JP2000028096A - Gas capsule - Google Patents

Gas capsule

Info

Publication number
JP2000028096A
JP2000028096A JP11096426A JP9642699A JP2000028096A JP 2000028096 A JP2000028096 A JP 2000028096A JP 11096426 A JP11096426 A JP 11096426A JP 9642699 A JP9642699 A JP 9642699A JP 2000028096 A JP2000028096 A JP 2000028096A
Authority
JP
Japan
Prior art keywords
capsule
free end
neck portion
filling
fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11096426A
Other languages
Japanese (ja)
Inventor
Michael Ernest Garrett
マイケル・アーネスト・ガレット
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BOC Group Ltd
Original Assignee
BOC Group Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BOC Group Ltd filed Critical BOC Group Ltd
Publication of JP2000028096A publication Critical patent/JP2000028096A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C5/00Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
    • F17C5/06Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with compressed gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00Details of vessels or of the filling or discharging of vessels
    • F17C13/06Closures, e.g. cap, breakable member
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01Shape
    • F17C2201/0104Shape cylindrical
    • F17C2201/0109Shape cylindrical with exteriorly curved end-piece
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/05Size
    • F17C2201/058Size portable (<30 l)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0646Aluminium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/068Special properties of materials for vessel walls
    • F17C2203/069Break point in the wall
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/01Pure fluids
    • F17C2221/016Noble gases (Ar, Kr, Xe)
    • F17C2221/017Helium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0107Single phase
    • F17C2223/0123Single phase gaseous, e.g. CNG, GNC
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/035High pressure (>10 bar)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2260/00Purposes of gas storage and gas handling
    • F17C2260/01Improving mechanical properties or manufacturing
    • F17C2260/013Reducing manufacturing time or effort
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/07Applications for household use
    • F17C2270/0736Capsules, e.g. CO2

Abstract

PROBLEM TO BE SOLVED: To provide a method for filling a capsule with fluid under high pressure. SOLUTION: A method for filling this capsule with helium includes steps that a first contracted diameter part is formed in the neck part 4 of the capsule separated from the free end part 6 of the neck part 4, and next, a second contracted diameter part is formed in a position located adjacently to the free end part 6 of the neck part 4, thereby forming a chamber effectively between two contracted diameter parts. The chamber prevents such that helium reaches the welded free end part 6.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、30バール〜80
バールの間の高圧における流体の容積を含むカプセルに
関する。
[0001] The present invention relates to a method for producing a bar between 30 bar and 80 bar.
It relates to a capsule containing a volume of fluid at high pressure between the bars.

【0002】[0002]

【従来の技術】シールされたカプセルは、ビールディス
ペンサーから生ビールを注ぐ場合やソーダサイホンから
ソーダ水を注ぐ場合など圧力下の流体の力は、内容物を
分配するということは、公知である。シールされたカプ
セルは、また、圧力下のソフトドリンク又はビール用の
流体容器としても用いられる。
BACKGROUND OF THE INVENTION It is known that sealed capsules distribute the contents under the pressure of a fluid under pressure, such as when pouring draft beer from a beer dispenser or when pouring soda water from a soda siphon. Sealed capsules are also used as fluid containers for soft drinks or beer under pressure.

【0003】さらに、患者の皮膚を通して治療薬剤を分
配するために、加圧されたヘリウムのエネルギーを用い
る医療機器において、高圧下のヘリウムを含有するシー
ルされたカプセルを用いることも公知である。
[0003] It is further known to use sealed capsules containing helium under high pressure in medical devices that use pressurized helium energy to distribute therapeutic agents through the skin of a patient.

【0004】国際公開された国際出願WO94/242
63において、ニードルのないシリンジが記載されてい
る。このシリンジは、実質的に痛みのない態様で、治療
薬剤の粒子を患者の皮膚に強制的に通過させるために用
いられる高圧のヘリウムガスを含有する金属カプセルを
含む。このカプセルは、シリンジの残りの部分から脱着
可能であり、一度使用されると、カプセル内へのガスの
新規充填が可能であるか、より好ましくはカプセルを廃
棄して、ガスで充填された新しいカプセルをシリンジの
残りの部分に取り付けることができる。
[0004] International published application WO 94/242.
At 63, a syringe without a needle is described. The syringe includes a metal capsule containing high pressure helium gas that is used to force particles of the therapeutic agent through the patient's skin in a substantially painless manner. The capsule is detachable from the rest of the syringe and, once used, allows a new filling of the gas into the capsule or, more preferably, discards the capsule and replaces it with a new gas-filled one. The capsule can be attached to the rest of the syringe.

【0005】ガスカプセルが使い捨てアイテムである場
合には、ガスカプセルは簡単に且つ低コストで製造でき
ることが重要である。医療機器への適用において、ヘリ
ウムガスは非常に軽量であり、患者の皮膚に突き当たる
際に治療薬剤の推進剤として用いるのに適しており、大
気中に跳ね返って患者の皮膚を通過しないので、ヘリウ
ムガスは好ましい流体源である。しかし、ヘリウムガス
は軽量であるので、容器の微細な欠陥からリークするで
あろうから、容器に充填することは困難である。
When the gas capsule is a disposable item, it is important that the gas capsule can be manufactured easily and at low cost. In medical device applications, helium gas is very lightweight, suitable for use as a propellant for therapeutic agents when striking the patient's skin, and does not bounce back into the atmosphere and pass through the patient's skin, making it helium gas. Gas is a preferred source of fluid. However, helium gas is lightweight and will leak from microscopic defects in the container, making it difficult to fill the container.

【0006】[0006]

【発明が解決しようとする課題】本発明の目的は、高圧
下の流体でカプセルを充填する方法を提供することにあ
る。特に、少なくとも30バールの圧力下のヘリウムガ
スでガスカプセルを充填する方法を提供することにあ
る。
It is an object of the present invention to provide a method for filling capsules with a fluid under high pressure. In particular, it is an object to provide a method for filling gas capsules with helium gas under a pressure of at least 30 bar.

【0007】[0007]

【課題を解決するための手段】本発明によれば、中空本
体部分と、中空本体部分から延びる中空首部分と、を有
するカプセルを圧力下の流体で充填する方法が提供され
る。この方法は、a)流密状態で、充填キャップを上記
首部分の自由端部に取り付けて、上記中空本体部分を真
空にして、続いて、上記中空本体部分を圧力下の流体で
充填する工程と、b)流体に圧力がかけられているま
ま、上記充填キャップが定置に置かれているままで、上
記首部分の自由端部から離隔した位置で、上記首部分を
縮径させる工程と、c)上記充填キャップを取り除き、
こうして上記首部分の自由端部を露出させる工程と、
d)上記首部分の自由端部に隣接して、第2の縮径を与
える工程と、e)上記首部分の自由端部を溶接して、カ
プセルを密閉してシールする工程と、を備える。
According to the present invention, there is provided a method of filling a capsule having a hollow body portion and a hollow neck portion extending from the hollow body portion with a fluid under pressure. The method comprises the steps of: a) in a fluid-tight condition, attaching a filling cap to the free end of the neck portion, evacuating the hollow body portion, and subsequently filling the hollow body portion with a fluid under pressure. B) reducing the diameter of the neck portion at a location remote from the free end of the neck portion while the fill cap remains stationary while fluid is under pressure; c) removing the filling cap,
Exposing the free end of the neck portion in this way;
d) providing a second reduced diameter adjacent to the free end of the neck portion; and e) welding the free end of the neck portion to hermetically seal the capsule. .

【0008】好ましくは、上記流体は、少なくとも30
バールの圧力下のヘリウムである。
Preferably, the fluid comprises at least 30
Helium under bar pressure.

【0009】[0009]

【好ましい実施形態】以下、添付図面を参照しながら、
本発明を更に詳細に説明するが、本発明はこれらに限定
されるものではない。
Preferred embodiments will be described below with reference to the accompanying drawings.
The present invention will be described in more detail, but the present invention is not limited thereto.

【0010】図示するように、カプセル1は、例えばア
ルミニウム又はアルミニウム合金から作られた中空円筒
状本体部分2を備える。中空円筒状本体部分2からは、
細長い中空首部分4が延びている。中空首部分4の直径
は、中空本体部分2の直径よりも小さい。初期状態にお
いて、首部分4は、開放自由端部6を有している。
As shown, the capsule 1 comprises a hollow cylindrical body part 2 made for example of aluminum or an aluminum alloy. From the hollow cylindrical main body part 2,
An elongated hollow neck portion 4 extends. The diameter of the hollow neck portion 4 is smaller than the diameter of the hollow body portion 2. In the initial state, the neck part 4 has an open free end 6.

【0011】カプセル1を圧力下のヘリウムガスなどで
充填したい場合には、充填キャップ(図示せず)を首部
分4の自由端部6に公知の態様で取り付ける。充填キャ
ップが取りつけられ、中空円筒状本体部分2が真空にさ
れた後、本体部分2は圧力下の流体で充填される。充填
キャップが首部分4の自由端部上の定置にあり、圧力が
本体部分2内の流体にかけられている状態で、首部分4
は自由端部6から離隔した位置で縮径させられる(図2
参照)。この縮径は、本体部分2から流体の顕著なリー
クを避けるために十分にしっかりと堅い。
If it is desired to fill the capsule 1 with helium gas or the like under pressure, a filling cap (not shown) is attached to the free end 6 of the neck 4 in a known manner. After the filling cap is attached and the hollow cylindrical body part 2 is evacuated, the body part 2 is filled with a fluid under pressure. With the filling cap in place on the free end of the neck portion 4 and pressure applied to the fluid in the body portion 2, the neck portion 4
Is reduced at a position away from the free end 6 (FIG. 2).
reference). This reduced diameter is sufficiently rigid to avoid significant leakage of fluid from the body portion 2.

【0012】次いで、充填キャップは、首部分4の自由
端部6から取り除かれて、自由端部6を露出させる。自
由端部6が露出されるとすぐに、自由端部に隣接した位
置に、第2の縮径が与えられる(図3参照)。ほぼ同時
に、自由端部6は、レーザー溶接されて、首部分4の端
部を密閉状態にシールする。
[0012] The filling cap is then removed from the free end 6 of the neck portion 4 exposing the free end 6. As soon as the free end 6 is exposed, a second diameter reduction is applied at a position adjacent to the free end (see FIG. 3). At about the same time, the free end 6 is laser welded to hermetically seal the end of the neck portion 4.

【0013】第1の縮径の目的は、圧力下の流体が第2
の縮径よって自由端部6に到達することを防止すること
にあり、ガス透過孔なしにレーザー溶接可能とすること
にある。効果的に、2つの縮径は、溶接されるべき首部
分4の自由端部6のポイントに圧力下の流体が到達する
ことを防止又は抑制する暫定チャンバを規定する。
[0013] The purpose of the first diameter reduction is to make the fluid under pressure the second diameter.
Is to prevent the free end 6 from being reached by the reduced diameter, and to enable laser welding without gas permeation holes. Effectively, the two reduced diameters define a provisional chamber that prevents or suppresses fluid under pressure from reaching the point of the free end 6 of the neck portion 4 to be welded.

【0014】縮径は、円形スエージングタイプでも、単
純なフラットタイプでもよい。カプセルがニードルなし
のシリンジと一緒に用いられるべき場合には、流体は少
なくとも30バールのヘリウムガスである。
The diameter can be reduced to a circular swaging type or a simple flat type. If the capsule is to be used with a syringe without a needle, the fluid is at least 30 bar of helium gas.

【0015】本発明は、実質的に30バール以下のガス
又は液体を含有するカプセルなどの別の実施形態にも適
用可能であることは明らかである。
Obviously, the invention is also applicable to other embodiments, such as capsules containing substantially no more than 30 bar of gas or liquid.

【図面の簡単な説明】[Brief description of the drawings]

【図1】図1は、圧力下の流体を含有するためのカプセ
ルの平面図である。
FIG. 1 is a plan view of a capsule for containing a fluid under pressure.

【図2】図2は、カプセルの首部分に与えられた第1の
縮径を示す図1と同様の平面図である。
FIG. 2 is a plan view similar to FIG. 1, showing a first diameter reduction applied to the neck of the capsule.

【図3】図3は、本発明による首部分の第2の縮径を示
す図1及び図2と同様の平面図である。
FIG. 3 is a plan view similar to FIGS. 1 and 2 showing a second diameter reduction of the neck portion according to the present invention.

【符号の説明】[Explanation of symbols]

1:カプセル 2:本体部分 4:首部分 6:自由端部 1: Capsule 2: Body part 4: Neck part 6: Free end

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 圧力下の流体で、中空本体部分及び上記
中空本体部分から延びる中空首部分を有するカプセルを
充填する方法であって、 a)流密状態で、充填キャップを上記首部分の自由端部
に取り付け、上記中空本体部分を空にして、続いて上記
中空本体部分を圧力下の流体で充填する工程と、 b)上記充填キャップを定置に置いたまま及び圧力が上
記流体にかけられているままで、上記首部分を上記首部
分の自由端部から離隔した位置にて縮径させる工程と、 c)上記充填キャップを取り除き、こうして上記首部分
の自由端部を露出させる工程と、 d)上記首部分の上記自由端部に隣接して第2の縮径を
与える工程と、 e)上記首部分の上記自由端部を溶接して、カプセルを
密閉的にシールする工程と、を備えることを特徴とする
カプセルの充填方法。
1. A method for filling a capsule having a hollow body portion and a hollow neck portion extending from said hollow body portion with a fluid under pressure, comprising: a) in a fluid-tight state, a filling cap free of said neck portion. Attaching to the end, emptying said hollow body portion and subsequently filling said hollow body portion with fluid under pressure; b) leaving said filling cap in place and applying pressure to said fluid. Reducing the diameter of the neck portion at a location remote from the free end of the neck portion while remaining, c) removing the filler cap, thus exposing the free end of the neck portion; d. A) providing a second reduced diameter adjacent the free end of the neck portion; and e) welding the free end of the neck portion to hermetically seal the capsule. Caps characterized by the following The method of filling Lumpur.
【請求項2】 請求項1のカプセルの充填方法であっ
て、前記流体は少なくとも30バールの圧力下のヘリウ
ムであることを特徴とするカプセルの充填方法。
2. The method according to claim 1, wherein the fluid is helium under a pressure of at least 30 bar.
【請求項3】 請求項1又は請求項2のカプセルの充填
方法であって、前記カプセルはアルミニウム又はアルミ
ニウム合金から作られていることを特徴とするカプセル
の充填方法。
3. The method according to claim 1, wherein the capsule is made of aluminum or an aluminum alloy.
【請求項4】 請求項1〜請求項3のいずれか1に記載
のカプセルの充填方法であって、前記首部分の自由端部
は、レーザー溶接されて、カプセルを密閉してシールす
ることを特徴とするカプセルの充填方法。
4. The capsule filling method according to claim 1, wherein the free end of the neck portion is laser-welded to hermetically seal the capsule. Characteristic capsule filling method.
JP11096426A 1998-04-03 1999-04-02 Gas capsule Pending JP2000028096A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9807175.6 1998-04-03
GBGB9807175.6A GB9807175D0 (en) 1998-04-03 1998-04-03 Gas capsule

Publications (1)

Publication Number Publication Date
JP2000028096A true JP2000028096A (en) 2000-01-25

Family

ID=10829802

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11096426A Pending JP2000028096A (en) 1998-04-03 1999-04-02 Gas capsule

Country Status (12)

Country Link
EP (1) EP0947760B1 (en)
JP (1) JP2000028096A (en)
AU (1) AU742318B2 (en)
CA (1) CA2267483C (en)
CZ (1) CZ300634B6 (en)
DE (1) DE69934159T2 (en)
ES (1) ES2274603T3 (en)
GB (1) GB9807175D0 (en)
HU (1) HU226351B1 (en)
PL (1) PL190106B1 (en)
SK (1) SK285394B6 (en)
ZA (1) ZA992515B (en)

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FR2895060B1 (en) * 2005-12-20 2008-02-15 Renault Sas DEVICE FOR FILLING A GAS BOTTLE.
RU2690394C2 (en) * 2017-10-03 2019-06-03 Акционерное общество "Военно-промышленная корпорация "Научно-производственное объединение машиностроения" Device for gas cylinder charging and sealing by welding
US20190240694A1 (en) 2018-02-05 2019-08-08 Airgas, Inc. Method for filling pressurized gas cartridges for medical use

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DE69934159D1 (en) 2007-01-11
EP0947760A3 (en) 1999-12-01
HUP9900776A3 (en) 2001-06-28
CZ111599A3 (en) 1999-12-15
EP0947760A2 (en) 1999-10-06
EP0947760B1 (en) 2006-11-29
AU742318B2 (en) 2001-12-20
HU226351B1 (en) 2008-09-29
ES2274603T3 (en) 2007-05-16
DE69934159T2 (en) 2007-09-27
HUP9900776A2 (en) 2000-05-28
PL332350A1 (en) 1999-10-11
HU9900776D0 (en) 1999-05-28
SK43999A3 (en) 1999-11-08
AU2245599A (en) 1999-10-14
PL190106B1 (en) 2005-10-31
ZA992515B (en) 1999-10-05
SK285394B6 (en) 2007-01-04
CZ300634B6 (en) 2009-07-08
CA2267483A1 (en) 1999-10-03
GB9807175D0 (en) 1998-06-03
CA2267483C (en) 2007-01-30

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