and the workability of the weld is significantly reduced. Also,
It causes deterioration of toughness and causes trouble in the manufacturing process. Therefore, the Nb addition amount is set to 0.4 wt% or less. In addition,
When combined with Ti, it is preferable to limit Ti + Nb to 0.6 wt% or less.

【0019】Ti/48 >N/14 かつTi/48 +Nb/92 >N/1
4 +C/12 TiおよびNbは、前述したVおよびBの効果を有効に
作用させるため、すなわち、NをTiNとして、CをT
iCまたはNbCとして析出固定するために添加する。
そこで、化学量論比から、TiおよびNbの複合添加の
場合にはTi/48>N/14 かつTi/48 +Nb/92 >N/14 +
C/12 を満足する量を添加することが必要である。
Ti / 48> N / 14 and Ti / 48 + Nb / 92> N / 1
4 + C / 12 Ti and Nb are effective for the above-mentioned effects of V and B, that is, N is TiN and C is T
It is added to precipitate and fix as iC or NbC.
Therefore, from the stoichiometric ratio, in the case of a composite addition of Ti and Nb, Ti / 48> N / 14 and Ti / 48 + Nb / 92> N / 14 +
It is necessary to add an amount satisfying C / 12.

【0020】本発明では、さらに、必要に応じて以下の
元素を含有することができる。 Ca:0.01wt%以下 Caは、溶鋼中でCaSを生成して、Tiを含有する溶
鋼を鋳造する際に発生するTiS系介在物によるノズル
詰まりを抑制するのに有用な元素である。しかし、過剰
に添加すると耐食性の劣化をもたらすので、その添加量
を0.01wt%以下、好ましくはS含有量との関係において
S≦(32/40)Ca≦1.5 Sの範囲とする。
In the present invention, the following elements can be further contained as needed. Ca: 0.01 wt% or less Ca is an element useful for generating CaS in molten steel and suppressing nozzle clogging due to TiS-based inclusions generated when casting molten steel containing Ti. However, if added excessively, the corrosion resistance deteriorates, so the amount of addition is limited to 0.01 wt% or less, preferably in the range of S ≦ (32/40) Ca ≦ 1.5 S in relation to the S content.

【0021】Mo:2.0 wt%以下 Moは、耐食性を一層向上させる効果があり、必要に応
じて添加することができる。しかしながら、添加量が2.
0 wt%を超えると熱間圧延中の加工性が低下するので、
2.0 wt%以下とする。なお、Cuと複合添加する場合に
は、両者の合計含有量で2.0 wt%以下とするのが望まし
い。
Mo: 2.0 wt% or less Mo has the effect of further improving the corrosion resistance, and can be added as necessary. However, the amount added was 2.
If the content exceeds 0 wt%, the workability during hot rolling is reduced.
2.0 wt% or less. In addition, in the case of adding a composite with Cu, the total content of both is desirably 2.0 wt% or less.

【0022】Cu:2.0 wt%以下 Cuは、耐食性を一層向上させる効果があり、必要に応
じて添加することができる。しかしながら、添加量が2.
0 wt%を超えると熱間圧延中の加工性が低下するので、
2.0 wt%以下とする。なお、Moと複合添加する場合に
は、両者の合計含有量で2.0 wt%以下とするのが望まし
い。
Cu: 2.0 wt% or less Cu has the effect of further improving the corrosion resistance, and can be added as needed. However, the amount added was 2.
If the content exceeds 0 wt%, the workability during hot rolling is reduced.
2.0 wt% or less. When Mo and Mo are added in combination, the total content of both is desirably 2.0 wt% or less.

【0023】なお、Pについては言及しなかったが、P
は、一般にPb、Snと同様に熱間割れ性を高め、熱間
圧延性および熱延板靭性を低下させるので0.03wt%以下
とすることが望ましい。また、本発明鋼板の製造にあた
っては、加熱温度:1250〜1050℃、仕上げ温度:900 〜
600 ℃、巻取温度:700 ℃以下の熱間圧延ののち、800
〜1100℃で焼鈍するのが望ましい。
Although P was not mentioned, P
Is generally 0.03% by weight or less, because it increases the hot cracking property and decreases the hot rolling property and the hot rolled sheet toughness similarly to Pb and Sn. In the production of the steel sheet of the present invention, the heating temperature: 1,250 to 1,050 ° C and the finishing temperature: 900 to 900 ° C.
600 ℃, winding temperature: 800 ℃ after hot rolling below 700 ℃
Annealing at ~ 1100 ° C is desirable.

【0024】[0024]

【実施例】以下、実施例により本発明を具体的に説明す
る。表1に示す化学組成の鋼1〜22を、容量30kgの
真空溶解炉にて溶製した。得られた小型鋼塊を1250℃に
加熱したのち、仕上げ温度:700 ℃、圧延パス数:8パ
スからなる熱間圧延により、板厚2mmの熱延板を製造し
た。この熱延板を表2に示す温度にて60sec 保持の焼鈍
を施し、酸洗した。
The present invention will be described below in detail with reference to examples. Steels 1 to 22 having the chemical compositions shown in Table 1 were melted in a vacuum melting furnace having a capacity of 30 kg. After heating the obtained small ingot to 1250 ° C, a hot-rolled sheet having a thickness of 2 mm was manufactured by hot rolling comprising a finishing temperature of 700 ° C and a number of rolling passes of eight. This hot-rolled sheet was annealed at a temperature shown in Table 2 for 60 seconds and pickled.

【0025】[0025]

【表1】 [Table 1]

【0026】[0026]

【表2】 [Table 2]

【0027】得られた熱延焼鈍板について、表面を#10
00のエメリー紙により研磨して熱延ロール面などの影響
を除去した。この供試材から、圧延方向にJIS13号B
引張試験片を採取し、r値(15%の引張歪みを与えた
後、3点法により測定)を測定した。さらに肌荒れ性の
指標としてこの15%の引張後の試験片について引張方向
の表面粗さ(Ra)を調査した。最後にこの試験片を破
断まで引っ張り、破断伸び(El.)を測定した。ま
た、高温疲労特性は図1に示す板状試験片を用いて、試
験温度700 ℃、試験速度1700回/ 分の曲げモーメントと
するシェンク式高温平面曲げ疲労試験機により評価し
た。試験方法の概要は、図2に示すように、試験片の一
端を固定し逆側に繰り返し曲げモーメントを加えること
により疲労試験が行うものである。図3は、試験結果の
一例として、No. 8(発明例)とNo. 6b(比較例)の
結果を示したものである。このような試験結果より破損
寿命が10サイクルとなる応力(10疲労限応力、
以下単に「疲労限応力」と略記する。)を求めた。上記
の方法により、成形加工性(r値、破断伸び)、耐肌荒
れ性(Ra)、高温疲労特性(疲労限応力)を評価しこ
れらの試験結果を表2に示す。
The surface of the obtained hot-rolled annealed sheet was # 10
Polishing was carried out with emery paper No. 00 to remove the influence of the hot roll surface. From this test material, JIS No. B
Tensile test specimens were sampled, and the r value (measured by a three-point method after 15% tensile strain) was measured. Further, the surface roughness (Ra) in the tensile direction of the test piece after 15% tension was examined as an index of the surface roughness. Finally, the test piece was pulled to break and the elongation at break (El.) Was measured. The high-temperature fatigue characteristics were evaluated using a plate-shaped test piece shown in FIG. 1 by a Schenk-type high-temperature plane bending fatigue tester at a test temperature of 700 ° C. and a bending speed of 1700 times / minute. The outline of the test method is to perform a fatigue test by fixing one end of a test piece and repeatedly applying a bending moment to the opposite side, as shown in FIG. FIG. 3 shows the results of No. 8 (inventive example) and No. 6b (comparative example) as an example of the test results. Stress such test results from damage life is 10 7 cycles (10 7 fatigue limit stress,
Hereinafter, it is simply abbreviated as “fatigue limit stress”. ). Formability (r value, elongation at break), surface roughness resistance (Ra), and high temperature fatigue properties (fatigue limit stress) were evaluated by the above method. The test results are shown in Table 2.

【0028】鋼1〜3は11wt%Crベースのものであ
る。VとBの添加量が不足する鋼1を850℃で焼鈍し
たNo. 1aは、焼鈍温度が低く再結晶不足であり、伸
び、r値が低かった。焼鈍温度を900℃に高めたNo.
1bは、伸び、r値は向上し加工性は満足するものの、
表面粗度がRa=7,3と高く、目視によっても激しい
肌荒れが確認された。さらに焼鈍温度を950℃に高め
たNo. 1cは、耐肌荒れ性が一層劣化するだけでなく、
疲労限応力も成形加工性を満足する焼鈍温度で製造した
No. 1bに対して7.7%低下してしまい高温疲労特性
も劣化することがわかる。また、B添加量が不足する鋼
を900℃で焼鈍したNo. 2は、No. 1bに対して耐肌
荒れ性および高温疲労特性は若干向上するもののその効
果は十分ではない。V添加量が不足するNo. 3も同様で
ある。
Steels 1 to 3 are based on 11 wt% Cr. No. 1a, annealed at 850 ° C., of Steel 1 with insufficient amounts of V and B, had a low annealing temperature, lacked recrystallization, and had a low elongation and low r-value. No. 1 with an annealing temperature raised to 900 ° C
1b is elongation, r value is improved and workability is satisfied,
The surface roughness was as high as Ra = 7.3, and severe skin roughness was confirmed visually. Further, No. 1c in which the annealing temperature was increased to 950 ° C. not only further deteriorated the rough surface resistance,
Manufactured at an annealing temperature that satisfies moldability and fatigue limit stress
It can be seen that the temperature is reduced by 7.7% with respect to No. 1b, and the high temperature fatigue property is also deteriorated. Further, No. 2 obtained by annealing steel having an insufficient amount of B at 900 ° C. slightly improves the surface roughening resistance and the high-temperature fatigue property with respect to No. 1b, but the effect is not sufficient. The same applies to No. 3 where the amount of V added is insufficient.

【0029】鋼6〜12は、15Cr系でTi−Nb複
合添加したものである。V,Bの添加量が不足する鋼6
は、950℃の焼鈍(No. 6a)では再結晶が十分では
なく、伸び,r値が低く、また焼鈍温度を1000℃
(No. 6b)に高めると加工性は向上するものの再結晶
粒が粗大化し、耐肌荒れ性および高温疲労特性が劣化す
る。また、VとBを含有してもV/Bが低すぎるNo. 7
は、耐肌荒れ性、疲労特性ともNo. 6bに比して若干の
向上は見られるもののその効果は僅かである。それに対
して、鋼6をベースにV,Bを複合添加した発明例No.
8〜10はいずれも良い成形加工性を有しつつ、良好な
耐肌荒れ性(Ra:3.0 以下)を示し、さらに良好な高
温疲労特性(疲労限応力:90MPa以上で、No. 6bに
対して11%以上向上)を有していることが分かる。な
お、Bを過剰に含む比較例No. 11、Vを過剰に含む比
較例No. 12はいずれも加工性(伸び、r値)が劣って
いる。
Steels 6 to 12 are 15Cr-based and Ti-Nb composite added. Steel 6 with insufficient amounts of V and B added
In 950 ° C. annealing (No. 6a), recrystallization was not sufficient, elongation and r value were low, and the annealing temperature was 1000 ° C.
When it is increased to (No. 6b), the workability is improved, but the recrystallized grains are coarsened, and the surface roughening resistance and the high temperature fatigue property are deteriorated. No. 7 where V / B is too low even if V and B are contained
In the case of No. 6b, although the surface roughening resistance and the fatigue properties are slightly improved as compared with No. 6b, the effect is slight. On the other hand, Invention Example No. No.
Nos. 8 to 10 all have good moldability, show good surface roughness resistance (Ra: 3.0 or less), and further have good high-temperature fatigue properties (fatigue limit stress: 90 MPa or more; 11% or more). In each of Comparative Example No. 11 containing excessive B and Comparative Example No. 12 containing excessive V, workability (elongation, r value) is inferior.

【0030】鋼13〜22は、18Cr系のものであ
る。V,Bの量が不足するNo. 13は、再結晶粒が粗大
化し、耐肌荒れ性および高温疲労特性に劣る。C量が過
剰なNo. 14は常温での成形加工性が劣るばかりでな
く、耐肌荒れ性および高温疲労強度も低い。N量に対し
てTiが不足するNo. 15は耐肌荒れ性に劣る。それに
対し発明例No. 16、17、18a、19はいずれも優
れた耐肌荒れ性および高温疲労特性を有している。ま
た、より高温の1100℃で焼鈍した18bも粒成長は
抑制されており、1050℃で焼鈍した比較例No. 13
よりも良好な成形性、耐肌荒れ性、高温疲労特性を示
す。この傾向は、さらにMoを添加したNo. 20やCu
を添加したNo. 21、MoとCuを添加したNo. 22に
おいても同様である。
The steels 13 to 22 are of 18Cr type. In No. 13 in which the amounts of V and B are insufficient, the recrystallized grains are coarse, and the surface roughening resistance and the high temperature fatigue properties are inferior. No. 14 having an excessive C content not only has poor moldability at room temperature, but also has poor surface roughness resistance and high temperature fatigue strength. No. 15 in which Ti is insufficient with respect to the N content is inferior in rough surface resistance. In contrast, Invention Examples Nos. 16, 17, 18a, and 19 all have excellent surface roughness resistance and high-temperature fatigue characteristics. Also, the grain growth of 18b annealed at a higher temperature of 1100 ° C. was suppressed, and Comparative Example No. 13 annealed at 1050 ° C.
It shows better moldability, surface roughening resistance, and high temperature fatigue properties. This tendency can be seen in No. 20 and Cu with further addition of Mo.
The same applies to No. 21 to which Mo is added and No. 22 to which Mo and Cu are added.

【0031】[0031]

【発明の効果】上述したように、本発明によれば、成形
加工性を劣化させることなく、成形加工後の表面の肌荒
れや高温振動環境下での高温疲労特性を向上させること
が可能となるので、従来高価な冷延鋼板を用いざるを得
なかった自動車排気系部材等の用途にも適用可能なフェ
ライト系ステンレス熱延鋼板が提供できる。さらに、本
発明によれば、熱延鋼板の焼鈍時における焼鈍温度域が
広範囲に許容できるので工業的に容易に製造可能にな
る。
As described above, according to the present invention, it is possible to improve the surface roughness after forming and the high-temperature fatigue characteristics in a high-temperature vibration environment without deteriorating the formability. Therefore, it is possible to provide a hot rolled ferritic stainless steel sheet which can also be used for automobile exhaust system members and the like, which has conventionally had to use expensive cold rolled steel sheets. Furthermore, according to the present invention, an annealing temperature range during annealing of a hot-rolled steel sheet can be allowed in a wide range, so that it can be industrially easily manufactured.

【図面の簡単な説明】[Brief description of the drawings]

【図1】シェンク式高温平面曲げ疲労試験用板状試験片
を示した図である。
FIG. 1 is a view showing a plate-shaped test piece for a Schenk type high temperature plane bending fatigue test.

【図2】シェンク式高温平面曲げ疲労試験方法の概略を
示した図である。
FIG. 2 is a view schematically showing a Schenk type high-temperature plane bending fatigue test method.

【図3】高温疲労試験による破損寿命と疲労限応力の関
係を示したグラフである。
FIG. 3 is a graph showing a relationship between a fracture life and a fatigue limit stress by a high-temperature fatigue test.

【手続補正書】[Procedure amendment]

【提出日】平成12年1月7日(2000.1.7)[Submission date] January 7, 2000 (2000.1.7)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】特許請求の範囲[Correction target item name] Claims

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【特許請求の範囲】[Claims]

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0003[Correction target item name] 0003

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0003】さて、このフェライト系ステンレス鋼板
は、通常、連続鋳造鋳片を加熱した後、熱間圧延熱延
板焼鈍・酸洗冷間圧延仕上げ焼鈍・酸洗の各工程を
経て製造される。そこで、これらのうちの一部の工程、
とくに冷間圧延以降の工程を省略して製造されるステン
レス熱延鋼板は、冷間圧延以降の設備費や運転費を大幅
に軽減できるため、オーステナイト系に比較して安価で
あるフェライト系ステンレス鋼板を一層安価にかつ短期
間に製造することができ、工業上のメリットは極めて大
きい。
[0003] Now, the ferritic stainless steel sheet is generally after heating the continuously cast slab, hot rolling - hot-rolled sheet annealing, pickling - cold rolling - through each step of finish annealing, pickling production Is done. Therefore, some of these steps,
In particular, hot-rolled stainless steel sheets manufactured by omitting the steps after cold rolling can significantly reduce equipment and operating costs after cold rolling, so ferritic stainless steel sheets are cheaper than austenitic steel sheets. Can be manufactured at lower cost and in a shorter time, and the industrial advantage is extremely large.

【手続補正3】[Procedure amendment 3]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0006[Correction target item name] 0006

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0006】[0006]

【課題を解決するための手段】さて、上掲の目的の実現
に向けて鋭意研究した結果、発明者らは、フェライト系
ステンレス鋼において、TiによるC,Nの固定、VとB
の複合添加などの化学組成を適正範囲に調整することに
より、成形加工後の耐肌荒れ性、高温疲労特性および成
形加工性のいずれにも優れるステンレス熱延鋼板を製造
可能であることを見いだし、本発明を完成するに至っ
た。
Means for Solving the Problems As a result of diligent research for realizing the above-mentioned object, the inventors have found that, in ferritic stainless steel, C and N are fixed by Ti, V and B are fixed.
Of By adjusting the appropriate range of chemical composition, such as a combined addition, found that molding after surface roughening resistance, can be manufactured of stainless hot-rolled steel sheet excellent in any of the high temperature fatigue characteristics and moldability, the The invention has been completed.

【手続補正4】[Procedure amendment 4]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0007[Correction target item name] 0007

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0007】本発明は、上記の考え方を具体化した下記
の構成を要旨とするものである。 (1) C:0.03wt%以下、 Si:2.0 wt%以下 Mn:0.8 wt%以下、 S:0.002 超〜0.03wt%、 Cr: 6〜25wt%、 N:0.03wt%以下、 Al:0.3 wt%以下、 Ti:0.4 wt%以下、 V:0.02〜0.4 wt%、 B:0.0002〜0.0050wt%、 Nb:0.5 wt%以下を含み、かつ下記式: Ti/48 >N/14 Ti/48 +Nb/92 >N/14 +C/12 V/B>10 を満たして含有し、残部がFeおよび不可避的不純物から
なることを特徴とする成形加工後の耐肌あれ性および高
温疲労特性に優れるフェライト系ステンレス熱延鋼板。
[0007] The present invention provides the following that embodies the above concept.
The gist of the configuration is as follows. (1) C: 0.03 wt% or less, Si: 2.0 wt% or less Mn: 0.8 wt% or less, S:0.002 or more0.03wt%,  Cr: 6 to 25 wt%, N: 0.03 wt% or less, Al: 0.3 wt% or less, Ti: 0.4 wt% or less, V: 0.02 to 0.4 wt%, B: 0.0002 to 0.0050 wt%, Nb: 0.5 wt% or less And the following formula: Ti / 48> N / 14 Ti / 48 + Nb / 92> N / 14 + C / 12 V / B> 10, the balance being Fe and unavoidable impurities.
Characterized by high skin roughness after molding
Ferritic stainless steel hot rolled steel sheet with excellent thermal fatigue properties.

【手続補正5】[Procedure amendment 5]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0008[Correction target item name] 0008

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0008】(2) C:0.03wt%以下、 Si:2.0 wt%以
下 Mn:0.8 wt%以下、 S:0.002 超〜0.03wt%、 Cr: 6〜25wt%、 N:0.03wt%以下、 Al:0.3 wt%以下、 Ti:0.4 wt%以下、 V:0.02〜0.4 wt%、 B:0.0002〜0.0050wt%、 Nb:0.5 wt%以下を含み、かつ下記式: Ti/48 >N/14 Ti/48 +Nb/92 >N/14 +C/12 V/B>10 を満たして含有し、さらに Ca:0.01wt%以下、 Mo:2.0 wt%以下 Cu:2.0 wt%以下 から選ばれるいずれか1種または2種以上を含有し、残
部がFeおよび不可避的不純物からなることを特徴とする
成形加工後の耐肌あれ性および高温疲労特性に優れるフ
ェライト系ステンレス熱延鋼板。
(2) C: 0.03 wt% or less, Si: 2.0 wt% or less
Lower Mn: 0.8 wt% or less, S:0.002 or more0.03wt%,  Cr: 6 to 25 wt%, N: 0.03 wt% or less, Al: 0.3 wt% or less, Ti: 0.4 wt% or less, V: 0.02 to 0.4 wt%, B: 0.0002 to 0.0050 wt%, Nb: 0.5 wt% or less And satisfying the following formula: Ti / 48> N / 14 Ti / 48 + Nb / 92> N / 14 + C / 12 V / B> 10, Ca: 0.01 wt% or less, Mo: 2.0 wt % Or less Cu: 2.0 wt% or less
Characterized in that the part consists of Fe and inevitable impurities
Excellent in surface roughening resistance and high temperature fatigue properties after molding
Hot-rolled stainless steel sheet.

【手続補正6】[Procedure amendment 6]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0014[Correction target item name] 0014

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0014】N:0.03wt%以下 Nは、Cと同様に、鋼板の成形加工性(r値)を低下さ
せる元素であるので、可能な限り低減させることが望ま
しい。また、後述するようなBの効果を発揮させるため
にも、固溶する量を可能な限り低減することが望まし
い。そのために本発明においては、NをTiあるいはさ
らにNbの添加により固定し、無害化するしかしなが
ら、その含有量が0.03wt%を超えると鋼板中の析出物量
が増加し、成形加工性の低下および表面性状の悪化を招
く。従って、Nの含有量は0.03wt%以下、好ましくは0.
01wt%以下に制限する。
N: 0.03 wt% or less N, like C, is an element that lowers the formability (r value) of a steel sheet, and therefore it is desirable to reduce it as much as possible. Also, in order to exert the effect of B as described later, it is desirable to reduce the amount of solid solution as much as possible. Therefore, in the present invention, N is fixed and rendered harmless by the addition of Ti or Nb . However, if the content exceeds 0.03 wt%, the amount of precipitates in the steel sheet increases, leading to deterioration in formability and deterioration in surface properties. Therefore, the content of N is 0.03 wt% or less, preferably 0.1 wt%.
Limit to 01 wt% or less.

【手続補正7】[Procedure amendment 7]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0025[Correction target item name] 0025

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0025】[0025]

【表1】 [Table 1]

【手続補正8】[Procedure amendment 8]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0026[Correction target item name] 0026

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0026】[0026]

【表2】 [Table 2]

───────────────────────────────────────────────────── フロントページの続き (72)発明者 佐藤 進 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社技術研究所内 (72)発明者 大和 康二 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社技術研究所内 ──────────────────────────────────────────────────続 き Continuing from the front page (72) Inventor Susumu Sato 1 Kawasaki-cho, Chuo-ku, Chiba City, Chiba Prefecture Inside the Technical Research Institute of Kawasaki Steel Co., Ltd. (72) Koji Yamato 1 Kawasaki-cho, Chuo-ku, Chiba City, Chiba Prefecture Kawasaki Steel Research Institute

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】C:0.03wt%以下、 Si:2.0 wt%以下 Mn:0.8 wt%以下、 S:0.03wt%以下、 Cr: 6〜25wt%、 N:0.03wt%以下、 Al:0.3 wt%以下、 Ti:0.4 wt%以下、 V:0.02〜0.4 wt%、B:0.0002〜0.0050wt%、 Nb:0.5 wt%以下を含み、かつ下記式: Ti/48 >N/14 Ti/48 +Nb/92 >N/14 +C/12 V/B>10 を満たして含有し、残部がFeおよび不可避的不純物から
なることを特徴とする成形加工後の耐肌あれ性および高
温疲労特性に優れるフェライト系ステンレス熱延鋼板。
C: 0.03 wt% or less, Si: 2.0 wt% or less Mn: 0.8 wt% or less, S: 0.03 wt% or less, Cr: 6 to 25 wt%, N: 0.03 wt% or less, Al: 0.3 wt% %, Ti: 0.4 wt% or less, V: 0.02 to 0.4 wt%, B: 0.0002 to 0.0050 wt%, Nb: 0.5 wt% or less, and the following formula: Ti / 48> N / 14 Ti / 48 + Nb / 92> N / 14 + C / 12 V / B> 10, with the balance being Fe and unavoidable impurities, characterized by having excellent surface roughening resistance and high temperature fatigue properties after forming. Stainless hot rolled steel sheet.
【請求項2】C:0.03wt%以下、 Si:2.0 wt%以下 Mn:0.8 wt%以下、 S:0.03wt%以下、 Cr: 6〜25wt%、 N:0.03wt%以下、 Al:0.3 wt%以下、 Ti:0.4 wt%以下、 V:0.02〜0.4 wt%、B:0.0002〜0.0050wt%、 Nb:0.5 wt%以下を含み、かつ下記式: Ti/48 >N/14 Ti/48 +Nb/92 >N/14 +C/12 V/B>10 を満たして含有し、さらに Ca:0.01wt%以下、 Mo:2.0 wt%以下 Cu:2.0 wt%以下 から選ばれるいずれか1種または2種以上を含有し、残
部がFeおよび不可避的不純物からなることを特徴とする
成形加工後の耐肌あれ性および高温疲労特性に優れるフ
ェライト系ステンレス熱延鋼板。
2. C: 0.03 wt% or less, Si: 2.0 wt% or less Mn: 0.8 wt% or less, S: 0.03 wt% or less, Cr: 6 to 25 wt%, N: 0.03 wt% or less, Al: 0.3 wt% %, Ti: 0.4 wt% or less, V: 0.02 to 0.4 wt%, B: 0.0002 to 0.0050 wt%, Nb: 0.5 wt% or less, and the following formula: Ti / 48> N / 14 Ti / 48 + Nb / 92> N / 14 + C / 12 V / B> 10, and any one or two selected from Ca: 0.01 wt% or less, Mo: 2.0 wt% or less Cu: 2.0 wt% or less A hot-rolled ferritic stainless steel sheet having the above characteristics, the balance being Fe and unavoidable impurities, and having excellent surface roughening resistance and high-temperature fatigue properties after forming.
JP36137499A 1995-06-22 1999-12-20 Ferritic stainless steel hot rolled steel sheet with excellent skin resistance and high temperature fatigue properties after forming Expired - Lifetime JP3613387B2 (en)

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