JP2000066384A - Formation of hole pattern - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a hole pattern having a round form by dry-etching a film to be etched using a hole pattern formed of a chemical amplification type resist as a mask in order to form the hole pattern. SOLUTION: In the method for forming the hole pattern, which is comprised of the first step of forming a hole patterned photosensitive material film on a film to be etched which is formed on a semiconductor substrate 1 and the second step of dry-etching the film to be etched using the hole patterned photosensitive material film, as at least a part of a mask, to form hole patterns 4 and 5 formed of the etched film, the photosensitive material contains at least one selected from onium salt compounds, sulfonimide compound, halogenated compounds, sulfon compounds, sulonate compounds and quinone diacid compounds and an apparatus equipped with two electric power sources is used for dry-etching the film to be etched, as the dry-etching apparatus.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for forming a hole pattern, and more particularly, to a method for performing dry etching on a film to be etched on a semiconductor substrate using a hole-patterned photosensitive material film as a mask. The present invention relates to a method for forming a hole pattern made of a film.

[0002]

2. Description of the Related Art A conventional method for forming a hole pattern will be described below with reference to FIGS. 1 (a) to 1 (c).

[0003] First, as shown in FIG.
On the film 2 to be etched, a photosensitive material (hereinafter referred to as a resist) film 3 having a hole pattern (4) is formed. This involves depositing a resist 3 on the film 2 to be etched, and irradiating the resist film 3 with visible light (wavelength 700 to 400 nm) or near ultraviolet light (wavelength 400 to 300 nm) as an exposure light source. Resist 3
And irradiating the irradiated part or the unirradiated part with a developing solution to dissolve.

Next, as shown in FIG. 1B, the film 2 to be etched is dry-etched using the resist film 3 having the hole pattern (4) as a mask, thereby forming the hole pattern (4). The pattern shape of the resist film 3) is transferred to the film 2 to be etched to form a hole pattern 5 composed of the film 3 to be etched.

[0005] Next, as shown in FIG. 1 (c), by removing the resist film 3 having the hole pattern, a hole pattern 5 made of a film to be etched is obtained on the semiconductor substrate 1.

The above-mentioned visible light (wavelength 700 to 400 n)
m) or a typical resist corresponding to an exposure light source of near ultraviolet rays (wavelength 400 to 300 nm) using a novolak resin as a base polymer and a quinone diacid compound as a photosensitive component (hereinafter referred to as the resist). Is referred to as a novolak type resist). In this resist, tetramethylammonium hydroxide (hereinafter referred to as T
When the substrate is immersed in a developing solution of a dilute alkaline aqueous solution typified by MAH (hereinafter referred to as “developing”), the exposed portions are dissolved and removed. This is because the quinone diacid compound constituting the photosensitive component has a dissolution inhibiting ability with respect to the novolak resin as the base polymer, but the quinone diacid compound becomes indene carboxylic acid by exposure to the exposure light source, and conversely, the base The reason therefor is to exhibit a dissolution promoting effect on the novolak resin which is a polymer.

In order to dry-etch the film 2 to be etched using the hole pattern 4 formed by the resist as a mask, a reactive ion etching method is used. The reactive ion etching method includes a capacitively coupled plasma type, an inductively coupled plasma type, an electron cyclone resonance type, a capacitively coupled plasma dual frequency type, a surface wave plasma type, and the like.

[0008]

As a system using a complicated semiconductor integrated circuit is downsized, a contact hole (hereinafter, referred to as a hole) is also required to be miniaturized.
For this reason, in the lithography process, a shorter wavelength of the exposure light source is required. Lithography processes using such short-wavelength radiation include far ultraviolet rays such as KrF excimer laser (wavelength 248 nm) and ArF excimer laser (wavelength 193 nm), X-rays such as synchrotron radiation, and charged particles such as electron beams. A method using lines has been proposed. International Business Machines (IBM) has proposed a "chemically amplified resist" as a high-resolution resist corresponding to such short-wavelength radiation. Chemically amplified resists generate an acid by exposure to radiation to a radiation-sensitive acid generator contained in the resist, and in the resist coating due to the catalytic reaction of the acid, for example, change in polarity, cleavage of chemical bonds, crosslinking. A pattern is formed by using a phenomenon in which a chemical reaction such as a reaction occurs and the solubility in a developing solution changes in an exposed portion. Therefore, the material has a chemical reaction mechanism different from that of the conventional novolak type resist.

On the other hand, when the film to be etched 2 is dry-etched using the hole pattern 4 formed of a resist as a mask, the relative thickness of the film to be etched 2 with respect to the hole size (hereinafter, referred to as "the hole size") becomes smaller as the hole size becomes smaller.
This ratio is called the aspect ratio). For this reason,
With the miniaturization of systems using complicated semiconductor integrated circuits, a dry etching process capable of forming holes with a high aspect ratio has been demanded. In order to realize a hole having a high aspect ratio, a process having a high vacuum and a high plasma density is required. For this reason, the dry etching apparatus has two or more power sources, a source power source that mainly generates plasma, and a bias power source that mainly pulls ions into the substrate, from a method using a single power source. , And a system that independently controls a bias power supply. In addition, in the reactive ion etching, the plasma generation method is a capacitively coupled plasma type having a single power supply, an inductively coupled plasma type having two or more power supplies, an electron cyclone resonance type, and a capacitively coupled plasma dual frequency. Type and surface wave plasma type are being used.

Here, when a chemically amplified resist is used as a mask and a capacitively coupled plasma type etching apparatus having a single power supply for reactive etching is used, the hole pattern formed in the film to be etched is It does not become star-shaped and its size does not become large. However, as shown in FIG. 2, reactive etching of inductively coupled plasma type, electron cyclone resonance type, capacitively coupled plasma dual frequency type, and surface wave plasma type is performed using a hole pattern using a chemically amplified resist as a mask. When the film 2 to be etched is dry-etched, that is, for example, when a diazomethane compound is used as an acid generator and an inductively coupled plasma type is used for reactive etching, or an onium salt compound and a diazomethane compound are used as an acid generator When an inductively coupled plasma type is used for reactive etching of the mixture, the hole pattern 5 formed in the film to be etched has a star shape, and the hole size is a hole using a chemically amplified resist. It becomes extremely larger than pattern 4.

In a semiconductor integrated circuit, when a star-shaped and large-sized contact hole as shown in FIG. 2 is formed, a star-shaped and large-sized contact hole as shown in FIG. Are unnecessarily interconnected, causing an abnormal leakage current to flow, which causes a problem of deteriorating element characteristics.

When a conventional novolak type resist is used as a mask, a hole pattern formed in a film to be etched becomes star-shaped when a capacitively coupled plasma type etching apparatus having one power supply is used. In addition, the size does not become large. However, this cannot form a hole pattern having a high aspect ratio.

In view of the above, the present invention provides a reaction between an inductively coupled plasma type, an electron cyclone resonance type, a capacitively coupled plasma dual frequency type, and a surface wave plasma type using a hole pattern formed by a chemically amplified resist as a mask. Even if a hole pattern is formed in a film to be etched by performing dry etching by reactive etching, a round hole pattern shape can be obtained, an abnormal leak current flows, and the device characteristics are deteriorated. An object of the present invention is to provide a method for forming a hole pattern that does not occur.

It is another object of the present invention to provide a method of forming a round hole pattern having a high aspect ratio when forming a hole pattern in a film to be etched using a hole pattern of a novolak type resist as a mask.

[0015]

The inventors of the present invention have examined the cause of the star pattern of the hole pattern of the film to be etched and found that the cause is an acid generator of the chemically amplified resist. Was. Further, by using a specific acid generator, an inductively coupled plasma type, an electron cyclone resonance type, a capacitively coupled plasma
It has been found that a round hole pattern can be obtained even when a hole pattern is formed in a film to be etched by performing dry etching by reactive etching of a frequency type or a surface wave plasma type.

Therefore, a method of forming a hole pattern according to claim 1 of the present invention is a first step of forming a hole-patterned photosensitive material film on a film to be etched formed on a semiconductor substrate. A second step of performing dry etching on the film to be etched with the hole-patterned photosensitive material film as at least a part of a mask to form a hole pattern made of the film to be etched; In the method for forming a hole pattern provided with the above, the photosensitive material constituting the photosensitive material film may be an onium salt compound, a sulfonimide compound, a halogen-containing compound, a sulfone compound, a sulfonate compound, and a quinone diacid as an acid generator. It is assumed that the resist is a chemically amplified resist containing at least one compound among the compounds. Apparatus for dry-etching the etching layer is characterized in that the one having two or more power.

According to a second aspect of the present invention, in the method for forming a hole pattern according to the first aspect, the photosensitive material constituting the photosensitive material film of the chemically amplified resist is a base material. It is characterized by containing a polyhydroxystyrene derivative as a polymer.

According to a third aspect of the present invention, there is provided the hole pattern forming method according to the second aspect, wherein the solvent constituting the photosensitive material film of the chemically amplified resist is ethyl lactate. It is characterized by including.

According to a fourth aspect of the present invention, there is provided a method of forming a hole pattern according to any one of the first to third aspects, wherein the apparatus for dry-etching the film to be etched mainly comprises a plasma. Characterized in that a source power source for generating the electric field and a bias power source for mainly drawing ions into the substrate are separately provided.

According to a fifth aspect of the present invention, there is provided a method of forming a hole pattern according to any one of the first to fourth aspects, wherein the apparatus for dry etching the film to be etched is an inductive coupling type. It is a plasma type, an electron cyclone resonance type, a capacitively coupled plasma dual frequency type, or a surface wave plasma type.

According to a sixth aspect of the present invention, there is provided a method for forming a hole pattern, comprising: forming a hole-patterned photosensitive material film on a film to be etched formed on a semiconductor substrate; A second step of dry-etching the film to be etched with the hole-patterned photosensitive material film as at least a part of a mask to form a hole pattern made of the film to be etched. In the method of forming a hole pattern, the photosensitive material constituting the photosensitive material film is a novolak resin containing a novolak resin as a base polymer and a quinone diacid compound as an acid generator, and the film to be etched is dry-etched. The device is mainly composed of a source power source that generates plasma and a bias that mainly pulls ions into the substrate. Of the source, with two or more power,
It is a dry etching apparatus for generating inductively coupled plasma.

[0022]

(Embodiment 1) Hereinafter, a method of forming a hole pattern according to an embodiment of the present invention will be described.
This will be described with reference to FIGS.

First, as shown in FIG. 1A, a resist film 3 having a hole pattern (4) is formed on a film 2 to be etched. This is because the resist 3 is applied to the film 2 to be etched.
And exposure of deep ultraviolet rays such as KrF excimer laser (wavelength 248 nm) and ArF excimer laser (wavelength 193 nm) as exposure light sources, X-rays such as synchrotron radiation, or charged particle beams such as electron beams. A step of irradiating the coating film 3 with an irradiating portion of the resist coating 3,
Or a step of dissolving the unirradiated portion in a developer.

Next, as shown in FIG. 1B, the film 2 to be etched is dry-etched using the resist film 3 having the hole pattern (4) as a mask, thereby forming the hole pattern ( 4) Resist coating 3
Is transferred to the film 2 to be etched to form a hole pattern 5 made of the film 2 to be etched.

Next, as shown in FIG. 1C, by removing the resist film 3 having the hole pattern (4), a hole pattern 5 composed of the film 2 to be etched is obtained on the semiconductor substrate 1. Can be

As described above, in the above-described process, conventionally, visible light (wavelength 700 to 40) was used as an exposure light source.
0 nm) and near ultraviolet rays (wavelength 400 to 300 nm). As described above, as a typical resist corresponding to the above-mentioned exposure light source, a novolak resin is used as a base polymer and a quinone diacid compound is used as a photosensitive component. Since the alkali solubility of the light-exposed portion of the resist increases, when the resist is immersed in a developing solution of a dilute alkali aqueous solution represented by TMAH (tetramethylammonium hydroxide), the exposed portion is dissolved and removed. This is because the quinone diacid compound that forms the photosensitive component has a dissolution inhibiting ability with respect to the novolak resin that is the base polymer, but the quinone diacid compound becomes indene carboxylic acid by exposure to the exposure light source, and conversely, the base polymer This is because the compound has a dissolution promoting effect on the novolak resin.

On the other hand, in recent years, as the size of a system using a complicated semiconductor integrated circuit has been reduced, the contact hole has also been required to be finer. Therefore, in a lithography process, an exposure light source for a resist has been used. Shortening of the wavelength is required. Lithography processes using such short-wavelength radiation include a KrF excimer laser (wavelength 248 nm) and an ArF excimer laser (wavelength 1).
A method using a charged particle beam such as far ultraviolet rays such as 93 nm), X-rays such as synchrotron radiation, or electron beams has been proposed. As a high-resolution resist corresponding to such short-wavelength radiation, the above-described chemically amplified resist has been proposed, which is exposed to radiation to a radiation-sensitive acid generator contained therein. An acid is generated, and the catalytic reaction of the acid generates
For example, a pattern is formed using a phenomenon in which a chemical reaction such as a change in polarity, cleavage of a chemical bond, a cross-linking reaction, or the like is caused, and solubility in a developing solution is changed in an exposed portion. Therefore, the material has a chemical reaction mechanism different from that of the conventional novolak type resist.

Examples of the acid generator as a constituent material of the chemically amplified resist include an onium salt compound, a sulfonimide compound, a halogen-containing compound, a sulfone compound, a sulfonate compound, a quinone diacid compound, and a diazomethane compound.

However, among the above acid generators, biscyclohexylsulfonyldiazomethane, bis (3-
A chemically amplified resist using a diazomethane compound typified by methylphenylsulfonyl) diazomethane or the like is used when dry etching is performed on the film to be etched 2 using the resist film 4 having a circular hole pattern as a mask. When a dry etching apparatus having two or more power supplies is used, as shown in FIG. 2, the hole pattern 5 of the film to be etched has a star shape. This is because while other acid generators are more stable to heat (eg, temperatures above 160 ° C.) and plasma, diazomethane compounds are more resistant to heat and plasma than other acid generators. On the other hand, it has low stability and sublimates.

When a large-sized contact hole 5 as shown in FIG. 2 is formed in the semiconductor integrated circuit, a star-shaped and large-sized contact hole 5 as shown in FIG. 2 and wiring are not required. In such a case, an abnormal leak current flows, which causes a problem of deteriorating element characteristics.

Examples of the onium salt compounds described in the present embodiment include sulfonium salts, iodonium salts, pyridium salts, phoshonium salts, oxonium salts, and ammonium salts. As the sulfonimide compound,
N-sulfonyloxy aphthalimide acid generators. Examples of the halogen-containing compound include a haloalkyl group-containing hydrocarbon compound and a haloalkyl group-containing heterocyclic compound. Examples of the sulfone compound include β-ketone sulfone, β-sulfonylsulfone, and the like. Examples of the sulfonic acid ester compound include an alkylsulfonic acid ester, a holoalkylsulfonic acid ester, an arylsulfonic acid ester, and an iminosulfonate.

In the dry etching method having two or more power supplies described in this embodiment, a source power supply for mainly generating plasma and a bias power supply for mainly drawing ions into a substrate are separately provided. Equipment.
Specific examples include inductively coupled plasmas (ICP, Induc
tion Coupling Plasma), Electron Cyclotron Resonance (ECR), Capacitively Coupled Plasma 2 Frequency (RIE, Reactive Ion Etcing-D)
ouble Freqency Plasma) type, surface wave plasma (SW)
P, Surface Wave Plasma) type.

On the other hand, as a dry etching method using a single power supply, a capacitively coupled plasma (RIE, Reactive Io
n Etcing-Plasma) type.

Comparing the dry etching method having two or more power supplies with the dry etching method having a single power supply, the dry etching method having two or more power supplies generates high-density plasma. be able to. Therefore, a hole pattern having a high aspect ratio can be formed.

FIG. 3 shows the relationship between the plasma density, the hole size, and the hole shape. As a condition, a BPSG (Boro-Phos) is formed on a semiconductor substrate 1 made of silicon.
An etching target film 2 made of pho Silicate Glass was deposited to a thickness of 1200 nm. The resist film thickness is 1000 nm, and the hole size after lithography is
It was 300 nm. In this case, in a low-density plasma region up to a plasma density of 1 × 10E10 / cm ^2, which is an RIE region, the hole pattern 5 of the film to be etched has a round shape, and the hole size after dry etching is almost equal to that after lithography. Of 300 nm. However, 1 ×
It can be seen that the hole pattern 5 of the film to be etched becomes star-shaped and the hole size increases as the high density plasma region of 10E10 / cm ² or more is reached. From this result, it is understood that the shape of the hole pattern 5 of the film to be etched is greatly related to the plasma density.

However, when the conventional novolak type resist is used as a mask, even if the hole pattern 5 of the film to be etched 2 is formed by using any type of reactive etching, the hole pattern 5 of the film to be etched 2 is star-shaped. It does not take shape. Further, even when the chemically amplified resist is used as a mask, even if the hole pattern 5 formed by the film 2 to be etched is formed by using the capacitively coupled plasma type reactive etching, the hole pattern 5 formed by the film 2 to be etched is star-shaped. It is clear from the following specific examples and reference examples that the shape is not formed. Therefore, the hole pattern 5 is transformed into a star shape by using a specific chemically amplified resist (using a diazomethane compound as an acid generator) in a specific dry etching process (a dry etching method having two or more power supplies). It is surprising that it has been found that this occurs when combined.

As shown in the following specific examples and reference examples, the protective group, which is a constituent part of the chemically amplified resist, has almost no dependency on the deformation of the hole pattern into the star shape. It became clear. In addition, it has been clarified that the heat resistance of the resist and the removal speed of the resist by dry etching have almost no dependence on the deformation of the hole pattern into a star shape. It was also clarified that the annealing treatment of the resist film had almost no dependence on the deformation of the hole pattern into a star shape. In addition, it became clear that the solvent of the resist did not depend on the deformation of the hole pattern into a star shape.

An experimental result on the shape of the hole pattern depending on the difference between the resist and the dry etching method will be described below. A summary is shown in Table 1.

(First Specific Example) First, a film to be etched 2 made of BPSG was deposited to 1200 nm on a semiconductor substrate 1 made of silicon. Next, a PHS (polyhydroxystyrene) derivative which is a poorly soluble alkali resin as a base polymer, a t-butyl acrylate group as a protecting group bonded to the base polymer, and a sulfonimide compound as an acid generator. A resist (chemically-amplified resist) composed of N-camphorsulfonyloxynaphthalimide and ethyl lactate as a solvent is applied on the film 2 to be etched, and then heat-treated at 140 ° C. for 60 seconds to form a film having a thickness of 1000 nm. A resist film 3 having a film thickness was formed.

Next, after irradiating the resist film 3 with a KrF excimer laser through a mask, a post-exposure bake (hereinafter referred to as PEB, post-exposure baking) is performed at 150 ° C. for 90 seconds. Heat treatment was performed. Next, the irradiated portion of the resist film 3 is dissolved in a developing solution composed of a 2.38% TMAH aqueous solution to form a hole pattern having an opening size (hole diameter) of 300 nm, which is formed of the unirradiated portion of the resist film 3. A resist film 4 was formed.

The resist is subjected to a heat treatment condition near the glass transition temperature of the base polymer to which the protective group has been bonded as a heat treatment condition after the resist application. Is a resist intended to prevent diffusion and infiltration (hereinafter, this process is referred to as an annealing process). By this treatment, the heat resistance of the resist is such that the resist pattern shape is not deformed even by heat treatment up to around 150 ° C. which is the glass transition temperature. The heat resistance is superior to that of a conventional novolak resist.

Next, the film to be etched 2 was dry-etched using the resist film 4 having the hole pattern as a mask. The dry etching apparatus used was an inductively coupled plasma type. Dry etching conditions are:
The etching gas is C ₂ F ₆ , the chamber vacuum is 5 to 10 mTorr, and the bias power is 1000.
W, source power is 2100W. The plasma density at this time is 8 × 10E10 / cm ³ . Further, the etching selectivity between the resist and the film 2 to be etched was about 90% as compared with the novolak type resist (that is, the chemically amplified type resist was more easily removed).

When a hole pattern 5 was formed in the film 2 to be etched under the above-mentioned resist and dry etching conditions, the hole pattern 5 was formed as shown in FIG.
Had a clean round shape, and good characteristics were obtained. In addition, the hole size was about 310 nm, and the characteristics were excellent without an extremely large dimension.

(First Reference Example) A PHS (polyhydroxystyrene) derivative which is a poorly alkali-soluble resin as a base polymer, a t-butyl acrylate acrylate group as a protecting group bonded to the base polymer, an acid generator A resist (chemically-amplified resist) comprising biscyclohexylsulfonyldiazomethane as a diazomethane compound and ethyl lactate as a solvent is applied on the film 2 to be etched, and then heat-treated at 140 ° C. for 60 seconds. A resist film 3 having a thickness of 1000 nm was formed. As a result, the heat resistance of the resist and the etching selectivity between the resist and the film to be etched were the same as in the first specific example. Other experimental conditions are the same as those of the first specific example.

When a hole pattern 5 was formed in the film 2 to be etched under the above-mentioned resist and dry etching conditions, as shown in FIG.
It became a star shape. The hole size is about 360nm
And an extremely large dimension was observed, which was very undesirable.

(Second Reference Example) A PHS (polyhydroxystyrene) derivative which is a hardly soluble alkali resin as a base polymer, an acetal group as a protecting group bonded to the base polymer, and a diazomethane compound as an acid generator. A resist (chemically amplified resist) composed of a certain biscyclohexylsulfonyldiazomethane and ethyl lactate as a solvent is applied on the film 2 to be etched,
Next, heat treatment was performed at 80 ° C. for 90 seconds to form a resist film 3 having a thickness of 1000 nm. Since this resist uses an acetal group as a protective group,
Deprotection occurred to an extent, and no annealing treatment was performed.

Next, the resist film 3 was irradiated with a KrF excimer laser through a mask, and then subjected to a heat treatment at 110 ° C. for 90 seconds as PEB. Next, the irradiated portion of the resist film 3 is dissolved in a developing solution composed of a 2.38% TMAH aqueous solution to form a hole pattern having an opening size (diameter of a hole) of 300 nm composed of the unirradiated portion of the resist film 3. The resist film 4 thus formed was formed.

Next, the film to be etched 2 was dry-etched using the patterned resist film 4 as a mask. The dry etching apparatus used was a capacitively coupled plasma type. The dry etching conditions were such that a mixed gas of CHF ₃ , CF ₄ , and Ar was used as an etching gas, the chamber vacuum was 150 mTorr, and the power supply power was 1000 W. The plasma density at this time is
It is 5 × 10E9 / cm ³ .

When a hole pattern 5 was formed in the film to be etched under the above-mentioned resist and dry etching conditions, a round shape was obtained as shown in FIG. 4D, and good characteristics were obtained. In addition, the hole size was about 305 nm, and the characteristics were excellent without an extreme increase in dimensions.

(Second Specific Example) A PHS (polyhydroxystyrene) derivative which is a poorly alkali-soluble resin as a base polymer, an acetal group as a protecting group bonded to the base polymer, an onium salt compound as an acid generator (Chemically amplified resist) comprising triphenylsulfonium triflate as a solvent and ethyl lactate as a solvent is applied on the film 2 to be etched.
Heat treatment was performed at 90 ° C. for 90 seconds to form a resist film 3 having a thickness of 1000 nm. Since this resist uses an acetal group as a protecting group, a deprotecting group (elimination of the protecting group) occurs at about 130 ° C., and no annealing treatment is performed.

Next, the resist film 3 was irradiated with a KrF excimer laser through a mask, and then subjected to a heat treatment at 110 ° C. for 90 seconds as PEB. Next, the irradiated portion of the resist coating 3 is dissolved in a developing solution composed of a 2.38% TMAH aqueous solution to form a hole pattern having an opening size (diameter of a hole) of 300 nm composed of the unirradiated portion of the resist coating 3. The resist film 4 thus formed was formed.

Next, the film to be etched 2 was dry-etched using the patterned resist film 3 as a mask. The conditions were the same as in the first specific example, and an inductively coupled plasma type was used. The selectivity between the resist and the film to be etched was about 80% as compared with the novolak type resist. That is, it was shown that the chemically amplified resist was easier to remove.

When a hole pattern 5 was formed in the film 2 to be etched under the above-mentioned resist and dry etching conditions, a round shape was obtained as shown in FIG. 4B, and good characteristics were obtained. In addition, the hole size was about 305 nm, and the characteristics were excellent without an extreme increase in dimensions.

(Third Reference Example) A PHS (polyhydroxystyrene) derivative which is a poorly alkali-soluble resin as a base polymer, an acetal group as a protecting group bonded to the base polymer, an onium salt as an acid generator A resist (chemically-amplified resist) comprising an additive comprising both triphenylsulfonium triflate as a compound and bis (3-methylphenylsulfonyl) diazomethane as a diazomethane compound, and propylene glycol monomethyl ether acetate as a solvent is coated. The resist film 3 having a thickness of 1000 nm is applied on the etching film 2 and then heated at 80 ° C. for 90 seconds.
Was formed. Since this resist uses an acetal group as a protecting group, a deprotecting group (elimination of the protecting group) occurs at about 130 ° C., and no annealing treatment is performed.

Next, the resist film 3 was irradiated with a KrF excimer laser through a mask, and then subjected to a heat treatment at 110 ° C. for 90 seconds as PEB.

Next, the film to be etched 2 was dry-etched using the patterned resist film 3 as a mask. The conditions were the same as in the first specific example, and an inductively coupled plasma type was used. The selectivity between the resist and the film to be etched 2 was about 80% as compared with the novolak type resist. That is, it was shown that the chemically amplified resist was more easily removed.

When a hole pattern 5 was formed in the film 2 to be etched under the above-mentioned resist and dry etching conditions, a star shape having a large diameter was obtained as shown in FIG. In addition, the hole size was about 345 nm, and an extremely large dimension was observed, which was very undesirable.

(Fourth Reference Example) A resist (a novolak type resist) comprising a novolak resin, which is a poorly soluble alkali resin as a base polymer, a quinone diacid compound as a photosensitizer, and propylene glycol monomethyl ether acetate as a solvent, was applied. It is applied on the etching film 2 and then heat-treated at 80 ° C. for 90 seconds.
A resist film 4 having a thickness of 000 nm was formed.

Next, the resist film 3 was irradiated with i-line (wavelength 365 nm) through a mask, and then subjected to a heat treatment at 110 ° C. for 90 seconds as PEB. Next, the irradiated portion of the resist film 3 is dissolved in a developer consisting of a 2.38% TMAH aqueous solution to form a hole pattern in which the opening size (hole diameter) of the unirradiated portion of the resist film 3 is 300 nm. A resist film 4 was formed. The heat resistance of the resist pattern 4 was 130 ° C.

Next, the film to be etched 2 was dry-etched using the resist film 4 having the hole pattern as a mask. The conditions were the same for the inductively coupled plasma type as in the first embodiment and the same for the capacitively coupled plasma type as in the second embodiment, and dry etching was performed.

When a hole pattern 5 was formed in the film 2 to be etched under the above-mentioned resist and dry etching conditions, as shown in FIG.
Under either dry etching condition, it becomes round shape,
Almost good characteristics were obtained.

The hole size is about 305 nm,
The characteristics were good without any extreme expansion of the dimensions.

[0063]

[Table 1]

[0064]

According to the method of forming a hole pattern according to the first aspect, a first step of forming a hole-patterned photosensitive material film on a film to be etched formed on a semiconductor substrate. A second step of performing dry etching on the film to be etched with the hole-patterned photosensitive material film as at least a part of a mask to form a hole pattern made of the film to be etched; In the method for forming a hole pattern provided with the above, the photosensitive material constituting the photosensitive material film may be an onium salt compound, a sulfonimide compound, a halogen-containing compound, a sulfone compound, a sulfonate compound, and a quinone diacid as an acid generator. At least one of the compounds
It is assumed that the resist is a chemically amplified resist containing various kinds of compounds, and the apparatus for dry-etching the film to be etched is provided with two or more power supplies. Thus, a round hole pattern can be formed on the substrate, and excellent device characteristics can be obtained without unnecessary interconnection between a contact hole of a normal size and a wiring.

According to the method for forming a hole pattern according to the second aspect, in the method for forming a hole pattern according to the first aspect, the photosensitive material constituting the photosensitive material film of the chemically amplified resist is: Characterized in that it contains a polyhydroxystyrene derivative as a base polymer, and the shape of the hole pattern formed on the film to be etched does not become a star with a large diameter, but a round hole pattern is obtained. be able to.

According to the hole pattern forming method of the third aspect, in the hole pattern forming method of the second aspect, the solvent constituting the photosensitive material film of the chemically amplified resist is lactic acid. It is characterized by containing ethyl, and the shape of the hole pattern formed in the film to be etched does not become a star with a large diameter, but a round hole pattern can be obtained.

According to the method for forming a hole pattern according to the fourth aspect, in the method for forming a hole pattern according to any one of the first to third aspects, the apparatus for dry-etching the film to be etched mainly comprises: A source power supply for generating plasma and a bias power supply for mainly drawing ions into the substrate are separately provided. By using a dry etching apparatus provided with two or more power supplies, Since high-density plasma can be generated, a hole pattern having a high aspect ratio can be formed.

According to the method for forming a hole pattern according to the fifth aspect, in the method for forming a hole pattern according to any one of the first to fourth aspects, the apparatus for dry-etching the to-be-etched film includes Characterized by a coupled plasma type, an electron cyclone resonance type, or a capacitively coupled plasma dual frequency type, or a surface wave plasma type, by using reactive etching with two or more power supplies. Since high-density plasma can be generated, a hole pattern having a high aspect ratio can be formed.

According to the method of forming a hole pattern according to the sixth aspect, a first step of forming a hole-patterned photosensitive material film on a film to be etched formed on a semiconductor substrate. A second step of performing dry etching on the film to be etched with the hole-patterned photosensitive material film as at least a part of a mask to form a hole pattern made of the film to be etched; In the method of forming a hole pattern provided with, the photosensitive material constituting the photosensitive material film is a novolak resin as a base polymer, a novolak type resist containing a quinone diacid compound as an acid generator, and the film to be etched is An apparatus for dry etching mainly includes a source power supply for generating plasma and a bias for mainly drawing ions into a substrate. And a dry etching apparatus for generating inductively coupled plasma with two or more power sources, such that a round hole pattern can be formed in a film to be etched. By using inductively coupled plasma type reactive etching having a power supply of (1), a high-density plasma can be generated, so that a hole pattern having a high aspect ratio can be formed.

[Brief description of the drawings]

FIGS. 1A to 1C are a front view, a cross-sectional view, a cross-sectional view, and a front view and a cross-sectional view showing each step of a hole pattern forming method according to the present invention and a conventional example.

2A and 2B are a front view and a cross-sectional view illustrating a problem in a conventional hole pattern forming method.

FIG. 3 is a diagram illustrating a relationship between a plasma density and a hole shape and size in the hole pattern forming method according to the present invention.

FIGS. 4A to 4F are diagrams showing shapes of hole patterns formed on a film to be etched under the conditions of Examples 1 and 2 and Reference Examples 1 to 4. FIGS.

[Explanation of symbols]

 Reference Signs List 1 semiconductor substrate 2 film to be etched 3 resist film 4 hole pattern 5 hole pattern

 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 2H025 AA03 AA09 AB16 AC01 AD03 BE00 BE01 BE07 BE08 CB16 CB29 CB41 CB42 CB45 CC03 FA07 FA41 5F004 AA11 BA04 BA14 BB13 BB19 DA01 DA02 DA16 DA23 DB06 EA04 EB01 FA01

Claims (6)

[Claims] A first step of forming a hole-patterned photosensitive material film on a film to be etched formed on a semiconductor substrate; A second step of performing a dry etching on the film to be etched as a part of a mask to form a hole pattern formed of the film to be etched; and a method of forming a hole pattern, comprising: The photosensitive material forming the film is a chemically amplified type containing at least one compound selected from the group consisting of an onium salt compound, a sulfonimide compound, a halogen-containing compound, a sulfone compound, a sulfonate compound, and a quinone diacid compound as an acid generator. The apparatus for dry etching the film to be etched is 2
A method of forming a hole pattern, comprising at least one power supply. 2. The method for forming a hole pattern according to claim 1, wherein the photosensitive material constituting the photosensitive material film of the chemically amplified resist contains a polyhydroxystyrene derivative as a base polymer. Of forming a hole pattern. 3. The method for forming a hole pattern according to claim 2, wherein the solvent constituting the photosensitive material film of the chemically amplified resist contains ethyl lactate. 4. The method for forming a hole pattern according to claim 1, wherein the apparatus for dry-etching the film to be etched mainly comprises: a source power supply for generating plasma; A method for forming a hole pattern, comprising separately providing a bias power supply to be drawn in. 5. The method for forming a hole pattern according to claim 1, wherein the apparatus for dry-etching the film to be etched is an inductively coupled plasma type, an electron cyclone resonance type, or a capacitively coupled type. A method for forming a hole pattern, wherein the hole pattern is a plasma two-frequency type or a surface wave plasma type. 6. A first step of forming a hole-patterned photosensitive material film on a film to be etched formed on a semiconductor substrate; A second step of performing a dry etching on the film to be etched as a part of a mask to form a hole pattern formed of the film to be etched; and a method of forming a hole pattern, comprising: The photosensitive material constituting the film is a novolak type resist containing a novolak resin as a base polymer and a quinone diacid compound as an acid generator. The apparatus for dry-etching the film to be etched mainly includes a source for generating plasma. Inductively coupled, with two or more power supplies, a power supply and a bias power supply that primarily pulls ions into the substrate Hole pattern forming method which is a dry etching apparatus for generating a plasma.