JP2000038317A - Make-up cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a make-up cosmetic comprising complex powder composed of different kinds of organopolysiloxanes, having excellent extensibility and spreadability and excellent feeling in use and stability. SOLUTION: This make-up cosmetic comprises (A) complex powder composed of different kinds of organopolysiloxanes, (B) powder containing colored powder and (C) an oil agent.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION The present invention relates to a makeup cosmetic which contains a composite powder comprising different kinds of organopolysiloxanes to provide a feeling of use such as a feeling of dryness, a refreshing feeling, and a good spreadability. The present invention relates to a makeup cosmetic having improved properties.

[0002]

2. Description of the Related Art Conventionally, polyorganosilsesquioxane resin fine particles and silicone rubber particles having rubber elasticity have been known as silicone fine particles. 1-2686
No. 15 and Japanese Patent Publication No. 7-053646 have already been proposed.

[0003]

However, the former cosmetics containing fine particles of polyorganosilsesquioxane resin, although having a high hardness of the fine particles of polyorganosilsesquioxane resin, are soft, It gave a hard feeling of discomfort. In addition, the latter fine particles having rubber elasticity have largely eliminated the disadvantages of the former, but are difficult to handle due to poor fluidity, and have a strong cohesiveness, so that they can be uniformly dispersed in various base materials. There were considerable restrictions on blending it into cosmetics, such as difficulty and poor compatibility with the base material.

[0004]

Means for Solving the Problems The inventors of the present invention have conducted intensive studies to solve the above-mentioned problems, and as a result, by blending a composite powder composed of different kinds of organopolysiloxanes into a makeup cosmetic, the present invention has been improved. It has been found that a makeup cosmetic having good usability such as feeling of use, refreshing feeling, and good spreadability can be obtained, and the present invention has been completed. That is, the present invention relates to a make-up cosmetic characterized by blending a composite powder composed of different kinds of organopolysiloxanes.

Hereinafter, the present invention will be described in detail.

The composite powder of the component (A) used in the present invention is obtained by adding a catalyst to an oil-based oil-in-water emulsion containing a) a vinyl group-containing organopolysiloxane and b) an organohydrogenpolysiloxane. After the curing reaction, a spherical silicone rubber cured product fine particle dispersion is obtained, an alkaline substance or an aqueous alkaline solution and an organotrialkoxysilane are added to the aqueous dispersion, and the organotrialkoxysilane is hydrolyzed and subjected to a condensation curing reaction. And a composite powder in which fine particles of a cured silicone rubber obtained by drying are coated with a cured polyorganosilsesquioxane.
A method for producing this composite powder is disclosed in
No. 5 publication may be followed. The average particle diameter of the spherical silicone rubber cured product fine particles of the spherical silicone rubber cured product fine particle dispersion is preferably 0.1 to 100 μm in terms of usability and usability. In the makeup cosmetic of the present invention, the compounding amount of this composite powder is 0.0
The content is preferably 1 to 30% by weight (hereinafter, simply referred to as "%"), and more preferably 0.05 to 10%. If the amount is less than 0.01%, effects such as a dry feeling cannot be sufficiently obtained, and if it exceeds 30%, it is not preferable in terms of usability. One or more of the composite powders can be used as necessary.

As the powder of the component (B) used in the present invention, if it is used in ordinary cosmetics, its shape (spherical, needle-like, plate-like, etc.) and particle size (haze) Irrespective of particle shape, fine particles, pigment grade, etc.) and particle structure (porous, non-porous, etc.), for example, inorganic powders such as titanium oxide, zirconium oxide, zinc oxide , Cerium oxide, magnesium oxide, barium sulfate,
Calcium sulfate, magnesium sulfate, calcium carbonate,
Magnesium carbonate, talc, synthetic mica, mica, kaolin, sericite, muscovite, synthetic mica, phlogopite, phlogopite,
Biotite, Lithium mica, Silicic acid, Silicic anhydride, Aluminum silicate, Magnesium silicate, Aluminum magnesium silicate, Calcium silicate, Barium silicate, Strontium silicate, Metal tungstate, Hydroxyapatite, Vermiculite, Heidilite , Bentonite, montmorillonite, hectorite, zeolite, ceramic powder, dibasic calcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, silica, etc .; organic powders include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, Polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, polymethyl methacrylate Doo powder, cellulose,
Silk powder, nylon powder, 12 nylon, 6
Nylon, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol resin, fluororesin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, microcrystalline fiber powder , Rice starch, lauroyl lysine, etc .; surfactant metal salt powders (metal soaps) include zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, cetyl Calcium phosphate, sodium sodium cetyl phosphate, etc .; Examples of colored pigments include iron oxide, iron hydroxide, inorganic red pigments of iron titanate, inorganic brown pigments such as γ-iron oxide,
Yellow iron oxide, inorganic yellow pigments such as loess, black iron oxide, inorganic black pigments such as carbon black, mango violet, inorganic violet pigments such as cobalt violet, chromium hydroxide,
Chromium oxide, cobalt oxide, inorganic green pigments such as cobalt titanate, navy blue, inorganic blue pigments such as ultramarine blue, tar pigments, lakes of natural pigments,
Pearl pigments include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, fish scale foil, titanium oxide Coated colored mica, etc .; as metal powder pigments, aluminum powder, copper powder, stainless powder, etc .; as tar pigments, Red No. 3, Red No. 104, Red No. 10
6, Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 227
No., Red No. 228, Red No. 230, Red No. 401, Red No. 505, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 2
No. 03, Yellow No. 204, Yellow No. 401, Blue No. 1, Blue No. 2, Blue No. 201, Blue No. 404, Green No. 3, Green No. 2
01, green 204, green 205, orange 201,
Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 20
No. 7, etc .; natural pigments are powders selected from carminic acid, laccaic acid, calsamine, bradyline, crocin, etc. These powders are compounded, and surface treatment is performed with an oil agent, silicone, or a fluorine compound. Powders may be used, and if necessary, one kind or two or more kinds can be used. In the makeup cosmetic of the present invention, the above-mentioned inorganic red pigment, brown pigment, yellow pigment, black pigment, purple pigment, green pigment, blue pigment, pearl pigment, tar pigment, It is essential that natural pigments and their raked ones, and furthermore, contain one or more of these pigments in a complex or colored powder that has been surface-treated with an oil agent, silicone, or fluorine compound I do. The amount of these colored powders varies depending on the use, and is not particularly limited.
01 to 30%.

The oil component (C) used in the present invention comprises:
As long as it is used for ordinary cosmetics, any of solid, semi-solid, liquid oils can be used,
For example, natural animal and vegetable fats and oils, and semi-synthetic fats and oils,
Avocado oil, linseed oil, almond oil, lobster wax, eno oil, olive oil, cocoa butter, kapok wax, kaya oil,
Carnauba wax, liver oil, candelilla wax, beef tallow, beef tallow, beef tallow, hardened tallow, kyonin oil, spermaceti, hardened oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sugar cane wax, sasanqua oil, sa Flower oil, shea butter, cinnamon oil, cinnamon oil, jojoba wax, shellac wax, turtle oil, soybean oil, teaseed oil, camellia oil, evening primrose oil, corn oil, lard, rapeseed oil, Japanese kiri oil,
Nuka wax, germ oil, horse fat, persic oil, palm oil, palm kernel oil, castor oil, hydrogenated castor oil, castor oil fatty acid methyl ester, sunflower oil, grape oil, bayberry wax, jojoba oil, macadamia nut oil, beeswax, mink oil, Cottonseed oil, cotton wax, mokuro, mokuro kernel oil, montan wax, coconut oil, hydrogenated coconut oil, tricoconut oil fatty acid glyceride, sheep fat, peanut oil, lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin fatty acid Isopropyl, hexyl laurate, POE lanolin alcohol ether, POE lanolin alcohol acetate, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, egg yolk oil, etc .; hydrocarbon oils such as ozokerite,
Squalane, squalene, ceresin, paraffin, paraffin wax, liquid paraffin, pristane, polyisobutylene, microcrystalline wax, petrolatum, etc .; As higher fatty acids, lauric acid, myristic acid,
Palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), isostearic acid, 12-hydroxystearic acid, etc .; Is lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyldecanol, octyldodecanol, cetostearyl alcohol, 2-decyltetradecinol, cholesterol, phytosterol , P
OE cholesterol ether, monostearyl glycerin ether (batyl alcohol) and the like; ester oils include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, N-alkyl glycol monoisostearate, isostearic acid Isocetyl, trimethylolpropane triisostearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate Octyldodecyl gum ester, oleyl oleate, octyldodecyl oleate, decyl oleate,
Neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, butyl acetate, isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate Isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, cholesteryl 12-hydroxystearylate, dipentaerythritol fatty acid ester, isopropyl myristate, octyldodecyl myristate, myristic acid 2-hexyldecyl, myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, N-lauroyl-L-glutamic acid-2-octyl Dodecyl ester, malic acid diisostearyl; the glyceride oil, aceto glyceride, triisooctanoate acid glyceride, triisostearate glyceride, triisopalmitate glyceride, tree 2-ethylhexanoic acid glyceride,
Glyceride monostearate, glyceride di-2-heptylundecanoate, glyceride trimyristate, etc .;
Higher alkoxy-modified silicones such as methylphenylpolysiloxane, methylhydrogenpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetramethylcyclotetrasiloxane, and stearosilicone, higher fatty acid-modified silicones, Silicone resin, silicone rubber, silicone resin, etc .; Examples of fluorine-based oils include perfluoropolyether, perfluorodecalin, perfluorooctane, etc. These oils may be used alone or in combination of two or more as necessary. it can.

The makeup cosmetic of the present invention includes components, water, alcohols, water-soluble polymers, film-forming agents, surfactants, and the like used in ordinary cosmetics as long as the effects of the present invention are not impaired. Oil-soluble gelling agent, organically modified clay mineral, resin,
UV absorbers, humectants, preservatives, antibacterials, fragrances, salts,
Antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin care ingredients, vitamins, amino acids, nucleic acids, hormones, clathrates and the like can be added.

The alcohols include lower alcohols such as ethanol and isopropanol, sugar alcohols such as sorbitol and maltose, and the sterols include cholesterol, sitosterol, phytosterol and lanosterol.

The water-soluble polymers include gum arabic, tragacanth, galactan, carob gum, guar gum,
Karaya gum, carrageenan, pectin, agar, quince seed (quince), starch (rice, corn,
Plant polymers such as potato, wheat), algae colloid, trant gum, locust bean gum, etc., microbial polymers such as xanthan gum, dextran, succinoglucan, pullulan, animal polymers such as collagen, casein, albumin, gelatin, etc. Carboxymethyl starch, starch polymers such as methylhydroxypropyl starch, methylcellulose, ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, nitrocellulose, cellulose sodium sulfate, sodium carboxymethylcellulose,
Crystalline cellulose, cellulose-based cellulosic polymer,
Alginate polymers such as sodium alginate and propylene glycol alginate; vinyl polymers such as polyvinyl methyl ether and carboxyvinyl polymer; polyoxyethylene polymers; polyoxyethylene polyoxypropylene copolymer polymers; polyacrylic acid Acrylic polymers such as sodium, polyethyl acrylate and polyacrylamide, polyethyleneimine, cationic polymers, bentonite, aluminum magnesium silicate, laponite, hectorite, and inorganic water-soluble polymers such as silicic anhydride are exemplified. Also, in this,
Film forming agents such as polyvinyl alcohol and polyvinyl pyrrolidone are also included.

The surfactant includes anionic, cationic, nonionic and amphoteric surfactants. Examples of the anionic surfactant include fatty acid soaps such as sodium stearate and triethanolamine palmitate, and alkyl surfactants. Ether carboxylic acids and salts thereof, carboxylic acid salts such as condensation of amino acids and fatty acids, alkyl sulfonic acids, alkene sulfonic acid salts, fatty acid ester sulfonic acid salts, fatty acid amide sulfonic acid salts, alkyl sulfonic acid salts and formalin condensates thereof Sulfonates, alkyl sulfates, secondary higher alcohol sulfates, alkyl and allyl ether sulfates, fatty acid ester sulfates, fatty acid alkylolamide sulfates, and roto oil sulfates , Alkyl phosphate, ether Phosphates, alkyl allyl ether phosphates, amide phosphates, N-acyl amino acid surfactants, etc .; Examples of the cationic surfactants include amine salts such as alkylamine salts, polyamines and amino alcohol fatty acid derivatives, and alkyl quaternaries. Ammonium salts, aromatic quaternary ammonium salts, pyridium salts, imidazolium salts and the like; as nonionic surfactants, sorbitan fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, propylene glycol fatty acid esters, polyethylene glycol fatty acid esters, Sucrose fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbita Fatty acid esters, polyoxyethylene sorbitol fatty acid esters,
Polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene hardened castor oil, polyoxyethylene phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxy Ethylene cholesteryl ether, polyoxyalkylene-modified organopolysiloxane, polyoxyalkylene
Alkyl co-modified organopolysiloxanes, alkanolamides, sugar ethers, sugar amides, etc .; Examples of amphoteric surfactants include betaines, aminocarboxylates, imidazoline derivatives and the like.

Examples of the oil-soluble gelling agent include metal soaps such as aluminum stearate, magnesium stearate and zinc myristate; amino acid derivatives such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine; Dextrin fatty acid esters such as dextrin palmitate, dextrin stearate, dextrin 2-ethylhexanoate palmitate, sucrose fatty acid esters such as sucrose palmitate and sucrose stearate, monobenzylidene sorbitol, dibenzylidene sorbitol Benzylidene derivatives of sorbitol such as dimethylbenzyl dodecylammonium montmorillonite clay, dimethyldioctadecyl ammonium montmorillonite clay, etc. Of organically modified clay minerals.

Examples of the ultraviolet absorber include benzoic acid-based ultraviolet absorbers such as para-aminobenzoic acid, anthranilic acid-based ultraviolet absorbers such as methyl anthranilate, salicylic acid-based ultraviolet absorbers such as methyl salicylate, and octyl paramethoxycinnamate. Cinnamic acid ultraviolet absorbers, benzophenone ultraviolet absorbers such as 2,4-dihydroxybenzophenone, and urocanic acid ultraviolet absorbers such as ethyl urocanate.

Examples of the humectant include sorbitol, xylitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, diglycerin, polyethylene glycol, hyaluronic acid, chondroitin sulfate, and pyrrolidone carboxylate.

Examples of preservatives include alkyl paraoxybenzoate, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol and the like.
Antibacterial agents include benzoic acid, salicylic acid, carboxylic acid, sorbic acid, paraoxybenzoate, parachloromethcresol, hexachlorophen, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide,
Photosensitizer, phenoxyethanol and the like.

As antioxidants, tocopherol, butylhydroxyanisole, dibutylhydroxytoluene and the like, and as pH adjusters, lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium hydrogencarbonate Chelating agents such as ammonium bicarbonate, alanine, sodium edetate,
Cooling agents such as sodium polyphosphate, sodium metaphosphate, phosphoric acid and the like include L-menthol and camphor, and anti-inflammatory agents include allantoin, glycyrrhetinic acid, tranixamic acid and azulene.

[0018] Components for beautifying skin include whitening agents such as placenta extract, arbutin, glutathione, and saxifrage extract, cell activating agents such as royal jelly, photosensitizer, cholesterol derivative, and calf blood extract, skin roughness improving agents, and nonyl. Acid valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, canthari tincture, ittamol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandate, cinnarizine Blood circulation promoters such as trazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol, zinc oxide, skin astringents such as tannic acid, sulfur,
Antiseborrheic agents such as thiantrol and the like, and the vitamins include vitamin A oil, retinol, retinol acetate, vitamin A such as retinol palmitate, riboflavin, riboflavin butyrate, vitamin B2 such as flavin adenine nucleotide, Vitamin B6 such as pyridoxine hydrochloride, pyridoxine dioctanoate, L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, dl-
Vitamin Cs such as α-tocopherol-L-ascorbic acid diester phosphate dipotassium, pantothenic acids such as calcium pantothenate, D-pantothenyl alcohol, pantothenyl ethyl ether, acetyl pantothenyl ethyl ether, ergocalciferol, cholecalciferol Vitamin Ds such as nicotinic acid, benzyl nicotinate, nicotinic acid such as nicotinamide, dl-
α-tocopherol, dl-α-tocopherol acetate,
Dl-α-tocopherol nicotinate, dl-succinate
There are vitamin Es such as α-tocopherol, vitamin P, biotin and the like. Examples of amino acids include arginine, aspartic acid, cystine, cysteine, methionine, serine, leucine, tryptophan and the like, nucleic acids such as deoxyribonucleic acid, and hormones such as estradiol and ethenyl estradiol.

The make-up cosmetics of the present invention may be in any form, shape, powder, press, cream, emulsion, liquid, stick, mousse, spray, emulsified, oily type. Any of them may be used, and examples thereof include white powder, foundation, blusher, eyeshadow, lipstick, eyeliner, mascara, eyebrow, nail polish and the like.

[0020]

EXAMPLES The present invention will be described below with reference to examples, but the present invention is not limited thereto.

(Production Example 1) The following chemical formula (1)

[0022]

Embedded image

The viscosity at 25 ° C. is 600 c
St methylvinylsiloxane (500 g) and the following chemical formula (2)

[0024]

Embedded image

The viscosity at 25 ° C. is 30 cS
20 g of methyl hydrogen polysiloxane of
After charging into a liter glass beaker and stirring and mixing at 2,000 rpm using a homomixer, 1 g of polyoxyethylene (additional mole number: 9 mol) octylphenyl ether and 150 g of water were added, and the mixture was stirred at 6,000 rpm.
After phase inversion, 329 g of water is further stirred under 2,000 rpm.
Was added to obtain an O / W emulsion.

The O / W type emulsion was transferred to a glass flask equipped with a stirrer using an anchor type stirring blade, and stirred at room temperature with 1 g of a toluene solution of chloroplatinic acid-olefin complex (platinum content: 0.05%). A mixture of 1 g of polyoxyethylene (additional mole number: 9 mol) octyl phenyl ether was added and a curing reaction was performed for 12 hours to obtain a dispersion of fine particles of a cured spherical silicone rubber. The average particle size of the fine particles of the cured spherical silicone rubber in this dispersion was measured using a Coulter Counter (manufactured by Coulter Electronics Co., Ltd.) and found to be 15 μm.

Next, 580 g of this spherical silicone rubber cured product fine particle dispersion, 2,290 g of water, and 60 g of aqueous ammonia (concentration: 28% by weight) were charged into a 3 liter glass flask and anchored at 10 ° C. and 200 rpm. Stir with stirring blades, 65 g of methyltrimethoxysilane
Was added dropwise over 20 minutes. The solution was stirred at a liquid temperature of 5 to 15 ° C. for 4 hours and further stirred at 55 to 60 ° C. for 1 hour to obtain a cake of about 30% water using a pressure filter. After drying at 105 ° C. with a jet mill, a composite powder was obtained.

This composite powder was dispersed in water using a surfactant, and the average particle size was measured by a Coulter counter to be 15 μm. Further, this composite powder was analyzed by weight analysis to obtain spherical silicone rubber cured product fine particles 100%.
10 parts by weight of the cured product of the polyorganosilsesquioxane was applied to the parts by weight.

(Production Example 2) 65 g of the methyltrimethoxysilane of Production Example 1 was replaced with methyltrimethoxysilane 5
5 g and γ-glycidoxypropyltrimethoxysilane 1
A composite powder was prepared in the same manner as in Production Example 1, except that the mixture was 0 g. This composite powder was dispersed in water using a surfactant, and the average particle size was measured by a Coulter counter to be 15 μm. This composite powder was determined by weight analysis to have 11 parts by weight of the cured polyorganosilsesquioxane coated on 100 parts by weight of the cured spherical silicone rubber fine particles.

(Production Example 3) O in Production Example 1
In the same manner as in Production Example 1, a dispersion of fine particles of spherical silicone rubber cured product was obtained in the same manner as in Production Example 1, except that the amount of polyoxyethylene (additional mole number: 9 mol) octylphenyl ether used in preparing the / W emulsion was 5 g. The average particle size of the spherical fine particles of silicone rubber was 3 μm as measured by using a Coulter counter. Production Example 1 using this spherical silicone rubber cured product fine particle dispersion
A composite powder was prepared in the same manner as described above. This composite powder was dispersed in water using a surfactant, and the average particle size was 3 μm as measured by a Coulter counter. or,
According to weight analysis, this composite powder was obtained by coating 10 parts by weight of a cured product of polyorganosilsesquioxane with respect to 100 parts by weight of the spherical silicone rubber cured product fine particles.

Example 1 and Comparative Examples 1-2: Foundations Foundations of the respective compositions shown in Table 1 were produced, and their feeling and usability were evaluated by the following methods.
Table 1 also shows the results.

[0032]

[Table 1]

* 1: Polymethylsilsesquioxane powder; Tospearl 3120 (spherical, average particle size: 12 μm, manufactured by Toshiba Silicone Co.) * 2: Silicone rubber cured product powder; Trefil E50
1 (spherical, average particle diameter 10 μm, manufactured by Dow Corning Toray)

(Production method) A: Components 1 to 10 are uniformly mixed. B: Components 11 to 16 are mixed, and A is added. C: Component 17 is added to B and press-molded on a metal plate.

(Evaluation method) A use test was carried out by a professional panel of 50 women, and it was taken off on a mat or sponge during use, difficult to cause caking, a feeling of dryness at the time of application, spread to the skin, smoothness, The goodness of the setting,
Then, the non-stickiness of the back skin, the beauty of the finish, and the goodness of the makeup were evaluated according to the following criteria, and the average score was determined. [Evaluation criteria] 5 points: Very good 4 points: Good 3 points: Normal 2 points: Somewhat poor 1 point: Poor [Judgment] ：: Average score of 4.5 or more ○: Average score of 3.5 or more and less than 4.5 Δ: Average score of 2.5 or more and less than 3.5 ×: Average score of less than 2.5

As is clear from the results shown in Table 1, the foundation of Example 1 in which the composite powder of the present invention was blended was much smoother than Comparative Example 1, and had a good fit, a beautiful finish, and a long lasting makeup. Was found to be excellent. In addition, it was found that, as compared with Comparative Example 2, the mat and sponge were easily removed during use, caking was less likely to occur, the fit was good, the finish was beautiful, and the makeup lasting was very good.

Example 2 Pressed Powder Foundation (Component) (%) Titanium oxide 5.0 2. Sericite 10.0 3. Kaolin 5.0 4. Talc balance 5. 5. zinc myristate 5.0 Bengara 0.77. Yellow iron oxide 2.2 8. Black iron oxide 0.19. Composite silicone powder (Production Example 2) 5.0 10. Porous spherical silica 10.0 11. Squalane 3.0 12. 12. Glyceryl trioctanoate 2.0 Preservative appropriate amount 14. Appropriate amount of fragrance

(Production method) A: Components 1 to 10 are mixed. B: Components 11 to 13 are mixed and added to A. C: Add component 14 to B, mix uniformly, and press into a gold pan.

The pressed powder foundation of the product of the present invention obtained as described above is very smooth and smooth, spreads lightly, is well settled, and is excellent in the beauty of the finish and the long lasting makeup. I understand.

Example 3 Stick Eye Shadow (Component) (%) Gypsum 35.0 2. Mica 10.0 3. Talc balance 4. Red No. 202 1.8 5. Yellow iron oxide 0.1 6. Black iron oxide 0.1 7. Ultramarine 8.0 8.0 Nylon powder 15.0 9. Composite silicone powder (Production Example 3) 5.0 10. Squalane 3.0 11. 11. Polyoxyethylene sorbitan monooleate 0.5 Glycerin 4.0 13. Preservative appropriate amount 14. Appropriate amount of perfume 15. Purified water qs (100.0) Ethanol appropriate amount (50.0)

(Production method) A: Components 1 to 9 are mixed. B: Components 10 to 16 are mixed. C: A is added to B, mixed, filled into a container, allowed to stand, cured, and dried.

The stick eyeshadow of the product of the present invention obtained as described above is very smooth and smooth, spreads lightly, is well settled, and is excellent in the beauty of the finish and the long lasting makeup. I understand.
In addition, it was excellent in usability, for example, it was not powdery and easily blurred during use.

Example 4: Blush (Ingredients) (%) 1. Titanium oxide 3.0 Mica 11.0 3. Red No. 226 0.44. Iron oxide yellow 0.65. 5. Composite silicone powder (Production Example 1) 10.0 Non-porous spherical silica 20.0 7. Selesin 4.0 8. Candelilla wax 1.09. Squalane balance 10. Dimethyl polysiloxane 15.0 11. Preservative qs. Appropriate amount of fragrance

(Production method) A: Components 7 to 11 are dissolved by heating. B: Components 1 to 6 are mixed and added to A. C: Add component 12 to B, mix uniformly, pour into container and cool.

The blusher of the product of the present invention obtained as described above is very smooth and smooth, spreads lightly, has a good fit, and is excellent in beauty of the finish and good durability of makeup. all right.

[0046]

The composite powder composed of different organopolysiloxanes used in the present invention has excellent fluidity and compatibility with the base material, and has low cohesiveness and excellent dispersibility. The makeup cosmetic of the present invention, which contains
Uses without stickiness or weight during application, lightly spreads, spreads lightly, and has a smooth and smooth feel on the back skin.It is also easy to remove on mats and sponges and does not cause caking. It is excellent in feeling and usability.

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Claims (4)

[Claims] (1) The following components (A) to (C): (A) a composite powder composed of different kinds of organopolysiloxanes; (B) a powder containing a colored powder; and (C) an oil agent. Makeup cosmetics. 2. A composite powder of component (A) is cured by adding a catalyst to an oil-based oil-in-water emulsion containing a) a vinyl group-containing organopolysiloxane and b) an organohydrogenpolysiloxane. After preparing an aqueous dispersion of fine particles of the cured spherical silicone rubber, an alkaline substance or an alkaline aqueous solution and an organotrialkoxysilane are added to the aqueous dispersion, and the organotrialkoxysilane is hydrolyzed, condensation-cured, and then dried. The makeup cosmetic according to claim 1 or 2, wherein the makeup powder is a composite powder obtained by coating a cured polyorganosilsesquioxane on fine particles of a cured spherical silicone rubber obtained by the above method. 3. The spherical silicone rubber cured product fine particle dispersion of the spherical silicone rubber cured product fine particle dispersion has an average particle size of:
The thickness is 0.1 to 100 μm.
3. The makeup cosmetic according to any one of 3. 4. The compounding powder of component (A) having a compounding amount of 0.0
The amount is 1 to 30% by weight.
The makeup cosmetic according to any one of the above.