JP2000079796A - Laminate film for manufacturing insert molding, manufacture of insert film using the film, and manufacture of insert molding - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a laminate film and the method for manufacturing a deeply drawn three-dimensionally shaped insert molding having a surface excellent in wear resistance and chemical resistance by employing the laminate film. SOLUTION: This laminate film has a release film 3 made of a heat resisting film having a release surface, a transfer layer 4 and a shapable film 2, the elongation represented by the area formed on the transfer surface of the transfer layer after preforming/that before preforming X 100(%) of which can be 150 % or more. In addition, this transfer layer 4 is equipped with a surface protective layer 5 made of the heat reactive body of a head and active energy containing a polymer having its (meth)acrylic equivalent of 100-300 g/eq, its hydroxyl group value of 20-500 and its weight average molecular weight of 5,000-50,000 and a multifunctional isocyanate formed on the release surface of the release film, and further, in the transfer layer or between the transfer layer and the shapable film, the transfer layer has a pasting layer 8 for bonding the shapable film.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a laminated film and an insert film for imparting abrasion resistance and chemical resistance to the surface of a deep drawn three-dimensionally shaped insert molded product, and to abrasion resistance on the surface. The present invention also relates to a method for producing a deep drawn three-dimensional insert molded article provided with chemical resistance.

The present invention is particularly applicable to power window switches, floor console panels, switch bases,
It is useful for manufacturing automobile interior panels such as door trim panels, meter gauges, and dashboards, and automobile exterior panels such as moldings, wheel caps, center pillars, door mirrors, and tail lamps.

[0003]

2. Description of the Related Art As a method for producing a molded article having excellent surface abrasion resistance and chemical resistance, a transfer film having a layer including a surface protective layer as a transfer layer on one side of a release film is used. Insert the transfer film into the molding die so that the transfer layer is inside and adhere to the molding resin, close the die and inject the molten molding resin into the cavity to inject and fill the resin molded product. At the same time as obtaining, a transfer layer having a surface protective layer is adhesively coated on the surface, a molded product is taken out from the mold, the release film is peeled off, and then the surface protective layer is cured by various means. there were.

As a transfer film used in such a method, for example, JP-A-10-58895 discloses a release film and a (meth) acrylic equivalent of 100 to 300 g / eq formed on the release surface. Includes a tack-free surface protective layer which is obtained by thermally reacting a heat and active energy ray-curable resin composition containing a polymer having a hydroxyl value of 20 to 500 and a weight average molecular weight of 5,000 to 50,000 and a polyfunctional isocyanate as an active ingredient. One having a transfer layer is described. The surface protective layer is completely cured by irradiating with an active energy ray after removing the molded product from the mold and peeling and removing the release film.

In this transfer film, since the surface protective layer is tack-free, it is easy to print another layer thereon or to wind up the transfer film. In addition, the surface protective layer is not completely cured until it is irradiated with active energy rays, and is rich in flexibility.
It has an excellent feature that it can sufficiently follow the surface of a molded article having a three-dimensional shape.

[0006]

However, in this transfer film, in order to make the surface protective layer tack-free, it is necessary to perform a thermal reaction with the surface protective layer formed on the release film. At that time, generally, 100
Heated in the range of ~ 180 ° C.

[0007] Therefore, when a material having no heat resistance is used as the release film and passed through a heated atmosphere, the release film extends in the tension direction due to the tension applied for feeding the film, and the surface is wavy. Or cut. If the release film is stretched and the surface is wavy, it may cause wrinkles, and when a pattern layer is printed on the surface protective layer in a later step, it becomes difficult to obtain a desired pattern. Furthermore, dimensional stability becomes a problem when heating in a later step, for example, at the time of drying each of the printed layers, at the time of heat treatment of the anchor layer or the like, or at the time of forming the deposited layer. That is, in the transfer film described in the above publication, it is necessary to use a material having excellent heat resistance for the release film.

[0008] However, such heat-resistant materials generally have poor flexibility. For example, a polyethylene terephthalate resin film (biaxially stretched) is excellent in heat resistance to the above-mentioned heating, but is insufficient in flexibility, so that it cannot sufficiently conform to the surface of a deep drawn three-dimensional shape.

As a result, in the transfer film having the surface protective layer described in the above-mentioned publication, the surface protective layer is rich in flexibility, but the release film is poor in flexibility. There is a problem that it is not possible to sufficiently conform to the surface of the three-dimensional shape and cannot be used for manufacturing such a molded product.

SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to solve the above-mentioned problems, and an object of the present invention is to provide a three-dimensional insert molded product having a deep drawing with a wear-resistant and chemical-resistant surface. Provide a laminated film and an insert film that can be used to form a protective layer, and use these films to manufacture a deep drawn three-dimensional insert molded product having a surface excellent in wear resistance and chemical resistance. It is to provide a method.

[0011]

In order to achieve the above object, a laminated film for producing an insert molded product according to the present invention comprises:
A release film made of a heat-resistant film material having a release surface, a transfer layer formed on the release surface of the release film, and an area formed on the transfer surface of the transfer layer after preforming / before preforming And a shape-forming film made of a film material having a shape-forming property capable of elongation of 150% or more represented by the area of × 100 (%) of the release layer on the release surface of the release film. (Meth) acrylic equivalent formed 100-300 g / eq, hydroxyl value
20 to 500, having a surface protective layer which is a thermal reactant of a heat and active energy ray-curable resin composition containing a polymer having a weight average molecular weight of 5,000 to 50,000 and a polyfunctional isocyanate as an active ingredient, in a transfer layer or It has a bonding layer for bonding the shapeable film between the transfer layer and the shapeable film.

The release film may be a polyethylene terephthalate resin film.

The shape-forming film is made of a soft vinyl chloride film, a non-stretched polypropylene film, a non-stretched polyester film, a polycarbonate film, a film made of an acrylic resin and an acrylic rubber, and a copolymer resin (AS) of styrene and acrylonitrile. The film may be at least one selected from the group consisting of a film made of a copolymer resin (ABS) of styrene, butadiene and acrylonitrile.

The above-mentioned polymer can be a reaction product of an addition reaction of an α, β-unsaturated monocarboxylic acid with a glycidyl (meth) acrylate polymer.

The glycidyl (meth) acrylate polymer is a homopolymer of glycidyl (meth) acrylate or a copolymer of glycidyl (meth) acrylate and an α, β-unsaturated monomer containing no carboxyl group. It can be.

The transfer layer may have a design layer for decoration.

A pattern layer for decoration may be provided on the surface of the shape-forming film.

The insert film of the present invention can be manufactured by peeling off the release film from the laminated film.

The method for producing an insert molded product of the present invention comprises:
A step of peeling and removing the release film from the laminated film; a step of inserting and placing the remaining insert film in a molding die with the formable film inside; Closing the mold, injecting and filling the molten resin into the cavity, molding the resin, and simultaneously bonding and covering the surface with an insert film; and applying an active energy ray to the surface protective layer of the insert film. Curing the surface protective layer by irradiation.

The term "insert film" refers to a film material used by inserting it into a mold in the process of manufacturing an insert molded product.

Further, “has shapeability” means, for example,
In the manufacturing process of the insert molded product using the laminated film schematically shown in FIGS. 7 to 11, the film supporting the surface protective layer is deformed along the cavity surface of the mold corresponding to the three-dimensional shape of the deep drawing. Say they have enough flexibility to do so. "Poor shapeability" means that, for example, a polyethylene terephthalate film has insufficient flexibility and can only fit along a three-dimensional surface with a shallow aperture.

[0022]

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A laminated film for producing an insert molded product, a method for producing an insert film using the laminated film, and a method for producing an insert molded product according to the present invention will be described below in detail with reference to the drawings.

FIG. 1 is a sectional view showing an embodiment of the laminated film according to the present invention. FIG. 2 is a sectional view showing another embodiment of the laminated film according to the present invention. FIG. 3 is a sectional view showing another embodiment of the laminated film according to the present invention. FIG.
FIG. 4 is a sectional view showing another embodiment of the laminated film according to the present invention. FIG. 5 is a sectional view showing another embodiment of the laminated film according to the present invention. FIG. 6 is a sectional view showing another embodiment of the laminated film according to the present invention. FIG. 7 is a view showing one embodiment of the manufacturing process of the insert molded product according to the present invention. FIG. 8 is a view showing one embodiment of the manufacturing process of the insert molded product according to the present invention. FIG. 9 is a diagram showing one embodiment of the manufacturing process of the insert molded product according to the present invention. FIG.
FIG. 3 is a view showing one embodiment of a manufacturing process of the insert molded product according to the present invention. FIG. 11 is a diagram showing one embodiment of the manufacturing process of the insert molded product according to the present invention. In the figure, reference numeral 1
Is a transfer film; 2 is a shaping film; 3 is a release film; 4 is a transfer layer; 5 is a surface protective layer; 6 is an anchor layer; Reference numeral 7 is a design layer; reference numeral 8 is a bonding layer; reference numeral 9 is a deposition layer; reference numeral 10 is a transparent coloring layer; reference numeral 11 is an insert film;
Reference numeral 13 denotes a mold cavity surface; Reference numeral 14 denotes a cavity; Reference numeral 15 denotes a heating means; Reference numeral 16 denotes a suction hole; Reference numeral 17 denotes a molding resin; Reference numeral 19 denotes an insert molded product; reference numeral 20 denotes an active energy ray.

First, the laminated film for producing an insert molded product according to the present invention will be described.

The laminated film shown as an example in FIG. 1 has a (meth) acrylic equivalent of 100 to 300 g / e on one side of the release film 3 having resistance to heating when the surface protective layer 5 is formed.
q, a surface protective layer 5, which is a thermal crosslinking reaction product of a heat and active energy ray-curable resin composition containing a polymer having a hydroxyl value of 20 to 500 and a weight average molecular weight of 5000 to 50000 and a polyfunctional isocyanate as active ingredients; The transfer film 1 provided with the transfer layer 4 in which the anchor layer 6, the design layer 7, and the bonding layer 8 are sequentially laminated has an elongation represented by the area after preforming / the area before preforming × 100 (%). The transfer layer 4 is adhered to the shape-forming film 2 capable of 150% or more with the transfer layer 4 side as an adhesive surface.

As a material of the release film 3 of the transfer film 1, heating at the time of forming the surface protective layer 5 such as a polyethylene terephthalate film, a polyimide film, and a polybutylene terephthalate film, that is, resistance to heating at 100 to 180 ° C. Can be used. Here, the term “resistant” means that the release film 3 is formed by the tension applied for feeding the film.
Are stretched in the tension direction so that the surface does not undulate or cut. The release film may be a material having poor shapeability, such as a polyethylene terephthalate film.

The release surface of the release film may be prepared by forming a release layer on the entire surface of the resin film for improving the releasability from the transfer layer 4. However, if the material of the release film itself has sufficient release properties, it is not necessary to form a release layer.

Materials for forming the release layer include melamine resin release agents, silicone resin release agents, fluororesin release agents, cellulose derivative release agents, urea resin release agents, There are a polyolefin resin-based release agent, a paraffin-based release agent, an epoxy resin-based release agent, an amino alkyd resin-based release agent, and a composite release agent thereof.

The surface protective layer 5 is a layer which can be cured by irradiating active energy rays after insert molding to protect the resin molded product 18 and the decoration applied thereon from chemicals, friction and the like. And a thermal cross-linking reaction product of an active energy ray-curable resin composition containing the above specific amounts of the polymer and the polyfunctional isocyanate as active ingredients.

The amount of the polymer is specified in consideration of the required physical and chemical properties of the surface protective layer 5 before and after irradiation with active energy rays. That is, from the viewpoint of curability upon irradiation with active energy rays, the (meth) acrylic equivalent is 100
To 300 g / eq, preferably 150 to 300 g / eq. When the (meth) acrylic equivalent is more than 300 g / eq, the abrasion resistance after irradiation with active energy rays is insufficient, and it is difficult to obtain the one having less than 100 g / eq.
Further, from the viewpoint of reactivity with the polyfunctional isocyanate used in combination, the hydroxyl value of the polymer is 20 to 500, preferably 100 to 30.
It is set to 0. When the hydroxyl value is less than 20, the reaction with the polyfunctional isocyanate is insufficient, and the degree of thermal crosslinking of the active energy ray-curable resin composition is low. Therefore, if the surface protective layer 5 obtained by thermal crosslinking has adhesiveness remaining or lacks solvent resistance, another layer is overprinted on the surface protective layer 5 or the transfer film 1 is wound up. It becomes difficult. In addition, those having a hydroxyl value exceeding 500 are difficult to obtain. The weight average molecular weight of the polymer is
It is 5000-50000, preferably 8000-40000. If the weight-average molecular weight of the polymer is less than 5,000, the surface protective layer 5 may remain sticky or lack solvent resistance. Also 5000
If it exceeds 0, the resin viscosity becomes too high, and the workability of applying the ink is reduced.

The method for producing the polymer is as follows.
There is no particular limitation, and a conventionally known method can be adopted. For example, [1] a method of introducing a (meth) acryloyl group into a part of a side chain of a polymer containing a hydroxyl group, [2] α, β-unsaturation containing a hydroxyl group in a copolymer containing a carboxyl group A method of subjecting a monomer to a condensation reaction, [3] an α, β-containing epoxy group-containing copolymer containing a carboxyl group.
There are a method in which an unsaturated monomer is added, and a method in which [4] an α, β-unsaturated carboxylic acid is reacted with an epoxy group-containing polymer.

Taking the method [4] as an example, the method for producing the polymer used in the present invention will be described more specifically. For example, a polymer having a glycidyl group is added to an α, β-
The polymer used in the present invention can be easily obtained by a method of reacting an unsaturated carboxylic acid. Preferred as the polymer having a glycidyl group are, for example, a copolymer of glycidyl (meth) acrylate and a copolymer of glycidyl (meth) acrylate and an α, β-unsaturated monomer containing no carboxyl group. No. Examples of the α, β-unsaturated monomer containing no carboxyl group include various (meth) acrylic esters, styrene, vinyl acetate, acrylonitrile, and the like. If an α, β-unsaturated monomer containing a carboxyl group is used, crosslinking occurs during a copolymerization reaction with glycidyl (meth) acrylate, resulting in high viscosity and gelation.

In any case, when each of the above methods [1] to [4] is adopted, the types of monomers and polymers to be used, the amounts of these monomers and the like are used so as to satisfy the above-mentioned numerical limitation ranges relating to polymers. It is necessary to appropriately set the conditions. Such operations are well known to the parties.

The polyfunctional isocyanate used for preparing the active energy ray-curable resin composition in combination with the above polymer is not particularly limited, and various known isocyanates can be used. For example, isophorone diisocyanate, xylylene diisocyanate, hydrogenated xylylene diisocyanate, tolylene diisocyanate, diphenyl methane diisocyanate, 1,6-hexane diisocyanate, the above trimer, a prepolymer obtained by reacting a polyhydric alcohol with the diisocyanate, and the like. Can be used.

The ratio of the number of hydroxyl groups to the number of isocyanate groups in the polymer is preferably from 1 / 0.01 to 1/1, and more preferably from 1 / 0.05 to 1/1.
It is determined to be 1 / 0.8. Further, the active energy ray-curable resin composition may contain components such as an ultraviolet absorber, a light stabilizer, a reactive diluent monomer, a solvent, a colorant, a photopolymerization initiator, and a lubricant, if necessary. .

When the above active energy ray-curable resin composition is heat-treated at 100 to 180 ° C., the ethylenically unsaturated groups, hydroxyl groups, and isocyanate groups contained in the composition react with each other to crosslink the resin. . Since this thermal crosslinking reaction product, that is, the surface protective layer 5 is in a tack-free state,
It becomes easy to print another layer thereon and wind up the transfer film 1.

The design layer 7 is for decorating the surface of the molded product. As a material of the pattern layer 7, a polyvinyl resin,
Polyamide resin, polyester resin, polyacrylic resin, polyurethane resin, polyvinyl acetal resin, polyester urethane resin, cellulose ester resin, alkyd resin and the like as a binder,
It is preferable to use a coloring ink containing a pigment or dye of an appropriate color as a coloring agent.

The anchor layer 6 is a resin layer provided between the two layers to enhance the adhesion between the upper and lower layers. In the case of the laminated film for producing an insert molded article shown in FIG. The purpose is to adhere the layer 7. As a material of the anchor layer 6, for example, a two-component curable urethane resin, a melamine-based or epoxy-based thermosetting resin, or a thermoplastic resin such as a vinyl chloride copolymer resin can be used. When a thermosetting resin is used as the anchor layer 6, heat treatment is performed. However, since the release film 3 of the present invention is made of a material having resistance to heating when forming the surface protective layer 5, Can also maintain stable dimensions.

The laminating layer 8 is for laminating the above layers and the release film 3 to the shape-forming film 2. As the bonding layer 8, an acrylic resin, an acrylic vinyl resin, a polyamide resin, or the like suitable for the material of the shape-forming film 2 may be used.

The shapeable film 2 to be bonded to the transfer film 1 is: area after preforming / area before preforming ×
The elongation represented by 100 (%) can be 150% or more. Examples of the material include a soft vinyl chloride film, an unstretched polypropylene film, an unstretched polyester film, a polycarbonate film, a film made of an acrylic resin and an acrylic rubber, and styrene. A film composed of a copolymer resin (AS) of styrene and acrylonitrile, and a film composed of a copolymer resin (ABS) of styrene, butadiene and acrylonitrile can be used. Further, as the executionable film, two or more layers of the above resin film may be laminated.

The structure of the transfer layer 4 in the present invention is as follows.
(Meth) acrylic equivalent 100 to 300 g / eq, hydroxyl value 20 to
The surface protective layer 5 which is a thermal cross-linking reaction product of an active energy ray-curable resin composition containing a polymer having a weight average molecular weight of 5,000 to 50,000 and a polyfunctional isocyanate as active ingredients may be used as at least one constituent layer. However, the present invention is not limited to the embodiment shown in FIG. For example, in the case of using a laminated film for producing an insert molded product only for the surface protection treatment by utilizing the ground pattern and transparency of the molded product, the design layer 7 can be omitted from the transfer layer 4 (FIG. 2). reference).

In the embodiment shown in FIG. 1, the design layer 7 is provided as a decoration layer. However, as shown in FIG. 3, a vapor deposition layer 9 may be provided as a decoration layer. Both the design layer 7 and the vapor deposition layer 9 may be provided (not shown). Evaporation layer 9
Is formed by forming at least one metal selected from the group of aluminum, nickel, chromium, indium, tin and the like by a vacuum evaporation method, a sputtering method, an ion plating method, or the like. Although the release film 3 is heated by this vapor deposition, in the present invention, since a material having resistance to heating when forming the surface protective layer 5 is used, a stable dimension is maintained even after the above vapor deposition is performed. Can be kept. The transparent coloring layer 10 provided in FIG. 3 is for coloring the vapor deposition layer 9. Further, an anchor layer 6 is provided between the transfer layers in FIG. 3 in order to enhance the adhesion.

Further, the shape-forming film 2 may also have a decoration layer, for example, a design layer 7 on the side of the transfer film 1 to which the transfer film 1 is to be attached or on the opposite side thereof. 4 and 5). Further, a bonding layer 8 may be provided on the bonding surface side of the shaping film 2, and the bonding layer 8 may be omitted from the configuration of the transfer layer 4 (see FIG. 6). In addition,
In the case where the bonding layer 8 is provided on either the shapeable film 2 side or the transfer film 1 side, after the bonding layer 8 is formed, it may be dried once before bonding and then wound up, The bonding layer 8 may be formed immediately before bonding, and bonded in an undried state.

Hereinafter, a method of manufacturing an insert molded product according to the present invention using the laminated film having the above-described layer structure will be described.

First, the release film 3 is peeled off from the laminated film to obtain an insert film 11 (see FIG. 7). In addition, the release film 3 does not need to be peeled off immediately before the laminated film is inserted and arranged in the mold 12, or the release film 3 may be peeled off far before being inserted and arranged in the mold 12. Absent. However, the former is effective in preventing dust on the surface of the insert film 11, and the surface protective layer 5 before being irradiated with the active energy rays 20 is easily scratched, so that the effect of preventing scratches is obtained. More preferred.

Next, the obtained insert film 11 is inserted and arranged in the molding die 12 so that the side opposite to the surface on which the transfer layer 4 is provided is integrated with the molding resin (see FIG. 8). At this time, a necessary portion may be intermittently fed as it is as shown in FIG. 8, or the insert film 11 may be made into a single sheet and fed one by one (not shown). When a long insert film 11 is used, a layer for decorating the insert film 11 and the mold 1 are used by using a feeding device having a positioning mechanism.
It is good to make the register of 2 coincide. Also, when the insert film 11 is intermittently fed, if the position of the insert film 11 is detected by a sensor and then the insert film 11 is fixed, the insert film 11 can be fixed at the same position at all times. This is convenient because there is no displacement of the layer for decoration.

Next, the insert film 11 is preformed. For example, the insert film 11 is softened by a heating means 15 such as a hot pack or the like, and is vacuum-sucked through a suction hole 16 provided in the mold 12 so that the insert film 11 follows the mold cavity surface 13 (see FIG. 9).

Thereafter, the mold 12 is closed and the cavity 14 is closed.
The injection molding is filled with the molding resin 17 in the molten state (FIG. 10).
reference). Thereby, at the same time as obtaining the resin molded product 18, the insert film 11 is coated along the surface thereof.
Examples of the molding resin 17 include general-purpose resins such as a polystyrene resin, a polyolefin resin, an ABS resin, and an AS resin. In addition, polyphenylene oxide
General-purpose engineering resins such as polystyrene resin, polycarbonate resin, polyacetal resin, acrylic resin, polycarbonate-modified polyphenylene ether resin, polyethylene terephthalate resin, polybutylene terephthalate resin, ultra-high molecular weight polyethylene resin, polysulfone resin, polyphenylene sulfide resin, Super engineering resins such as polyphenylene oxide resin, polyacrylate resin, polyetherimide resin, polyimide resin, liquid crystal polyester resin, and polyallyl heat resistant resin can also be used. Further, a composite resin to which a reinforcing material such as glass fiber or inorganic filler is added can be used.

Finally, the resin molded product 18 is cooled and the mold 1 is cooled.
After taking out the insert-molded product 19 from inside 2, the active energy ray 20 is irradiated (see FIG. 11). Since the surface protective layer 5 of the present invention contains an ethylenically unsaturated group, when irradiated with the active energy ray 20, the ethylenically unsaturated group is polymerized, the resin is crosslinked, and the resin is completely cured. Examples of the active energy rays 20 include electron beams, ultraviolet rays, and γ rays. Irradiation conditions are determined according to the material of the surface protective layer 5.

Further, an adhesive layer for adhering each of the above layers may be provided on the surface of the insert film 11 which is in close contact with the resin molded product 18. As the adhesive layer, a heat-sensitive or pressure-sensitive resin suitable for the material of the resin molded product 18 is appropriately used. For example, when the material of the resin molded product 18 is a polyacrylic resin, a polyacrylic resin may be used. When the material of the resin molded product 18 is a polyphenylene oxide / polystyrene resin, a polycarbonate resin, a styrene copolymer resin, or a polystyrene blend resin, a polyacrylic resin, a polystyrene resin having an affinity for these resins. , A polyamide resin or the like may be used.
Further, when the material of the resin molded product 18 is a polypropylene resin, a chlorinated polyolefin resin, a chlorinated ethylene-
Vinyl acetate copolymer resins, cyclized rubbers, and coumarone indene resins can be used.

[0051]

EXAMPLES The present invention will be described more specifically with reference to the following examples, but the present invention is not limited to these examples. The following parts and percentages are based on weight.

First, a 38 μm thick polyethylene terephthalate resin film was used as a release film. This polyethylene terephthalate resin film has resistance to heating when forming the surface protective layer. On one side, a melamine resin-based release agent is applied to a thickness of 1 μm by a gravure coating method to form a release layer.

On the release layer forming surface of this release film, 200 parts of the following varnish (solid content: 100 parts) and 10 parts of 1,6-hexanediisocyanate trimer (trade name: Coronate HX, manufactured by Nippon Polyurethane Industry Co., Ltd.) And a layer composed of an active energy ray-curable composition containing 5 parts of a photopolymerization initiator (trade name: Irgacure 184, manufactured by Ciba Geigy), 8 parts of an ultraviolet absorber, and 2 parts of a light stabilizer formed by a lip coating method. did.
The thickness of this layer was 5 μm.

By heating at 150 ° C. for 20 seconds, the layer composed of the active energy ray-curable composition is partially crosslinked and cured to form a surface protective layer, a urethane ink as an anchor layer, an acrylic ink as a design layer, and a bonding layer. An acrylic resin was sequentially formed by gravure printing to obtain a transfer film.

The varnish was obtained as follows.
First, 250 parts of glycidyl methacrylate (hereinafter, referred to as GMA), 75 parts of methyl methacrylate (hereinafter, referred to as MMA), lauryl mercaptan 1.3 were placed in a reactor equipped with a stirrer, a cooling pipe, a dropping funnel, and a nitrogen introduction pipe.
Parts, 1,000 parts of butyl acetate and 7.5 parts of 2,2'-azobisisobutyronitrile (hereinafter referred to as AIBN) until the temperature in the system reaches about 90 ° C. in about 1 hour under a nitrogen stream. The temperature was raised and kept for 1 hour. Then, G
From a dropping funnel charged with a mixed solution composed of 750 parts of MA, 225 parts of MMA, 3.7 parts of lauryl mercaptan and 22.5 parts of AIBN, the mixed solution was dropped into the system in about 2 hours under a nitrogen stream, and the temperature was maintained for 3 hours. After heating, 10 parts of AIBN was charged and kept warm for 1 hour. Thereafter, the temperature was raised to 120 ° C. and kept for 2 hours. After cooling to 60 ° C., the nitrogen inlet tube was replaced with an air inlet tube, and 507 parts of acrylic acid (hereinafter referred to as AA), 2.0 parts of methoquinone and 5.4 parts of triphenylphosphine were charged and mixed. The temperature was raised to ° C. After keeping the temperature at the same temperature for 8 hours, 1.4 parts of methoquinone was charged and cooled, and ethyl acetate was added so that the nonvolatile content became 50%, to obtain a varnish. The polymer contained in the varnish had an acrylic equivalent of 214 g / eq, a hydroxyl value of 262, and a weight average molecular weight of 20,000 (based on styrene conversion by GPC). The UV absorber is hydroxyphenylbenzotriazole.

On the other hand, a 200 μm thick
A film made of acrylic resin and acrylic rubber was used. This film has an elongation of 700% expressed as area after preforming / area before preforming × 100 (%).

The above transfer film and the shape-forming film are overlapped so that the transfer layer composed of the surface protective layer, the anchor layer, the design layer and the bonding layer is inside, and passed between the heating roll and the cooling roll. A laminated film was obtained by thermocompression bonding. At this time, the release film side of the transfer film is in contact with the heating roll.

The release film is peeled and removed from the laminated film to form an insert film, and the insert film is inserted and arranged in a molding die so that the side opposite to the surface on which the transfer layer is provided is integrated with the molding resin. At the same time as obtaining a resin molded product by preforming in the heating state of 150 ℃ and aligning the insert film along the mold cavity surface, closing the mold and injecting the molding resin in the molten state into the cavity An insert film was coated along the surface, the insert molded product was taken out of the mold, and then irradiated with active energy rays to cure the surface protective layer. The molding conditions were a resin temperature of 240 ° C., a mold temperature of 55 ° C., and a resin pressure of about 300 kg / cm ² . Molded products are
Acrylic resin material, height 95mm, width 65mm, rising
It was formed into a tray shape of 4.5 mm and R2.5 mm at the corners. Ultraviolet rays are used as active energy rays, and irradiation conditions are 12
0w / cm, 2 lights, lamp height 10cm, belt speed 2.5m
/ Min.

The insert molded product thus obtained had a transfer layer formed on the surface of the three-dimensional shape having a deep drawing, and had a beautiful appearance with excellent abrasion resistance and chemical resistance. .

[0060]

According to the present invention, there is provided a laminated film for producing an insert molded product according to the present invention and a method for producing an insert film using the same.
Since the method of manufacturing an insert molded product has the above-described configuration and operation, the following effects are achieved.

That is, the laminated film for producing an insert molded article of the present invention comprises a heat-crosslinking reaction product of an active energy ray-curable resin composition on one side of a release film having resistance to heating during formation of a surface protective layer. The transfer film provided with a transfer layer having at least one surface protective layer as a constituent layer is: area after preforming / area before preforming × 100 (%)
Is attached to a shape-forming film capable of elongation of 150% or more, with the transfer layer side as an adhesive surface.

Therefore, when forming the surface protective layer,
Even if the release film coated with the active energy ray-curable resin composition is passed through a heating atmosphere, the release film extends in the tension direction due to the tension applied for feeding the film, or the surface is wavy, By using the laminated film, a molded article having excellent abrasion resistance and chemical resistance and a beautiful appearance can be obtained.

When an insert molded article is manufactured using the laminated film, the insert film is peeled and removed from the laminated film before placing it in the molding die, and the transfer layer has excellent elongation. Since it is then preformed while being supported by the shapeable film, a molded article having a transfer layer on a three-dimensional surface having a deep drawing can be obtained.

[Brief description of the drawings]

FIG. 1 is a cross-sectional view showing one embodiment of a laminated film according to the present invention.

FIG. 2 is a sectional view showing another embodiment of the laminated film according to the present invention.

FIG. 3 is a cross-sectional view showing another embodiment of the laminated film according to the present invention.

FIG. 4 is a sectional view showing another embodiment of the laminated film according to the present invention.

FIG. 5 is a sectional view showing another embodiment of the laminated film according to the present invention.

FIG. 6 is a cross-sectional view showing another embodiment of the laminated film according to the present invention.

FIG. 7 is a view showing one embodiment of a manufacturing process of the insert molded product according to the present invention.

FIG. 8 is a view showing one embodiment of a manufacturing process of the insert molded product according to the present invention.

FIG. 9 is a view showing one embodiment of a manufacturing process of the insert molded product according to the present invention.

FIG. 10 is a view showing one embodiment of a manufacturing process of the insert molded product according to the present invention.

FIG. 11 is a view showing one embodiment of a manufacturing process of the insert molded product according to the present invention.

[Explanation of symbols]

 REFERENCE SIGNS LIST 1 transfer film 2 formable film 3 release film 4 transfer layer 5 surface protection layer 6 anchor layer 7 design layer 8 bonding layer 9 vapor deposition layer 10 transparent coloring layer 11 insert film 12 mold 13 mold cavity surface 14 cavity 15 Heating means 16 Suction hole 17 Molded resin 18 Resin molded product 19 Insert molded product 20 Active energy ray

Claims (9)

[Claims] 1. A release film made of a heat-resistant film material having a release surface, a transfer layer formed on the release surface of the release film, and a transfer layer formed on the transfer surface of the transfer layer after preforming. Elongation expressed as area / area before preforming x 100 (%) is 1
And a transferable layer formed on a release surface of a release film, wherein the transfer layer has a (meth) acrylic equivalent of 100 to 300 g / e.
q, a hydroxyl value of 20 to 500, and a surface protective layer comprising a thermal reactant of a heat and active energy ray-curable resin composition containing a polymer having a weight average molecular weight of 5,000 to 50,000 and a polyfunctional isocyanate as an active ingredient, A laminated film for producing an insert molded product, having a bonding layer for bonding a shapeable film in a transfer layer or between the transfer layer and the shapeable film. 2. The laminated film according to claim 1, wherein the release film is a polyethylene terephthalate resin film. 3. The shaping film is a soft vinyl chloride film, an unstretched polypropylene film, an unstretched polyester film, a polycarbonate film, a film made of an acrylic resin and an acrylic rubber, a copolymer resin of styrene and acrylonitrile (AS). 3. The method according to claim 1, wherein the film is at least one selected from the group consisting of a film composed of a copolymer resin (ABS) of styrene, butadiene and acrylonitrile. 4. Laminated film. 4. The insert molding according to claim 1, wherein the polymer is a reaction product obtained by adding an α, β-unsaturated monocarboxylic acid to a glycidyl (meth) acrylate polymer. Laminated film for product manufacturing. 5. The glycidyl (meth) acrylate polymer is a homopolymer of glycidyl (meth) acrylate or a copolymer of glycidyl (meth) acrylate and an α, β-unsaturated monomer containing no carboxyl group. The laminated film according to claim 4, which is a polymer. 6. The laminated film according to claim 1, wherein the transfer layer has a design layer for decoration. 7. The laminated film for producing an insert molded product according to claim 1, wherein a pattern layer for decoration is provided on the surface of the shape-forming film. 8. A method for producing an insert film, comprising a step of removing and releasing a release film from the laminated film for producing an insert molded product according to claim 1. 9. A step of peeling and removing a release film from the laminated film for producing an insert molded product according to claim 1; inserting the remaining insert film into a molding die with the shapeable film inside. Step of preforming the insert film along the mold cavity surface; Injecting and filling the molten resin into the cavity to perform resin molding, and at the same time, adhesive coating the surface with the insert film And a step of irradiating the surface protective layer of the insert film with active energy rays to cure the surface protective layer.