JP2000001884A - Water path branch member, water stop member and discharge device - Google Patents
Water path branch member, water stop member and discharge deviceInfo
- Publication number
- JP2000001884A JP2000001884A JP10186980A JP18698098A JP2000001884A JP 2000001884 A JP2000001884 A JP 2000001884A JP 10186980 A JP10186980 A JP 10186980A JP 18698098 A JP18698098 A JP 18698098A JP 2000001884 A JP2000001884 A JP 2000001884A
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- Prior art keywords
- branch
- phase
- water
- channel
- member according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、水路分岐部材およ
び止水部材、これらを具備する吐水装置に関するもので
ある。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a water channel branching member and a water stopping member, and to a water discharging device provided with these members.
【0002】[0002]
【従来の技術】図1は水路分岐部材を具備する吐水装置
を示しており、この吐水装置は、吐水装置本体1、分岐
金具2、吐水温度、流量制御用のカートリッジ3、カー
トリッジ3を分岐金具2に取り付けるためのカバーナッ
ト4、カバー5、レバーハンドル6より構成されてい
る。2. Description of the Related Art FIG. 1 shows a water spouting device provided with a water channel branching member. This water spouting device includes a water spouting device main body 1, a branch fitting 2, a cartridge 3 for controlling water discharge temperature and flow rate, and a cartridge 3 with a branch fitting. The cover 2 includes a cover nut 4, a cover 5, and a lever handle 6.
【0003】分岐金具2の側面には分岐出口7が形成さ
れており、分岐出口7には、袋ナット8、ストレーナ
9、止水栓10、パッキン11を介して給湯ホース12
が接続されており、給湯ホース12は、また、食器洗い
器(図示せず)等の末端機器に接続されている。A branch outlet 7 is formed on a side surface of the branch fitting 2, and the branch outlet 7 is provided with a hot water supply hose 12 through a cap nut 8, a strainer 9, a water stopcock 10, and a packing 11.
The hot water supply hose 12 is also connected to a terminal device such as a dishwasher (not shown).
【0004】以上の示した吐水装置では、吐水装置本体
1下方に接続された給湯、給水管(図示せず)からの給
湯、給水を、レバーハンドル6の操作によりカートリッ
ジ3内部で適温、適量の混合湯とし、吐水装置本体1先
端の吐水口1aへ供給するものである。In the above-described water discharge device, the hot water and the hot water supplied from the water supply pipe (not shown) connected below the water discharge device main body 1 are supplied to the inside of the cartridge 3 by operating the lever handle 6 at an appropriate temperature and amount. The mixed water is supplied to the water discharge port 1a at the tip of the water discharge device main body 1.
【0005】一方、給湯管からの給湯の一部は、カート
リッジ3に至る前に分岐出口7から分岐し、給湯ホース
12を介して食器洗い器等に供給されるのである。On the other hand, a part of the hot water supplied from the hot water supply pipe branches off from the branch outlet 7 before reaching the cartridge 3 and is supplied to the dishwasher or the like via the hot water supply hose 12.
【0006】図2は分岐金具2の詳細を示しており、分
岐金具2には分岐部材21が内蔵され、分岐部材21に
は長短2つのブッシュ22、23が挿入されている。FIG. 2 shows the details of the branch metal fitting 2. The branch metal fitting 2 has a built-in branch member 21, into which two long and short bushings 22, 23 are inserted.
【0007】分岐部材21には、また、上面に給水出口
24b、給湯出口25b、混合湯入口26、側面に給水
分岐出口24c、給湯出口25cが形成されるととも
に、Oリング27、28が具備されている。The branch member 21 has a water supply outlet 24b, a hot water supply outlet 25b, a mixed hot water inlet 26 on the upper surface, a water supply branch outlet 24c and a hot water supply outlet 25c on the side surface, and O-rings 27 and 28. ing.
【0008】図3は、この分岐部材21の断面図であ
り、分岐部材21内部には、給水路24、給湯路25、
混合湯流路(図示せず)が形成されている。給水路24
には、両端に給水入口24a、給水出口24b、中途に
給水分岐出口24cが形成され、給湯路25には、両端
に給湯入口25a、給湯出口25b、中途に給湯分岐出
口25cが形成されている。FIG. 3 is a cross-sectional view of the branching member 21. Inside the branching member 21, a water supply channel 24, a hot water supply channel 25,
A mixed hot water channel (not shown) is formed. Water supply channel 24
, A water supply inlet 24a and a water supply outlet 24b at both ends, a water supply branch outlet 24c at the middle, and a hot water supply passage 25 having a water supply inlet 25a, a water supply outlet 25b at both ends, and a water supply branch outlet 25c at the middle. .
【0009】そして、給水路24には、給水入口24a
側から長い方のブッシュ22が挿入され、給水分岐出口
24cを閉塞している。一方、給湯路25には、給湯入
口25a側から短い方のブッシュ23が挿入されるた
め、給湯分岐出口25cは閉塞されない。したがって、
給湯入口25aから入った給湯は、給湯分岐出口25c
を経て分岐出口7に至るのである。A water supply passage 24 has a water supply inlet 24a.
The longer bush 22 is inserted from the side, and closes the water supply branch outlet 24c. On the other hand, since the shorter bush 23 is inserted into the hot water supply passage 25 from the hot water supply inlet 25a side, the hot water supply branch outlet 25c is not closed. Therefore,
Hot water supplied from the hot water inlet 25a is supplied to the hot water branch outlet 25c.
And reaches the branch exit 7.
【0010】以上は、分岐出口7から給湯を分岐する例
であったが、給水路24に短い方のブッシュ23を挿入
し、給湯路25に長い方のブッシュ22を挿入すれば、
分岐出口7から給水を分岐するようになっている。In the above description, the hot water is branched from the branch outlet 7, but if the short bush 23 is inserted into the water supply channel 24 and the long bush 22 is inserted into the hot water channel 25,
Water is branched from the branch outlet 7.
【0011】[0011]
【発明が解決しようとする課題】以上のように分岐部材
21は、内部に流路を有する構造であるため、従来より
その材料としては、鍛造性や切削性に優れた黄銅材料が
用いられていた。As described above, since the branch member 21 has a structure having a flow path therein, a brass material excellent in forgeability and machinability has been conventionally used as the material. Was.
【0012】しかしながら、黄銅材料には常に耐食性
(耐脱亜鉛腐食性)の問題があるため、耐食性を向上さ
せた黄銅材料を用いることが従来より検討されてきた
が、従来知られている材料では、耐食性を向上させると
逆に加工性が低下するため、単一の材料にて加工性と耐
食性を両立させるのは困難であった。However, since brass materials always have a problem of corrosion resistance (dezincification corrosion resistance), the use of brass materials with improved corrosion resistance has been conventionally studied. On the other hand, when the corrosion resistance is improved, the workability is reduced, and it is difficult to achieve both the workability and the corrosion resistance with a single material.
【0013】そこで、従来は、加工性に優れた黄銅製の
分岐部材21に、耐食性に優れた青銅製ブッシュ22、
23を挿入することも行われていた。Therefore, conventionally, a bronze bush 22 having excellent corrosion resistance is provided on a brass branch member 21 having excellent workability.
23 was also inserted.
【0014】ところが、青銅製ブッシュ22、23それ
自体は耐食性に優れているものの、黄銅製の分岐部材2
1と青銅製ブッシュ22、23は異種金属であるため、
その接触面で腐食を起こすという新たな問題を生じてい
た。However, although the bronze bushes 22 and 23 themselves are excellent in corrosion resistance, the brass branch member 2 is made of brass.
1 and bronze bushes 22 and 23 are different metals,
There has been a new problem of corrosion at the contact surface.
【0015】本発明は、加工性と耐食性を両立した材料
を用いることにより、寸法精度が良く、かつ耐久性に優
れた水路分岐部材を提供することを目的とする。An object of the present invention is to provide a waterway branching member having good dimensional accuracy and excellent durability by using a material having both workability and corrosion resistance.
【0016】[0016]
【課題を解決するための手段およびその作用・効果】本
発明では、外壁に流入孔、流出孔、分岐流出孔を備え、
内部には、流入孔から流出孔に至る主流路と、主流路か
ら分岐して分岐流出孔に至る分岐流路と、を形成してな
る水路分岐部材において、主流路内壁、分岐流路内壁の
少なくとも一部が、見掛け上のZn含有量が37〜46
wt%で、Snの含有量が0.5〜7wt%である黄銅
材料を具備しているため、寸法精度が良く、かつ耐久性
に優れた水路分岐部材を提供することができる。According to the present invention, an outer wall is provided with an inflow hole, an outflow hole, and a branch outflow hole.
Inside, a main flow path from the inflow hole to the outflow hole, and a branch flow path branching from the main flow path to the branch outflow hole, in the waterway branch member, the main flow path inner wall, the branch flow path inner wall At least a portion has an apparent Zn content of 37 to 46.
Since the brass material having a Sn content of 0.5 to 7 wt% in wt% is provided, it is possible to provide a waterway branching member having good dimensional accuracy and excellent durability.
【0017】すなわち、従来の耐脱亜鉛腐食性に優れた
黄銅材料は、耐脱亜鉛腐食性向上のために、結晶組織を
α単相化としたため、鍛造性、切削性等の加工性に劣っ
ていたのに対して、本発明では、見掛け上のZn含有量
が37〜46wt%としたため、結晶組織にβ、γ相を
適正比率で存在させて鍛造性、切削性等の加工性を向上
させることが可能となったのである。そして一方、Sn
の含有量を0.5〜7wt%にすることによって、耐脱
亜鉛腐食性を確保しているのである。That is, the conventional brass material having excellent dezincification corrosion resistance is inferior in workability such as forgeability and machinability because the crystal structure is made into an α single phase in order to improve the dezincification corrosion resistance. On the other hand, in the present invention, the apparent Zn content is set to 37 to 46 wt%, so that β and γ phases are present at an appropriate ratio in the crystal structure to improve workability such as forgeability and machinability. It became possible to make it. And on the other hand, Sn
The zinc content is set to 0.5 to 7% by weight to ensure the dezincification corrosion resistance.
【0018】ここで、「見かけ上のZn含有量」という
用語は、AをCu含有量〔wt%〕、BをZn含有量
〔wt%〕、tを添加した第3元素(例えばSn)のZ
n当量、Qをその第3元素の含有量〔wt%〕としたと
き、「{(B+t・Q)/(A+B+t・Q)}×10
0」の意味で用いる。Here, the term "apparent Zn content" means that A is Cu content [wt%], B is Zn content [wt%], and t is the third element (for example, Sn). Z
When n equivalents and Q are the content of the third element [wt%], “{(B + t · Q) / (A + B + t · Q)} × 10
0 ”is used.
【0019】本発明の実施形態としては、主流路とし
て、水流路、湯流路、前記水流路の水と前記湯流路の湯
の混合湯流路、のように複数流路を備え、分岐流路も複
数備えたものに適用することが好ましい。なぜならば、
限られたスペースの中にこのような複数の流路を内蔵す
ると、各流路の壁面の肉厚をさほど取れないため、耐脱
亜鉛腐食性向上の要求がより高いからである。According to an embodiment of the present invention, a plurality of flow paths are provided as a main flow path, such as a water flow path, a hot water flow path, and a mixed hot water flow path of water in the water flow path and hot water in the hot water flow path. It is preferable to apply the present invention to a device having a plurality of flow paths. because,
This is because if such a plurality of flow paths are built in a limited space, the wall thickness of each flow path cannot be made so large, and the demand for improvement in the dezincification corrosion resistance is higher.
【0020】また、以上のような黄銅材料により構成さ
れた主流路内壁、分岐流路内壁の少なくとも一部は、切
削加工、鍛造により形成される他、基材に挿入された管
材により形成されても良い。特に、主流路、分岐流路を
複数具備するとともに、管材を基材に挿入して分岐流路
を閉塞するようにすれば、給湯分岐用部材、給水分岐用
部材というように2種類の水路分岐部材を準備する必要
がない。Further, at least a part of the inner wall of the main flow passage and the inner wall of the branch flow passage made of the brass material as described above is formed by cutting or forging, and is formed by a pipe material inserted into the base material. Is also good. In particular, if a plurality of main flow paths and branch flow paths are provided and a pipe material is inserted into the base material to close the branch flow path, two types of water path branching members such as a hot water supply branch member and a water supply branch member are provided. There is no need to prepare components.
【0021】黄銅材料の結晶組織としては、平均結晶粒
径15μm以下とすることにより、熱間鍛造性の向上を
図れるほか、2相以上の結晶組織とすることにより、切
削性、耐脱亜鉛腐食性を向上させることができる。As for the crystal structure of the brass material, it is possible to improve the hot forging property by setting the average crystal grain size to 15 μm or less. Performance can be improved.
【0022】具体的には、切削性のよいβ相の面積比率
を15%以上にして切削性を確保し、かつβ相中のSn
濃度を1.5wt%以上にして耐脱亜鉛腐食性を確保し
ている。このような結晶組織は、結晶相の変態温度域か
らの冷却速度を制御、例えば急冷することにより、結晶
相比率及び結晶相内のSn濃度を調整して得られる。More specifically, the area ratio of the β phase having good machinability is set to 15% or more to secure the machinability, and Sn in the β phase is secured.
By making the concentration 1.5% by weight or more, dezincification corrosion resistance is secured. Such a crystal structure is obtained by controlling the cooling rate of the crystal phase from the transformation temperature range, for example, by quenching to adjust the crystal phase ratio and the Sn concentration in the crystal phase.
【0023】また、α相の面積比率が40〜94%、β
相の面積比率が3〜30%、γ相の面積比率が3〜30
%の結晶組織では、β相の存在とα、γ相粒界の硬度差
により切削性を確保し、Sn濃度8wt%以上のγ相で
β相を囲むことにより耐脱亜鉛腐食性を確保している。Further, the area ratio of the α phase is 40 to 94%,
Phase area ratio is 3 to 30%, γ phase area ratio is 3 to 30
%, The cutting property is secured by the existence of the β phase and the hardness difference between the α and γ phase grain boundaries, and the dezincification corrosion resistance is secured by surrounding the β phase with the γ phase having a Sn concentration of 8 wt% or more. ing.
【0024】別の具体例では、耐脱亜鉛腐食性に劣るβ
相の面積比率を2%以下、γ相中のSn濃度を8wt%
以上にして耐脱亜鉛腐食性を確保し、γ相の面積比率を
8〜15%、残部α相としてα、γ相粒界の硬度差によ
り切削性を確保している。このような結晶組織は、α+
γの変態温度域で焼鈍し、β相の面積比率を減少させる
ことにより得られる。In another embodiment, β has a poor zinc-free corrosion resistance.
Phase area ratio is 2% or less, Sn concentration in γ phase is 8wt%
As described above, the dezincification corrosion resistance is secured, the area ratio of the γ phase is 8 to 15%, and the machinability is secured by the hardness difference between the α and γ phase grain boundaries as the remaining α phase. Such a crystal structure is α +
It is obtained by annealing in the transformation temperature range of γ to reduce the area ratio of β phase.
【0025】また、水路分岐部材を具備する吐水装置で
は、特に台所用吐水装置や、水路分岐部材が取り付け、
取り外し自在である場合、見栄えの都合上、水路分岐部
材のコンパクト化の要求が強い。そこで以上説明した水
路分岐部材を適用すれば、内部流路壁面の肉厚が薄くて
も耐久性があるためコンパクト化の要求に沿うばかり
か、加工性が良いためコンパクト化されても寸法精度が
確保できるのである。In the water spouting device having the water channel branching member, the kitchen water spouting device and the water channel branching member are attached.
When it is detachable, there is a strong demand for downsizing the waterway branching member for convenience of appearance. Therefore, if the above-described channel branching member is applied, even if the wall thickness of the internal flow path is thin, it is durable and not only meets the demand for compactness, but also has good workability, so that the dimensional accuracy is reduced even if the size is reduced. It can be secured.
【0026】尚、分岐流出孔に連通する末端機器として
は、食器洗い器、浄水器、アルカリイオン整水器等の機
器が有り、給水仕様の機器の場合は分岐流出孔から給水
し、給湯仕様の機器の場合は、分岐流出孔から給湯すれ
ばよい。In addition, as terminal devices communicating with the branch outlet, there are devices such as a dishwasher, a water purifier, and an alkali ion water conditioner. In the case of a water supply type device, water is supplied from the branch outlet and a hot water supply type. In the case of equipment, hot water may be supplied from the branch outlet.
【0027】本発明の別の側面では、外壁に流入孔、流
出孔を備え、内部には、流入孔から流出孔に至る流路
と、この流路を開閉する弁体と、この弁体が着座する弁
座と、を具備してなる止水部材において、流路内壁およ
び弁座を、見掛け上のZn含有量が37〜46wt%
で、Snの含有量が0.5〜7wt%である黄銅材料に
て一体で形成することができる。According to another aspect of the present invention, an outer wall is provided with an inflow hole and an outflow hole, and a flow path from the inflow hole to the outflow hole, a valve element for opening and closing the flow path, and a valve element are provided inside. And a valve seat to be seated, wherein the inner wall of the flow passage and the valve seat have an apparent Zn content of 37 to 46 wt%.
Thus, it can be integrally formed of a brass material having a Sn content of 0.5 to 7 wt%.
【0028】すなわち、本発明によれば、耐エロージョ
ン腐食性に優れた黄銅材料を用いているため、別部材に
て弁座を形成する必要がないのである。That is, according to the present invention, since a brass material having excellent erosion corrosion resistance is used, there is no need to form a valve seat with a separate member.
【0029】この止水部材の流路および弁座は、切削加
工、鍛造により形成されるが、その結晶組織としては、
平均結晶粒径15μm以下とすることにより、熱間鍛造
性の向上を図れるほか、2相以上の結晶組織とすること
により、切削性、耐脱亜鉛腐食性を向上させることがで
きる。The flow path and valve seat of this water-stopping member are formed by cutting or forging.
By setting the average crystal grain size to 15 μm or less, hot forgeability can be improved, and by having a crystal structure of two or more phases, machinability and dezincification corrosion resistance can be improved.
【0030】具体的には、切削性のよいβ相の面積比率
を15%以上にして切削性を確保し、かつβ相中のSn
濃度を1.5wt%以上にして耐脱亜鉛腐食性を確保し
ている。このような結晶組織は、結晶相の変態温度域か
らの冷却速度を制御、例えば急冷することにより、結晶
相比率及び結晶相内のSn濃度を調整して得られる。Specifically, the area ratio of the β phase having good machinability is set to 15% or more to secure the machinability, and Sn in the β phase is secured.
By making the concentration 1.5% by weight or more, dezincification corrosion resistance is secured. Such a crystal structure is obtained by controlling the cooling rate of the crystal phase from the transformation temperature range, for example, by quenching to adjust the crystal phase ratio and the Sn concentration in the crystal phase.
【0031】別の具体例では、耐脱亜鉛腐食性に劣るβ
相の面積比率を2%以下、γ相中のSn濃度を8wt%
以上にして耐脱亜鉛腐食性を確保し、γ相の面積比率を
8〜15%、残部α相としてα、γ相粒界の硬度差によ
り切削性を確保している。このような結晶組織は、α+
γの変態温度域で焼鈍し、β相の面積比率を減少させる
ことにより得られる。In another embodiment, β is poor in dezincification corrosion resistance.
Phase area ratio is 2% or less, Sn concentration in γ phase is 8wt%
As described above, the dezincification corrosion resistance is secured, the area ratio of the γ phase is 8 to 15%, and the machinability is secured by the hardness difference between the α and γ phase grain boundaries as the remaining α phase. Such a crystal structure is α +
It is obtained by annealing in the transformation temperature range of γ to reduce the area ratio of β phase.
【0032】また、このような止水部材が適用されるの
は、吐水装置、特に台所用吐水装置が好適であり、止水
部材が取り付け、取り外し自在である吐水装置にも好適
である。The application of such a water stopping member is preferably a water discharging device, particularly a kitchen water discharging device, and is also suitable for a water discharging device to which the water stopping member can be attached and detached.
【0033】[0033]
【発明の実施の形態】本発明の実施形態は、図1の構成
をそのまま流用するが、従来と異なる点は、図4に示す
黄銅製分岐部材21の材料組成が、見掛け上のZn含有
量が37〜46wt%、Snの含有量を0.5〜7wt
%であって、以下の(1)〜(3)何れかの結晶組織を
有することによって、耐脱亜鉛腐食性確保のための青銅
製ブッシュ22、23を不要とし、黄銅製分岐部材21
の内壁で直接給水路24、給湯路25を形成している点
である。30は、給水分岐出口24c閉塞用のねじ式ま
たはパッキンからなる蓋である。以下に結晶組織を説明
する。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS In the embodiment of the present invention, the structure shown in FIG. 1 is used as it is. The difference from the conventional one is that the material composition of the brass branch member 21 shown in FIG. 37-46 wt%, Sn content 0.5-7 wt%
%, And having any of the following crystal structures (1) to (3) eliminates the need for bronze bushes 22 and 23 for ensuring dezincification corrosion resistance, and the brass branch member 21
Is that water supply channel 24 and hot water supply channel 25 are formed directly on the inner wall of the device. Reference numeral 30 denotes a screw-type or packing lid for closing the water supply branch outlet 24c. The crystal structure will be described below.
【0034】(1)α+β相の2相で、β相の面積比率
が15%以上、残部α相、α、β相の平均結晶粒径が1
5μm以下、β相中のSn濃度が1.5wt%以上。(1) Two phases of α + β phase, the area ratio of β phase is 15% or more, and the average crystal grain size of the remaining α phase, α, β phase is 1
5 μm or less, Sn concentration in β phase is 1.5 wt% or more.
【0035】(2)α+γ相の2相が主体で、β相の面
積比率が2%未満、γ相の面積比率が8〜15%、残部
α相、α相の平均結晶粒径が15μm以下、γ相の平均
結晶粒径(短径)が8μm以下であって、α相の粒界に
γ相が散在しており、γ相中のSn濃度が8wt%以
上。(2) Mainly two phases of α + γ phase, the area ratio of β phase is less than 2%, the area ratio of γ phase is 8 to 15%, and the average crystal grain size of the remaining α phase and α phase is 15 μm or less. The average crystal grain size (minor diameter) of the γ phase is 8 μm or less, the γ phase is scattered at the grain boundaries of the α phase, and the Sn concentration in the γ phase is 8 wt% or more.
【0036】(3)α+β+γ相の3相で、α相の面積
比率が40〜94%、β相の面積比率が3〜30%、γ
相の面積比率が3〜30%、γ相中のSn濃度が8wt
%以上であって、γ相がβ相を囲むように配置されてい
る。(3) The α + β + γ phase has an α-phase area ratio of 40 to 94%, a β-phase area ratio of 3 to 30%, and γ
The area ratio of the phase is 3 to 30%, and the Sn concentration in the γ phase is 8 wt.
% Or more, and the γ phase is arranged so as to surround the β phase.
【0037】結晶組織(1)は、結晶相の変態温度域以
上(例えば650℃)から、水冷等により急冷すること
により得られ、結晶組織(2)は、α+γの変態温度域
(例えば450℃)で2h焼鈍し、β相の面積比率を減
少させることにより得られる。そして結晶組織(3)
は、結晶相の変態温度域以上(例えば650℃)から、
結晶組織(1)に比べて冷却速度をやや遅くすることに
より得られる。The crystal structure (1) is obtained by quenching with a water-cooling or the like from a temperature higher than the transformation temperature range of the crystal phase (for example, 650 ° C.), and the crystal structure (2) is obtained by the transformation temperature range of α + γ (for example, 450 ° C.). ) For 2 h to reduce the area ratio of the β phase. And the crystal structure (3)
From above the transformation temperature range of the crystalline phase (eg 650 ° C.)
It can be obtained by slightly lowering the cooling rate as compared with the crystal structure (1).
【0038】ここで、「見掛け上のZn含有量」という
用語は、AをCu含有量〔wt%〕、BをZn含有量
〔wt%〕、tを添加した第3元素(例えばSn)のZ
n当量、Qをその第3元素の含有量〔wt%〕としたと
き、「{(B+t・Q)/(A+B+t・Q)}×10
0」の意味で用いる。Here, the term "apparent Zn content" means that A is Cu content [wt%], B is Zn content [wt%], and t is the third element (for example, Sn). Z
When n equivalents and Q are the content of the third element [wt%], “{(B + t · Q) / (A + B + t · Q)} × 10
0 ”is used.
【0039】これら(1)、(2)の結晶組織によれ
ば、以下の(A)〜(C)の特性が得られる。According to the crystal structures (1) and (2), the following characteristics (A) to (C) can be obtained.
【0040】(A)日本工業規格JIS C−3604
に従う快削黄銅棒を基準とした切削抵抗指数が80以上
の特性。(A) Japanese Industrial Standard JIS C-3604
A cutting resistance index of 80 or more based on a free-cutting brass bar according to
【0041】(B)日本伸銅協会技術標準JBMA T
−303に従う脱亜鉛腐食試験を行なったとき、最大脱
亜鉛浸透深さ方向が加工方向と平行な場合には最大脱亜
鉛深さ100μm以下、又は最大脱亜鉛浸透深さ方向が
加工方向と直角な場合には最大脱亜鉛深さ70μm以下
の耐食性を満たす特性。尚、鍛造品の場合は、日本伸銅
協会技術標準JBMA T−303に従う脱亜鉛腐食試
験を行なったとき、最大脱亜鉛浸透深さ方向が加工方向
と直角な場合に該当し、最大脱亜鉛深さ70μm以下の
耐食性を満たす特性を満たすものとする。(B) Japan Copper and Brass Association Technical Standard JBMA T
When performing a dezincification corrosion test in accordance with -303, if the maximum dezincification depth direction is parallel to the processing direction, the maximum dezincification depth is 100 μm or less, or the maximum dezincification depth direction is perpendicular to the processing direction. In this case, the properties satisfy the corrosion resistance with a maximum dezincing depth of 70 μm or less. In the case of a forged product, when a dezincification corrosion test was conducted in accordance with the Japan Copper and Brass Association Technical Standard JBMA T-303, this corresponds to the case where the maximum dezincification penetration depth direction is perpendicular to the processing direction. It shall satisfy the characteristics satisfying the corrosion resistance of 70 μm or less.
【0042】(C)円筒形試料を14%アンモニア水溶
液上のアンモニア雰囲気中に荷重を加えながら24時間
暴露したとき、試料が割れない最大応力が180N/m
m2以上の特性。(C) When a cylindrical sample was exposed to an ammonia atmosphere on a 14% ammonia aqueous solution for 24 hours while applying a load, the maximum stress at which the sample was not cracked was 180 N / m.
Characteristics of m2 or more.
【0043】(A)の切削抵抗指数について図5を用い
て詳説すると、切削試験では、旋盤で丸棒状の試料31
の周面を100〔m/min〕と400〔m/min〕
の2つの異なる速度で切削しつつ、主分力Fvを測定し
た。切削抵抗指数は、主分力に対する切削性が最も良い
といわれる快削黄銅棒(日本工業規格JIS C−36
04)の主分力の百分率である。(切削速度毎の切削抵
抗指数を平均した。)The cutting resistance index of (A) will be described in detail with reference to FIG. 5. In the cutting test, a round bar-shaped sample 31 is turned on a lathe.
100 m / min and 400 m / min
The main component force Fv was measured while cutting at two different speeds. The cutting resistance index is a free-cutting brass bar (Japanese Industrial Standard JIS C-36) which is said to have the best machinability for the main component force.
04) is the percentage of the main component. (The cutting resistance index for each cutting speed was averaged.)
【0044】(C)の耐SCC性試験は、図6に示すよ
うに、ガラスデジケータ32内で円筒状の試料33に垂
直に荷重を加えた状態で、NH3蒸気雰囲気中に24時
間暴露した後、割れの発生を調査した。In the (C) SCC resistance test, as shown in FIG. 6, a cylindrical sample 33 was exposed to an NH3 vapor atmosphere for 24 hours in a state where a load was applied vertically to the cylindrical sample 33 in the glass digitizer 32. Later, the occurrence of cracks was investigated.
【0045】また、結晶組織(1)、(2)によれば、
耐エロージョン腐食性にも良好な特性を示す。図7は、
その耐エロージョン腐食性試験の方法を示している。耐
エロージョン腐食性試験では、図7に示すように、オリ
フィス34を内部に有する円筒状試料35を用い、その
オリフィス34に水を流速40m/secで所定時間流
した後、4.9×105Pa(5Kg/cm2)の水圧
下でオリフィス34をシールするのに要する樹脂栓36
への締めつけトルクを測定した。According to the crystal structures (1) and (2),
Also shows good characteristics in erosion corrosion resistance. FIG.
The method of the erosion corrosion resistance test is shown. In the erosion corrosion resistance test, as shown in FIG. 7, a cylindrical sample 35 having an orifice 34 therein was used, and water was flowed through the orifice 34 at a flow rate of 40 m / sec for a predetermined time, and then 4.9 × 10 5 Resin stopper 36 required to seal orifice 34 under water pressure of Pa (5 kg / cm 2)
The tightening torque for the was measured.
【0046】図7の試験の結果は図8に示す通りであ
り、結晶組織(1)、(2)の黄銅材は従来例よりも良
好な特性を得た。尚、従来例にはSnの含有量が0.5
wt%未満のものを用いた。The results of the test shown in FIG. 7 are as shown in FIG. 8, and the brass material having the crystal structures (1) and (2) obtained better characteristics than the conventional example. In the conventional example, the Sn content was 0.5%.
Less than wt% was used.
【0047】また、上記(1)、(2)の結晶組織によ
れば、鍛造時には、(3)480〜650℃で、β相比
率が30〜80%、平均結晶粒径が15μm以下の結晶
組織が得られ、0.00083/secの歪み速度で1
60%の歪みを与えて破損の無いこと、0.0083/
secの歪み速度で50%の歪みを与えて破損の無いこ
と、0.083/secの歪み速度で30%の歪みを与
えて破損の無いこと、の少なくとも一つを満たす延性が
実現できる。According to the crystal structures of the above (1) and (2), at the time of forging, (3) a crystal having a β phase ratio of 30 to 80% and an average crystal grain size of 15 μm or less at 480 to 650 ° C. A tissue is obtained, and at a strain rate of 0.00083 / sec.
No damage due to 60% strain, 0.0083 /
Ductility that satisfies at least one of: applying 50% strain at a strain rate of sec to provide no damage and applying 30% strain at a strain rate of 0.083 / sec to provide no damage.
【0048】これにより、650℃以下の温度で鍛造し
ても十分な伸びが確保できて、700℃以上の高温鍛造
時に生じる脱亜鉛や酸化被膜付着が抑えられて、鍛造後
の研磨工程が削減できる。As a result, sufficient elongation can be ensured even when forging is performed at a temperature of 650 ° C. or less, dezincification and adhesion of an oxide film that occur during high-temperature forging at 700 ° C. or more are reduced, and the polishing process after forging is reduced. it can.
【0049】さらに、Snの含有量を1.5〜4.0%
に限定することによって、(4)300〜550℃で、
α相の比率が44〜65%、β相の比率が10〜55
%、γ相の比率が1〜25%、平均結晶粒径15μm以
下の結晶組織を有し、0.00083/secの歪み速
度で50%の歪みを与えて破損の無いこと、0.008
3/secの歪み速度で25%の歪みを与えて破損の無
いこと、0.083/secの歪み速度で30%の歪み
を与えて破損の無いこと、の少なくとも一つを満たす延
性が実現できる。Further, the content of Sn is set to 1.5 to 4.0%.
By limiting to (4) 300 to 550 ° C.,
The ratio of the α phase is 44 to 65%, and the ratio of the β phase is 10 to 55.
%, The ratio of the γ phase is 1 to 25%, and the crystal structure has an average crystal grain size of 15 μm or less, and a strain of 50% is given at a strain rate of 0.00083 / sec without breakage.
Ductility that satisfies at least one of the following: no damage by applying 25% strain at a strain rate of 3 / sec and no damage by applying 30% strain at a strain rate of 0.083 / sec. .
【0050】これにより、550℃以下の温度で鍛造し
ても高い延性が得られるため、脱亜鉛や酸化被膜付着を
さらに低減できるのである。As a result, high ductility can be obtained even when forging is performed at a temperature of 550 ° C. or lower, so that dezincification and adhesion of an oxide film can be further reduced.
【0051】これらの特性についての試験片の形状、寸
法(標点間距離12mm、外径φ2.5mm)を図9に、
試験条件を図10に示す。使用した引っ張り試験機は機
械式を用い、加熱は電気ヒータで、雰囲気は大気中とし
た。FIG. 9 shows the shape and dimensions (distance between gauges of 12 mm and outer diameter of φ2.5 mm) of the test pieces for these characteristics.
The test conditions are shown in FIG. The tensile tester used was a mechanical type, the heating was an electric heater, and the atmosphere was air.
【0052】図11は温度と伸びの関係を示しており、
450℃において結晶組織(4)が従来例に比べて高い
伸びを示していることがわかる。ここで、従来例には、
450℃で、α+β、β<25%、平均粒径>15μm
の結晶構造のものを用いた。FIG. 11 shows the relationship between temperature and elongation.
It can be seen that the crystal structure (4) shows a higher elongation at 450 ° C. than the conventional example. Here, in the conventional example,
At 450 ° C., α + β, β <25%, average particle size> 15 μm
With a crystal structure of
【0053】尚、本発明に係る別の実施形態としては、
図2、3における青銅製ブッシュ22、23に代えて、
上記示した見掛け上のZn含有量が37〜46wt%、
Snの含有量が0.5〜7wt%の材料組成、上記
(1)、(2)何れかの結晶組織を有する黄銅材料から
なるブッシュ22、23を用いるようにしても良い。As another embodiment according to the present invention,
Instead of the bronze bushes 22, 23 in FIGS.
The apparent Zn content shown above is 37 to 46 wt%,
The bushes 22 and 23 made of a brass material having a material composition having a Sn content of 0.5 to 7 wt% and having any one of the crystal structures (1) and (2) above may be used.
【0054】また、図2〜4のように、給水出口24b
と給湯出口25bを有する分岐部材21だけでなく、給
水出口24bと給湯出口25bの何れか一方しか有しな
い分岐部材21に、上記材料組成、結晶組織を適用して
も良いことは言うまでもない。Also, as shown in FIGS.
Needless to say, the above-described material composition and crystal structure may be applied not only to the branch member 21 having the hot water supply outlet 25b but also to the branch member 21 having only one of the water supply outlet 24b and the hot water supply outlet 25b.
【0055】さらに、分岐流出孔に連通する末端機器と
しては、食器洗い器、浄水器、アルカリイオン整水器等
の機器が有り、給水仕様の機器の場合は分岐流出孔から
給水し、給湯仕様の機器の場合は、分岐流出孔から給湯
すればよい。Further, as end devices communicating with the branch outlet, there are devices such as a dishwasher, a water purifier, and an alkali ion water conditioner. In the case of a water supply type device, water is supplied from the branch outlet and a hot water supply type. In the case of equipment, hot water may be supplied from the branch outlet.
【0056】図12は、本発明の他の実施形態としての
止水部材を具備する吐水装置であって、この吐水装置
は、混合栓40と給水取り付け脚41が、パッキン4
2、スペーサ43、パッキン44を介して接続され、混
合栓40と給湯取り付け脚51が、パッキン52、チー
ズ53、パッキン54を介して接続される。FIG. 12 shows a water discharging device provided with a water stopping member according to another embodiment of the present invention. In this water discharging device, a mixing tap 40 and a water supply mounting leg 41 are attached to a packing 4.
2, are connected via a spacer 43 and a packing 44, and the mixing tap 40 and the hot water supply attachment leg 51 are connected via a packing 52, a cheese 53 and a packing 54.
【0057】チーズ53には、また、パッキン61、止
水部材62、ストレーナ63を介して給湯ホース64が
接続されており、止水部材62には、ビス65により止
水レバー66が取り付けられている。A hot water supply hose 64 is connected to the cheese 53 via a packing 61, a water stopping member 62, and a strainer 63, and a water stopping lever 66 is attached to the water stopping member 62 by a screw 65. I have.
【0058】図13は、止水部材62の詳細図であり、
止水部材62には、入口71、出口72、弁座73が形
成される他、止水レバー66の操作に連動して進退する
弁体74が内蔵されている。FIG. 13 is a detailed view of the water stopping member 62.
The water stop member 62 includes an inlet 71, an outlet 72, and a valve seat 73, and a built-in valve 74 that moves forward and backward in response to the operation of the water stop lever 66.
【0059】そして、この入口71から弁座73を経て
出口72に至る流路部分は、見掛け上のZn含有量が3
7〜46wt%、Snの含有量を0.5〜7wt%の黄
銅材料により一体で形成されているのである。そして、
その結晶組織は、上記分岐部材21と同様に結晶組織
(1)〜(4)をとるようにしているから、上記分岐部
材21と同様に、切削性、耐食性、耐SCC性、耐エロ
ージョン腐食性、熱間鍛造性に優れた特性を有するので
ある。The flow path from the inlet 71 to the outlet 72 through the valve seat 73 has an apparent Zn content of 3%.
It is formed integrally from a brass material having a content of 7 to 46 wt% and a Sn content of 0.5 to 7 wt%. And
Since the crystal structure takes the crystal structures (1) to (4) in the same manner as the branch member 21, the cutability, the corrosion resistance, the SCC resistance, and the erosion corrosion resistance are the same as in the branch member 21. It has excellent hot forgeability.
【0060】特に、耐エロージョン腐食性に優れた特性
を生かすことにより、図14のように弁座73を含む部
分Aを青銅製、他の部分Bを一般黄銅とする必要がなく
なったのである。In particular, by making use of the characteristics excellent in erosion corrosion resistance, it is not necessary to make the portion A including the valve seat 73 made of bronze and the other portion B made of general brass as shown in FIG.
【図1】本発明の実施形態および従来技術に係る水路分
岐部材を具備する吐水装置FIG. 1 is a perspective view of a water discharge device including a waterway branching member according to an embodiment of the present invention and a conventional technology.
【図2】従来の水路分岐部材に係る分岐金具2の詳細図FIG. 2 is a detailed view of a branch fitting 2 according to a conventional waterway branch member.
【図3】同従来技術に係る分岐部材21の断面図FIG. 3 is a cross-sectional view of a branch member 21 according to the related art.
【図4】本発明の実施形態に係る分岐部材21の断面図FIG. 4 is a sectional view of a branch member 21 according to the embodiment of the present invention.
【図5】同実施形態の切削試験の説明図FIG. 5 is an explanatory diagram of a cutting test of the embodiment.
【図6】同実施形態の耐応力腐食割れ性(耐SCC性)
試験の説明図FIG. 6 shows stress corrosion cracking resistance (SCC resistance) of the embodiment.
Illustration of test
【図7】同実施形態の耐エロージョン腐食性試験の説明
図FIG. 7 is an explanatory diagram of an erosion corrosion resistance test of the same embodiment.
【図8】同実施形態の耐エロージョン腐食性試験結果FIG. 8 shows the results of an erosion corrosion resistance test of the same embodiment.
【図9】同実施形態の高温引張り試験片形状FIG. 9 shows the shape of a high-temperature tensile test piece of the embodiment.
【図10】同実施形態の高温引張り試験条件FIG. 10 shows high-temperature tensile test conditions of the embodiment.
【図11】同実施形態と従来例の高温引張り試験結果
(温度と延びの関係)FIG. 11 shows the results of a high-temperature tensile test of the embodiment and a conventional example (relation between temperature and elongation).
【図12】本発明の他の実施形態に係る止水部材を具備
する吐水装置FIG. 12 is a water discharge device including a water stopping member according to another embodiment of the present invention.
【図13】同実施形態に係る止水部材62の断面図FIG. 13 is a sectional view of a water stopping member 62 according to the same embodiment.
【図14】従来の止水部材62の断面図FIG. 14 is a cross-sectional view of a conventional water stop member 62.
1…吐水装置本体、1a…吐水口、2…分岐金具、3…
カートリッジ、4…カバーナット、5…カバー、6…レ
バーハンドル、7…分岐出口、8…袋ナット、9…スト
レーナ、10…止水栓、11…パッキン、12…給湯ホ
ース、21…分岐部材、22…長めのブッシュ、23…
短めのブッシュ、24…給水路、24a…給水入口、2
4b…給水出口、24c…給水分岐出口、25…給湯
路、25a…給湯入口、25b…給湯出口、25c…給
湯分岐出口、26…混合湯入口、27、28…Oリン
グ、40…混合栓、41…給水取り付け脚、42…パッ
キン、43…スペーサ、44…パッキン、51…給湯取
り付け脚、52…パッキン、53…チーズ、54…パッ
キン、61…パッキン、62…止水部材、63…ストレ
ーナ、64…給湯ホース、65…ビス、66…止水レバ
ー、71…入口、72…出口、73…弁座、74…弁体DESCRIPTION OF SYMBOLS 1 ... Water discharge apparatus main body, 1a ... Water discharge port, 2 ... Branch metal fitting, 3 ...
Cartridge, 4 cover nut, 5 cover, 6 lever handle, 7 branch outlet, 8 cap nut, 9 strainer, 10 water stopcock, 11 packing, 12 hot water supply hose, 21 branch member, 22 ... longer bush, 23 ...
Short bush, 24 ... water supply channel, 24a ... water supply inlet, 2
4b: Water supply outlet, 24c: Water supply branch outlet, 25: Hot water supply path, 25a: Hot water supply inlet, 25b: Hot water supply outlet, 25c: Hot water supply branch outlet, 26: Mixed hot water inlet, 27, 28: O-ring, 40: Mixing tap, 41: Water supply mounting leg, 42: Packing, 43: Spacer, 44: Packing, 51: Hot water supply mounting leg, 52: Packing, 53: Cheese, 54: Packing, 61: Packing, 62: Water blocking member, 63: Strainer, 64 hot water supply hose, 65 screws, 66 water stop lever, 71 inlet, 72 outlet, 73 valve seat, 74 valve body
───────────────────────────────────────────────────── フロントページの続き (72)発明者 中尾 健一郎 福岡県北九州市小倉北区中島2丁目1番1 号 東陶機器株式会社内 Fターム(参考) 2D060 BB09 BD01 ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Kenichiro Nakao 2-1-1 Nakajima, Kokurakita-ku, Kitakyushu-shi, Fukuoka F-term (in reference) 2D060 BB09 BD01
Claims (19)
備え、内部には、前記流入孔から前記流出孔に至る主流
路と、前記主流路から分岐して前記分岐流出孔に至る分
岐流路と、を形成してなる水路分岐部材において、 前記主流路内壁、前記分岐流路内壁の少なくとも一部
が、見掛け上のZn含有量が37〜46wt%で、Sn
の含有量が0.5〜7wt%である黄銅材料を具備して
なる水路分岐部材。An outer wall includes an inflow hole, an outflow hole, and a branch outflow hole. Inside the main passage, the main flow passage extends from the inflow hole to the outflow hole, and a branch branches from the main flow passage to the branch outflow hole. And a flow path branch member formed with a flow path, wherein at least a part of the main flow path inner wall and the branch flow path inner wall has an apparent Zn content of 37 to 46 wt%,
A channel branch member comprising a brass material having a content of 0.5 to 7 wt%.
なる請求項1記載の水路分岐部材。2. The waterway branch member according to claim 1, comprising a plurality of the main flow paths and the branch flow paths.
前記水流路の水と前記湯流路の湯の混合湯流路と、であ
る請求項1または2記載の水路分岐部材。3. The main flow path includes a water flow path, a hot water flow path,
The water channel branching member according to claim 1 or 2, wherein the water channel is a mixed hot water flow channel of the water and the hot water flow channel.
流路内壁、分岐流路内壁の少なくとも一部は、切削加工
により形成される請求項1〜3の何れか記載の水路分岐
部材。4. The channel branching member according to claim 1, wherein at least a part of the inner wall of the main channel and the inner wall of the branch channel formed of the brass material are formed by cutting.
流路内壁、分岐流路内壁の少なくとも一部は、鍛造によ
り形成される請求項1〜3の何れか記載の水路分岐部
材。5. The channel branch member according to claim 1, wherein at least a part of the main channel inner wall and the branch channel inner wall made of the brass material are formed by forging.
流路内壁、分岐流路内壁の少なくとも一部は、基材に挿
入された管材により形成される請求項1〜3の何れか記
載の水路分岐部材。6. The waterway branch according to claim 1, wherein at least a part of the inner wall of the main flow path and the inner wall of the branch flow path made of the brass material are formed of a pipe material inserted into a base material. Element.
とともに、前記管材は、前記基材に挿入することにより
前記分岐流路を閉塞するものである請求項6記載の水路
分岐部材。7. The waterway branching member according to claim 6, comprising a plurality of the main flow passages and the branch flow passages, and wherein the pipe member closes the branch flow passages by being inserted into the base material.
m以下の結晶組織を有してなる請求項1〜7の何れか記
載の水路分岐部材。8. The brass material has an average crystal grain size of 15 μm.
The channel branch member according to any one of claims 1 to 7, which has a crystal structure of m or less.
を有してなる請求項8記載の水路分岐部材。9. The channel branch member according to claim 8, wherein the brass material has a crystal structure of two or more phases.
15%以上であり、かつβ相中のSn濃度が1.5wt
%以上である結晶組織を有してなる請求項1〜9の何れ
か記載の水路分岐部材。10. The brass material has an area ratio of β phase of 15% or more and an Sn concentration in β phase of 1.5 wt.
%. The waterway branching member according to claim 1, having a crystal structure of not less than 10%.
相で、α相の面積比率が40〜94%、β相の面積比率
が3〜30%、γ相の面積比率が3〜30%、γ相中の
Sn濃度が8wt%以上であって、γ相がβ相を囲む結
晶組織を有してなる請求項1〜9の何れか記載の水路分
岐部材。11. The brass material comprises an α + β + γ phase 3
In the phase, the area ratio of the α phase is 40 to 94%, the area ratio of the β phase is 3 to 30%, the area ratio of the γ phase is 3 to 30%, and the Sn concentration in the γ phase is 8 wt% or more, The channel branch member according to any one of claims 1 to 9, wherein the γ phase has a crystal structure surrounding the β phase.
域からの冷却速度を制御することにより、結晶相比率及
び結晶相内のSn濃度が調整されたものである請求項1
〜11の何れか記載の水路分岐部材。12. The brass material having a crystal phase ratio and a Sn concentration in the crystal phase adjusted by controlling a cooling rate of the crystal phase from a transformation temperature range.
12. The waterway branching member according to any one of items 11 to 11.
2%以下、γ相の面積比率が8〜15%、残部α相であ
るとともに、γ相中のSn濃度が8wt%以上である結
晶組織を有してなる請求項1〜9の何れか記載の水路分
岐部材。13. The brass material has an area ratio of a β phase of 2% or less, an area ratio of a γ phase of 8 to 15%, a balance of an α phase, and a Sn concentration in the γ phase of 8% by weight or more. The channel branch member according to any one of claims 1 to 9, which has a crystal structure.
域で焼鈍することにより、β相の面積比率を減少させた
ものである請求項1〜9、13の何れか記載の水路分岐
部材。14. The waterway branching member according to claim 1, wherein the brass material has a reduced area ratio of the β phase by annealing in an α + γ transformation temperature range.
分岐部材を具備してなる吐水装置。15. A water discharge device comprising the waterway branching member according to claim 1. Description:
載の水路分岐部材を具備してなる吐水装置。16. A water discharging device comprising the water channel branching member according to claim 15, which is a kitchen water discharging device.
取り付け、取り外し自在である請求項15または16記
載の水路分岐部材を具備してなる吐水装置。17. A water discharge device comprising the water channel branch member according to claim 15, wherein the water channel branch member is detachably attached to the water discharge device.
には、前記流入孔から前記流出孔に至る流路と、この流
路を開閉する弁体と、この弁体が着座する弁座と、を具
備してなる止水部材において、 前記流路内壁および前記弁座を、見掛け上のZn含有量
が37〜46wt%で、Snの含有量が0.5〜7wt
%である黄銅材料にて一体で形成してなる止水部材。18. An outer wall having an inflow hole and an outflow hole, and a flow passage from the inflow hole to the outflow hole, a valve body for opening and closing the flow passage, and a valve seat on which the valve body is seated. Wherein the apparent Zn content is 37 to 46 wt% and the Sn content is 0.5 to 7 wt%.
% Water-blocking member that is integrally formed of brass material that is
てなる吐水装置。19. A water discharging apparatus comprising the water stopping member according to claim 18.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10186980A JP2000001884A (en) | 1998-06-17 | 1998-06-17 | Water path branch member, water stop member and discharge device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10186980A JP2000001884A (en) | 1998-06-17 | 1998-06-17 | Water path branch member, water stop member and discharge device |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2000001884A true JP2000001884A (en) | 2000-01-07 |
Family
ID=16198104
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP10186980A Pending JP2000001884A (en) | 1998-06-17 | 1998-06-17 | Water path branch member, water stop member and discharge device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2000001884A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001323527A (en) * | 2000-05-12 | 2001-11-22 | San-Ei Faucet Mfg Co Ltd | One-hole-type hot-water branched combination faucet |
KR20140014196A (en) * | 2011-03-31 | 2014-02-05 | 닛뽄 케미콘 가부시끼가이샤 | Electrode body for solar cells, method for producing same, and solar cell provided with electrode body |
KR20140014228A (en) * | 2011-03-31 | 2014-02-05 | 닛뽄 케미콘 가부시끼가이샤 | Electrode for solar cell, manufacturing method therefor, and solar cell provided with electrode |
-
1998
- 1998-06-17 JP JP10186980A patent/JP2000001884A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001323527A (en) * | 2000-05-12 | 2001-11-22 | San-Ei Faucet Mfg Co Ltd | One-hole-type hot-water branched combination faucet |
JP4504510B2 (en) * | 2000-05-12 | 2010-07-14 | 株式会社三栄水栓製作所 | One-hole hot water branch mixer tap |
KR20140014196A (en) * | 2011-03-31 | 2014-02-05 | 닛뽄 케미콘 가부시끼가이샤 | Electrode body for solar cells, method for producing same, and solar cell provided with electrode body |
KR20140014228A (en) * | 2011-03-31 | 2014-02-05 | 닛뽄 케미콘 가부시끼가이샤 | Electrode for solar cell, manufacturing method therefor, and solar cell provided with electrode |
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